CN106746250A - The processing method of Ipomoea batatas alcohol waste water - Google Patents

The processing method of Ipomoea batatas alcohol waste water Download PDF

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Publication number
CN106746250A
CN106746250A CN201611254962.5A CN201611254962A CN106746250A CN 106746250 A CN106746250 A CN 106746250A CN 201611254962 A CN201611254962 A CN 201611254962A CN 106746250 A CN106746250 A CN 106746250A
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Prior art keywords
waste water
aluminum
iron
composite powder
manganese composite
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Pending
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CN201611254962.5A
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Chinese (zh)
Inventor
龙炳清
苏光麒
李燕
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Sichuan Normal University
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Sichuan Normal University
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Priority to CN201611254962.5A priority Critical patent/CN106746250A/en
Publication of CN106746250A publication Critical patent/CN106746250A/en
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    • C—CHEMISTRY; METALLURGY
    • C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F9/00—Multistage treatment of water, waste water or sewage
    • C—CHEMISTRY; METALLURGY
    • C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00—Treatment of water, waste water, or sewage
    • C02F1/34—Treatment of water, waste water, or sewage with mechanical oscillations
    • C02F1/36—Treatment of water, waste water, or sewage with mechanical oscillations ultrasonic vibrations
    • C—CHEMISTRY; METALLURGY
    • C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00—Treatment of water, waste water, or sewage
    • C02F1/66—Treatment of water, waste water, or sewage by neutralisation; pH adjustment
    • C—CHEMISTRY; METALLURGY
    • C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00—Treatment of water, waste water, or sewage
    • C02F1/70—Treatment of water, waste water, or sewage by reduction
    • C02F1/705—Reduction by metals
    • C—CHEMISTRY; METALLURGY
    • C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00—Treatment of water, waste water, or sewage
    • C02F2001/007—Processes including a sedimentation step
    • C—CHEMISTRY; METALLURGY
    • C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F3/00—Biological treatment of water, waste water, or sewage
    • C02F2003/001—Biological treatment of water, waste water, or sewage using granular carriers or supports for the microorganisms
    • C—CHEMISTRY; METALLURGY
    • C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F3/00—Biological treatment of water, waste water, or sewage
    • C02F2003/001—Biological treatment of water, waste water, or sewage using granular carriers or supports for the microorganisms
    • C02F2003/003—Biological treatment of water, waste water, or sewage using granular carriers or supports for the microorganisms using activated carbon or the like
    • C—CHEMISTRY; METALLURGY
    • C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F2101/00—Nature of the contaminant
    • C02F2101/30—Organic compounds
    • C—CHEMISTRY; METALLURGY
    • C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F2103/00—Nature of the water, waste water, sewage or sludge to be treated
    • C02F2103/34—Nature of the water, waste water, sewage or sludge to be treated from industrial activities not provided for in groups C02F2103/12 - C02F2103/32
    • C02F2103/36—Nature of the water, waste water, sewage or sludge to be treated from industrial activities not provided for in groups C02F2103/12 - C02F2103/32 from the manufacture of organic compounds
    • C—CHEMISTRY; METALLURGY
    • C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F2301/00—General aspects of water treatment
    • C02F2301/04—Flow arrangements
    • C02F2301/046—Recirculation with an external loop
    • C—CHEMISTRY; METALLURGY
    • C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F2301/00—General aspects of water treatment
    • C02F2301/08—Multistage treatments, e.g. repetition of the same process step under different conditions
    • C—CHEMISTRY; METALLURGY
    • C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F2303/00—Specific treatment goals
    • C02F2303/24—Separation of coarse particles, e.g. by using sieves or screens
    • C—CHEMISTRY; METALLURGY
    • C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F3/00—Biological treatment of water, waste water, or sewage
    • C02F3/02—Aerobic processes
    • C—CHEMISTRY; METALLURGY
    • C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F3/00—Biological treatment of water, waste water, or sewage
    • C02F3/28—Anaerobic digestion processes
    • C—CHEMISTRY; METALLURGY
    • C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F3/00—Biological treatment of water, waste water, or sewage
    • C02F3/34—Biological treatment of water, waste water, or sewage characterised by the microorganisms used
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E50/00—Technologies for the production of fuel of non-fossil origin
    • Y02E50/30—Fuel from waste, e.g. synthetic alcohol or diesel

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  • Life Sciences & Earth Sciences (AREA)
  • Hydrology & Water Resources (AREA)
  • Engineering & Computer Science (AREA)
  • Environmental & Geological Engineering (AREA)
  • Water Supply & Treatment (AREA)
  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Treatment Of Water By Oxidation Or Reduction (AREA)
  • Purification Treatments By Anaerobic Or Anaerobic And Aerobic Bacteria Or Animals (AREA)

Abstract

The processing method of the Ipomoea batatas alcohol waste water that the present invention is introduced includes solid-liquor separation, the CO under ul-trasonic irradiation2The operations such as the reduction of pressurization iron-aluminum-manganese composite powder, anaerobism, the treatment of aerobic and biological filtering tower combined working, the waste water after treatment can stably reaching standard discharge.

Description

The processing method of Ipomoea batatas alcohol waste water
Technical field
The present invention relates to a kind of processing method of Ipomoea batatas alcohol waste water.
Background technology
Ipomoea batatas is one of primary raw material of production alcohol, and the organic waste water pollutant COD concentration that its production is produced is high, into Divide complexity, intractability is big.If the waste water is not processed is directly discharged into environment, severe contamination will be caused to environment.Current sweet potato wine The processing method of smart waste water is mainly biological treatment.Due to containing persistence organic pollutant in Ipomoea batatas alcohol waste water（Containing benzene Ring and（Or）Heterocycle organic matter）, during especially with fresh sweet potatoes for primary raw material, the concentration of persistence organic pollutant is higher, Biochemical method Ipomoea batatas alcohol waste water is thereby resulted in it is difficult to stably reaching standard is discharged.The Ipomoea batatas alcohol of exploitation energy stably reaching standard discharge gives up The processing method of water has larger practical value.
The content of the invention
For the problem of current Ipomoea batatas alcohol method of wastewater treatment, the purpose of the present invention is to find energy stably reaching standard discharge The processing method of Ipomoea batatas alcohol waste water, it is characterised in that Ipomoea batatas alcohol waste water is carried out into solid-liquor separation, the waste water isolated enters Regulating reservoir, the solid isolated makees feed.Ipomoea batatas alcohol waste water feeding voltage-resistant reactor after adjusted pond regulation, will clean iron Aluminium manganese composite powder adds reactor, and is passed through industrial CO2Reacted.The granularity of iron-aluminum-manganese composite powder is less than 180 mesh, iron-aluminum-manganese The content of every kind of metal is not less than 5% in composite powder（The iron-aluminum-manganese composite powder that return is used is not limited）, every liter of waste water addition Iron-aluminum-manganese composite powder 5g~30g.The stirring reaction time is 10min~40min under ul-trasonic irradiation.Reaction temperature be 25 DEG C~ 60℃。CO2Pressure be 0.1MPa~0.6MPa.The ultrasonic power of every cubic metre of waste water input is 2kW~8kW.After reaction Waste water carry out solid-liquor separation, the iron-aluminum-manganese composite powder Returning reactor isolated.Waste water milk of lime after solid-liquor separation or Other alkaline matters adjust its pH value to 7.0~8.5, subsequently into anaerobic reactor.Waste water anaerobic reactor stop 24h~ 120h, anaerobism temperature is 25 DEG C~55 DEG C.Into the treatment of biology aerobic pond normal temperature, the Aerobic Process for Treatment time is 4h to waste water after anaerobism ~12h.Waste water after Aerobic Process for Treatment enters sedimentation basin, and the sedimentation time is 1h~3h.Irregularly sludge is extracted out from sedimentation basin to enter Row filtering, filter cake makees general disposition of solid waste, and filtrate returns to Aerobic Pond.The supernatant waste water of sedimentation basin send multi-layer biological filter tower Treatment.The filler of biological filtering tower combined working is activated carbon or porous ceramic grain, is 0.5m~1.0m per thickness degree, and gross thickness is 1m~3m.It is raw The dominant bacteria of thing filter tower is the red pseudomonas in photosynthetic bacteria（Rhodopseudomonas）.The hydraulic load of biological filtering tower combined working It is 50 m3/m2.d~150m3/m2.d.The standard water discharge discharge or reuse of biological filtering tower combined working.
The object of the present invention is achieved like this, and the solid matter of Ipomoea batatas alcohol waste water is more, is combined iron-aluminum-manganese is entered Before powder reduction reactor, solid-liquor separation is carried out, it is to avoid the influence that solid matter is reduced to iron-aluminum-manganese composite powder, be also beneficial to not anti- The iron-aluminum-manganese composite powder recycling answered.After waste water enters iron-aluminum-manganese composite powder reduction reactor, the macromolecular in waste water Organic matter, particularly persistence organic pollutant（Containing phenyl ring and（Or）The organic matter of heterocycle etc.）Reduced by iron-aluminum-manganese composite powder Produce strong reduction free radical effect and destroy, be subsequent biochemical treatment create favorable conditions.It is passed through pressure CO2Purpose be Iron-aluminum-manganese composite powder is maintained to reduce suitable pH value（2.0~5.0）；The effect for being input into ultrasonic wave is the mass transfer of Accelerating reduction reaction Process.Waste water milk of lime or other alkaline matters after reduction adjust its pH, to meet wanting for follow-up anaerobic and aerobic process Ask.Through the waste water of aforementioned processing in anaerobic processes, by the effect of microorganism, larger molecular organicses further become small molecule Organic matter, is that more favorable condition is created in subsequent bio oxidation.Processed by biological oxidation, remaining most of organic matters are gone Remove, while going to denitrogenate the pollutants such as phosphorus.Waste water finally enters activated carbon or porous ceramic grain biological filtering tower combined working, in microorganism, particularly In the presence of red pseudomonas, the pollutant such as further organics removal and nitrogen phosphorus, it is ensured that the waste water stably reaching standard row after treatment Put.
Relative to existing method, outstanding advantages of the invention are reduced using iron-aluminum-manganese composite powder, will be lasting in waste water Contact scar thing is destroyed, and is that subsequent biological treatment creates favorable conditions, so as to ensure the waste water stably reaching standard discharge after treatment；Relatively In the metal deoxidization used in other wastewater treatments, using CO2Make acidulant instead of now widely used sulfuric acid, do not draw Enter SO4 2-Ion, eliminates generation H2The material base of S, so as to avoid H2The pollution of S, while it also avoid SO4 2-To anaerobism With it is aerobic during microorganism inhibitory action, greatly improve the efficiency of biological treatment；Boiler, fuel are all had in Ipomoea batatas Alcohol Plant Burn the CO for producing2Waste gas can make full use of, and can not only reduce processing cost, and can reduce carbon emission；It is useless after treatment Water energy stably reaching standard is discharged, with obvious economic benefit and environmental benefit.
Specific implementation method
Embodiment 1：1m is processed daily3Ipomoea batatas alcohol waste water（Composition： CODCr38500 mg/L、T-N42.2m/L、 SS28000mg/L, T-P4.5mg/L, colourity 750）, reduced through solid-liquor separation, iron-aluminum-manganese composite powder（10min、40℃、CO2Pressure The ultrasonic power 4kW that power 0.6MPa, every liter of waste water add iron-aluminum-manganese composite powder 15g, every cubic metre of waste water to be input into）, anaerobism （PH8.5,72h, 25 DEG C~35 DEG C）, it is aerobic（4h）And biological filtering tower combined working（Porous ceramic grain packing layer gross thickness 1m, hydraulic load 50m3/m2.d）The COD of water outlet after treatmentCrIt is 68mg/L, T-N7.2mg/L, T-P0.2mg/L, colourity 23.
Embodiment 2：5m is processed daily3Ipomoea batatas alcohol waste water（Composition:CODCr40500 mg/L、T-N45.1m/L、 SS31500mg/L, T-P4.2mg/L, colourity 780）, reduced through solid-liquor separation, iron-aluminum-manganese composite powder（25min、25℃、CO2Pressure The ultrasonic power 2kW that power 0.1MPa, every liter of waste water add iron-aluminum-manganese composite powder 5g, every cubic metre of waste water to be input into）, anaerobism （PH7.0,24h, 35 DEG C~55 DEG C）, it is aerobic（6h）And biological filtering tower combined working（Active carbon filler layer gross thickness 2m, hydraulic load 150m3/ m2.d）The COD of water outlet after treatmentCrIt is 72mg/L, T-N8.3mg/L, T-P0.2mg/L, colourity 26.

Claims (1)

1. a kind of processing method of Ipomoea batatas alcohol waste water, it is characterised in that Ipomoea batatas alcohol waste water is carried out into solid-liquor separation, is isolated Waste water enter regulating reservoir, the solid isolated makees feed, and the Ipomoea batatas alcohol waste water after adjusted pond regulation sends into pressure-resistant reaction Device, adds reactor, and be passed through industrial CO by cleaning iron-aluminum-manganese composite powder2Reacted, the granularity of iron-aluminum-manganese composite powder is less than 180 mesh, the content of every kind of metal is not less than 5% in iron-aluminum-manganese composite powder, and every liter of waste water adds iron-aluminum-manganese composite powder 5g~30g, Under ul-trasonic irradiation the stirring reaction time be 10min~40min, reaction temperature be 25 DEG C~60 DEG C, CO2Pressure be 0.1MPa ~0.6MPa, the ultrasonic power of every cubic metre of waste water input is 2kW~8kW, and reacted waste water carries out solid-liquor separation, is separated The iron-aluminum-manganese composite powder Returning reactor for going out, waste water milk of lime or other alkaline matters after solid-liquor separation adjust its pH value and arrive 7.0~8.5, subsequently into anaerobic reactor, waste water stops 24h~120h in anaerobic reactor, and anaerobism temperature is 25 DEG C~55 DEG C, into the treatment of biology aerobic pond normal temperature, the Aerobic Process for Treatment time is 4h~12h, the waste water after Aerobic Process for Treatment to the waste water after anaerobism Into sedimentation basin, the sedimentation time is 1h~3h, irregularly extracts sludge out from sedimentation basin and is filtered, and filter cake is made general solid and given up Gurry is disposed, and filtrate returns to Aerobic Pond, and the supernatant waste water of sedimentation basin send multi-layer biological filter tower to process, and the filler of biological filtering tower combined working is work Property charcoal or porous ceramic grain, filler gross thickness is 1m~3m, and the dominant bacteria of biological filtering tower combined working is the red pseudomonas in photosynthetic bacteria, The hydraulic load of biological filtering tower combined working is 50 m3/m2.d~150m3/m2.d, the standard water discharge discharge or reuse of biological filtering tower combined working.
CN201611254962.5A 2016-12-30 2016-12-30 The processing method of Ipomoea batatas alcohol waste water Pending CN106746250A (en)

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Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101665311A (en) * 2009-09-24 2010-03-10 中南大学 Catalysis and micro-electrolysis combined technology for high-concentration refractory organic wastewater

Patent Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101665311A (en) * 2009-09-24 2010-03-10 中南大学 Catalysis and micro-electrolysis combined technology for high-concentration refractory organic wastewater

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Application publication date: 20170531