CN106678452B - A kind of tubing with activated water and adjusting water pH value function - Google Patents
A kind of tubing with activated water and adjusting water pH value function Download PDFInfo
- Publication number
- CN106678452B CN106678452B CN201510998517.9A CN201510998517A CN106678452B CN 106678452 B CN106678452 B CN 106678452B CN 201510998517 A CN201510998517 A CN 201510998517A CN 106678452 B CN106678452 B CN 106678452B
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- powder
- water
- tubing
- value function
- functional
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Classifications
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- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F16—ENGINEERING ELEMENTS AND UNITS; GENERAL MEASURES FOR PRODUCING AND MAINTAINING EFFECTIVE FUNCTIONING OF MACHINES OR INSTALLATIONS; THERMAL INSULATION IN GENERAL
- F16L—PIPES; JOINTS OR FITTINGS FOR PIPES; SUPPORTS FOR PIPES, CABLES OR PROTECTIVE TUBING; MEANS FOR THERMAL INSULATION IN GENERAL
- F16L9/00—Rigid pipes
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F1/00—Treatment of water, waste water, or sewage
- C02F1/28—Treatment of water, waste water, or sewage by sorption
- C02F1/281—Treatment of water, waste water, or sewage by sorption using inorganic sorbents
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F1/00—Treatment of water, waste water, or sewage
- C02F1/28—Treatment of water, waste water, or sewage by sorption
- C02F1/283—Treatment of water, waste water, or sewage by sorption using coal, charred products, or inorganic mixtures containing them
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F1/00—Treatment of water, waste water, or sewage
- C02F1/30—Treatment of water, waste water, or sewage by irradiation
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F1/00—Treatment of water, waste water, or sewage
- C02F1/66—Treatment of water, waste water, or sewage by neutralisation; pH adjustment
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F16—ENGINEERING ELEMENTS AND UNITS; GENERAL MEASURES FOR PRODUCING AND MAINTAINING EFFECTIVE FUNCTIONING OF MACHINES OR INSTALLATIONS; THERMAL INSULATION IN GENERAL
- F16L—PIPES; JOINTS OR FITTINGS FOR PIPES; SUPPORTS FOR PIPES, CABLES OR PROTECTIVE TUBING; MEANS FOR THERMAL INSULATION IN GENERAL
- F16L11/00—Hoses, i.e. flexible pipes
Landscapes
- Engineering & Computer Science (AREA)
- Chemical & Material Sciences (AREA)
- Water Supply & Treatment (AREA)
- Hydrology & Water Resources (AREA)
- Life Sciences & Earth Sciences (AREA)
- Environmental & Geological Engineering (AREA)
- Organic Chemistry (AREA)
- General Engineering & Computer Science (AREA)
- Mechanical Engineering (AREA)
- Inorganic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Toxicology (AREA)
- Physical Water Treatments (AREA)
- Solid-Sorbent Or Filter-Aiding Compositions (AREA)
Abstract
The present invention provides a kind of tubing for having and activating and adjusting water pH value function, which is characterized in that the plastic pipe is squeezed out by double-layer coextrusion, and wherein internal layer is composite material, and outer layer is pure resin material.Inner layer material is the composite material with activating and purifying water function, is prepared by functional powder and fluoropolymer resin blending extrusion;A certain amount of functional powder is added in inner layer composite material, composition includes tourmaline powder, graphene, medical stone powder, bamboo charcoal powder, cerium oxide, zirconium oxide, titanium oxide, compound rare-earth powder Multiple components.The functional form tubing is activated with water body, adjusts the effect of water pH value.
Description
Technical field
The present invention relates to tubing technical fields, specifically, be it is a kind of have the function of activated water and adjust water pH value
Tubing.
Background technology
Water is Source of life, is that the mankind depend on for existence material base.Water clusters in life are about by 30~40
Hydrone forms, the water molecule cluster bigger being contaminated, and it is strong to show that small molecule water body is beneficial to human body by research practice
Health.Therefore, the hydrone number for reducing daily water consumption molecular cluster, to be more suitable for human health water.Small molecule water body is formed
Right low, dissolving power, penetration, metabolism power, extension, emulsifying ability are higher, can enhance the new of organism to a certain extent
Old metabolism, blood lipid metabolism, enzymatic activity and immune function.
Inner tubing layers prepared by the present invention use composite material, by introducing functional powder, in pipeline water delivery process
In, it realizes activation water body, adjusts water PH value, and the effect of purifying water body to a certain extent.The function powder has infrared
Line transmitting, surface field function, and adjusted by certain formula, various functions are strengthened.Can have to a certain extent
Effect destroys hydrogen bond action, so that associated water molecules effect is reduced, realizes the effect of activated water.In addition, the complex function powder can also
The harmful substances such as bleaching powder in tap water are adsorbed and neutralized, have the function of adjusting pH value and purifying water body.Water body after activation,
It can be applied in multiple fields such as family kitchen and bath, industry, agricultural, health cares.
Invention content
There is activated water it is an object of the invention to overcome the deficiencies of the prior art and provide one kind and adjust water pH value work(
The tubing of energy.
The purpose of the present invention is achieved through the following technical solutions:
A kind of tubing with activated water and adjusting water pH value function, which is characterized in that tubing is squeezed by double-layer coextrusion
Go out, internal layer is the composite material with activating and purifying water function, and cladding material is resin matrix;Internal layer is auxiliary by functional powder
Auxiliary agent is prepared with resin matrix blending extrusion;The material quality percentage of functional powder is:Graphene 0.1~1%,
Medical stone powder 5~20%, bamboo charcoal powder 5~10%, cerium oxide 10~15%, zirconium oxide 5~8%, titanium oxide 5~10% are compound
Rare earth powder 5~15%, porous silica are 20~30%, and tourmaline is surplus.
The internal layer thickness is 1 with outer layer thickness ratio:10~1:Between 1.
The internal layer is prepared by auxiliary addition agent, functional powder with resin matrix blending extrusion.
The functional powder accounts for the 5~20% of inner layer material gross mass.
The auxiliary addition agent accounts for the 1~6% of inner layer material gross mass.
The auxiliary addition agent is divided into compatilizer and dispersant etc., and adding proportion is adjusted according to powder and resin ratio.
There is tourmaline natural electric polarity, electric field can destroy the hydrogen bond in hydrone, change the cluster structure of hydrone,
Macromolecular water is become micromolecular water.Further, since it is with pyroelectricity and piezoelectricity, when minor change occurs for temperature or pressure
When, the variation of tourmaline interior molecules dipole moment, makes molecule be energized into high level caused by meeting, extra when its downward transition
Energy will be released in the form of infra-red radiation.Therefore, tourmaline also has the function of emitting far-infrared, far infrared
Energy and water in hydrogen bond generate resonance, the hydrogen bond in hydrone can be opened, make associated water molecules effect reduce, realization
The effect of activated water.
Likewise, graphene, bamboo charcoal powder also have far-infrared transmitting function, acted synergistically by certain allotment, it can be with
Realize the optimization of infrared effect emissivity.
Cerium oxide, compound rare-earth powder are rare earth material, and under tourmaline electric field action, part electronics is forced with direction of an electric field
Displacement, recombination probability are reduced, electronics -- the reduction of hole-recombination probability, and dissociation hydrone has been gathered for composite granule surface
Big energy, water body activation effect can be improved to a certain extent.And the doping of zirconium oxide, titanium oxide and rare earth material, it can
To further increase the performance.
In addition, the harmful substances such as bleaching powder in tap water can also be adsorbed and be neutralized to medical stone, bamboo charcoal powder, has and adjust pH value
And the effect of purifying water body.
The average-size of the functional powder is at 0.01~1 micron.
The resin matrix that the plastic pipe ectonexine is selected is same raw material, be PP complete serieses product (PPR,
PPB, PPH, PP-RCT), PE series of products (PE, PERT etc.), one kind in PB series of products.
As preferred technical solution:
The mass percent of functional powder is respectively to press tourmaline 20%, graphene 0.3%, medical stone powder 8%, bamboo charcoal
Powder 7.7%, cerium oxide 9%, zirconium oxide 5%, titanium oxide 5%, compound rare-earth powder 10%, porous silica 35% are matched
Material;
The preparation of functional powder:By tourmaline, graphene, medical stone powder, bamboo charcoal powder, cerium oxide, zirconium oxide, oxidation
Titanium, compound rare-earth powder dispensing are component A;And the porous silica that average grain diameter is 10~20 microns is B component, is then adopted
With the method for ball mill dry grinding, the mixture of component A and B component is ground, is controlled in process of lapping, zirconium strain is ground
Average grain diameter is 0.1~1.5mm, filling rate 65~70%, and grinding rotating speed is 2000~3500r/min, milling time for 25~
55min makes powder adequately be mixed, and then abrasive material is transferred in the high-temperature laser agglomerating chamber of nitrogen protection again, into
Row laser Fast Sintering, power is 900W in sintering process, and the abrasive material thickness that tiles is 0.3mm, sintering rate 0.5m/min,
Functional powder is prepared.
Mainly control function powder and porous silica not only improve powder again at mineralization process in sintering process
It is bonded in porous silica, reduces powder and be lost in, while using high-temperature laser promotion functions powder in porous silica
Middle chanza improves the synergistic effect of function powder.
Compared with prior art, the positive effect of the present invention is:
It is of the present invention that there is activated water, the tubing of water pH value function is adjusted, the advantage is that in existing plastic conduit
On the basis of, by certain modification, assign duct products multiple functions., it can be achieved that activating water body during pipeline water delivery,
Adjust water pH value, and the effect of purifying water body to a certain extent.The pipeline can be protected in family kitchen and bath, industry, agricultural, medical treatment
The multiple fields such as strong are applied.
Description of the drawings
Fig. 1 is the radial and axial sectional view with the tubing for activating and adjusting water pH value function;1a is radial section
Figure, 1b is axial section;
Label in attached drawing is respectively:1 internal layer, 2 outer layers, 3 function powders.
Specific implementation mode
A kind of specific implementation mode with activated water and the tubing for adjusting water pH value function of the present invention presented below.
Embodiment 1
Such as a kind of tubing with activated water and adjusting water pH value function of Fig. 1, which is characterized in that by internal layer 1 and outer layer 2
Compound two layers, internal layer is the functional layer of activating and purifying water function.Containing functional in the functional layer of the activating and purifying water function
Property powder 3.
Shown prepare has activated water, adjusts the tubing of water pH value function, is squeezed out by double-layer coextrusion, and specification ruler is made
It is very little to bePPR pipe, internal layer wall thickness 0.8mm, outer layer wall thickness 1.5mm.Outer layer is PPR pure resins, interior
Layer is the composite material with activating and purifying water function, is prepared by functional powder and PPR resin melt blending extrusion, work(
Energy powder accounts for the 15% of gross weight.The function powder added, mixed proportion are:The mass percent of functional powder is respectively
By tourmaline 20%, graphene 0.3%, medical stone powder 8%, bamboo charcoal powder 7.7%, cerium oxide 9%, zirconium oxide 5%, titanium oxide
5%, compound rare-earth powder 10%, porous silica 35% carry out dispensing;
The preparation of functional powder:By tourmaline, graphene, medical stone powder, bamboo charcoal powder, cerium oxide, zirconium oxide, oxidation
Titanium, compound rare-earth powder dispensing are component A;And the porous silica that average grain diameter is 10~20 microns is B component, is then adopted
With the method for ball mill dry grinding, the mixture of component A and B component is ground, is controlled in process of lapping, zirconium strain is ground
Average grain diameter is 0.1~1.5mm, filling rate 65~70%, and grinding rotating speed is 2000~3500r/min, milling time for 25~
55min makes powder adequately be mixed, and then abrasive material is transferred in the high-temperature laser agglomerating chamber of nitrogen protection again, into
Row laser Fast Sintering, power is 900W in sintering process, and the abrasive material thickness that tiles is 0.3mm, sintering rate 0.5m/min,
Functional powder is prepared.
Prepared function tubing has carried out nuclear-magnetism and pH value test, as a result as follows:
Data are shown, after of short duration processing tap water, half peak of nuclear magnetic resonance of water body decreased significantly.H NMR spectroscopy line
Width can characterize the average relative size of liquid water cluster, and spectral line is wider, and cluster is bigger, and vice versa.Thus, it is believed that logical
The function line treatment is crossed, the water body activation of first-class degree may be implemented.In addition, after water body is handled 48 hours in function pipe,
It can be risen with the pH value of water body, reach adjusting pH value to a certain extent, neutralize the effect of water quality.
The above is only a preferred embodiment of the present invention, it is noted that for the ordinary skill people of the art
Member, without departing from the inventive concept of the premise, can also make several improvements and modifications, these improvements and modifications also should be regarded as
In protection scope of the present invention.
Claims (6)
1. a kind of tubing with activated water and adjusting water pH value function, which is characterized in that tubing is squeezed out by double-layer coextrusion,
Internal layer is the composite material with activating and purifying water function, and cladding material is resin matrix;Internal layer is helped by functional powder, auxiliary
Agent is prepared with resin matrix blending extrusion;The material quality percentage of functional powder is:Graphene 0.1~1%, wheat meal
Mountain flour 5~20%, bamboo charcoal powder 5~10%, cerium oxide 10~15%, zirconium oxide 5~8%, titanium oxide 5~10%, compound rare-earth powder 5~
15%, porous silica is 20~30%, and tourmaline is surplus;
The preparation of functional powder:By tourmaline, graphene, medical stone powder, bamboo charcoal powder, cerium oxide, zirconium oxide, titanium oxide is multiple
It closes rare earth powder and is made into component A;And the porous silica that average grain diameter is 10~20 microns is B component, then uses ball milling
The method of machine dry grinding is ground the mixture of component A and B component, controls in process of lapping, and grinding zirconium pearl is averaged grain
Diameter is 0.1~1.5mm, and filling rate 65~70%, grinding rotating speed is 2000~3500r/min, and milling time is 25~55min, is made
Powder is adequately mixed, and then abrasive material is transferred in the high-temperature laser agglomerating chamber of nitrogen protection again, and it is fast to carry out laser
Speed is sintered, and power is 900W in sintering process, and abrasive material tiles thickness as 0.3mm, and sintering rate 0.5m/min is prepared
Functional powder.
2. a kind of tubing with activated water and adjusting water pH value function as described in claim 1, which is characterized in that described
Internal layer thickness and outer layer thickness ratio be 1:10~1:Between 1.
3. a kind of tubing with activated water and adjusting water pH value function as described in claim 1, which is characterized in that described
Functional powder account for the 5~20% of inner layer material gross mass.
4. a kind of tubing with activated water and adjusting water pH value function as described in claim 1, which is characterized in that described
Auxiliary addition agent account for the 1~6% of inner layer material gross mass.
5. a kind of tubing with activated water and adjusting water pH value function as described in claim 1, which is characterized in that described
Auxiliary addition agent be divided into compatilizer and dispersant.
6. a kind of tubing with activated water and adjusting water pH value function as described in claim 1, which is characterized in that described
Functional powder average-size at 0.01~1 micron.
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CN201510998517.9A CN106678452B (en) | 2015-12-26 | 2015-12-26 | A kind of tubing with activated water and adjusting water pH value function |
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CN201510998517.9A CN106678452B (en) | 2015-12-26 | 2015-12-26 | A kind of tubing with activated water and adjusting water pH value function |
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CN106678452A CN106678452A (en) | 2017-05-17 |
CN106678452B true CN106678452B (en) | 2018-07-13 |
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Families Citing this family (3)
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CN108278422B (en) * | 2018-01-29 | 2020-01-21 | 天智羲王管道科技有限公司 | Construction method of silver ion graphene CIPP (CIPP) overturning lining |
CN111387206A (en) * | 2019-09-05 | 2020-07-10 | 绿城装饰工程集团有限公司 | Antibacterial tourmaline negative ion powder master batch and preparation method thereof |
CN117658612B (en) * | 2023-12-05 | 2024-07-16 | 宜兴市海王陶瓷研究所 | Super-induction functional material and preparation method and application thereof |
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CN1392115A (en) * | 2002-08-13 | 2003-01-22 | 河北工业大学 | Multifunctinoal health ceramic material and its preparing method and use |
CN101311212A (en) * | 2007-05-25 | 2008-11-26 | 施健 | Tourmaline plastic-based agglomerate material, production process thereof and pipes prepared from the material |
CN103274674A (en) * | 2013-06-17 | 2013-09-04 | 金刚新材料股份有限公司 | Preparation method of alumina porcelain ball for dry process ball mill |
CN103289540A (en) * | 2013-05-27 | 2013-09-11 | 河南新飞制冷器具有限公司 | Plastic powder releasing negative ions and manufacturing method thereof |
CN104829219A (en) * | 2015-05-22 | 2015-08-12 | 魏健 | Multifunctional composite tourmaline energy ceramic ball and manufacturing method thereof |
Family Cites Families (1)
Publication number | Priority date | Publication date | Assignee | Title |
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JP2008051331A (en) * | 2006-08-28 | 2008-03-06 | Shigeju Akiyama | Pipe material such as tap water pipe, water supply pipe and pipe coupling of various shapes |
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Patent Citations (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN1392115A (en) * | 2002-08-13 | 2003-01-22 | 河北工业大学 | Multifunctinoal health ceramic material and its preparing method and use |
CN101311212A (en) * | 2007-05-25 | 2008-11-26 | 施健 | Tourmaline plastic-based agglomerate material, production process thereof and pipes prepared from the material |
CN103289540A (en) * | 2013-05-27 | 2013-09-11 | 河南新飞制冷器具有限公司 | Plastic powder releasing negative ions and manufacturing method thereof |
CN103274674A (en) * | 2013-06-17 | 2013-09-04 | 金刚新材料股份有限公司 | Preparation method of alumina porcelain ball for dry process ball mill |
CN104829219A (en) * | 2015-05-22 | 2015-08-12 | 魏健 | Multifunctional composite tourmaline energy ceramic ball and manufacturing method thereof |
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