CN106700545B - A kind of compound abrasive rubber material - Google Patents
A kind of compound abrasive rubber material Download PDFInfo
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- CN106700545B CN106700545B CN201611225951.4A CN201611225951A CN106700545B CN 106700545 B CN106700545 B CN 106700545B CN 201611225951 A CN201611225951 A CN 201611225951A CN 106700545 B CN106700545 B CN 106700545B
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L77/00—Compositions of polyamides obtained by reactions forming a carboxylic amide link in the main chain; Compositions of derivatives of such polymers
- C08L77/10—Polyamides derived from aromatically bound amino and carboxyl groups of amino-carboxylic acids or of polyamines and polycarboxylic acids
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/011—Nanostructured additives
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2203/00—Applications
- C08L2203/18—Applications used for pipes
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/14—Polymer mixtures characterised by other features containing polymeric additives characterised by shape
- C08L2205/16—Fibres; Fibrils
Abstract
A kind of compound abrasive rubber material is kneaded 1h under the conditions of 170-180 DEG C by the enhancing rubber of rubber base-material and rubber base-material weight 20-25% and is made.The present invention to be formed by the way that the rubber base-material of special composition to be kneaded at high temperature with enhancing rubber, the characteristics of making it not only have both two kinds of rubber, and, the wherein reinforcing agent containing modified aluminas micro mist, modified hollow glass micropearl and modified manometer silicon dioxide, since the surface nature of these substances has been changed, to when being added in rubber matrix, can and inorganic component organic with remaining preferably combined, the intensity and wear-resisting property of Compound rubber has been greatly enhanced.
Description
Technical field
The invention belongs to the rubber liner materials that pipeline fluid transportation art is used, specifically a kind of compound wear-resisting
Rubber material.
Background technique
Pipeline is connected into pipe, pipe connector and valve etc. for conveying gas, liquid or with solid particle
Fluid device.In general, fluid flows to low pressure from the high pressure of pipeline after the pressurization such as air blower, compressor, pump and boiler
The pressure or gravity conveying of fluid itself can also be used in place.During transportation, the fluid in pipeline can make the inner wall of pipeline
At washing away and wearing, thus the problems such as will lead to the abrasion of pipeline after a protracted use.It is asked to solve the abrasion of pipeline
Often rubber or ceramic lining is arranged in inner wall of the pipe in topic, and existing rubber liner layer is due to the restriction of material, wear-resisting
Performance is not excellent, very low so as to cause its service life.
Summary of the invention
Make caused by wear-resisting property to solve rubber liner used in abrasion-proof pipe in the prior art is not excellent
It is compound resistance to by the way that this is arranged in pipeline the present invention provides a kind of compound abrasive rubber material with the problem that the service life is low
Rubber milling material, to greatly strengthen the wear-resisting property of the pipeline.
The present invention to solve above-mentioned technical problem used by technical solution are as follows: a kind of compound abrasive rubber material, by
The enhancing rubber of rubber base-material and rubber base-material weight 20-25% are kneaded 1h under the conditions of 170-180 DEG C and are made, wherein according to weight
Ratio is measured, the rubber base-material is by 40~50 parts of aramid fiber rubber, 10~20 parts of nylon fibre, 1~3 part of vulcanizing agent, 3~4
The promotor, 7~9 parts of carbon black, 2~3 parts of calcium carbonate and 1~2 part of talcum powder of part are kneaded under the conditions of 120~140 DEG C
It forms；The enhancing rubber is by 10~12 parts of nylon fibre, 30~34 parts of fluorubber, 4~5 parts of carbon fiber, 2~3 parts
Vulcanizing agent, 5~7 parts of carbon black, 1~2 part of alumina powder and 3~5 parts of reinforcing agent under the conditions of 120~140 DEG C mix
It refines, according to weight ratio, the reinforcing agent is changed by 24-26 parts of silica solution, 3-5 parts of modified aluminas micro mist, 5-7 parts
Property hollow glass micropearl and 6-8 parts of modified manometer silicon dioxide mix, and the modified hollow glass micropearl refers to will be commercially available
Hollow glass micropearl mixed with the surface modifier I of its weight 3-5% after stand 1-2h after filtering dry to obtain, surface used
Modifying agent I is mixed by KH550, ethyl alcohol, acetone and barium hydroxide according to the ratio of weight ratio 3-4:80:2-3:1-2；It is described
Modified manometer silicon dioxide and modified aluminas micro mist are that commercially available nano silica and alumina powder is heavy with it respectively
The surface modifier II of amount 3-5% is mixed to get, and the surface modifier II is by barium hydroxide, sodium carbonate and KH550 according to weight ratio
The ratio of 3-4:1-2:30 mixes.
The talcum powder first passes through modification before use, and modification refers to: by commercially available talcum powder and its weight
Filtering dries to obtain the surface modifier I of 3-5% stands 1-2h after mixing after, and surface modifier I used is by KH550, ethyl alcohol, third
Ketone and barium hydroxide are mixed according to the ratio of weight ratio 3-4:80:2-3:1-2.
Filler containing aramid fiber rubber weight 10% in the rubber base-material, according to weight ratio, the filler is by 4~5 parts of seas
Afrodite suede, 1~2 part of nano zinc powder, 10~15 parts of ethyl orthosilicates are made, the filler the preparation method comprises the following steps: according to weight
Than taking 10~15 parts of ethyl orthosilicates and deionized water to mix according to the ratio of 1:8-10, then sequentially add positive silicic acid thereto
The glacial acetic acid of ethyl ester weight 10%, the carbon dust of ethyl orthosilicate weight 5%, 4~5 parts of sepiolite cashmeres and 1~2 part of nano zinc powder are mixed
Conjunction is uniformly reacted, and in reaction process, applies the ultrasonic wave of frequency 350-370kHz into reaction system every 20min
1min obtains solid powder to carry out ultrafiltration to reaction system after reaction, finally fills solid powder under aerobic conditions
Divide calcination to remove carbon dust and obtains filler.
Contain modified hollow glass micropearl, modified aluminas micro mist and modified nano-silica in reinforcing agent of the invention
Silicon, on the one hand can it is evenly dispersed in the base, be on the other hand that these material surfaces is made to be grafted a large amount of silicon in modifying process
Hydroxyl, these groups are connected it with matrix by chemically reacting, and guarantee to have between these three substances and matrix good
Interface binding power, to enhance the wear-resisting property and intensity of basis material；And when by external force, hollow glass micropearl
Deformation occurs by stress in the material for particle, destroys etc., to absorb impact energy, improves impact property, while can be with
Cause crazing, terminates crack extension, cause the shear yielding of matrix under certain morphosis, to consume a large amount of impact energy
Amount, and born external force can be preferably transmitted, improve the compressive strength, bending strength, impact strength of matrix；
It is mixed as catalyst using barium hydroxide and sodium carbonate by nanoscale SiO2The table of particle and alumina powder
Face, to contain a certain number of oxygen-containing functional groups, can be increased nanoscale SiO by the effect of hydroxyl2Particle and oxidation
The related surface compatability of aluminium micro mist, in nanoscale SiO2Particle and alumina powder are sufficiently mixed as filler material and remaining raw material
When conjunction, because the particle of the two all very littles, and large specific surface area, the structure of imperceptibility make the contact area of rest materials and its
Increase, make the two can be evenly dispersed in material, consequently facilitating chemical bonding or physics knot occur for the two and remaining substance
It closes.In addition, evenly dispersed nanoscale SiO2It is equivalent to " anchor point ", the reinforcing matrix generated under hot environment and its can be made
In conjunction in the case where being acted on by external impacts, the effect of " stress concentration " can be generated, " bent so that surrounding some matrixes
Clothes " simultaneously absorb more work of deformation, furthermore can also generate " pinning-is climbed up and over " effect, and it is suffered in extension to increase crackle
Resistance consumes work of deformation, so that its toughness be made to increase；
Likewise, talcum powder after modified processing, so that its surface be made to contain a certain number of oxygen-containing functional groups, increases
Related surface compatability, allow to it is evenly dispersed in material, consequently facilitating with remaining substance occur chemical bonding or
Physical bond.
In the present invention, the sepiolite cashmere in the filler can first pass through modification, the modification before use
Refer to: filtering dries to obtain after standing 1-2h after commercially available sepiolite cashmere powder is mixed with the surface modifier I of its weight 3-5%,
Surface modifier I used is mixed by KH550, ethyl alcohol, acetone and barium hydroxide according to the ratio of weight ratio 3-4:80:2-3:1-2
It forms.Sepiolite cashmere powder first passes through modification, is the micro mist with microcellular structure since it has very big internal surface area,
These microcellular structures can effectively cut down the vibration that impact generates, and on the other hand be make sepiolite cashmere powder in modifying process inside and outside
The a large amount of silicone hydroxyl of surface grafting, these groups are connected sepiolite cashmere powder with matrix by chemically reacting, and guarantee have
Good interface binding power.
The utility model has the advantages that compared with prior art, the present invention having following advantages:
1) present invention to be formed by the way that the rubber base-material of special composition to be kneaded at high temperature with enhancing rubber, keeps it not only simultaneous
Has the characteristics of two kinds of rubber, moreover, wherein containing modified aluminas micro mist, modified hollow glass micropearl and modified nano-silica
The reinforcing agent of silicon, since the surface nature of these substances has been changed, thus when being added in rubber matrix, it can be with remaining
Organic and inorganic component preferably combines, and the intensity and wear-resisting property of Compound rubber has been greatly enhanced；
2) it is additionally added the filler made of sepiolite cashmere, nano zinc powder and ethyl orthosilicate in rubber base-material of the invention,
So that rubber base-material has excellent wear-resisting, resistance to erosion and corrosion resistance, when preparing filler, glacial acetic acid is by Nano-Zinc
Powder dissolution generates zinc acetate, and since sepiolite cashmere has very big internal surface area, can destroy one under ultrasonic wave effect
The structure of part sepiolite cashmere, so that the silica and zinc acetate that generate teos hydrolysis enter directly into Hai Pao
Inside aminanthine, so as to improve the surface characteristic of silica and the physical property of sepiolite cashmere, in this way as filler with
It, can be sufficiently in conjunction with rubber, to increase substantially the wear-resisting of rubber, resistance to erosion and corrosion resistance when compounding rubber.
Specific embodiment
The present invention is further elaborated combined with specific embodiments below, and raw material used in following embodiment is
The raw material of this field routine either from can be commercially available on the market.
Embodiment 1
A kind of compound abrasive rubber material, by rubber base-material and the enhancing rubber of rubber base-material weight 20% in 170 DEG C of items
It is kneaded 1h under part to be made, wherein according to weight ratio, the rubber base-material is by 40 parts of aramid fiber rubber, 10 parts of nylon fibre, 1
Part vulcanizing agent, 3 parts of promotor, 7 parts of carbon black, 2 parts of calcium carbonate and 1 part of talcum powder be kneaded under the conditions of 120 DEG C and
At；The enhancing rubber is by 10 parts of nylon fibre, 30 parts of fluorubber, 4 parts of carbon fiber, 2 parts of vulcanizing agent, 5 parts of charcoal
Black, 1 part of alumina powder and 3 parts of reinforcing agent are kneaded under the conditions of 120 DEG C, according to weight ratio, the reinforcing agent by
24 parts of silica solution, 3 parts of modified aluminas micro mist, 5 parts of modification hollow glass micropearl and 6 parts of modified manometer silicon dioxide
It mixes, the modified hollow glass micropearl, which refers to, mixes commercially available hollow glass micropearl and the surface modifier I of its weight 3%
Filtering dries to obtain after standing 1h after conjunction, and surface modifier I used is by KH550, ethyl alcohol, acetone and barium hydroxide according to weight ratio
The ratio of 3:80:2:1 mixes；The modified manometer silicon dioxide and modified aluminas micro mist are by commercially available nanometer respectively
Silica and alumina powder and the surface modifier II of its weight 3% are mixed to get, and the surface modifier II is by hydroxide
Barium, sodium carbonate and KH550 are mixed according to the ratio of weight ratio 3:1:30.
The above are the basic embodiments of the present embodiment, further can be improved, optimized and limited on the basis of above:
Such as, the talcum powder first passes through modification before use, and modification refers to: commercially available talcum powder is heavy with it
The surface modifier II of amount 3% is mixed to get, and the surface modifier II is by barium hydroxide, sodium carbonate and KH550 according to weight ratio 3:
The ratio of 1:30 mixes；
For another example, the filler containing aramid fiber rubber weight 10% in the rubber base-material, according to weight ratio, the filler is by 4 parts
Sepiolite cashmere, 1 part of nano zinc powder, 10 parts of ethyl orthosilicates are made, the filler the preparation method comprises the following steps: according to weight ratio, take
10 parts of ethyl orthosilicates and deionized water are mixed according to the ratio of 1:8, then sequentially add ethyl orthosilicate weight 10% thereto
Glacial acetic acid, the carbon dust of ethyl orthosilicate weight 5%, 4 parts of sepiolite cashmeres and 1 part of nano zinc powder, which are uniformly mixed, to be reacted, and is reacted
In the process, the ultrasonic wave 1min for applying frequency 350kHz into reaction system every 20min, to after reaction to reaction system
It carries out ultrafiltration and obtains solid powder, it is to obtain filler that finally abundant calcination, which removes carbon dust, under aerobic conditions by solid powder.
Embodiment 2
A kind of compound abrasive rubber material, by rubber base-material and the enhancing rubber of rubber base-material weight 25% in 180 DEG C of items
It is kneaded 1h under part to be made, wherein according to weight ratio, the rubber base-material is by 50 parts of aramid fiber rubber, 20 parts of nylon fibre, 3
Part vulcanizing agent, 4 parts of promotor, 9 parts of carbon black, 3 parts of calcium carbonate and 2 parts of talcum powder be kneaded under the conditions of 140 DEG C and
At；The enhancing rubber is by 12 parts of nylon fibre, 34 parts of fluorubber, 5 parts of carbon fiber, 3 parts of vulcanizing agent, 7 parts of charcoal
Black, 2 parts of alumina powder and 5 parts of reinforcing agent are kneaded under the conditions of 140 DEG C, according to weight ratio, the reinforcing agent by
26 parts of silica solution, 5 parts of modified aluminas micro mist, 7 parts of modification hollow glass micropearl and 8 parts of modified manometer silicon dioxide
It mixes, the modified hollow glass micropearl, which refers to, mixes commercially available hollow glass micropearl and the surface modifier I of its weight 5%
Filtering dries to obtain after standing 2h after conjunction, and surface modifier I used is by KH550, ethyl alcohol, acetone and barium hydroxide according to weight ratio
The ratio of 4:80:3:2 mixes；The modified manometer silicon dioxide and modified aluminas micro mist are by commercially available nanometer respectively
Silica and alumina powder and the surface modifier II of its weight 5% are mixed to get, and the surface modifier II is by hydroxide
Barium, sodium carbonate and KH550 are mixed according to the ratio of weight ratio 4:2:30.
The above are the basic embodiments of the present embodiment, further can be improved, optimized and limited on the basis of above:
Such as, the talcum powder first passes through modification before use, and modification refers to: commercially available talcum powder is heavy with it
The surface modifier II of amount 5% is mixed to get, and the surface modifier II is by barium hydroxide, sodium carbonate and KH550 according to weight ratio 4:
The ratio of 2:30 mixes；
For another example, the filler containing aramid fiber rubber weight 10% in the rubber base-material, according to weight ratio, the filler is by 5 parts
Sepiolite cashmere, 2 parts of nano zinc powder, 15 parts of ethyl orthosilicates are made, the filler the preparation method comprises the following steps: according to weight ratio, take
15 parts of ethyl orthosilicates and deionized water are mixed according to the ratio of 1:10, then sequentially add ethyl orthosilicate weight 10% thereto
Glacial acetic acid, the carbon dust of ethyl orthosilicate weight 5%, 5 parts of sepiolite cashmeres and 2 parts of nano zinc powder be uniformly mixed and reacted, instead
During answering, apply the ultrasonic wave 1min of frequency 370kHz into reaction system every 20min, to after reaction to reactant
System carries out ultrafiltration and obtains solid powder, and it is to obtain filler that finally by solid powder, abundant calcination, which removes carbon dust, under aerobic conditions.
Embodiment 3
A kind of compound abrasive rubber material, by rubber base-material and the enhancing rubber of rubber base-material weight 22.5% at 175 DEG C
Under the conditions of be kneaded 1h be made, wherein according to weight ratio, the rubber base-material by 45 parts of aramid fiber rubber, 15 parts of nylon fibre,
2 parts of vulcanizing agent, 3.5 parts of promotor, 8 parts of carbon black, 2.5 parts of calcium carbonate and 1.5 parts of talcum powder are under the conditions of 130 DEG C
It is kneaded；The enhancing rubber is by 11 parts of nylon fibre, 32 parts of fluorubber, 4.5 parts of carbon fiber, 2.5 parts of vulcanization
Agent, 6 parts of carbon black, 1.5 parts of alumina powder and 4 parts of reinforcing agent are kneaded under the conditions of 130 DEG C, according to weight ratio,
The reinforcing agent is by 25 parts of silica solution, 4 parts of modified aluminas micro mist, 6 parts of modification hollow glass micropearl and 7 parts of modification
Nano silica mixes, and the modified hollow glass micropearl refers to commercially available hollow glass micropearl and its weight 3.5%
Filtering dries to obtain surface modifier I stands 1.5h after mixing after, and surface modifier I used is by KH550, ethyl alcohol, acetone and hydrogen
Barium monoxide is mixed according to the ratio of weight ratio 3.5:80:2.5:1.5；The modified manometer silicon dioxide and modified aluminas
Micro mist is to be mixed to get commercially available nano silica and alumina powder and the surface modifier II of its weight 4% respectively, should
Surface modifier II is mixed by barium hydroxide, sodium carbonate and KH550 according to the ratio of weight ratio 3.5:1.5:30.
The above are the basic embodiments of the present embodiment, further can be improved, optimized and limited on the basis of above:
Such as, the talcum powder first passes through modification before use, and modification refers to: commercially available talcum powder is heavy with it
The surface modifier II of amount 4% is mixed to get, and the surface modifier II is by barium hydroxide, sodium carbonate and KH550 according to weight ratio
3.5:1.5:30 ratio mix；
For another example, the filler containing aramid fiber rubber weight 10% in the rubber base-material, according to weight ratio, the filler is by 4.5
Part sepiolite cashmere, 1.5 parts of nano zinc powder, 12.5 parts of ethyl orthosilicates are made, the filler the preparation method comprises the following steps: according to weight
Than taking 12.5 parts of ethyl orthosilicates and deionized water to mix according to the ratio of 1:9, then sequentially add ethyl orthosilicate weight thereto
Amount 10% glacial acetic acid, ethyl orthosilicate weight 5% carbon dust, 4.5 parts of sepiolite cashmeres and 1.5 parts of nano zinc powder be uniformly mixed into
Row reacts, and in reaction process, applies the ultrasonic wave 1min of frequency 360kHz into reaction system every 20min, to the end of reacting
Ultrafiltration is carried out to reaction system afterwards and obtains solid powder, finally abundant calcination removing carbon dust is under aerobic conditions by solid powder
Obtain filler.
Claims (2)
1. a kind of compound abrasive rubber material, it is characterised in that: by the enhancing of rubber base-material and rubber base-material weight 20-25%
Rubber is kneaded 1h under the conditions of 170-180 DEG C and is made, wherein according to weight ratio, the rubber base-material is by 40~50 parts of aramid fiber
Rubber, 10~20 parts of nylon fibre, 1~3 part of vulcanizing agent, 3~4 parts of promotor, 7~9 parts of carbon black, 2~3 parts of carbon
The filler of sour calcium, 1~2 part of talcum powder and aramid fiber rubber weight 10% is kneaded under the conditions of 120~140 DEG C；The enhancing
Rubber is by 10~12 parts of nylon fibre, 30~34 parts of fluorubber, 4~5 parts of carbon fiber, 2~3 parts of vulcanizing agent, 5~7
The carbon black, 1~2 part of alumina powder and 3~5 parts of reinforcing agent of part are kneaded under the conditions of 120~140 DEG C, according to weight
Ratio is measured, the reinforcing agent is micro- by 24-26 parts of silica solution, 3-5 parts of modified aluminas micro mist, 5-7 parts of modification hollow glass
Pearl and 6-8 parts of modified manometer silicon dioxide mix, and the modified hollow glass micropearl refers to commercially available hollow glass is micro-
Pearl mixed with the surface modifier I of its weight 3-5% after stand 1-2h after filtering dry to obtain, surface modifier I used by
KH550, ethyl alcohol, acetone and barium hydroxide are mixed according to the ratio of weight ratio 3-4:80:2-3:1-2；The modified Nano
Silica and modified aluminas micro mist are by commercially available nano silica and alumina powder and its weight 3-5% respectively
Surface modifier II is mixed to get, and the surface modifier II is by barium hydroxide, sodium carbonate and KH550 according to weight ratio 3-4:1-2:
30 ratio mixes；According to weight ratio, the filler is by 4~5 parts of sepiolite cashmeres, 1~2 part of nano zinc powder, 10~15
Part ethyl orthosilicate is made, the filler the preparation method comprises the following steps: according to weight ratio, take 10~15 parts of ethyl orthosilicates and deionization
Water is mixed according to the ratio of 1:8-10, then sequentially adds the glacial acetic acid of ethyl orthosilicate weight 10%, ethyl orthosilicate weight thereto
Carbon dust, 4~5 parts of sepiolite cashmeres and 1~2 part of the nano zinc powder of amount 5%, which are uniformly mixed, to be reacted, in reaction process, every
20min applies the ultrasonic wave 1min of frequency 350-370kHz into reaction system, to surpass after reaction to reaction system
Filter obtains solid powder, and it is to obtain filler that finally by solid powder, abundant calcination, which removes carbon dust, under aerobic conditions.
2. a kind of compound abrasive rubber material according to claim 1, it is characterised in that: the talcum powder is before use
Modification is first passed through, modification refers to: the surface modifier II of commercially available talcum powder and its weight 3-5% is mixed to get,
The surface modifier II is mixed by barium hydroxide, sodium carbonate and KH550 according to the ratio of weight ratio 3-4:1-2:30.
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| CN112760030B (en) * | 2021-02-01 | 2023-08-18 | 湖南湘龙建材有限公司 | Wear-resistant high-strength paint and preparation method thereof |
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Citations (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH061966A (en) * | 1992-06-18 | 1994-01-11 | Aisin Chem Co Ltd | Dry friction material for clutch |
| JP2004360113A (en) * | 2003-06-04 | 2004-12-24 | Sekisui Chem Co Ltd | Method of sticking aramid fiber with rubber, and device for modifying surface of aramid fiber |
| KR20120073961A (en) * | 2010-12-27 | 2012-07-05 | 주식회사 효성 | Producing method of aramid filament for rubber reinforcement |
| CN103265734A (en) * | 2013-05-19 | 2013-08-28 | 北京化工大学 | Preparation method of pre-dispersed clay-aramid pulp flocculation masterbatch |
| CN103289150A (en) * | 2013-05-06 | 2013-09-11 | 广州加士特密封技术有限公司 | Cold-resistant wear-resistant nitrile rubber sealing material and preparation method thereof |
| CN104500870A (en) * | 2014-12-10 | 2015-04-08 | 平顶山华瑞锦橡耐磨材料有限公司 | Laminar wear-resistant scour-resistant pipeline and production method thereof |
| CN105070380A (en) * | 2015-07-15 | 2015-11-18 | 繁昌县菲德通讯材料设计有限公司 | Cable highly resistant to weather, impact, and tearing |
| CN105175902A (en) * | 2015-07-15 | 2015-12-23 | 繁昌县菲德通讯材料设计有限公司 | High-strength wear-resistant tear-resistant cable |
| CN106011556A (en) * | 2016-06-15 | 2016-10-12 | 平顶山市美伊金属制品有限公司 | Aluminum alloy used for casting pot and manufacturing method of aluminum alloy |
-
2016
- 2016-12-27 CN CN201611225951.4A patent/CN106700545B/en active Active
Patent Citations (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH061966A (en) * | 1992-06-18 | 1994-01-11 | Aisin Chem Co Ltd | Dry friction material for clutch |
| JP2004360113A (en) * | 2003-06-04 | 2004-12-24 | Sekisui Chem Co Ltd | Method of sticking aramid fiber with rubber, and device for modifying surface of aramid fiber |
| KR20120073961A (en) * | 2010-12-27 | 2012-07-05 | 주식회사 효성 | Producing method of aramid filament for rubber reinforcement |
| CN103289150A (en) * | 2013-05-06 | 2013-09-11 | 广州加士特密封技术有限公司 | Cold-resistant wear-resistant nitrile rubber sealing material and preparation method thereof |
| CN103265734A (en) * | 2013-05-19 | 2013-08-28 | 北京化工大学 | Preparation method of pre-dispersed clay-aramid pulp flocculation masterbatch |
| CN104500870A (en) * | 2014-12-10 | 2015-04-08 | 平顶山华瑞锦橡耐磨材料有限公司 | Laminar wear-resistant scour-resistant pipeline and production method thereof |
| CN105070380A (en) * | 2015-07-15 | 2015-11-18 | 繁昌县菲德通讯材料设计有限公司 | Cable highly resistant to weather, impact, and tearing |
| CN105175902A (en) * | 2015-07-15 | 2015-12-23 | 繁昌县菲德通讯材料设计有限公司 | High-strength wear-resistant tear-resistant cable |
| CN106011556A (en) * | 2016-06-15 | 2016-10-12 | 平顶山市美伊金属制品有限公司 | Aluminum alloy used for casting pot and manufacturing method of aluminum alloy |
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