CN106700438A - Novel environment-friendly plastic and preparation method thereof - Google Patents
Novel environment-friendly plastic and preparation method thereof Download PDFInfo
- Publication number
- CN106700438A CN106700438A CN201611124684.1A CN201611124684A CN106700438A CN 106700438 A CN106700438 A CN 106700438A CN 201611124684 A CN201611124684 A CN 201611124684A CN 106700438 A CN106700438 A CN 106700438A
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- novel environment
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- environment friendly
- friendly plastic
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L67/00—Compositions of polyesters obtained by reactions forming a carboxylic ester link in the main chain; Compositions of derivatives of such polymers
- C08L67/02—Polyesters derived from dicarboxylic acids and dihydroxy compounds
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/08—Stabilised against heat, light or radiation or oxydation
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
Abstract
The invention discloses a novel environment-friendly plastic consisting of the following raw materials in parts by weight: 10-20 parts of vinyltrimethoxysilane, 10-20 parts of a plastic base material PET, 3-5 parts of polycaprolactone, 5-8 parts of silicon ether resin, 1-8 parts of maleic anhydride, 1-3 parts of petroleum ether, 5-8 parts of barium stearate, 1-5 parts of cyclohexanone, and 2-5 parts of dibutyl sebacate. According to the novel environment-friendly plastic and a preparation method thereof disclosed by the invention, the raw material formula is reasonable and easy to obtain, the preparation method is simple and reliable, the strength, toughness and heat resistance of the product are improved, production costs are reduced, and the novel environment-friendly plastic can replace general plastics and can be applied in the field of engineering plastics.
Description
Technical field
The present invention relates to plastic material field, more particularly to a kind of novel environment friendly plastics and preparation method thereof.
Background technology
Common PP/PE plastics centuries under natural environment is all difficult to decompose.So plastic garbage is generally acknowledged people making a living
The material of the highly polluting environment that output is come.However, the purposes of plastics is but especially extensive, such as plastic toy, plastic bottle, modeling
Material packaging, polybag etc., we live and be unable to do without plastics at all.The environmental-protecting performance for how improving plastic material has become urgently
The problem of solution.
The content of the invention
To solve problems of the prior art, the invention provides a kind of novel environment friendly plastics and preparation method thereof.
The purpose of the present invention is implemented by the following technical programs：
A kind of novel environment friendly plastics, are made up of the raw material of following parts by weight：Vinyltrimethoxy silane 10-20 parts, plastics
Base material PET10-20 parts, pla-pcl 3-5 parts, 5-8 parts of silicon ether resin, maleic anhydride 1-8 parts, petroleum ether 1-3 parts, barium stearate
5-8 parts, cyclohexanone 1-5 parts, dibutyl sebacate 2-5 parts.
Further, 15 parts of vinyltrimethoxy silane, plastic basis material PET15 parts, 4 parts of pla-pcl, silicon ether resin 6
Part, 5 parts of maleic anhydride, 2 parts of petroleum ether, 6 parts of barium stearate, 3 parts of cyclohexanone, 3 parts of dibutyl sebacate.
A kind of preparation method of above-mentioned novel environment friendly plastics, comprises the following steps：1）Each component raw material is weighed in proportion,
80-120 DEG C is heated in reactor and stirs 15-30 minutes, 2）Filled mixture is obtained in step 1 at a temperature of 50-70 DEG C
Enter inert gas to place 1-2 hours；3) after mixture being heated up into 150-180 DEG C again in a kettle. 1-2 hours is incubated to make
.
Beneficial effect：
Disclosed novel environment friendly plastics of the invention and preparation method thereof, composition of raw materials is rationally easy to get, and preparation method simply may be used
Lean on, improve intensity, toughness and the heat resistance of product, reduce production cost, general-purpose plastics can be replaced, and can use
In engineering plastics field.
Specific embodiment
Embodiment 1：
A kind of novel environment friendly plastics, are made up of the raw material of following parts by weight：1 part of vinyltrimethoxy silane, plastic basis material
PET1 parts, 3 parts of pla-pcl, 5 parts of silicon ether resin, 1 part of maleic anhydride, 1 part of petroleum ether, 5 parts of barium stearate, 1 part of cyclohexanone, the last of the ten Heavenly stems
2 parts of adipate.
A kind of preparation method of above-mentioned novel environment friendly plastics, comprises the following steps：1）Each component raw material is weighed in proportion,
100 DEG C are heated in reactor and stir 20 minutes, 2）By mixture is obtained in step 1 inert gas is filled with a temperature of 60 DEG C
Place 1.5 hours；3) after mixture being heated up into 175 DEG C again in a kettle. 1.5 hours are incubated to be obtained.
Embodiment 2：
A kind of novel environment friendly plastics, are made up of the raw material of following parts by weight：15 parts of vinyltrimethoxy silane, plastic basis material
PET15 parts, 4 parts of pla-pcl, 6 parts of silicon ether resin, 5 parts of maleic anhydride, 2 parts of petroleum ether, 6 parts of barium stearate, 3 parts of cyclohexanone,
3 parts of dibutyl sebacate.
A kind of preparation method of above-mentioned novel environment friendly plastics, comprises the following steps：1）Each component raw material is weighed in proportion,
80 DEG C are heated in reactor and stir 15 minutes, 2）By mixture is obtained in step 1 inert gas is filled with a temperature of 50 DEG C
Place 1 hour；3) after mixture being heated up into 150 DEG C again in a kettle. 1 hour is incubated to be obtained.
Embodiment 3：
A kind of novel environment friendly plastics, are made up of the raw material of following parts by weight：2 parts of vinyltrimethoxy silane, plastic basis material
PET2 parts, 5 parts of pla-pcl, 8 parts of silicon ether resin, 8 parts of maleic anhydride, 3 parts of petroleum ether, 8 parts of barium stearate, 5 parts of cyclohexanone, the last of the ten Heavenly stems
5 parts of adipate.
A kind of preparation method of above-mentioned novel environment friendly plastics, comprises the following steps：1）Each component raw material is weighed in proportion,
120 DEG C are heated in reactor and stir 30 minutes, 2）By mixture is obtained in step 1 inert gas is filled with a temperature of 70 DEG C
Place 2 hours；3) after mixture being heated up into 180 DEG C again in a kettle. 2 hours are incubated to be obtained.
Finally it should be noted that：The preferred embodiments of the present invention are the foregoing is only, are not intended to limit the invention,
Although being described in detail to the present invention with reference to the foregoing embodiments, for a person skilled in the art, it still may be used
Modified with to the technical scheme described in foregoing embodiments, or equivalent is carried out to which part technical characteristic.
All any modification, equivalent substitution and improvements within the spirit and principles in the present invention, made etc., should be included in of the invention
Within protection domain.
Claims (3)
1. a kind of novel environment friendly plastics, it is characterised in that：It is made up of the raw material of following parts by weight：Vinyltrimethoxy silane
10-20 parts, plastic basis material PET10-20 parts, pla-pcl 3-5 parts, 5-8 parts of silicon ether resin, maleic anhydride 1-8 parts, petroleum ether 1-
3 parts, barium stearate 5-8 parts, cyclohexanone 1-5 parts, dibutyl sebacate 2-5 parts.
2. a kind of novel environment friendly plastics according to claim 1, it is characterised in that：15 parts of vinyltrimethoxy silane,
Plastic basis material PET15 parts, 4 parts of pla-pcl, 6 parts of silicon ether resin, 5 parts of maleic anhydride, 2 parts of petroleum ether, 6 parts of barium stearate, ring
3 parts of ketone, 3 parts of dibutyl sebacate.
3. a kind of preparation method of novel environment friendly plastics according to claim 1, it is characterised in that：Comprise the following steps：
1）Each component raw material is weighed in proportion, 80-120 DEG C is heated in a kettle. and stirs 15-30 minutes, 2）To be obtained in step 1
Mixture is filled with inert gas at a temperature of 50-70 DEG C and places 1-2 hours；3) mixture is heated again in a kettle.
1-2 hours is incubated after to 150-180 DEG C to be obtained.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201611124684.1A CN106700438A (en) | 2016-12-08 | 2016-12-08 | Novel environment-friendly plastic and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201611124684.1A CN106700438A (en) | 2016-12-08 | 2016-12-08 | Novel environment-friendly plastic and preparation method thereof |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN106700438A true CN106700438A (en) | 2017-05-24 |
Family
ID=58935964
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201611124684.1A Pending CN106700438A (en) | 2016-12-08 | 2016-12-08 | Novel environment-friendly plastic and preparation method thereof |
Country Status (1)
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| CN (1) | CN106700438A (en) |
Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1126731A (en) * | 1994-10-14 | 1996-07-17 | 瓦克化学有限公司 | Solution of organic multi-molecular siloxanharzloesung, preparation and application of same |
| CN1778833A (en) * | 2004-11-18 | 2006-05-31 | 成都新柯力化工科技有限公司 | Biological-degradable starch/polyester plastic completely and production thereof |
| CN101680162A (en) * | 2007-04-03 | 2010-03-24 | 蓝星有机硅法国简易股份有限公司 | Method for obtaining a fibrous material/silicone composite, and said fibrous material/silicone composite |
| CN105713357A (en) * | 2016-05-05 | 2016-06-29 | 金宝丽科技（苏州）有限公司 | Flame retardant APET (amorphous polyethylene glycol terephthalate) composite packaging material capable of being subjected to high-frequency heat sealing and preparation method thereof |
| CN105802156A (en) * | 2016-05-13 | 2016-07-27 | 金宝丽科技（苏州）有限公司 | Environment-friendly easily degradable APET sheet and preparation method thereof |
-
2016
- 2016-12-08 CN CN201611124684.1A patent/CN106700438A/en active Pending
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1126731A (en) * | 1994-10-14 | 1996-07-17 | 瓦克化学有限公司 | Solution of organic multi-molecular siloxanharzloesung, preparation and application of same |
| CN1778833A (en) * | 2004-11-18 | 2006-05-31 | 成都新柯力化工科技有限公司 | Biological-degradable starch/polyester plastic completely and production thereof |
| CN101680162A (en) * | 2007-04-03 | 2010-03-24 | 蓝星有机硅法国简易股份有限公司 | Method for obtaining a fibrous material/silicone composite, and said fibrous material/silicone composite |
| CN105713357A (en) * | 2016-05-05 | 2016-06-29 | 金宝丽科技（苏州）有限公司 | Flame retardant APET (amorphous polyethylene glycol terephthalate) composite packaging material capable of being subjected to high-frequency heat sealing and preparation method thereof |
| CN105802156A (en) * | 2016-05-13 | 2016-07-27 | 金宝丽科技（苏州）有限公司 | Environment-friendly easily degradable APET sheet and preparation method thereof |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PB01 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| RJ01 | Rejection of invention patent application after publication | ||
| RJ01 | Rejection of invention patent application after publication |
Application publication date: 20170524 |