CN106705108A - High-temperature flue gas oxygen-doped type oxygen-enriched combustion steam-injection boiler - Google Patents

High-temperature flue gas oxygen-doped type oxygen-enriched combustion steam-injection boiler Download PDF

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Publication number
CN106705108A
CN106705108A CN201611242748.8A CN201611242748A CN106705108A CN 106705108 A CN106705108 A CN 106705108A CN 201611242748 A CN201611242748 A CN 201611242748A CN 106705108 A CN106705108 A CN 106705108A
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CN
China
Prior art keywords
oxygen
flue gas
temperature flue
enriched
water
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Pending
Application number
CN201611242748.8A
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Chinese (zh)
Inventor
王春华
岳悦
潘颢丹
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Liaoning Shihua University
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Liaoning Shihua University
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Priority to CN201611242748.8A priority Critical patent/CN106705108A/en
Publication of CN106705108A publication Critical patent/CN106705108A/en
Pending legal-status Critical Current

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Classifications

    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F23COMBUSTION APPARATUS; COMBUSTION PROCESSES
    • F23LSUPPLYING AIR OR NON-COMBUSTIBLE LIQUIDS OR GASES TO COMBUSTION APPARATUS IN GENERAL ; VALVES OR DAMPERS SPECIALLY ADAPTED FOR CONTROLLING AIR SUPPLY OR DRAUGHT IN COMBUSTION APPARATUS; INDUCING DRAUGHT IN COMBUSTION APPARATUS; TOPS FOR CHIMNEYS OR VENTILATING SHAFTS; TERMINALS FOR FLUES
    • F23L7/00Supplying non-combustible liquids or gases, other than air, to the fire, e.g. oxygen, steam
    • F23L7/007Supplying oxygen or oxygen-enriched air
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F23COMBUSTION APPARATUS; COMBUSTION PROCESSES
    • F23LSUPPLYING AIR OR NON-COMBUSTIBLE LIQUIDS OR GASES TO COMBUSTION APPARATUS IN GENERAL ; VALVES OR DAMPERS SPECIALLY ADAPTED FOR CONTROLLING AIR SUPPLY OR DRAUGHT IN COMBUSTION APPARATUS; INDUCING DRAUGHT IN COMBUSTION APPARATUS; TOPS FOR CHIMNEYS OR VENTILATING SHAFTS; TERMINALS FOR FLUES
    • F23L7/00Supplying non-combustible liquids or gases, other than air, to the fire, e.g. oxygen, steam
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F23COMBUSTION APPARATUS; COMBUSTION PROCESSES
    • F23LSUPPLYING AIR OR NON-COMBUSTIBLE LIQUIDS OR GASES TO COMBUSTION APPARATUS IN GENERAL ; VALVES OR DAMPERS SPECIALLY ADAPTED FOR CONTROLLING AIR SUPPLY OR DRAUGHT IN COMBUSTION APPARATUS; INDUCING DRAUGHT IN COMBUSTION APPARATUS; TOPS FOR CHIMNEYS OR VENTILATING SHAFTS; TERMINALS FOR FLUES
    • F23L2900/00Special arrangements for supplying or treating air or oxidant for combustion; Injecting inert gas, water or steam into the combustion chamber
    • F23L2900/07001Injecting synthetic air, i.e. a combustion supporting mixture made of pure oxygen and an inert gas, e.g. nitrogen or recycled fumes
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02EREDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E20/00Combustion technologies with mitigation potential
    • Y02E20/32Direct CO2 mitigation
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02EREDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E20/00Combustion technologies with mitigation potential
    • Y02E20/34Indirect CO2mitigation, i.e. by acting on non CO2directly related matters of the process, e.g. pre-heating or heat recovery

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  • Engineering & Computer Science (AREA)
  • Chemical & Material Sciences (AREA)
  • Combustion & Propulsion (AREA)
  • Mechanical Engineering (AREA)
  • General Engineering & Computer Science (AREA)

Abstract

The invention relates to a high-temperature flue gas oxygen-doped type oxygen-enriched combustion steam-injection boiler. The steam-injection boiler comprises an oxygen-enriched generation device, a combustion improver matching and preheating device, a boiler body, a radiation section, a convection section, a water feeding pump, a water mixer, a steam-water separator, a collecting header and a burner. The oxygen-enriched generation device is connected with the combustion improver matching and preheating device. The radiation section is arranged in an inner cavity of the boiler body. The convection section is arranged on the outer side of the boiler body. The water mixer communicates with the water feeding pump, the convection section and the collecting header. The steam-water separator communicates with the radiation section and the collecting header. The burner communicates with the boiler body and a gas mixing tank. The oxygen-enriched generation device is used for producing pure oxygen, a circulating fan is introduced to pump high-temperature flue gas from the tail portion of the boiler, the pure oxygen and the high-temperature flue gas are directly mixed in the gas mixing tank into an oxygen-enriched combustion improver with the oxygen concentration being higher than the concentration (larger than 21%) of conventional air to be fed into the boiler for supporting combustion, and accordingly fuel burning efficiency can be improved and pollutant emission concentration can be lowered.

Description

High-temperature flue gas oxygen admixing type oxygen-enriched combusting injection boiler
Technical field
The present invention relates to a kind of thickened oil recovery high-temperature flue gas oxygen admixing type oxygen-enriched combusting injection boiler.
Background technology
Uphole steam generator is one of key equipment of thickened oil recovery.The injection boiler of operation is in order to improve boiler hot at present Efficiency, saves fuel, adopts various measures, and such as uses thermal insulation material, installs flue gas waste heat recovery apparatus additional, and fuel oil changes and combusts Gas, change burning mode etc., wherein energy-saving effect are significantly to use oxygen-enriched combustion technology, and fractional energy savings is more than 4%.Oxygen-enriched Under burning condition, flame temperature is raised, increased flame speeds, and complete combustibility is improved, the ignition temperature reduction of fuel, is burnt Time shortens, and excess air coefficient reduction, exhaust gas volumn is reduced;But its greatest problem for existing is NOxConcentration of emission is higher.This master If because:N in combustion adjuvant2Concentration reduction, causes thermal NOxGrowing amount reduction, but flame temperature raising and oxygen it is dense The raising of degree can but increase thermal NOxGrowing amount, and NOxGather way and be higher than NOxReduction speed, final NOxRow High-volume still increase.
Be conjointly employed in injection boiler for flue gas recirculation technology and oxygen-enriched combustion technology by imagination, will improve burning effect Really, Fuel Consumption is saved, NO is reducedxDischarge, reaches the dual purpose that oilfield enterprise increases economic efficiency with energy-conserving and environment-protective.Cause This, the technical barrier for solving is thirsted for as this area always.
The content of the invention
Present invention solves the technical problem that being to provide a kind of thickened oil recovery high-temperature flue gas oxygen admixing type oxygen-enriched combusting steam injection pot Stove, the injection boiler can greatly improve boiler thermal output, and energy saving reduces NOxConcentration of emission.
The purpose of the present invention is achieved through the following technical solutions:
High-temperature flue gas oxygen admixing type oxygen-enriched combusting injection boiler, including oxygen-enriched generating means, combustion adjuvant proportioning and preheating device, stove Body, radiant section, convection section, feed pump, water-water jet, steam-water separator, collection header and burner;Described oxygen-enriched generating means and Combustion adjuvant proportioning is connected with preheating device;Radiant section is arranged on body of heater inner chamber;Convection section is arranged on body of heater outside;Water-water jet is connected Feed pump, convection section and collection header, steam-water separator connection radiant section and collection header, burner connection body of heater and mixed gas tank.
Described oxygen-enriched generating means is sequentially connected and is constituted by air blower, membrane type oxygen-enriched generator and pure oxygen storage tank.
Described combustion adjuvant proportioning is made up of with preheating device flue gas recirculation pipeline, mixed gas tank, circulating fan, mixes gas tank and leads to Cross flue gas recirculation pipeline communication circulating fan.
Described combustion adjuvant proportioning is high-temperature flue gas and the gaseous mixture of oxygen with the combustion adjuvant in preheating device.
Oxygen concentration in described combustion adjuvant is controlled in 25%-40%.
Described convection section, steam-water separator and collection header are arranged in body of heater outside.
Described collection header is connected with blowoff valve.
Between described collection header and water-water jet check-valves is provided with saturation waterpipe VI.
The advantage of the invention is that:Extract a part of high-temperature flue gas of injection boiler afterbody(Flue-gas temperature is up to 1000 DEG C)With Pure oxygen is mixed to form high-temperature oxygen-enriched combustion adjuvant, forms high-temperature oxygen-enriched combustion technology, is applied on injection boiler.High-temperature flue gas Repeatedly after circulation, formed and be rich in CO2High-temperature flue gas.Quote and be rich in CO2High-temperature flue gas circulating technology overcomes oxygen-enriched combusting mode band The NO high for comingxThe problem of concentration of emission, fuel availability than conventional injection boiler improve more than 15%, steam generating capacity improve 10% with On, NO in flue gasxConcentration of emission reduce more than 50%.Using can be with variation, whether exotic fuels be also for fuel simultaneously It is low calorie fuels, whether liquid fuel, gaseous fuel or solid fuel can apply this device.
Brief description of the drawings
Fig. 1 is the schematic diagram of high-temperature flue gas oxygen admixing type oxygen-enriched combusting injection boiler.
In figure:1 is air blower, and 2 is membrane type oxygen-enriched generator, and 3 is oxygen container, and 4 is mixed gas tank, and 5 is burner, and 6 is spoke Section is penetrated, 7 is circulating fan, and 8 is convection section, and 9 is water-water jet, and 10 is feed pump, and 11 is steam-water separator, and 12 is collection header, 13 It is blowoff valve, 14 is check-valves, and 15 is pipeline I, and 16 is pipeline II, and 17 is pipeline III, and 18 is Fuel inlet pipe, and 19 is cigarette Gas circulating line, 20 is low-temperature flue gas discharge line, and 21 is treated softening deaerated water with pressure, and 22 is pipeline IV, and 23 are Pipeline V, 24 export for saturated vapor, and 25 is pipeline VI.
Specific embodiment
The present invention is described in further detail below in conjunction with the accompanying drawings.
Embodiment
As shown in figure 1, high-temperature flue gas oxygen admixing type oxygen-enriched combusting injection boiler of the present invention includes oxygen-enriched generating means, combustion adjuvant Proportioning and preheating device, body of heater, radiant section, convection section, feed pump 10, water-water jet 9, steam-water separator 11, collection header 12 and combustion Burner 5.Oxygen-enriched generating means is sequentially connected and is constituted by air blower 1, membrane type oxygen-enriched generator 2, pure oxygen storage tank 3;Combustion adjuvant is matched It is made up of flue gas recirculation pipeline 19, mixed gas tank 4, circulating fan 7 with preheating device, mixed gas tank is followed by flue gas recirculation pipeline communication Ring blower fan;Radiant section 6 is arranged on body of heater inner chamber;Convection section 8 is arranged on body of heater outside;Water-water jet 9 respectively with feed pump 10, convection current Section 8 and collection header 12 connect, steam-water separator 11 respectively with radiant section 6 and collection header 12 connect, burner 5 respectively with body of heater and Mixed gas tank 4 is connected.
Described combustion adjuvant proportioning is high-temperature flue gas and the gaseous mixture of oxygen with the combustion adjuvant in preheating device;Oxygen concentration Control is in 25%-40%.
Described convection section 8, steam-water separator 11 and collection header 12 are arranged in body of heater outside;Described collection header is connected with Blowoff valve 13;Check-valves 14 is provided between described collection header and water-water jet on saturation waterpipe VI.
The Water flow-path of boiler is:It is treated it is with pressure softening deaerated water 21 by feed pump 10 boosting after, into mixed water Device 9, the convection section 8 of the boiler is entered by pipeline IV 22, is heated to be high-temperature water, is entered back into radiant section 6 and is heated as Saturation moist steam, saturation moist steam carries out steam-water separation by pipeline V 23 through steam-water separator 11, and saturated vapor is by carbonated drink point Saturated vapor outlet 24 from the top of device 11 is flowed out, and is injected underground by corresponding pipeline and is recovered the oil;Isolated by steam-water separator 11 Saturation water flowed out by the bottom saturation water outlet end of steam-water separator 11, set associative is entered by the top saturation water arrival end of collection header 12 Case 12, saturation water is flowed out by the saturation water outlet end of collection header 12, enters water-water jet 9 to the saturation water arrival end of water-water jet 9, with boiler Feedwater mixing, improves boiler feed temperature;Collection header 12 bottom blow-down mouthful setting blowoff valve 13, when inorganic salts reach it is certain dense Blowdown is carried out when spending;Check-valves 14 is set between collection header 12 and water-water jet 9 on saturation waterpipe VI 25, prevents saturation water from falling Stream.
The flue gas flow of boiler is:After flue gas passes sequentially through the radiant section 6 of the boiler, a part of high-temperature flue gas are via following Ring blower fan 7 flows into mixed gas tank 4 by flue gas recirculation pipeline 19 after being pressurized by the mixed smoke inlet end of gas tank 4;Remainder high temperature cigarette Gas enters air after carrying out fume treatment by the discharge of low-temperature flue gas discharge line 20 via boiler convection section 8;Flue gas recirculation amount by Adjustable circulating fan regulation, is adjusted according to oxygen concentration in combustion adjuvant.
The combustion adjuvant flow of boiler:Outside air is entered after air blower 1 is pressurized by the arrival end of membrane type oxygen-enriched generator 2 Enter membrane type oxygen-enriched generator 2 and produce pure oxygen, pure oxygen enters pure oxygen storage tank by the port of export flow ipe II16 of membrane type oxygen-enriched generator 2 3, with flue gas recirculation pipeline 19 flow into high-temperature flue gas carry out being mixed to form high-temperature oxygen-enriched combustion adjuvant, oxygen concentration in 25%-40%, Finally by burner 5 and fuel mixed combustion in body of heater.
Be combined together for flue gas recirculation technology and oxygen-enriched combustion technology by the present invention, forms high-temperature oxygen-enriched burning, pure oxygen by Membrane type oxygen-enriched generator is produced, and is directly mixed into higher than oxygen concentration in regular air using high-temperature flue gas and pure oxygen(>21%)'s Burner is sent into after high-temperature oxygen-enriched combustion adjuvant, mixed combustion is carried out with fuel, realize high-temperature oxygen-enriched burning.It is right that the technology can be realized Without interruption high-temperature oxygen-enriched combustion adjuvant in injection boiler, it is ensured that the stability of furnace flame, flue gas is formed after repeatedly circulating Rich in CO2High-temperature flue gas, solve the NO high that high-temperature oxygen-enriched combustion technology is broughtxConcentration of emission problem.Meanwhile, water-water jet reality The saturation water now isolated by steam-water separator mixes with the direct of boiler feedwater, improves the temperature of boiler feedwater.
The present invention is square with section, and the length of side is 230 mm, and the vertical furnace chamber of 1000 mm high is experimental furnace, and fuel is Natural gas carries out research and shows:During conventional flue gas recirculation, the CO in stove in circulation flue gas2Increase with vapor share, N2 Share reduction;It is pure CO in initial cycle2When, CO in stove2Share reduction, vapor and N2Share increases;Flue gas recirculation 10 times with When upper, various component shares tend to a stationary value in both flue gases, and the share of both same compositions is of substantially equal, only nitrogen There is deviation in content;This also causes both in NOxDifference in concentration.As a example by when oxygen concentration 25%, followed using two kinds of flue gases After ring, the former is NOxConcentration ratio the latter reduces by 10% or so less.It follows which kind of endless form no matter used, flue gas will be into It is rich in CO2High-temperature flue gas, NO is most greatly reduced at lastxConcentration of emission.Therefore oxygen-enriched combustion can be solved with flue gas recirculation technology The NO high that burning is broughtxEmission problem.
The above is specific embodiment of the invention and the know-why used, any based on technical solution of the present invention On the basis of equivalent transformation, belong within protection scope of the present invention.

Claims (8)

1. high-temperature flue gas oxygen admixing type oxygen-enriched combusting injection boiler, it is characterised in that including oxygen-enriched generating means, combustion adjuvant proportioning with Preheating device, body of heater, radiant section, convection section, feed pump, water-water jet, steam-water separator, collection header and burner;Described richness Oxygengenerating plant and combustion adjuvant proportioning are connected with preheating device;Radiant section is arranged on body of heater inner chamber;Convection section is arranged on outside body of heater Side;Water-water jet connection feed pump, convection section and collection header, steam-water separator connection radiant section and collection header, burner connection stove Body and mixed gas tank.
2. high-temperature flue gas oxygen admixing type oxygen-enriched combusting injection boiler according to claim 1, it is characterised in that described is oxygen-enriched Generating means is sequentially connected and is constituted by air blower, membrane type oxygen-enriched generator and pure oxygen storage tank.
3. high-temperature flue gas oxygen admixing type oxygen-enriched combusting injection boiler according to claim 1, it is characterised in that described is combustion-supporting Agent proportioning is made up of with preheating device flue gas recirculation pipeline, mixed gas tank, circulating fan, mixes gas tank and passes through flue gas recirculation pipeline communication Circulating fan.
4. high-temperature flue gas oxygen admixing type oxygen-enriched combusting injection boiler according to claim 1, it is characterised in that described is combustion-supporting Agent proportioning is high-temperature flue gas and the gaseous mixture of oxygen with the combustion adjuvant in preheating device.
5. high-temperature flue gas oxygen admixing type oxygen-enriched combusting injection boiler according to claim 4, it is characterised in that described is combustion-supporting Oxygen concentration in agent is controlled in 25%-40%.
6. high-temperature flue gas oxygen admixing type oxygen-enriched combusting injection boiler according to claim 1, it is characterised in that described convection current Section, steam-water separator and collection header are arranged in body of heater outside.
7. high-temperature flue gas oxygen admixing type oxygen-enriched combusting injection boiler according to claim 1, it is characterised in that described set associative Case is connected with blowoff valve.
8. high-temperature flue gas oxygen admixing type oxygen-enriched combusting injection boiler according to claim 1, it is characterised in that described set associative Between case and water-water jet check-valves is provided with saturation waterpipe VI.
CN201611242748.8A 2016-12-29 2016-12-29 High-temperature flue gas oxygen-doped type oxygen-enriched combustion steam-injection boiler Pending CN106705108A (en)

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CN201611242748.8A CN106705108A (en) 2016-12-29 2016-12-29 High-temperature flue gas oxygen-doped type oxygen-enriched combustion steam-injection boiler

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN113803739A (en) * 2020-06-15 2021-12-17 中国石油化工股份有限公司 Fuel low-nitrogen combustion system for steam injection boiler

Citations (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101343989A (en) * 2008-08-22 2009-01-14 新疆石油管理局机械制造总公司 High-dryness oil field steam-injection boiler and high-dryness steam production method
JP2011141075A (en) * 2010-01-07 2011-07-21 Babcock Hitachi Kk Oxygen combustion power-generating plant and method of operating the same
CN102431974A (en) * 2011-09-23 2012-05-02 山东大学 Oxygen-enriched combustion poly-generation process and equipment for steam injection boiler in oil field
CN102635852A (en) * 2012-05-02 2012-08-15 中国科学院工程热物理研究所 Fuel oil/gas boiler for reducing emission of nitric oxides and method
CN104266175A (en) * 2014-09-30 2015-01-07 张宏伟 Superheating boiler superheating steam desalting device for oil field steam injection and utilization method thereof
CN105222123A (en) * 2015-11-10 2016-01-06 辽宁石油化工大学 A kind of high-temperature oxygen-enriched formula overheat steam injection boiler
CN105423333A (en) * 2015-11-10 2016-03-23 辽宁石油化工大学 High-temperature oxygen-enrichment type steam-injection boiler

Patent Citations (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101343989A (en) * 2008-08-22 2009-01-14 新疆石油管理局机械制造总公司 High-dryness oil field steam-injection boiler and high-dryness steam production method
JP2011141075A (en) * 2010-01-07 2011-07-21 Babcock Hitachi Kk Oxygen combustion power-generating plant and method of operating the same
CN102431974A (en) * 2011-09-23 2012-05-02 山东大学 Oxygen-enriched combustion poly-generation process and equipment for steam injection boiler in oil field
CN102635852A (en) * 2012-05-02 2012-08-15 中国科学院工程热物理研究所 Fuel oil/gas boiler for reducing emission of nitric oxides and method
CN104266175A (en) * 2014-09-30 2015-01-07 张宏伟 Superheating boiler superheating steam desalting device for oil field steam injection and utilization method thereof
CN105222123A (en) * 2015-11-10 2016-01-06 辽宁石油化工大学 A kind of high-temperature oxygen-enriched formula overheat steam injection boiler
CN105423333A (en) * 2015-11-10 2016-03-23 辽宁石油化工大学 High-temperature oxygen-enrichment type steam-injection boiler

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN113803739A (en) * 2020-06-15 2021-12-17 中国石油化工股份有限公司 Fuel low-nitrogen combustion system for steam injection boiler

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