CN106747081B - Cementitious capillary waterproofing material - Google Patents
Cementitious capillary waterproofing material Download PDFInfo
- Publication number
- CN106747081B CN106747081B CN201611125889.1A CN201611125889A CN106747081B CN 106747081 B CN106747081 B CN 106747081B CN 201611125889 A CN201611125889 A CN 201611125889A CN 106747081 B CN106747081 B CN 106747081B
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- parts
- zeolite
- complex catalyst
- gluconate
- cement
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Classifications
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- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B28/00—Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements
- C04B28/02—Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements containing hydraulic cements other than calcium sulfates
- C04B28/04—Portland cements
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B14/00—Use of inorganic materials as fillers, e.g. pigments, for mortars, concrete or artificial stone; Treatment of inorganic materials specially adapted to enhance their filling properties in mortars, concrete or artificial stone
- C04B14/02—Granular materials, e.g. microballoons
- C04B14/04—Silica-rich materials; Silicates
- C04B14/047—Zeolites
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B20/00—Use of materials as fillers for mortars, concrete or artificial stone according to more than one of groups C04B14/00 - C04B18/00 and characterised by shape or grain distribution; Treatment of materials according to more than one of the groups C04B14/00 - C04B18/00 specially adapted to enhance their filling properties in mortars, concrete or artificial stone; Expanding or defibrillating materials
- C04B20/10—Coating or impregnating
- C04B20/1051—Organo-metallic compounds; Organo-silicon compounds, e.g. bentone
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B40/00—Processes, in general, for influencing or modifying the properties of mortars, concrete or artificial stone compositions, e.g. their setting or hardening ability
- C04B40/0028—Aspects relating to the mixing step of the mortar preparation
- C04B40/0039—Premixtures of ingredients
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2103/00—Function or property of ingredients for mortars, concrete or artificial stone
- C04B2103/60—Agents for protection against chemical, physical or biological attack
- C04B2103/65—Water proofers or repellants
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2111/00—Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
- C04B2111/20—Resistance against chemical, physical or biological attack
- C04B2111/27—Water resistance, i.e. waterproof or water-repellent materials
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Ceramic Engineering (AREA)
- Materials Engineering (AREA)
- Structural Engineering (AREA)
- Organic Chemistry (AREA)
- Civil Engineering (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Inorganic Chemistry (AREA)
- Curing Cements, Concrete, And Artificial Stone (AREA)
Abstract
A kind of cementitious capillary waterproofing material, belongs to building material technical field.It is characterized by: the waterproof material is mixed by the component of following weight proportion: 56~62 parts of cement, 27 parts~33 parts of quartz sand, 7~11 parts of complex catalyst, 1~3 part of zeolite waterproofing agent；The complex catalyst mixed and modified is formed by the component of following weight proportion: 87~75 parts of zeolite powder, 5~10 parts of lithium metasilicate, 5~10 parts of gluconate, 3~5 parts of isobutyl triethoxy silane.The present invention is because only use cement, quartz sand, four kinds of complex catalyst, zeolite waterproofing agent Matter Compositions, and four kinds of Matter Composition prices are all very limited, so low manufacture cost, is easy to promote；In addition, waterproof performance is greatly improved；It there are also either composition composition, is used for, the related request of national green environment-friendly building materials product can be met.
Description
Technical field
The invention belongs to building material technical fields, and in particular to a kind of cementitious capillary waterproofing material.
Background technique
As concrete largely uses in construction, the durability deficiency problem of concrete structure increasingly causes people
Attention, wherein the infiltration of water is to lead to concrete deterioration, the major reason of its durability is reduced, therefore, it is necessary to coagulation
Soil carries out water-proofing treatment to avoid concrete from generating deterioration, improve its durability." permeable crystalline waterproofing material " abbreviation CCCW
(Cementitious Capillary Crystalline Waterproofing Materials), as a kind of novel rigid
Waterproof material can preferably solve the problems, such as concrete water-permeating, it in 20th century the eighties in a manner of SMD core master batch into
Enter China market, because of its price, is not easy to promote at home.There has been proposed many " cement-base infiltration crystallization types thus
The technical solution of waterproof material ", such as notification number: CN 101830674A " a kind of cementitious capillary waterproofing material ", bulletin
Number: CN 102786275A " cementitious capillary waterproofing material ", notification number: CN 101074355B " cement-based penetrant knot
Crystal form waterproof material and preparation method thereof ", notification number: a kind of CN 104355584A " cement-base infiltration crystallization type buildings waterproof material
The technical solutions such as material ".These many technical solutions have the advantages that common and respective, common advantage be price be all far below into
" cementitious capillary waterproofing material " of mouth, but there is also common disadvantage, that is, the Matter Composition sample number formed is more, so
Its price reduces again has any problem；In addition, the performance of its waterproof and " the cement-base infiltration crystallization type water-proof material " of import still have gap.
Summary of the invention
The invention aims to overcome the deficiencies of the prior art and provide a kind of cementitious capillary waterproofing material,
The Matter Composition that it is formed is simple, and several Matter Composition prices are low, so the waterproof material low manufacture cost of composition, is easy to push away
Extensively；In addition, waterproof performance is greatly improved；In addition, either composition is formed, is used for, national green can be met
The related request of environment-friendly building materials product.
Above-mentioned goal of the invention is achieved through the following technical solutions, a kind of cementitious capillary waterproofing material,
It is characterized by: the waterproof material is mixed by the component of following weight proportion: 56~62 parts of cement, 27 parts of quartz sand~
33 parts, 7~11 parts of complex catalyst, 1~3 part of zeolite waterproofing agent；The complex catalyst by following weight proportion component
It is mixed and modified to form: 87~75 parts of zeolite powder, 5~10 parts of lithium metasilicate, 5~10 parts of gluconate, isobutyl triethoxy silane
3~5 parts.
Preferably, the zeolite waterproofing agent is modified zeolite, fatty acid, the surface-modified processing of silane Composite Milk again
Rubber powder, cellulose ether form.
Preferably, the gluconate be one of calcium gluconate, sodium gluconate, magnesium gluconate or
Two kinds or more.
Beneficial effects of the present invention are as follows: because this waterproof material only uses cement, quartz sand, complex catalyst, zeolite anti-
Four kinds of Matter Compositions of aqua, and four kinds of Matter Composition prices are all very limited, so low manufacture cost, is easy to promote；And four kinds of objects
Zeolite waterproofing agent in matter composition utilizes its distinctive adsorptivity, ion exchange using high grade natural zeolite as primary raw material
Property, acid resistance, alkali resistance, by the way that activation, roasting, surface be modified etc., series of process are handled, and are that collection is closely knit, bleed, are hated
The water-proofing anticrackings such as water, secondary crystallization, microdilatancy, decrement mechanism is in the multifunctional mortar of one.Its water-proof mechanism: modified processing
Zeolite crystallite afterwards can improve the uniformity of cement mixture, workability, promote hydrated cementitious and form hydrophobic adsorption layer and not
Dissolubility colloidal substance, filling concrete capillary slit prevent water translocation, reduce water absorption, improve hydrophobicity and impermeability.Due to
Zeolite is rich in SiO2, activity A12O3And various trace elements, the hydration reaction of continuous uniform can be carried out with cement, generation has
Calcium sulphoaluminate, that is, entringite of micro-expansibility can play the role of compensation and shrink；Due to the zeolite through silane surface modified processing,
It can significantly reduce the surface tension of Behavior of Hardened Cement Paste, reduce the negative pressure generated after the dehydration of cement pore, to reduce the dry of Behavior of Hardened Cement Paste
Contracting.Activated silica and activated aluminum in zeolite can participate in cementitious material hydration and hardening, generate hydrated calcium silicate and calcium aluminate, increase
Gelled product improves cementing with cementitious material, increase density of gathering materials, raising compression strength.It simultaneously can also be with hydrated cementitious
Secondary response occurs for the calcium hydroxide and gypsum generated afterwards, generates hydrophobicity crystalline material blocking pore, seam, further increases
Density and crack self-healing.The special porous rack-like structure of zeolite and pozzolanic activity, moreover it is possible to reduce hydration heat of cement and
Inhibit alkali-aggregate reaction, makes waterproof effect that there are long-time stability.Cementitious capillary waterproofing material of the invention is adopted
With complexing-precipitation reaction mechanism, there is the chemical activities that can be complexed with calcium ion in cementitious capillary waterproofing material
Substance-complex catalyst, under the collective effect of concentration and pressure difference, complex catalyst penetrates into concrete by carrier of water
Portion is complexed when by calcium hydroxide high concentration region with the calcium ion ionized out in concrete, is formed soluble easily in water unstable
Calcium complex.Complex compound is spread in concrete pore with water, encounters the higher unhydrated cement of activity, cement gel body
Deng, active chemistry will be replaced by more stable silicate, aluminate etc., occur crystallization, precipitation reaction, thus by hydrogen-oxygen
Change calcium and be converted into the crystalline compounds with some strength, is filled in crack and capillary porosity in concrete.And activity chemistry
Substance then becomes free radical again, and continuation is internally migrated with water.When concrete is in drying regime, it is situated between due to lacking diffusion
Matter, active material is in " suspend mode " state, and when there is water infiltration, active material will be activated once again, and new crystallization occurs for catalysis
Reaction, makes structurally waterproof.Therefore, such material has permanent waterproof characteristic.
Show that the difference of the present invention and the prior art can be summarized as follows from above description:
Complex catalyst is different.The present invention utilizes the physicochemical property of natural zeolite, mainly adsorptivity and ion exchangeable
Lithium metasilicate, gluconate, isobutyl triethoxy silane are adsorbed in zeolite nanoaperture, and wrap up zeolite microparticles table
Face constitutes core component complex catalyst.
The compositing formula of material is different.The most basic material composition of cement based penetration crystallization type water proofing paint is by silicate
Cement, catalyst, quartz sand, silicon ash, siliceous miberal powder, water-retaining agent composition.But it since its early stage impermeability pressure is not high, and crystallizes
Process time is longer, and coating hardening is able to satisfy water-tight requirement after the early stage impermeability and construction in order to improve material, only
It could accelerate waterproof requirement by combination of materials technology, therefore this technology has been further added by zeolite on the basis of existing conventional techniques
Waterproofing agent component significantly improves the early stage impermeability and waterproofness of material.The present invention is not only suitable for concrete structure upstream face
First waterproof, waterproofing and leakage-stopping is administered after being also suitable for concrete structure back side.
Because of above-mentioned reason, this waterproof material has as described above than general cement-base infiltration crystallization: increasing
The performance advantages such as closely knit, bleed, hydrophobic, secondary crystallization, microdilatancy, decrement, make waterproof performance be greatly improved, can with into
" cementitious capillary waterproofing material " of mouth compares favourably.In addition, the present invention either composition is formed, is used for, all accord with
It closes radionuclide limitation and ammonia burst size standard requirements, national Drinking Water product requirement, national green environmental protection is built
The related requests such as material product requirement.
Detailed description of the invention
Fig. 1: the Indexes Comparison table of product of the embodiment of the present invention and same kind of products at abroad.
Specific embodiment
Below in conjunction with Fig. 1, the invention will be further described, a kind of cementitious capillary waterproofing material, the waterproof
Material is mixed by the component of following weight proportion: 59 parts of cement, 30 parts of quartz sand, and 9 parts of complex catalyst, zeolite waterproofing agent
2 parts；The complex catalyst mixed and modified is formed by the component of following weight proportion: 80 parts of zeolite powder, 7 parts of lithium metasilicate, and Portugal
7 parts of grape sugar lime, 5 parts of isobutyl triethoxy silane；The zeolite waterproofing agent is modified zeolite, fatty acid, silane through table
Composite Milk rubber powder, cellulose ether form again for face modification；The gluconate is calcium gluconate.
Claims (1)
1. a kind of cementitious capillary waterproofing material, it is characterised in that: the waterproof material by following weight proportion group
Divide and mix: 56~62 parts of cement, 27 parts~33 parts of quartz sand, 7~11 parts of complex catalyst, 1~3 part of zeolite waterproofing agent；
The complex catalyst mixed and modified is formed by the component of following weight proportion: 87~75 parts of zeolite powder, lithium metasilicate 5~10
Part, 5~10 parts of gluconate, 3~5 parts of isobutyl triethoxy silane；The zeolite waterproofing agent is modified zeolite, fat
Composite Milk rubber powder, cellulose ether form the surface-modified processing of acid, silane again；The gluconate be calcium gluconate,
One of sodium gluconate, magnesium gluconate or two kinds or more.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201611125889.1A CN106747081B (en) | 2016-12-09 | 2016-12-09 | Cementitious capillary waterproofing material |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201611125889.1A CN106747081B (en) | 2016-12-09 | 2016-12-09 | Cementitious capillary waterproofing material |
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| Publication Number | Publication Date |
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| CN106747081A CN106747081A (en) | 2017-05-31 |
| CN106747081B true CN106747081B (en) | 2019-09-10 |
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| Application Number | Title | Priority Date | Filing Date |
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| CN201611125889.1A Active CN106747081B (en) | 2016-12-09 | 2016-12-09 | Cementitious capillary waterproofing material |
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Families Citing this family (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN109704661B (en) * | 2019-03-04 | 2022-09-13 | 上海会当防水材料有限公司 | Cement-based capillary crystalline waterproof coating |
| CN111574879B (en) * | 2020-05-26 | 2021-11-23 | 安徽工业大学 | Semi-dry desulfurization ash-based interior wall putty powder without oxidation treatment and preparation method thereof |
| CN112142437B (en) * | 2020-09-14 | 2022-03-18 | 安徽朗凯奇防水科技股份有限公司 | Cement-based capillary crystalline waterproof material and preparation method thereof |
| CN114685093B (en) * | 2022-04-27 | 2023-06-27 | 长沙标朗住工科技有限公司 | Wall repairing paste and preparation method and application thereof |
| CN117003507B (en) * | 2023-08-07 | 2023-12-29 | 贵州钰琦盛达实业有限公司 | High-efficiency waterproof polysilicone permeable crystallization type waterproof coating |
Citations (6)
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|---|---|---|---|---|
| JPH11130496A (en) * | 1997-10-30 | 1999-05-18 | Kubota Corp | Production of water repellent ceramic based building material |
| CN101117280A (en) * | 2007-05-10 | 2008-02-06 | 陈土兴 | Sand pulp concrete waterproof agent and method for making same |
| CN101830674B (en) * | 2010-05-12 | 2012-02-08 | 中国建筑材料科学研究总院苏州防水研究院 | Cementitious capillary crystalline waterproof material |
| CN104402289A (en) * | 2014-11-26 | 2015-03-11 | 金华市欣生沸石开发有限公司 | Zeolite cement mortar waterproof agent and preparation method thereof |
| CN104844079A (en) * | 2015-04-03 | 2015-08-19 | 杭州泰正建材有限公司 | Cement-based capillary crystalline waterproof material and preparation method thereof |
| CN104961415A (en) * | 2015-06-10 | 2015-10-07 | 金华市欣生沸石开发有限公司 | Concrete crack resistance silicon waterproof agent |
Family Cites Families (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105272065B (en) * | 2015-11-18 | 2017-06-30 | 南阳理工学院 | A kind of cementitious capillary waterproofing material for building |
-
2016
- 2016-12-09 CN CN201611125889.1A patent/CN106747081B/en active Active
Patent Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH11130496A (en) * | 1997-10-30 | 1999-05-18 | Kubota Corp | Production of water repellent ceramic based building material |
| CN101117280A (en) * | 2007-05-10 | 2008-02-06 | 陈土兴 | Sand pulp concrete waterproof agent and method for making same |
| CN101830674B (en) * | 2010-05-12 | 2012-02-08 | 中国建筑材料科学研究总院苏州防水研究院 | Cementitious capillary crystalline waterproof material |
| CN104402289A (en) * | 2014-11-26 | 2015-03-11 | 金华市欣生沸石开发有限公司 | Zeolite cement mortar waterproof agent and preparation method thereof |
| CN104844079A (en) * | 2015-04-03 | 2015-08-19 | 杭州泰正建材有限公司 | Cement-based capillary crystalline waterproof material and preparation method thereof |
| CN104961415A (en) * | 2015-06-10 | 2015-10-07 | 金华市欣生沸石开发有限公司 | Concrete crack resistance silicon waterproof agent |
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| CN106747081A (en) | 2017-05-31 |
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