CN106700907A - Tire glazing agent and preparation method thereof, and tire glazing method - Google Patents
Tire glazing agent and preparation method thereof, and tire glazing method Download PDFInfo
- Publication number
- CN106700907A CN106700907A CN201611021251.3A CN201611021251A CN106700907A CN 106700907 A CN106700907 A CN 106700907A CN 201611021251 A CN201611021251 A CN 201611021251A CN 106700907 A CN106700907 A CN 106700907A
- Authority
- CN
- China
- Prior art keywords
- tire
- glazing agent
- viscosity
- oil
- tire glazing
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- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D183/00—Coating compositions based on macromolecular compounds obtained by reactions forming in the main chain of the macromolecule a linkage containing silicon, with or without sulfur, nitrogen, oxygen, or carbon only; Coating compositions based on derivatives of such polymers
- C09D183/04—Polysiloxanes
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/20—Diluents or solvents
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/02—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
- C08L2205/025—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group containing two or more polymers of the same hierarchy C08L, and differing only in parameters such as density, comonomer content, molecular weight, structure
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- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Paints Or Removers (AREA)
- Tires In General (AREA)
Abstract
The invention provides a tire glazing agent and a preparation method thereof, and a tire glazing method. The tire glazing agent disclosed by the invention is prepared from 20 to 60 percent by mass of low viscosity silica oil with the viscosity of 100 to 500 mPa*s, 10 to 50 percent by mass of high viscosity silica oil with the viscosity of 12,500 to 100,000 mPa*s and 20 to 40 percent by mass of alkanes solvent oil with the flashing point of 40 to 95 DEG C. After a tire is coated with the tire glazing agent, a glazed coating layer with high glazing property, durability and application property can be formed.
Description
Technical field
This disclosure relates to car detailing field, more particularly to tire glazing agent and tire method of lustering.
Background technology
Automobile tire glazing agent is widely used in car detailing field and growth requirement is very fast.Presently commercially available automobile tire
Glazing agent is based on waterborne glazing agent, but waterborne glazing agent is in upper photosensitiveness (glossiness after coating), persistence (after coating
Washing stability) and the combination property of application property (wiping properties after coating) on Shortcomings.
The content of the invention
The disclosure provides a kind of tire glazing agent of oiliness, and it can be formed in photosensitiveness, persistence and apply on tire
The excellent upper light coating of all aspects of work.
The first aspect of the disclosure provides a kind of tire glazing agent, and the viscosity that it includes 20-60 mass % is 100-
The silicone oil with low viscosity of 500mPas, the viscosity of 10-50 mass % are the viscous silicone fluid and 20- of 12500-100000mPas
Alkane solvents oil of the flash-point of 40 mass % in the range of 40-95 DEG C.
The second aspect of the disclosure provides a kind of method for preparing tire glazing agent, including is 100-500mPa by viscosity
The alkane of the silicone oil with low viscosity of s, the viscous silicone fluid and flash-point that viscosity is 12500-100000mPas in the range of 50-95 DEG C
Class solvent naphtha presses 20-60：The step of 10-50: 20-40 mass percent mixes.
The third aspect of the disclosure provides a kind of tire method of lustering, including will be applied according to the tire glazing agent of first aspect
Cloth on surface of tyre with light coating in formation the step of.
Tire glazing agent according to disclosure offer can be formed in photosensitiveness, persistence after being coated on tire
The excellent upper light coating with all aspects of application property.
Specific embodiment
It should be appreciated that in the case where the scope of the present disclosure or spirit is not departed from, those skilled in the art can be according to this
The teaching of specification envisions other various embodiments and it can be modified.Therefore, specific embodiment below is not
Restrictive meaning.
Except as otherwise noted, expression characteristic size, quantity and the materialization for otherwise being used in specification and claims are special
All numerals of property are construed as being modified by term " about " in all cases.Therefore, unless there are opposite
Illustrate, the numerical parameter otherwise listed in description above and appended claims is approximation, those skilled in the art
Member can seek the required characteristic of acquisition using teachings disclosed herein, suitably change these approximations.Use end points table
The use of the number range shown includes all numerals and any scope in the range of this in the range of this, for example, 1 to 5 includes
1st, 1.1,1.3,1.5,2,2.75,3,3.80,4 and 5 etc..
Tire glazing agent
The tire glazing agent that the disclosure is provided includes viscous silicone fluid, silicone oil with low viscosity and the alkanes as organic solvent
Solvent naphtha.
According to some specific embodiments, the viscous silicone fluid for the tire glazing agent of the disclosure is that viscosity is 12500-
The viscous silicone fluid of 100000mPas.Although being reluctant to stick to any theory, it is believed that viscosity high viscosity within the above range
Silicone oil makes light coating have intensity and the relatively strong adhesive force to tire higher, so as to be conducive to the upper photosensitiveness of tire glazing agent
And persistence.For this viewpoint, the lower limit of the viscosity of viscous silicone fluid is preferably 20000mPas, more preferably
30000mPas, its higher limit can be 90000mPas or 80000mPas.
According to some specific embodiments, content of the viscous silicone fluid in the tire glazing agent of the disclosure is 10-50 matter
Amount %.Content viscous silicone fluid within this range can ensure tire glazing agent height on photosensitiveness and it is persistent simultaneously,
Also making tire glazing agent has good application property.
According to some specific embodiments, the silicone oil with low viscosity for the tire glazing agent of the disclosure is that viscosity is 100-
The silicone oil with low viscosity of 500mPas.The viscosity of silicone oil with low viscosity can also be 200-400mPas, or 300-400mPas.
Although being reluctant to stick to any theory, it is believed that the entirety that silicone oil with low viscosity reduces tire glazing agent with viscous silicone fluid compounding is glued
Degree, makes it easier to be uniformly distributed in surface of tyre, so as to improve the persistence and application property of tire glazing agent.
According to some specific embodiments, content of the silicone oil with low viscosity in the tire glazing agent of the disclosure is 20-60 matter
Amount %.Content silicone oil with low viscosity within this range can ensure that tire glazing agent has persistence and application property high, while
Keep upper photosensitiveness higher.Silicone oil with low viscosity can be preferably 5: 1 to 2 with the quality ratio scope of viscous silicone fluid: 5, herein
In proportion, it is possible to achieve upper balance good between photosensitiveness, persistence and application property three.
According to some specific embodiments, viscous silicone fluid and silicone oil with low viscosity for the tire glazing agent of the disclosure can
Being same type or different types of silicone oil.For the viewpoint of excellent compatibility between the two, preferred viscous silicone fluid and low
Viscosity silicone oil is the silicone oil of same type.
According to some specific embodiments, viscous silicone fluid and silicone oil with low viscosity for the tire glazing agent of the disclosure can
Being the non-reacted dimethyl silicone polymer of line style.The non-reacted dimethyl silicone polymer of such line style can include watt
The AK series silicone oil of gram chemistry, for example, AK-100 silicone oil, AK-350 silicone oil, AK-60K silicone oil, AK-100K silicone oil etc..
According to some specific embodiments, the alkane solvents oil for the tire glazing agent of the disclosure is flash-point in 40-
Alkane solvents oil in the range of 95 DEG C.Flash-point alkane solvents oil within this range can with above-mentioned viscous silicone fluid and
Both silicone oil with low viscosity matched well, not only act as reduce tire glazing agent denseness effect, and allow viscous silicone fluid and
Mixing between silicone oil with low viscosity evenly, so as to significantly improve the performance of tire glazing agent, especially application property.
According to some specific embodiments, the alkane solvents oil for the tire glazing agent of the disclosure can be straight chain alkane
Hydrocarbon solvent oil.
According to some specific embodiments, the alkane solvents oil for the tire glazing agent of the disclosure can include isoparaffin
At least one in class solvent naphtha and N-alkanes hydro carbons solvent naphtha.Isomeric alkane hydro carbons solvent naphtha can include Isopar H, Isopar L
With Isopar M solvents etc..N-alkanes hydro carbons solvent naphtha includes D40 solvent naphthas, D60 solvent naphthas, D80 solvent naphthas, D95 solvent naphthas etc..
According to some specific embodiments, content of the alkane solvents oil in tire glazing agent can be 20-40 matter
Amount %.Alkane solvents oil content can fully play dilution, dissolving to silicone oil component etc. in the range of 20-40 mass %
Effect, so as to ensure enough upper photosensitiveness and it is persistent simultaneously, significantly improve application property.
According to some specific embodiments, the tire glazing agent of the disclosure can also contain some auxiliary elements, for example, with
In improvement silicone oil dispersion, or for improving the composition with surface of tyre tack, such as nonionic surfactant etc..But
It is that preferably the tire glazing agent of the disclosure is only made up of viscous silicone fluid, silicone oil with low viscosity and alkane solvents oil.
The method for preparing tire glazing agent
According to some aspects, the disclosure provides a kind of method for preparing tire glazing agent, and it includes that by viscosity be 100-
The silicone oil with low viscosity of 500mPas, viscosity are the viscous silicone fluid and flash-point of 12500-100000mPas in 50-95 DEG C of scope
Interior alkane solvents oil presses 20-60：10-50：The step of mass percent of 20-40 mixes.
On silicone oil with low viscosity, viscous silicone fluid and alkane solvents oil description, referring to this specification "Tire glazing Agent" part.
According to some specific embodiments, silicone oil with low viscosity, viscous silicone fluid and alkane solvents oil are mixed under agitation.
According to some specific embodiments, other auxiliary elements, such as nonionic table can also be added in blend step
Face activating agent etc..
Tire method of lustering
According to some aspects, the disclosure provides a kind of tire method of lustering, and it is included according to the tire glazing of the disclosure
The step of agent is coated on surface of tyre to form upper light coating.
According to some specific embodiments, tire can be the tire that any material is made.According to some specific embodiment parties
Formula, tire is rubber tyre.
According to some specific embodiments, after the tire glazing agent of the disclosure is coated on surface of tyre, 1- is stood
30 minutes, or 1-15 minutes.
According to some specific embodiments, the thickness of the upper light coating of the tire glazing agent formation of the disclosure can be 1-
5000 microns, or 1-1000 microns, or 1-100 microns.
The upper light coating formed by the tire glazing agent of the disclosure has the glossiness more than 90, after current are rinsed 30 minutes
Glossiness be more than 80, and application property is excellent.
Embodiment
Examples provided below and comparative example help to understand the present invention, and these embodiments and comparative example should not be managed
It is limitation of the scope of the invention to solve.Except as otherwise noted, all of parts and percentages are by mass.
The raw material and source used in embodiment of the disclosure and comparative example are summarized in table 1 below.
Table 1
Embodiment 1
By Isopar M solvents, 350mPas silicone oil and 60K mPas silicone oil are according to 40：40：20 mass percent
Pour into glass beaker, stir, obtain the tire glazing agent of embodiment 1.
In such a way, the upper photosensitiveness of the tire glazing agent of measurement embodiment 1, persistence and application property.
Upper photosensitiveness test
Choose General Purpose Rubber piece (long：Width=12cm：12cm) (Shanghai Bin Fei Hardware Companies), rubber is coated in by tire glazing agent
On film, wait 2 minutes, wiped uniform (coating layer thickness is about 5 microns) using 3M superfine fibres cloth, it is then hand-held using BYK
Formula vancometer tests glossiness.
The glossiness of blank sheet rubber (in coating before light coating) be 62.5, in coating after light coating sheet rubber light
Damp degree ＞ 90 for qualified,<90 for unqualified.
Persistence is tested
Tire glazing agent is coated on sheet rubber, is waited 2 minutes, uniform (coating layer thickness is wiped using 3M superfine fibres cloth
About 5 microns), after waiting 15 minutes, sheet rubber is rinsed 30 minutes with lasting current (flow rate of water flow is 40ml/s), then make
Glossiness is tested with BYK hand-helds vancometer.
After rinsing 30 minutes, qualified, the glossiness that is defined as persistence of glossiness ＞ 80<80 are defined as persistence
It is unqualified.
Workability is tested
Tire glazing agent is coated on sheet rubber, 2 minutes is waited afterwards, is wiped with 3M superfine fibres cloth.With the wiping of 5N
Light coating on tire can be wiped uniform (coating layer thickness is about 5 microns) 5 times by the speed of power and 5cm/s back and forth, be defined as wiping
Performance is qualified (application property passes through), is otherwise defined as wiping properties unqualified (application property does not pass through).
Embodiment 2-15 and comparative example 1-17
According to the proportioning shown in table 2 below, prepare in the same manner as example 1 and testing example 2-15 and contrast
The tire glazing agent of example 1-17.
Table 2
Be can be seen that from the performance test results in table 2 and be in the silicone oil with low viscosity for meeting viscosity 100-500mPas
20-60 mass %, the viscous silicone fluid of viscosity 12500-100000mPas are 10-50 mass %, the alkane of 40-95 DEG C of flash-point
It is excellent at upper photosensitiveness, persistence and three aspects of application property during class solvent naphtha is for the embodiment 1-15 of the condition of 20-40 mass %
It is different, and in comparative example 1-17 of any one of above-mentioned condition is unsatisfactory for, at least one of upper photosensitiveness, persistence and application property
It is unqualified.
Although for exemplary purposes, above-mentioned specific embodiment includes many details, this area is common
It should be understood to the one skilled in the art that this public affairs that many modifications of these details, change, replacement and change are protected in specific embodiment
In the range of opening.Therefore, the disclosure that the disclosure described in specific embodiment is not protected to specific embodiment applies
Any limitation.The proper range of the disclosure should be limited by detailed description below book and its appropriate legal equivalents.It is all
The bibliography of reference is incorporated by herein by reference.
Claims (12)
1. a kind of tire glazing agent, the viscosity that it includes 20-60 mass % is silicone oil with low viscosity, the 10-50 of 100-500mPas
The viscosity of quality % is the viscous silicone fluid of 12500-100000mPas and the flash-point of 20-40 mass % in 40-95 DEG C of scope
Interior alkane solvents oil.
2. tire glazing agent according to claim 1, wherein the quality of the silicone oil with low viscosity and the viscous silicone fluid
Ratio is 5：1 to 2：In the range of 5.
3. tire glazing agent according to claim 1, wherein the viscosity of the silicone oil with low viscosity is in 200-400mPas models
In enclosing.
4. tire glazing agent according to claim 1, wherein the viscosity of the viscous silicone fluid is in 20000-
In the range of 80000mPas.
5. tire glazing agent according to claim 1, wherein the silicone oil with low viscosity and/or viscous silicone fluid are line styles
Non-reacted dimethyl silicone polymer.
6. tire glazing agent according to claim 1, wherein alkane solvents oil includes isomeric alkane hydro carbons solvent naphtha
With at least one in N-alkanes hydro carbons solvent naphtha.
7. tire glazing agent according to claim 6, wherein the isoparaffin class solvent naphtha includes Isopar H,
Isopar L and Isopar M solvents.
8. tire glazing agent according to claim 6, wherein the n-alkane class solvent naphtha includes D40 solvent naphthas, D60
Solvent naphtha, D80 solvent naphthas and D95 solvent naphthas.
9. a kind of method for preparing tire glazing agent, including be the silicone oil with low viscosity of 100-500mPas by viscosity, viscosity be
Alkane solvents oil of the viscous silicone fluid and flash-point of 12500-100000mPas in the range of 50-95 DEG C presses 20-60：10-
50：The step of mass percent of 20-40 mixes.
10. method according to claim 9, wherein the silicone oil with low viscosity and/or viscous silicone fluid are the non-anti- of line style
Answering property dimethyl silicone polymer.
11. methods according to claim 9, wherein alkane solvents oil includes isomeric alkane hydro carbons solvent naphtha and positive structure
At least one in alkane solvents oil.
A kind of 12. tire method of lustering, including the tire glazing agent according to any one of claim 1-8 is coated on wheel
The step of on tire surface to form upper light coating.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201611021251.3A CN106700907B (en) | 2016-11-15 | 2016-11-15 | Tire glazing agent, preparation method thereof and tire glazing method |
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201611021251.3A CN106700907B (en) | 2016-11-15 | 2016-11-15 | Tire glazing agent, preparation method thereof and tire glazing method |
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| CN106700907A true CN106700907A (en) | 2017-05-24 |
| CN106700907B CN106700907B (en) | 2019-12-27 |
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Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN110746881A (en) * | 2019-11-06 | 2020-02-04 | 3M中国有限公司 | Tire care composition, method of caring a tire, and tire |
| CN111303767A (en) * | 2020-03-26 | 2020-06-19 | 北京京蝠环保科技有限公司 | Tire glazing glaze |
| CN113004788A (en) * | 2021-02-19 | 2021-06-22 | 3M中国有限公司 | Surface finishing composition |
| CN116063923A (en) * | 2022-01-28 | 2023-05-05 | 浙江丽境环保科技工程有限公司 | Engine coating liquid and application |
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|---|---|---|---|---|
| CN110746881A (en) * | 2019-11-06 | 2020-02-04 | 3M中国有限公司 | Tire care composition, method of caring a tire, and tire |
| CN111303767A (en) * | 2020-03-26 | 2020-06-19 | 北京京蝠环保科技有限公司 | Tire glazing glaze |
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| CN116063923A (en) * | 2022-01-28 | 2023-05-05 | 浙江丽境环保科技工程有限公司 | Engine coating liquid and application |
Also Published As
| Publication number | Publication date |
|---|---|
| CN106700907B (en) | 2019-12-27 |
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