CN106701172B - 一种渣油加氢处理方法 - Google Patents
一种渣油加氢处理方法 Download PDFInfo
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- CN106701172B CN106701172B CN201510769160.7A CN201510769160A CN106701172B CN 106701172 B CN106701172 B CN 106701172B CN 201510769160 A CN201510769160 A CN 201510769160A CN 106701172 B CN106701172 B CN 106701172B
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- 238000000034 method Methods 0.000 title claims abstract description 88
- 238000006243 chemical reaction Methods 0.000 claims abstract description 149
- 229910052739 hydrogen Inorganic materials 0.000 claims abstract description 45
- 239000001257 hydrogen Substances 0.000 claims abstract description 45
- 239000002994 raw material Substances 0.000 claims abstract description 35
- 238000013461 design Methods 0.000 claims abstract description 25
- 239000003054 catalyst Substances 0.000 claims description 73
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims description 44
- 238000011068 loading method Methods 0.000 claims description 26
- 229910052751 metal Inorganic materials 0.000 claims description 11
- 239000002184 metal Substances 0.000 claims description 11
- 238000012856 packing Methods 0.000 claims description 10
- 239000000463 material Substances 0.000 claims description 8
- 238000002203 pretreatment Methods 0.000 claims description 4
- WURBVZBTWMNKQT-UHFFFAOYSA-N 1-(4-chlorophenoxy)-3,3-dimethyl-1-(1,2,4-triazol-1-yl)butan-2-one Chemical compound C1=NC=NN1C(C(=O)C(C)(C)C)OC1=CC=C(Cl)C=C1 WURBVZBTWMNKQT-UHFFFAOYSA-N 0.000 claims description 3
- 230000006837 decompression Effects 0.000 claims description 3
- 239000007789 gas Substances 0.000 claims description 3
- 239000002893 slag Substances 0.000 claims description 2
- 239000012530 fluid Substances 0.000 claims 4
- 125000004435 hydrogen atom Chemical class [H]* 0.000 abstract 1
- 230000006641 stabilisation Effects 0.000 abstract 1
- 238000011105 stabilization Methods 0.000 abstract 1
- 239000003921 oil Substances 0.000 description 40
- 238000005984 hydrogenation reaction Methods 0.000 description 27
- 230000000052 comparative effect Effects 0.000 description 26
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical group [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 10
- 230000000694 effects Effects 0.000 description 8
- 238000005516 engineering process Methods 0.000 description 8
- 230000001965 increasing effect Effects 0.000 description 8
- 238000004517 catalytic hydrocracking Methods 0.000 description 7
- 239000000047 product Substances 0.000 description 7
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 6
- 238000006477 desulfuration reaction Methods 0.000 description 6
- 230000023556 desulfurization Effects 0.000 description 6
- 239000000295 fuel oil Substances 0.000 description 5
- 239000003223 protective agent Substances 0.000 description 5
- 239000012535 impurity Substances 0.000 description 4
- 238000004519 manufacturing process Methods 0.000 description 4
- 238000012545 processing Methods 0.000 description 4
- PNEYBMLMFCGWSK-UHFFFAOYSA-N Alumina Chemical compound [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 description 3
- 239000003795 chemical substances by application Substances 0.000 description 3
- 238000009826 distribution Methods 0.000 description 3
- 229910052757 nitrogen Inorganic materials 0.000 description 3
- 238000002407 reforming Methods 0.000 description 3
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 2
- 239000011575 calcium Substances 0.000 description 2
- 239000000084 colloidal system Substances 0.000 description 2
- 238000007324 demetalation reaction Methods 0.000 description 2
- 238000011156 evaluation Methods 0.000 description 2
- 229910000765 intermetallic Inorganic materials 0.000 description 2
- 239000007788 liquid Substances 0.000 description 2
- 238000005457 optimization Methods 0.000 description 2
- 239000002699 waste material Substances 0.000 description 2
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 description 1
- MKYBYDHXWVHEJW-UHFFFAOYSA-N N-[1-oxo-1-(2,4,6,7-tetrahydrotriazolo[4,5-c]pyridin-5-yl)propan-2-yl]-2-[[3-(trifluoromethoxy)phenyl]methylamino]pyrimidine-5-carboxamide Chemical compound O=C(C(C)NC(=O)C=1C=NC(=NC=1)NCC1=CC(=CC=C1)OC(F)(F)F)N1CC2=C(CC1)NN=N2 MKYBYDHXWVHEJW-UHFFFAOYSA-N 0.000 description 1
- 239000005864 Sulphur Substances 0.000 description 1
- 239000010426 asphalt Substances 0.000 description 1
- 239000012752 auxiliary agent Substances 0.000 description 1
- 230000033228 biological regulation Effects 0.000 description 1
- 229910052791 calcium Inorganic materials 0.000 description 1
- 229910052799 carbon Inorganic materials 0.000 description 1
- 239000007795 chemical reaction product Substances 0.000 description 1
- 239000003245 coal Substances 0.000 description 1
- 238000005336 cracking Methods 0.000 description 1
- 239000010779 crude oil Substances 0.000 description 1
- 230000007812 deficiency Effects 0.000 description 1
- 230000003111 delayed effect Effects 0.000 description 1
- 230000008021 deposition Effects 0.000 description 1
- 239000002283 diesel fuel Substances 0.000 description 1
- 239000002552 dosage form Substances 0.000 description 1
- 230000002708 enhancing effect Effects 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- ZZUFCTLCJUWOSV-UHFFFAOYSA-N furosemide Chemical compound C1=C(Cl)C(S(=O)(=O)N)=CC(C(O)=O)=C1NCC1=CC=CO1 ZZUFCTLCJUWOSV-UHFFFAOYSA-N 0.000 description 1
- 239000010763 heavy fuel oil Substances 0.000 description 1
- 230000002779 inactivation Effects 0.000 description 1
- 229910052809 inorganic oxide Inorganic materials 0.000 description 1
- 239000012263 liquid product Substances 0.000 description 1
- 230000007774 longterm Effects 0.000 description 1
- 229910052976 metal sulfide Inorganic materials 0.000 description 1
- 229910021404 metallic carbon Inorganic materials 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 229910052750 molybdenum Inorganic materials 0.000 description 1
- 229910052759 nickel Inorganic materials 0.000 description 1
- 229910052698 phosphorus Inorganic materials 0.000 description 1
- 238000007781 pre-processing Methods 0.000 description 1
- 238000007670 refining Methods 0.000 description 1
- 229910052717 sulfur Inorganic materials 0.000 description 1
- 239000011593 sulfur Substances 0.000 description 1
- 229910052721 tungsten Inorganic materials 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G65/00—Treatment of hydrocarbon oils by two or more hydrotreatment processes only
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G65/00—Treatment of hydrocarbon oils by two or more hydrotreatment processes only
- C10G65/02—Treatment of hydrocarbon oils by two or more hydrotreatment processes only plural serial stages only
- C10G65/04—Treatment of hydrocarbon oils by two or more hydrotreatment processes only plural serial stages only including only refining steps
- C10G65/08—Treatment of hydrocarbon oils by two or more hydrotreatment processes only plural serial stages only including only refining steps at least one step being a hydrogenation of the aromatic hydrocarbons
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G45/00—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds
- C10G45/72—Controlling or regulating
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G2300/00—Aspects relating to hydrocarbon processing covered by groups C10G1/00 - C10G99/00
- C10G2300/10—Feedstock materials
- C10G2300/1003—Waste materials
- C10G2300/1007—Used oils
Landscapes
- Chemical & Material Sciences (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)
Priority Applications (10)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201510769160.7A CN106701172B (zh) | 2015-11-12 | 2015-11-12 | 一种渣油加氢处理方法 |
| EP16863564.7A EP3375847B1 (fr) | 2015-11-12 | 2016-11-01 | Système de traitement d'hydrogénation de pétrole lourd et procédé de traitement d'hydrogénation de pétrole lourd |
| US15/775,694 US11001768B2 (en) | 2015-11-12 | 2016-11-01 | Heavy oil hydrotreating system and heavy oil hydrotreating method |
| RU2018119500A RU2685266C1 (ru) | 2015-11-12 | 2016-11-01 | Система гидроочистки тяжелой нефти и способ гидроочистки тяжелой нефти |
| PCT/CN2016/104206 WO2017080387A1 (fr) | 2015-11-12 | 2016-11-01 | Système de traitement d'hydrogénation de pétrole lourd et procédé de traitement d'hydrogénation de pétrole lourd |
| DK16863564.7T DK3375847T3 (da) | 2015-11-12 | 2016-11-01 | Tungoliehydrering-behandlingssystem og tungoliehydrering-behandlingsfremgangsmåde |
| KR1020187016757A KR102097650B1 (ko) | 2015-11-12 | 2016-11-01 | 중유 수소처리 시스템 및 중유 수소처리 방법 |
| SG11201804018XA SG11201804018XA (en) | 2015-11-12 | 2016-11-01 | Heavy Oil Hydrotreating System and Heavy Oil Hydrotreating Method |
| CA3005154A CA3005154C (fr) | 2015-11-12 | 2016-11-01 | Systeme de traitement d'hydrogenation de petrole lourd et procede de traitement d'hydrogenation de petrole lourd |
| TW105135887A TWI700362B (zh) | 2015-11-12 | 2016-11-04 | 一種重油加氫處理系統和重油加氫處理方法 |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201510769160.7A CN106701172B (zh) | 2015-11-12 | 2015-11-12 | 一种渣油加氢处理方法 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN106701172A CN106701172A (zh) | 2017-05-24 |
| CN106701172B true CN106701172B (zh) | 2018-06-12 |
Family
ID=58694468
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201510769160.7A Active CN106701172B (zh) | 2015-11-12 | 2015-11-12 | 一种渣油加氢处理方法 |
Country Status (10)
| Country | Link |
|---|---|
| US (1) | US11001768B2 (fr) |
| EP (1) | EP3375847B1 (fr) |
| KR (1) | KR102097650B1 (fr) |
| CN (1) | CN106701172B (fr) |
| CA (1) | CA3005154C (fr) |
| DK (1) | DK3375847T3 (fr) |
| RU (1) | RU2685266C1 (fr) |
| SG (1) | SG11201804018XA (fr) |
| TW (1) | TWI700362B (fr) |
| WO (1) | WO2017080387A1 (fr) |
Families Citing this family (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US20190233741A1 (en) | 2017-02-12 | 2019-08-01 | Magēmā Technology, LLC | Multi-Stage Process and Device for Reducing Environmental Contaminates in Heavy Marine Fuel Oil |
| US11788017B2 (en) | 2017-02-12 | 2023-10-17 | Magëmã Technology LLC | Multi-stage process and device for reducing environmental contaminants in heavy marine fuel oil |
| US10604709B2 (en) | 2017-02-12 | 2020-03-31 | Magēmā Technology LLC | Multi-stage device and process for production of a low sulfur heavy marine fuel oil from distressed heavy fuel oil materials |
| CN112391199B (zh) * | 2019-08-13 | 2022-09-27 | 中国石油化工股份有限公司 | 一种渣油加氢装置和一种渣油加氢的方法 |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US6447671B1 (en) * | 1999-03-25 | 2002-09-10 | Institut Francais Du Petrole | Process for converting heavy petroleum fractions, comprising an ebullated bed hydroconversion step and a hydrotreatment step |
| CN102311786A (zh) * | 2010-07-07 | 2012-01-11 | 中国石油化工股份有限公司 | 一种延长装置运转周期的渣油加氢处理方法 |
| CN102676218A (zh) * | 2011-03-16 | 2012-09-19 | 中国石油化工股份有限公司 | 一种固定床渣油加氢工艺 |
| US8696888B2 (en) * | 2005-10-20 | 2014-04-15 | Exxonmobil Chemical Patents Inc. | Hydrocarbon resid processing |
Family Cites Families (20)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3972686A (en) * | 1974-01-31 | 1976-08-03 | Universal Oil Products Company | Device for loading catalyst particles into a reaction zone |
| US4017382A (en) * | 1975-11-17 | 1977-04-12 | Gulf Research & Development Company | Hydrodesulfurization process with upstaged reactor zones |
| US5472928A (en) | 1989-07-19 | 1995-12-05 | Scheuerman; Georgieanna L. | Catalyst, method and apparatus for an on-stream particle replacement system for countercurrent contact of a gas and liquid feed stream with a packed bed |
| CA2168339A1 (fr) * | 1994-04-29 | 1995-11-09 | Robert W. Bachtel | Catalyseur, procede et appareil destine a un systeme de remplacement de particules assurant un contact a contre-courant entre une charge et un lit garni |
| WO1996017903A1 (fr) * | 1994-11-25 | 1996-06-13 | Kvaerner Process Technology Ltd | Procede d'hydrodesulfuration en plusieurs etapes |
| FR2784687B1 (fr) * | 1998-10-14 | 2000-11-17 | Inst Francais Du Petrole | Procede d'hydrotraitement d'une fraction lourde d'hydrocarbures avec reacteurs permutables et introduction d'un distillat moyen |
| BR0017384B1 (pt) * | 2000-12-11 | 2011-04-05 | processo de hidrotratamento de uma fração pesada de hidrocarbonetos com reatores permutáveis e reatores curto-circuitáveis. | |
| CN1144860C (zh) | 2001-07-02 | 2004-04-07 | 中国石油化工股份有限公司 | 一种渣油加氢处理方法 |
| WO2009073436A2 (fr) * | 2007-11-28 | 2009-06-11 | Saudi Arabian Oil Company | Processus d'hydrotraitement catalytique des pétroles bruts sulfureux |
| CN101768468B (zh) | 2008-12-31 | 2013-11-06 | 中国石油化工股份有限公司 | 一种渣油的加氢方法 |
| US8529754B2 (en) * | 2009-09-28 | 2013-09-10 | China Petroleum & Chemical Corporation | Catalytic conversion process for producing more diesel and propylene |
| CN102041065B (zh) * | 2009-10-21 | 2014-07-23 | 中国石油化工股份有限公司 | 一种焦化馏分油加氢处理方法 |
| CN102041095B (zh) | 2009-10-21 | 2013-11-06 | 中国石油化工股份有限公司 | 渣油加氢处理和催化裂化组合加工方法 |
| CN102453530B (zh) * | 2010-10-26 | 2015-05-20 | 中国石油化工股份有限公司 | 一种加工重质油品的加氢方法 |
| FR2970261B1 (fr) * | 2011-01-10 | 2013-05-03 | IFP Energies Nouvelles | Procede d'hydrotraitement de charges lourdes d'hydrocarbures avec des reacteurs permutables incluant au moins une etape de permutation progressive |
| FR2981659B1 (fr) * | 2011-10-20 | 2013-11-01 | Ifp Energies Now | Procede de conversion de charges petrolieres comprenant une etape d'hydroconversion en lit bouillonnant et une etape d'hydrotraitement en lit fixe pour la production de fiouls a basse teneur en soufre |
| CN103059931B (zh) | 2011-10-21 | 2014-12-31 | 中国石油化工股份有限公司 | 一种渣油加氢处理方法 |
| CN103059928B (zh) | 2011-10-24 | 2014-12-31 | 中国石油化工股份有限公司 | 一种加氢处理装置及其应用和渣油加氢处理方法 |
| CN103540349B (zh) | 2012-07-12 | 2016-02-10 | 中国石油天然气股份有限公司 | 一种延长催化剂使用寿命的劣质重油、渣油加氢处理组合工艺 |
| CN104119954B (zh) | 2013-04-23 | 2016-04-27 | 中国石油化工股份有限公司 | 一种重质原料油的处理方法 |
-
2015
- 2015-11-12 CN CN201510769160.7A patent/CN106701172B/zh active Active
-
2016
- 2016-11-01 SG SG11201804018XA patent/SG11201804018XA/en unknown
- 2016-11-01 CA CA3005154A patent/CA3005154C/fr active Active
- 2016-11-01 US US15/775,694 patent/US11001768B2/en active Active
- 2016-11-01 RU RU2018119500A patent/RU2685266C1/ru active
- 2016-11-01 WO PCT/CN2016/104206 patent/WO2017080387A1/fr active Application Filing
- 2016-11-01 DK DK16863564.7T patent/DK3375847T3/da active
- 2016-11-01 KR KR1020187016757A patent/KR102097650B1/ko active IP Right Grant
- 2016-11-01 EP EP16863564.7A patent/EP3375847B1/fr active Active
- 2016-11-04 TW TW105135887A patent/TWI700362B/zh active
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US6447671B1 (en) * | 1999-03-25 | 2002-09-10 | Institut Francais Du Petrole | Process for converting heavy petroleum fractions, comprising an ebullated bed hydroconversion step and a hydrotreatment step |
| US8696888B2 (en) * | 2005-10-20 | 2014-04-15 | Exxonmobil Chemical Patents Inc. | Hydrocarbon resid processing |
| CN102311786A (zh) * | 2010-07-07 | 2012-01-11 | 中国石油化工股份有限公司 | 一种延长装置运转周期的渣油加氢处理方法 |
| CN102676218A (zh) * | 2011-03-16 | 2012-09-19 | 中国石油化工股份有限公司 | 一种固定床渣油加氢工艺 |
Non-Patent Citations (1)
| Title |
|---|
| 渣油加氢与催化裂化深度联合工艺技术研究;刘铁斌等;《当代化工》;20120630;第41卷(第6期);第582-584页 * |
Also Published As
| Publication number | Publication date |
|---|---|
| SG11201804018XA (en) | 2018-06-28 |
| CN106701172A (zh) | 2017-05-24 |
| KR102097650B1 (ko) | 2020-04-06 |
| US11001768B2 (en) | 2021-05-11 |
| TW201716562A (zh) | 2017-05-16 |
| CA3005154C (fr) | 2020-09-01 |
| TWI700362B (zh) | 2020-08-01 |
| WO2017080387A1 (fr) | 2017-05-18 |
| US20180346828A1 (en) | 2018-12-06 |
| RU2685266C1 (ru) | 2019-04-17 |
| KR20180086212A (ko) | 2018-07-30 |
| EP3375847A1 (fr) | 2018-09-19 |
| CA3005154A1 (fr) | 2017-05-18 |
| EP3375847B1 (fr) | 2020-07-29 |
| DK3375847T3 (da) | 2020-10-19 |
| EP3375847A4 (fr) | 2019-05-15 |
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