CN106699231A - Preparation method of dyeing seal hardening agent for concrete - Google Patents
Preparation method of dyeing seal hardening agent for concrete Download PDFInfo
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- CN106699231A CN106699231A CN201611043477.3A CN201611043477A CN106699231A CN 106699231 A CN106699231 A CN 106699231A CN 201611043477 A CN201611043477 A CN 201611043477A CN 106699231 A CN106699231 A CN 106699231A
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- stirring
- concrete
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- room temperature
- distilled water
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Classifications
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- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B41/00—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
- C04B41/60—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone of only artificial stone
- C04B41/61—Coating or impregnation
- C04B41/65—Coating or impregnation with inorganic materials
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B41/00—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
- C04B41/45—Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements
- C04B41/50—Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements with inorganic materials
- C04B41/5072—Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements with inorganic materials with oxides or hydroxides not covered by C04B41/5025
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2111/00—Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
- C04B2111/20—Resistance against chemical, physical or biological attack
- C04B2111/2038—Resistance against physical degradation
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2111/00—Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
- C04B2111/80—Optical properties, e.g. transparency or reflexibility
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Ceramic Engineering (AREA)
- Inorganic Chemistry (AREA)
- Materials Engineering (AREA)
- Structural Engineering (AREA)
- Organic Chemistry (AREA)
- Sealing Material Composition (AREA)
- Paints Or Removers (AREA)
Abstract
The invention relates to the technical field of building materials and aims to provide a preparation method of a dyeing seal hardening agent for concrete. The preparation method comprises the following steps: firstly, taking half of ethanol and distilled water by mass; stirring uniformly, and then adding pseudo-boehmite sol and acrylic resin emulsion; heating, stirring and then cooling to a room temperature; taking the remaining ethanol and distilled water, stirring in another container uniformly; then, adding an inorganic pigment and a surfactant; stirring at a room temperature; mixing and stirring the two obtained mixtures; adding a silane coupling agent; stirring and then adding nano-rigid particles; stirring and then performing ultrasonic treatment; stirring under a condition of water bath; cooling to a room temperature after completing the reaction to obtain a product. The preparation method provided by the invention can change surface color of concrete; the product is a water-based material and convenient to construct; the treated concrete ground has characteristics of high hardness, high wear resistance, high gloss and the like; the dyeing seal hardening agent is simple in preparation process, easy in reaction process control, mild in reaction condition, and especially suitable for large-scale industrial production.
Description
Technical field
It is a kind of preparation side of concrete dyeing hardening sealant agent specifically the invention belongs to building material field
Method.
Background technology
Concrete is the maximum manufactured construction materials of mankind's usage amount, is widely used in all kinds of Structural Engineerings；But based on mixed
Solidifying soil material is in itself and construction level is limited, and the breakage already such as many infrastructure, Industrial Plant Ground be can't bear, and hole occurs in surface
Hole, weathering, dirt, dusting, skin effect phenomenon, cause to wear no resistance, and service life is short, does not adapt to modern production environment
Demand, be badly in need of transformation；To solve this problem, instead scheme generally has laying timber floor, floor tile or directly applies
Cover one layer of epoxies floor paint etc.；But such scheme all cost performances are too low, field of employment is limited, such as laying ceramic tile or floor tile,
Except artificial and in addition to material cost is costly, it is often more important that field of employment is limited, typically can be used only in household ground or
More lightly face loaded, as run into the loading demands such as industrial premises, machine shop high field institute, then cannot significantly shorten in the life-span,
And the impervious poor performance such as grease proofing；And it is short to coat epoxies floor paint one side service life, occurs after generally using 2 years or so
Warp, the phenomenon such as delamination, better performances extend to 5 years, but the life-span is still shorter；On the other hand, epoxies floor paint is not
Environmental protection, VOC discharge capacities are higher, big to workmen's actual bodily harm.
Defect in technology and performance based on the said goods, in the last few years numerous scholars have developed dedicated for
The curing agent of mattess, can greatly improve its service life.At present, most ground hardening agents is used on domestic and international market
Material mainly has two classes：One class is lithium base salt product, and this kind of curing agent can greatly improve the abrasion resistance of concrete, glossiness etc.
Performance, and the common fault of the whiting of early stage product appearance limited can be avoided, thus it is very popular；Such as CN101618956A,
CN200910055825 and CN201110083155.2 etc. is disclosed all with lithium base salt (lithium metasilicate) as main component, with concrete
Humidification is played after reacting, then adds magnesium fluosilicate, silane emulsion, paraffin etc. increases packing, the glossiness of concrete
Etc. performance；But its active constituent content is relatively low, single brought concrete performance lifting of constructing is few, and done product gloss
Durability and weatherability are poor, and gloss goes down substantially in the short period.It is another kind of be with Nano silica sol (such as
CN201010543000.8) or boehmite sol (CN105645835A) be main component hardening sealant agent, wherein, in Ludox
Containing a large amount of silicon oxygen bonds, the afwillite (C-S-H) of concrete abrasion-resistant performance can be improved with concrete reaction generation, and vigorous nurse
Stone colloidal sol can improve the calcium aluminate of its intensity with calcium ion and water generation；Above-mentioned formula can be effectively improved and to lift concrete hard
The performances such as degree, wearability.As people are to the diversified increase in demand in ground, not only durable but also attractive in appearance product is progressively pursued in beginning
In product, especially concrete apparent colour, but patent described above, there is no a kind of technology to improve concrete basic nature
Can, its appearance luster can be changed again, thus application choice is small.
The content of the invention
The technical problem to be solved in the present invention is to overcome deficiency of the prior art, there is provided the hardening of one kind collection and dyeing work(
The concrete that can the be integrated preparation method for dyeing hardening sealant agent.
To solve technical problem, solution of the invention is：
The preparation method that a kind of concrete dyes hardening sealant agent is provided, is comprised the following steps：
(1) each component is weighed by following quality proportionings：Boehmite colloidal sol 25%~65%, emulsion acrylic resin
4%~10%, surfactant 0.1%~1%, silane coupler 3%~8%, nano redigity particle 1%~5%, inorganic color
Powder 1%~6%, ethanol 6%~11%, balance of distilled water；The nano redigity particle is SiC, BC4、C3N4、Fe3O4Or
TiO2In the combination of one or more；
(2) ethanol and distilled water of half quality are first taken, is placed in container and is stirred；It is subsequently added boehmite molten
Glue and emulsion acrylic resin；20~50 DEG C are heated to, and 20~60min is stirred with the speed of 150~300rmp, then cooled down
To room temperature；
(3) remaining ethanol and distilled water are taken, is placed in another container and is stirred；Sequentially add inorganic toner and surface
Activating agent, then stirs 40~80min with the speed of 150~300rmp at room temperature；
(4) step (2) gained mixture is added into step (3) gained mixture, persistently stirs 20~60min, stirred
Mix 300~800rmp of speed；
(5) to silane coupler is added in step (4) gained mixture, nano redigity particle is added after stirring, fully
Ultrasonically treated 15min after stirring；It is then transferred in water-bath, 1~4h is stirred under 20~80 DEG C of water bath conditions, keeps 150
The stir speed (S.S.) of~500rmp is constant；Room temperature is down to after the completion of question response, products therefrom is concrete dyeing hardening sealant
Agent.
In the step (5), it is further continued for stirring 20min after silane coupler is added；When ultrasonically treated, control ultrasound
Frequency is 2000Hz, ultrasonic power 350W.
In the present invention, the solid content of the boehmite colloidal sol is 20~50%, and average grain diameter is 45nm；Its molecular formula
It is AlOOHnH2O, n=0.08~0.62.
In the present invention, the solid content of the emulsion acrylic resin is 30~50%, its decentralized medium is distilled water, go from
The combination of one or more in sub- water or ethanol.
In the present invention, the surfactant is cetyl trimethylammonium bromide (CTAB), polyethylene glycol 2000
(PEG2000), the combination of one or more in neopelex (SDBS) or polyvinylpyrrolidone (PVP).
In the present invention, the silane coupler is 3- ureas propyl trimethoxy silicane (KH592) or dilute through absolute ethyl alcohol
3- urea propyl trimethoxy silicane dilutions after releasing, absolute ethyl alcohol is 0~50: 1 with the mass ratio of KH592.
In the present invention, the particle diameter of the nano redigity particle is 30~70nm.
In the present invention, the inorganic toner is mixed with talcum powder by inorganic mineral pigments, and its mass ratio is 2:1.
Inventive principle is described：
The primary raw material composition of concrete dyeing hardening sealant agent of the present invention is nanoscale boehmite (AlOOH
nH2The colloidal sol of O, n=0.08~0.62), boehmite colloidal sol is typically used as ceramics, the catalyst of refractory fibrous material, bonds
Agent etc., but in the present invention, can be penetrated into concrete pore in the presence of surfactant and silane coupler are common
Hydrated product calcium hydroxide and unhydrated cement in portion and concrete react, and generate big point of network-like cross-linked structure
Sub- gel, fill concrete hole makes its closely knit, furthermore, boehmite colloidal sol also reacts generation with the calcium ion in concrete
The main component calcium aluminate of alumina cement, so as to further enhance concrete, while metal ion content in concrete is reduced again,
Advantageously reduce the infringement caused by alkali-aggregate reaction in former concrete；Additionally, the inorganic mineral in the present invention in inorganic toner
Particle uniformly mixes by with boehmite colloidal sol, and together penetrates into concrete ion exchange occurs therewith, so as to change
Become concrete color.Nano redigity particle in product of the present invention can improve concrete hardness and wearability；In addition, in the present invention
The addition of emulsion acrylic resin improve the surface gloss and hydrophobic performance of concrete；Added into present invention utilizes each
The above-mentioned characteristic divided, so as to develop a kind of new concrete hardening sealant agent for collecting hardening and dyeing one.
Compared with prior art, the advantage of the invention is that：
(1) present invention in add nano-particle inorganic toner in the presence of surfactant and silane coupler, compared with
It is scattered in well in whole network shape sol system, and together infiltrates into concrete pore, so that it is apparent to change concrete
Color and luster, reaches visual aesthetic feeling, solves the problems, such as different crowd to terrace diversity requirements；
(2) present invention is water-based material, easy construction, directly large area roller coating or can be sprayed into concrete surface and applied
Work, has the characteristics such as high rigidity, high-wearing feature, high glaze through the mattess after treatment, and gloss is got over about lasting, surface
Show gloss as waxing；
(3) present invention is the novel product for collecting concrete hardening and dyeing one, and its preparation process is simple, course of reaction is held
Easy to control, reaction condition is gentle, also non-volatility toxic gas in reaction, environmentally safe, and raw material is simple, low cost,
It is particularly suitable for large-scale industrial production.
Specific embodiment
The present invention is described in further detail below in conjunction with embodiment, it will be appreciated by those skilled in the art that
The following example is merely to illustrate the present invention, and should not be taken as limiting the scope of the invention.
The dyeing hardening sealant agent of heretofore described concrete, is blended by the raw material components of following mass percents
：Boehmite colloidal sol 25%~65%, emulsion acrylic resin 4%~10%, surfactant 0.1%~1%,
Silane coupler 3%~8%, nano redigity particle 1%~5%, inorganic toner 1%~6%, ethanol 6%~11% is balance of
Distilled water；The nano redigity particle is SiC, BC4、C3N4、Fe3O4Or TiO2In the combination of one or more.
The concrete preparation method of dyeing hardening sealant agent, comprises the following steps：
(1) each component is weighed by following quality proportionings：Boehmite colloidal sol 25%~65%, emulsion acrylic resin
4%~10%, surfactant 0.1%~1%, silane coupler 3%~8%, nano redigity particle 1%~5%, inorganic color
Powder 1%~6%, ethanol 6%~11%, balance of distilled water；The nano redigity particle is SiC, BC4、C3N4、Fe3O4Or
TiO2In the combination of one or more；
(2) ethanol and distilled water of half quality are first taken, is placed in container and is stirred；It is subsequently added boehmite molten
Glue and emulsion acrylic resin；20~50 DEG C are heated to, and 20~60min is stirred with the speed of 150~300rmp, then cooled down
To room temperature；
(3) remaining ethanol and distilled water are taken, is placed in another container and is stirred；Sequentially add inorganic toner and surface
Activating agent, then stirs 40~80min with the speed of 150~300rmp at room temperature；
(4) step (2) gained mixture is added into step (3) gained mixture, persistently stirs 20~60min, stirred
Mix 300~800rmp of speed；
(5) to silane coupler is added in step (4) gained mixture, nano redigity particle is added after stirring, fully
Ultrasonically treated 15min after stirring；It is then transferred in water-bath, 1~4h is stirred under 20~80 DEG C of water bath conditions, keeps 150
The stir speed (S.S.) of~500rmp is constant；Room temperature is down to after the completion of question response, products therefrom is concrete dyeing hardening sealant
Agent.
Operated as further optimization, in the step (5), be further continued for stirring 20min after silane coupler is added；
When ultrasonically treated, it is 2000Hz, ultrasonic power 350W to control supersonic frequency.
Test data in each embodiment see the table below：
Note：Boehmite colloidal sol in form, surfactant, emulsion acrylic resin, silane coupler, nanometer are firm
The percentage composition (% numerical value) of property particle, inorganic toner, ethanol and distilled water, refers to that the component accounts for whole raw materials in this step
The percentage of constituent mass summation.
The application method of concrete dyeing hardening sealant agent is obtained by of the invention：
Mattess is first ground successively with the abrasive sheet of various different models, then by product of the present invention (i.e. concrete
Dyeing hardening sealant agent) directly roller coating or it is sprayed on polished ground and (can as requested adjusts the inorganic of different colours
Toner), keep earth's surface to be hardened the infiltration of agent product in 1h, then it is ground.Wherein, this product consumption be about 0.1~
0.5kg/㎡。
Greatly improved through the performance such as the concrete hardness after treatment, glossiness, impervious, anti-skidding, and various color and lusters are available for adjusting
Whole and selection.After construction processing of the present invention, the Mohs' hardness on ground can improve 1~3 grade than original ground, and abrasion resistance is improved
More than 200%, glossiness improves more than 50%, and the glossiness of 60 ° of angle incident lights can reach 85 °.Additionally, dry friction coefficient
Up to 0.85, while penetration depth is in 2~8mm.
Claims (8)
1. a kind of concrete use dyes the preparation method of hardening sealant agent, it is characterised in that comprise the following steps：
(1) each component is weighed by following quality proportionings：Boehmite colloidal sol 25%~65%, emulsion acrylic resin 4%~
10%, surfactant 0.1%~1%, silane coupler 3%~8%, nano redigity particle 1%~5%, inorganic toner 1%
~6%, ethanol 6%~11%, balance of distilled water；The nano redigity particle is SiC, BC4、C3N4、Fe3O4Or TiO2In
The combination of one or more；
(2) ethanol and distilled water of half quality are first taken, is placed in container and is stirred；Be subsequently added boehmite colloidal sol and
Emulsion acrylic resin；20~50 DEG C are heated to, and 20~60min is stirred with the speed of 150~300rmp, be subsequently cooled to room
Temperature；
(3) remaining ethanol and distilled water are taken, is placed in another container and is stirred；Sequentially add inorganic toner and surface-active
Agent, then stirs 40~80min with the speed of 150~300rmp at room temperature；
(4) step (2) gained mixture is added into step (3) gained mixture, persistently stirs 20~60min, stirring speed
300~800rmp of rate；
(5) to silane coupler is added in step (4) gained mixture, nano redigity particle is added after stirring, is sufficiently stirred for
Ultrasonically treated 15min afterwards；It is then transferred in water-bath, 1~4h of stirring under 20~80 DEG C of water bath conditions, holding 150~
The stir speed (S.S.) of 500rmp is constant；Room temperature is down to after the completion of question response, products therefrom is concrete dyeing hardening sealant agent.
2. method according to claim 1, it is characterised in that in the step (5), after silane coupler is added followed by
Continuous stirring 20min；When ultrasonically treated, it is 2000Hz, ultrasonic power 350W to control supersonic frequency.
3. method according to claim 1, it is characterised in that the solid content of the boehmite colloidal sol is 20~
50%, average grain diameter is 45nm；Its molecular formula is AlOOHnH2O, n=0.08~0.62.
4. method according to claim 1, it is characterised in that the solid content of the emulsion acrylic resin is 30~
50%, its decentralized medium is the combination of one or more in distilled water, deionized water or ethanol.
5. method according to claim 1, it is characterised in that the surfactant is cetyl trimethyl bromination
The combination of one or more in ammonium, polyethylene glycol 2000, neopelex or polyvinylpyrrolidone.
6. method according to claim 1, it is characterised in that the silane coupler is 3- urea propyl trimethoxy silicanes
Or the 3- urea propyl trimethoxy silicane dilutions after being diluted through absolute ethyl alcohol, the mass ratio of absolute ethyl alcohol and KH592 for 0~
50∶1。
7. method according to claim 1, it is characterised in that the particle diameter of the nano redigity particle is 30~70nm.
8. method according to claim 1, it is characterised in that the inorganic toner is by inorganic mineral pigments and talcum powder
Mix, its mass ratio is 2:1.
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| CN201611043477.3A CN106699231B (en) | 2016-11-24 | 2016-11-24 | A kind of preparation method of concrete dyeing hardening sealant agent |
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| CN201611043477.3A CN106699231B (en) | 2016-11-24 | 2016-11-24 | A kind of preparation method of concrete dyeing hardening sealant agent |
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Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108002779A (en) * | 2017-12-11 | 2018-05-08 | 浙江大学自贡创新中心 | A kind of concrete land used surface mending agent |
| CN109535879A (en) * | 2018-12-15 | 2019-03-29 | 浙江大学自贡创新中心 | A kind of preparation method of terrace antilubricant |
| CN109761576A (en) * | 2019-03-20 | 2019-05-17 | 深圳市航天新材科技有限公司 | A kind of functional seal curing agent and preparation method thereof |
Citations (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1271799A (en) * | 1999-04-28 | 2000-11-01 | 牛文禄 | Hardened artiwear ground and its construction method |
| CN103755381A (en) * | 2014-01-10 | 2014-04-30 | 陆天献 | Nano color concrete sealing and curing agent |
| CN104788124A (en) * | 2015-04-13 | 2015-07-22 | 哈尔滨中建璟园科技开发有限公司 | Coloring agent for concrete ground and preparation method of coloring agent |
| CN104926263A (en) * | 2015-05-27 | 2015-09-23 | 英杰惠能（北京）能源新技术有限公司 | Water-based inorganic ceramic coating, and preparation method and using method thereof |
| CN105272357A (en) * | 2014-05-26 | 2016-01-27 | 株式会社友利产业开发 | Composition for coloring surface of concrete |
| CN105503264A (en) * | 2015-11-25 | 2016-04-20 | 浙江大学自贡创新中心 | Method for preparing foam concrete nano reinforcing agent |
| CN105800998A (en) * | 2016-03-21 | 2016-07-27 | 深圳市纳路特科技有限公司 | Ultra-nanometer color concrete seal solidification agent |
-
2016
- 2016-11-24 CN CN201611043477.3A patent/CN106699231B/en active Active
Patent Citations (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1271799A (en) * | 1999-04-28 | 2000-11-01 | 牛文禄 | Hardened artiwear ground and its construction method |
| CN103755381A (en) * | 2014-01-10 | 2014-04-30 | 陆天献 | Nano color concrete sealing and curing agent |
| CN105272357A (en) * | 2014-05-26 | 2016-01-27 | 株式会社友利产业开发 | Composition for coloring surface of concrete |
| CN104788124A (en) * | 2015-04-13 | 2015-07-22 | 哈尔滨中建璟园科技开发有限公司 | Coloring agent for concrete ground and preparation method of coloring agent |
| CN104926263A (en) * | 2015-05-27 | 2015-09-23 | 英杰惠能（北京）能源新技术有限公司 | Water-based inorganic ceramic coating, and preparation method and using method thereof |
| CN105503264A (en) * | 2015-11-25 | 2016-04-20 | 浙江大学自贡创新中心 | Method for preparing foam concrete nano reinforcing agent |
| CN105800998A (en) * | 2016-03-21 | 2016-07-27 | 深圳市纳路特科技有限公司 | Ultra-nanometer color concrete seal solidification agent |
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108002779A (en) * | 2017-12-11 | 2018-05-08 | 浙江大学自贡创新中心 | A kind of concrete land used surface mending agent |
| CN108002779B (en) * | 2017-12-11 | 2020-04-24 | 浙江大学自贡创新中心 | Ground repairing agent for concrete |
| CN109535879A (en) * | 2018-12-15 | 2019-03-29 | 浙江大学自贡创新中心 | A kind of preparation method of terrace antilubricant |
| CN109761576A (en) * | 2019-03-20 | 2019-05-17 | 深圳市航天新材科技有限公司 | A kind of functional seal curing agent and preparation method thereof |
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| CN106699231B (en) | 2019-04-19 |
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