CN106723535A - A kind of preparation method of touch-screen dipped gloves - Google Patents

A kind of preparation method of touch-screen dipped gloves Download PDF

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Publication number
CN106723535A
CN106723535A CN201611105702.1A CN201611105702A CN106723535A CN 106723535 A CN106723535 A CN 106723535A CN 201611105702 A CN201611105702 A CN 201611105702A CN 106723535 A CN106723535 A CN 106723535A
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CN
China
Prior art keywords
gloves
touch
screen
preparation
conducting resinl
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201611105702.1A
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Chinese (zh)
Inventor
张晖
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Jiangyin Yi Hui Chemical Co Ltd
Original Assignee
Jiangyin Yi Hui Chemical Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Jiangyin Yi Hui Chemical Co Ltd filed Critical Jiangyin Yi Hui Chemical Co Ltd
Priority to CN201611105702.1A priority Critical patent/CN106723535A/en
Publication of CN106723535A publication Critical patent/CN106723535A/en
Pending legal-status Critical Current

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Classifications

    • AHUMAN NECESSITIES
    • A41WEARING APPAREL
    • A41DOUTERWEAR; PROTECTIVE GARMENTS; ACCESSORIES
    • A41D19/00Gloves
    • A41D19/015Protective gloves
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00Use of inorganic substances as compounding ingredients
    • C08K3/02Elements
    • C08K3/04Carbon
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00Use of inorganic substances as compounding ingredients
    • C08K3/18Oxygen-containing compounds, e.g. metal carbonyls
    • C08K3/20Oxides; Hydroxides
    • C08K3/22Oxides; Hydroxides of metals
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00Use of inorganic substances as compounding ingredients
    • C08K3/34Silicon-containing compounds
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K7/00Use of ingredients characterised by shape
    • C08K7/02Fibres or whiskers
    • C08K7/04Fibres or whiskers inorganic
    • C08K7/06Elements
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00Use of inorganic substances as compounding ingredients
    • C08K3/18Oxygen-containing compounds, e.g. metal carbonyls
    • C08K3/20Oxides; Hydroxides
    • C08K3/22Oxides; Hydroxides of metals
    • C08K2003/2237Oxides; Hydroxides of metals of titanium
    • C08K2003/2241Titanium dioxide
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K2201/00Specific properties of additives
    • C08K2201/001Conductive additives

Abstract

The invention discloses a kind of preparation method of touch-screen dipped gloves, the preparation method of the touch-screen dipped gloves:Comprise the following steps that:S1, will be soaked with the gloves core retainer plate of coagulator on fingerprint;S2, will be enclosed within the gloves immersion conducting resinl on fingerprint, make to form conducting resinl in glove surface;S3, the gloves to being soaked with conducting resinl are dried or air-dried.The present invention adds aqueous type Polyurethane material, environment friendly and pollution-free, and is one-shot forming, directly in process of production, adds conductive materials, overall gloves to have touch screen effect in itself, and production process is simple, long service life, low cost.

Description

A kind of preparation method of touch-screen dipped gloves
Technical field
The present invention relates to gloves preparing technical field, specially a kind of preparation method of touch-screen dipped gloves.
Background technology
Gloves are protected instrument and are widely used in live and work as hand.PU is impregnated by base material of gloves core (Polyurethane polyurethanes, abbreviation polyurethane)The safety protection glove of resin, so that its rubber shoe latex layer is relatively thin, Dai Yong Comfortably, with preferable grease proofing, anti-wear performance, low cost and other advantages, as staple product is obtained in the safety gloves of international market, closely Sales volume constantly rises over year.But this kind of PU dippings gloves are produced, dimethylformamide need to be used(DMF)As the production of solvent Technique, but DMF has toxicity higher, such as has DMF to remain in gloves, and skin can be stimulated after wearing;Meanwhile, in production It is middle because using DMF as solvent, will to enterprise employee health protection impact;After gloves scrap discarding, environment can also be made Into greatly pollution.Because PU dipping gloves have disadvantage mentioned above using DMF, European Union assert, is opened from May, 2009 Begin, prohibit the use of the product using DMF as solvent, including gloves product, this will bring huge to gloves plant produced, outlet Influence.China is limited in the ability of the recycling of discarded object, to even more limited in the rate of recovery of DMF, not only causes Pollutant emission, can not effectively reduce production cost.
File 1:Publication No. CN101849719A, publication date is the patent of invention Shen on October 6 in 2010 Please《Using the knitted and dipped PU (polyurethane) gloves production technology of methyl pyrrolidone》, it is replaced with methyl pyrrolidone in process of production For poisonous DMF;File 2:Publication No. CN101849717A, publication date is the hair on October 6 in 2010 Bright patent application《Using the knitted and dipped PU (polyurethane) gloves production technology of dimethyl sulfoxide (DMSO)》, it is sub- with dimethyl in process of production Sulfone instead of poisonous DMF;File 3:Publication No. CN101828780A, publication date is on September 15th, 2010 Application for a patent for invention《Aqueous PU foam gloves production technology》, it adds NBR in PU natural gum.
In above-mentioned three invention disclosed patent application documents, the technical scheme of file 1 is added in PU slurries Methyl pyrrolidone, alkyl is contained in methyl pyrrolidone molecule, has a taste of amine;There is stronger permeability, it is several recently It was put aside toxicity or had carcinogenic possibility through Europe and the U.S.'s recent studies on year.The technical scheme of file 2 is added in PU slurries Enter dimethyl sulfoxide (DMSO), dimethyl sulfoxide (DMSO) has the special nature of easily skin permeation as chemical substance, causes user of service to feel Feel the taste as oyster, and have stimulation to eyes.The technical scheme of file 3 be in PU slurries add be fourth Nitrile glue, NBR has stimulation to eyes and skin, and toxicity medium poison class can also be made containing this kind of material in gloves to personnel Polluted into harm and to environment.
We are often responded as the use of gloves equally can bring some inconvenience to our work in actual use, with The development of science and technology, the increasing equipment with touch screen displays is appeared in our industrial production, but we are past Toward that can find that the use after often our wear gloves to touch screen displays can make troubles, these are all that we need especially note The place of meaning.
The content of the invention
It is an object of the invention to provide a kind of preparation method of touch-screen dipped gloves, the touch-screen dipped gloves Preparation method:Comprise the following steps that:
S1, will be soaked with the gloves core retainer plate of coagulator on fingerprint;
S2, will be enclosed within the gloves immersion conducting resinl on fingerprint, make to form conducting resinl in glove surface;
S3, the gloves to being soaked with conducting resinl are dried or air-dried.
Preferably, the coagulator is one or more in calcium nitrate, aluminum sulfate and calcium chloride, also can be glacial acetic acid.
Preferably, the conducting resinl is that the aqueous type Polyurethane material proportionings of conducting medium 3-10% and 90-97% are formed, and Gloves core dipping temperature in conducting resinl is 5-50 DEG C, and the time is 0.1-30s.
Preferably, the conducting medium can be conductive black, conductive titanium dioxide, conductive carbon fibre, Graphene and conduction One kind in mica powder.
Preferably, there is the technique of foaming after the impregnation, the foam volume ratio before foaming and after foaming is 1:3 to 1:1.05。
Preferably, before baking, the gloves for forming conductive adhesive layer are washed.
Compared with prior art, the beneficial effects of the invention are as follows:The present invention adds aqueous type Polyurethane material, and environmental protection is without dirt Dye, and be one-shot forming, directly in process of production, add conductive materials, overall gloves that there is touch screen effect in itself, produce work Sequence is simple, long service life, low cost.
Specific embodiment
In order to make the purpose , technical scheme and advantage of the present invention be clearer, below in conjunction with specific embodiment, to this Invention is further elaborated.It should be appreciated that the specific embodiments described herein are merely illustrative of the present invention, not For limiting the present invention.
Embodiment 1
A kind of preparation method of touch-screen dipped gloves, the preparation method of the touch-screen dipped gloves:Comprise the following steps that:
S1, will be soaked with the gloves core retainer plate of coagulator on fingerprint;
S2, will be enclosed within the gloves immersion conducting resinl on fingerprint, make to form conducting resinl in glove surface;
S3, the gloves to being soaked with conducting resinl are dried or air-dried.
The coagulator is one or more in calcium nitrate, aluminum sulfate and calcium chloride, also can be glacial acetic acid.
The conducting resinl is that conducting medium 3 is formed with 97% aqueous type Polyurethane material proportioning, and gloves core is in conducting resinl Middle dipping temperature is 5 DEG C, and the time is 0.1s.
The conducting medium can be in conductive black, conductive titanium dioxide, conductive carbon fibre, Graphene and conductive mica powder One kind.
There is the technique of foaming after the impregnation, the foam volume ratio before foaming and after foaming is 1:3 to 1: 1.05。
Before baking, the gloves for forming conductive adhesive layer are washed.
Embodiment 2
A kind of preparation method of touch-screen dipped gloves, the preparation method of the touch-screen dipped gloves:Comprise the following steps that:
S1, will be soaked with the gloves core retainer plate of coagulator on fingerprint;
S2, will be enclosed within the gloves immersion conducting resinl on fingerprint, make to form conducting resinl in glove surface;
S3, the gloves to being soaked with conducting resinl are dried or air-dried.
The coagulator is one or more in calcium nitrate, aluminum sulfate and calcium chloride, also can be glacial acetic acid.
The conducting resinl is that conducting medium 7 is formed with 93% aqueous type Polyurethane material proportioning, and gloves core is in conducting resinl Middle dipping temperature is 25 DEG C, and the time is 15s.
The conducting medium can be in conductive black, conductive titanium dioxide, conductive carbon fibre, Graphene and conductive mica powder One kind.
There is the technique of foaming after the impregnation, the foam volume ratio before foaming and after foaming is 1:3 to 1: 1.05。
Preferably, before baking, the gloves for forming conductive adhesive layer are washed.
Embodiment 3
A kind of preparation method of touch-screen dipped gloves, the preparation method of the touch-screen dipped gloves:Comprise the following steps that:
S1, will be soaked with the gloves core retainer plate of coagulator on fingerprint;
S2, will be enclosed within the gloves immersion conducting resinl on fingerprint, make to form conducting resinl in glove surface;
S3, the gloves to being soaked with conducting resinl are dried or air-dried.
The coagulator is one or more in calcium nitrate, aluminum sulfate and calcium chloride, also can be glacial acetic acid.
The conducting resinl is that conducting medium 10% is formed with 90% aqueous type Polyurethane material proportioning, and gloves core is in conduction Dipping temperature is 50 DEG C in glue, and the time is 30s.
The conducting medium can be in conductive black, conductive titanium dioxide, conductive carbon fibre, Graphene and conductive mica powder One kind.
There is the technique of foaming after the impregnation, the foam volume ratio before foaming and after foaming is 1:3 to 1: 1.05。
Before baking, the gloves for forming conductive adhesive layer are washed.
The present invention adds aqueous type Polyurethane material, environment friendly and pollution-free, and is one-shot forming, directly in process of production, Add conductive materials, overall gloves has touch screen effect in itself, and production process is simple, long service life, low cost.
The above, the only present invention preferably specific embodiment, but protection scope of the present invention is not limited thereto, Any one skilled in the art the invention discloses technical scope in, technology according to the present invention scheme and its Inventive concept is subject to equivalent or change, should all be included within the scope of the present invention.

Claims (6)

1. a kind of preparation method of touch-screen dipped gloves, it is characterised in that:The preparation method of the touch-screen dipped gloves: Comprise the following steps that:
S1, will be soaked with the gloves core retainer plate of coagulator on fingerprint;
S2, will be enclosed within the gloves immersion conducting resinl on fingerprint, make to form conducting resinl in glove surface;
S3, the gloves to being soaked with conducting resinl are dried or air-dried.
2. the preparation method of a kind of touch-screen dipped gloves according to claim 1, it is characterised in that:The coagulator It is one or more in calcium nitrate, aluminum sulfate and calcium chloride, also can is glacial acetic acid.
3. the preparation method of a kind of touch-screen dipped gloves according to claim 1, it is characterised in that:The conducting resinl For conducting medium 3-10% and 90-97% resins proportioning is formed, and gloves core dipping temperature in conducting resinl is 5-50 DEG C, time It is 0.1-30s.
4. the preparation method of a kind of touch-screen dipped gloves according to claim 3, it is characterised in that:Conductive Jie Matter can be the one kind in conductive black, conductive titanium dioxide, conductive carbon fibre, Graphene and conductive mica powder.
5. the preparation method of a kind of touch-screen dipped gloves according to claim 1, it is characterised in that:After the impregnation The technique for also foaming, the foam volume ratio before foaming and after foaming is 1:3 to 1:1.05.
6. the preparation method of a kind of touch-screen dipped gloves according to claim 1, it is characterised in that:Before baking, Gloves to forming conductive adhesive layer are washed.
CN201611105702.1A 2016-12-05 2016-12-05 A kind of preparation method of touch-screen dipped gloves Pending CN106723535A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201611105702.1A CN106723535A (en) 2016-12-05 2016-12-05 A kind of preparation method of touch-screen dipped gloves

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201611105702.1A CN106723535A (en) 2016-12-05 2016-12-05 A kind of preparation method of touch-screen dipped gloves

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Publication Number Publication Date
CN106723535A true CN106723535A (en) 2017-05-31

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Cited By (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN107440199A (en) * 2017-09-07 2017-12-08 绵阳凤面科技有限公司 A kind of touch-screen dipped gloves and preparation method thereof
CN107772581A (en) * 2017-12-07 2018-03-09 遂宁市明川零贰零科技有限公司 A kind of touch-screen dipped gloves and preparation method thereof
CN108623858A (en) * 2018-05-17 2018-10-09 合肥科天水性科技有限责任公司 A kind of acid cure polymerizing preparation method of medical gloves
CN108783676A (en) * 2018-07-11 2018-11-13 山东登升安防科技有限公司 A kind of touch screen conduction dipped gloves and its preparation process
CN111395001A (en) * 2020-03-30 2020-07-10 联新(开平)高性能纤维有限公司 Conductive dipping solution, preparation method and application thereof, dipped cord and preparation method and application thereof
CN113498899A (en) * 2021-05-25 2021-10-15 鸿瀚防护科技南通有限公司 Conductive glove and preparation process thereof

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CN104562723A (en) * 2013-10-16 2015-04-29 禾欣可乐丽超纤皮(嘉兴)有限公司 Wet-process production method of polyurethane conductive superfine fiber suede leather

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CN101962875A (en) * 2010-08-20 2011-02-02 沈阳天荣电缆材料有限公司 Semi-conductive waterproof elastic nonwoven fabric and manufacturing method thereof
CN102981611A (en) * 2011-08-08 2013-03-20 福特全球技术公司 Glove having conductive ink and method of interacting with proximity sensor
CN102429331A (en) * 2011-10-16 2012-05-02 张晖 Manufacturing technique for aqueous PU (Polyurethane) glove
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Cited By (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN107440199A (en) * 2017-09-07 2017-12-08 绵阳凤面科技有限公司 A kind of touch-screen dipped gloves and preparation method thereof
CN107772581A (en) * 2017-12-07 2018-03-09 遂宁市明川零贰零科技有限公司 A kind of touch-screen dipped gloves and preparation method thereof
CN108623858A (en) * 2018-05-17 2018-10-09 合肥科天水性科技有限责任公司 A kind of acid cure polymerizing preparation method of medical gloves
CN108623858B (en) * 2018-05-17 2021-07-13 兰州科天健康科技股份有限公司 Acid coagulation preparation method of medical gloves
CN108783676A (en) * 2018-07-11 2018-11-13 山东登升安防科技有限公司 A kind of touch screen conduction dipped gloves and its preparation process
CN111395001A (en) * 2020-03-30 2020-07-10 联新(开平)高性能纤维有限公司 Conductive dipping solution, preparation method and application thereof, dipped cord and preparation method and application thereof
CN113498899A (en) * 2021-05-25 2021-10-15 鸿瀚防护科技南通有限公司 Conductive glove and preparation process thereof

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Application publication date: 20170531