CN106673338A - Treatment method of sweet potato alcohol wastewater - Google Patents

Treatment method of sweet potato alcohol wastewater Download PDF

Info

Publication number
CN106673338A
CN106673338A CN201611256238.6A CN201611256238A CN106673338A CN 106673338 A CN106673338 A CN 106673338A CN 201611256238 A CN201611256238 A CN 201611256238A CN 106673338 A CN106673338 A CN 106673338A
Authority
CN
China
Prior art keywords
waste water
composite powder
zinc composite
solid
iron zinc
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201611256238.6A
Other languages
Chinese (zh)
Inventor
龙炳清
邓国海
陈建平
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Sichuan Normal University
Original Assignee
Sichuan Normal University
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Sichuan Normal University filed Critical Sichuan Normal University
Priority to CN201611256238.6A priority Critical patent/CN106673338A/en
Publication of CN106673338A publication Critical patent/CN106673338A/en
Pending legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F9/00—Multistage treatment of water, waste water or sewage
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/34—Chemical or biological purification of waste gases
    • B01D53/46—Removing components of defined structure
    • B01D53/62—Carbon oxides
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/34—Chemical or biological purification of waste gases
    • B01D53/74—General processes for purification of waste gases; Apparatus or devices specially adapted therefor
    • B01D53/77—Liquid phase processes
    • B01D53/78—Liquid phase processes with gas-liquid contact
    • C—CHEMISTRY; METALLURGY
    • C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00—Treatment of water, waste water, or sewage
    • C02F1/34—Treatment of water, waste water, or sewage with mechanical oscillations
    • C02F1/36—Treatment of water, waste water, or sewage with mechanical oscillations ultrasonic vibrations
    • C—CHEMISTRY; METALLURGY
    • C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00—Treatment of water, waste water, or sewage
    • C02F1/66—Treatment of water, waste water, or sewage by neutralisation; pH adjustment
    • C—CHEMISTRY; METALLURGY
    • C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00—Treatment of water, waste water, or sewage
    • C02F1/70—Treatment of water, waste water, or sewage by reduction
    • C02F1/705—Reduction by metals
    • C—CHEMISTRY; METALLURGY
    • C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00—Treatment of water, waste water, or sewage
    • C02F2001/007—Processes including a sedimentation step
    • C—CHEMISTRY; METALLURGY
    • C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F2101/00—Nature of the contaminant
    • C02F2101/30—Organic compounds
    • C—CHEMISTRY; METALLURGY
    • C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F2103/00—Nature of the water, waste water, sewage or sludge to be treated
    • C02F2103/32—Nature of the water, waste water, sewage or sludge to be treated from the food or foodstuff industry, e.g. brewery waste waters
    • C02F2103/325—Nature of the water, waste water, sewage or sludge to be treated from the food or foodstuff industry, e.g. brewery waste waters from processes relating to the production of wine products
    • C—CHEMISTRY; METALLURGY
    • C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F2103/00—Nature of the water, waste water, sewage or sludge to be treated
    • C02F2103/34—Nature of the water, waste water, sewage or sludge to be treated from industrial activities not provided for in groups C02F2103/12 - C02F2103/32
    • C02F2103/36—Nature of the water, waste water, sewage or sludge to be treated from industrial activities not provided for in groups C02F2103/12 - C02F2103/32 from the manufacture of organic compounds
    • C—CHEMISTRY; METALLURGY
    • C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F2209/00—Controlling or monitoring parameters in water treatment
    • C02F2209/08—Chemical Oxygen Demand [COD]; Biological Oxygen Demand [BOD]
    • C—CHEMISTRY; METALLURGY
    • C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F2209/00—Controlling or monitoring parameters in water treatment
    • C02F2209/16—Total nitrogen (tkN-N)
    • C—CHEMISTRY; METALLURGY
    • C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F2209/00—Controlling or monitoring parameters in water treatment
    • C02F2209/18—PO4-P
    • C—CHEMISTRY; METALLURGY
    • C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F3/00—Biological treatment of water, waste water, or sewage
    • C02F3/02—Aerobic processes
    • C—CHEMISTRY; METALLURGY
    • C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F3/00—Biological treatment of water, waste water, or sewage
    • C02F3/28—Anaerobic digestion processes
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E50/00—Technologies for the production of fuel of non-fossil origin
    • Y02E50/30—Fuel from waste, e.g. synthetic alcohol or diesel

Landscapes

  • Engineering & Computer Science (AREA)
  • Chemical & Material Sciences (AREA)
  • Environmental & Geological Engineering (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Biomedical Technology (AREA)
  • Analytical Chemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Health & Medical Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Hydrology & Water Resources (AREA)
  • Water Supply & Treatment (AREA)
  • Organic Chemistry (AREA)
  • Water Treatment By Sorption (AREA)
  • Purification Treatments By Anaerobic Or Anaerobic And Aerobic Bacteria Or Animals (AREA)
  • Treatment Of Water By Oxidation Or Reduction (AREA)

Abstract

The invention provides a treatment method of sweet potato alcohol wastewater. The treatment method comprises the procedures of carrying out liquid-solid separation, reducing by CO2 pressurized iron-zinc composite powder, carrying out anaerobic and aerobic treatment, and treating by a biological filtering tower and the like. The treated wastewater can stably reach emission standards and then is discharged.

Description

The processing method of Ipomoea batatas alcohol waste water
Technical field
The present invention relates to a kind of processing method of Ipomoea batatas alcohol waste water.
Background technology
Ipomoea batatas is one of primary raw material of production alcohol, and the organic waste water pollutant COD concentration that its production is produced is high, into Divide complexity, intractability is big.If the waste water is not processed is directly discharged into environment, severe contamination will be caused to environment.Current sweet potato wine The processing method of smart waste water is mainly biological treatment.Due to containing persistence organic pollutant in Ipomoea batatas alcohol waste water（Containing benzene Ring and（Or）Heterocycle organic matter）, during especially with fresh sweet potatoes for primary raw material, the concentration of persistence organic pollutant is higher, Biochemical method Ipomoea batatas alcohol waste water is thereby resulted in it is difficult to stably reaching standard is discharged.The Ipomoea batatas alcohol of exploitation energy stably reaching standard discharge gives up The processing method of water has larger practical value.
The content of the invention
For the problem of current Ipomoea batatas alcohol method of wastewater treatment, the purpose of the present invention is to find energy stably reaching standard discharge The processing method of Ipomoea batatas alcohol waste water, it is characterised in that Ipomoea batatas alcohol waste water is carried out into solid-liquor separation, the waste water isolated enters Regulating reservoir, the solid isolated makees feed.Ipomoea batatas alcohol waste water feeding voltage-resistant reactor after adjusted pond regulation, will clean iron Zinc composite powder adds reactor, and is passed through industrial CO2Reacted, the granularity of iron zinc composite powder is less than 180 mesh, and cleaning iron zinc is answered The content for closing each metal in powder is not less than 5%（The iron zinc composite powder that return is used is not limited）, every liter of waste water addition Iron zinc composite powder 5g~30g, the stirring reaction time be 1h~3h, reaction temperature be 25 DEG C~60 DEG C, CO2Pressure be 0.1MPa ~0.6MPa.Reacted waste water carries out solid-liquor separation, the iron zinc composite powder Returning reactor isolated.It is useless after solid-liquor separation Water milk of lime or other alkaline matters adjust its pH value to 7.0~8.5, subsequently into anaerobic reactor.Waste water is anti-in anaerobism Device is answered to stop 24h~120h, anaerobism temperature is 25 DEG C~55 DEG C.Waste water after anaerobism is good into the treatment of biology aerobic pond normal temperature Oxygen process time is 4h~12h.Waste water after Aerobic Process for Treatment enters sedimentation basin, and the sedimentation time is 1h~3h.Irregularly from precipitation Extract sludge in pond out to be filtered, filter cake makees general disposition of solid waste, filtrate returns to Aerobic Pond.The supernatant waste water of sedimentation basin Multi-layer biological filter tower is sent to process.The filler of biological filtering tower combined working is activated carbon or porous ceramic grain, is 0.5m~1.0m, total thickness per thickness degree It is 1m~3m to spend.The dominant bacteria of biological filtering tower combined working is the red pseudomonas in photosynthetic bacteria（Rhodopseudomonas）.It is biological The hydraulic load of filter tower is 50 m3/m2.d~150m3/m2.d.The standard water discharge discharge or reuse of biological filtering tower combined working.
The object of the present invention is achieved like this, and the solid matter of Ipomoea batatas alcohol waste water is more, is entering iron zinc composite powder Before reduction reactor, solid-liquor separation is carried out, it is to avoid the influence that solid matter is reduced to iron zinc composite powder, be also beneficial to unreacted complete Iron zinc composite powder recycling.After waste water enters iron zinc composite powder reduction reactor, the larger molecular organicses in waste water are special It is not persistence organic pollutant（Containing phenyl ring and（Or）The organic matter of heterocycle etc.）The strong also of generation is reduced by iron zinc composite powder The effect of former free radical and destroy, be subsequent biochemical treatment create favorable conditions.It is passed through pressure CO2Purpose be to maintain iron zinc to answer Close powder and reduce suitable pH value（2.0~5.0）, waste water milk of lime or other alkaline matters after reduction adjust its pH, with full The requirement of the follow-up anaerobic and aerobic process of foot.Through the waste water of aforementioned processing in anaerobic processes, by the effect of microorganism, big point Sub- organic matter further becomes small organic molecule, is that more favorable condition is created in subsequent bio oxidation.Processed by biological oxidation, Remaining most of organic matters are removed, while going to denitrogenate the pollutants such as phosphorus.Waste water finally enters activated carbon or porous ceramic grain life Thing filter tower, in the presence of microorganism, particularly red pseudomonas, the pollutant such as further organics removal and nitrogen phosphorus, it is ensured that Waste water stably reaching standard discharge after treatment.
Relative to existing method, outstanding advantages of the invention are reduced using iron zinc composite powder, by the persistence in waste water Pollutant is destroyed, and is that subsequent biological treatment creates favorable conditions, so as to ensure the waste water stably reaching standard discharge after treatment；Relative to The metal deoxidization used in other wastewater treatments, using CO2Make acidulant instead of now widely used sulfuric acid, do not introduce SO4 2-Ion, eliminates generation H2The material base of S, so as to avoid H2The pollution of S, while it also avoid SO4 2-To anaerobism and The inhibitory action of microorganism in aerobic process, greatly improves the efficiency of biological treatment；Boiler, fuel combustion are all had in Ipomoea batatas Alcohol Plant Burn the CO for producing2Waste gas can make full use of, and can not only reduce processing cost, and can reduce carbon emission；Waste water after treatment Energy stably reaching standard discharge, with obvious economic benefit and environmental benefit.
Specific implementation method
Embodiment 1：1m is processed daily3Ipomoea batatas alcohol waste water（Composition： CODCr38500 mg/L、T-N42.2m/L、 SS28000mg/L, T-P4.5mg/L, colourity 750）, reduced through solid-liquor separation, iron zinc composite powder（1h、40℃、CO2Pressure 0.6MPa, every liter of waste water add iron zinc composite powder 15g）, anaerobism（PH8.5,72h, 25 DEG C~35 DEG C）, it is aerobic（4h）And biological filter Tower（Porous ceramic grain packing layer gross thickness 1m, hydraulic load 50m3/m2.d）The COD of water outlet after treatmentCrIt is 60mg/L, T- N7.0mg/L, T-P0.2mg/L, colourity 26.
Embodiment 2：5m is processed daily3Ipomoea batatas alcohol waste water（Composition:CODCr40500 mg/L、T-N45.1m/L、 SS31500mg/L, T-P4.2mg/L, colourity 780）, reduced through solid-liquor separation, iron zinc composite powder（2.5h、25℃、CO2Pressure 0.1MPa, every liter of waste water add iron zinc composite powder 5g）, anaerobism（PH7.0,24h, 35 DEG C~55 DEG C）, it is aerobic（6h）And biological filter Tower（Active carbon filler layer gross thickness 2m, hydraulic load 150m3/m2.d）The COD of water outlet after treatmentCrIt is 63mg/L, T-N7.5mg/ L, T-P0.2mg/L, colourity 28.

Claims (1)

1. a kind of processing method of Ipomoea batatas alcohol waste water, it is characterised in that Ipomoea batatas alcohol waste water is carried out into solid-liquor separation, is isolated Waste water enter regulating reservoir, the solid isolated makees feed, and the Ipomoea batatas alcohol waste water after adjusted pond regulation sends into pressure-resistant reaction Device, adds reactor, and be passed through industrial CO by cleaning iron zinc composite powder2Reacted, the granularity of iron zinc composite powder is less than 180 Mesh, the content of each metal in cleaning iron zinc composite powder is not less than 5%, and every liter of waste water adds iron zinc composite powder 5g~30g, The stirring reaction time be 1h~3h, reaction temperature be 25 DEG C~60 DEG C, CO2Pressure be 0.1MPa~0.6MPa, it is reacted Waste water carries out solid-liquor separation, the iron zinc composite powder Returning reactor isolated, waste water milk of lime after solid-liquor separation or other Alkaline matter adjusts its pH value to 7.0~8.5, subsequently into anaerobic reactor, waste water anaerobic reactor stop 24h~ 120h, anaerobism temperature is 25 DEG C~55 DEG C, and into the treatment of biology aerobic pond normal temperature, the Aerobic Process for Treatment time is 4h to the waste water after anaerobism ~12h, the waste water after Aerobic Process for Treatment enters sedimentation basin, and the sedimentation time is 1h~3h, irregularly extracts sludge out from sedimentation basin and enters Row filtering, filter cake makees general disposition of solid waste, and filtrate returns to Aerobic Pond, and the supernatant waste water of sedimentation basin send multi-layer biological filter tower Treatment, the filler of biological filtering tower combined working is activated carbon or porous ceramic grain, and filler gross thickness is 1m~3m, and the dominant bacteria of biological filtering tower combined working is Red pseudomonas in photosynthetic bacteria, the hydraulic load of biological filtering tower combined working is 50 m3/m2.d~150m3/m2.d, biological filtering tower combined working goes out Water qualified discharge or reuse.
CN201611256238.6A 2016-12-30 2016-12-30 Treatment method of sweet potato alcohol wastewater Pending CN106673338A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201611256238.6A CN106673338A (en) 2016-12-30 2016-12-30 Treatment method of sweet potato alcohol wastewater

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201611256238.6A CN106673338A (en) 2016-12-30 2016-12-30 Treatment method of sweet potato alcohol wastewater

Publications (1)

Publication Number Publication Date
CN106673338A true CN106673338A (en) 2017-05-17

Family

ID=58873407

Family Applications (1)

Application Number Title Priority Date Filing Date
CN201611256238.6A Pending CN106673338A (en) 2016-12-30 2016-12-30 Treatment method of sweet potato alcohol wastewater

Country Status (1)

Country Link
CN (1) CN106673338A (en)

Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101665311A (en) * 2009-09-24 2010-03-10 中南大学 Catalysis and micro-electrolysis combined technology for high-concentration refractory organic wastewater

Patent Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101665311A (en) * 2009-09-24 2010-03-10 中南大学 Catalysis and micro-electrolysis combined technology for high-concentration refractory organic wastewater

Non-Patent Citations (5)

* Cited by examiner, † Cited by third party
Title
宋志伟 等: "《水污染控制工程》", 31 July 2013, 中国矿业大学出版社 *
张修正: "《化工厂电气手册》", 31 December 1994, 化学工业出版社 *
施悦 等: "《环境氧化还原处理技术原理与应用》", 31 August 2013, 哈尔滨工业大学出版社 *
湖南省爱国卫生运动委员会办公室 等: "《爱国卫生运动工作手册》", 31 July 1986, 湖南人民出版社 *
郑西来: "《地下水污染控制》", 31 July 2009, 华中科技大学出版社 *

Similar Documents

Publication Publication Date Title
CN106746236A (en) The processing method of chemical industrial organic wastewater
CN106673338A (en) Treatment method of sweet potato alcohol wastewater
CN106746286A (en) The processing method of Ipomoea batatas alcohol waste water
CN106746285A (en) The processing method of Ipomoea batatas alcohol waste water
CN106746239A (en) The processing method of Ipomoea batatas alcohol waste water
CN106673324A (en) Treatment method of sweet potato alcohol wastewater
CN106673315A (en) Treatment method of sweet potato alcohol waste water
CN106746237A (en) The processing method of Ipomoea batatas alcohol waste water
CN106746250A (en) The processing method of Ipomoea batatas alcohol waste water
CN106746251A (en) The processing method of Ipomoea batatas alcohol waste water
CN106673337A (en) Processing method of sweet potato alcohol waste water
CN106746238A (en) The processing method of Ipomoea batatas alcohol waste water
CN106673336A (en) Method for treating wastewater of alcohol produced from sweet potatoes
CN106587512A (en) Method for treating sweet-potato alcohol wastewater
CN106698827A (en) Treatment method of sweet potato alcohol wastewater
CN106673339A (en) Sweet potato alcohol wastewater treatment method
CN106673352A (en) Treatment method of wastewater produced from C-D total solvent production
CN106746283A (en) The processing method of Ipomoea batatas alcohol waste water
CN106746284A (en) The processing method of Ipomoea batatas alcohol waste water
CN106746315A (en) Propyl-butyl total solvent produces the processing method of waste water
CN106698832A (en) Method for treating sweet potato alcohol wastewater
CN107055935A (en) The processing method of sweet potato alcohol waste water
CN106746260A (en) Propyl-butyl total solvent produces the processing method of waste water
CN106673343A (en) Treatment method of production wastewater of acetone-butanol-ethanol total solvent
CN106746263A (en) Propyl-butyl total solvent produces the processing method of waste water

Legal Events

Date Code Title Description
PB01 Publication
PB01 Publication
SE01 Entry into force of request for substantive examination
SE01 Entry into force of request for substantive examination
RJ01 Rejection of invention patent application after publication
RJ01 Rejection of invention patent application after publication

Application publication date: 20170517