CN106308347A - Anti-slip filter water cup - Google Patents
Anti-slip filter water cup Download PDFInfo
- Publication number
- CN106308347A CN106308347A CN201610925047.8A CN201610925047A CN106308347A CN 106308347 A CN106308347 A CN 106308347A CN 201610925047 A CN201610925047 A CN 201610925047A CN 106308347 A CN106308347 A CN 106308347A
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- China
- Prior art keywords
- water
- cup
- kit
- sodium
- sodium silicate
- Prior art date
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Classifications
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- A—HUMAN NECESSITIES
- A47—FURNITURE; DOMESTIC ARTICLES OR APPLIANCES; COFFEE MILLS; SPICE MILLS; SUCTION CLEANERS IN GENERAL
- A47G—HOUSEHOLD OR TABLE EQUIPMENT
- A47G19/00—Table service
- A47G19/22—Drinking vessels or saucers used for table service
- A47G19/2205—Drinking glasses or vessels
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
- B01J20/02—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material
- B01J20/0203—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material comprising compounds of metals not provided for in B01J20/04
- B01J20/0207—Compounds of Sc, Y or Lanthanides
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
- B01J20/02—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material
- B01J20/10—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material comprising silica or silicate
- B01J20/16—Alumino-silicates
- B01J20/18—Synthetic zeolitic molecular sieves
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F1/00—Treatment of water, waste water, or sewage
- C02F1/28—Treatment of water, waste water, or sewage by sorption
- C02F1/281—Treatment of water, waste water, or sewage by sorption using inorganic sorbents
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F1/00—Treatment of water, waste water, or sewage
- C02F1/28—Treatment of water, waste water, or sewage by sorption
- C02F1/288—Treatment of water, waste water, or sewage by sorption using composite sorbents, e.g. coated, impregnated, multi-layered
Abstract
The invention provides an anti-slip filter water cup. The anti-slip filter water cup comprises a water cup body, wherein an anti-slip rubber sleeve is arranged outside the water cup body, a filter case is mounted at the rim of the water cup body, a micro-pore filter screen is arranged at the bottom of the filter case, a clamp ring is arranged on the outer side of the edge of the upper part, the diameter of the clamp ring is larger than the inner diameter of the rim, so that the filter case can be fixed at the rim of the water cup body, and 3-6 clamp pieces are arranged on the outer side of the edge at the lower part of the filter case; a filter case cover is arranged at the upper part of the filter case, the upper part of the filter case is in threaded connection with the filter case cover, and a filter material is accommodated in the filter case.
Description
Technical field
The present invention relates to a kind of anti-skidding filtering cup, belong to daily life field.
Background technology
Water is the essential condition that the mankind depend on for existence, is also the important component part of human body, therefore drink hardness of water with
The healthy relation of human body is the closest.Hardness of water refers to the content i.e. calcium salt of salts substances and the magnesium salt content being dissolved in water
Number, it is the important indicator representing water quality.Calcium, the quality summation of magnesium ion are equivalent to 10mgCaO or 7.19mgMgO
Referred to as 1 " degree (°) ".Specifying that 8 degree (°) is soft water below, 8 ~ 16 degree (°) is middle water, is hard water more than 16 degree (°), 30 degree
It is extremely hard water more than (°).Although calcium and magnesium are all the elements of needed by human, but the water drinking much higher hard can cause the stomaches such as diarrhoea
Intestinal tract disease, simultaneously high hardness water be also unfavorable for people live in culinary art and washing, therefore the monitoring of determining total hardness of water is very
Important, water tumbler is the instrument that in daily life, people commonly use, but general water tumbler does not have the calcium ions and magnesium ions filtered in hard water, needs
Want a kind of and purify the water tumbler that hard water is effective.
Summary of the invention
The problem existed for above-mentioned prior art, the present invention provides a kind of anti-skidding filtering cup, and skidproof effect is good, purifies
Water is effective.
To achieve these goals, the technical solution used in the present invention is: a kind of anti-skidding filtering cup, including water tumbler originally
Body, described water tumbler body exterior has antiskid glue sleeve, and the rim of a cup of water tumbler body goes out to be provided with filter box, and described filter cassette bottom portion is
Micro-strainer, has snap ring outside top edge, the diameter of snap ring is more than rim of a cup internal diameter so that filter box can be fixed on water tumbler originally
The rim of a cup of body, is provided with 3-6 card outside filter box lower edge；
It is threaded that filter box top is provided with filter lid, filter box top and filter lid, and filter box is built with filtrate.
Described cup body bottom portion has external screw thread, and anti-skid base is provided with female thread, and anti-skid base is arranged at the bottom of glass body
Portion.
Described water tumbler body is also equipped with cup handle.
Described filtrate is new E u-KIT-1 absorbent filter medium, for water purification effect.
The water tumbler of the present invention has an antiskid glue sleeve, good antiskid effect, filter box can dismounting and change, convenient use, and filter
Box is connected with filter lid threaded engagement, the filtrate that can the most more renew, and filtrate is new E u-prepared by special process
KIT-1 absorbent filter medium, its good purification.
Accompanying drawing explanation
Fig. 1 is the schematic diagram of the present invention.
Fig. 2 is overall structure figure.
Fig. 3 is filter box structure chart.
1, water tumbler body, 2, filter box, 3, filter lid, 4, anti-skidding upper cover, 5, antiskid glue sleeve, 6, anti-skid base, 21, snap ring,
22, card.
Detailed description of the invention
The invention will be further described for 1-3 and embodiment below in conjunction with the accompanying drawings.
A kind of anti-skidding filtering cup, including water tumbler body, described water tumbler body exterior has antiskid glue sleeve 5, and water tumbler is originally
The rim of a cup of body 1 goes out to be provided with filter box 2, and described filter cassette bottom portion is micro-strainer, has snap ring 21, snap ring 21 outside top edge
Diameter more than rim of a cup internal diameter so that filter box can be fixed on the rim of a cup of water tumbler body, is provided with 3-6 outside filter box lower edge
Individual card 22, card is welded on outside filter box lower edge, outwards bends and stretches, and when by external force, card sector-meeting is shunk, when filter box is put
Water inlet cup this most internal time, the inwall of water tumbler body can make card to inner side shrink so that filter box can clamping water tumbler body,
It is threaded that filter box top is provided with filter lid 3, filter box top and filter lid, and filter box, built with filtrate, filters lid 3 surface
There is micropore.
Described cup body bottom portion has external screw thread, and anti-skid base is provided with female thread, and anti-skid base is arranged at the bottom of glass body
Portion.
Described water tumbler body is also equipped with cup handle.
Described filtrate is new E u-KIT-1 absorbent filter medium, for water purification effect.
Concrete preparation method is as follows:
Embodiment 1 produces europium nitrate, the sample of sodium silicate mol ratio 1:5.0.01mol europium nitrate, 0.05mol sodium silicate,
0.1mol cetyl trimethylammonium bromide, 0.1mol sodium ethylene diamine tetracetate, the sodium hydroxide of 2mol/L, the nitre of 0.1mol/L
Acid, 300ml deionized water.
Step 1, first by sodium silicate and cetyl trimethylammonium bromide, sodium ethylene diamine tetracetate is under ultrasonic wave concussion
100 DEG C of oil bath ultrasonic 3h remove impurity;
Step 2, by 0.05mol sodium silicate, 0.1mol sodium ethylene diamine tetracetate and 0.1mol cetyl trimethylammonium bromide
Join 100 DEG C of 3h of magnetic agitation oil bath heating in 100ml deionized water;
Step 3, then through microwave treatment 2h;
Step 4, above-mentioned solution is poured in the reactor that politef is liner by drainage device, then reactor is put into
Cool down after 373 K constant temperature 24h in autoclave, with the sodium hydroxide of 2mol/L regulate the pH of mixture be 10.5～
11.0,2 crystallization of constant temperature；
Step 5, to take out after crystallization thing with the pH of distilled water cyclic washing to filtrate be 7, naturally dries, then at 813K, N2
Roasting 1 h in atmosphere, in air, roasting 6 h obtains NaKIT-1 powder body；
Step 6, the HNO3 solution of NaKIT-1 powder body 0.1mol/L is carried out pickling, control HNO3 solution and NaKIT-1 powder
The mass ratio of body is 10:1, room temperature magnetic agitation 0.5h, and vacuum pump filters, and the pH being washed with distilled water to filtrate is 7,110
At DEG C, vacuum drying oven is dried and is prepared KIT-1 absorbent filter medium；
Step 7, by the remove impurity under ultrasonic wave concussion of 0.01mol europium nitrate, be then dissolved in 200ml deionized water, by leaching
Eu element is impregnated in KIT-1 absorbent filter medium by stain method；
Step 8, then centrifugation under centrifugal separator, vacuum rotary evaporator removes water, and 110 DEG C of vacuum drying oven is dried,
Last 550 DEG C of calcining 10h under sufficient air atmosphere in Muffle furnace, obtain absorbent filter medium Eu-KIT-1.
Embodiment 2 produces europium nitrate, the sample of sodium silicate mol ratio 1:6.0.01mol europium nitrate, 0.06mol sodium silicate,
0.1mol cetyl trimethylammonium bromide, 0.1mol sodium ethylene diamine tetracetate, the sodium hydroxide of 2mol/L, the nitre of 0.1mol/L
Acid, 300ml deionized water.
Step 1, first by sodium silicate and cetyl trimethylammonium bromide, sodium ethylene diamine tetracetate is under ultrasonic wave concussion
100 DEG C of oil bath ultrasonic 3h remove impurity;
Step 2, by 0.06mol sodium silicate, 0.1mol sodium ethylene diamine tetracetate and 0.1mol cetyl trimethylammonium bromide
Join 100 DEG C of 3h of magnetic agitation oil bath heating in 100ml deionized water;
Step 3, then through microwave treatment 2h;
Step 4, above-mentioned solution is poured in the reactor that politef is liner by drainage device, then reactor is put into
Cool down after 373 K constant temperature 24h in autoclave, with the sodium hydroxide of 2mol/L regulate the pH of mixture be 10.5～
11.0,2 crystallization of constant temperature；
Step 5, to take out after crystallization thing with the pH of distilled water cyclic washing to filtrate be 7, naturally dries, then at 813K, N2
Roasting 1 h in atmosphere, in air, roasting 6 h obtains NaKIT-1 powder body；
Step 6, the HNO3 solution of NaKIT-1 powder body 0.1mol/L is carried out pickling, control HNO3 solution and NaKIT-1 powder
The mass ratio of body is 10:1, room temperature magnetic agitation 0.5h, and vacuum pump filters, and the pH being washed with distilled water to filtrate is
At 7,110 DEG C, vacuum drying oven is dried and is prepared KIT-1 absorbent filter medium；
Step 7, by the remove impurity under ultrasonic wave concussion of 0.01mol europium nitrate, be then dissolved in 200ml deionized water, by leaching
Eu element is impregnated in KIT-1 absorbent filter medium by stain method；
Step 8, then centrifugation under centrifugal separator, vacuum rotary evaporator removes water, and 110 DEG C of vacuum drying oven is dried,
Last 550 DEG C of calcining 10h under sufficient air atmosphere in Muffle furnace, obtain absorbent filter medium Eu-KIT-1.
Embodiment 3 produces europium nitrate, the sample of sodium silicate mol ratio 1:7.0.01mol europium nitrate, 0.07mol sodium silicate,
0.1mol cetyl trimethylammonium bromide, 0.1mol sodium ethylene diamine tetracetate, the sodium hydroxide of 2mol/L, the nitre of 0.1mol/L
Acid, 300ml deionized water.
Step 1, first by sodium silicate and cetyl trimethylammonium bromide, sodium ethylene diamine tetracetate is under ultrasonic wave concussion
100 DEG C of oil bath ultrasonic 3h remove impurity;
Step 2, by 0.07mol sodium silicate, 0.1mol sodium ethylene diamine tetracetate and 0.1mol cetyl trimethylammonium bromide
Join 100 DEG C of 3h of magnetic agitation oil bath heating in 100ml deionized water;
Step 3, then through microwave treatment 2h;
Step 4, above-mentioned solution is poured in the reactor that politef is liner by drainage device, then reactor is put into
Cool down after 373 K constant temperature 24h in autoclave, with the sodium hydroxide of 2mol/L regulate the pH of mixture be 10.5～
11.0,2 crystallization of constant temperature；
Step 5, to take out after crystallization thing with the pH of distilled water cyclic washing to filtrate be 7, naturally dries, then at 813K, N2
Roasting 1 h in atmosphere, in air, roasting 6 h obtains NaKIT-1 powder body；
Step 6, the HNO3 solution of NaKIT-1 powder body 0.1mol/L is carried out pickling, control HNO3 solution and NaKIT-1 powder
The mass ratio of body is 10:1, room temperature magnetic agitation 0.5h, and vacuum pump filters, and the pH being washed with distilled water to filtrate is
At 7,110 DEG C, vacuum drying oven is dried and is prepared KIT-1 absorbent filter medium；
Step 7, by the remove impurity under ultrasonic wave concussion of 0.01mol europium nitrate, be then dissolved in 200ml deionized water, by leaching
Eu element is impregnated in KIT-1 absorbent filter medium by stain method；
Step 8, then centrifugation under centrifugal separator, vacuum rotary evaporator removes water, and 110 DEG C of vacuum drying oven is dried,
Last 550 DEG C of calcining 10h under sufficient air atmosphere in Muffle furnace, obtain absorbent filter medium Eu-KIT-1.
Embodiment 4 produces europium nitrate, the sample of sodium silicate mol ratio 1:8.0.01mol europium nitrate, 0.08mol sodium silicate,
0.1mol cetyl trimethylammonium bromide, 0.1mol sodium ethylene diamine tetracetate, the sodium hydroxide of 2mol/L, the nitre of 0.1mol/L
Acid, 300ml deionized water.
Step 1, first by sodium silicate and cetyl trimethylammonium bromide, sodium ethylene diamine tetracetate is under ultrasonic wave concussion
100 DEG C of oil bath ultrasonic 3h remove impurity;
Step 2, by 0.08mol sodium silicate, 0.1mol sodium ethylene diamine tetracetate and 0.1mol cetyl trimethylammonium bromide
Join 100 DEG C of 3h of magnetic agitation oil bath heating in 100ml deionized water;
Step 3, then through microwave treatment 2h;
Step 4, above-mentioned solution is poured in the reactor that politef is liner by drainage device, then reactor is put into
Cool down after 373 K constant temperature 24h in autoclave, with the sodium hydroxide of 2mol/L regulate the pH of mixture be 10.5～
11.0,2 crystallization of constant temperature；
Step 5, to take out after crystallization thing with the pH of distilled water cyclic washing to filtrate be 7, naturally dries, then at 813K, N2
Roasting 1 h in atmosphere, in air, roasting 6 h obtains NaKIT-1 powder body；
Step 6, the HNO3 solution of NaKIT-1 powder body 0.1mol/L is carried out pickling, control HNO3 solution and NaKIT-1 powder
The mass ratio of body is 10:1, room temperature magnetic agitation 0.5h, and vacuum pump filters, and the pH being washed with distilled water to filtrate is
At 7,110 DEG C, vacuum drying oven is dried and is prepared KIT-1 absorbent filter medium；
Step 7, by the remove impurity under ultrasonic wave concussion of 0.01mol europium nitrate, be then dissolved in 200ml deionized water, by leaching
Eu element is impregnated in KIT-1 absorbent filter medium by stain method；
Step 8, then centrifugation under centrifugal separator, vacuum rotary evaporator removes water, and 110 DEG C of vacuum drying oven is dried,
Last 550 DEG C of calcining 10h under sufficient air atmosphere in Muffle furnace, obtain absorbent filter medium Eu-KIT-1.
Embodiment 5 produces europium nitrate, the sample of sodium silicate mol ratio 1:9.0.01mol europium nitrate, 0.09mol sodium silicate, 0.1mol
Cetyl trimethylammonium bromide, 0.1mol sodium ethylene diamine tetracetate, the sodium hydroxide of 2mol/L, the nitric acid of 0.1mol/L,
300ml deionized water.
Step 1, first by sodium silicate and cetyl trimethylammonium bromide, sodium ethylene diamine tetracetate is under ultrasonic wave concussion
100 DEG C of oil bath ultrasonic 3h remove impurity;
Step 2, by 0.09mol sodium silicate, 0.1mol sodium ethylene diamine tetracetate and 0.1mol cetyl trimethylammonium bromide
Join 100 DEG C of 3h of magnetic agitation oil bath heating in 100ml deionized water;
Step 3, then through microwave treatment 2h;
Step 4, above-mentioned solution is poured in the reactor that politef is liner by drainage device, then reactor is put into
Cool down after 373 K constant temperature 24h in autoclave, with the sodium hydroxide of 2mol/L regulate the pH of mixture be 10.5～
11.0,2 crystallization of constant temperature；
Step 5, to take out after crystallization thing with the pH of distilled water cyclic washing to filtrate be 7, naturally dries, then at 813K, N2
Roasting 1 h in atmosphere, in air, roasting 6 h obtains NaKIT-1 powder body；
Step 6, the HNO3 solution of NaKIT-1 powder body 0.1mol/L is carried out pickling, control HNO3 solution and NaKIT-1 powder
The mass ratio of body is 10:1, room temperature magnetic agitation 0.5h, and vacuum pump filters, and the pH being washed with distilled water to filtrate is
At 7,110 DEG C, vacuum drying oven is dried and is prepared KIT-1 absorbent filter medium；
Step 7, by the remove impurity under ultrasonic wave concussion of 0.01mol europium nitrate, be then dissolved in 200ml deionized water, by leaching
Eu element is impregnated in KIT-1 absorbent filter medium by stain method；
Step 8, then centrifugation under centrifugal separator, vacuum rotary evaporator removes water, and 110 DEG C of vacuum drying oven is dried,
Last 550 DEG C of calcining 10h under sufficient air atmosphere in Muffle furnace, obtain absorbent filter medium Eu-KIT-1.
Embodiment 6 produces europium nitrate, the sample of sodium silicate mol ratio 1:10.0.01mol europium nitrate, 0.1mol sodium silicate,
0.1mol cetyl trimethylammonium bromide, 0.1mol sodium ethylene diamine tetracetate, the sodium hydroxide of 2mol/L, the nitre of 0.1mol/L
Acid, 300ml deionized water.
Step 1, first by sodium silicate and cetyl trimethylammonium bromide, sodium ethylene diamine tetracetate is under ultrasonic wave concussion
100 DEG C of oil bath ultrasonic 3h remove impurity;
Step 2,0.1mol sodium silicate, 0.1mol sodium ethylene diamine tetracetate and 0.1mol cetyl trimethylammonium bromide are added
Enter in 100ml deionized water magnetic agitation oil bath 100 DEG C of 3h of heating;
Step 3, then through microwave treatment 2h;
Step 4, above-mentioned solution is poured in the reactor that politef is liner by drainage device, then reactor is put into
Cool down after 373 K constant temperature 24h in autoclave, with the sodium hydroxide of 2mol/L regulate the pH of mixture be 10.5～
11.0,2 crystallization of constant temperature；
Step 5, to take out after crystallization thing with the pH of distilled water cyclic washing to filtrate be 7, naturally dries, then at 813K, N2
Roasting 1 h in atmosphere, in air, roasting 6 h obtains NaKIT-1 powder body；
Step 6, the HNO3 solution of NaKIT-1 powder body 0.1mol/L is carried out pickling, control HNO3 solution and NaKIT-1 powder
The mass ratio of body is 10:1, room temperature magnetic agitation 0.5h, and vacuum pump filters, and the pH being washed with distilled water to filtrate is
At 7,110 DEG C, vacuum drying oven is dried and is prepared KIT-1 absorbent filter medium；
Step 7, by the remove impurity under ultrasonic wave concussion of 0.01mol europium nitrate, be then dissolved in 200ml deionized water, by leaching
Eu element is impregnated in KIT-1 absorbent filter medium by stain method；
Step 8, then centrifugation under centrifugal separator, vacuum rotary evaporator removes water, and 110 DEG C of vacuum drying oven is dried,
Last 550 DEG C of calcining 10h under sufficient air atmosphere in Muffle furnace, obtain absorbent filter medium Eu-KIT-1.
Embodiment 7 produces europium nitrate, the sample of sodium silicate mol ratio 1:11.0.01mol europium nitrate, 0.11mol sodium silicate,
0.1mol cetyl trimethylammonium bromide, 0.1mol sodium ethylene diamine tetracetate, the sodium hydroxide of 2mol/L, the nitre of 0.1mol/L
Acid, 300ml deionized water.
Step 1, first by sodium silicate and cetyl trimethylammonium bromide, sodium ethylene diamine tetracetate is under ultrasonic wave concussion
100 DEG C of oil bath ultrasonic 3h remove impurity;
Step 2, by 0.11mol sodium silicate, 0.1mol sodium ethylene diamine tetracetate and 0.1mol cetyl trimethylammonium bromide
Join 100 DEG C of 3h of magnetic agitation oil bath heating in 100ml deionized water;
Step 3, then through microwave treatment 2h;
Step 4, above-mentioned solution is poured in the reactor that politef is liner by drainage device, then reactor is put into
Cool down after 373 K constant temperature 24h in autoclave, with the sodium hydroxide of 2mol/L regulate the pH of mixture be 10.5～
11.0,2 crystallization of constant temperature；
Step 5, to take out after crystallization thing with the pH of distilled water cyclic washing to filtrate be 7, naturally dries, then at 813K, N2
Roasting 1 h in atmosphere, in air, roasting 6 h obtains NaKIT-1 powder body；
Step 6, the HNO3 solution of NaKIT-1 powder body 0.1mol/L is carried out pickling, control HNO3 solution and NaKIT-1 powder
The mass ratio of body is 10:1, room temperature magnetic agitation 0.5h, and vacuum pump filters, and the pH being washed with distilled water to filtrate is 7,110
At DEG C, vacuum drying oven is dried and is prepared KIT-1 absorbent filter medium；
Step 7, by the remove impurity under ultrasonic wave concussion of 0.01mol europium nitrate, be then dissolved in 200ml deionized water, by leaching
Eu element is impregnated in KIT-1 absorbent filter medium by stain method；
Step 8, then centrifugation under centrifugal separator, vacuum rotary evaporator removes water, and 110 DEG C of vacuum drying oven is dried,
Last 550 DEG C of calcining 10h under sufficient air atmosphere in Muffle furnace, obtain absorbent filter medium Eu-KIT-1.
Embodiment 8 produces europium nitrate, the sample of sodium silicate mol ratio 1:12.0.01mol europium nitrate, 0.12mol sodium silicate,
0.1mol cetyl trimethylammonium bromide, 0.1mol sodium ethylene diamine tetracetate, the sodium hydroxide of 2mol/L, the nitre of 0.1mol/L
Acid, 300ml deionized water.
Step 1, first by sodium silicate and cetyl trimethylammonium bromide, sodium ethylene diamine tetracetate is under ultrasonic wave concussion
100 DEG C of oil bath ultrasonic 3h remove impurity;
Step 2, by 0.12mol sodium silicate, 0.1mol sodium ethylene diamine tetracetate and 0.1mol cetyl trimethylammonium bromide
Join 100 DEG C of 3h of magnetic agitation oil bath heating in 100ml deionized water;
Step 3, then through microwave treatment 2h;
Step 4, above-mentioned solution is poured in the reactor that politef is liner by drainage device, then reactor is put into
Cool down after 373 K constant temperature 24h in autoclave, with the sodium hydroxide of 2mol/L regulate the pH of mixture be 10.5～
11.0,2 crystallization of constant temperature；
Step 5, to take out after crystallization thing with the pH of distilled water cyclic washing to filtrate be 7, naturally dries, then at 813K, N2
Roasting 1 h in atmosphere, in air, roasting 6 h obtains NaKIT-1 powder body；
Step 6, the HNO3 solution of NaKIT-1 powder body 0.1mol/L is carried out pickling, control HNO3 solution and NaKIT-1 powder
The mass ratio of body is 10:1, room temperature magnetic agitation 0.5h, and vacuum pump filters, and the pH being washed with distilled water to filtrate is
At 7,110 DEG C, vacuum drying oven is dried and is prepared KIT-1 absorbent filter medium；
Step 7, by the remove impurity under ultrasonic wave concussion of 0.01mol europium nitrate, be then dissolved in 200ml deionized water, by leaching
Eu element is impregnated in KIT-1 absorbent filter medium by stain method；
Step 8, then centrifugation under centrifugal separator, vacuum rotary evaporator removes water, and 110 DEG C of vacuum drying oven is dried,
Last 550 DEG C of calcining 10h under sufficient air atmosphere in Muffle furnace, obtain absorbent filter medium Eu-KIT-1.
Embodiment 9 produces europium nitrate, the sample of sodium silicate mol ratio 1:13.0.01mol europium nitrate, 0.13mol sodium silicate,
0.1mol cetyl trimethylammonium bromide, 0.1mol sodium ethylene diamine tetracetate, the sodium hydroxide of 2mol/L, the nitre of 0.1mol/L
Acid, 300ml deionized water.
Step 1, first by sodium silicate and cetyl trimethylammonium bromide, sodium ethylene diamine tetracetate is under ultrasonic wave concussion
100 DEG C of oil bath ultrasonic 3h remove impurity;
Step 2, by 0.13mol sodium silicate, 0.1mol sodium ethylene diamine tetracetate and 0.1mol cetyl trimethylammonium bromide
Join 100 DEG C of 3h of magnetic agitation oil bath heating in 100ml deionized water;
Step 3, then through microwave treatment 2h;
Step 4, above-mentioned solution is poured in the reactor that politef is liner by drainage device, then reactor is put into
Cool down after 373 K constant temperature 24h in autoclave, with the sodium hydroxide of 2mol/L regulate the pH of mixture be 10.5～
11.0,2 crystallization of constant temperature；
Step 5, to take out after crystallization thing with the pH of distilled water cyclic washing to filtrate be 7, naturally dries, then at 813K, N2
Roasting 1 h in atmosphere, in air, roasting 6 h obtains NaKIT-1 powder body；
Step 6, the HNO3 solution of NaKIT-1 powder body 0.1mol/L is carried out pickling, control HNO3 solution and NaKIT-1 powder
The mass ratio of body is 10:1, room temperature magnetic agitation 0.5h, and vacuum pump filters, and the pH being washed with distilled water to filtrate is 7,110
At DEG C, vacuum drying oven is dried and is prepared KIT-1 absorbent filter medium；
Step 7, by the remove impurity under ultrasonic wave concussion of 0.01mol europium nitrate, be then dissolved in 200ml deionized water, by leaching
Eu element is impregnated in KIT-1 absorbent filter medium by stain method；
Step 8, then centrifugation under centrifugal separator, vacuum rotary evaporator removes water, and 110 DEG C of vacuum drying oven is dried,
Last 550 DEG C of calcining 10h under sufficient air atmosphere in Muffle furnace, obtain absorbent filter medium Eu-KIT-1.
Embodiment 10 produces europium nitrate, the sample of sodium silicate mol ratio 1:14.0.01mol europium nitrate, 0.14mol sodium silicate,
0.1mol cetyl trimethylammonium bromide, 0.1mol sodium ethylene diamine tetracetate, the sodium hydroxide of 2mol/L, the nitre of 0.1mol/L
Acid, 300ml deionized water.
Step 1, first by sodium silicate and cetyl trimethylammonium bromide, sodium ethylene diamine tetracetate is under ultrasonic wave concussion
100 DEG C of oil bath ultrasonic 3h remove impurity;
Step 2, by 0.14mol sodium silicate, 0.1mol sodium ethylene diamine tetracetate and 0.1mol cetyl trimethylammonium bromide
Join 100 DEG C of 3h of magnetic agitation oil bath heating in 100ml deionized water;
Step 3, then through microwave treatment 2h;
Step 4, above-mentioned solution is poured in the reactor that politef is liner by drainage device, then reactor is put into
Cool down after 373 K constant temperature 24h in autoclave, with the sodium hydroxide of 2mol/L regulate the pH of mixture be 10.5～
11.0,2 crystallization of constant temperature；
Step 5, to take out after crystallization thing with the pH of distilled water cyclic washing to filtrate be 7, naturally dries, then at 813K, N2
Roasting 1 h in atmosphere, in air, roasting 6 h obtains NaKIT-1 powder body；
Step 6, the HNO3 solution of NaKIT-1 powder body 0.1mol/L is carried out pickling, control HNO3 solution and NaKIT-1 powder
The mass ratio of body is 10:1, room temperature magnetic agitation 0.5h, and vacuum pump filters, and the pH being washed with distilled water to filtrate is
At 7,110 DEG C, vacuum drying oven is dried and is prepared KIT-1 absorbent filter medium；
Step 7, by the remove impurity under ultrasonic wave concussion of 0.01mol europium nitrate, be then dissolved in 200ml deionized water, by leaching
Eu element is impregnated in KIT-1 absorbent filter medium by stain method；
Step 8, then centrifugation under centrifugal separator, vacuum rotary evaporator removes water, and 110 DEG C of vacuum drying oven is dried,
Last 550 DEG C of calcining 10h under sufficient air atmosphere in Muffle furnace, obtain absorbent filter medium Eu-KIT-1.
Embodiment 11 produces europium nitrate, the sample of sodium silicate mol ratio 1:15.0.01mol europium nitrate, 0.15mol sodium silicate,
0.1mol cetyl trimethylammonium bromide, 0.1mol sodium ethylene diamine tetracetate, the sodium hydroxide of 2mol/L, the nitre of 0.1mol/L
Acid, 300ml deionized water.
Step 1, first by sodium silicate and cetyl trimethylammonium bromide, sodium ethylene diamine tetracetate is under ultrasonic wave concussion
100 DEG C of oil bath ultrasonic 3h remove impurity;
Step 2, by 0.15mol sodium silicate, 0.1mol sodium ethylene diamine tetracetate and 0.1mol cetyl trimethylammonium bromide
Join 100 DEG C of 3h of magnetic agitation oil bath heating in 100ml deionized water;
Step 3, then through microwave treatment 2h;
Step 4, above-mentioned solution is poured in the reactor that politef is liner by drainage device, then reactor is put into
Cool down after 373 K constant temperature 24h in autoclave, with the sodium hydroxide of 2mol/L regulate the pH of mixture be 10.5～
11.0,2 crystallization of constant temperature；
Step 5, to take out after crystallization thing with the pH of distilled water cyclic washing to filtrate be 7, naturally dries, then at 813K, N2
Roasting 1 h in atmosphere, in air, roasting 6 h obtains NaKIT-1 powder body；
Step 6, the HNO3 solution of NaKIT-1 powder body 0.1mol/L is carried out pickling, control HNO3 solution and NaKIT-1 powder
The mass ratio of body is 10:1, room temperature magnetic agitation 0.5h, and vacuum pump filters, and the pH being washed with distilled water to filtrate is
At 7,110 DEG C, vacuum drying oven is dried and is prepared KIT-1 absorbent filter medium；
Step 7, by the remove impurity under ultrasonic wave concussion of 0.01mol europium nitrate, be then dissolved in 200ml deionized water, by leaching
Eu element is impregnated in KIT-1 absorbent filter medium by stain method；
Step 8, then centrifugation under centrifugal separator, vacuum rotary evaporator removes water, and 110 DEG C of vacuum drying oven is dried,
Last 550 DEG C of calcining 10h under sufficient air atmosphere in Muffle furnace, obtain absorbent filter medium Eu-KIT-1.
Embodiment 12 produces europium nitrate, the sample of sodium silicate mol ratio 1:16.0.01mol europium nitrate, 0.16mol sodium silicate,
0.1mol cetyl trimethylammonium bromide, 0.1mol sodium ethylene diamine tetracetate, the sodium hydroxide of 2mol/L, the nitre of 0.1mol/L
Acid, 300ml deionized water.
Step 1, first by sodium silicate and cetyl trimethylammonium bromide, sodium ethylene diamine tetracetate is under ultrasonic wave concussion
100 DEG C of oil bath ultrasonic 3h remove impurity;
Step 2, by 0.16mol sodium silicate, 0.1mol sodium ethylene diamine tetracetate and 0.1mol cetyl trimethylammonium bromide
Join 100 DEG C of 3h of magnetic agitation oil bath heating in 100ml deionized water;
Step 3, then through microwave treatment 2h;
Step 4, above-mentioned solution is poured in the reactor that politef is liner by drainage device, then reactor is put into
Cool down after 373 K constant temperature 24h in autoclave, with the sodium hydroxide of 2mol/L regulate the pH of mixture be 10.5～
11.0,2 crystallization of constant temperature；
Step 5, to take out after crystallization thing with the pH of distilled water cyclic washing to filtrate be 7, naturally dries, then at 813K, N2
Roasting 1 h in atmosphere, in air, roasting 6 h obtains NaKIT-1 powder body；
Step 6, the HNO3 solution of NaKIT-1 powder body 0.1mol/L is carried out pickling, control HNO3 solution and NaKIT-1 powder
The mass ratio of body is 10:1, room temperature magnetic agitation 0.5h, and vacuum pump filters, and the pH being washed with distilled water to filtrate is
At 7,110 DEG C, vacuum drying oven is dried and is prepared KIT-1 absorbent filter medium；
Step 7, by the remove impurity under ultrasonic wave concussion of 0.01mol europium nitrate, be then dissolved in 200ml deionized water, by leaching
Eu element is impregnated in KIT-1 absorbent filter medium by stain method；
Step 8, then centrifugation under centrifugal separator, vacuum rotary evaporator removes water, and 110 DEG C of vacuum drying oven is dried,
Last 550 DEG C of calcining 10h under sufficient air atmosphere in Muffle furnace, obtain absorbent filter medium Eu-KIT-1.
Embodiment 13 produces europium nitrate, the sample of sodium silicate mol ratio 1:17.0.01mol europium nitrate, 0.17mol sodium silicate,
0.1mol cetyl trimethylammonium bromide, 0.1mol sodium ethylene diamine tetracetate, the sodium hydroxide of 2mol/L, the nitre of 0.1mol/L
Acid, 300ml deionized water.
Step 1, first by sodium silicate and cetyl trimethylammonium bromide, sodium ethylene diamine tetracetate is under ultrasonic wave concussion
100 DEG C of oil bath ultrasonic 3h remove impurity;
Step 2, by 0.17mol sodium silicate, 0.1mol sodium ethylene diamine tetracetate and 0.1mol cetyl trimethylammonium bromide
Join 100 DEG C of 3h of magnetic agitation oil bath heating in 100ml deionized water;
Step 3, then through microwave treatment 2h;
Step 4, above-mentioned solution is poured in the reactor that politef is liner by drainage device, then reactor is put into
Cool down after 373 K constant temperature 24h in autoclave, with the sodium hydroxide of 2mol/L regulate the pH of mixture be 10.5～
11.0,2 crystallization of constant temperature；
Step 5, to take out after crystallization thing with the pH of distilled water cyclic washing to filtrate be 7, naturally dries, then at 813K, N2
Roasting 1 h in atmosphere, in air, roasting 6 h obtains NaKIT-1 powder body；
Step 6, the HNO3 solution of NaKIT-1 powder body 0.1mol/L is carried out pickling, control HNO3 solution and NaKIT-1 powder
The mass ratio of body is 10:1, room temperature magnetic agitation 0.5h, and vacuum pump filters, and the pH being washed with distilled water to filtrate is
At 7,110 DEG C, vacuum drying oven is dried and is prepared KIT-1 absorbent filter medium；
Step 7, by the remove impurity under ultrasonic wave concussion of 0.01mol europium nitrate, be then dissolved in 200ml deionized water, by leaching
Eu element is impregnated in KIT-1 absorbent filter medium by stain method；
Step 8, then centrifugation under centrifugal separator, vacuum rotary evaporator removes water, and 110 DEG C of vacuum drying oven is dried,
Last 550 DEG C of calcining 10h under sufficient air atmosphere in Muffle furnace, obtain absorbent filter medium Eu-KIT-1.
Embodiment 14 produces europium nitrate, the sample of sodium silicate mol ratio 1:18.0.01mol europium nitrate, 0.18mol sodium silicate,
0.1mol cetyl trimethylammonium bromide, 0.1mol sodium ethylene diamine tetracetate, the sodium hydroxide of 2mol/L, the nitre of 0.1mol/L
Acid, 300ml deionized water.
Step 1, first by sodium silicate and cetyl trimethylammonium bromide, sodium ethylene diamine tetracetate is under ultrasonic wave concussion
100 DEG C of oil bath ultrasonic 3h remove impurity;
Step 2, by 0.05mol sodium silicate, 0.1mol sodium ethylene diamine tetracetate and 0.1mol cetyl trimethylammonium bromide
Join 100 DEG C of 3h of magnetic agitation oil bath heating in 100ml deionized water;
Step 3, then through microwave treatment 2h;
Step 4, above-mentioned solution is poured in the reactor that politef is liner by drainage device, then reactor is put into
Cool down after 373 K constant temperature 24h in autoclave, with the sodium hydroxide of 2mol/L regulate the pH of mixture be 10.5～
11.0,2 crystallization of constant temperature；
Step 5, to take out after crystallization thing with the pH of distilled water cyclic washing to filtrate be 7, naturally dries, then at 813K, N2
Roasting 1 h in atmosphere, in air, roasting 6 h obtains NaKIT-1 powder body；
Step 6, the HNO3 solution of NaKIT-1 powder body 0.1mol/L is carried out pickling, control HNO3 solution and NaKIT-1 powder
The mass ratio of body is 10:1, room temperature magnetic agitation 0.5h, and vacuum pump filters, and the pH being washed with distilled water to filtrate is
At 7,110 DEG C, vacuum drying oven is dried and is prepared KIT-1 absorbent filter medium；
Step 7, by the remove impurity under ultrasonic wave concussion of 0.01mol europium nitrate, be then dissolved in 200ml deionized water, by leaching
Eu element is impregnated in KIT-1 absorbent filter medium by stain method；
Step 8, then centrifugation under centrifugal separator, vacuum rotary evaporator removes water, and 110 DEG C of vacuum drying oven is dried,
Last 550 DEG C of calcining 10h under sufficient air atmosphere in Muffle furnace, obtain absorbent filter medium Eu-KIT-1.
Reference examples 1 produces europium nitrate, the sample of sodium silicate mol ratio 1:11.0.01mol europium nitrate, 0.11mol sodium silicate, 0.1mol
Cetyl trimethylammonium bromide, 0.1mol sodium ethylene diamine tetracetate, the sodium hydroxide of 2mol/L, the nitric acid of 0.1mol/L,
300ml deionized water.
Step 1, first by sodium silicate and cetyl trimethylammonium bromide, sodium ethylene diamine tetracetate is under common concussion
100 DEG C of oil bath ultrasonic 3h remove impurity;
Step 2, by 0.11mol sodium silicate, 0.1mol sodium ethylene diamine tetracetate and 0.1mol cetyl trimethylammonium bromide
Join 100 DEG C of 3h of magnetic agitation oil bath heating in 100ml deionized water;
Step 3, then through microwave treatment 2h;
Step 4, above-mentioned solution is poured in the reactor that politef is liner by drainage device, then reactor is put into
Cool down after 373 K constant temperature 24h in autoclave, with the sodium hydroxide of 2mol/L regulate the pH of mixture be 10.5～
11.0,2 crystallization of constant temperature；
Step 5, to take out after crystallization thing with the pH of distilled water cyclic washing to filtrate be 7, naturally dries, then at 813K, N2
Roasting 1 h in atmosphere, in air, roasting 6 h obtains NaKIT-1 powder body；
Step 6, the HNO3 solution of NaKIT-1 powder body 0.1mol/L is carried out pickling, control HNO3 solution and NaKIT-1 powder
The mass ratio of body is 10:1, room temperature magnetic agitation 0.5h, and vacuum pump filters, and the pH being washed with distilled water to filtrate is
At 7,110 DEG C, vacuum drying oven is dried and is prepared KIT-1 absorbent filter medium；
Step 7, by the remove impurity under common concussion of 0.01mol europium nitrate, be then dissolved in 200ml deionized water, by dipping
Eu element is impregnated in KIT-1 absorbent filter medium by method；
Step 8, then centrifugation under centrifugal separator, vacuum rotary evaporator removes water, and 110 DEG C of vacuum drying oven is dried,
Last 550 DEG C of calcining 10h under sufficient air atmosphere in Muffle furnace, obtain absorbent filter medium Eu-KIT-1.
Reference examples 2 produces europium nitrate, the sample of sodium silicate mol ratio 1:11.0.01mol europium nitrate, 0.11mol sodium silicate, 0.1mol
Cetyl trimethylammonium bromide, 0.1mol sodium ethylene diamine tetracetate, the sodium hydroxide of 2mol/L, the nitric acid of 0.1mol/L,
300ml deionized water.
Step 1, first by sodium silicate and cetyl trimethylammonium bromide, sodium ethylene diamine tetracetate is under ultrasonic wave concussion
100 DEG C of oil bath ultrasonic 3h remove impurity;
Step 2, by 0.11mol sodium silicate, 0.1mol sodium ethylene diamine tetracetate and 0.1mol cetyl trimethylammonium bromide
Join 100 DEG C of 3h of normal agitation oil bath heating in 100ml deionized water;
Step 3, then through microwave treatment 2h;
Step 4, above-mentioned solution is poured in the reactor that politef is liner by drainage device, then reactor is put into
Cool down after 373 K constant temperature 24h in autoclave, with the sodium hydroxide of 2mol/L regulate the pH of mixture be 10.5～
11.0,2 crystallization of constant temperature；
Step 5, to take out after crystallization thing with the pH of distilled water cyclic washing to filtrate be 7, naturally dries, then at 813K, N2
Roasting 1 h in atmosphere, in air, roasting 6 h obtains NaKIT-1 powder body；
Step 6, the HNO3 solution of NaKIT-1 powder body 0.1mol/L is carried out pickling, control HNO3 solution and NaKIT-1 powder
The mass ratio of body is 10:1, room temperature normal agitation 0.5h, and vacuum pump filters, and the pH being washed with distilled water to filtrate is
At 7,110 DEG C, vacuum drying oven is dried and is prepared KIT-1 absorbent filter medium；
Step 7, by the remove impurity under ultrasonic wave concussion of 0.01mol europium nitrate, be then dissolved in 200ml deionized water, by leaching
Eu element is impregnated in KIT-1 absorbent filter medium by stain method；
Step 8, then centrifugation under centrifugal separator, vacuum rotary evaporator removes water, and 110 DEG C of vacuum drying oven is dried,
Last 550 DEG C of calcining 10h under sufficient air atmosphere in Muffle furnace, obtain absorbent filter medium Eu-KIT-1.
Reference examples 3 produces europium nitrate, the sample of sodium silicate mol ratio 1:11.0.01mol europium nitrate, 0.11mol sodium silicate, 0.1mol
Cetyl trimethylammonium bromide, 0.1mol sodium ethylene diamine tetracetate, the sodium hydroxide of 2mol/L, the nitric acid of 0.1mol/L,
300ml deionized water.
Step 1, first by sodium silicate and cetyl trimethylammonium bromide, sodium ethylene diamine tetracetate is under ultrasonic wave concussion
100 DEG C of oil bath ultrasonic 3h remove impurity;
Step 2, by 0.11mol sodium silicate, 0.1mol sodium ethylene diamine tetracetate and 0.1mol cetyl trimethylammonium bromide
Join 100 DEG C of 3h of magnetic agitation oil bath heating in 100ml deionized water;
Step 3, then through microwave treatment 2h;
Step 4, above-mentioned solution is poured in the reactor that politef is liner by drainage device, then reactor is put into
Cool down after 373 K constant temperature 24h in autoclave, with the sodium hydroxide of 2mol/L regulate the pH of mixture be 10.5～
11.0,2 crystallization of constant temperature；
Step 5, to take out after crystallization thing with the pH of distilled water cyclic washing to filtrate be 7, naturally dries, then at 813K, sky
Roasting 1 h in gas atmosphere, in air, roasting 6 h obtains NaKIT-1 powder body；
Step 6, the HNO3 solution of NaKIT-1 powder body 0.1mol/L is carried out pickling, control HNO3 solution and NaKIT-1 powder
The mass ratio of body is 10:1, room temperature magnetic agitation 0.5h, and vacuum pump filters, and the pH being washed with distilled water to filtrate is 7,110
At DEG C, vacuum drying oven is dried and is prepared KIT-1 absorbent filter medium；
Step 7, by the remove impurity under ultrasonic wave concussion of 0.01mol europium nitrate, be then dissolved in 200ml deionized water, by leaching
Eu element is impregnated in KIT-1 absorbent filter medium by stain method；
Step 8, then centrifugation under centrifugal separator, vacuum rotary evaporator removes water, and 110 DEG C of vacuum drying oven is dried,
Last 550 DEG C of calcining 10h under sufficient air atmosphere in Muffle furnace, obtain absorbent filter medium Eu-KIT-1.
Reference examples 4 is produced and is not added with the element modified sample of Eu.0.11mol sodium silicate, 0.1mol cetyl trimethylammonium bromide,
0.1mol
Sodium ethylene diamine tetracetate, the sodium hydroxide of 2mol/L, the nitric acid of 0.1mol/L, 300ml deionized water.
Step 1, first by sodium silicate and cetyl trimethylammonium bromide, sodium ethylene diamine tetracetate is under ultrasonic wave concussion
100 DEG C of oil bath ultrasonic 3h remove impurity;
Step 2, by 0.11mol sodium silicate, 0.1mol sodium ethylene diamine tetracetate and 0.1mol cetyl trimethylammonium bromide
Join 100 DEG C of 3h of magnetic agitation oil bath heating in 100ml deionized water;
Step 3, then through microwave treatment 2h;
Step 4, above-mentioned solution is poured in the reactor that politef is liner by drainage device, then reactor is put into
Cool down after 373 K constant temperature 24h in autoclave, with the sodium hydroxide of 2mol/L regulate the pH of mixture be 10.5～
11.0,2 crystallization of constant temperature；
Step 5, to take out after crystallization thing with the pH of distilled water cyclic washing to filtrate be 7, naturally dries, then at 813K, N2
Roasting 1 h in atmosphere, in air, roasting 6 h obtains NaKIT-1 powder body；
Step 6, the HNO3 solution of NaKIT-1 powder body 0.1mol/L is carried out pickling, control HNO3 solution and NaKIT-1 powder
The mass ratio of body is 10:1, room temperature magnetic agitation 0.5h, and vacuum pump filters, and the pH being washed with distilled water to filtrate is 7,110
At DEG C, vacuum drying oven is dried and is prepared KIT-1 absorbent filter medium.
Adsorption cleaning tap water effect assessment
The Eu-KIT-1 absorbent filter medium water tumbler of prepared various ratios is unified volume 500ml, by same faucet synchronization
The water taken fills each water tumbler, does not add absorbent filter medium doing one group of common water tumbler of blank experiment group.Stand 5min, then use
EDTA complexometry measures the calcium ions and magnesium ions content of drinking water, and this method is simple and efficient, accurately and reliably, it is adaptable to life is drunk
The detection of the calcium ions and magnesium ions of water.
The total hardness (mg/L in terms of CaCO3) of table one drinking water, national standard < 450mg/L.
Test result indicate that Eu-KIT-1 molecular sieve prepared by embodiment 7,8 adsorbs the calcium and magnesium in drinking water in water tumbler
Ion effect is best, and europium nitrate is described, sodium silicate mol ratio 1:11, the when of 1:12, and the acidity of molecular sieve under both ratios
Position high adsorption capacity, duct is narrower, and the synergism between each element is also best, can reach the hydraulic best to human body
Scale is accurate.But the Eu-KIT-1 molecular sieve prepared under other ratio has certain absorbability effect bad in water tumbler.
Comparative example 7, comparative example 1,2,3,4 it appeared that.Without ultrasonic wave concussion, magnetic agitation, nitrogen atmosphere calcines, or
It is added without prepared Eu-KIT-1, the KIT-1 molecular sieve of Eu element bad for water tumbler adsorption cleaning calcium ions and magnesium ions effect from the beginning.
Claims (4)
1. an anti-skidding filtering cup, including water tumbler body, described water tumbler body exterior has antiskid glue sleeve, water tumbler body
Rim of a cup goes out to be provided with filter box, and described filter cassette bottom portion is micro-strainer, has snap ring outside top edge, and the diameter of snap ring is more than
Rim of a cup internal diameter so that filter box can be fixed on the rim of a cup of water tumbler body, is provided with 3-6 card outside filter box lower edge；
It is threaded that filter box top is provided with filter lid, filter box top and filter lid, and filter box is built with filtrate.
The anti-skidding filtering cup of one the most according to claim 1, it is characterised in that described cup body bottom portion has outer spiral shell
Stricture of vagina, anti-skid base is provided with female thread, and anti-skid base is arranged on a glass body bottom portion.
The anti-skidding filtering cup of one the most according to claim 1, it is characterised in that described water tumbler body is also equipped with cup
Handle.
The anti-skidding filtering cup of one the most according to claim 1, it is characterised in that described filtrate is new E u-KIT-1
Absorbent filter medium, for water purification effect.
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Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN109925014A (en) * | 2019-04-03 | 2019-06-25 | 北京大学第三医院（北京大学第三临床医学院） | A kind of fat purifying plant |
| CN115569674A (en) * | 2022-09-29 | 2023-01-06 | 中国科学院地球环境研究所 | Ion exchange chromatographic column capable of being rapidly mounted and dismounted |
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| JP2003275084A (en) * | 2002-03-20 | 2003-09-30 | Kunio Yokoyama | Pitcher cup |
| CN201452604U (en) * | 2009-06-15 | 2010-05-12 | 王立平 | Water purifying cup |
| US20110278216A1 (en) * | 2008-03-18 | 2011-11-17 | Rubbermaid Inc. | Drinking Container and Filter Assembly |
| CN104665457A (en) * | 2014-12-20 | 2015-06-03 | 青岛格瑞特建筑安装工程有限公司 | Multifunctional antiskid cup |
| CN205072591U (en) * | 2015-09-14 | 2016-03-09 | 广州韩能大健康产品有限公司 | But drinking cup of mineralize mineralization drinking water |
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2016
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| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2003275084A (en) * | 2002-03-20 | 2003-09-30 | Kunio Yokoyama | Pitcher cup |
| US20110278216A1 (en) * | 2008-03-18 | 2011-11-17 | Rubbermaid Inc. | Drinking Container and Filter Assembly |
| CN201452604U (en) * | 2009-06-15 | 2010-05-12 | 王立平 | Water purifying cup |
| CN104665457A (en) * | 2014-12-20 | 2015-06-03 | 青岛格瑞特建筑安装工程有限公司 | Multifunctional antiskid cup |
| CN205072591U (en) * | 2015-09-14 | 2016-03-09 | 广州韩能大健康产品有限公司 | But drinking cup of mineralize mineralization drinking water |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN109925014A (en) * | 2019-04-03 | 2019-06-25 | 北京大学第三医院（北京大学第三临床医学院） | A kind of fat purifying plant |
| CN109925014B (en) * | 2019-04-03 | 2024-03-22 | 北京阿拉布丁生物科技有限公司 | Fat purification device |
| CN115569674A (en) * | 2022-09-29 | 2023-01-06 | 中国科学院地球环境研究所 | Ion exchange chromatographic column capable of being rapidly mounted and dismounted |
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