CN106747149A - A kind of corrosion resistant type reinforced concrete sewer pipe of Stainless-steel fibre and preparation method thereof - Google Patents
A kind of corrosion resistant type reinforced concrete sewer pipe of Stainless-steel fibre and preparation method thereof Download PDFInfo
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- CN106747149A CN106747149A CN201611157939.4A CN201611157939A CN106747149A CN 106747149 A CN106747149 A CN 106747149A CN 201611157939 A CN201611157939 A CN 201611157939A CN 106747149 A CN106747149 A CN 106747149A
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- reinforced concrete
- steel fibre
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- corrosion resistant
- sewer pipe
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- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B28/00—Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements
- C04B28/02—Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements containing hydraulic cements other than calcium sulfates
- C04B28/08—Slag cements
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B14/00—Use of inorganic materials as fillers, e.g. pigments, for mortars, concrete or artificial stone; Treatment of inorganic materials specially adapted to enhance their filling properties in mortars, concrete or artificial stone
- C04B14/02—Granular materials, e.g. microballoons
- C04B14/04—Silica-rich materials; Silicates
- C04B14/08—Diatomaceous earth
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B14/00—Use of inorganic materials as fillers, e.g. pigments, for mortars, concrete or artificial stone; Treatment of inorganic materials specially adapted to enhance their filling properties in mortars, concrete or artificial stone
- C04B14/02—Granular materials, e.g. microballoons
- C04B14/04—Silica-rich materials; Silicates
- C04B14/10—Clay
- C04B14/104—Bentonite, e.g. montmorillonite
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B14/00—Use of inorganic materials as fillers, e.g. pigments, for mortars, concrete or artificial stone; Treatment of inorganic materials specially adapted to enhance their filling properties in mortars, concrete or artificial stone
- C04B14/02—Granular materials, e.g. microballoons
- C04B14/04—Silica-rich materials; Silicates
- C04B14/10—Clay
- C04B14/106—Kaolin
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B14/00—Use of inorganic materials as fillers, e.g. pigments, for mortars, concrete or artificial stone; Treatment of inorganic materials specially adapted to enhance their filling properties in mortars, concrete or artificial stone
- C04B14/38—Fibrous materials; Whiskers
- C04B14/48—Metal
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B24/00—Use of organic materials as active ingredients for mortars, concrete or artificial stone, e.g. plasticisers
- C04B24/24—Macromolecular compounds
- C04B24/28—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- C04B24/281—Polyepoxides
-
- E—FIXED CONSTRUCTIONS
- E03—WATER SUPPLY; SEWERAGE
- E03F—SEWERS; CESSPOOLS
- E03F3/00—Sewer pipe-line systems
- E03F3/04—Pipes or fittings specially adapted to sewers
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2111/00—Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
- C04B2111/20—Resistance against chemical, physical or biological attack
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2111/00—Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
- C04B2111/20—Resistance against chemical, physical or biological attack
- C04B2111/23—Acid resistance, e.g. against acid air or rain
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Ceramic Engineering (AREA)
- Materials Engineering (AREA)
- Structural Engineering (AREA)
- Organic Chemistry (AREA)
- Civil Engineering (AREA)
- Dispersion Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Inorganic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Hydrology & Water Resources (AREA)
- Public Health (AREA)
- Water Supply & Treatment (AREA)
- Curing Cements, Concrete, And Artificial Stone (AREA)
- Rigid Pipes And Flexible Pipes (AREA)
Abstract
Corrosion resistant type reinforced concrete sewer pipe the invention discloses a kind of Stainless-steel fibre and preparation method thereof, it is characterized in that, with flyash, slag powders, metakaolin, gypsum, sodium sulphate, naphthalene series high-efficiency water-reducing agent, sand, rubble, bisphenol A type epoxy resin E 44, benzoyl peroxide, acrylic acid, N, N dimethylethanolamines, organo montmorillonite, cement, steel fibre, calcined diatomite, reinforcing bar etc. are raw material.The present invention is prepared for aqueous epoxy resins by the method for graft copolymerization, is applied in modified cement-concrete, obtains the network structure of polymer and concrete base material IPN；With organo montmorillonite as filler, it is added in aqueous epoxy resins matrix using high polymeric solution graft process, prepares aqueous epoxy resins/Nano composite material of montmorillonite；Uniform magnetic field is applied to steel fiber reinforced concrete mixture, the steel fiber reinforced concrete of unidirectional distribution is prepared, fiber utilization rate is high, and enhancing effect is good.
Description
Technical field
The present invention relates to a kind of preparation method of reinforced concrete sewer pipe, and in particular to a kind of corrosion resistant of Stainless-steel fibre
Erosion shaped steel reinforced concrete drainage pipe and preparation method thereof.
Background technology
With the development of urban construction, start to build sewage treatment plant, substantial amounts of industrial wastewater and sanitary sewage need logical
Cross drainpipe and enter sewage treatment plant, and black water usually containing acid or other corrosive substances and concentration difference, this
Require that drainpipe has stronger decay resistance.
Liu Yuanxiang exists《The research and the application in drainpipe of alkali-activated slag flyash concrete performance》In one text, with
Flyash, slag, alkali-activator, FKJ special additives, sandstone aggregate etc. are raw material, are prepared for alkali ore slag fly ash coagulation
Soil；Stone is first put into during feeding, powder is then put into, then puts into sand, be eventually adding liquid exciting agent and water, use overhang roll legal system
Plumber's skill produces acidproof, alkali corrosion resistance concrete drain tile；Concrete drain tile uses steam curing, steam curing system point
For it is quiet stop, heat up, constant temperature, cooling four-stage.But it is not enough to there is decay resistance in gained drainpipe.
The present invention with the addition of metakaolin, have good filing effect and volcano ash effect in concrete；The present invention
With epoxy resin, acrylic acid as raw material, salt forming agent N, N- dimethylethanolamine is added, water is prepared for by the method for graft copolymerization
Property epoxy resin, is applied in modified cement-concrete, obtains the network structure of polymer and concrete base material IPN；This hair
It is bright to be added in aqueous epoxy resins matrix using high polymeric solution graft process with organo montmorillonite as filler, prepare
Aqueous epoxy resins/Nano composite material of montmorillonite；The characteristics of calcined diatomite has specific surface area high, finer grain size, uses
Carry out fill concrete cement matrix internal void, so as to improve the packing of concrete substrate, mechanical property, impervious freeze proof
Property；Uniform magnetic field is applied to steel fiber reinforced concrete mixture, the steel fiber reinforced concrete of unidirectional distribution, fiber utilization rate is prepared
Height, enhancing effect is good.Obtain a kind of corrosion resistant type reinforced concrete sewer pipe of Stainless-steel fibre.
The content of the invention
The present invention solves the technical problem of a kind of corrosion resistant type armored concrete draining of Stainless-steel fibre of offer
Pipe and preparation method thereof, according to the technique prepare reinforced concrete sewer pipe mechanical property it is good, intensity is high, decay resistance
It is good.
The technical problems to be solved by the invention are realized using following technical scheme：
Flyash 10-15, slag powders 10-15, metakaolin 2-4, gypsum 1-2, sodium sulphate 4-6, naphthalene series high-efficiency water-reducing agent 1-3,
Sand 15-20, rubble 5-10, bisphenol A type epoxy resin E-44 3-5, benzoyl peroxide 2-3, acrylic acid 2-4, N, N- dimethyl
Monoethanolamine 1-2, organo montmorillonite 2-3, cement 5-10, steel fibre 3-6, calcined diatomite 2-3, reinforcing bar 6-9, propylene glycol monomethyl ether,
Appropriate amount of water.
The preparation method of the corrosion resistant type reinforced concrete sewer pipe of a kind of Stainless-steel fibre, it is characterised in that by following
Step is carried out：
A. flyash is mixed after mechanical grinding with slag powders, metakaolin, stir to obtain Binder Materials；
B. by gypsum, sodium sulphate mixing and ball milling it is uniform exciting agent, add resulting material in a with naphthalene series high-efficiency water-reducing agent, then with
2:4-6 adds sand and water, stirs to obtain mortar, adds the rubble of particle diameter 5-25mm, stirs 30-50min；
C. by bisphenol A type epoxy resin E-44 with 1:3-5 is dissolved in propylene glycol monomethyl ether, adds benzoyl peroxide, acrylic acid,
It is warming up to 105-115 DEG C of reaction 2-3h, stirring lower 1:4-6 adds N, N- dimethylethanolamines and water, and tune pH is 7-8, and addition has
Machine montmorillonite, 80-90 DEG C is reacted 1-2h, stand-by；
D. resulting material in a, b, c is mixed, adds cement, steel fibre, calcined diatomite, stirred, mixture is applied
Uniform magnetic field；
E. by reinforcing bar treatment obtain framework of steel reinforcement shaping, by d resulting material input wherein, start overhang-roll tubing machine, overhang roll into
Type, steam curing, the demoulding, obtain a kind of corrosion resistant type reinforced concrete sewer pipe of Stainless-steel fibre.
Reaction mechanism of the invention is as follows：
（1）Metakaolin is a kind of high-activity mineral blending material, and there is good filing effect and volcanic ash to imitate in concrete
Should, microstructure, intensity and the durability of concrete can be improved.
（2）With epoxy resin, acrylic acid as raw material, salt forming agent N, N- dimethylethanolamine is added, by graft copolymerization
Method is prepared for aqueous epoxy resins, is applied in modified cement-concrete, obtains polymer with concrete base material IPN
Network structure, composite has the characteristics of tensile strength is high, water absorption rate is low, and compressive strength loss is small.
（3）With organo montmorillonite as filler, aqueous epoxy resins matrix is added to using high polymeric solution graft process
In, aqueous epoxy resins/Nano composite material of montmorillonite is prepared, with high tenacity, impact resistance, decay resistance be strong, power
The characteristics of performance is good.
（4）The characteristics of calcined diatomite has specific surface area high, finer grain size, in fill concrete cement matrix
Portion's hole, so as to improve packing, mechanical property, the impervious frost resistance of concrete substrate.
（5）Apply uniform magnetic field to steel fiber reinforced concrete mixture, steel fibre is subject to magnetic fields so that most of steel is fine
Dimension direction is consistent with magnetic direction or close, forms unidirectional distribution, prepares the steel fiber reinforced concrete of unidirectional distribution, fiber utilization
Rate is high, and enhancing effect is good.
Specific embodiment
In order that technological means, creation characteristic, reached purpose and effect that the present invention is realized are easy to understand, tie below
Specific embodiment is closed, the present invention is expanded on further.
Embodiment
A kind of corrosion resistant type reinforced concrete sewer pipe of Stainless-steel fibre, is obtained by the raw material of following weight parts (g)：
Flyash 10, slag powders 10, metakaolin 4, gypsum 2, sodium sulphate 6, naphthalene series high-efficiency water-reducing agent 3, sand 15, rubble 10 is double
Phenol A types epoxy resin E-44 5, benzoyl peroxide 3, acrylic acid 4, N, N- dimethylethanolamines 1, organo montmorillonite 3, cement
10, steel fibre 6, calcined diatomite 3, reinforcing bar 9, propylene glycol monomethyl ether, appropriate amount of water.
The preparation method of the corrosion resistant type reinforced concrete sewer pipe of a kind of Stainless-steel fibre, it is characterised in that by following
Step is carried out：
A. flyash is mixed after mechanical grinding with slag powders, metakaolin, stir to obtain Binder Materials；
B. by gypsum, sodium sulphate mixing and ball milling it is uniform exciting agent, add resulting material in a with naphthalene series high-efficiency water-reducing agent, then with
2:6 add sand and water, stir to obtain mortar, add the rubble of particle diameter 10-20mm, stir 30-40min；
C. by bisphenol A type epoxy resin E-44 with 1:5 are dissolved in propylene glycol monomethyl ether, add benzoyl peroxide, acrylic acid, rise
Temperature stirs lower 1 to 105-115 DEG C of reaction 3h:6 add N, N- dimethylethanolamines and water, and tune pH is 7-8, adds organic illiteracy to take off
Soil, 80-90 DEG C is reacted 1h, stand-by；
D. resulting material in a, b, c is mixed, adds cement, steel fibre, calcined diatomite, stirred, mixture is applied
Uniform magnetic field；
E. by reinforcing bar treatment obtain framework of steel reinforcement shaping, by d resulting material input wherein, start overhang-roll tubing machine, overhang roll into
Type, steam curing, the demoulding, obtain a kind of corrosion resistant type reinforced concrete sewer pipe of Stainless-steel fibre.
A kind of corrosion resistant type reinforced concrete sewer pipe performance test results of Stainless-steel fibre prepared by above-described embodiment are as follows
It is shown：
Acidproof and alkali corrosion resistance coefficient >=0.87, drainpipe cracking load >=61kN/m, failing load >=89kN/m reaches
The I grade of pipe requirement of 1200mm reinforced concrete sewer pipes.
Claims (2)
1. the corrosion resistant type reinforced concrete sewer pipe of a kind of Stainless-steel fibre, it is characterised in that by the raw material of following weight parts
It is obtained：
Flyash 10-15, slag powders 10-15, metakaolin 2-4, gypsum 1-2, sodium sulphate 4-6, naphthalene series high-efficiency water-reducing agent 1-3,
Sand 15-20, rubble 5-10, bisphenol A type epoxy resin E-44 3-5, benzoyl peroxide 2-3, acrylic acid 2-4, N, N- dimethyl
Monoethanolamine 1-2, organo montmorillonite 2-3, cement 5-10, steel fibre 3-6, calcined diatomite 2-3, reinforcing bar 6-9, propylene glycol monomethyl ether,
Appropriate amount of water.
2. the preparation method of the corrosion resistant type reinforced concrete sewer pipe of a kind of Stainless-steel fibre according to claim 1,
Characterized in that, carrying out according to the following steps：
Flyash is mixed after mechanical grinding with slag powders, metakaolin, stir to obtain Binder Materials；
B. by gypsum, sodium sulphate mixing and ball milling it is uniform exciting agent, add resulting material in a with naphthalene series high-efficiency water-reducing agent, then with
2:4-6 adds sand and water, stirs to obtain mortar, adds the rubble of particle diameter 5-25mm, stirs 30-50min；
C. by bisphenol A type epoxy resin E-44 with 1:3-5 is dissolved in propylene glycol monomethyl ether, adds benzoyl peroxide, acrylic acid,
It is warming up to 105-115 DEG C of reaction 2-3h, stirring lower 1:4-6 adds N, N- dimethylethanolamines and water, and tune pH is 7-8, and addition has
Machine montmorillonite, 80-90 DEG C is reacted 1-2h, stand-by；
D. resulting material in a, b, c is mixed, adds cement, steel fibre, calcined diatomite, stirred, mixture is applied
Uniform magnetic field；
E. by reinforcing bar treatment obtain framework of steel reinforcement shaping, by d resulting material input wherein, start overhang-roll tubing machine, overhang roll into
Type, steam curing, the demoulding, obtain a kind of corrosion resistant type reinforced concrete sewer pipe of Stainless-steel fibre.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201611157939.4A CN106747149A (en) | 2016-12-15 | 2016-12-15 | A kind of corrosion resistant type reinforced concrete sewer pipe of Stainless-steel fibre and preparation method thereof |
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201611157939.4A CN106747149A (en) | 2016-12-15 | 2016-12-15 | A kind of corrosion resistant type reinforced concrete sewer pipe of Stainless-steel fibre and preparation method thereof |
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| CN106747149A true CN106747149A (en) | 2017-05-31 |
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| CN201611157939.4A Pending CN106747149A (en) | 2016-12-15 | 2016-12-15 | A kind of corrosion resistant type reinforced concrete sewer pipe of Stainless-steel fibre and preparation method thereof |
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Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102320775A (en) * | 2010-09-07 | 2012-01-18 | 深圳市陆基建材技术有限公司 | Seawater corrosion resisting mineral additive for concrete, and preparation method thereof |
| CN103224356A (en) * | 2013-02-07 | 2013-07-31 | 黄贺明 | Green environmentally-friendly powder reinforced concrete water delivery pipe |
| CN105948803A (en) * | 2016-06-02 | 2016-09-21 | 湖州汇能新材料科技有限公司 | Preparing method for aerated concrete products |
-
2016
- 2016-12-15 CN CN201611157939.4A patent/CN106747149A/en active Pending
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102320775A (en) * | 2010-09-07 | 2012-01-18 | 深圳市陆基建材技术有限公司 | Seawater corrosion resisting mineral additive for concrete, and preparation method thereof |
| CN103224356A (en) * | 2013-02-07 | 2013-07-31 | 黄贺明 | Green environmentally-friendly powder reinforced concrete water delivery pipe |
| CN105948803A (en) * | 2016-06-02 | 2016-09-21 | 湖州汇能新材料科技有限公司 | Preparing method for aerated concrete products |
Non-Patent Citations (1)
| Title |
|---|
| 穆惠民: "《中国建材技术装备制造安装维护与修理》", 30 September 2002 * |
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Application publication date: 20170531 |