CN106732491A - A kind of horizontal continuous regeneration equipment of powdery waste active carbon - Google Patents

A kind of horizontal continuous regeneration equipment of powdery waste active carbon Download PDF

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Publication number
CN106732491A
CN106732491A CN201710075004.XA CN201710075004A CN106732491A CN 106732491 A CN106732491 A CN 106732491A CN 201710075004 A CN201710075004 A CN 201710075004A CN 106732491 A CN106732491 A CN 106732491A
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China
Prior art keywords
regenerating
tube
drying
regeneration
active carbon
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CN201710075004.XA
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蒋应梯
庄晓伟
潘炘
王进
刘亚群
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Zhejiang Academy of Forestry
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Zhejiang Academy of Forestry
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Priority to CN201710075004.XA priority Critical patent/CN106732491A/en
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    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/30Processes for preparing, regenerating, or reactivating
    • B01J20/34Regenerating or reactivating
    • B01J20/3416Regenerating or reactivating of sorbents or filter aids comprising free carbon, e.g. activated carbon

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Analytical Chemistry (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Solid-Sorbent Or Filter-Aiding Compositions (AREA)

Abstract

A kind of horizontal continuous regeneration equipment of powdery waste active carbon, it is made up of drying oven, regenerating furnace and the part of cooling discharging pipe three, is specifically made up of useless charcoal drying oven, drying offgas outlet, raw materials bucket, regeneration tail gas outlet, regenerating tube, feedstock transportation helical axis, spiral page, spiral sleeve, drive sprocket, regeneration apparatus casing, fresh air inlet, drying oven and regenerating furnace temperature probe, cooling water jecket, discharging spiral, discharge nozzle, fuel burner nozzle and blast pipe.More than one layer horizontally arranged drying tube is installed in drying oven, multiple rows of multi-layer recycled pipe is set in regenerating furnace, drying tube is connected with the top regenerating tube of regenerating furnace, and raw material is fed sequentially into next layer of regenerating tube by conveyor screw, and useless charcoal is moved in drying tube and regenerating tube.Useless charcoal is heated regeneration after being dried in drying tube with helical feed to regenerating tube, and the fuel gas of volatilization escapes burning to heat the regenerating tube of upper row from regenerating tube, and high temperature regeneration tail gas is used to dry waste active carbon raw material.

Description

A kind of horizontal continuous regeneration equipment of powdery waste active carbon
First, technical field
Generating apparatus again the present invention relates to recover waste active carbon adsorption capacity, especially a kind of powdery waste active carbon is horizontal Continuous regeneration equipment.
2nd, technical background
At present, most of high performance powdered activated carbon is produced by raw material chemical activation method of wood chip, such as wood chip phosphorus Powdered activated carbon prepared by acid activation method, it produces activate tail gas and phosphorous poaching wastewater containing pyrophosphoric acid in process of production, needs Larger in the investment of the Environmental-protecting treater of activation tail gas and poaching wastewater, and production process is cumbersome, production cost also compared with It is high.And used chemical carbon is regenerated, its cost charcoal more former than production is much lower, while the regeneration of waste active carbon, both The environmental protection treatment of waste active carbon can be solved the problems, such as, the high-valued recycling of waste resource can be realized again.But it is useless to powdery at present to live The regeneration of property charcoal is limited only to the used waste active carbon of food service industry, and for the used waste active carbon of the industries such as pharmacy, chemical industry again It is raw, volatilization or decompose the organic gas for producing and can pollute greatly because the organic matter that waste active carbon is adsorbed in regenerative process is heated Compression ring border, into medicine enterprise, the discarded object of chemical enterprise, enterprise is forced to spend to ask qualified mechanism to be processed waste active carbon, Increase the cost burden of enterprise.Hence it is highly desirable to environmentally friendly advanced powdery Regenevating Waste Activated Carbon technique and equipment, by these powder Shape waste active carbon carries out concentration regeneration, can both realize turning waste into wealth, while being again to solve the problems, such as offal treatment.At present, it is right The equipment that powdery waste active carbon is regenerated mainly tunnel cave, useless carbon feedstock is placed in tunnel cave in smoldering tank to be carried out Smoldering thermal regeneration, technique relatively falls behind, and intermittently operated, labour intensity is big;It has been similar to the special of powdery Regenevating Waste Activated Carbon equipment Profit is such as:The patent " high-performance intermediate frequency activated carbon regenerating equipment " of Application No. 200920011186.5, it is carried out with intermediate frequency power supply Heating, power consumption is larger;The patent " the charcoal regenerating treater of built-in preliminary heating zone " of Application No. 201220519647.1, it Burnt with fuel oil and heated, there is a problem that flue gas pollutes environment;The patent " one of Application No. 201520931753.1 The vertical regenerating furnace of kind of waste active carbon ", it by powdery waste active carbon with molasses as binding agent be made cylindrical particle after could be vertical Moved from top to down in formula activation tube, needed before regeneration through overmolding granulation process, it appears trouble;Application No. A kind of 201610708657.2 patent " Powdered Activated Carbon regenerating furnace ", it makees heating energy source with combustion gas, high-moisture it is useless wet Carbon feedstock is directly added into regenerating tube, and water vapour and flammable the volatilization gas concentration that mixes are brought out regenerating tube after being heated, Collect and burnt by sending back to the burner of regenerating furnace both sides after spray column purification with air-introduced machine again, have lost high temperature regeneration tail The waste heat of gas, and it is also not uniform enough to the heating of regenerating tube, while the load of spray column is larger, investment is high.Based on above-mentioned background, Invention a kind of simple structure, reduced investment, the horizontal cyclic regeneration that directly can be regenerated to powdery waste active carbon set It is standby.
3rd, the content of the invention
A kind of horizontal continuous regeneration equipment of powdery waste active carbon of invention, it is by useless charcoal drying oven, regenerating furnace Constituted with the part of cooling discharging pipe three, specifically by useless charcoal drying oven (1), drying offgas outlet (2), raw materials bucket (3), drying Stove temperature probe (4), regeneration tail gas outlet (5), regenerating tube (6) and (12), feedstock transportation helical axis (7), spiral page (8), spiral shell Spin axis set (9), drive sprocket (10), regeneration apparatus casing (11), fresh air inlet (13), regenerating furnace temperature probe (14), cooling water Chuck (15), discharging spiral (16), discharge nozzle (17), fuel burner nozzle (18) and blast pipe (19) are constituted.Useless charcoal drying oven and The housing of regenerating furnace is built into by refractory brick and heat-insulation layer and common brick, installed in the charcoal drying oven of giving up more than one layer it is horizontally arranged Drying tube;Multiple rows of multi-layer recycled pipe is set from top to bottom in regenerating furnace, and drying tube is linked to be with the top regenerating tube of regenerating furnace Integrally, raw material is transported to drying tube from loading hopper by conveyor screw, then is fed sequentially into next layer of regeneration by conveyor screw Pipe, drives conveying worm to operate, the conveying of neighbouring two root regenerations pipe through reducing gear with buncher by Chain conveyer Spiral rotation direction is conversely, allow useless carbon feedstock to be moved in drying tube and regenerating tube, powdery waste active carbon is by multi-layer recycled pipe High-temperature heating regeneration, after most being cooled down through the cooling water jecket of discharge nozzle afterwards discharge.Drying tube and regenerating tube and discharge nozzle Diameter it is identical, be 0.2~0.4 meter, the diameter of feedstock transportation helical axis is smaller 0.10~0.15 meter than regeneration bore, makes charcoal Thickness degree is 0.05~0.075 meter, to ensure that layer of charcoal is comparatively fast heated.In regeneration furnace shell both sides bottom, the combustion of heating is set Gas burner, for the regenerating tube in thermal regeneration stove, is uniformly arranged multiple ventholes, for waste active carbon on every root regeneration pipe In flammable volatilization gas effusion, in regenerating furnace both sides, multiple fresh air inlets are set, be passed through appropriate air with air blower, it is flammable to wave Body of getting angry is burnt under air-breathing to heat the regenerating tube arranged thereon, is analogized with secondary.So, both heated useless in regenerating tube Activated carbon, eliminates pollution of the volatilization gas to air again.The high-temperature tail gas produced in regenerating furnace export (5) quilt by regeneration tail gas Heat drying pipe in useless charcoal drying oven is directed to, to dry the waste active carbon raw material in pipe, is reduced and is entered activity of being given up in regenerating furnace The moisture of charcoal.Waste active carbon after drying is extensive into heated removal adsorbate therein in the regenerating tube of regenerating furnace Multiple its adsorption capacity.The tail gas of useless charcoal drying oven heats water vapor in being directed into waste heat boiler, finally by tail gas through spray Entered in air by chimney after drenching purified treatment.A kind of horizontal cyclic regeneration of powdery waste active carbon of the present invention sets Standby, it is characterized in that being heated regeneration with helical feed to regenerating tube after useless carbon feedstock is dried in drying tube, what is volatilized is flammable Gas escapes burning to heat the regenerating tube of upper row from regenerating tube, and high temperature regeneration tail gas is used to dry waste active carbon raw material, Realize the comprehensive utilization of residual heat resources.
4th, illustrate
Fig. 1 is a kind of facade schematic cross-sectional view of the horizontal continuous regeneration equipment of powdery waste active carbon of the present invention, (1) It is useless charcoal drying oven;(2) it is drying offgas outlet;(3) it is raw materials bucket;(4) it is drying oven temperature probe;(5) it is regeneration Offgas outlet;(6), (12) are regenerating tube;(7) it is feedstock transportation helical axis;(8) it is spiral page;(9) it is spiral sleeve;(10) It is drive sprocket;(11) it is regeneration apparatus casing;(13) it is fresh air inlet;(14) it is regenerating furnace temperature probe;(15) it is cooling water Chuck;(16) it is discharging spiral;(17) it is discharge nozzle;(18) it is fuel burner nozzle;(19) it is blast pipe.Fig. 2 is A-A sections in Fig. 1 The profile in face, Fig. 3 is the top cross-sectional view of section B-B in Fig. 1, and Fig. 4 is the structural representation of regenerating tube, part description Ibid.
5th, specific embodiment
When regeneration equipment black furnace is started, light fuel burner nozzle (18) and begin to warm up regenerating furnace, when regenerating furnace temperature rise to 300 DEG C or so when, during waste active carbon added into loading hopper (3), open the motor of conveying worm, be transported to waste active carbon In drying tube and regenerating tube, charging motor is closed down when the discharging opening of discharge nozzle (17) has material to draw off.When regenerating furnace When temperature is raised to 550 DEG C or so, blower fan is opened, appropriate air is passed through to regenerating furnace by fresh air inlet (13), volatilize useless charcoal The gas fuel burning for coming, aids in thermal regeneration pipe.When the temperature of regenerating furnace reaches 800 DEG C or so, it is again started up driving electricity Machine, makes conveying worm microrunning, to the useless charcoal of regenerating tube addition, to supplement flammable volatilization gas.When furnace temperature rises very fast Just turn the combusting firepower of fuel burner nozzle (18) down, otherwise the combusting firepower of fuel burner nozzle (18) is just tuned up when furnace temperature is reduced, make Control for Kiln Temperature is at 850~900 DEG C.Regulation charging motor speed, and operate and pause after certain hour appropriate time, to extend useless charcoal The rotating speed of the residence time in regenerating furnace, charging and discharging machine is adjusted to identical.When the adsorptivity of discharging opening regenerated carbon When energy index reaches requirement, it is determined that the parameter such as rotating speed and the duration of runs and dead time of charging and discharging machine.
Example:
One a length of 5 meters of useless charcoal drying oven, regeneration bore are 0.4 meter, the spiral diameter of axle is 0.25 meter, regenerating furnace a length of 6 The generating apparatus again of four rows, five layers of regenerating tube of rice, regulation feeds and the rotating speed of discharging machine is 600 revs/min as stated above, The speed reducing ratio of reductor is 80, and revolution speed of screw is 7.5 revs/min, and at 850~900 DEG C, often operating stops regeneration Control for Kiln Temperature for 10 minutes Situation about pausing 5 minutes, the yield of regenerated carbon is 120 kgs/hr, and its methylene blue adsorption value is 225mg/g;Regulation adds Material and discharging machine rotating speed are 600 revs/min, and regeneration Control for Kiln Temperature is operated at 850~900 DEG C, often pauses 5 minutes for 15 minutes Situation, the yield of regenerated carbon is 135 kgs/hr, and its methylene blue adsorption value is 210mg/g;Regulation charging and discharging The rotating speed of motor is 500 revs/min, and regeneration Control for Kiln Temperature operates situation about pausing 5 minutes for 10 minutes at 850~900 DEG C, often, Regeneration activity carbon yield is double centner/hour, and its methylene blue adsorption value is 233mg/g;Regulation charging turns with discharging machine Speed is 500 revs/min, and regeneration Control for Kiln Temperature operates situation about pausing 5 minutes for 15 minutes, regeneration activity at 850~900 DEG C, often The yield of charcoal is 115 kgs/hr, and its methylene blue adsorption value is 218mg/g.

Claims (2)

1. a kind of horizontal continuous regeneration equipment of powdery waste active carbon, it is characterized in that:It is by useless charcoal drying oven, regenerating furnace and cooling The part of discharge nozzle three is constituted, specifically by useless charcoal drying oven (1), drying offgas outlet (2), raw materials bucket (3), drying oven thermometric Probe (4), regeneration tail gas outlet (5), regenerating tube (6) and (12), feedstock transportation helical axis (7), spiral page (8), spiral sleeve (9), drive sprocket (10), regeneration apparatus casing (11), fresh air inlet (13), regenerating furnace temperature probe (14), cooling water jecket (15), discharging spiral (16), discharge nozzle (17), fuel burner nozzle (18) and blast pipe (19) are constituted.Drying oven and regenerating furnace Housing is built into by refractory brick and heat-insulation layer and common brick, and more than one layer horizontally arranged drying tube is installed in drying oven, in regeneration Multiple rows of multi-layer recycled pipe is set from top to bottom in stove, and drying tube is connected with the top regenerating tube of regenerating furnace, raw material from plus Hopper is transported to drying tube by conveyor screw, then is fed sequentially into next layer of regenerating tube by conveyor screw, uses buncher Conveying worm is driven to operate by Chain conveyer through reducing gear, the conveyor screw rotation direction phase of neighbouring two root regenerations pipe Instead, useless carbon feedstock is allowed to be moved in drying tube and regenerating tube, waste powdered activated carbon regenerates by the high-temperature heating of multi-layer recycled pipe, Discharged after most being cooled down through the cooling water jecket of discharge nozzle afterwards.
2. the horizontal continuous regeneration equipment of a kind of powdery waste active carbon according to claim 1, it is characterized in that:In regenerating furnace The side bottom of housing two sets the fuel burner nozzle of heating, for the regenerating tube in heated shell, is uniformly set on every root regeneration pipe Multiple ventholes are put, for the effusion of flammable volatilization gas in waste active carbon, multiple fresh air inlets is set in regenerating furnace both sides, it is flammable The volatilization gas regenerating tube that combustion heating is arranged thereon under air-breathing, drying tube is identical with the diameter of regenerating tube and discharge nozzle, 0.2~0.4 meter is, feedstock transportation spiral shaft diameter is smaller 0.10~0.15 meter than regeneration bore, makes carbon layer be 0.05 ~0.075 meter, to ensure that layer of charcoal is comparatively fast heated.
CN201710075004.XA 2017-02-10 2017-02-10 A kind of horizontal continuous regeneration equipment of powdery waste active carbon Pending CN106732491A (en)

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Cited By (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN107804850A (en) * 2017-12-26 2018-03-16 贵州贵恒环保科技有限公司 A kind of horizontal continuous regeneration equipment of powdery waste active carbon
CN108636390A (en) * 2018-06-20 2018-10-12 浙江省林业科学研究院 A kind of vertical serialization of powdery waste active carbon generating apparatus again
CN109289819A (en) * 2018-09-25 2019-02-01 浙江省林业科学研究院 A kind of the energy conservation and environmental protection regeneration method and technique of powdery waste active carbon
CN109985610A (en) * 2019-03-20 2019-07-09 中国科学院青岛生物能源与过程研究所 A kind of active carbon regenerating unit and method based on from maintenance burning
CN115814778A (en) * 2023-02-14 2023-03-21 天津市科碳环保工程有限公司 Activated carbon waste powder regeneration system and activation method
CN116078365A (en) * 2022-12-29 2023-05-09 四川金岸环保科技有限公司 Hazardous waste carbon regenerating furnace and using method thereof

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101357327A (en) * 2007-07-30 2009-02-04 项缙农 Regeneration method and device of waste powdered activated carbon rotary fluidization
CN104289211A (en) * 2013-06-17 2015-01-21 沈善明 Horizontal-stirring waste powdered activated carbon regeneration furnace
CN105148886A (en) * 2015-09-30 2015-12-16 徐州天正活性炭厂 Automatic production line for powdered activated carbon regeneration
CN205084748U (en) * 2015-11-12 2016-03-16 山西新华化工有限责任公司 Activated carbon regeneration activation furnace

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101357327A (en) * 2007-07-30 2009-02-04 项缙农 Regeneration method and device of waste powdered activated carbon rotary fluidization
CN104289211A (en) * 2013-06-17 2015-01-21 沈善明 Horizontal-stirring waste powdered activated carbon regeneration furnace
CN105148886A (en) * 2015-09-30 2015-12-16 徐州天正活性炭厂 Automatic production line for powdered activated carbon regeneration
CN205084748U (en) * 2015-11-12 2016-03-16 山西新华化工有限责任公司 Activated carbon regeneration activation furnace

Cited By (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN107804850A (en) * 2017-12-26 2018-03-16 贵州贵恒环保科技有限公司 A kind of horizontal continuous regeneration equipment of powdery waste active carbon
CN108636390A (en) * 2018-06-20 2018-10-12 浙江省林业科学研究院 A kind of vertical serialization of powdery waste active carbon generating apparatus again
CN109289819A (en) * 2018-09-25 2019-02-01 浙江省林业科学研究院 A kind of the energy conservation and environmental protection regeneration method and technique of powdery waste active carbon
CN109985610A (en) * 2019-03-20 2019-07-09 中国科学院青岛生物能源与过程研究所 A kind of active carbon regenerating unit and method based on from maintenance burning
CN116078365A (en) * 2022-12-29 2023-05-09 四川金岸环保科技有限公司 Hazardous waste carbon regenerating furnace and using method thereof
CN115814778A (en) * 2023-02-14 2023-03-21 天津市科碳环保工程有限公司 Activated carbon waste powder regeneration system and activation method
CN115814778B (en) * 2023-02-14 2023-04-14 天津市科碳环保工程有限公司 Activated carbon waste powder regeneration system and activation method

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Application publication date: 20170531