CN106724598A - A kind of cup containing filtrate - Google Patents
A kind of cup containing filtrate Download PDFInfo
- Publication number
- CN106724598A CN106724598A CN201710111434.2A CN201710111434A CN106724598A CN 106724598 A CN106724598 A CN 106724598A CN 201710111434 A CN201710111434 A CN 201710111434A CN 106724598 A CN106724598 A CN 106724598A
- Authority
- CN
- China
- Prior art keywords
- solution
- oil bath
- filter
- mtmos
- molecular sieves
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 239000000706 filtrate Substances 0.000 title claims abstract description 35
- 239000002808 molecular sieve Substances 0.000 claims abstract description 70
- URGAHOPLAPQHLN-UHFFFAOYSA-N sodium aluminosilicate Chemical compound [Na+].[Al+3].[O-][Si]([O-])=O.[O-][Si]([O-])=O URGAHOPLAPQHLN-UHFFFAOYSA-N 0.000 claims abstract description 70
- 238000000746 purification Methods 0.000 claims abstract description 9
- 239000000243 solution Substances 0.000 claims description 134
- FJLUATLTXUNBOT-UHFFFAOYSA-N 1-Hexadecylamine Chemical compound CCCCCCCCCCCCCCCCN FJLUATLTXUNBOT-UHFFFAOYSA-N 0.000 claims description 114
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 114
- KFZMGEQAYNKOFK-UHFFFAOYSA-N Isopropanol Chemical compound CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 claims description 78
- 238000013019 agitation Methods 0.000 claims description 56
- 238000002604 ultrasonography Methods 0.000 claims description 54
- BOTDANWDWHJENH-UHFFFAOYSA-N Tetraethyl orthosilicate Chemical compound CCO[Si](OCC)(OCC)OCC BOTDANWDWHJENH-UHFFFAOYSA-N 0.000 claims description 48
- GPNDARIEYHPYAY-UHFFFAOYSA-N palladium(ii) nitrate Chemical compound [Pd+2].[O-][N+]([O-])=O.[O-][N+]([O-])=O GPNDARIEYHPYAY-UHFFFAOYSA-N 0.000 claims description 39
- 230000015572 biosynthetic process Effects 0.000 claims description 38
- 238000003786 synthesis reaction Methods 0.000 claims description 38
- 239000011259 mixed solution Substances 0.000 claims description 37
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 claims description 33
- 239000001301 oxygen Substances 0.000 claims description 33
- 229910052760 oxygen Inorganic materials 0.000 claims description 33
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 33
- 239000012535 impurity Substances 0.000 claims description 23
- 230000010355 oscillation Effects 0.000 claims description 20
- 238000005119 centrifugation Methods 0.000 claims description 19
- 238000010285 flame spraying Methods 0.000 claims description 19
- 238000010438 heat treatment Methods 0.000 claims description 19
- 238000002347 injection Methods 0.000 claims description 19
- 239000007924 injection Substances 0.000 claims description 19
- 150000002500 ions Chemical group 0.000 claims description 19
- 230000000694 effects Effects 0.000 claims description 10
- 239000008367 deionised water Substances 0.000 claims description 8
- 229910021641 deionized water Inorganic materials 0.000 claims description 8
- 238000002360 preparation method Methods 0.000 claims description 2
- 238000000034 method Methods 0.000 abstract description 7
- KDLHZDBZIXYQEI-UHFFFAOYSA-N palladium Substances [Pd] KDLHZDBZIXYQEI-UHFFFAOYSA-N 0.000 description 35
- 229910052763 palladium Inorganic materials 0.000 description 34
- -1 palladium nitrates Chemical class 0.000 description 34
- 239000003643 water by type Substances 0.000 description 28
- 239000000203 mixture Substances 0.000 description 18
- 238000012360 testing method Methods 0.000 description 5
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 4
- 238000001179 sorption measurement Methods 0.000 description 4
- 238000004140 cleaning Methods 0.000 description 3
- 238000001914 filtration Methods 0.000 description 3
- 239000008213 purified water Substances 0.000 description 3
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 2
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 description 2
- 229910052785 arsenic Inorganic materials 0.000 description 2
- RQNWIZPPADIBDY-UHFFFAOYSA-N arsenic atom Chemical compound [As] RQNWIZPPADIBDY-UHFFFAOYSA-N 0.000 description 2
- 238000003556 assay Methods 0.000 description 2
- 230000009514 concussion Effects 0.000 description 2
- 229910052802 copper Inorganic materials 0.000 description 2
- 239000010949 copper Substances 0.000 description 2
- 229910001385 heavy metal Inorganic materials 0.000 description 2
- 238000007689 inspection Methods 0.000 description 2
- 229910052742 iron Inorganic materials 0.000 description 2
- 239000011133 lead Substances 0.000 description 2
- WPBNNNQJVZRUHP-UHFFFAOYSA-L manganese(2+);methyl n-[[2-(methoxycarbonylcarbamothioylamino)phenyl]carbamothioyl]carbamate;n-[2-(sulfidocarbothioylamino)ethyl]carbamodithioate Chemical compound [Mn+2].[S-]C(=S)NCCNC([S-])=S.COC(=O)NC(=S)NC1=CC=CC=C1NC(=S)NC(=O)OC WPBNNNQJVZRUHP-UHFFFAOYSA-L 0.000 description 2
- 239000000463 material Substances 0.000 description 2
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 2
- 230000002906 microbiologic effect Effects 0.000 description 2
- 230000005180 public health Effects 0.000 description 2
- 238000007873 sieving Methods 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- 229910052725 zinc Inorganic materials 0.000 description 2
- 239000011701 zinc Substances 0.000 description 2
- 241000894006 Bacteria Species 0.000 description 1
- 238000010521 absorption reaction Methods 0.000 description 1
- 230000002378 acidificating effect Effects 0.000 description 1
- 230000000052 comparative effect Effects 0.000 description 1
- 238000002242 deionisation method Methods 0.000 description 1
- 238000010586 diagram Methods 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 150000002148 esters Chemical class 0.000 description 1
- 230000005415 magnetization Effects 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- ARYZCSRUUPFYMY-UHFFFAOYSA-N methoxysilane Chemical compound CO[SiH3] ARYZCSRUUPFYMY-UHFFFAOYSA-N 0.000 description 1
- 230000001151 other effect Effects 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- RMAQACBXLXPBSY-UHFFFAOYSA-N silicic acid Chemical compound O[Si](O)(O)O RMAQACBXLXPBSY-UHFFFAOYSA-N 0.000 description 1
- 235000012239 silicon dioxide Nutrition 0.000 description 1
- 238000003756 stirring Methods 0.000 description 1
- YUYCVXFAYWRXLS-UHFFFAOYSA-N trimethoxysilane Chemical compound CO[SiH](OC)OC YUYCVXFAYWRXLS-UHFFFAOYSA-N 0.000 description 1
- 238000003911 water pollution Methods 0.000 description 1
Classifications
-
- A—HUMAN NECESSITIES
- A47—FURNITURE; DOMESTIC ARTICLES OR APPLIANCES; COFFEE MILLS; SPICE MILLS; SUCTION CLEANERS IN GENERAL
- A47G—HOUSEHOLD OR TABLE EQUIPMENT
- A47G19/00—Table service
- A47G19/22—Drinking vessels or saucers used for table service
- A47G19/2205—Drinking glasses or vessels
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D24/00—Filters comprising loose filtering material, i.e. filtering material without any binder between the individual particles or fibres thereof
- B01D24/02—Filters comprising loose filtering material, i.e. filtering material without any binder between the individual particles or fibres thereof with the filter bed stationary during the filtration
- B01D24/10—Filters comprising loose filtering material, i.e. filtering material without any binder between the individual particles or fibres thereof with the filter bed stationary during the filtration the filtering material being held in a closed container
- B01D24/12—Downward filtration, the filtering material being supported by pervious surfaces
Landscapes
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Catalysts (AREA)
- Powder Metallurgy (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Abstract
The present invention provides a kind of cup containing filtrate, including cup body, described cup body interior has filter, filter includes filter box, filter lid and filtrate, described filtrate is arranged in filter box, described filter lid outside has external screw thread, filter box inner side has internal thread, filter box is connected with filter lid screw thread, filter box is installed inside cup of the invention, filter box being capable of dismounting and change, convenient use, and filter box is connected with filter lid screw thread, the filtrate that directly can more renew, and filtrate is new Pd HMS molecular sieve filtrates prepared by special process, its good purification.
Description
Technical field
The present invention relates to a kind of cup containing filtrate, belong to daily life field.
Background technology
Cup is the instrument that people commonly use in daily life, but general cup does not have filter effect, existing teacup
It is mostly to fill a filter screen in rim of a cup, this strainer filtering effect is almost ignored, is only capable of filtering some large-scale impurity, nothing
Bacterium or harmful element in method filter water, current water pollution are serious, it is necessary to a kind of cup of good purification.
The content of the invention
For the problem that above-mentioned prior art is present, the present invention provides a kind of cup containing filtrate, and purified water effect is good.
To achieve these goals, the technical solution adopted by the present invention is：A kind of cup containing filtrate, including cup sheet
Body, described cup body interior has filter.
Described filter includes filter box, filter lid and filtrate, and described filtrate is arranged in filter box, described filter
Lid outside has external screw thread, and filter box inner side has internal thread, and filter box is connected with filter lid screw thread.
Described, cup body interior has the diameter of the diameter less than filter box of annular protrusion so that filter box can be stuck in
On annular protrusion, prevent filter box from falling into bottom.
Described filtrate is new Pd-HMS molecular sieves filtrate, for water purification effect.
Filter box is installed, filter box being capable of dismounting and change, convenient use, and filter box and filter lid inside cup of the invention
Screw thread is connected, the filtrate that directly can more renew, and filtrate is new Pd-HMS molecules sieving prepared by special process
Material, its good purification.
Brief description of the drawings
Fig. 1 is schematic diagram of the invention.
1st, cup body, 2, cup lid, 3, filter box, 4, filter lid.
Specific embodiment
The invention will be further described with reference to the accompanying drawings and examples.
As shown in figure 1, a kind of cup containing filtrate, including cup body 1, described cup body interior is with filtering
Device.The top of cup body 1 also has cup lid 2, and cup lid is threadedly coupled with cup body,
Described filter includes filter, 3, filter lid 4 and filtrate, described filtrate is arranged in filter box, described
Filter lid outside has external screw thread, and filter box inner side has internal thread, and filter box is connected with filter lid screw thread.
Described, cup body interior has the diameter of the diameter less than filter box of annular protrusion so that filter box can be stuck in
On annular protrusion, prevent filter box from falling into bottom.
Described filtrate is new Pd-HMS molecular sieves filtrate, for water purification effect.
Filter box is installed, filter box being capable of dismounting and change, convenient use, and filter box and filter lid inside cup of the invention
Screw thread is connected, the filtrate that directly can more renew, and filtrate is new Pd-HMS molecules sieving prepared by special process
Material, its good purification.
In order to further verify filter effect, new Pd-HMS molecular sieves filtrate uses hexadecylamine (HDA), methyl
The raw materials such as trimethoxy silane (MTMOS), palladium nitrate, isopropanol, tetraethyl orthosilicate (TEOS) ethanol are by magnetization, ultrasonic wave shake
The modified method such as swing to prepare, specific preparation method is as follows：
Embodiment 1
Produce palladium nitrate, MTMS (MTMOS) mass ratio 1:1 sample.0.5g palladium nitrates, 0.5g methyl three
Methoxy silane (MTMOS), 10ml ethanol, 5ml tetraethyl orthosilicates, 8g hexadecylamines (HDA), 6g isopropanols, 200ml deionizations
Water.
Step 1, by 8g hexadecylamines (HDA) and 10ml ethanol, 100 DEG C of oil bath ultrasound 3h are removed under ultrasonic oscillation first
It is miscellaneous；
Step 2,8g hexadecylamines (HDA) are added into the solution being made up of 200ml deionized waters and 10ml ethanol in formed
Solution A, 100 DEG C of oil bath ultrasound 3h of magnetic agitation；
Step 3, by MTMS (MTMOS), palladium nitrate, isopropanol, tetraethyl orthosilicate (TEOS) is in ultrasound
Ripple shakes 100 DEG C of 2h removal of impurities of oil bath；
Step 4, by 0.5g MTMSs (MTMOS), 0.5g palladium nitrates are added to by 6g isopropanols and 5ml
Solution B, 100 DEG C of oil bath 2h of magnetic agitation are formed in the mixed solution of tetraethyl orthosilicate (TEOS) composition；
Step 5, solution A is mixed with solution B, 100 DEG C of oil bath 4h of magnetic agitation；
Step 6, above-mentioned mixed solution microwave treatment 2h is modified；
Step 7, using flame spraying one-step synthesis Pd-HMS molecular sieves, will above-mentioned solution be added to flame injection dress
In the needle tubing put, be subsequently adding the CH4 of high heating value, and be passed through oxygen, while igniting by obtained solution from pin hole with ion
Form eject at 3000 DEG C rapid synthesis Pd-HMS molecular sieves；
Step 8 and then the centrifugation under centrifugal separator, dry, and are finally forged under sufficient air atmosphere in Muffle furnace
6h is burnt, Pd-HMS molecular sieves are obtained.
Embodiment 2 produces palladium nitrate, MTMS (MTMOS) mass ratio 1:2 sample.0.5g palladium nitrates, 1g
MTMS (MTMOS), 10ml ethanol, 5ml tetraethyl orthosilicates, 8g hexadecylamines (HDA), 6g isopropanols, 200ml
Deionized water.
Step 1, by 8g hexadecylamines (HDA) and 10ml ethanol, 100 DEG C of oil bath ultrasound 3h are removed under ultrasonic oscillation first
It is miscellaneous；
Step 2,8g hexadecylamines (HDA) are added into the solution being made up of 200ml deionized waters and 10ml ethanol in formed
Solution A, 100 DEG C of oil bath ultrasound 3h of magnetic agitation；
Step 3, by MTMS (MTMOS), palladium nitrate, isopropanol, tetraethyl orthosilicate (TEOS) is in ultrasound
Ripple shakes 100 DEG C of 2h removal of impurities of oil bath；
Step 4, by 1g MTMSs (MTMOS), 0.5g palladium nitrates are added to by 6g isopropanols and 5ml just
Solution B, 100 DEG C of oil bath 2h of magnetic agitation are formed in the mixed solution of silester (TEOS) composition；
Step 5, solution A is mixed with solution B, 100 DEG C of oil bath 4h of magnetic agitation；
Step 6, above-mentioned mixed solution microwave treatment 2h is modified；
Step 7, using flame spraying one-step synthesis Pd-HMS molecular sieves, will above-mentioned solution be added to flame injection dress
In the needle tubing put, be subsequently adding the CH4 of high heating value, and be passed through oxygen, while igniting by obtained solution from pin hole with ion
Form eject at 3000 DEG C rapid synthesis Pd-HMS molecular sieves；
Step 8 and then the centrifugation under centrifugal separator, dry, and are finally forged under sufficient air atmosphere in Muffle furnace
6h is burnt, Pd-HMS molecular sieves are obtained.
Embodiment 3 produces palladium nitrate, MTMS (MTMOS) mass ratio 1:3 sample.0.5g palladium nitrates,
1.5g MTMSs (MTMOS), 10ml ethanol, 5ml tetraethyl orthosilicates, 8g hexadecylamines (HDA), 6g isopropanols,
200ml deionized waters.
Step 1, by 8g hexadecylamines (HDA) and 10ml ethanol, 100 DEG C of oil bath ultrasound 3h are removed under ultrasonic oscillation first
It is miscellaneous；
Step 2,8g hexadecylamines (HDA) are added into the solution being made up of 200ml deionized waters and 10ml ethanol in formed
Solution A, 100 DEG C of oil bath ultrasound 3h of magnetic agitation；
Step 3, by MTMS (MTMOS), palladium nitrate, isopropanol, tetraethyl orthosilicate (TEOS) is in ultrasound
Ripple shakes 100 DEG C of 2h removal of impurities of oil bath；
Step 4, by 1.5g MTMSs (MTMOS), 0.5g palladium nitrates are added to by 6g isopropanols and 5ml
Solution B, 100 DEG C of oil bath 2h of magnetic agitation are formed in the mixed solution of tetraethyl orthosilicate (TEOS) composition；
Step 5, solution A is mixed with solution B, 100 DEG C of oil bath 4h of magnetic agitation；
Step 6, above-mentioned mixed solution microwave treatment 2h is modified；
Step 7, using flame spraying one-step synthesis Pd-HMS molecular sieves, will above-mentioned solution be added to flame injection dress
In the needle tubing put, be subsequently adding the CH4 of high heating value, and be passed through oxygen, while igniting by obtained solution from pin hole with ion
Form eject at 3000 DEG C rapid synthesis Pd-HMS molecular sieves；
Step 8 and then the centrifugation under centrifugal separator, dry, and are finally forged under sufficient air atmosphere in Muffle furnace
6h is burnt, Pd-HMS molecular sieves are obtained.
Embodiment 4 produces palladium nitrate, MTMS (MTMOS) mass ratio 1:4 sample.0.5g palladium nitrates, 2g
MTMS (MTMOS), 10ml ethanol, 5ml tetraethyl orthosilicates, 8g hexadecylamines (HDA), 6g isopropanols, 200ml
Deionized water.
Step 1, by 8g hexadecylamines (HDA) and 10ml ethanol, 100 DEG C of oil bath ultrasound 3h are removed under ultrasonic oscillation first
It is miscellaneous；
Step 2,8g hexadecylamines (HDA) are added into the solution being made up of 200ml deionized waters and 10ml ethanol in formed
Solution A, 100 DEG C of oil bath ultrasound 3h of magnetic agitation；
Step 3, by MTMS (MTMOS), palladium nitrate, isopropanol, tetraethyl orthosilicate (TEOS) is in ultrasound
Ripple shakes 100 DEG C of 2h removal of impurities of oil bath；
Step 4, by 2g MTMSs (MTMOS), 0.5g palladium nitrates are added to by 6g isopropanols and 5ml just
Solution B, 100 DEG C of oil bath 2h of magnetic agitation are formed in the mixed solution of silester (TEOS) composition；
Step 5, solution A is mixed with solution B, 100 DEG C of oil bath 4h of magnetic agitation；
Step 6, above-mentioned mixed solution microwave treatment 2h is modified；
Step 7, using flame spraying one-step synthesis Pd-HMS molecular sieves, will above-mentioned solution be added to flame injection dress
In the needle tubing put, be subsequently adding the CH4 of high heating value, and be passed through oxygen, while igniting by obtained solution from pin hole with ion
Form eject at 3000 DEG C rapid synthesis Pd-HMS molecular sieves；
Step 8 and then the centrifugation under centrifugal separator, dry, and are finally forged under sufficient air atmosphere in Muffle furnace
6h is burnt, Pd-HMS molecular sieves are obtained.
Embodiment 5 produces palladium nitrate, MTMS (MTMOS) mass ratio 1:5 sample.0.5g palladium nitrates,
2.5g MTMSs (MTMOS), 10ml ethanol, 5ml tetraethyl orthosilicates, 8g hexadecylamines (HDA), 6g isopropanols,
200ml deionized waters.
Step 1, by 8g hexadecylamines (HDA) and 10ml ethanol, 100 DEG C of oil bath ultrasound 3h are removed under ultrasonic oscillation first
It is miscellaneous；
Step 2,8g hexadecylamines (HDA) are added into the solution being made up of 200ml deionized waters and 10ml ethanol in formed
Solution A, 100 DEG C of oil bath ultrasound 3h of magnetic agitation；
Step 3, by MTMS (MTMOS), palladium nitrate, isopropanol, tetraethyl orthosilicate (TEOS) is in ultrasound
Ripple shakes 100 DEG C of 2h removal of impurities of oil bath；
Step 4, by 2.5g MTMSs (MTMOS), 0.5g palladium nitrates are added to by 6g isopropanols and 5ml
Solution B, 100 DEG C of oil bath 2h of magnetic agitation are formed in the mixed solution of tetraethyl orthosilicate (TEOS) composition；
Step 5, solution A is mixed with solution B, 100 DEG C of oil bath 4h of magnetic agitation；
Step 6, above-mentioned mixed solution microwave treatment 2h is modified；
Step 7, using flame spraying one-step synthesis Pd-HMS molecular sieves, will above-mentioned solution be added to flame injection dress
In the needle tubing put, be subsequently adding the CH4 of high heating value, and be passed through oxygen, while igniting by obtained solution from pin hole with ion
Form eject at 3000 DEG C rapid synthesis Pd-HMS molecular sieves；
Step 8 and then the centrifugation under centrifugal separator, dry, and are finally forged under sufficient air atmosphere in Muffle furnace
6h is burnt, Pd-HMS molecular sieves are obtained.
Embodiment 6 produces palladium nitrate, MTMS (MTMOS) mass ratio 1:6 sample.0.5g palladium nitrates, 3g
MTMS (MTMOS), 10ml ethanol, 5ml tetraethyl orthosilicates, 8g hexadecylamines (HDA), 6g isopropanols, 200ml
Deionized water.
Step 1, by 8g hexadecylamines (HDA) and 10ml ethanol, 100 DEG C of oil bath ultrasound 3h are removed under ultrasonic oscillation first
It is miscellaneous；
Step 2,8g hexadecylamines (HDA) are added into the solution being made up of 200ml deionized waters and 10ml ethanol in formed
Solution A, 100 DEG C of oil bath ultrasound 3h of magnetic agitation；
Step 3, by MTMS (MTMOS), palladium nitrate, isopropanol, tetraethyl orthosilicate (TEOS) is in ultrasound
Ripple shakes 100 DEG C of 2h removal of impurities of oil bath；
Step 4, by 3g MTMSs (MTMOS), 0.5g palladium nitrates are added to by 6g isopropanols and 5ml just
Solution B, 100 DEG C of oil bath 2h of magnetic agitation are formed in the mixed solution of silester (TEOS) composition；
Step 5, solution A is mixed with solution B, 100 DEG C of oil bath 4h of magnetic agitation；
Step 6, above-mentioned mixed solution microwave treatment 2h is modified；
Step 7, using flame spraying one-step synthesis Pd-HMS molecular sieves, will above-mentioned solution be added to flame injection dress
In the needle tubing put, be subsequently adding the CH4 of high heating value, and be passed through oxygen, while igniting by obtained solution from pin hole with ion
Form eject at 3000 DEG C rapid synthesis Pd-HMS molecular sieves；
Step 8 and then the centrifugation under centrifugal separator, dry, and are finally forged under sufficient air atmosphere in Muffle furnace
6h is burnt, Pd-HMS molecular sieves are obtained.
Embodiment 7 produces palladium nitrate, MTMS (MTMOS) mass ratio 1:7 sample.0.5g palladium nitrates,
3.5g MTMSs (MTMOS), 10ml ethanol, 5ml tetraethyl orthosilicates, 8g hexadecylamines (HDA), 6g isopropanols,
200ml deionized waters.
Step 1, by 8g hexadecylamines (HDA) and 10ml ethanol, 100 DEG C of oil bath ultrasound 3h are removed under ultrasonic oscillation first
It is miscellaneous；
Step 2,8g hexadecylamines (HDA) are added into the solution being made up of 200ml deionized waters and 10ml ethanol in formed
Solution A, 100 DEG C of oil bath ultrasound 3h of magnetic agitation；
Step 3, by MTMS (MTMOS), palladium nitrate, isopropanol, tetraethyl orthosilicate (TEOS) is in ultrasound
Ripple shakes 100 DEG C of 2h removal of impurities of oil bath；
Step 4, by 3.5g MTMSs (MTMOS), 0.5g palladium nitrates are added to by 6g isopropanols and 5ml
Solution B, 100 DEG C of oil bath 2h of magnetic agitation are formed in the mixed solution of tetraethyl orthosilicate (TEOS) composition；
Step 5, solution A is mixed with solution B, 100 DEG C of oil bath 4h of magnetic agitation；
Step 6, above-mentioned mixed solution microwave treatment 2h is modified；
Step 7, using flame spraying one-step synthesis Pd-HMS molecular sieves, will above-mentioned solution be added to flame injection dress
In the needle tubing put, be subsequently adding the CH4 of high heating value, and be passed through oxygen, while igniting by obtained solution from pin hole with ion
Form eject at 3000 DEG C rapid synthesis Pd-HMS molecular sieves；
Step 8 and then the centrifugation under centrifugal separator, dry, and are finally forged under sufficient air atmosphere in Muffle furnace
6h is burnt, Pd-HMS molecular sieves are obtained.
Embodiment 8 produces palladium nitrate, MTMS (MTMOS) mass ratio 1:8 sample.0.5g palladium nitrates, 4g
MTMS (MTMOS), 10ml ethanol, 5ml tetraethyl orthosilicates, 8g hexadecylamines (HDA), 6g isopropanols, 200ml
Deionized water.
Step 1, by 8g hexadecylamines (HDA) and 10ml ethanol, 100 DEG C of oil bath ultrasound 3h are removed under ultrasonic oscillation first
It is miscellaneous；
Step 2,8g hexadecylamines (HDA) are added into the solution being made up of 200ml deionized waters and 10ml ethanol in formed
Solution A, 100 DEG C of oil bath ultrasound 3h of magnetic agitation；
Step 3, by MTMS (MTMOS), palladium nitrate, isopropanol, tetraethyl orthosilicate (TEOS) is in ultrasound
Ripple shakes 100 DEG C of 2h removal of impurities of oil bath；
Step 4, by 4g MTMSs (MTMOS), 0.5g palladium nitrates are added to by 6g isopropanols and 5ml just
Solution B, 100 DEG C of oil bath 2h of magnetic agitation are formed in the mixed solution of silester (TEOS) composition；
Step 5, solution A is mixed with solution B, 100 DEG C of oil bath 4h of magnetic agitation；
Step 6, above-mentioned mixed solution microwave treatment 2h is modified；
Step 7, using flame spraying one-step synthesis Pd-HMS molecular sieves, will above-mentioned solution be added to flame injection dress
In the needle tubing put, be subsequently adding the CH4 of high heating value, and be passed through oxygen, while igniting by obtained solution from pin hole with ion
Form eject at 3000 DEG C rapid synthesis Pd-HMS molecular sieves；
Step 8 and then the centrifugation under centrifugal separator, dry, and are finally forged under sufficient air atmosphere in Muffle furnace
6h is burnt, Pd-HMS molecular sieves are obtained.
Embodiment 9 produces palladium nitrate, MTMS (MTMOS) mass ratio 1:9 sample.0.5g palladium nitrates,
4.5g MTMSs (MTMOS), 10ml ethanol, 5ml tetraethyl orthosilicates, 8g hexadecylamines (HDA), 6g isopropanols,
200ml deionized waters.
Step 1, by 8g hexadecylamines (HDA) and 10ml ethanol, 100 DEG C of oil bath ultrasound 3h are removed under ultrasonic oscillation first
It is miscellaneous；
Step 2,8g hexadecylamines (HDA) are added into the solution being made up of 200ml deionized waters and 10ml ethanol in formed
Solution A, 100 DEG C of oil bath ultrasound 3h of magnetic agitation；
Step 3, by MTMS (MTMOS), palladium nitrate, isopropanol, tetraethyl orthosilicate (TEOS) is in ultrasound
Ripple shakes 100 DEG C of 2h removal of impurities of oil bath；
Step 4, by 4.5g MTMSs (MTMOS), 0.5g palladium nitrates are added to by 6g isopropanols and 5ml
Solution B, 100 DEG C of oil bath 2h of magnetic agitation are formed in the mixed solution of tetraethyl orthosilicate (TEOS) composition；
Step 5, solution A is mixed with solution B, 100 DEG C of oil bath 4h of magnetic agitation；
Step 6, above-mentioned mixed solution microwave treatment 2h is modified；
Step 7, using flame spraying one-step synthesis Pd-HMS molecular sieves, will above-mentioned solution be added to flame injection dress
In the needle tubing put, be subsequently adding the CH4 of high heating value, and be passed through oxygen, while igniting by obtained solution from pin hole with ion
Form eject at 3000 DEG C rapid synthesis Pd-HMS molecular sieves；
Step 8 and then the centrifugation under centrifugal separator, dry, and are finally forged under sufficient air atmosphere in Muffle furnace
6h is burnt, Pd-HMS molecular sieves are obtained.
Embodiment 10 produces palladium nitrate, MTMS (MTMOS) mass ratio 1:10 sample.0.5g palladium nitrates,
5g MTMSs (MTMOS), 10ml ethanol, 5ml tetraethyl orthosilicates, 8g hexadecylamines (HDA), 6g isopropanols,
200ml deionized waters.
Step 1, by 8g hexadecylamines (HDA) and 10ml ethanol, 100 DEG C of oil bath ultrasound 3h are removed under ultrasonic oscillation first
It is miscellaneous；
Step 2,8g hexadecylamines (HDA) are added into the solution being made up of 200ml deionized waters and 10ml ethanol in formed
Solution A, 100 DEG C of oil bath ultrasound 3h of magnetic agitation；
Step 3, by MTMS (MTMOS), palladium nitrate, isopropanol, tetraethyl orthosilicate (TEOS) is in ultrasound
Ripple shakes 100 DEG C of 2h removal of impurities of oil bath；
Step 4, by 5g MTMSs (MTMOS), 0.5g palladium nitrates are added to by 6g isopropanols and 5ml just
Solution B, 100 DEG C of oil bath 2h of magnetic agitation are formed in the mixed solution of silester (TEOS) composition；
Step 5, solution A is mixed with solution B, 100 DEG C of oil bath 4h of magnetic agitation；
Step 6, above-mentioned mixed solution microwave treatment 2h is modified；
Step 7, using flame spraying one-step synthesis Pd-HMS molecular sieves, will above-mentioned solution be added to flame injection dress
In the needle tubing put, be subsequently adding the CH4 of high heating value, and be passed through oxygen, while igniting by obtained solution from pin hole with ion
Form eject at 3000 DEG C rapid synthesis Pd-HMS molecular sieves；
Step 8 and then the centrifugation under centrifugal separator, dry, and are finally forged under sufficient air atmosphere in Muffle furnace
6h is burnt, Pd-HMS molecular sieves are obtained.
Embodiment 11 produces palladium nitrate, MTMS (MTMOS) mass ratio 1:11 sample.0.5g palladium nitrates,
5.5g MTMSs (MTMOS), 10ml ethanol, 5ml tetraethyl orthosilicates, 8g hexadecylamines (HDA), 6g isopropanols,
200ml deionized waters.
Step 1, by 8g hexadecylamines (HDA) and 10ml ethanol, 100 DEG C of oil bath ultrasound 3h are removed under ultrasonic oscillation first
It is miscellaneous；
Step 2,8g hexadecylamines (HDA) are added into the solution being made up of 200ml deionized waters and 10ml ethanol in formed
Solution A, 100 DEG C of oil bath ultrasound 3h of magnetic agitation；
Step 3, by MTMS (MTMOS), palladium nitrate, isopropanol, tetraethyl orthosilicate (TEOS) is in ultrasound
Ripple shakes 100 DEG C of 2h removal of impurities of oil bath；
Step 4, by 5.5g MTMSs (MTMOS), 0.5g palladium nitrates are added to by 6g isopropanols and 5ml
Solution B, 100 DEG C of oil bath 2h of magnetic agitation are formed in the mixed solution of tetraethyl orthosilicate (TEOS) composition；
Step 5, solution A is mixed with solution B, 100 DEG C of oil bath 4h of magnetic agitation；
Step 6, above-mentioned mixed solution microwave treatment 2h is modified；
Step 7, using flame spraying one-step synthesis Pd-HMS molecular sieves, will above-mentioned solution be added to flame injection dress
In the needle tubing put, be subsequently adding the CH4 of high heating value, and be passed through oxygen, while igniting by obtained solution from pin hole with ion
Form eject at 3000 DEG C rapid synthesis Pd-HMS molecular sieves；
Step 8 and then the centrifugation under centrifugal separator, dry, and are finally forged under sufficient air atmosphere in Muffle furnace
6h is burnt, Pd-HMS molecular sieves are obtained.
Embodiment 12 produces palladium nitrate, MTMS (MTMOS) mass ratio 1:12 sample.0.5g palladium nitrates,
6g MTMSs (MTMOS), 10ml ethanol, 5ml tetraethyl orthosilicates, 8g hexadecylamines (HDA), 6g isopropanols,
200ml deionized waters.
Step 1, by 8g hexadecylamines (HDA) and 10ml ethanol, 100 DEG C of oil bath ultrasound 3h are removed under ultrasonic oscillation first
It is miscellaneous；
Step 2,8g hexadecylamines (HDA) are added into the solution being made up of 200ml deionized waters and 10ml ethanol in formed
Solution A, 100 DEG C of oil bath ultrasound 3h of magnetic agitation；
Step 3, by MTMS (MTMOS), palladium nitrate, isopropanol, tetraethyl orthosilicate (TEOS) is in ultrasound
Ripple shakes 100 DEG C of 2h removal of impurities of oil bath；
Step 4, by 6g MTMSs (MTMOS), 0.5g palladium nitrates are added to by 6g isopropanols and 5ml just
Solution B, 100 DEG C of oil bath 2h of magnetic agitation are formed in the mixed solution of silester (TEOS) composition；
Step 5, solution A is mixed with solution B, 100 DEG C of oil bath 4h of magnetic agitation；
Step 6, above-mentioned mixed solution microwave treatment 2h is modified；
Step 7, using flame spraying one-step synthesis Pd-HMS molecular sieves, will above-mentioned solution be added to flame injection dress
In the needle tubing put, be subsequently adding the CH4 of high heating value, and be passed through oxygen, while igniting by obtained solution from pin hole with ion
Form eject at 3000 DEG C rapid synthesis Pd-HMS molecular sieves；
Step 8 and then the centrifugation under centrifugal separator, dry, and are finally forged under sufficient air atmosphere in Muffle furnace
6h is burnt, Pd-HMS molecular sieves are obtained.
Embodiment 13 produces palladium nitrate, MTMS (MTMOS) mass ratio 1:13 sample.0.5g palladium nitrates,
6.5g MTMSs (MTMOS), 10ml ethanol, 5ml tetraethyl orthosilicates, 8g hexadecylamines (HDA), 6g isopropanols,
200ml deionized waters.
Step 1, by 8g hexadecylamines (HDA) and 10ml ethanol, 100 DEG C of oil bath ultrasound 3h are removed under ultrasonic oscillation first
It is miscellaneous；
Step 2,8g hexadecylamines (HDA) are added into the solution being made up of 200ml deionized waters and 10ml ethanol in formed
Solution A, 100 DEG C of oil bath ultrasound 3h of magnetic agitation；
Step 3, by MTMS (MTMOS), palladium nitrate, isopropanol, tetraethyl orthosilicate (TEOS) is in ultrasound
Ripple shakes 100 DEG C of 2h removal of impurities of oil bath；
Step 4, by 6.5g MTMSs (MTMOS), 0.5g palladium nitrates are added to by 6g isopropanols and 5ml
Solution B, 100 DEG C of oil bath 2h of magnetic agitation are formed in the mixed solution of tetraethyl orthosilicate (TEOS) composition；
Step 5, solution A is mixed with solution B, 100 DEG C of oil bath 4h of magnetic agitation；
Step 6, above-mentioned mixed solution microwave treatment 2h is modified；
Step 7, using flame spraying one-step synthesis Pd-HMS molecular sieves, will above-mentioned solution be added to flame injection dress
In the needle tubing put, be subsequently adding the CH4 of high heating value, and be passed through oxygen, while igniting by obtained solution from pin hole with ion
Form eject at 3000 DEG C rapid synthesis Pd-HMS molecular sieves；
Step 8 and then the centrifugation under centrifugal separator, dry, and are finally forged under sufficient air atmosphere in Muffle furnace
6h is burnt, Pd-HMS molecular sieves are obtained.
Embodiment 14 produces palladium nitrate, MTMS (MTMOS) mass ratio 1:14 sample.0.5g palladium nitrates,
7g MTMSs (MTMOS), 10ml ethanol, 5ml tetraethyl orthosilicates, 8g hexadecylamines (HDA), 6g isopropanols,
200ml deionized waters.
Step 1, by 8g hexadecylamines (HDA) and 10ml ethanol, 100 DEG C of oil bath ultrasound 3h are removed under ultrasonic oscillation first
It is miscellaneous；
Step 2,8g hexadecylamines (HDA) are added into the solution being made up of 200ml deionized waters and 10ml ethanol in formed
Solution A, 100 DEG C of oil bath ultrasound 3h of magnetic agitation；
Step 3, by MTMS (MTMOS), palladium nitrate, isopropanol, tetraethyl orthosilicate (TEOS) is in ultrasound
Ripple shakes 100 DEG C of 2h removal of impurities of oil bath；
Step 4, by 7g MTMSs (MTMOS), 0.5g palladium nitrates are added to by 6g isopropanols and 5ml just
Solution B, 100 DEG C of oil bath 2h of magnetic agitation are formed in the mixed solution of silester (TEOS) composition；
Step 5, solution A is mixed with solution B, 100 DEG C of oil bath 4h of magnetic agitation；
Step 6, above-mentioned mixed solution microwave treatment 2h is modified；
Step 7, using flame spraying one-step synthesis Pd-HMS molecular sieves, will above-mentioned solution be added to flame injection dress
In the needle tubing put, be subsequently adding the CH4 of high heating value, and be passed through oxygen, while igniting by obtained solution from pin hole with ion
Form eject at 3000 DEG C rapid synthesis Pd-HMS molecular sieves；
Step 8 and then the centrifugation under centrifugal separator, dry, and are finally forged under sufficient air atmosphere in Muffle furnace
6h is burnt, Pd-HMS molecular sieves are obtained.
Reference examples 1 produce palladium nitrate, MTMS (MTMOS) mass ratio 1:10 sample.0.5g palladium nitrates, 5g
MTMS (MTMOS), 10ml ethanol, 5ml tetraethyl orthosilicates, 8g hexadecylamines (HDA), 6g isopropanols, 200ml
Deionized water.
Step 1,100 DEG C of oil bath ultrasound 3h removal of impurities under common concussion first by 8g hexadecylamines (HDA) and 10ml ethanol；
Step 2,8g hexadecylamines (HDA) are added into the solution being made up of 200ml deionized waters and 10ml ethanol in formed
Solution A, 100 DEG C of oil bath ultrasound 3h of magnetic agitation；
Step 3, by MTMS (MTMOS), palladium nitrate, isopropanol, tetraethyl orthosilicate (TEOS) is common
Concussion 100 DEG C of 2h removal of impurities of oil bath；
Step 4, by 5g MTMSs (MTMOS), 0.5g palladium nitrates are added to by 6g isopropanols and 5ml just
Solution B, 100 DEG C of oil bath 2h of magnetic agitation are formed in the mixed solution of silester (TEOS) composition；
Step 5, solution A is mixed with solution B, 100 DEG C of oil bath 4h of magnetic agitation；
Step 6, above-mentioned mixed solution microwave treatment 2h is modified；
Step 7, using flame spraying one-step synthesis Pd-HMS molecular sieves, will above-mentioned solution be added to flame injection dress
In the needle tubing put, be subsequently adding the CH4 of high heating value, and be passed through oxygen, while igniting by obtained solution from pin hole with ion
Form eject at 3000 DEG C rapid synthesis Pd-HMS molecular sieves；
Step 8 and then the centrifugation under centrifugal separator, dry, and are finally forged under sufficient air atmosphere in Muffle furnace
6h is burnt, Pd-HMS molecular sieves are obtained.
Reference examples 2 produce palladium nitrate, MTMS (MTMOS) mass ratio 1:10 sample.0.5g palladium nitrates, 5g
MTMS (MTMOS), 10ml ethanol, 5ml tetraethyl orthosilicates, 8g hexadecylamines (HDA), 6g isopropanols, 200ml
Deionized water.
Step 1, by 8g hexadecylamines (HDA) and 10ml ethanol, 100 DEG C of oil bath ultrasound 3h are removed under ultrasonic oscillation first
It is miscellaneous；
Step 2,8g hexadecylamines (HDA) are added into the solution being made up of 200ml deionized waters and 10ml ethanol in formed
Solution A, stirs 100 DEG C of oil bath ultrasound 3h；
Step 3, by MTMS (MTMOS), palladium nitrate, isopropanol, tetraethyl orthosilicate (TEOS) is in ultrasound
Ripple shakes 100 DEG C of 2h removal of impurities of oil bath；
Step 4, by 5g MTMSs (MTMOS), 0.5g palladium nitrates are added to by 6g isopropanols and 5ml just
Solution B is formed in the mixed solution of silester (TEOS) composition, 100 DEG C of oil bath 2h are stirred；
Step 5, solution A is mixed with solution B, 100 DEG C of oil bath 4h of magnetic agitation；
Step 6, above-mentioned mixed solution microwave treatment 2h is modified；
Step 7, using flame spraying one-step synthesis Pd-HMS molecular sieves, will above-mentioned solution be added to flame injection dress
In the needle tubing put, be subsequently adding the CH4 of high heating value, and be passed through oxygen, while igniting by obtained solution from pin hole with ion
Form eject at 3000 DEG C rapid synthesis Pd-Me-HMS molecular sieves；
Step 8 and then the centrifugation under centrifugal separator, dry, and are finally forged under sufficient air atmosphere in Muffle furnace
6h is burnt, Pd-HMS molecular sieves are obtained.
Reference examples 3 produce palladium nitrate, MTMS (MTMOS) mass ratio 1:10 sample.0.5g palladium nitrates, 5g
MTMS (MTMOS), 10ml ethanol, 5ml tetraethyl orthosilicates, 8g hexadecylamines (HDA), 6g isopropanols, 200ml
Deionized water.
Step 1, by 8g hexadecylamines (HDA) and 10ml ethanol, 100 DEG C of oil bath ultrasound 3h are removed under ultrasonic oscillation first
It is miscellaneous；
Step 2,8g hexadecylamines (HDA) are added into the solution being made up of 200ml deionized waters and 10ml ethanol in formed
Solution A, 100 DEG C of oil bath ultrasound 3h of magnetic agitation；
Step 3, by MTMS (MTMOS), palladium nitrate, isopropanol, tetraethyl orthosilicate (TEOS) is in ultrasound
Ripple shakes 100 DEG C of 2h removal of impurities of oil bath；
Step 4, by 5g MTMSs (MTMOS), 0.5g palladium nitrates are added to by 6g isopropanols and 5ml just
Solution B, 100 DEG C of oil bath 2h of magnetic agitation are formed in the mixed solution of silester (TEOS) composition；
Step 5, solution A is mixed with solution B, 100 DEG C of oil bath 4h of magnetic agitation；
Step 6, using flame spraying one-step synthesis Pd-HMS molecular sieves, will above-mentioned solution be added to flame injection dress
In the needle tubing put, be subsequently adding the CH4 of high heating value, and be passed through oxygen, while igniting by obtained solution from pin hole with ion
Form eject at 3000 DEG C rapid synthesis Pd-HMS molecular sieves；
Step 7 and then the centrifugation under centrifugal separator, dry, and are finally forged under sufficient air atmosphere in Muffle furnace
6h is burnt, Pd-HMS molecular sieves are obtained.
Reference examples 4 are produced and are added without the modified sample of palladium nitrate.5g MTMSs (MTMOS), 10ml ethanol,
5ml tetraethyl orthosilicates, 8g hexadecylamines (HDA), 6g isopropanols, 200ml deionized waters.
Step 1, by 8g hexadecylamines (HDA) and 10ml ethanol, 100 DEG C of oil bath ultrasound 3h are removed under ultrasonic oscillation first
It is miscellaneous；
Step 2,8g hexadecylamines (HDA) are added into the solution being made up of 200ml deionized waters and 10ml ethanol in formed
Solution A, 100 DEG C of oil bath ultrasound 3h of magnetic agitation；
Step 3, by MTMS (MTMOS), isopropanol, tetraethyl orthosilicate (TEOS) is in ultrasonic oscillation oil
100 DEG C of 2h removal of impurities of bath；Step 4, by 5g MTMSs (MTMOS), be added to by 6g isopropanols and the positive silicic acid second of 5ml
Solution B, 100 DEG C of oil bath 2h of magnetic agitation are formed in the mixed solution of ester (TEOS) composition；
Step 5, solution A is mixed with solution B, 100 DEG C of oil bath 4h of magnetic agitation；
Step 6, above-mentioned mixed solution microwave treatment 2h is modified；
Step 7, using flame spraying one-step synthesis HMS molecular sieves, will above-mentioned solution be added to flame injection device
Needle tubing in, be subsequently adding the CH4 of high heating value, and be passed through oxygen, while igniting by obtained solution from pin hole with ion
Form ejects the rapid synthesis HMS molecular sieves at 3000 DEG C；
Step 8 and then the centrifugation under centrifugal separator, dry, and are finally forged under sufficient air atmosphere in Muffle furnace
6h is burnt, HMS molecular sieves are obtained.
Adsorption cleaning running water effect assessment
The Pd-HMS molecular sieve cups of obtained various ratios are unified into volume 500ml, by same tap synchronization
The water for taking fills each cup, is doing one group of common cup inwall of blank assay group and notch does not add the molecule of my invention
Sieve.5min is stood, the indices of water are then detected.
The Testing index of Testing index and the method for inspection this research, with reference to the Ministry of Public Health for water purifier security and function
Property evaluate correlation
Standard, specifically includes purified water heavy metal index (iron, manganese, copper, zinc, lead, arsenic), general chemical index [oxygen demand
Clearance, acid-base value (pH value), colourity, turbidity] and microbiological indicator (total plate count, total coli group).It is net because that need to calculate
Hydrophone therefore adds the oxygen demand for surveying municipal water, oxygen demand clearance=(municipal water consume oxygen amount-purification for the clearance of oxygen demand
Water consume oxygen amount) the Pd-Me-HMS molecular sieve cups of obtained various ratios are unified volume by/municipal water consume oxygen amount × 100%
500ml, each cup is filled by the water that same tap synchronization takes, do one group of common cup inwall of blank assay group and
Notch does not add the molecular sieve of my invention.5min is stood, the indices of water are then detected.
The Testing index of Testing index and the method for inspection this research, with reference to the Ministry of Public Health for water purifier security and function
Property evaluate correlation
Standard, specifically includes purified water heavy metal index (iron, manganese, copper, zinc, lead, arsenic), general chemical index [oxygen demand
Clearance, acid-base value (pH value), colourity, turbidity] and microbiological indicator (total plate count, total coli group).It is net because that need to calculate
Hydrophone therefore adds the oxygen demand for surveying municipal water, oxygen demand clearance=(municipal water consume oxygen amount-purification for the clearance of oxygen demand
Water consume oxygen amount)/municipal water consume oxygen amount × 100%.
Test result indicate that Pd-Me-HMS molecular sieves prepared by embodiment 9,10 are used in cup in adsorption cleaning running water
Metal impurities and other effects preferably, illustrate in palladium nitrate, MTMS (MTMOS) mass ratio 1:9,1：When 10
Synergy between them is best, and at most, the narrower absorption in duct is most with stronger for the acidic site in molecular sieve.Under other ratios
Pd-Me-HMS molecular sieves are obtained, and for there is certain adsorption capacity in cup, still effect is bad.Row 10, comparative example are implemented in contrast
1,2,3,4 can be found that.Without magnetic agitation, ultrasonic oscillation, microwave treatment is added without the element modified obtained Pd- of Pd
It is bad that Me-HMS, Me-HMS molecular sieve are used for cup adsorption cleaning running water effect.
Claims (6)
1. a kind of cup containing filtrate, including cup body, described cup body interior has filter.
2. a kind of cup containing filtrate according to claim 1, it is characterised in that described filter includes filter
Box, filter lid and filtrate, described filtrate are arranged in filter box, and described filter lid outside has external screw thread, filter box inner side
With internal thread, filter box is connected with filter lid screw thread.
3. a kind of cup containing filtrate according to claim 1, it is characterised in that described cup body interior has
Annular protrusion, the diameter of the diameter less than filter box of annular protrusion so that filter box can be stuck on annular protrusion.
4. a kind of cup containing filtrate according to claim 2, it is characterised in that described filtrate is new Pd-HMS
Molecular sieve filtrate, for water purification effect.
5. a kind of cup containing filtrate according to claim 1, it is characterised in that the cup body upper part also has
Cup lid, cup lid is threadedly coupled with cup body.
6. a kind of cup containing filtrate according to claim 4, it is characterised in that described Pd-Me-HMS molecular sieves
Preparation method is as follows：
Step 1,100 DEG C of oil bath ultrasound 3h removal of impurities under ultrasonic oscillation first by hexadecylamine (HDA) and ethanol;
Step 2, hexadecylamine (HDA) is added into the solution being made up of deionized water and ethanol in form solution A, magnetic agitation
100 DEG C of oil bath ultrasound 3h；
Step 3, by MTMS (MTMOS), palladium nitrate, isopropanol, tetraethyl orthosilicate (TEOS) shakes in ultrasonic wave
Swing 100 DEG C of 2h removal of impurities of oil bath;
Step 4, by MTMS (MTMOS), palladium nitrate is added to by isopropanol and tetraethyl orthosilicate (TEOS) group
Into mixed solution in form solution B, 100 DEG C of oil bath 2h of magnetic agitation；
Step 5, solution A is mixed with solution B, 100 DEG C of oil bath 4h of magnetic agitation；
Step 6, above-mentioned mixed solution microwave treatment 2h is modified：
Step 7, using flame spraying one-step synthesis Pd-Me-HMS molecular sieves, will above-mentioned solution be added to flame injection dress
In the needle tubing put, be subsequently adding the CH4 of high heating value, and be passed through oxygen, while igniting by obtained solution from pin hole with ion
Form eject at 3000 DEG C rapid synthesis Pd-Me-HMS molecular sieves;
Step 8 and then the centrifugation under centrifugal separator, dry, and finally calcine 6h under sufficient air atmosphere in Muffle furnace,
Obtain Pd-Me-HMS molecular sieves.
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Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1113480A (en) * | 1995-06-20 | 1995-12-20 | 北京新奇材料研究所 | Zeolite molecular sieve water purifying material and its manufacture |
| US20090075996A1 (en) * | 2005-07-14 | 2009-03-19 | Irm Llc | Heterotetracyclic compounds as tpo mimetics |
| US20110278216A1 (en) * | 2008-03-18 | 2011-11-17 | Rubbermaid Inc. | Drinking Container and Filter Assembly |
| CN202843166U (en) * | 2012-11-01 | 2013-04-03 | 朱杵养 | Charging heating cup with lifting filter screen |
| CN106308346A (en) * | 2016-10-30 | 2017-01-11 | 宁波科邦华诚技术转移服务有限公司 | Embedded filter box cup |
-
2017
- 2017-02-28 CN CN201710111434.2A patent/CN106724598B/en not_active Expired - Fee Related
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1113480A (en) * | 1995-06-20 | 1995-12-20 | 北京新奇材料研究所 | Zeolite molecular sieve water purifying material and its manufacture |
| US20090075996A1 (en) * | 2005-07-14 | 2009-03-19 | Irm Llc | Heterotetracyclic compounds as tpo mimetics |
| US20110278216A1 (en) * | 2008-03-18 | 2011-11-17 | Rubbermaid Inc. | Drinking Container and Filter Assembly |
| CN202843166U (en) * | 2012-11-01 | 2013-04-03 | 朱杵养 | Charging heating cup with lifting filter screen |
| CN106308346A (en) * | 2016-10-30 | 2017-01-11 | 宁波科邦华诚技术转移服务有限公司 | Embedded filter box cup |
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