CN106699139A - Ceramic material for grinding head - Google Patents

Ceramic material for grinding head Download PDF

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Publication number
CN106699139A
CN106699139A CN201710059716.2A CN201710059716A CN106699139A CN 106699139 A CN106699139 A CN 106699139A CN 201710059716 A CN201710059716 A CN 201710059716A CN 106699139 A CN106699139 A CN 106699139A
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grinding head
purity
interior
ceramic material
silica
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CN201710059716.2A
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CN106699139B (en
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张国平
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NINGBO CHUJU CHUFANG TECHNOLOGY Co Ltd
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NINGBO CHUJU CHUFANG TECHNOLOGY Co Ltd
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    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B35/00Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products
    • C04B35/01Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products based on oxide ceramics
    • C04B35/10Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products based on oxide ceramics based on aluminium oxide
    • AHUMAN NECESSITIES
    • A47FURNITURE; DOMESTIC ARTICLES OR APPLIANCES; COFFEE MILLS; SPICE MILLS; SUCTION CLEANERS IN GENERAL
    • A47JKITCHEN EQUIPMENT; COFFEE MILLS; SPICE MILLS; APPARATUS FOR MAKING BEVERAGES
    • A47J42/00Coffee mills; Spice mills
    • A47J42/38Parts or details
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B35/00Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products
    • C04B35/622Forming processes; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products
    • C04B35/626Preparing or treating the powders individually or as batches ; preparing or treating macroscopic reinforcing agents for ceramic products, e.g. fibres; mechanical aspects section B
    • C04B35/63Preparing or treating the powders individually or as batches ; preparing or treating macroscopic reinforcing agents for ceramic products, e.g. fibres; mechanical aspects section B using additives specially adapted for forming the products, e.g.. binder binders
    • C04B35/6303Inorganic additives
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2235/00Aspects relating to ceramic starting mixtures or sintered ceramic products
    • C04B2235/02Composition of constituents of the starting material or of secondary phases of the final product
    • C04B2235/30Constituents and secondary phases not being of a fibrous nature
    • C04B2235/32Metal oxides, mixed metal oxides, or oxide-forming salts thereof, e.g. carbonates, nitrates, (oxy)hydroxides, chlorides
    • C04B2235/3205Alkaline earth oxides or oxide forming salts thereof, e.g. beryllium oxide
    • C04B2235/3206Magnesium oxides or oxide-forming salts thereof
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2235/00Aspects relating to ceramic starting mixtures or sintered ceramic products
    • C04B2235/02Composition of constituents of the starting material or of secondary phases of the final product
    • C04B2235/30Constituents and secondary phases not being of a fibrous nature
    • C04B2235/32Metal oxides, mixed metal oxides, or oxide-forming salts thereof, e.g. carbonates, nitrates, (oxy)hydroxides, chlorides
    • C04B2235/3231Refractory metal oxides, their mixed metal oxides, or oxide-forming salts thereof
    • C04B2235/3232Titanium oxides or titanates, e.g. rutile or anatase
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2235/00Aspects relating to ceramic starting mixtures or sintered ceramic products
    • C04B2235/02Composition of constituents of the starting material or of secondary phases of the final product
    • C04B2235/30Constituents and secondary phases not being of a fibrous nature
    • C04B2235/32Metal oxides, mixed metal oxides, or oxide-forming salts thereof, e.g. carbonates, nitrates, (oxy)hydroxides, chlorides
    • C04B2235/3231Refractory metal oxides, their mixed metal oxides, or oxide-forming salts thereof
    • C04B2235/3244Zirconium oxides, zirconates, hafnium oxides, hafnates, or oxide-forming salts thereof
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2235/00Aspects relating to ceramic starting mixtures or sintered ceramic products
    • C04B2235/02Composition of constituents of the starting material or of secondary phases of the final product
    • C04B2235/30Constituents and secondary phases not being of a fibrous nature
    • C04B2235/34Non-metal oxides, non-metal mixed oxides, or salts thereof that form the non-metal oxides upon heating, e.g. carbonates, nitrates, (oxy)hydroxides, chlorides
    • C04B2235/3418Silicon oxide, silicic acids, or oxide forming salts thereof, e.g. silica sol, fused silica, silica fume, cristobalite, quartz or flint

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  • Engineering & Computer Science (AREA)
  • Chemical & Material Sciences (AREA)
  • Ceramic Engineering (AREA)
  • Manufacturing & Machinery (AREA)
  • Materials Engineering (AREA)
  • Structural Engineering (AREA)
  • Organic Chemistry (AREA)
  • Inorganic Chemistry (AREA)
  • Mechanical Engineering (AREA)
  • Food Science & Technology (AREA)
  • Compositions Of Oxide Ceramics (AREA)
  • Polishing Bodies And Polishing Tools (AREA)

Abstract

The invention relates to a ceramic material for a grinding head. The ceramic material comprises an outer grinding head material and an inner grinding head material, wherein the outer grinding head material is prepared from the following raw materials in percentage by weight: 80-90% of aluminum oxide of which the purity is greater than or equal to 99%, 5-15% of magnesium oxide, 3-10% of silicon oxide and 3-5% of titanium dioxide; and the inner grinding head material is prepared from the following raw materials in percentage by weight: 50-60% of aluminum oxide of which the purity is greater than or equal to 99%, 20-30% of zirconium oxide of which the purity is greater than or equal to 94%, 5-15% of magnesium oxide, 3-10% of silicon oxide and 12-20% of titanium dioxide. Through the ceramic material, the defects of the existing ceramic material can be overcome, the aim that the outer grinding head material and the inner grinding head material are manufactured by ceramics is achieved, the dosage of the zirconium oxide is reduced, and thus the production cost is lowered.

Description

A kind of grinding head ceramic material
Technical field
The invention belongs to kitchen tools and ceramic material field, a kind of ceramics for producing mill for kitchen use are specifically referred to Bistrique material is constituted.
Background technology
The mode that now particulate species flavouring is crushed substantially has three kinds:A kind of entered in traditional mode such as smash to pieces Row grinding;One kind is taken at any time after flavouring is largely crushed;Another is to measure to grind at any time as needed.These three In mode, traditional approach grinding is wasted time and energy, and the equipment smashed to pieces is larger, in-convenience in use.Flavouring is carried out into a large amount of powder The mode that can be taken at any time after broken, it is upper relatively simple from using, but the shortcoming of this mode is after flavouring is pulverized, to break The guard system of former flavouring is broken, causes oxidation reaction to be accelerated, easily made flavouring reduction or lose its effect.In order to change The shortcoming of above two flavouring grinding mode, is widely used with a kind of Manual polisher with mill now.And this The small volume of device, it is easy to use, can be placed directly on dining table, flavouring is voluntarily ground according to personal taste.
The Manual polisher for now using consists essentially of following components, and housing, for accommodating particulate species flavouring, is pacified Loaded on the mill on housing, mill has generally comprised interior grinding machine head, outer grinding machine head and lid etc..According to the mode for using not Together, interior grinding machine head rotation and outer grinding machine head rotation mill can be divided into.Need to mill mill is also with good grounds Crush the device that is adjusted of grain graininess of flavouring, and the structure such as lid for health.It can be said that it is existing it is all of this Class Manual polisher is not only realized with the function with mill, and increased the enjoyment of diet.
The material for being now used to manufacture mill bistrique has metal or highstrenghtpiston, also has technology to consider to use stone material, but Be stone material intensity it is not high and easily split and cannot really come into operation.The intensity of metal grinding head is fine, but resistant to chemical etching Property is poor, if do not use just having corrosion phenomena for some time.Highstrenghtpiston can also use as bistrique, but its is wear-resisting Property it is poor, after a period of time, gap between bistrique increases so that the frequency for changing bistrique is higher.
For this problem, prior art proposes to use ceramics as bistrique material, but because the poor ductility of ceramics, must Assembling must be completed in mold process or is assembled after just burn, and to ensure to have been sintered finally in an assembling process Can keep relatively rotating after, gap is ensure that again less, its manufacture difficulty is excessive and high cost, hardly results in and pushes away Extensively.Therefore, the ceramic bistrique for now using is one side, i.e., only outer grinding head or interior grinding head are ceramics manufacture, another side It is metal or highstrenghtpiston.
Therefore, applicant proposes a kind of ceramic grinding head material technical scheme of mill, and in the technical program, grinding The inside and outside of the grinding head of device uses ceramic material, and material composition and the material composition of outer grinding head by interior grinding head Difference overcome because the poor ductility of ceramics, the inside and outside of grinding head use the big problem of manufacture difficulty of ceramic material.
In the technical program, the material of outer grinding head constitutes and is by weight percentage, the aluminum oxide of 80%-90%, The magnesia of 5%-15% and the silica of 3-10%;The material of interior grinding head is constituted, 25%-45%'s The silica of aluminum oxide, the zirconium oxide of 45%-55%, the magnesia of 5%-15% and 3%-10%.Existed using zirconia ceramics Volume Changes can occur during by the opposite tetragonal phase converting of monocline, and volume can round about occur in cooling and become The phenomenon of change, and aluminum oxide, in temperature changing process, the change of volume can be ignored, and the change of its volume after assembling Meet last clearance requirement.
But in this technology, largely using zirconia components, zirconium oxide it is relatively costly, cause the cost of final products It is higher.
The content of the invention
It is an object of the invention to provide a kind of grinding head ceramic material, existing ceramic material can be overcome by this material The defect of material, realizes that outer grinding head material and interior grinding-material are manufactured using ceramics, and reduce production cost.
The present invention is achieved by the following technical solutions:
A kind of grinding head ceramic material, includes outer grinding head material and interior grinding head material;The outer grinding head material Material is constituted by weight percentage, the aluminum oxide 80%-90% of purity >=99%, magnesia 5%-15%, silica 3%- 10% and titanium dioxide 3%-5%;The interior grinding head material constitutes and is by weight percentage, the aluminum oxide of purity >=99% 50%-60%, the zirconium oxide 20%-30% of purity >=94%, magnesia 5%-15%, silica 3%-10% and titanium dioxide 12%-20%.
Preferably, the amount of titanium in the interior grinding head is the titanium dioxide in the outer grinding head 3-5 times of consumption.
Preferably, the consumption sum and the interior grinding head of the magnesia in the outer grinding head and the silica In the magnesia it is equal with the consumption sum of the silica.
Preferably, the outer grinding head material constitutes and is by weight percentage, the aluminum oxide 82.5%, oxygen of purity >=99% Change magnesium 8%, silica 6% and titanium dioxide 3.5%;The interior grinding head material constitutes and is by weight percentage, and purity >= The zirconium oxide 20% of 99% aluminum oxide 52%, purity >=94%, magnesia 7%, silica 7% and titanium dioxide 14%.
Further, inhibitor is also included, described inhibitor is saturated calcium hydroxide solution.
The outer grinding head into molding pressure be 420MPa-450MPa, interior grinding head into molding pressure be 420MPa- 450MPa;And interior grinding head into molding pressure more than outer grinding head into molding pressure.
The beneficial effects of the invention are as follows:
By the technical program, can realize that the interior grinding head and outer grinding head of mill bistrique process common burning simultaneously System, and Volume Changes can occur during by the opposite tetragonal phase converting of monocline using zirconia ceramics, and in cooling The phenomenon of Volume Changes can occur round about again, and aluminum oxide, in temperature changing process, the change of volume can be ignored, And the change of its volume meets last clearance requirement after assembling.
Meanwhile, the application by adding titanium dioxide component in interior grinding head and outer grinding head, and by interior grinding The consumption of titanium dioxide is 3-5 times of the consumption of the titanium dioxide in outer grinding head in head, after ensureing to fire interior grinding head and The gap of outer grinding head meets outside bistrique requirement, also causes that the consumption of zirconium oxide reduces half or so.
By the use of the titanium dioxide in interior grinding head and outer grinding head so that interior grinding head after firing and grind outward The surface of bistrique is finer and smoother, while the cost of titanium dioxide is only a quarter of zirconium oxide.
Specific embodiment
Describe technical scheme in detail by the following examples, it should be appreciated that embodiment below is only It is exemplary, is only capable of for explaining and illustrating technical scheme, and is not to be construed as to technical solution of the present invention Limitation.
Because bistrique includes two parts, the mutual cooperation being ground by two parts could be realized grinding.Institute in the present invention The outer grinding head of explanation refers to the grinding outside the bistrique of mill;Interior grinding head refers to the mill inside the bistrique of mill Piece.In this application, it is described it is inside and outside be relative concept.
A kind of grinding head ceramic material, includes outer grinding head material and interior grinding head material;The outer grinding head material Material is constituted by weight percentage, the aluminum oxide 80%-90% of purity >=99%, magnesia 5%-15%, silica 3%- 10% and titanium dioxide 3%-5%;The interior grinding head material constitutes and is by weight percentage, the aluminum oxide of purity >=99% 50%-60%, the zirconium oxide 20%-30% of purity >=94%, magnesia 5%-15%, silica 3%-10% and titanium dioxide 12%-20%.
In this application, the ceramic material based on zirconium oxide is used to be mainly the thing according to zirconium oxide in interior grinding-material Change characteristic, it includes three kinds of crystallographic systems, monoclinic phase system, Tetragonal system and cubic system, and when more than 1000 DEG C, zirconium oxide meeting Tetragonal system is changed into by monoclinic phase system, in this course, volume can have greatly changed, i.e., volume increases, and cold When but, zirconium oxide can change round about again, i.e., changed from Tetragonal system to monoclinic phase system, and at this moment volume can reduce, but That when the too high levels of zirconium oxide Volume Changes can be caused excessive and ftractureed, therefore, the zirconium oxide that existing technology is used with It is based on 50 no more than weight ratio.And the application is according to research and tests, opening by interior grinding head obtained in this technology is found The rate of splitting can be disregarded.
In this application, the amount of titanium in interior grinding head is the titanium dioxide in the outer grinding head 3-5 times of consumption, preferably 4 times.
In this application, the consumption sum of the magnesia in the outer grinding head and the silica interior is ground with described The magnesia in bistrique is equal with the consumption sum of the silica, and the consumption of magnesia is not required for herein in interior grinding It is equal with consumption in outer grinding head in head, or silica is equal with the consumption in outer grinding head in interior grinding head.The application In, logical magnesia and silica are with the consumption in outer grinding head equal in the interior grinding head to balance interior grinding head and outer grinding Deflection of the head in sintering procedure so that the deflection between interior grinding head and outer grinding head passes through titanium dioxide and zirconium oxide To adjust, so while gap is ensured, accepted product percentage is improved.
Inhibitor is also included, described inhibitor is saturated calcium hydroxide solution.The use of inhibitor is primarily used to Suppress tissue overgrowth of the aluminum oxide in high temperature refining process.
The outer grinding head into molding pressure be 420MPa-450MPa, interior grinding head into molding pressure be 420MPa- 450MPa.In this application, although contain zirconium oxide in the material composition of interior grinding head, carried out by the technical scheme of the application Analysis and checking repeatedly, because the addition of titanium dioxide, it is not necessary to prevent the cracking of interior grinding head by increasing molding, because This molding by reducing interior grinding head, it is also possible to effectively reduce energy consumption.
It is described in detail below by way of specific embodiment:
Embodiment 1
In the present embodiment, outer grinding head material constitutes and is by weight percentage, the aluminum oxide 82.5% of purity >=99%, Magnesia 8%, silica 6% and titanium dioxide 3.5%;The interior grinding head material constitutes and is by weight percentage, and purity >= The zirconium oxide 20% of 99% aluminum oxide 52%, purity >=94%, magnesia 7%, silica 8% and titanium dioxide 14%.Adopt Into molding pressure be outer grinding head into molding pressure be 430MPa, interior grinding head into molding pressure be 450MPa;Just burn temperature For outer grinding head is 700 DEG C -800 DEG C, interior grinding head is 550 DEG C -600 DEG C;Then finally fired in two stages, herein Two benches refer to that temperature ramp de is carried out in two stages, final refining temperature be 1675 DEG C -1685 DEG C;Refining uses hydrogen Steam stove.The present embodiment is optimal technical solution.
Embodiment 2
In the present embodiment and later each embodiment, change be only each material composition and into molding pressure, remaining Part is same as Example 1.
Outer grinding head material constitutes and is by weight percentage, the aluminum oxide 80% of purity >=99%, magnesia 12%, oxidation Silicon 5% and titanium dioxide 3%;The interior grinding head material constitutes and is by weight percentage, the aluminum oxide 50% of purity >=99%, The zirconium oxide 25% of purity >=94%, magnesia 5%, silica 5% and titanium dioxide 15%.Use into molding pressure to grind outward Bistrique into molding pressure be 410MPa, interior grinding head into molding pressure be 430MPa.
Embodiment 3
Outer grinding head material constitutes and is by weight percentage, the aluminum oxide 85% of purity >=99%, magnesia 6%, oxidation Silicon 5% and titanium dioxide 4%;The interior grinding head material constitutes and is by weight percentage, the aluminum oxide 55% of purity >=99%, The zirconium oxide 27% of purity >=94%, magnesia 3%, silica 3% and 12%.Use into molding pressure for outer grinding head into Molding pressure is 420MPa, interior grinding head into molding pressure be 440MPa.
Embodiment 4
Outer grinding head material constitutes and is by weight percentage, the aluminum oxide 86% of purity >=99%, magnesia 3%, oxidation Silicon 6% and titanium dioxide 5%;The interior grinding head material constitutes and is by weight percentage, the aluminum oxide 51% of purity >=99%, The zirconium oxide 20% of purity >=94%, magnesia 3% and silica 6% and titanium dioxide 20%.It is outer into molding pressure to use Grinding head into molding pressure be 420MPa, interior grinding head into molding pressure be 450MPa.
The above is only the specific descriptions to technical solution of the present invention, and certain those skilled in the art can be according to this Technical scheme is improved, and these improvement should be considered as in protection scope of the present invention.

Claims (6)

1. a kind of grinding head ceramic material, includes outer grinding head material and interior grinding head material;It is characterized in that:It is described outer Grinding head material constitutes and is by weight percentage, the aluminum oxide 80%-90% of purity >=99%, magnesia 5%-15%, oxidation Silicon 3%-10% and titanium dioxide 3%-5%;The interior grinding head material constitutes and is by weight percentage, the oxygen of purity >=99% Change aluminium 50%-60%, the zirconium oxide 20%-30% of purity >=94%, magnesia 5%-15%, silica 3%-10% and dioxy Change titanium 12%-20%.
2. grinding head ceramic material according to claim 1, it is characterised in that:The dioxy in the interior grinding head Change titanium consumption is 3-5 times of the amount of titanium in the outer grinding head.
3. grinding head ceramic material according to claim 1, it is characterised in that:The oxidation in the outer grinding head The consumption sum phase of the magnesia in the consumption sum of magnesium and the silica and the interior grinding head and the silica Deng.
4. grinding head ceramic material according to claim 3, it is characterised in that:The outer grinding head material by weight hundred Point it is than composition, the aluminum oxide 82.5% of purity >=99%, magnesia 8%, silica 6% and titanium dioxide 3.5%;In described Grinding head material constitutes and is by weight percentage, the zirconium oxide 20%, oxygen of the aluminum oxide 52%, purity >=94% of purity >=99% Change magnesium 7%, silica 7% and titanium dioxide 14%.
5. grinding head ceramic material according to claim 1, it is characterised in that:Also include inhibitor, described suppression Preparation is saturated calcium hydroxide solution.
6. grinding head ceramic material according to claim 1, it is characterised in that:The outer grinding head is into molding pressure 420MPa-450MPa, interior grinding head into molding pressure be 420MPa-450MPa;And being more than into molding pressure for interior grinding head grinds outward Bistrique into molding pressure.
CN201710059716.2A 2017-01-24 2017-01-24 A kind of grinding head ceramic material Active CN106699139B (en)

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Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN111973010A (en) * 2020-08-18 2020-11-24 宁波厨聚厨房科技有限公司 Seasoning grinder provided with rotary handle
CN114073425A (en) * 2020-08-18 2022-02-22 宁波厨聚厨房科技有限公司 Portable grinder

Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102066283A (en) * 2008-06-13 2011-05-18 华盛顿密尔斯管理有限公司 Very low packing density ceramic abrasive grits and methods of producing and using the same
CN102176999A (en) * 2008-10-09 2011-09-07 法商圣高拜欧洲实验及研究中心 Abrasive molten grains
CN103387385A (en) * 2013-07-30 2013-11-13 宁波厨聚厨房科技有限公司 Ceramic grinding head material for grinder
EP2778144A1 (en) * 2013-03-11 2014-09-17 Keramik Holding AG Laufen Ceramic Material
CN105859256A (en) * 2015-02-06 2016-08-17 研磨剂与耐火品研究与开发中心C.A.R.R.D.有限公司 Sintered Shaped Abrasive Grains on Basis of Alumiunum Oxide Comprising Mineralogical Phases and a Method for Their Production

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102066283A (en) * 2008-06-13 2011-05-18 华盛顿密尔斯管理有限公司 Very low packing density ceramic abrasive grits and methods of producing and using the same
CN102176999A (en) * 2008-10-09 2011-09-07 法商圣高拜欧洲实验及研究中心 Abrasive molten grains
EP2778144A1 (en) * 2013-03-11 2014-09-17 Keramik Holding AG Laufen Ceramic Material
CN103387385A (en) * 2013-07-30 2013-11-13 宁波厨聚厨房科技有限公司 Ceramic grinding head material for grinder
CN105859256A (en) * 2015-02-06 2016-08-17 研磨剂与耐火品研究与开发中心C.A.R.R.D.有限公司 Sintered Shaped Abrasive Grains on Basis of Alumiunum Oxide Comprising Mineralogical Phases and a Method for Their Production

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN111973010A (en) * 2020-08-18 2020-11-24 宁波厨聚厨房科技有限公司 Seasoning grinder provided with rotary handle
CN114073425A (en) * 2020-08-18 2022-02-22 宁波厨聚厨房科技有限公司 Portable grinder
CN114073425B (en) * 2020-08-18 2024-04-19 宁波厨聚厨房科技有限公司 Portable grinder

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