CN106700276A - Degradable composite ethylene propylene rubber cable sleeve - Google Patents
Degradable composite ethylene propylene rubber cable sleeve Download PDFInfo
- Publication number
- CN106700276A CN106700276A CN201510770531.3A CN201510770531A CN106700276A CN 106700276 A CN106700276 A CN 106700276A CN 201510770531 A CN201510770531 A CN 201510770531A CN 106700276 A CN106700276 A CN 106700276A
- Authority
- CN
- China
- Prior art keywords
- parts
- rubbers
- ethylene propylene
- propylene rubber
- polyacrylamide
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Withdrawn
Links
- 229920000181 Ethylene propylene rubber Polymers 0.000 title abstract 5
- 239000002131 composite material Substances 0.000 title abstract 4
- 239000002994 raw material Substances 0.000 claims abstract description 14
- 229920002401 polyacrylamide Polymers 0.000 claims abstract description 12
- DQWPFSLDHJDLRL-UHFFFAOYSA-N triethyl phosphate Chemical compound CCOP(=O)(OCC)OCC DQWPFSLDHJDLRL-UHFFFAOYSA-N 0.000 claims abstract description 12
- RNFJDJUURJAICM-UHFFFAOYSA-N 2,2,4,4,6,6-hexaphenoxy-1,3,5-triaza-2$l^{5},4$l^{5},6$l^{5}-triphosphacyclohexa-1,3,5-triene Chemical class N=1P(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP=1(OC=1C=CC=CC=1)OC1=CC=CC=C1 RNFJDJUURJAICM-UHFFFAOYSA-N 0.000 claims abstract description 11
- 229920003063 hydroxymethyl cellulose Polymers 0.000 claims abstract description 11
- 229940031574 hydroxymethyl cellulose Drugs 0.000 claims abstract description 11
- 229920000515 polycarbonate Polymers 0.000 claims abstract description 10
- CERQOIWHTDAKMF-UHFFFAOYSA-N Methacrylic acid Chemical compound CC(=C)C(O)=O CERQOIWHTDAKMF-UHFFFAOYSA-N 0.000 claims abstract description 9
- 229920000954 Polyglycolide Polymers 0.000 claims abstract description 9
- 239000004633 polyglycolic acid Substances 0.000 claims abstract description 9
- 239000000463 material Substances 0.000 claims abstract description 7
- 229920001971 elastomer Polymers 0.000 claims description 22
- 239000005060 rubber Substances 0.000 claims description 22
- 229910052736 halogen Inorganic materials 0.000 claims description 21
- 150000002367 halogens Chemical class 0.000 claims description 21
- 150000001875 compounds Chemical class 0.000 claims description 11
- 239000003063 flame retardant Substances 0.000 claims description 11
- 238000004079 fireproofing Methods 0.000 claims description 10
- 239000004425 Makrolon Substances 0.000 claims description 9
- BPMFZUMJYQTVII-UHFFFAOYSA-N guanidinoacetic acid Chemical compound NC(=N)NCC(O)=O BPMFZUMJYQTVII-UHFFFAOYSA-N 0.000 claims 4
- 125000002887 hydroxy group Chemical group [H]O* 0.000 claims 3
- 241001131796 Botaurus stellaris Species 0.000 claims 1
- 229920002678 cellulose Polymers 0.000 claims 1
- 239000001913 cellulose Substances 0.000 claims 1
- -1 hydroxylmethyl Chemical group 0.000 claims 1
- 229920000036 polyvinylpyrrolidone Polymers 0.000 abstract description 7
- 239000011810 insulating material Substances 0.000 abstract description 3
- 229920001661 Chitosan Polymers 0.000 abstract 1
- 239000004417 polycarbonate Substances 0.000 abstract 1
- 239000001267 polyvinylpyrrolidone Substances 0.000 abstract 1
- 235000013855 polyvinylpyrrolidone Nutrition 0.000 abstract 1
- 229920003023 plastic Polymers 0.000 description 3
- 239000004033 plastic Substances 0.000 description 3
- 239000002253 acid Substances 0.000 description 2
- 150000001336 alkenes Chemical class 0.000 description 2
- 150000002148 esters Chemical class 0.000 description 2
- 238000009413 insulation Methods 0.000 description 2
- JRZJOMJEPLMPRA-UHFFFAOYSA-N olefin Natural products CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 description 2
- 238000012856 packing Methods 0.000 description 2
- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 description 1
- NIXOWILDQLNWCW-UHFFFAOYSA-N 2-Propenoic acid Natural products OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 1
- 108010011935 Poly 18 antigen Chemical group 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 238000006065 biodegradation reaction Methods 0.000 description 1
- 230000007797 corrosion Effects 0.000 description 1
- 238000005260 corrosion Methods 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 238000003912 environmental pollution Methods 0.000 description 1
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 1
- 229920000915 polyvinyl chloride Polymers 0.000 description 1
- 150000004040 pyrrolidinones Chemical class 0.000 description 1
- 238000011084 recovery Methods 0.000 description 1
- 238000004064 recycling Methods 0.000 description 1
- 229920002554 vinyl polymer Polymers 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
- C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L23/16—Elastomeric ethene-propene or ethene-propene-diene copolymers, e.g. EPR and EPDM rubbers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/02—Flame or fire retardant/resistant
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/08—Stabilised against heat, light or radiation or oxydation
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2203/00—Applications
- C08L2203/20—Applications use in electrical or conductive gadgets
- C08L2203/202—Applications use in electrical or conductive gadgets use in electrical wires or wirecoating
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
Abstract
The invention discloses a degradable composite ethylene propylene rubber cable sleeve, and belongs to the technical field of insulating materials. The degradable composite ethylene propylene rubber cable sleeve mainly comprises, by mass, 25-28 parts of ethylene propylene rubber, 4-5 parts of polyacrylamide, 14-15 parts of methacrylic acid, 13-14 parts of a halogenated flame retardation material, 2.5 parts of a halogenated flame retardant, 17-18 parts of polycarbonate, 7-9 parts of polyvinyl pyrrolidone, 5-6 parts of hydroxymethyl cellulose, 3-4 parts of polyglycolic acid, 2-3 parts of chitosan and 1-1.5 parts of triethyl phosphate. The degradable composite ethylene propylene rubber cable sleeve has the advantages of low price and reasonable compatibility of raw materials, good flame retardation and full biodegradability, and is mainly used for making electric power insulating materials.
Description
Technical field
The invention belongs to insulating materials technical field, specifically, more particularly to a kind of degradable compound EP rubbers cable joint-box.
Background technology
The external packing such as cable and electrical equipment uses lightweight plastic material mostly, in order to avoid be damaged or corrode.Dress plastics material to be outsourced
It is most of everywhere as discarded object garbage disposal after material is removed, easily cause environmental pollution.At present, it is poly- in plastic material
Vinyl plastics packing articles, belong to non-returnable container articles for use, cheap, are widely used in daily life.Due to substantially
It is worth without recycling, the rate of recovery is extremely low, with wind drift, contaminated land and water caused by its light weight with the characteristic for being difficult to degrade
Face, the chief component accounted in the established white garbage of China.
The content of the invention
It is an object of the invention to overcome drawbacks described above, there is provided a kind of degradable compound EP rubbers cable joint-box, its raw material is cheap,
Compatibility is reasonable, good insulation preformance, on the basis of possessing good anti-flammability, can be fully biodegradable.
Described degradable compound EP rubbers cable joint-box, including according to the following raw material of mass fraction meter：EP rubbers 25-28
Part, polyacrylamide 4-5 parts, methacrylic acid 14-15 parts, 13-14 parts of halogen type fire proofing, 2.5 parts of halogen containing flame-retardant,
Makrolon 17-18 parts, PVP 7-9 parts, hydroxymethyl cellulose 5-6 parts, polyglycolic acid 3-4 parts, shell gather
It is sugared 2-3 parts, triethyl phosphate 1-1.5 parts.
Further, including according to the following raw material of mass fraction meter：25 parts of EP rubbers, 4 parts of polyacrylamide, methyl-prop
14 parts of olefin(e) acid, 13 parts of halogen type fire proofing, 2.5 parts of halogen containing flame-retardant, 17 parts of makrolon, PVP
7 parts, 5 parts of hydroxymethyl cellulose, 3 parts of polyglycolic acid, 2 parts of shitosan, 1 part of triethyl phosphate.
Further, including according to the following raw material of mass fraction meter：28 parts of EP rubbers, 5 parts of polyacrylamide, methyl-prop
15 parts of olefin(e) acid, 14 parts of halogen type fire proofing, 2.5 parts of halogen containing flame-retardant, 18 parts of makrolon, PVP
9 parts, 6 parts of hydroxymethyl cellulose, 4 parts of polyglycolic acid, 3 parts of shitosan, 1.5 parts of triethyl phosphate.
Further, including according to the following raw material of mass fraction meter：27 parts of EP rubbers, 4.3 parts of polyacrylamide, methyl
14.7 parts of acrylic acid, 13.1 parts of halogen type fire proofing, 2.5 parts of halogen containing flame-retardant, 17.4 parts of makrolon, polyvinyl
7.9 parts of pyrrolidones, 5.23 parts of hydroxymethyl cellulose, 3.14 parts of polyglycolic acid, 2.4 parts of shitosan, triethyl phosphate
1.45 parts.
Compared with prior art, the beneficial effects of the invention are as follows：
Raw material of the present invention is cheap, compatibility rationally, good insulation preformance is high temperature resistant, corrosion-resistant, with good anti-flammability, significantly
Improve safety coefficient；And realize abundant biodegradation.
Specific embodiment
With reference to embodiment, the invention will be further described：
Embodiment one：Degradable compound EP rubbers cable joint-box, including according to the following raw material of mass fraction meter：EP rubbers
25 parts, it is 4 parts of polyacrylamide, 14 parts of methacrylic acid, 13 parts of halogen type fire proofing, 2.5 parts of halogen containing flame-retardant, poly-
17 parts of carbonic ester, 7 parts of PVP, 5 parts of hydroxymethyl cellulose, 3 parts of polyglycolic acid, 2 parts of shitosan,
1 part of triethyl phosphate.
Embodiment two：Degradable compound EP rubbers cable joint-box, including according to the following raw material of mass fraction meter：EP rubbers
28 parts, it is 5 parts of polyacrylamide, 15 parts of methacrylic acid, 14 parts of halogen type fire proofing, 2.5 parts of halogen containing flame-retardant, poly-
18 parts of carbonic ester, 9 parts of PVP, 6 parts of hydroxymethyl cellulose, 4 parts of polyglycolic acid, 3 parts of shitosan,
1.5 parts of triethyl phosphate.
Embodiment three：Degradable compound EP rubbers cable joint-box, including according to the following raw material of mass fraction meter：EP rubbers
27 parts, 4.3 parts of polyacrylamide, 14.7 parts of methacrylic acid, 13.1 parts of halogen type fire proofing, halogen containing flame-retardant 2.5
Part, 17.4 parts of makrolon, 7.9 parts of PVP, 5.23 parts of hydroxymethyl cellulose, polyglycolic acid 3.14
Part, 2.4 parts of shitosan, 1.45 parts of triethyl phosphate.
Claims (4)
1. a kind of degradable compound EP rubbers cable joint-box, it is characterised in that：Including the following raw material according to mass fraction meter：
EP rubbers 25-28 parts, polyacrylamide 4-5 parts, methacrylic acid 14-15 parts, it is 13-14 parts of halogen type fire proofing, halogen
2.5 parts of fire retardant, makrolon 17-18 parts, PVP 7-9 parts, hydroxymethyl cellulose 5-6 parts, poly- hydroxyl second
It is sour 3-4 parts, shitosan 2-3 parts, triethyl phosphate 1-1.5 parts.
2. degradable compound EP rubbers cable joint-box according to claim 1, it is characterised in that：Including according to mass parts
The following raw material of number meter：25 parts of EP rubbers, 4 parts of polyacrylamide, 14 parts of methacrylic acid, halogen type fire proofing 13
Part, 2.5 parts of halogen containing flame-retardant, 17 parts of makrolon, 7 parts of PVP, 5 parts of hydroxymethyl cellulose, poly- hydroxyl
3 parts of guanidine-acetic acid, 2 parts of shitosan, 1 part of triethyl phosphate.
3. degradable compound EP rubbers cable joint-box according to claim 1, it is characterised in that：Including according to mass parts
The following raw material of number meter：28 parts of EP rubbers, 5 parts of polyacrylamide, 15 parts of methacrylic acid, halogen type fire proofing 14
Part, 2.5 parts of halogen containing flame-retardant, 18 parts of makrolon, 9 parts of PVP, 6 parts of hydroxymethyl cellulose, poly- hydroxyl
4 parts of guanidine-acetic acid, 3 parts of shitosan, 1.5 parts of triethyl phosphate.
4. degradable compound EP rubbers cable joint-box according to claim 1, it is characterised in that：Including according to mass parts
The following raw material of number meter：27 parts of EP rubbers, 4.3 parts of polyacrylamide, 14.7 parts of methacrylic acid, containing bittern type flame-retarded material
13.1 parts of material, 2.5 parts of halogen containing flame-retardant, 17.4 parts of makrolon, 7.9 parts of PVP, hydroxylmethyl cellulose
5.23 parts of element, 3.14 parts of polyglycolic acid, 2.4 parts of shitosan, 1.45 parts of triethyl phosphate.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201510770531.3A CN106700276A (en) | 2015-11-12 | 2015-11-12 | Degradable composite ethylene propylene rubber cable sleeve |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201510770531.3A CN106700276A (en) | 2015-11-12 | 2015-11-12 | Degradable composite ethylene propylene rubber cable sleeve |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN106700276A true CN106700276A (en) | 2017-05-24 |
Family
ID=58929618
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201510770531.3A Withdrawn CN106700276A (en) | 2015-11-12 | 2015-11-12 | Degradable composite ethylene propylene rubber cable sleeve |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN106700276A (en) |
-
2015
- 2015-11-12 CN CN201510770531.3A patent/CN106700276A/en not_active Withdrawn
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PB01 | Publication | ||
| PB01 | Publication | ||
| WW01 | Invention patent application withdrawn after publication | ||
| WW01 | Invention patent application withdrawn after publication |
Application publication date: 20170524 |