CN106747081A - Cementitious capillary waterproofing material - Google Patents
Cementitious capillary waterproofing material Download PDFInfo
- Publication number
- CN106747081A CN106747081A CN201611125889.1A CN201611125889A CN106747081A CN 106747081 A CN106747081 A CN 106747081A CN 201611125889 A CN201611125889 A CN 201611125889A CN 106747081 A CN106747081 A CN 106747081A
- Authority
- CN
- China
- Prior art keywords
- parts
- zeolite
- complex catalyst
- cement
- cementitious capillary
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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Classifications
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B28/00—Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements
- C04B28/02—Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements containing hydraulic cements other than calcium sulfates
- C04B28/04—Portland cements
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B14/00—Use of inorganic materials as fillers, e.g. pigments, for mortars, concrete or artificial stone; Treatment of inorganic materials specially adapted to enhance their filling properties in mortars, concrete or artificial stone
- C04B14/02—Granular materials, e.g. microballoons
- C04B14/04—Silica-rich materials; Silicates
- C04B14/047—Zeolites
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B20/00—Use of materials as fillers for mortars, concrete or artificial stone according to more than one of groups C04B14/00 - C04B18/00 and characterised by shape or grain distribution; Treatment of materials according to more than one of the groups C04B14/00 - C04B18/00 specially adapted to enhance their filling properties in mortars, concrete or artificial stone; Expanding or defibrillating materials
- C04B20/10—Coating or impregnating
- C04B20/1051—Organo-metallic compounds; Organo-silicon compounds, e.g. bentone
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B40/00—Processes, in general, for influencing or modifying the properties of mortars, concrete or artificial stone compositions, e.g. their setting or hardening ability
- C04B40/0028—Aspects relating to the mixing step of the mortar preparation
- C04B40/0039—Premixtures of ingredients
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2103/00—Function or property of ingredients for mortars, concrete or artificial stone
- C04B2103/60—Agents for protection against chemical, physical or biological attack
- C04B2103/65—Water proofers or repellants
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2111/00—Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
- C04B2111/20—Resistance against chemical, physical or biological attack
- C04B2111/27—Water resistance, i.e. waterproof or water-repellent materials
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Ceramic Engineering (AREA)
- Materials Engineering (AREA)
- Structural Engineering (AREA)
- Organic Chemistry (AREA)
- Civil Engineering (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Inorganic Chemistry (AREA)
- Curing Cements, Concrete, And Artificial Stone (AREA)
Abstract
A kind of cementitious capillary waterproofing material, belongs to building material technical field.It is characterized in that：The waterproof material is mixed by the component of following weight proportion：56~62 parts of cement, 27 parts~33 parts of quartz sand, 7~11 parts of complex catalyst, 1~3 part of zeolite waterproofing agent；Described complex catalyst mixed and modified is formed by the component of following weight proportion：87~75 parts of zeolite powder, 5~10 parts of lithium metasilicate, 5~10 parts of gluconate, 3~5 parts of isobutyl triethoxy silane.The present invention is because only use cement, quartz sand, complex catalyst, four kinds of Matter Compositions of zeolite waterproofing agent, and four kinds of Matter Composition prices are all very limited, so low manufacture cost, easily promotes；In addition, water resistance is greatly improved；Also either composition is constituted, is used for, and can meet the related request of national green environment-friendly building materials product.
Description
Technical field
The invention belongs to building material technical field, and in particular to a kind of cementitious capillary waterproofing material.
Background technology
As concrete is largely used in construction, the durability deficiency problem of concrete structure increasingly causes people
Attention, the infiltration of its reclaimed water is to cause concrete deterioration, reduces the major reason of its durability, therefore, it is necessary to coagulation
Soil carries out water-proofing treatment to avoid concrete from producing deterioration, improve its durability." permeable crystalline waterproofing material " abbreviation CCCW
（Cementitious Capillary Crystalline Waterproofing Materials）, as a kind of novel rigid
Waterproof material, can preferably solve the problems, such as concrete water-permeating, it in 20th century the eighties entered in the way of SMD core master batches
Enter China market, because its price, be not easy to promote at home.It is this there has been proposed many " cement-base infiltration crystallization types
The technical scheme of waterproof material ", such as notification number：CN 101830674A " a kind of cementitious capillary waterproofing material ", bulletin
Number：CN 102786275A " cementitious capillary waterproofing material ", notification number：CN 101074355B " cement-based penetrant knots
Crystal formation waterproof material and preparation method thereof ", notification number：A kind of CN 104355584A " cement-base infiltration crystallization type buildings waterproof materials
The technical schemes such as material ".These many technical schemes have a common and respective advantage, common advantage be price be all far below into
" cementitious capillary waterproofing material " of mouth, but there is also common shortcoming, that is, the Matter Composition sample number for constituting is more, so
Its price is reduced again has any problem；In addition, the performance of its waterproof still has gap with " the cement-base infiltration crystallization type water-proof material " of import.
The content of the invention
The invention aims to overcome the deficiencies in the prior art, there is provided a kind of cementitious capillary waterproofing material,
The Matter Composition that it is constituted is simple, and several Matter Composition prices are low, so the waterproof material low manufacture cost of composition, easily pushes away
Extensively；In addition, water resistance is greatly improved；Further, either composition is constituted, is used for, and can meet national green
The related request of environment-friendly building materials product.
Above-mentioned goal of the invention is achieved through the following technical solutions, a kind of cementitious capillary waterproofing material,
It is characterized by：The waterproof material is mixed by the component of following weight proportion：56~62 parts of cement, 27 parts of quartz sand~
33 parts, 7~11 parts of complex catalyst, 1~3 part of zeolite waterproofing agent；Described complex catalyst by following weight proportion component
It is mixed and modified to form：87~75 parts of zeolite powder, 5~10 parts of lithium metasilicate, 5~10 parts of gluconate, isobutyl triethoxy silane
3~5 parts.
Preferably, described zeolite waterproofing agent is modified zeolite, aliphatic acid, the surface-modified treatment of silane Composite Milk again
Rubber powder, cellulose ether are formed.
Preferably, described gluconate be one kind in calcium gluconae, sodium gluconate, magnesium gluconate or
More than two kinds.
Beneficial effects of the present invention are as follows：Because this waterproof material is only prevented with cement, quartz sand, complex catalyst, zeolite
Four kinds of Matter Compositions of aqua, and four kinds of Matter Composition prices are all very limited, so low manufacture cost, easily promotes；And four kinds of things
Zeolite waterproofing agent in matter composition, with grade natural zeolite high as primary raw material, using its distinctive adsorptivity, ion exchange
Property, acid resistance, alkali resistance, by the way that activation, roasting, surface be modified etc., series of process processes forms, and is to collect closely knit, bleed, hate
The water-proofing anticracking such as water, secondary crystallization, microdilatancy, decrement mechanism is in the multifunctional mortar of one.Its water-proof mechanism：Modified treatment
Zeolite crystallite afterwards can improve the uniformity of cement mixture, workability, promote hydrated cementitious and form hydrophobic adsorption layer and not
Dissolubility colloidal substance, filling concrete capillary slit prevents water translocation, reduces water absorption, improves hydrophobicity and impermeability.Due to
Zeolite is rich in SiO2, activity A12O3And various trace elements, the hydration reaction of continuous uniform can be carried out with cement, generation has
The calcium sulphoaluminate of micro-expansibility is entringite, can play a part of compensation and shrink；Due to the zeolite through silane surface modified treatment,
The surface tension of Behavior of Hardened Cement Paste can be significantly reduced, reduces the negative pressure produced after cement pore dehydration, so as to reduce the dry of Behavior of Hardened Cement Paste
Contracting.Activated silica and activated aluminum in zeolite, can participate in Binder Materials hydration and hardening, generate hydrated calcium silicate and calcium aluminate, increase
Gelled product, improvement gathers materials cementing with Binder Materials, increases density, improves compression strength.Simultaneously can also be with hydrated cementitious
There is secondary response in the calcium hydroxide and gypsum for producing afterwards, generation hydrophobicity crystalline material blocks pore, seam, further improves
Density and crack self-healing.The special porous rack-like structure of zeolite and pozzolanic activity, moreover it is possible to reduce hydration heat of cement and
Suppress alkali-aggregate reaction, make waterproof effect that there are long-time stability.Cementitious capillary waterproofing material of the invention is adopted
With complexing-precipitation reaction mechanism, the chemism that can be complexed with calcium ion is there is in cementitious capillary waterproofing material
Material-complex catalyst, under the collective effect of concentration and pressure differential, complex catalyst is penetrated into concrete by carrier of water
Portion, when by calcium hydroxide high concentration region, with the calcium ion complexing that ionizes out in concrete, forms soluble in water unstable
Calcium complex.Complex compound spreads with water in concrete pore, runs into activity unhydrated cement, cement gel body higher
Deng active chemistry will be replaced by more stable silicate, aluminate etc., and crystallization, precipitation reaction occur, so as to by hydrogen-oxygen
Change calcium and be converted into the crystalline compounds with some strength, be filled in crack and capillary porosity in concrete.And activity chemistry
Material then becomes free radical again, and continuation is internally migrated with water.When concrete is in drying regime, it is situated between due to lacking diffusion
Matter, active material is in " dormancy " state, and when there is water to penetrate into, active material will be activated once again, and catalysis occurs new crystallization
Reaction, makes structurally waterproof.Therefore, such material has permanent waterproof characteristic.
Description more than shows that the present invention can be summarized as follows with the difference of prior art：
Complex catalyst is different.The present invention using natural zeolite physicochemical property, mainly adsorptivity and ion exchangeable is by silicon
Sour lithium, gluconate, isobutyl triethoxy silane absorption wrap up zeolite microparticles surface, structure in zeolite nanoaperture
Into core component complex catalyst.
The compositing formula of material is different.The most basic material composition of cement based penetration crystallization type water proofing paint is by silicate
Cement, catalyst, quartz sand, silicon ash, siliceous miberal powder, water-loss reducer composition.But because its early stage impermeability pressure is not high, and crystallize
Process time is more long, in order to coating hardening can meet water-tight requirement after improving the early stage impermeability of material and constructing, only
Waterproof requirement could be accelerated by combination of materials technology, therefore this technology has been further added by zeolite on the basis of existing conventional techniques
Waterproofing agent component, significantly improves the early stage impermeability and water proofing property of material.The present invention is not only suitable for concrete structure upstream face
First waterproof, waterproofing and leakage-stopping is administered after being also suitable for concrete structure back side.
Because above-mentioned reason, this waterproof material has as described above than general cement-base infiltration crystallization：Increased
The performance advantages such as closely knit, bleed, hydrophobic, secondary crystallization, microdilatancy, decrement, make water resistance be greatly improved, can with enter
" cementitious capillary waterproofing material " of mouth compares favourably.Further, either composition is constituted, is used for the present invention, is all accorded with
Close radionuclide limitation and the requirement of ammonia burst size standard, national Drinking Water product use requirement, national green environmental protection are built
The related requests such as material product use requirement.
Brief description of the drawings
Fig. 1:The Indexes Comparison table of embodiment of the present invention product and same kind of products at abroad.
Specific embodiment
Below in conjunction with Fig. 1, the invention will be further described, a kind of cementitious capillary waterproofing material, the waterproof
Material is mixed by the component of following weight proportion：59 parts of cement, 30 parts of quartz sand, 9 parts of complex catalyst, zeolite waterproofing agent
2 parts；Described complex catalyst mixed and modified is formed by the component of following weight proportion：80 parts of zeolite powder, 7 parts of lithium metasilicate, Portugal
7 parts of grape sugar lime, 5 parts of isobutyl triethoxy silane；Described zeolite waterproofing agent is modified zeolite, aliphatic acid, silane through table
Composite Milk rubber powder, cellulose ether are formed face modification again；Described gluconate is calcium gluconae.
Claims (3)
1. a kind of cementitious capillary waterproofing material, it is characterised in that：The waterproof material by following weight proportion group
Divide and mix：56~62 parts of cement, 27 parts~33 parts of quartz sand, 7~11 parts of complex catalyst, 1~3 part of zeolite waterproofing agent；
Described complex catalyst mixed and modified is formed by the component of following weight proportion：87~75 parts of zeolite powder, lithium metasilicate 5~10
Part, 5~10 parts of gluconate, 3~5 parts of isobutyl triethoxy silane.
2. cementitious capillary waterproofing material according to claim 1, it is characterised in that：Described zeolite waterproofing agent
For modified zeolite, aliphatic acid, Composite Milk rubber powder, cellulose ether are formed the surface-modified treatment of silane again.
3. cementitious capillary waterproofing material according to claim 1 and 2, it is characterised in that：Described glucose
Hydrochlorate is one or two or more kinds in calcium gluconae, sodium gluconate, magnesium gluconate.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201611125889.1A CN106747081B (en) | 2016-12-09 | 2016-12-09 | Cementitious capillary waterproofing material |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201611125889.1A CN106747081B (en) | 2016-12-09 | 2016-12-09 | Cementitious capillary waterproofing material |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN106747081A true CN106747081A (en) | 2017-05-31 |
| CN106747081B CN106747081B (en) | 2019-09-10 |
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| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201611125889.1A Active CN106747081B (en) | 2016-12-09 | 2016-12-09 | Cementitious capillary waterproofing material |
Country Status (1)
| Country | Link |
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| CN (1) | CN106747081B (en) |
Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN109704661A (en) * | 2019-03-04 | 2019-05-03 | 上海会当防水材料有限公司 | A kind of cement based penetration crystallization type water proofing paint |
| CN111574879A (en) * | 2020-05-26 | 2020-08-25 | 安徽工业大学 | Semi-dry desulfurization ash-based interior wall putty powder without oxidation treatment and preparation method thereof |
| CN112142437A (en) * | 2020-09-14 | 2020-12-29 | 安徽朗凯奇防水科技股份有限公司 | Cement-based capillary crystalline waterproof material and preparation method thereof |
| CN114685093A (en) * | 2022-04-27 | 2022-07-01 | 长沙标朗住工科技有限公司 | Wall-repairing paste and preparation method and application thereof |
| CN117003507A (en) * | 2023-08-07 | 2023-11-07 | 贵州钰琦盛达实业有限公司 | High-efficiency waterproof polysilicone permeable crystallization type waterproof coating |
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| CN101117280A (en) * | 2007-05-10 | 2008-02-06 | 陈土兴 | Sand pulp concrete waterproof agent and method for making same |
| CN101830674B (en) * | 2010-05-12 | 2012-02-08 | 中国建筑材料科学研究总院苏州防水研究院 | Cementitious capillary crystalline waterproof material |
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Cited By (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN109704661A (en) * | 2019-03-04 | 2019-05-03 | 上海会当防水材料有限公司 | A kind of cement based penetration crystallization type water proofing paint |
| CN111574879A (en) * | 2020-05-26 | 2020-08-25 | 安徽工业大学 | Semi-dry desulfurization ash-based interior wall putty powder without oxidation treatment and preparation method thereof |
| CN112142437A (en) * | 2020-09-14 | 2020-12-29 | 安徽朗凯奇防水科技股份有限公司 | Cement-based capillary crystalline waterproof material and preparation method thereof |
| CN112142437B (en) * | 2020-09-14 | 2022-03-18 | 安徽朗凯奇防水科技股份有限公司 | Cement-based capillary crystalline waterproof material and preparation method thereof |
| CN114685093A (en) * | 2022-04-27 | 2022-07-01 | 长沙标朗住工科技有限公司 | Wall-repairing paste and preparation method and application thereof |
| CN117003507A (en) * | 2023-08-07 | 2023-11-07 | 贵州钰琦盛达实业有限公司 | High-efficiency waterproof polysilicone permeable crystallization type waterproof coating |
| CN117003507B (en) * | 2023-08-07 | 2023-12-29 | 贵州钰琦盛达实业有限公司 | High-efficiency waterproof polysilicone permeable crystallization type waterproof coating |
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| CN106747081B (en) | 2019-09-10 |
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