CN106687631A - Deodorant fabric - Google Patents
Deodorant fabric Download PDFInfo
- Publication number
- CN106687631A CN106687631A CN201580028095.0A CN201580028095A CN106687631A CN 106687631 A CN106687631 A CN 106687631A CN 201580028095 A CN201580028095 A CN 201580028095A CN 106687631 A CN106687631 A CN 106687631A
- Authority
- CN
- China
- Prior art keywords
- fabric
- polyurethane elastic
- elastic yarn
- polyurethane
- weight
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 239000004744 fabric Substances 0.000 title claims abstract description 103
- 239000002781 deodorant agent Substances 0.000 title abstract description 5
- 239000004814 polyurethane Substances 0.000 claims abstract description 103
- 229920002635 polyurethane Polymers 0.000 claims abstract description 103
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 claims abstract description 69
- 238000000034 method Methods 0.000 claims abstract description 47
- 239000000835 fiber Substances 0.000 claims abstract description 44
- 229920000728 polyester Polymers 0.000 claims abstract description 37
- 238000011156 evaluation Methods 0.000 claims abstract description 33
- 238000005406 washing Methods 0.000 claims abstract description 15
- 239000004753 textile Substances 0.000 claims abstract description 10
- 238000005516 engineering process Methods 0.000 claims abstract description 9
- 125000002091 cationic group Chemical group 0.000 claims abstract description 4
- 229910021529 ammonia Inorganic materials 0.000 claims description 34
- 238000004043 dyeing Methods 0.000 claims description 26
- 150000001768 cations Chemical class 0.000 claims description 25
- 238000004332 deodorization Methods 0.000 claims description 22
- 238000001514 detection method Methods 0.000 claims description 7
- 210000004243 sweat Anatomy 0.000 abstract description 8
- 208000035985 Body Odor Diseases 0.000 abstract description 7
- 206010040904 Skin odour abnormal Diseases 0.000 abstract description 7
- 238000002156 mixing Methods 0.000 abstract description 7
- 230000001877 deodorizing effect Effects 0.000 description 43
- 238000009940 knitting Methods 0.000 description 43
- 239000000243 solution Substances 0.000 description 41
- 229920000642 polymer Polymers 0.000 description 26
- 238000009987 spinning Methods 0.000 description 22
- 208000012886 Vertigo Diseases 0.000 description 21
- 239000000975 dye Substances 0.000 description 20
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 description 18
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 18
- 150000002009 diols Chemical class 0.000 description 17
- -1 nonenyl aldehyde Chemical class 0.000 description 17
- 239000007789 gas Substances 0.000 description 16
- 230000008569 process Effects 0.000 description 16
- 238000004519 manufacturing process Methods 0.000 description 15
- 239000003795 chemical substances by application Substances 0.000 description 13
- 239000006185 dispersion Substances 0.000 description 12
- 238000000578 dry spinning Methods 0.000 description 12
- FXHOOIRPVKKKFG-UHFFFAOYSA-N N,N-Dimethylacetamide Chemical compound CN(C)C(C)=O FXHOOIRPVKKKFG-UHFFFAOYSA-N 0.000 description 10
- 230000000052 comparative effect Effects 0.000 description 9
- 239000000463 material Substances 0.000 description 9
- 239000000203 mixture Substances 0.000 description 9
- 238000012545 processing Methods 0.000 description 9
- 238000004804 winding Methods 0.000 description 9
- 229910000166 zirconium phosphate Inorganic materials 0.000 description 9
- LEHFSLREWWMLPU-UHFFFAOYSA-B zirconium(4+);tetraphosphate Chemical compound [Zr+4].[Zr+4].[Zr+4].[O-]P([O-])([O-])=O.[O-]P([O-])([O-])=O.[O-]P([O-])([O-])=O.[O-]P([O-])([O-])=O LEHFSLREWWMLPU-UHFFFAOYSA-B 0.000 description 9
- WYURNTSHIVDZCO-UHFFFAOYSA-N Tetrahydrofuran Chemical compound C1CCOC1 WYURNTSHIVDZCO-UHFFFAOYSA-N 0.000 description 7
- 150000001875 compounds Chemical class 0.000 description 7
- 150000002500 ions Chemical class 0.000 description 7
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- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 6
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 6
- 125000005442 diisocyanate group Chemical group 0.000 description 6
- UAOMVDZJSHZZME-UHFFFAOYSA-N diisopropylamine Chemical compound CC(C)NC(C)C UAOMVDZJSHZZME-UHFFFAOYSA-N 0.000 description 6
- MWUXSHHQAYIFBG-UHFFFAOYSA-N nitrogen oxide Inorganic materials O=[N] MWUXSHHQAYIFBG-UHFFFAOYSA-N 0.000 description 6
- 239000011164 primary particle Substances 0.000 description 6
- 238000012360 testing method Methods 0.000 description 6
- UNXRWKVEANCORM-UHFFFAOYSA-I triphosphate(5-) Chemical compound [O-]P([O-])(=O)OP([O-])(=O)OP([O-])([O-])=O UNXRWKVEANCORM-UHFFFAOYSA-I 0.000 description 6
- BJZYYSAMLOBSDY-QMMMGPOBSA-N (2s)-2-butoxybutan-1-ol Chemical compound CCCCO[C@@H](CC)CO BJZYYSAMLOBSDY-QMMMGPOBSA-N 0.000 description 5
- IAZDPXIOMUYVGZ-UHFFFAOYSA-N Dimethylsulphoxide Chemical compound CS(C)=O IAZDPXIOMUYVGZ-UHFFFAOYSA-N 0.000 description 5
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- 235000019832 sodium triphosphate Nutrition 0.000 description 5
- 239000002904 solvent Substances 0.000 description 5
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- 239000004411 aluminium Substances 0.000 description 4
- 150000001412 amines Chemical class 0.000 description 4
- 238000004140 cleaning Methods 0.000 description 4
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- 210000004177 elastic tissue Anatomy 0.000 description 4
- 150000002148 esters Chemical class 0.000 description 4
- 125000004836 hexamethylene group Chemical group [H]C([H])([*:2])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[*:1] 0.000 description 4
- 229910001463 metal phosphate Inorganic materials 0.000 description 4
- XFNJVJPLKCPIBV-UHFFFAOYSA-N trimethylenediamine Chemical compound NCCCN XFNJVJPLKCPIBV-UHFFFAOYSA-N 0.000 description 4
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- JOYRKODLDBILNP-UHFFFAOYSA-N Ethyl urethane Chemical compound CCOC(N)=O JOYRKODLDBILNP-UHFFFAOYSA-N 0.000 description 3
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 3
- SECXISVLQFMRJM-UHFFFAOYSA-N N-Methylpyrrolidone Chemical compound CN1CCCC1=O SECXISVLQFMRJM-UHFFFAOYSA-N 0.000 description 3
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 3
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- 239000002253 acid Substances 0.000 description 3
- 239000003963 antioxidant agent Substances 0.000 description 3
- 230000003078 antioxidant effect Effects 0.000 description 3
- GWYFCOCPABKNJV-UHFFFAOYSA-N beta-methyl-butyric acid Natural products CC(C)CC(O)=O GWYFCOCPABKNJV-UHFFFAOYSA-N 0.000 description 3
- 230000018044 dehydration Effects 0.000 description 3
- 238000006297 dehydration reaction Methods 0.000 description 3
- 239000003599 detergent Substances 0.000 description 3
- 238000010528 free radical solution polymerization reaction Methods 0.000 description 3
- 239000012948 isocyanate Substances 0.000 description 3
- 229910052751 metal Inorganic materials 0.000 description 3
- 239000002184 metal Substances 0.000 description 3
- 239000000049 pigment Substances 0.000 description 3
- 229920003226 polyurethane urea Polymers 0.000 description 3
- 230000009467 reduction Effects 0.000 description 3
- MYRTYDVEIRVNKP-UHFFFAOYSA-N 1,2-Divinylbenzene Chemical compound C=CC1=CC=CC=C1C=C MYRTYDVEIRVNKP-UHFFFAOYSA-N 0.000 description 2
- HZAXFHJVJLSVMW-UHFFFAOYSA-N 2-Aminoethan-1-ol Chemical compound NCCO HZAXFHJVJLSVMW-UHFFFAOYSA-N 0.000 description 2
- CDOWNLMZVKJRSC-UHFFFAOYSA-N 2-hydroxyterephthalic acid Chemical compound OC(=O)C1=CC=C(C(O)=O)C(O)=C1 CDOWNLMZVKJRSC-UHFFFAOYSA-N 0.000 description 2
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 2
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 description 2
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 2
- 229920000742 Cotton Polymers 0.000 description 2
- ROSDSFDQCJNGOL-UHFFFAOYSA-N Dimethylamine Chemical compound CNC ROSDSFDQCJNGOL-UHFFFAOYSA-N 0.000 description 2
- KCXVZYZYPLLWCC-UHFFFAOYSA-N EDTA Chemical compound OC(=O)CN(CC(O)=O)CCN(CC(O)=O)CC(O)=O KCXVZYZYPLLWCC-UHFFFAOYSA-N 0.000 description 2
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- RTZKZFJDLAIYFH-UHFFFAOYSA-N ether Substances CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 1
- 238000001125 extrusion Methods 0.000 description 1
- 239000010419 fine particle Substances 0.000 description 1
- 239000011737 fluorine Substances 0.000 description 1
- 229910052731 fluorine Inorganic materials 0.000 description 1
- 238000007306 functionalization reaction Methods 0.000 description 1
- KWIUHFFTVRNATP-UHFFFAOYSA-N glycine betaine Chemical compound C[N+](C)(C)CC([O-])=O KWIUHFFTVRNATP-UHFFFAOYSA-N 0.000 description 1
- 125000003827 glycol group Chemical group 0.000 description 1
- 150000002334 glycols Chemical class 0.000 description 1
- 230000036541 health Effects 0.000 description 1
- 150000002431 hydrogen Chemical class 0.000 description 1
- 239000001257 hydrogen Substances 0.000 description 1
- 229910052739 hydrogen Inorganic materials 0.000 description 1
- 229910010272 inorganic material Inorganic materials 0.000 description 1
- 239000011147 inorganic material Substances 0.000 description 1
- 230000001788 irregular Effects 0.000 description 1
- 125000000959 isobutyl group Chemical group [H]C([H])([H])C([H])(C([H])([H])[H])C([H])([H])* 0.000 description 1
- 125000001972 isopentyl group Chemical group [H]C([H])([H])C([H])(C([H])([H])[H])C([H])([H])C([H])([H])* 0.000 description 1
- NIMLQBUJDJZYEJ-UHFFFAOYSA-N isophorone diisocyanate Chemical compound CC1(C)CC(N=C=O)CC(C)(CN=C=O)C1 NIMLQBUJDJZYEJ-UHFFFAOYSA-N 0.000 description 1
- 239000004611 light stabiliser Substances 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 238000011068 loading method Methods 0.000 description 1
- 239000000314 lubricant Substances 0.000 description 1
- 239000000395 magnesium oxide Substances 0.000 description 1
- CPLXHLVBOLITMK-UHFFFAOYSA-N magnesium oxide Inorganic materials [Mg]=O CPLXHLVBOLITMK-UHFFFAOYSA-N 0.000 description 1
- 235000019359 magnesium stearate Nutrition 0.000 description 1
- AXZKOIWUVFPNLO-UHFFFAOYSA-N magnesium;oxygen(2-) Chemical compound [O-2].[Mg+2] AXZKOIWUVFPNLO-UHFFFAOYSA-N 0.000 description 1
- 238000002074 melt spinning Methods 0.000 description 1
- 238000002844 melting Methods 0.000 description 1
- 230000008018 melting Effects 0.000 description 1
- 229910021645 metal ion Inorganic materials 0.000 description 1
- 239000002480 mineral oil Substances 0.000 description 1
- 235000010446 mineral oil Nutrition 0.000 description 1
- QSOCODZVGPDGDA-UHFFFAOYSA-N n,3-dimethylbutan-1-amine Chemical compound CNCCC(C)C QSOCODZVGPDGDA-UHFFFAOYSA-N 0.000 description 1
- DAZXVJBJRMWXJP-UHFFFAOYSA-N n,n-dimethylethylamine Chemical compound CCN(C)C DAZXVJBJRMWXJP-UHFFFAOYSA-N 0.000 description 1
- XHFGWHUWQXTGAT-UHFFFAOYSA-N n-methylpropan-2-amine Chemical compound CNC(C)C XHFGWHUWQXTGAT-UHFFFAOYSA-N 0.000 description 1
- JACMPVXHEARCBO-UHFFFAOYSA-N n-pentylpentan-1-amine Chemical compound CCCCCNCCCCC JACMPVXHEARCBO-UHFFFAOYSA-N 0.000 description 1
- 229910052757 nitrogen Inorganic materials 0.000 description 1
- 229920001778 nylon Polymers 0.000 description 1
- 239000007800 oxidant agent Substances 0.000 description 1
- AUONHKJOIZSQGR-UHFFFAOYSA-N oxophosphane Chemical compound P=O AUONHKJOIZSQGR-UHFFFAOYSA-N 0.000 description 1
- IWDCLRJOBJJRNH-UHFFFAOYSA-N p-cresol Chemical compound CC1=CC=C(O)C=C1 IWDCLRJOBJJRNH-UHFFFAOYSA-N 0.000 description 1
- 230000008447 perception Effects 0.000 description 1
- 150000002989 phenols Chemical class 0.000 description 1
- DGTNSSLYPYDJGL-UHFFFAOYSA-N phenyl isocyanate Chemical compound O=C=NC1=CC=CC=C1 DGTNSSLYPYDJGL-UHFFFAOYSA-N 0.000 description 1
- 239000010452 phosphate Substances 0.000 description 1
- SDKTUKJXHDZWMB-UHFFFAOYSA-N phosphoric acid zirconium Chemical compound [Zr].P(O)(O)(O)=O SDKTUKJXHDZWMB-UHFFFAOYSA-N 0.000 description 1
- 229910052698 phosphorus Inorganic materials 0.000 description 1
- 239000011574 phosphorus Substances 0.000 description 1
- 238000001259 photo etching Methods 0.000 description 1
- 230000000704 physical effect Effects 0.000 description 1
- 229920001610 polycaprolactone Polymers 0.000 description 1
- 239000004632 polycaprolactone Substances 0.000 description 1
- 238000012643 polycondensation polymerization Methods 0.000 description 1
- 229920000570 polyether Polymers 0.000 description 1
- 238000006116 polymerization reaction Methods 0.000 description 1
- 229920001451 polypropylene glycol Polymers 0.000 description 1
- 229920002223 polystyrene Polymers 0.000 description 1
- 239000000843 powder Substances 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- BDERNNFJNOPAEC-UHFFFAOYSA-N propan-1-ol Chemical compound CCCO BDERNNFJNOPAEC-UHFFFAOYSA-N 0.000 description 1
- 239000001294 propane Substances 0.000 description 1
- 150000003242 quaternary ammonium salts Chemical class 0.000 description 1
- 150000005838 radical anions Chemical class 0.000 description 1
- 239000002516 radical scavenger Substances 0.000 description 1
- 229920005604 random copolymer Polymers 0.000 description 1
- 239000011347 resin Substances 0.000 description 1
- 229920005989 resin Polymers 0.000 description 1
- 239000000377 silicon dioxide Substances 0.000 description 1
- 235000012239 silicon dioxide Nutrition 0.000 description 1
- 239000011863 silicon-based powder Substances 0.000 description 1
- 229910052709 silver Inorganic materials 0.000 description 1
- 239000004332 silver Substances 0.000 description 1
- 239000000344 soap Substances 0.000 description 1
- 239000003381 stabilizer Substances 0.000 description 1
- 230000003068 static effect Effects 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 238000010189 synthetic method Methods 0.000 description 1
- 125000000999 tert-butyl group Chemical group [H]C([H])([H])C(*)(C([H])([H])[H])C([H])([H])[H] 0.000 description 1
- YLQBMQCUIZJEEH-UHFFFAOYSA-N tetrahydrofuran Natural products C=1C=COC=1 YLQBMQCUIZJEEH-UHFFFAOYSA-N 0.000 description 1
- 239000010936 titanium Substances 0.000 description 1
- 229910052719 titanium Inorganic materials 0.000 description 1
- OGIDPMRJRNCKJF-UHFFFAOYSA-N titanium oxide Inorganic materials [Ti]=O OGIDPMRJRNCKJF-UHFFFAOYSA-N 0.000 description 1
- JUWGUJSXVOBPHP-UHFFFAOYSA-B titanium(4+);tetraphosphate Chemical compound [Ti+4].[Ti+4].[Ti+4].[O-]P([O-])([O-])=O.[O-]P([O-])([O-])=O.[O-]P([O-])([O-])=O.[O-]P([O-])([O-])=O JUWGUJSXVOBPHP-UHFFFAOYSA-B 0.000 description 1
- DVKJHBMWWAPEIU-UHFFFAOYSA-N toluene 2,4-diisocyanate Chemical compound CC1=CC=C(N=C=O)C=C1N=C=O DVKJHBMWWAPEIU-UHFFFAOYSA-N 0.000 description 1
- 230000001052 transient effect Effects 0.000 description 1
- 238000004078 waterproofing Methods 0.000 description 1
- 238000002166 wet spinning Methods 0.000 description 1
- 229910052725 zinc Inorganic materials 0.000 description 1
- 239000011701 zinc Substances 0.000 description 1
- 229910052726 zirconium Inorganic materials 0.000 description 1
Classifications
-
- D—TEXTILES; PAPER
- D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
- D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
- D01F1/00—General methods for the manufacture of artificial filaments or the like
- D01F1/02—Addition of substances to the spinning solution or to the melt
- D01F1/10—Other agents for modifying properties
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
- D06N7/00—Flexible sheet materials not otherwise provided for, e.g. textile threads, filaments, yarns or tow, glued on macromolecular material
-
- D—TEXTILES; PAPER
- D03—WEAVING
- D03D—WOVEN FABRICS; METHODS OF WEAVING; LOOMS
- D03D15/00—Woven fabrics characterised by the material, structure or properties of the fibres, filaments, yarns, threads or other warp or weft elements used
- D03D15/50—Woven fabrics characterised by the material, structure or properties of the fibres, filaments, yarns, threads or other warp or weft elements used characterised by the properties of the yarns or threads
- D03D15/56—Woven fabrics characterised by the material, structure or properties of the fibres, filaments, yarns, threads or other warp or weft elements used characterised by the properties of the yarns or threads elastic
-
- D—TEXTILES; PAPER
- D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
- D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
- D01F6/00—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof
- D01F6/58—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof from homopolycondensation products
- D01F6/62—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof from homopolycondensation products from polyesters
-
- D—TEXTILES; PAPER
- D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
- D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
- D01F6/00—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof
- D01F6/58—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof from homopolycondensation products
- D01F6/70—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof from homopolycondensation products from polyurethanes
-
- D—TEXTILES; PAPER
- D02—YARNS; MECHANICAL FINISHING OF YARNS OR ROPES; WARPING OR BEAMING
- D02G—CRIMPING OR CURLING FIBRES, FILAMENTS, THREADS, OR YARNS; YARNS OR THREADS
- D02G3/00—Yarns or threads, e.g. fancy yarns; Processes or apparatus for the production thereof, not otherwise provided for
- D02G3/02—Yarns or threads characterised by the material or by the materials from which they are made
-
- D—TEXTILES; PAPER
- D02—YARNS; MECHANICAL FINISHING OF YARNS OR ROPES; WARPING OR BEAMING
- D02G—CRIMPING OR CURLING FIBRES, FILAMENTS, THREADS, OR YARNS; YARNS OR THREADS
- D02G3/00—Yarns or threads, e.g. fancy yarns; Processes or apparatus for the production thereof, not otherwise provided for
- D02G3/44—Yarns or threads characterised by the purpose for which they are designed
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/32—Phosphorus-containing compounds
- C08K2003/321—Phosphates
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
- D06N2209/00—Properties of the materials
- D06N2209/16—Properties of the materials having other properties
- D06N2209/165—Odour absorbing, deodorizing ability
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
- D06N2211/00—Specially adapted uses
- D06N2211/10—Clothing
-
- D—TEXTILES; PAPER
- D10—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
- D10B—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
- D10B2321/00—Fibres made from polymers obtained by reactions only involving carbon-to-carbon unsaturated bonds
- D10B2321/08—Fibres made from polymers obtained by reactions only involving carbon-to-carbon unsaturated bonds polymers of unsaturated carboxylic acids or unsaturated organic esters, e.g. polyacrylic esters, polyvinyl acetate
-
- D—TEXTILES; PAPER
- D10—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
- D10B—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
- D10B2331/00—Fibres made from polymers obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds, e.g. polycondensation products
- D10B2331/04—Fibres made from polymers obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds, e.g. polycondensation products polyesters, e.g. polyethylene terephthalate [PET]
-
- D—TEXTILES; PAPER
- D10—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
- D10B—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
- D10B2401/00—Physical properties
- D10B2401/06—Load-responsive characteristics
- D10B2401/061—Load-responsive characteristics elastic
-
- D—TEXTILES; PAPER
- D10—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
- D10B—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
- D10B2501/00—Wearing apparel
-
- D—TEXTILES; PAPER
- D10—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
- D10B—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
- D10B2509/00—Medical; Hygiene
Landscapes
- Engineering & Computer Science (AREA)
- Textile Engineering (AREA)
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Manufacturing & Machinery (AREA)
- Mechanical Engineering (AREA)
- Knitting Of Fabric (AREA)
- Artificial Filaments (AREA)
- Woven Fabrics (AREA)
Abstract
To provide a fabric containing a polyester fiber and a polyurethane elastic yarn that are excellent in deodorant function of sweat odor and the distinctive body odor of elderly. A fabric that is a combined fabric including a polyurethane elastic yarn and a cationic dyeable polyester fiber where a deodorant ratio of ammonia gas measured according to the detector tube method defined by Japan Textile Evaluation Technology Council for 0.15 g of polyurethane elastic yarn is greater than or equal to 40% both after washing 0 times and 10 times, also a mixing ratio of the polyurethane elastic yarn is from 5 wt.% to 30 wt.%, and a mass of 10 cm*10 cm is greater than or equal to 1 g.
Description
Technical field
The present invention relates to the fabric of a kind of combination polyester fiber and Polyurethane elastic yarn, the polyester fiber and polyurethane bullet
Property yarn has excellent deodorizing effect for unique body odor of fetid sweat and old people.
Background technology
In recent years, due to enhanced health perception, expanded material is widely used in functional underwear and bottom shirt.Especially,
In summer, for underwear and sport shirt field, the excellent material for combining polyester fiber preferably in terms of rapid draing and durability
Material.
It is very high for the demand of fetid sweat and the deodorizer of unique body odor of old people in these purposes, in order to according to used
Example provides this function, it has been proposed that by the functionalization (patent documentation 1) of post-processing approach.
In addition, it is proposed that the method (patent documentation 2) of deodorizer is directly incorporated into in the elastic fiber that elasticity is provided.For this
Using inorganic deodorizer such as activated carbon, containing silver zeolite, zeolite, zinc oxide fine particles and metal phosphate.These inorganic deodorizer
With excellent weatherability and chemical resistance, and also with the low excellent specific property of acute oral toxicity.Further, since thermostability
Height, even if during the manufacture or processing of elastic fiber, will not also weaken deodorizing effect.
Background technology document
Patent documentation
Patent documentation 1：Japanese Unexamined Patent Application discloses 2012-140731, patent documentation 2：PCT international applications
2012-053401's discloses again.
The content of the invention
The problem to be solved in the present invention
But, although can by post-processing approach obtain with temporary transient deodorizing effect product, but exist problem
It is that the binding agent for adhering to functional reagent on elastic fabric may damage texture, long manufacture process causes productivity ratio
Reduce, and cyclic washing reduces deodorizing effect.
Additionally, when trial shows deodorizing effect by the way that conventional polyester fiber is combined with the elastic fiber for mixing deodorizer
When, the ratio (hereinafter referred to mixed proportion) of elastic fiber must be significantly high in fabric, accordingly, there exist needed for can not obtaining
Texture and physical property problem.
It is an object of the present invention to provide a kind of have resilient fabric, it is for fetid sweat and unique body odor of old people
With excellent deodorizing effect.
The means of solve problem
In order to solve the above problems, the present invention uses any one in following means：
(1) a kind of fabric, it includes Polyurethane elastic yarn and cation dyeable polyester fiber, wherein 10cm × 10cm's
Quality is more than or equal to 1g, and wherein Polyurethane elastic yarn has for 0.15g Polyurethane elastic yarns are according to Japan Textile
It is that the detection tube method of Evaluation Technology Council definition is measured, be more than washing to be afterwards for 0 time and 10 times
Or the ammonia deodorization ratio equal to 40%, and the mixed proportion of Polyurethane elastic yarn is 5 to 30 weight %.
(2) fabric according to (1), the mixed proportion of cation dyeable polyester fiber is more than or waits wherein in fabric
In 40 weight %.
(3) fabric according to (1) or (2), it is by cationic dyeing.
(4) fabric according to any one of (1) to (3), wherein Polyurethane elastic yarn are comprising 0.5 weight % to 10 weights
The inorganic deodorizer of amount %.
The effect of the present invention
In accordance with the invention it is possible to obtain the resilient fabric of tool, it is excellent for unique body odor of fetid sweat and old people has
Different deodorizing effect.Therefore, the clothes using this fabric is excellent for unique body odor of fetid sweat and old people can have
Deodorizing effect.
Specific embodiment
The present invention is described in more detail below.
The present invention realizes that the fabric contains polyurethane bullet by obtaining the fabric with extra fine quality/unit area
Property yarn, and by combine cation dyeable polyester fiber and Polyurethane elastic yarn and for fetid sweat and unique body of old people
It is smelly that with excellent deodorizing effect, the Polyurethane elastic yarn has the ammonia deodorization ratio more than or equal to setting, so that
In fabric Polyurethane elastic yarn mixed proportion in particular range.
The fabric of the present invention is the fabric containing Polyurethane elastic yarn and cation dyeable polyester fiber.By containing
Mixed proportion is the Polyurethane elastic yarn of 5 to 30 weight % in fabric, it is possible to obtain Polyurethane elastic yarn have originally to second
The effective deodorizing effect of acid gas, isovaleric acid, nonenyl aldehyde.
By with reference to cation dyeable polyester fiber with formed with remove fetid sweat and old people unique body odor it
Between well balanced deodorizing effect fabric, the dye of positive ion exhausts and just illustrates the deodorizing effect to ammonia.It is preferred that sun from
Mixed proportion of the sub- dyeable polyester fiber in fabric is more than or equal to 40 weight %, to show the deodorizing effect to ammonia,
From the angle for showing the deodorizing effect to acetic acid gas, isovaleric acid and nonenyl aldehyde, preferred upper limit is less than or equal to 95 weights
Amount %.Note, when mixed proportion of the cation dyeable polyester fiber in fabric is 40 weight % or more hour, preferably with sun
Ionic dye is dyeed.
It is more than or equal to 1g by making the weight of 10cm × 10cm, it can be ensured that be enough to show the polyurethane bullet of deodorizing effect
The amount of property yarn and cation dyeable polyester fiber.Additionally, from the feel for clothing etc. and the angle of texture, preferably
The weight of 10cm × 10cm is less than or equal to 7g.
In the Polyurethane elastic yarn for using in the present invention, for 0.15g Polyurethane elastic yarns are according to Japan Textile
The deodorization ratio to ammonia that measures of detection tube method of Evaluation Technology Council definition is in carrying out washing treatment 0 time
It is afterwards more than or equal to 40% with 10 times.By using the mixed proportion in fabric in the range of 5 to 30 weight %
This Polyurethane elastic yarn, there is cation dyeable polyester fiber the deodorizing effect to ammonia to be added originally, and gather
The deodorizing effect to acetic acid gas, isovaleric acid, nonenyl aldehyde that urethane elastomeric yarn has is shown completely.
In the Polyurethane elastic yarn for using in the present invention, for 0.15g Polyurethane elastic yarns are according to Japan Textile
The deodorization ratio to ammonia that measures of detection tube method of Evaluation Technology Council definition is in carrying out washing treatment 0 time
It is afterwards more than or equal to 40% with 10 times.Japan Textile Evaluation Technology Council are defined
Detection tube method be determine how many ammonias were reduced in 2 hours in regulation sample method, by 0.15g polyurethane bullets
Property the ammonia deodorization that obtains of yarn application the method than becoming polyurethane yarn from the index of the ammonia deodorization ratio contributed in fabric.
The method for obtaining the Polyurethane elastic yarn with this ammonia deodorization ratio is not particularly limited, it may be preferred, however, that using containing
Those of inorganic deodorizer with ammonia deodorizing effect.By comprising there is deodorizing effect to ammonia and without prejudice to acetic acid gas
The inorganic deodorizer of the deodorization power of body, nonenyl aldehyde gas and isoamyl acid gas, can improve the deodorization properties to ammonia.
For inorganic deodorizer, it is possible to use containing silicon dioxide comprising calcium, the zirconium of zinc, titanium, aluminum metal phosphate
Deng.Wherein, at least one for selecting from the zirconium phosphate with layer structure, titanium phosphate or aluminium dihydrogen tripolyphosphate is preferred for
Purpose to the deodorization properties of ammonia, particularly preferred zirconium phosphate.
Additionally, for the purpose to the deodorization properties of ammonia, metal phosphate (such as zirconium phosphate) is preferably and do not have silver ion
Or the material of the metal ion such as copper ion.
Relative to the gross mass of Polyurethane elastic yarn, the content of inorganic deodorizer is in the range of 0.5 to 10 weight %.When
When the content of inorganic deodorizer is less than 0.5 weight %, when as fabric sufficient ammonia deodorization properties can hardly be obtained.More
It is preferred that the content is more than or equal to 1.5 weight %.Conversely, when content is more than 10 weight %, it may occur however that elastic performance it is bad
The cost changed or increase.More preferably the content is more than or equal to 7.0 weight %.When in view of the deodorization properties and physics to ammonia
During balance between performance and cost, the content is particularly preferably in the range of 1.5 to 5.0 weight %.
Additionally, from the angle for preventing spinning solution from blocking spinning head, the inorganic deodorizer of the present invention is preferably averagely
Powder of the primary particle diameter less than or equal to 3.0 μm, more particularly, average primary particle diameter is less than or equal to 1.5 μm.Additionally, when flat
When primary particle diameter is less than 0.05 μm, cohesiveness increase, it is difficult to equably mix in spinning solution, therefore, from dispersibility
Angle set out, average primary particle diameter is preferably greater than or equal to 0.05 μm.
Polyurethane elastic yarn used in the present invention, can also be containing such as photostabilizer, antioxygen in addition to inorganic deodorizer
The preparation of agent, pigment etc..It is, for example possible to use the manufacture of Hinered phenols medicine, such as Sumitomo Chemical Co., Ltd.s
" Sumilizer " (registered trade mark) GA-80, and as photostabilizer and the BHT of antioxidant, benzotriazole system such as Ciba
Various " Tinuvins " (registered trade mark) of Geigy manufactures, benzophenone medicine, the such as Sumitomo of the medicine based on phosphorus
" Sumilizer " (registered trade mark) P-16 of Chemical Co., Ltd.s manufacture, various hindered amines medicines, various pigment are such as
Ferrum oxide, titanium oxide, inorganic material such as Zinc Oxide, cerium oxide, magnesium oxide, Calcium Carbonate, white carbon black, based on fluorine or the resin based on silicon
Powder, metallic soap such as magnesium stearate, lubricant such as mineral oil, it is also preferred that comprising various antistatic additive such as cerium oxide, glycine betaine or
Phosphoric acid, and they preferably with polymer reaction.Additionally, in order to improve the durability to particularly lightweight various nitrogen oxides,
The HN-150 that nitrogen oxides scavenger is such as manufactured by Japan Hydrazine Co., Ltd.s is preferably used, thermal oxidation stabilizer is such as
" Sumilizer " (registered trade mark) GA-80 of Sumitomo Chemical Co., Ltd.s manufacture, light stabilizer is such as
" Sumisorb " (registered trade mark) 300#622.
The cation dyeable polyester fiber of the fabric for the present invention is described below.
Generally, cation dyeable polyester fiber is to contain metal sulfonate salt group by the copolymerization in polyester molecule structure
Compound and the fiber that obtains, the definition in the present invention is and this identical.This cation dyeable polyester fiber can be with
All kinds are obtained, and the compound of one of which type contains metal sulfonate salt group, or wherein copolymerization rate due to dyeability
Enhancing, texture improve etc. and it is different；However, the cation dyeable polyester fiber for using in the present invention can be without special
Use with limiting, as long as the common dye of positive ion shows dyeability.
Fabric in the present invention preferably have greater than or cation dyeable polyester fiber equal to 40 weight % mixing
Ratio, to show the deodorizing effect with appropriate balance, with more than or equal to 5 weight % and poly- less than 30 weight %
The mixed proportion of urethane elastomeric yarn, and the quality of the 10cm × 10cm more than or equal to 1g.When the conditions are satisfied, it is knitting to knit
Thing can be the combination of conventional polyester fiber or Fypro, Cotton Gossypii etc..As long as meeting above-mentioned condition, knitting fabric does not have yet
Especially limit, knitting fabric can be made in any method, such as cylinder knitting, warp knit is knitting, and braiding, La Sheer warp knits are knitting,
Or as cored finished product yarn.
Furthermore it is preferred that the fabric of the present invention is by cationic dyeing.It is used for the cation dye of dyeing in this case
Material is not particularly limited, even if there is polytype, such as polymethine, and azo, azomethine, anthraquinone, thiazole etc., and generally city
The dyestuff sold can be used under normal operation.Furthermore it is preferred that the dye of positive ion includes counter ion counterionsl gegenions and carboxylate anion, sulphur
Acid radical anion, sulfate ester anion, phosphate ester anion etc., to show fabric deodorizing effect, particularly preferably sulfonate radical
Anion.Additionally, in order to improve texture and after dyeing course provide other functions, softening can be suitably provided and arranged,
Antimicrobial treatment, water suction is processed, water-proofing treatment, antistatic treatment etc..
It is preferred that the fabric of the present invention is knitting fabric.In order to represent the deodorizing effect with appropriate balance, knitting fabric is
Preferably, the wherein mixed proportion of cation dyeable polyester fiber is more than or equal to 40 weight %, Polyurethane elastic yarn it is mixed
Composition and division in a proportion example is more than or equal to 5 weight % and less than 30 weight %, and the quality of 10cm × 10cm is more than or equal to 1g, as long as and
Meet the construction, in addition to Polyurethane elastic yarn or cation dyeable polyester fiber, it can be conventional polyester fiber, gather
The combination of nylon, cotton etc..
Hereinafter, the Polyurethane elastic yarn used in the present invention is illustrated and (below, will be constituted poly- used in the present invention
The polyurethane of urethane elastomeric yarn is referred to as the polyurethane used in the present invention).
Polyurethane used in the present invention can be any material, be not particularly limited, as long as polymer diol and two different
Cyanate is parent material.Synthetic method is also not particularly limited.That is, it is, for example possible to use by polymer diol, two Carbimide .s
Ester and the polyurethane-urea of low-molecular-weight diamidogen synthesis, or synthesized by polymer diol, diisocyanate and low molecular weight diols
Polyurethane carbamate.In addition it is possible to use wherein have the compound of hydroxyl and amino as the polyurethane of cahin extension agent-
Urea.By using the poly- ammonia of the acquisitions such as isocyanates, the glycol of three or higher functionality of advantageous effects of the without prejudice to present invention
Ester is also preferably used for the present invention.
For polymer diol, preferred, polyethers, polyester-diol, PCDL etc..It is flexible and elasticity from yarn is given
Angle is set out, particularly preferably using PTMEG.
For PTMEG, such as poly(ethylene oxide) is preferably used, Polyethylene Glycol, polyethyleneglycol derivative, polypropylene glycol,
Polytetramethylene ether diol (hereinafter referred to as PTMG), is tetrahydrofuran (hereinafter referred to as THF) and 3- methyltetrahydrofurans
The modified PTMG (hereinafter referred to as 3M-PTMG) of copolymer is THF and the copolymer of 2,3- dimethyl THF it is modified
PTMG, has polyhydric alcohol of side chain etc. disclosed in patent No.2615131 in both sides, wherein THG and oxirane and/or
Random copolymer of expoxy propane irregular alignment etc..These PTMEGs can be a kind of PTMEG, or for two kinds or more
Various mixing or the PTMEG of copolymerization.
Additionally, obtaining wearability and sunproof angle from as Polyurethane elastic yarn, adipic acid fourth is preferably used
Diol ester, polycaprolactone glycol, polyester-diol, such as having disclosed in Japanese Unexamined Patent Application Publication S61-26612
PEPA of side chain etc., or the PCDL disclosed in Japanese Unexamined Patent Application Publication H02-289616
Deng.
Additionally, these polymer diols can be used alone, or can be with two or more mixing or copolymerization.
For the molecular weight of polymer diol, from the angle for obtaining elasticity, intensity, thermostability etc., number-average molecular weight
It is preferred that between 1000 and 8000, more preferably between 1500 and 6000.Using the polyhydric alcohol in range of number-average molecular weight, can
To be readily available elasticity, intensity, elastic recovery intensity and the elastomeric yarn of excellent heat resistance.Note, number-average molecular weight passes through GPC
Measurement, and by polystyrene (same way is applied to other compositions hereafter and polymer) conversion.
Secondly, for diisocyanate, aromatic diisocyanates, such as methyl diphenylene diisocyanate are (hereinafter referred to as
MDI), toluene di-isocyanate(TDI), Isosorbide-5-Nitrae-diisocyanate benzene, XDI, 2,6- naphthalene diisocyanates etc. are especially
It is suitable to synthesize heat-resisting and high-strength polyurethane.Additionally, for alicyclic diisocyanate, preferably for example, di-2-ethylhexylphosphine oxide (hexamethylene
Based isocyanate) (hereinafter referred to as H12MDI), isophorone diisocyanate, hexahydrotoluene 2,4- diisocyanate, first
Butylcyclohexane 2,6- diisocyanate, hexamethylene Isosorbide-5-Nitrae-diisocyanate, hexahydro XDI, hexahydrotoluene two is different
Cyanate, octahydro 1,5- naphthalene diisocyanates etc..Particularly when the yellowish discoloration of Polyurethane elastic yarn is suppressed, can be effectively
Using aliphatic vulcabond.Additionally, these diisocyanate may be used alone or two or more kinds used in combination.
Secondly, preferably poly- ammonia is synthesized in the low molecular weight diols and low-molecular-weight diamidogen by molecular weight less than or equal to 300
Using the cahin extension agent of at least one type during ester.Note, it can even have hydroxyl and amino, such as ethanolamine.
Preferred low-molecular-weight diamidogen includes, for example, ethylenediamine, 1,2- propane diamine, 1,3- propane diamine, hexa-methylene two
Amine, p-phenylenediamine, xylol diamidogen, m-xylene diamine, p, p '-methylene dianiline (MDA), 1,3- cyclohexyl diamine, hexahydro U.S.
Sha Fenlin diamidogen (hexahydromethaphenilenediamine), 2- methyl pentamethylene diamines, double (4- aminophenyls)
Phosphine oxide etc..Preferably use one or more of these.Particularly preferred ethylenediamine.By using ethylenediamine, can easily obtain
There must be the yarn of excellent resilience, elastic recovery intensity and thermostability.Can be possible to form the triamine compound example of cross-linked structure
As diethylenetriamines are added in these cahin extension agents to the degree for not losing effect.
Additionally, the low molecular weight diols for molecular weight less than or equal to 300, ethylene glycol, 1,3-PD, Isosorbide-5-Nitrae-fourth two
Alcohol, double hydroxyl-oxethyl benzene, double hydroxyterephthalic acid's glycol esters, 1- methyl isophthalic acids, 2- ethylene glycol etc. are typical examples.It is excellent
Choosing uses one or more type in these.Ethylene glycol, 1,3- Propylene Glycol and 1,4- butanediols are particularly preferred.By making
With them, thermostability can be further improved, because the polyurethane of glycol chain and the yarn of higher intensity can be obtained.
Additionally, the polyurethane used in the angle for obtaining the fiber with durability and higher intensity, the present invention
Molecular weight preferably between 30000 and 150000 (as number-average molecular weight).
For polyurethane, further preferably mix the end chelating agen of one or more type.Preferred end chelating agen includes
Monoamine, such as dimethylamine, diisopropylamine, ethyl dimethylamine, diethylamine, methyl propylamine, isopropyl methylamine, diisopropylamine, butyl methylamine,
Isobutyl group methylamine, isopentyl methylamine, dibutyl amine, diamylamine etc.；Single methanol, such as ethanol, propanol, butanol, isopropanol, 1-propenol-3, ring
Amylalcohol etc.；Monoisocyanates, such as carbanil.
Hereinafter, the manufacture method of the Polyurethane elastic yarn used in the present invention is illustrated.
Polyurethane elastic yarn used in the present invention in spinning solution by containing inorganic deodorizer (such as metal tripolyphosphate
Salt such as zirconium phosphate) and quaternary ammonium salt antiseptic or the like (if necessary) and be spun into, the spinning solution is included by using poly-
The polyurethane that compound glycol and diisocyanate are obtained as parent material.It is preferred that previously prepared polyurethane solutions, then from steady
The angle of fixed polymerization adds inorganic deodorizer.Additionally, as the polyurethane of solute manufacture method can be melt phase polycondensation or
Solution polymerization process, or additive method.Wherein, more preferably solution polymerization process.In the case of solution polymerization process, in poly- ammonia
The foreign bodies such as gel are nearly free from ester, spinning is easier, are readily obtained the low Polyurethane elastic yarn of fiber number.
Additionally, the polyurethane particularly preferably used in the present invention include by using number-average molecular weight 1500 to 6000 it
Between PTMG as polymer diol, MDI as diisocyanate and 1,2- propane diamine, 1,3- propane diamine, hexa-methylene two
In amine or ethylenediamine it is at least one as cahin extension agent synthesis those.
Polyurethane used in the present invention can in a solvent synthesize acquisition, the solvent example by using mentioned component
Such as, N,N-dimethylacetamide (hereinafter referred to as DMAc), in DMF (hereinafter referred to as DMF), dimethyl
Sulfoxide (hereinafter referred to as DMSO), METHYLPYRROLIDONE (hereinafter referred to as NMP) or more are stated as the molten of main component
Agent.The particularly preferred method that can be used is for example so-called one-step method, wherein by the way that all material is put into into this solvent
In, they are dissolved, and by the way that solution is heated to into suitable temperature reaction is carried out preparing polyurethane；Or wherein by head
First polymer diol and diisocyanate are melted and reacted, then product is dissolved in a solvent and made above-mentioned cahin extension agent
Deng method of the reaction to prepare polyurethane.
When using glycol as cahin extension agent, from the angle for obtaining excellent thermostability, preferably by the molten of high temperature side
Point is adjusted in the range of 200 to 260 DEG C.Representational method can be by control polymer diol, MDI, diol type
Realize with ratio.When the molecular weight of polymer diol is low, it is obtained in that with high temperature melting by the ratio of relative increase MDI
The polyurethane of point.In an identical manner, when the molecular weight of glycol is low, can be obtained by the ratio of relative reduction polymer diol
There must be the polyurethane of high temperature fusing point.
When the number-average molecular weight of polymer diol is 1800 or bigger, in order that high temperature side fusing point is 200 DEG C or higher,
It is preferred that being polymerized with ratio (molal quantity of MDI)/(molal quantity of polymer diol)=1.5 or higher.
In the present invention, it is preferred to contain inorganic deodorizer such as metal phosphate in this polyurethane solutions.When will be inorganic
When deodorizer is added in polyurethane solutions, it is possible to use any method.As representational method, it is possible to use various sides
Formula, such as using the method for static mixer, the method by stirring, by the method for homogeneous mixer, using twin-screw extrusion
Method of machine etc..
For the polyurethane used in the present invention, in order to improve the deodorizing effect to ammonia, contain in Polyurethane elastic yarn
There is the inorganic deodorizer in prescribed limit；It is preferable, however, that before spinning inorganic deodorizer is evenly dispersed into into polyurethane spinning
In silk solution, and preferably above-mentioned inorganic deodorizer is added in polyurethane spinning solution (that is, DMF, DMAc's etc. is molten
Agent), then stir and mix so as to dispersed.More specifically, it is preferable to inorganic deodorizer is prepared as wherein to be dispersed with advance
The dispersion soln of DMF, DMA etc., and dispersion soln is mixed in polyurethane spinning solution.From in polyurethane solutions equably
The angle being added is set out, and is preferably used and the polyurethane for disperse medium (in for the dispersion soln of inorganic deodorizer)
Solution identical solvent.Additionally, when inorganic deodorizer is added in polyurethane solutions, for example, can add simultaneously as resistance to
The medicament of photo etching, oxidation retarder or pigment.
Polyurethane yarn used in the present invention can be for example, by being rolled up by dry spinning, wet spinning or melt spinning
Obtain around spinning solution configured as above.Wherein, stablize from the spinning of all fiber numbers (from very thin yarn to rove)
From the perspective of property, dry spinning is preferred.
Fiber number and shape of cross section for the Polyurethane elastic yarn of the present invention is not particularly limited.For example, yarn is transversal
Face shape can be circular or flat pattern.
Dry spinning method is also not particularly limited, can be according to the spinning condition and spinning equipment for being adapted to desired characteristic
Suitably to select spinning process.
Embodiment
Embodiment of the present invention will be described in more detail.
Washing methods
According to by Japanese Association for the Functional Evaluation of Textiles
The washing methods handbook of foundation is washed.That is, using in JIS L0217:Washing methods 103 in 1995 annex table 1
Defined in domestic electric washer, cleaning mixture is prepared, wherein by 40ml JAFET standard detergents (by Japanese
Association for the Functional Evaluation of Textiles are manufactured) at 40 DEG C with 30 liters of water
Dissolving, the detergent of 1kg samples is put in cleaning mixture.Then, detergent is washed 5 minutes, rotary dehydration, rinsing 2
Minute, rotary dehydration is rinsed 2 minutes, and rotary dehydration in this order, and the process is considered as once washing.10 meanings of washing
Taste and repeats the sequence of maneuvers 10 times, and washing means for 50 times to repeat the sequence of maneuvers 50 times.
The deodorizing effect of Polyurethane elastic yarn
Based on Deodorant Processed Textiles Certification Criteria (by Japan
Textile Evaluation Technology Council, product certification department publishes, and September is issued on the 1st within 2002) standard
Deodorizing test is carried out, and the deodorizing effect evaluation of malodor components is carried out by following equipment test.
(detection tube method)
1. sample (Polyurethane elastic yarn 0.15g) is put in Tedlar bags.
2. the desired amount of test gases (ammonia is injected：100ppm, acetic acid gas：30ppm), and by corresponding to composition
Detection pipe (GASTEC Co. manufactures) measurement two hours after remaining gas concentration (ppm) as sampling test residue gas
Bulk concentration.Additionally, gas loading is 3L, diluent gas is dry air or nitrogen.
3. carry out identical evaluation and sample is not put in Tedlar bags, as the residual gas concentration of blank assay.
4. evaluated to calculate deodorizing rate according to following formula.
Formula 1：
Deodorizing rate (%)=100x (the residual gas concentration of the residual gas concentration-sampling test of blank assay)/blank
The residual gas concentration of test
Note, measured value is the meansigma methodss acquisition as n=3.
The deodorizing effect of fabric
As sample, in addition to replacing 0.15g Polyurethane elastic yarns using 10cm × 10cm fabrics, with " polyurethane
The deodorizing effect of elastomeric yarn " identical mode carries out the deodorizing effect evaluation of malodor components, to calculate deodorization ratio.
It is 70% or higher that fabric deodorizing effect is preferably in the washing resistance in ammonia and acetic acid after washing 10 times,
More preferably in ammonia and acetic acid washing 50 times afterwards be 70%.
Embodiment 1
Prepare by the PTMG that ethylenediamine, MDI and number-average molecular weight are 1800 and the diethylamine group as end chelating agen
Into polyurethane-urea polymers DMAc solution (35 weight %).Secondly, as antioxidant, will be by tert-butyl group diethanol
Polyurethane solutions (DuPont Co. " Methacrol " TM that amine and methylene-bis--(4- cyclohexyl isocyanates) reaction are obtained
2462D) and paracresol and divinylbenzene condensation polymer (DuPont Co. " Methacrol " TM 2390D) with 2:1 weight
Than mixing to prepare antioxidant DMAc solution.By the anti-of the polyurethaneurea polymer DMAc solution of 96 weight portions and 4 weight portions
Oxidizing agent solution mixes to prepare polymer solution A1.Secondly, by homo-mixer by zirconium phosphate deodorizer " Kesumon " TM
During NS-10 (Toagosei Co., 0.9 μm of average primary particle diameter) is dispersed in DMAc, to prepare zirconium phosphate dispersion B1 (35 weights
Amount %).Zirconium phosphate dispersion B1 of the polymer solution A1 of 99 weight % ratios and 2 weight % uniformly is mixed to prepare spinning
Solution C 1.By it with the speed dry spinning of 720m/min, wherein the speed ratio of godet and up- coiler is 1.3, and is obtained
The dtex of Polyurethane elastic yarn 22 of 200g windings, 2 threads, phosphoric acid zirconium content is 2 weight %.
The result evaluated after ammonia deodorizing effect with the Polyurethane elastic yarn obtained by 0.15g is shown in Table 1.
Then, by using Polyurethane elastic yarn and cation dyeable polyester fiber (WFOF types, Toray Co. manufactures,
84 dtexs, 72 threads), it is circulated by the typical method for fabric knitting.
The circular knitting fabric of acquisition is used as described below carries out dyeing course, to obtain the mixing ratio of wherein Polyurethane elastic yarn
Example is 9 weight %, and the quality of 10cm × 10cm is the knitting fabric of the dyeing of 1.3g.
(1) subtractive process：Prepare " Sunmol " BL650 of 2g/L (by Nikka Chemical Co., the moon of Ltd. productions
Ionic surface active agent) aqueous solution, and at 80 DEG C process 20 minutes.
(2) pre-setting：At 190 DEG C × 1 minute, processed with tentering rate 30%.
(3) dye：Using dyestuff Kayacryl Black FB-ED (by Nippon Kayaku Co., the sun of Ltd. manufactures
Ionic dye), and dyeed 60 minutes with the concentration of 8%owf at 125 DEG C.Here, %owf is represented relative to the fibre in dye bath
The percentage ratio of the dyestuff quality of dimension quality.
Each knitting fabric after the dyeing in knitting fabric and (3) after processing the pre-setting in (2) determines deodorization
Effect.Evaluation result is shown in Table 2.
Comparative example 1
Circular knitting fabric is prepared using the Polyurethane elastic yarn used in embodiment 1, and is carried out according to following methods
Dyeing is processed：Replace cation polyurethane with conventional polyester fiber (Tetoron, Toray (Inc.), 84 dtexs and 72 threads)
Elastomeric yarn (Tetoron, Toray Co., 84 dtexs and 72 threads).
(1) subtractive process：Prepare " Sunmol " BL650 of 2g/L (by Nikka Chemical Co., the moon of Ltd. productions
Ionic surface active agent) aqueous solution, and at 80 DEG C process 20 minutes.
(2) pre-setting：At 190 DEG C × 1 minute, processed with tentering rate 30%.
(3) dye：Using dyestuff Dianix Tuxde Black F (trade name, by DyStar Japan Ltd. manufacture,
And dyeed 60 minutes with the concentration of 10%owf at 125 DEG C.
(4) reduction cleaning：Containing bisulfites 3.0g/L, sodium hydroxide 1.5g/L, Bisnol US-10 (commodity
Name, by Ipposha Oil Industries, Co., Ltd.'s manufacture) 1.5g/L bath in process 20 minutes at 80 DEG C.
Each knitting fabric after processing the knitting fabric after the pre-setting process in (2) and the dyeing completed in (4)
Determine deodorizing effect.
Each evaluation result is shown in Tables 1 and 2.
Embodiment 2
Replace zirconium phosphate dispersion B1, removed the aluminium dihydrogen tripolyphosphate manufactured by TAYCA Co. by homo-mixer
During smelly dose of " K-FRESH " (registered trade mark) #100P (1.0 μm of average primary particle diameter) is dispersed in DMAc, to prepare tripolyphosphate two
Hydrogen aluminum dispersion B2 (35 weight %).
Aluminium dihydrogen tripolyphosphate dispersion B2 of the polymer solution A1 of 96 weight % ratios and 4 weight % is uniformly mixed
To prepare spinning solution C2, in the same manner as example 1 by its dry spinning, the Polyurethane elastic yarn of 200g windings is obtained
22 dtexs, 2 threads silk threads, aluminium dihydrogen tripolyphosphate content is 4 weight %.Similarly to Example 1 to the polyurethane of acquisition
Elastomeric yarn carries out the deodorizing effect evaluation to ammonia.Then, circular knitting fabric and its dyeing are prepared similarly to Example 1
Knitting fabric is evaluated these fabrics as fabric.
Each evaluation result is shown in Tables 1 and 2.
Embodiment 3
Replace zirconium phosphate dispersion B1, will be by Rasa Industries, inorganic the removing of Ltd. manufactures by homo-mixer
Smelly dose of " Shu-Clenase " (registered trade mark) KD-211 is dispersed in DMAc, to prepare dispersion B3 (35 weight %).
The dispersion liquid B3 of the polymer solution A1 of 96 weight % ratios and 4 weight % uniformly is mixed to prepare spinning solution
C3, in the same manner as example 1 by its dry spinning, obtains the dtex of Polyurethane elastic yarn 22 of 200g windings, 2 threads
Silk thread, inorganic deodorization agent content is 4 weight %.Similarly to Example 1 the Polyurethane elastic yarn to obtaining is carried out to ammonia
Deodorizing effect is evaluated.Then, the knitting fabric of circular knitting fabric and its dyeing is prepared similarly to Example 1 as fabric,
And these fabrics are evaluated.
Each evaluation result is shown in Tables 1 and 2.
Embodiment 4
Polymer solution A1 and B1 is uniformly mixed to prepare spinning solution C4 with 99 weight % and 1 weight %.With with reality
The identical mode of example 1 is applied by its dry spinning, the dtex of Polyurethane elastic yarn 22 of 200g windings is obtained, 2 threads silk threads are inorganic
Deodorization agent content is 1 weight %.Similarly to Example 1 the Polyurethane elastic yarn to obtaining carries out commenting the deodorizing effect of ammonia
Valency.Then, the knitting fabric of circular knitting fabric and its dyeing is prepared similarly to Example 1 as fabric, and these are knitted
Thing is evaluated.
Each evaluation result is shown in Tables 1 and 2.
Embodiment 5
By spinning solution C1 with the speed dry spinning of 710m/min, the speed ratio of wherein godet and up- coiler is
1.21, and the dtex of Polyurethane elastic yarn 44 of 350g windings, 4 threads are obtained, inorganic deodorization agent content is 2 weight %.With
Mode same as Example 1 carries out the deodorizing effect evaluation to ammonia to the Polyurethane elastic yarn for obtaining.Then by conventional
Method uses cation dyeable polyester fiber (FS92 types：Manufactured by Toray Co.) by bidirectional needle fabric it is knitting for fabric it is (mixed
Composition and division in a proportion example 76%), and by the Polyurethane elastic yarn (mixed proportion 24%) of 44 dtexs for bag.The bidirectional needle of acquisition is used as described below
Fabric carries out dyeing course, to obtain the mixed proportion of wherein Polyurethane elastic yarn as 24 weight %, the quality of 10cm × 10cm
For the knitting fabric of the dyeing of 1.88g.
(1) subtractive process：By anion surfactant " Sunmol " (registered trade mark) BL650 of 2g/L (by Nikka
Chemical Co., Ltd. manufacture) and 1500ppm EDTA quasi-chelate compounds " Acromar " (registered trade mark) DH 700 (by
Nagase chemteX Co. are manufactured) it is added to prepare the solution as processing solution in the soft water that total hardness is 10ppm, and
Processed 20 minutes at 80 DEG C using processing solution.
(2) pre-setting：At 190 DEG C × 1 minute, processed with tentering rate 30%.
(3) dye：Using the dye of positive ion " Kayacryl Black " (registered trade mark) FB-ED (by Nippon Kayaku
Co., Ltd. manufactures), and dyeed 60 minutes with the concentration of 8%owf at 125 DEG C.
Each knitting fabric after the dyeing in knitting fabric and (3) after processing the pre-setting in (2) determines deodorization
Effect.
Each evaluation result is shown in Tables 1 and 2.
Embodiment 6
By the dye of positive ion used in embodiment 1 change into (3H) -one of 1,3- dimethyl -1H- benzos (d) imidazoles -2 and
2- amino -3- methyl chloride benzene, and dyed fabric prepared in the same manner as example 1.
Evaluation result is shown in Table 2.
Embodiment 7
By the dye of positive ion used in embodiment 1 change into (3H) -one of 1,3- dimethyl -1H- benzos (d) imidazoles -2 and
2- amino -3- dimethylamino methyl phenyl base sulfate, and dyed fabric prepared in the same manner as example 1.
Evaluation result is shown in Table 2.
Embodiment 8
Except using cation dyeable polyester fiber and conventional polyester fiber (W20F types：Manufactured by TorayCo., 84 points
Special 72 threads) it is 40:The fiber of 51 ratio replace cation dyeable polyester fiber used in embodiment 1 (WFOF types,
Toray Co. are manufactured, the threads of 84 dtex 72) beyond, the circular knitting for being prepared as dyeing in the same manner as example 1 is knitted
The knitting fabric of thing is evaluated as fabric.
Each evaluation result is shown in Tables 1 and 2.
Embodiment 9
Except using cation dyeable polyester fiber and conventional polyester fiber (W20F types：Manufactured by TorayCo., 84 points
Special 72 threads) it is 30:The fiber of 61 ratio replace cation dyeable polyester fiber used in embodiment 1 (WFOF types,
Toray Co. are manufactured, the threads of 84 dtex 72) beyond, circular knitting fabric and its dye are prepared in the same manner as example 1
The knitting fabric of color is evaluated as fabric.
Each evaluation result is shown in Tables 1 and 2.
Embodiment 10
In addition to carry out dyeing process with the identical mode of comparative example 1, circle is prepared in mode same as Example 8
The knitting fabric of shape and its knitting fabric of dyeing are evaluated these fabrics as fabric.
Each evaluation result is shown in Tables 1 and 2.
Comparative example 2
In the same manner as example 1 by polymer solution A1 dry spinnings, the elastic polyurethane of 200g windings is obtained
The dtex of yarn 22,2 threads.Similarly to Example 1 the Polyurethane elastic yarn to obtaining carries out the deodorizing effect evaluation to ammonia.
Then, the knitting fabric of circular knitting fabric and its dyeing is made similarly to Example 1 as fabric, and these fabrics are entered
Row is evaluated.
Each evaluation result is shown in Tables 1 and 2.
Comparative example 3
Dispersion B3 of the polymer solution A1 of 99.5 weight % ratios and 0.5 weight % uniformly is mixed to prepare spinning
Solution C 5.In the same manner as example 1 by its dry spinning, the dtex of Polyurethane elastic yarn 22 of acquisition 200g windings, 2
Long filament, inorganic deodorization agent content is 0.5 weight %.Similarly to Example 1 the Polyurethane elastic yarn to obtaining carries out ammonia
Deodorizing effect is evaluated.Then, the knitting fabric of circular knitting fabric and its dyeing is made similarly to Example 1 as fabric,
And these fabrics are evaluated.
Each evaluation result is shown in Tables 1 and 2.
Comparative example 4
In mode same as Example 5 by polymer solution A1 dry spinnings, the elastic polyurethane of 350g windings is obtained
The dtex of yarn 44,4 threads.Similarly to Example 1 the Polyurethane elastic yarn to obtaining carries out the deodorizing effect evaluation to ammonia.
Then, the knitting fabric of bidirectional needle fabric and its dyeing is prepared similarly to Example 5 as fabric, and these fabrics are carried out
Evaluate.
Each evaluation result is shown in Tables 1 and 2.
Comparative example 5
In mode same as Example 5 by spinning solution C3 dry spinnings, the Polyurethane elastic yarn of 350g windings is obtained
44 dtexs, 4 threads, inorganic deodorization agent content is 4 weight %.In the same manner as example 1 to the polyurethane bullet of acquisition
Property yarn carries out the deodorizing effect evaluation to ammonia.Then, using conventional polyester fiber (model S962)：Toray Co. are manufactured)
(mixed proportion 76%), by Polyurethane elastic yarn Imixing (ratio 24%) by 44 dtexs for bag, by conventional method
Bidirectional needle fabric is knitting for fabric.The bidirectional needle fabric of acquisition is used as described below carries out dyeing course, to obtain wherein polyurethane
The mixed proportion of elastomeric yarn is 24 weight %, and the quality of 10cm × 10cm is the knitting fabric of the dyeing of 1.86g.
(1) subtractive process：By anion surfactant " Sunmol " (registered trade mark) BL650 of 2g/L (by Nikka
Chemical Co., Ltd. manufacture) and 1500ppm EDTA quasi-chelate compounds " Acromar " (registered trade mark) DH 700 (by
Nagase chemteX Co. are manufactured) it is added to prepare the solution as processing solution in the soft water that total hardness is 10ppm, and
Processed 20 minutes at 80 DEG C using processing solution.
(2) pre-setting：At 190 DEG C × 1 minute, processed with tentering rate 30%.
(3) dye：Using dyestuff Dianix Tuxde Black F (trade name, by DyStar Japan Ltd. manufacture,
And dyeed 60 minutes with the concentration of 10%owf at 125 DEG C.
(4) reduction cleaning：Containing bisulfites 3.0g/L, sodium hydroxide 1.5g/L, Bisnol US-10 (commodity
Name, by Ipposha Oil Industries, Co., Ltd.'s manufacture) 1.5g/L bath in process 20 minutes at 80 DEG C.
Each knitting fabric after processing the knitting fabric after the pre-setting process in (2) and the dyeing completed in (4)
Determine deodorizing effect.
Each evaluation result is shown in Tables 1 and 2.
Comparative example 6
In addition to inorganic deodorizer used in by comparative example 3 is changed to 0.3 weight %, make in the same manner as comparative example 3
Make the knitting fabric of circular knitting fabric and its dyeing as fabric, and these fabrics are evaluated.
Each evaluation result is shown in Tables 1 and 2.
Claims (4)
1. a kind of fabric, it includes Polyurethane elastic yarn and cation dyeable polyester fiber, the wherein quality of 10cm × 10cm
More than or equal to 1g, wherein Polyurethane elastic yarn has for 0.15g Polyurethane elastic yarns are according to Japan Textile
It is that the detection tube method of Evaluation Technology Council definition is measured, be more than washing to be afterwards for 0 time and 10 times
Or the ammonia deodorization ratio equal to 40%, and the mixed proportion of Polyurethane elastic yarn is 5 to 30 weight %.
2. fabric according to claim 1, wherein in fabric the mixed proportion of cation dyeable polyester fiber be more than or
Equal to 40 weight %.
3. fabric according to claim 1 and 2, it is by cationic dyeing.
4. fabric according to any one of claim 1 to 3, wherein Polyurethane elastic yarn are comprising 0.5 weight % to 10 weights
The inorganic deodorizer of amount %.
Applications Claiming Priority (5)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP2014110918 | 2014-05-29 | ||
| JP2014-110918 | 2014-05-29 | ||
| JP2015090171A JP6677936B2 (en) | 2014-05-29 | 2015-04-27 | Deodorant fabric |
| JP2015-090171 | 2015-04-27 | ||
| PCT/US2015/033397 WO2015184400A1 (en) | 2014-05-29 | 2015-05-29 | Deodorant fabric |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN106687631A true CN106687631A (en) | 2017-05-17 |
Family
ID=54699934
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201580028095.0A Pending CN106687631A (en) | 2014-05-29 | 2015-05-29 | Deodorant fabric |
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| Country | Link |
|---|---|
| US (1) | US20170096772A1 (en) |
| JP (1) | JP6677936B2 (en) |
| KR (1) | KR20170008272A (en) |
| CN (1) | CN106687631A (en) |
| TW (1) | TWI716351B (en) |
| WO (1) | WO2015184400A1 (en) |
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| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
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| WO2020153375A1 (en) * | 2019-01-22 | 2020-07-30 | 旭化成株式会社 | Polyurethane elastic fiber and fabric containing same |
| JP7341773B2 (en) * | 2019-07-30 | 2023-09-11 | 東レ・オペロンテックス株式会社 | Polyurethane elastic yarn and its manufacturing method |
| CN110565201B (en) * | 2019-10-30 | 2021-05-04 | 华峰化学股份有限公司 | Preparation method of antibacterial and deodorant spandex |
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- 2015-05-29 KR KR1020167035136A patent/KR20170008272A/en unknown
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Also Published As
| Publication number | Publication date |
|---|---|
| TW201610248A (en) | 2016-03-16 |
| TWI716351B (en) | 2021-01-21 |
| US20170096772A1 (en) | 2017-04-06 |
| KR20170008272A (en) | 2017-01-23 |
| JP2016006242A (en) | 2016-01-14 |
| JP6677936B2 (en) | 2020-04-08 |
| WO2015184400A1 (en) | 2015-12-03 |
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