CN106676918B - A kind of hydrophilic color fixing agent of environment-friendly type cotton - Google Patents
A kind of hydrophilic color fixing agent of environment-friendly type cotton Download PDFInfo
- Publication number
- CN106676918B CN106676918B CN201710052986.0A CN201710052986A CN106676918B CN 106676918 B CN106676918 B CN 106676918B CN 201710052986 A CN201710052986 A CN 201710052986A CN 106676918 B CN106676918 B CN 106676918B
- Authority
- CN
- China
- Prior art keywords
- polyquaternium
- ethyl
- quaternary ammonium
- acrylyl oxy
- ammonium chloride
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Active
Links
Classifications
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P5/00—Other features in dyeing or printing textiles, or dyeing leather, furs, or solid macromolecular substances in any form
- D06P5/02—After-treatment
- D06P5/04—After-treatment with organic compounds
- D06P5/08—After-treatment with organic compounds macromolecular
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F220/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
- C08F220/02—Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
- C08F220/10—Esters
- C08F220/34—Esters containing nitrogen, e.g. N,N-dimethylaminoethyl (meth)acrylate
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F222/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a carboxyl radical and containing at least one other carboxyl radical in the molecule; Salts, anhydrides, esters, amides, imides, or nitriles thereof
- C08F222/10—Esters
- C08F222/1006—Esters of polyhydric alcohols or polyhydric phenols
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F222/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a carboxyl radical and containing at least one other carboxyl radical in the molecule; Salts, anhydrides, esters, amides, imides, or nitriles thereof
- C08F222/10—Esters
- C08F222/1006—Esters of polyhydric alcohols or polyhydric phenols
- C08F222/104—Esters of polyhydric alcohols or polyhydric phenols of tetraalcohols, e.g. pentaerythritol tetra(meth)acrylate
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Textile Engineering (AREA)
- Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
Abstract
The present invention provides a kind of hydrophilic color fixing agent of environment-friendly type cotton, it calculates by weight, it includes 10~50 parts of quaternary ammonium salt monomers, 5~25 parts of amine monomers, 5~40 parts of acrylic ester monomers, 1~5 part of pentaerythritol triallyl ether, 5~15 parts of polyquaterniums that the environment-friendly type cotton prepares raw material with hydrophilic color fixing agent；Wherein, the quaternary ammonium salt monomer includes one or more in acrylyl oxy-ethyl alkyl quaternary ammonium salts, allyl alkyl quaternary ammonium salt；The amine monomers include one or more in diethylenetriamine, triethylene tetramine, tetraethylenepentamine.
Description
Technical field
The present invention relates to color fixing agent technical fields, more particularly it relates to a kind of hydrophilic color fixing agent of environment-friendly type cotton
And preparation method thereof.
Background technology
In today's society, people pay more attention to health dress, increasingly like the natural fiber of Eco-friendly.Cotton is fine
Dimension is a natural fiber, and has the series of advantages such as good warmth retention property, hygroscopicity in wearability, thus natural
There is consequence in fiber.
Reactive dye have that cheap, chromatography is complete, the series of advantages such as bright in colour, have been widely used for the dye of cotton
Color.Although it can be combined into covalent bond with cotton fiber, since reactive dye exist in hydrolysis and color dyeing kind fiber
Group for reactive dye reaction is limited, therefore its covalent bonding between cotton fiber is still not enough, upper on fiber
Dye rate is not high, still needs to color fixing agent and carries out fixation.
Color fixing agent is exactly the color fastness in order to make dyed fabric reach satisfied as the use of dyeing and finishing auxiliaries, keeps appearance.
Fabric using color fixing agent processing after, then can by make dyestuff formed insoluble color lake, on the fabric generate reticulated film, make dyestuff
The mode for generating chemical bonds between fiber and increasing the intermolecular attraction of dyestuff and fiber improves the washing of dyed fabric
Fastness.
Polyquaternium cationic type color fixing agent can be used for the fixation of Fabrics Dyed with Reactive Dyes, energy and dyestuff well
Insoluble color lake is generated on dyed fabric, while it can also form a film in fiber surface, reduce falling off for dyestuff, it is good to reach
Good colour fixation.But so that the hydrophily of cotton fabric is deteriorated due to the crosslinking feature of its high temperature film forming, after fixation, or make to knit
Object is hardened, and feel is bad.
Therefore, the present invention provides a kind of hydrophilic color fixing agent of environment-friendly type cotton, does not influence the hydrophily and hand of fabric not only
Sense, and reticulated film can be generated on the fabric, there is good film forming, improve washing fastness and the wet friction jail of dyed fabric
Degree, colour fixation is good, does not reduce the sunlight fastness of fabric, fastness to perspiration also.
Invention content
The present invention provides a kind of hydrophilic color fixing agent of environment-friendly type cotton, calculates by weight, and the environment-friendly type cotton is with hydrophilic solid
It includes 10~50 parts of quaternary ammonium salt monomers, 5~25 parts of amine monomers, 5~40 parts of acrylic ester monomers, 1~5 that toner, which prepares raw material,
Part pentaerythritol triallyl ether, 5~15 parts of polyquaterniums；Wherein, the quaternary ammonium salt monomer includes acrylyl oxy-ethyl alkyl
It is one or more in quaternary ammonium salt, allyl alkyl quaternary ammonium salt；The amine monomers include diethylenetriamine, triethylene tetramine, four
It is one or more in five amine of ethylene.
In one embodiment, the weight of the acrylyl oxy-ethyl alkyl quaternary ammonium salts and the allyl alkyl quaternary ammonium salt
Amount is than being 1：(0.2~1).
In one embodiment, the acrylyl oxy-ethyl alkyl quaternary ammonium salts includes acrylyl oxy-ethyl-trimethyl chlorination
Ammonium, MethacryloyloxyethylTrimethyl Trimethyl Ammonium Chloride, acrylyl oxy-ethyl-trimethyl ammonium bromide, methylacryoyloxyethyl front three
Base ammonium bromide, acrylyl oxy-ethyl-dodecyl-alkyl dimethyl ammonium chloride, methylacryoyloxyethyl-dodecyl-dimethyl
Ammonium chloride, acrylyl oxy-ethyl-dodecyl-ditallowdimethyl ammonium bromide, methylacryoyloxyethyl-dodecyl-diformazan bromide
Change ammonium, acrylyl oxy-ethyl-myristyl-alkyl dimethyl ammonium chloride, methylacryoyloxyethyl-myristyl-dimethylammonium chloride
Ammonium, acrylyl oxy-ethyl-myristyl-ditallowdimethyl ammonium bromide, methylacryoyloxyethyl-myristyl-ditallowdimethyl ammonium bromide,
Acrylyl oxy-ethyl-cetyl-alkyl dimethyl ammonium chloride, methylacryoyloxyethyl-cetyl-alkyl dimethyl ammonium chloride, third
Alkene acyloxyethyl-cetyl-ditallowdimethyl ammonium bromide, methylacryoyloxyethyl-cetyl-ditallowdimethyl ammonium bromide, propylene
Acyloxyethyl-octadecyl-alkyl dimethyl ammonium chloride, methylacryoyloxyethyl-octadecyl-alkyl dimethyl ammonium chloride, acryloyl
Oxygen ethyl-octadecyl-ditallowdimethyl ammonium bromide, one kind in methylacryoyloxyethyl-octadecyl-ditallowdimethyl ammonium bromide or
It is a variety of；The allyl alkyl quaternary ammonium salt includes allyl trimethyl ammonium chloride, allyl trimethylammonium bromide, dimethyl diene
Propyl ammonium chloride, dimethyl diallyl ammonium bromide, dodecylallyldimethylammonium chloride, dodecyl dimethyl allyl
Base ammonium bromide, dodecyldimethylamine base allyl ammonium chloride, dodecyldimethylamine base allylic bromination ammonium, hexadecyldimethyl benzyl ammonium
Allyl ammonium chloride, hexadecyldimethyl benzyl ammonium allylic bromination ammonium, solution property, octadecyl two
It is one or more in methacrylic ammonium bromide.
In one embodiment, the acrylic ester monomer includes methyl acrylate, ethyl acrylate, acrylic acid third
Ester, butyl acrylate, n-octyl, acrylic acid-2-ethyl caproite, pentaerythritol triacrylate, diethylene glycol double third
It is one or more in olefin(e) acid ester, 2-hydroxyethyl methacry-late, methyl methacrylate.
In one embodiment, the acrylic ester monomer is methyl acrylate, pentaerythritol triacrylate, two
Ethylene glycol diacrylate.
In one embodiment, the methyl acrylate and the pentaerythritol triacrylate, the diethylene glycol
Double methacrylate weight ratio is 1：(1~5)：(0.5~1).
In one embodiment, the polyquaternium includes polyquaternium -2, polyquaternium -4, polyquaternium -5, is gathered
Quaternary ammonium salt -6, polyquaternium -7, Polyquaternium-10, polyquaternium -11, polyquaternium -16, Merquat 280, polyquaternium -
24, polyquaternium -28, polyquaternium -32, polyquaternium -37, polyquaternium -39, polyquaternium -42, polyquaternium -43, gather
Quaternary ammonium salt -44, polyquaternium -46, polyquaternium -47, polyquaternium -51, polyquaternium -53, polyquaternium -55, polyquaternary amine
Salt -57, polyquaternium -58, polyquaternium -59, polyquaternium -60, polyquaternium -63, polyquaternium -65, polyquaternium -68
In it is one or more.
In one embodiment, the polyquaternium is polyquaternium -4 and polyquaternium -46.
In one embodiment, the polyquaternium -4 and -46 weight ratio of the polyquaternium are 1：(0.3~1).
Another aspect of the present invention provides a kind of environment-friendly type cotton preparation method of hydrophilic color fixing agent, includes the following steps：
(1) quaternary ammonium salt monomer, amine monomers, acrylic ester monomer, Ji Wusi is added into reactor according to parts by weight
Alcohol triallyl ether and water are warming up to 70~85 DEG C；
(2) initiator is added portionwise into reactor by weight, reacts 4~10h, obtains cationic copolymer, it is described
Initiator is 1~2 part；
(3) cationic copolymer, polyquaternium, catalyst and water that step (2) obtains are added into reactor, is warming up to
85~90 DEG C；
(4) initiator is added portionwise, reacts 6~8h, obtains the hydrophilic color fixing agent of the environment-friendly type cotton.
The above-mentioned of the application and other features, aspect and advantage is more readily understood with reference to following detailed description.
Specific implementation mode
The detailed description for preferred implementation method of the invention below of participating in the election of and including embodiment this hair can be more easily understood
Bright content.Unless otherwise defined, all technologies used herein and scientific terminology have common with fields of the present invention
The normally understood identical meaning of technical staff.When there is a conflict, the definition in this specification shall prevail.
As used herein term " by ... prepare " it is synonymous with "comprising".Term "comprising" used herein, " comprising ",
" having ", " containing " or its any other deformation, it is intended that cover non-exclusionism includes.For example, the combination comprising listed elements
Object, step, method, product or device are not necessarily limited to those elements, but may include not expressly listed other elements or
Such composition, step, method, product or the intrinsic element of device.
Conjunction " Consists of " excludes any element that do not point out, step or component.If in claim, this
Phrase will make claim be closed, so that it is not included the material in addition to the material of those descriptions, but relative normal
Except rule impurity.When being rather than immediately following after theme in the clause that phrase " Consists of " appears in claim main body,
It is only limited to the element described in the clause；Other elements are not excluded except the claim as a whole.
Equivalent, concentration or other values or parameter are excellent with range, preferred scope or a series of upper limit preferred values and lower limit
When the Range Representation that choosing value limits, this, which should be understood as, specifically discloses by any range limit or preferred value and any range
Any pairing of lower limit or preferred value is formed by all ranges, regardless of whether the range separately discloses.For example, when open
When range " 1 to 5 ", described range should be interpreted as including range " 1 to 4 ", " 1 to 3 ", " 1 to 2 ", " 1 to 2 and 4 to
5 ", " 1 to 3 and 5 " etc..When numberical range is described herein, unless otherwise stated, otherwise range intention includes its end
Value and all integers and score in the range.
Singulative includes that plural number discusses object, unless the context clearly dictates otherwise." optional " or it is " arbitrary
It is a kind of " refer to that the item described thereafter or event may or may not occur, and the description include situation that event occurs and
The situation that event does not occur.
Approximate term in specification and claims is used for modifying quantity, and it is specific to indicate that the present invention is not limited to this
Quantity further includes the modified part of the acceptable change without lead to related basic function close to the quantity.Phase
It answers, modifies a numerical value with " about ", " about " etc., mean that the present invention is not limited to the exact numericals.In some examples, approximate
Term likely corresponds to the precision of the instrument of measured value.In present specification and claims, range limits can be with
Combination and/or exchange, these ranges include all subranges contained therebetween if not stated otherwise.
In addition, indefinite article "an" before element of the present invention or component and "one" quantitative requirement to element or component
(i.e. occurrence number) unrestriction.Therefore "one" or "an" should be read as including one or at least one, and odd number
The element or component of form also include plural form, unless the apparent purport of the quantity refers to singulative.
" polymer " means the polymerizable compound prepared by the monomer by the identical or different type of polymerization.Generic term
" polymer " includes term " homopolymer ", " copolymer ", " terpolymer " and " copolymer ".
" copolymer " means the polymer prepared by polymerizeing at least two different monomers.Generic term " copolymer " includes
(it is general with term " terpolymer " for term " copolymer " (its generally to refer to the polymer prepared by two kinds of different monomers)
To refer to the polymer prepared by three kinds of different monomers).It also includes the polymer manufactured by polymerizeing more kinds of monomers.
" blend " means the polymer that two or more polymer is formed by mixing jointly by physics or chemical method.
The present invention provides a kind of hydrophilic color fixing agent of environment-friendly type cotton, calculates by weight, and the environment-friendly type cotton is with hydrophilic solid
It includes 10~50 parts of quaternary ammonium salt monomers, 5~25 parts of amine monomers, 5~40 parts of acrylic ester monomers, 1~5 that toner, which prepares raw material,
Part pentaerythritol triallyl ether, 5~15 parts of polyquaterniums；Wherein, the quaternary ammonium salt monomer includes acrylyl oxy-ethyl alkyl
It is one or more in quaternary ammonium salt, allyl alkyl quaternary ammonium salt；The amine monomers include diethylenetriamine, triethylene tetramine, four
It is one or more in five amine of ethylene.
In one embodiment, the amine monomers are diethylenetriamine, triethylene tetramine.
In one embodiment, the weight ratio of the diethylenetriamine and the triethylene tetramine is 1：(0.2~
1.1)；Preferably, the weight ratio of the diethylenetriamine and the triethylene tetramine is 1：(0.3~0.7)；It is highly preferred that institute
The weight ratio for stating diethylenetriamine and the triethylene tetramine is 1：0.32.
Quaternary ammonium salt has bactericidal active quaternary ammonium salt compound, and there are one cation groups, it is easy to be adsorbed on band negative electricity
The bacterium surface of lotus, the ionic group that high concentration is formed in cell surface directly affect bacterium to change the property of cell membrane
Metabolism.
In one embodiment, the weight of the acrylyl oxy-ethyl alkyl quaternary ammonium salts and the allyl alkyl quaternary ammonium salt
Amount is than being 1：(0.2~1)；Preferably, the weight of the acrylyl oxy-ethyl alkyl quaternary ammonium salts and the allyl alkyl quaternary ammonium salt
Amount is than being 1：(0.5~1)；It is highly preferred that the acrylyl oxy-ethyl alkyl quaternary ammonium salts and the allyl alkyl quaternary ammonium salt
Weight ratio is 1：0.63.
In one embodiment, the acrylyl oxy-ethyl alkyl quaternary ammonium salts includes acrylyl oxy-ethyl-trimethyl chlorination
Ammonium, MethacryloyloxyethylTrimethyl Trimethyl Ammonium Chloride, acrylyl oxy-ethyl-trimethyl ammonium bromide, methylacryoyloxyethyl front three
Base ammonium bromide, acrylyl oxy-ethyl-dodecyl-alkyl dimethyl ammonium chloride, methylacryoyloxyethyl-dodecyl-dimethyl
Ammonium chloride, acrylyl oxy-ethyl-dodecyl-ditallowdimethyl ammonium bromide, methylacryoyloxyethyl-dodecyl-diformazan bromide
Change ammonium, acrylyl oxy-ethyl-myristyl-alkyl dimethyl ammonium chloride, methylacryoyloxyethyl-myristyl-dimethylammonium chloride
Ammonium, acrylyl oxy-ethyl-myristyl-ditallowdimethyl ammonium bromide, methylacryoyloxyethyl-myristyl-ditallowdimethyl ammonium bromide,
Acrylyl oxy-ethyl-cetyl-alkyl dimethyl ammonium chloride, methylacryoyloxyethyl-cetyl-alkyl dimethyl ammonium chloride, third
Alkene acyloxyethyl-cetyl-ditallowdimethyl ammonium bromide, methylacryoyloxyethyl-cetyl-ditallowdimethyl ammonium bromide, propylene
Acyloxyethyl-octadecyl-alkyl dimethyl ammonium chloride, methylacryoyloxyethyl-octadecyl-alkyl dimethyl ammonium chloride, acryloyl
Oxygen ethyl-octadecyl-ditallowdimethyl ammonium bromide, one kind in methylacryoyloxyethyl-octadecyl-ditallowdimethyl ammonium bromide or
It is a variety of；The allyl alkyl quaternary ammonium salt includes allyl trimethyl ammonium chloride, allyl trimethylammonium bromide, dimethyl diene
Propyl ammonium chloride, dimethyl diallyl ammonium bromide, dodecylallyldimethylammonium chloride, dodecyl dimethyl allyl
Base ammonium bromide, dodecyldimethylamine base allyl ammonium chloride, dodecyldimethylamine base allylic bromination ammonium, hexadecyldimethyl benzyl ammonium
Allyl ammonium chloride, hexadecyldimethyl benzyl ammonium allylic bromination ammonium, solution property, octadecyl two
It is one or more in methacrylic ammonium bromide；
Preferably, the acrylyl oxy-ethyl alkyl quaternary ammonium salts includes acrylyl oxy-ethyl-dodecyl-dimethylammonium chloride
Ammonium, methylacryoyloxyethyl-dodecyl-alkyl dimethyl ammonium chloride, acrylyl oxy-ethyl-myristyl-alkyl dimethyl ammonium chloride,
Methylacryoyloxyethyl-myristyl-alkyl dimethyl ammonium chloride, acrylyl oxy-ethyl-cetyl-alkyl dimethyl ammonium chloride, first
Base acrylyl oxy-ethyl-cetyl-alkyl dimethyl ammonium chloride, acrylyl oxy-ethyl-octadecyl-alkyl dimethyl ammonium chloride, methyl
It is one or more in acrylyl oxy-ethyl-octadecyl-alkyl dimethyl ammonium chloride；It is highly preferred that the acrylyl oxy-ethyl alkane
Based quaternary ammonium salt is acrylyl oxy-ethyl-dodecyl-alkyl dimethyl ammonium chloride, acrylyl oxy-ethyl-myristyl-dimethylammonium chloride
Ammonium；Acrylyl oxy-ethyl-dodecyl-the alkyl dimethyl ammonium chloride and acrylyl oxy-ethyl-myristyl-alkyl dimethyl ammonium chloride
Weight ratio be 1：0.52.
Preferably, the allyl alkyl quaternary ammonium salt include allyl trimethyl ammonium chloride, allyl trimethylammonium bromide,
Dimethyl diallyl ammonium chloride, dimethyl diallyl ammonium bromide, dodecylallyldimethylammonium chloride, dodecyl
Dimethyl-allyl ammonium bromide, dodecyldimethylamine base allyl ammonium chloride, dodecyldimethylamine base allylic bromination ammonium, 16
Alkyl dimethyl allyl ammonium chloride, hexadecyldimethyl benzyl ammonium allylic bromination ammonium, solution property,
It is one or more in octadecyldimethyl allylic bromination ammonium；Preferably, the allyl alkyl quaternary ammonium salt is dimethyl
Diallyl ammonium chloride and dodecyldimethylamine base allyl ammonium chloride；The dimethyl diallyl ammonium chloride and described 14
The weight ratio of alkyl dimethyl allyl ammonium chloride is 1：1.1.
Alkyl carbon number is C in the present invention12-C18Cationic monomer also have other than with excellent fixing property
Excellent bactericidal performance, and it is C that fabric can be made, which to obtain better flexibility and feel, especially alkyl carbon number,12-C14
Quaternary ammonium salt bactericide bacteriostasis property it is best；In addition, compared with single quaternary ammonium salt small molecule and hydrophilic quaternary ammonium salt, the present invention provides
Cationic monomer copolymerization polymeric quaternary ammonium salt compound, will not be by bio-absorbable, toxicity smaller.
In one embodiment, the acrylic ester monomer includes methyl acrylate, ethyl acrylate, acrylic acid third
Ester, butyl acrylate, n-octyl, acrylic acid-2-ethyl caproite, pentaerythritol triacrylate, diethylene glycol double third
It is one or more in olefin(e) acid ester, 2-hydroxyethyl methacry-late, methyl methacrylate.
In one embodiment, the acrylic ester monomer is methyl acrylate, pentaerythritol triacrylate, two
Ethylene glycol diacrylate.
In one embodiment, the methyl acrylate and the pentaerythritol triacrylate, the diethylene glycol
Double methacrylate weight ratio is 1：(1~5)：(0.5~1)；Preferably, the methyl acrylate and three propylene of the pentaerythrite
Acid esters, the diethylene glycol double methacrylate weight ratio are 1：3：0.6.
In one embodiment, the polyquaternium includes polyquaternium -2, polyquaternium -4, polyquaternium -5, is gathered
Quaternary ammonium salt -6, polyquaternium -7, Polyquaternium-10, polyquaternium -11, polyquaternium -16, Merquat 280, polyquaternium -
24, polyquaternium -28, polyquaternium -32, polyquaternium -37, polyquaternium -39, polyquaternium -42, polyquaternium -43, gather
Quaternary ammonium salt -44, polyquaternium -46, polyquaternium -47, polyquaternium -51, polyquaternium -53, polyquaternium -55, polyquaternary amine
Salt -57, polyquaternium -58, polyquaternium -59, polyquaternium -60, polyquaternium -63, polyquaternium -65, polyquaternium -68
In it is one or more.
Polyquaternium-X
Polyquaternium -2 is two (2- chloroethyls) ethers and N, N '-bis- [3- (dimethylamino) Bing Jis ]The polymer of urea；
Polyquaternium -4 is the copolymer of hydroxy ethyl cellulose and dimethyl diallyl ammonium chloride；
Polyquaternium -5 is the copolymer of acrylamide and Beta-methyl acryloyl group oxygroup ethyl-trimethyl ammonium methyl sulfate；
Polyquaternium -6 is polydimethyl diallyl ammonium chloride；
Polyquaternium -7 is the copolymer of dimethyl diallyl ammonium chloride and acrylamide；
Polyquaternium-10 is the epoxide reactive hydroxyethyl cellulose replaced with trimethyl ammonium；
Polyquaternium -11 is PVP and N, the copolymer dithyl sulfate solution of N- dimethyl aminoethyl methacrylic acids；
Polyquaternium -16 is 3- methyl-1s-vinylimidazolium chloride imidazoles-l-vinyl-2-pyrrolidone chloride；
Merquat 280 is acrylic acid-diallyldimethylammonium chloride (DADMAC) polymer；
Polyquaternium -24 is the polyquaternary amine of the epoxide reactive hydroxyethyl cellulose replaced with lauryl dimethyl ammonium
Salt；
Polyquaternium -28 is vinyl pyrrolidone/methacryiamidopropyl trimethyl ammonium chloride copolymer；
Polyquaternium -32 is total for acrylamide-dimethylamine ethylacrylate methyl chloride (DMAEMA)
Polymers；
Polyquaternium -37 is base acrylic acid trimethylaminoethyl group ester chloride polymer；
Polyquaternium -39 is the polymerization of acrylic acid (AA)/acrylamide and diallyldimethylammonium chloride (DADMAC)
Object；
Polyquaternium -42 is polyoxyethylene (dimethyl) ethylidene-(dimethyl) ethylene dichloride；
Polyquaternium -43 be acrylamide, acrylamidopropyl trimethyl ammonium chloride, amidopropyl acrylamide and
The copolymer of DMAPA monomers；
Polyquaternium -44 is the polyquaternium of vinyl pyrrolidone and quaternized imidazoline monomer；
Polyquaternium -46 is alkenyl caprolactam, the quaternary ammonium salt of vinyl pyrrolidone and methylvinyl imidazolium；
Polyquaternium -47 is aliquat-acrylic acid, methyl acrylate and methacryiamidopropyl trimethyl chlorine
Change ammonium；
Polyquaternium -51 is 3,5,8- tri- oxygen -4- phosphorus, 11 carbon -10- alkene -1- ammoniums, 4- hydroxy-ns, N, N, 10- tetramethyls -
9- oxos, inner salt, 4- oxides, the polymer with 2- methyl -2- butyl acrylates；
Polyquaternium -53 is acrylic acid (AA)/acrylamide/methacryiamidopropyl trimethyl ammonium chloride
(MAPTAC) copolymer；
Polyquaternium -55 is N, N- Er Jiaji-N-s [3-[(2- methyl-1s-oxo -2- acrylic) An Jibingji ]- 1- ten
Dialkylammonium chloride and N-[3- (dimethylamino) Bing Jis ]- 2- methyl -2- acrylamides and l-vinyl-2-pyrrolidone
Polymer；
Polyquaternium -57 is by castor-oil plant isostearate succinate and castor oil amidopropyl trimethyl ammonium chloride
The polymeric quaternary ammonium salt of (appropriate) monomer composition；
Polyquaternium -58 is 2- methyl acrylates and 2,2- bis-s [(2- acrylic oxygroup) Jia Ji ]N-butyl alcohol and divinyl
The polymer of base benzene, with N, the reaction product of N- dimethyl -1,3- propanediamine (chloromethanes-is quaternized)；
- 59 polyquaternium polyester of polyquaternium；
Polyquaternium -60 is 9- octadecenoic acids, 12- hydroxyls-, [(2- hydroxyethyls) Ya Anji ]Two -2,1- ethane two
Base ester, with 5- isocyanate groups -1- (isocyanatomethyl) -1, the polymer of 3,3- trimethyl-cyclohexanes is mixed with dimethyl suflfate
It closes；
Polyquaternium -63 is the copolymer of acrylamide, acrylic acid and ethyl-trimethyl salmiac acrylate；
Polyquaternium -65 is by 2- methylacryloyl oxygroup ethylphosphocholines, butyl methacrylate and methyl-prop
The polymeric quaternary ammonium salt of olefin(e) acid sodium monomer composition；
Polyquaternium -68 is vinyl pyrrolidone (VP), Methacrylamide (MAM) vinyl imidazole and quaternized
The quatemized copolymer of vinyl imidazole.
In one embodiment, the polyquaternium is polyquaternium -4 and polyquaternium -46.
In one embodiment, the polyquaternium -4 and -46 weight ratio of the polyquaternium are 1：(0.3~1).
Another aspect of the present invention provides a kind of environment-friendly type cotton preparation method of hydrophilic color fixing agent, includes the following steps：
(1) quaternary ammonium salt monomer, amine monomers, acrylic ester monomer, Ji Wusi is added into reactor according to parts by weight
Alcohol triallyl ether and water are warming up to 70~85 DEG C；
(2) initiator is added portionwise into reactor by weight, reacts 4~10h, obtains cationic copolymer, it is described
Initiator is 1~2 part；
(3) cationic copolymer, polyquaternium, catalyst and water that step (2) obtains are added into reactor, is warming up to
85~90 DEG C；
(4) initiator is added portionwise, reacts 6~8h, obtains the hydrophilic color fixing agent of the environment-friendly type cotton.
In one embodiment, it calculates by weight, the dosage of the water is 20~100 parts.
In one embodiment, the initiator includes azodiisobutyronitrile, azobisisoheptonitrile, azo diisobutyl
It is one or more in amidine hydrochloride, cyclohexanone peroxide, benzoyl peroxide, persulfate；Preferably, the initiator is
Azodiisobutyronitrile.
In one embodiment, it calculates by weight, the dosage of the initiator is 0.1~0.3 part；Preferably, institute
The dosage for stating initiator is 0.25 part.
In one embodiment, the weight average molecular weight of the cationic copolymer is 3000~20000；Preferably, institute
The weight average molecular weight for stating cationic copolymer is 5000~10000.
Weight average molecular weight is to be based on gel permeation chromatography (hreinafter referred to as " GPC ".) measure and carry out polystyrene and change
Value after calculation.The determination condition of GPC uses the condition test of this field routine, tests to obtain for example, following modes can be used.
Column：Following columns are connected in series with and are used.
" TSKgelG5000 " (7.8mmI.D. × 30cm) × 1 piece
" TSKgelG4000 " (7.8mmI.D. × 30cm) × 1 piece
" TSKgelG3000 " (7.8mmI.D. × 30cm) × 1 piece
" TSKgelG2000 " (7.8mmI.D. × 30cm) × 1 piece
Detector：RI (differential refractometer)；Column temperature：40℃；Eluent：Tetrahydrofuran；Flow velocity：1.0mL/ minute；Note
Enter amount：100 μ L (tetrahydrofuran solution of sample solution concentration 4mg/mL)；Standard sample：Using following monodisperse polystyrenes, make
Standard curve.
In one embodiment, the catalyst is Ziegler-Natta catalyst.
In one embodiment, it calculates by weight, the dosage of the catalyst is 0.5~1 part；Preferably, described
The dosage of catalyst is 0.56 part.
Reactive group is obtained in color fixing agent structure by making in the present invention, which can make color fixing agent itself
Reaction is crosslinked, and covalent bond can be formed with the hydroxyl reaction on fiber, makes color fixing agent that there is good filming performance
With cross-linking reaction performance.
Cationic monomer provided by the invention can be combined with reactive dye, form color lake；Wherein, alkyl carbon number is C12-
C18Cationic monomer also there is excellent bactericidal performance, and fabric can be made other than with excellent fixing property
Better flexibility and feel are obtained, in addition, compared with single quaternary ammonium salt small molecule and hydrophilic quaternary ammonium salt, it is provided by the invention
Cationic monomer be hydrophobicity and hydrophilic polymerized polymeric quaternary ammonium salt compound, will not be by bio-absorbable, toxicity smaller.
Traditional color fixing agent is easy to influence the feel of fabric, especially in high dosage after carrying out fixation treatment to fabric
When, the feel and flexibility of fabric can obviously be deteriorated, so generally require softening agent or fixation are added in fixation liquid after need
Soft treatment is carried out again；Contain methyl acrylate, pentaerythritol triallyl ether and Long carbon chain in the monomer that the present invention polymerize
When quaternary ammonium salt, the fabric after fixation treatment can have comfortable flexibility；Meanwhile monomer methyl acrylate provided by the invention,
Pentaerythritol triacrylate, diethylene glycol double methacrylate, pentaerythritol triallyl ether, quaternary ammonium salt are easy during the reaction
In polymerization, keep reaction process easily controllable, reaction product easily generates, and polymer itself crosslinks instead in the present invention
It answers, and covalent bond can be formed with the hydroxyl reaction on fiber, make color fixing agent that there is good filming performance and cross-linking reaction
Performance.
In addition, the cationic polymer that the present invention is 5000~10000 by polymerizeing weight average molecular weight, introduces polar group
Group's hydroxyl and amino, and the cationic polymer degree of cross linking is not high, the cationic polymer and polyquaternium -4 and poly- season
Ammonium salt -46 further polymerize, obtain high-crosslinking-degree and the hydroxyl on surface hydroxyl and amine based polymer, with dyestuff and fiber
Base or amido react crosslinking, enhance the binding force of polymer film and fiber and dyestuff, and the fixing property for improving color fixing agent is same
When also avoiding high temperature polymer crosslink and react and then influence hydrophily and flexibility.
The present invention is specifically described below by embodiment.It is necessarily pointed out that following embodiment is only used
In the invention will be further described, it should not be understood as limiting the scope of the invention, professional and technical personnel in the field
Some the nonessential modifications and adaptations made according to the content of aforementioned present invention, still fall within protection scope of the present invention.
In addition, if without other explanations, it is raw materials used to be all commercially available, it is purchased from traditional Chinese medicines chemical reagent.
Embodiment 1
The environment-friendly type cotton with hydrophilic color fixing agent prepare raw material include 24 parts of quaternary ammonium salt monomers, 16 parts of amine monomers, 30 parts
Acrylic ester monomer, 3 parts of pentaerythritol triallyl ethers, 8 parts of polyquaterniums；The quaternary ammonium salt monomer is acrylyl oxy-ethyl
Alkyl quaternary ammonium salts, allyl alkyl quaternary ammonium salt, the acrylyl oxy-ethyl alkyl quaternary ammonium salts and the allyl alkyl quaternary ammonium salt
Weight ratio be 1：0.63, the acrylyl oxy-ethyl alkyl quaternary ammonium salts is acrylyl oxy-ethyl-dodecyl-dimethylammonium chloride
Ammonium, acrylyl oxy-ethyl-myristyl-alkyl dimethyl ammonium chloride, the acrylyl oxy-ethyl-dodecyl-alkyl dimethyl ammonium chloride
Weight ratio with acrylyl oxy-ethyl-myristyl-alkyl dimethyl ammonium chloride is 1：0.52, the allyl alkyl quaternary ammonium salt is two
Methyl diallyl ammonium chloride and dodecyldimethylamine base allyl ammonium chloride, the dimethyl diallyl ammonium chloride with it is described
The weight ratio of dodecyldimethylamine base allyl ammonium chloride is 1：1.1；The amine monomers are diethylenetriamine, triethylene four
The weight ratio of amine, the diethylenetriamine and the triethylene tetramine is 1：0.32；The acrylic ester monomer is acrylic acid
Methyl esters, pentaerythritol triacrylate, diethylene glycol double methacrylate, the methyl acrylate and three propylene of the pentaerythrite
Acid esters, the diethylene glycol double methacrylate weight ratio are 1：3：0.6；The polyquaternium is polyquaternium -4 and polyquaternary amine
Salt -46, the polyquaternium -4 are 1 with -46 weight ratio of the polyquaternium：0.72；
The environment-friendly type cotton preparation method of hydrophilic color fixing agent, includes the following steps：
(1) quaternary ammonium salt monomer, amine monomers, acrylic ester monomer, Ji Wusi is added into reactor according to parts by weight
Alcohol triallyl ether and water are warming up to 80 DEG C；The water is 80 parts；
(2) initiator is added portionwise into reactor by weight, reacts 7h, obtains cationic copolymer, the initiation
Agent is azodiisobutyronitrile, and the initiator is 1.6 parts；
(3) cationic copolymer, polyquaternium, catalyst and water that step (2) obtains are added into reactor, is warming up to
90℃；The catalyst is Ziegler-Natta catalyst；The dosage of the catalyst is 0.56 part；The water is 100 parts；
The weight average molecular weight of the cationic copolymer is 6000；
(4) initiator is added portionwise into reactor, reacts 8h, obtains the hydrophilic color fixing agent of the environment-friendly type cotton；It is described
Initiator is 1.2 parts of benzoyl peroxides.
Embodiment 2
The environment-friendly type cotton with hydrophilic color fixing agent prepare raw material include 24 parts of quaternary ammonium salt monomers, 16 parts of amine monomers, 30 parts
Acrylic ester monomer, 3 parts of pentaerythritol triallyl ethers, 8 parts of polyquaterniums；The quaternary ammonium salt monomer is acrylyl oxy-ethyl
Alkyl quaternary ammonium salts, allyl alkyl quaternary ammonium salt, the acrylyl oxy-ethyl alkyl quaternary ammonium salts and the allyl alkyl quaternary ammonium salt
Weight ratio be 1：0.2, the acrylyl oxy-ethyl alkyl quaternary ammonium salts is acrylyl oxy-ethyl-dodecyl-dimethylammonium chloride
Ammonium, acrylyl oxy-ethyl-myristyl-alkyl dimethyl ammonium chloride, the acrylyl oxy-ethyl-dodecyl-alkyl dimethyl ammonium chloride
Weight ratio with acrylyl oxy-ethyl-myristyl-alkyl dimethyl ammonium chloride is 1：0.52, the allyl alkyl quaternary ammonium salt is two
Methyl diallyl ammonium chloride and dodecyldimethylamine base allyl ammonium chloride, the dimethyl diallyl ammonium chloride with it is described
The weight ratio of dodecyldimethylamine base allyl ammonium chloride is 1：1.1；The amine monomers are diethylenetriamine, triethylene four
The weight ratio of amine, the diethylenetriamine and the triethylene tetramine is 1：0.7；The acrylic ester monomer is acrylic acid first
Ester, pentaerythritol triacrylate, diethylene glycol double methacrylate, the methyl acrylate and three acrylic acid of the pentaerythrite
Ester, the diethylene glycol double methacrylate weight ratio are 1：3：0.6；The polyquaternium is polyquaternium -4 and polyquaternium -
46, the polyquaternium -4 is 1 with -46 weight ratio of the polyquaternium：1；
The environment-friendly type cotton preparation method of hydrophilic color fixing agent, includes the following steps：
(1) quaternary ammonium salt monomer, amine monomers, acrylic ester monomer, Ji Wusi is added into reactor according to parts by weight
Alcohol triallyl ether and water are warming up to 80 DEG C；The water is 80 parts；
(2) initiator is added portionwise into reactor by weight, reacts 7h, obtains cationic copolymer, the initiation
Agent is azodiisobutyronitrile, and the initiator is 1.6 parts；
(3) cationic copolymer, polyquaternium, catalyst and water that step (2) obtains are added into reactor, is warming up to
90℃；The catalyst is Ziegler-Natta catalyst；The dosage of the catalyst is 0.56 part；The water is 100 parts；
The weight average molecular weight of the cationic copolymer is 6000；
(4) initiator is added portionwise into reactor, reacts 8h, obtains the hydrophilic color fixing agent of the environment-friendly type cotton；It is described
Initiator is 1.2 parts of benzoyl peroxides.
Embodiment 3
The environment-friendly type cotton with hydrophilic color fixing agent prepare raw material include 24 parts of quaternary ammonium salt monomers, 16 parts of amine monomers, 30 parts
Acrylic ester monomer, 3 parts of pentaerythritol triallyl ethers, 8 parts of polyquaterniums；The quaternary ammonium salt monomer is acrylyl oxy-ethyl
Alkyl quaternary ammonium salts, the acrylyl oxy-ethyl alkyl quaternary ammonium salts are acrylyl oxy-ethyl-dodecyl-alkyl dimethyl ammonium chloride, third
Alkene acyloxyethyl-myristyl-alkyl dimethyl ammonium chloride, the acrylyl oxy-ethyl-dodecyl-alkyl dimethyl ammonium chloride and propylene
The weight ratio of acyloxyethyl-myristyl-alkyl dimethyl ammonium chloride is 1：0.52；The amine monomers are diethylenetriamine, three second
The weight ratio of alkene tetramine, the diethylenetriamine and the triethylene tetramine is 1：0.32；The acrylic ester monomer is third
E pioic acid methyl ester, pentaerythritol triacrylate, diethylene glycol double methacrylate, the methyl acrylate and the pentaerythrite three
Acrylate, the diethylene glycol double methacrylate weight ratio are 1：3：0.6；The polyquaternium is polyquaternium -4 and poly- season
Ammonium salt -46, the polyquaternium -4 are 1 with -46 weight ratio of the polyquaternium：0.72；
The environment-friendly type cotton preparation method of hydrophilic color fixing agent, includes the following steps：
(1) quaternary ammonium salt monomer, amine monomers, acrylic ester monomer, Ji Wusi is added into reactor according to parts by weight
Alcohol triallyl ether and water are warming up to 80 DEG C；The water is 80 parts of water；
(2) initiator is added portionwise into reactor by weight, reacts 7h, obtains cationic copolymer, the initiation
Agent is azodiisobutyronitrile, and the initiator is 1.6 parts；
(3) cationic copolymer, polyquaternium, catalyst and water that step (2) obtains are added into reactor, is warming up to
90℃；The catalyst is Ziegler-Natta catalyst；The dosage of the catalyst is 0.56 part；The water is 100 parts
Water；The weight average molecular weight of the cationic copolymer is 6000；
(4) initiator is added portionwise into reactor, reacts 8h, obtains the hydrophilic color fixing agent of the environment-friendly type cotton；It is described
Initiator is 1.2 parts of benzoyl peroxides.
Embodiment 4
The environment-friendly type cotton with hydrophilic color fixing agent prepare raw material include 24 parts of quaternary ammonium salt monomers, 16 parts of amine monomers, 30 parts
Acrylic ester monomer, 3 parts of pentaerythritol triallyl ethers, 8 parts of polyquaterniums；The quaternary ammonium salt monomer is acrylyl oxy-ethyl
Alkyl quaternary ammonium salts, allyl alkyl quaternary ammonium salt, the acrylyl oxy-ethyl alkyl quaternary ammonium salts and the allyl alkyl quaternary ammonium salt
Weight ratio be 1：0.63, the acrylyl oxy-ethyl alkyl quaternary ammonium salts is acrylyl oxy-ethyl-dodecyl-dimethylammonium chloride
Ammonium, acrylyl oxy-ethyl-myristyl-alkyl dimethyl ammonium chloride, the acrylyl oxy-ethyl-dodecyl-alkyl dimethyl ammonium chloride
Weight ratio with acrylyl oxy-ethyl-myristyl-alkyl dimethyl ammonium chloride is 1：0.52, the allyl alkyl quaternary ammonium salt is two
Methyl diallyl ammonium chloride and dodecyldimethylamine base allyl ammonium chloride, the dimethyl diallyl ammonium chloride with it is described
The weight ratio of dodecyldimethylamine base allyl ammonium chloride is 1：1.1；The amine monomers are diethylenetriamine；The acrylic acid
Esters monomer is methyl acrylate, pentaerythritol triacrylate, diethylene glycol double methacrylate, the methyl acrylate and institute
State pentaerythritol triacrylate, the diethylene glycol double methacrylate weight ratio is 1：3：0.6；The polyquaternium is poly- season
Ammonium salt -4 and polyquaternium -46, the polyquaternium -4 are 1 with -46 weight ratio of the polyquaternium：0.72；
The environment-friendly type cotton preparation method of hydrophilic color fixing agent, includes the following steps：
(1) quaternary ammonium salt monomer, amine monomers, acrylic ester monomer, Ji Wusi is added into reactor according to parts by weight
Alcohol triallyl ether and water are warming up to 80 DEG C；The water is 80 parts；
(2) initiator is added portionwise into reactor by weight, reacts 7h, obtains cationic copolymer, the initiation
Agent is azodiisobutyronitrile, and the initiator is 1.6 parts；
(3) cationic copolymer, polyquaternium, catalyst and water that step (2) obtains are added into reactor, is warming up to
90℃；The catalyst is Ziegler-Natta catalyst；The dosage of the catalyst is 0.56 part；The water is 100 parts
Water；The weight average molecular weight of the cationic copolymer is 6000；
(4) initiator is added portionwise into reactor, reacts 8h, obtains the hydrophilic color fixing agent of the environment-friendly type cotton；It is described
Initiator is 1.2 parts of benzoyl peroxides.
Embodiment 5
The environment-friendly type cotton with hydrophilic color fixing agent prepare raw material include 24 parts of quaternary ammonium salt monomers, 16 parts of amine monomers, 30 parts
Acrylic ester monomer, 3 parts of pentaerythritol triallyl ethers, 8 parts of polyquaterniums；The quaternary ammonium salt monomer is acrylyl oxy-ethyl
Alkyl quaternary ammonium salts, allyl alkyl quaternary ammonium salt, the acrylyl oxy-ethyl alkyl quaternary ammonium salts and the allyl alkyl quaternary ammonium salt
Weight ratio be 1：0.63, the acrylyl oxy-ethyl alkyl quaternary ammonium salts is acrylyl oxy-ethyl-dodecyl-dimethylammonium chloride
Ammonium, acrylyl oxy-ethyl-myristyl-alkyl dimethyl ammonium chloride, the acrylyl oxy-ethyl-dodecyl-alkyl dimethyl ammonium chloride
Weight ratio with acrylyl oxy-ethyl-myristyl-alkyl dimethyl ammonium chloride is 1：0.52, the allyl alkyl quaternary ammonium salt is two
Methyl diallyl ammonium chloride and dodecyldimethylamine base allyl ammonium chloride, the dimethyl diallyl ammonium chloride with it is described
The weight ratio of dodecyldimethylamine base allyl ammonium chloride is 1：1.1；The amine monomers are diethylenetriamine, triethylene four
The weight ratio of amine, the diethylenetriamine and the triethylene tetramine is 1：0.32；The acrylic ester monomer is acrylic acid
Methyl esters；The polyquaternium is polyquaternium -4 and polyquaternium -46, the polyquaternium -4 and -46 weight of the polyquaternium
Amount is than being 1：0.72；
The environment-friendly type cotton preparation method of hydrophilic color fixing agent, includes the following steps：
(1) quaternary ammonium salt monomer, amine monomers, acrylic ester monomer, Ji Wusi is added into reactor according to parts by weight
Alcohol triallyl ether and water are warming up to 80 DEG C；The water is 80 parts；
(2) initiator is added portionwise into reactor by weight, reacts 7h, obtains cationic copolymer, the initiation
Agent is azodiisobutyronitrile, and the initiator is 1.6 parts；
(3) cationic copolymer, polyquaternium, catalyst and water that step (2) obtains are added into reactor, is warming up to
90℃；The catalyst is Ziegler-Natta catalyst；The dosage of the catalyst is 0.56 part；The water is 100 parts；
The weight average molecular weight of the cationic copolymer is 6000；
(4) initiator is added portionwise into reactor, reacts 8h, obtains the hydrophilic color fixing agent of the environment-friendly type cotton；It is described
Initiator is 1.2 parts of benzoyl peroxides.
Embodiment 6
The environment-friendly type cotton with hydrophilic color fixing agent prepare raw material include 24 parts of quaternary ammonium salt monomers, 16 parts of amine monomers, 30 parts
Acrylic ester monomer, 3 parts of pentaerythritol triallyl ethers, 8 parts of polyquaterniums；The quaternary ammonium salt monomer is acrylyl oxy-ethyl
Alkyl quaternary ammonium salts, allyl alkyl quaternary ammonium salt, the acrylyl oxy-ethyl alkyl quaternary ammonium salts and the allyl alkyl quaternary ammonium salt
Weight ratio be 1：0.63, the acrylyl oxy-ethyl alkyl quaternary ammonium salts is acrylyl oxy-ethyl-dodecyl-dimethylammonium chloride
Ammonium, acrylyl oxy-ethyl-myristyl-alkyl dimethyl ammonium chloride, the acrylyl oxy-ethyl-dodecyl-alkyl dimethyl ammonium chloride
Weight ratio with acrylyl oxy-ethyl-myristyl-alkyl dimethyl ammonium chloride is 1：0.52, the allyl alkyl quaternary ammonium salt is two
Methyl diallyl ammonium chloride and dodecyldimethylamine base allyl ammonium chloride, the dimethyl diallyl ammonium chloride with it is described
The weight ratio of dodecyldimethylamine base allyl ammonium chloride is 1：1.1；The amine monomers are diethylenetriamine, triethylene four
The weight ratio of amine, the diethylenetriamine and the triethylene tetramine is 1：0.32；The acrylic ester monomer is acrylic acid
Methyl esters, pentaerythritol triacrylate, diethylene glycol double methacrylate, the methyl acrylate and three propylene of the pentaerythrite
Acid esters, the diethylene glycol double methacrylate weight ratio are 1：3：0.6；The polyquaternium is polyquaternium -4；
The environment-friendly type cotton preparation method of hydrophilic color fixing agent, includes the following steps：
(1) quaternary ammonium salt monomer, amine monomers, acrylic ester monomer, Ji Wusi is added into reactor according to parts by weight
Alcohol triallyl ether and water are warming up to 80 DEG C；The water is 80 parts；
(2) initiator is added portionwise into reactor by weight, reacts 7h, obtains cationic copolymer, the initiation
Agent is azodiisobutyronitrile, and the initiator is 1.6 parts；
(3) cationic copolymer, polyquaternium, catalyst and water that step (2) obtains are added into reactor, is warming up to
90℃；The catalyst is Ziegler-Natta catalyst；The dosage of the catalyst is 0.56 part；The water is 100 parts；
The weight average molecular weight of the cationic copolymer is 6000；
(4) initiator is added portionwise into reactor, reacts 8h, obtains the hydrophilic color fixing agent of the environment-friendly type cotton；It is described
Initiator is 1.2 parts of benzoyl peroxides.
Embodiment 7
The environment-friendly type cotton with hydrophilic color fixing agent prepare raw material include 24 parts of quaternary ammonium salt monomers, 16 parts of amine monomers, 33 parts
Acrylic ester monomer, 8 parts of polyquaterniums；The quaternary ammonium salt monomer is acrylyl oxy-ethyl alkyl quaternary ammonium salts, allyl alkyl
The weight ratio of quaternary ammonium salt, the acrylyl oxy-ethyl alkyl quaternary ammonium salts and the allyl alkyl quaternary ammonium salt is 1：0.63, it is described
Acrylyl oxy-ethyl alkyl quaternary ammonium salts is acrylyl oxy-ethyl-dodecyl-alkyl dimethyl ammonium chloride, acrylyl oxy-ethyl-ten four
Alkyl-alkyl dimethyl ammonium chloride, the acrylyl oxy-ethyl-dodecyl-alkyl dimethyl ammonium chloride and acrylyl oxy-ethyl-tetradecane
The weight ratio of base-alkyl dimethyl ammonium chloride is 1：0.52, the allyl alkyl quaternary ammonium salt be dimethyl diallyl ammonium chloride and
Dodecyldimethylamine base allyl ammonium chloride, the dimethyl diallyl ammonium chloride and the dodecyldimethylamine base allyl
The weight ratio of ammonium chloride is 1：1.1；The amine monomers are diethylenetriamine, triethylene tetramine, the diethylenetriamine and institute
The weight ratio for stating triethylene tetramine is 1：0.32；The acrylic ester monomer is methyl acrylate, three acrylic acid of pentaerythrite
Ester, diethylene glycol double methacrylate, the methyl acrylate and the pentaerythritol triacrylate, the diethylene glycol double third
Olefin(e) acid ester weight ratio is 1：3：0.6；The polyquaternium be polyquaternium -4 and polyquaternium -46, the polyquaternium -4 with
- 46 weight ratio of the polyquaternium is 1：0.72；
The environment-friendly type cotton preparation method of hydrophilic color fixing agent, includes the following steps：
(1) quaternary ammonium salt monomer, amine monomers, acrylic ester monomer and water is added into reactor according to parts by weight, rises
Temperature is to 80 DEG C；The water is 80 parts；
(2) initiator is added portionwise into reactor by weight, reacts 7h, obtains cationic copolymer, the initiation
Agent is azodiisobutyronitrile, and the initiator is 1.6 parts；
(3) cationic copolymer, polyquaternium, catalyst and water that step (2) obtains are added into reactor, is warming up to
90℃；The catalyst is Ziegler-Natta catalyst；The dosage of the catalyst is 0.56 part；The water is 100 parts；
The weight average molecular weight of the cationic copolymer is 6000；
(4) initiator is added portionwise into reactor, reacts 8h, obtains the hydrophilic color fixing agent of the environment-friendly type cotton；It is described
Initiator is 1.2 parts of benzoyl peroxides.
Embodiment 8
The environment-friendly type cotton with hydrophilic color fixing agent prepare raw material include 20 parts of quaternary ammonium salt monomers, 20 parts of amine monomers, 30 parts
Acrylic ester monomer, 3 parts of pentaerythritol triallyl ethers, 8 parts of polyquaterniums；The quaternary ammonium salt monomer is acrylyl oxy-ethyl
Alkyl quaternary ammonium salts, allyl alkyl quaternary ammonium salt, the acrylyl oxy-ethyl alkyl quaternary ammonium salts and the allyl alkyl quaternary ammonium salt
Weight ratio be 1：0.63, the acrylyl oxy-ethyl alkyl quaternary ammonium salts is acrylyl oxy-ethyl-dodecyl-dimethylammonium chloride
Ammonium, acrylyl oxy-ethyl-myristyl-alkyl dimethyl ammonium chloride, the acrylyl oxy-ethyl-dodecyl-alkyl dimethyl ammonium chloride
Weight ratio with acrylyl oxy-ethyl-myristyl-alkyl dimethyl ammonium chloride is 1：0.52, the allyl alkyl quaternary ammonium salt is two
Methyl diallyl ammonium chloride and dodecyldimethylamine base allyl ammonium chloride, the dimethyl diallyl ammonium chloride with it is described
The weight ratio of dodecyldimethylamine base allyl ammonium chloride is 1：1.1；The amine monomers are diethylenetriamine, triethylene four
The weight ratio of amine, the diethylenetriamine and the triethylene tetramine is 1：0.32；The acrylic ester monomer is acrylic acid
Methyl esters, pentaerythritol triacrylate, diethylene glycol double methacrylate, the methyl acrylate and three propylene of the pentaerythrite
Acid esters, the diethylene glycol double methacrylate weight ratio are 1：3：0.6；The polyquaternium is polyquaternium -4 and polyquaternary amine
Salt -46, the polyquaternium -4 are 1 with -46 weight ratio of the polyquaternium：0.72；
The environment-friendly type cotton preparation method of hydrophilic color fixing agent, includes the following steps：
(1) quaternary ammonium salt monomer, amine monomers, acrylic ester monomer, Ji Wusi is added into reactor according to parts by weight
Alcohol triallyl ether and water are warming up to 80 DEG C；The water is 80 parts；
(2) initiator is added portionwise into reactor by weight, reacts 7h, obtains cationic copolymer, the initiation
Agent is azodiisobutyronitrile, and the initiator is 1.6 parts；
(3) cationic copolymer, polyquaternium, catalyst and water that step (2) obtains are added into reactor, is warming up to
90℃；The catalyst is Ziegler-Natta catalyst；The dosage of the catalyst is 0.56 part；The water is 100 parts；
The weight average molecular weight of the cationic copolymer is 8000；
(4) initiator is added portionwise into reactor, reacts 8h, obtains the hydrophilic color fixing agent of the environment-friendly type cotton；It is described
Initiator is 1.2 parts of benzoyl peroxides.
Embodiment 9
The environment-friendly type cotton with hydrophilic color fixing agent prepare raw material include 40 parts of quaternary ammonium salt monomers, 10 parts of amine monomers, 20 parts
Acrylic ester monomer, 3 parts of pentaerythritol triallyl ethers, 8 parts of polyquaterniums；The quaternary ammonium salt monomer is acrylyl oxy-ethyl
Alkyl quaternary ammonium salts, allyl alkyl quaternary ammonium salt, the acrylyl oxy-ethyl alkyl quaternary ammonium salts and the allyl alkyl quaternary ammonium salt
Weight ratio be 1：0.63, the acrylyl oxy-ethyl alkyl quaternary ammonium salts is acrylyl oxy-ethyl-dodecyl-dimethylammonium chloride
Ammonium, acrylyl oxy-ethyl-myristyl-alkyl dimethyl ammonium chloride, the acrylyl oxy-ethyl-dodecyl-alkyl dimethyl ammonium chloride
Weight ratio with acrylyl oxy-ethyl-myristyl-alkyl dimethyl ammonium chloride is 1：0.52, the allyl alkyl quaternary ammonium salt is two
Methyl diallyl ammonium chloride and dodecyldimethylamine base allyl ammonium chloride, the dimethyl diallyl ammonium chloride with it is described
The weight ratio of dodecyldimethylamine base allyl ammonium chloride is 1：1.1；The amine monomers are diethylenetriamine, triethylene four
The weight ratio of amine, the diethylenetriamine and the triethylene tetramine is 1：0.32；The acrylic ester monomer is acrylic acid
Methyl esters, pentaerythritol triacrylate, diethylene glycol double methacrylate, the methyl acrylate and three propylene of the pentaerythrite
Acid esters, the diethylene glycol double methacrylate weight ratio are 1：3：0.6；The polyquaternium is polyquaternium -4 and polyquaternary amine
Salt -46, the polyquaternium -4 are 1 with -46 weight ratio of the polyquaternium：0.72；
The environment-friendly type cotton preparation method of hydrophilic color fixing agent, includes the following steps：
(1) quaternary ammonium salt monomer, amine monomers, acrylic ester monomer, Ji Wusi is added into reactor according to parts by weight
Alcohol triallyl ether and water are warming up to 80 DEG C；The water is 80 parts；
(2) initiator is added portionwise into reactor by weight, reacts 7h, obtains cationic copolymer, the initiation
Agent is azodiisobutyronitrile, and the initiator is 1.6 parts；
(3) cationic copolymer, polyquaternium, catalyst and water that step (2) obtains are added into reactor, is warming up to
90℃；The catalyst is Ziegler-Natta catalyst；The dosage of the catalyst is 0.56 part；The water is 100 parts；
The weight average molecular weight of the cationic copolymer is 6000；
(4) initiator is added portionwise into reactor, reacts 8h, obtains the hydrophilic color fixing agent of the environment-friendly type cotton；It is described
Initiator is 1.2 parts of benzoyl peroxides.
Embodiment 10
The environment-friendly type cotton with hydrophilic color fixing agent prepare raw material include 24 parts of quaternary ammonium salt monomers, 16 parts of amine monomers, 30 parts
Acrylic ester monomer, 3 parts of pentaerythritol triallyl ethers, 8 parts of polyquaterniums；The quaternary ammonium salt monomer is acrylyl oxy-ethyl
Alkyl quaternary ammonium salts, allyl alkyl quaternary ammonium salt, the acrylyl oxy-ethyl alkyl quaternary ammonium salts and the allyl alkyl quaternary ammonium salt
Weight ratio be 1：1, the acrylyl oxy-ethyl alkyl quaternary ammonium salts be acrylyl oxy-ethyl-dodecyl-alkyl dimethyl ammonium chloride,
Acrylyl oxy-ethyl-myristyl-alkyl dimethyl ammonium chloride, the acrylyl oxy-ethyl-dodecyl-alkyl dimethyl ammonium chloride and third
The weight ratio of alkene acyloxyethyl-myristyl-alkyl dimethyl ammonium chloride is 1：0.52, the allyl alkyl quaternary ammonium salt is dimethyl
Diallyl ammonium chloride and dodecyldimethylamine base allyl ammonium chloride, the dimethyl diallyl ammonium chloride and described 14
The weight ratio of alkyl dimethyl allyl ammonium chloride is 1：1.1；The amine monomers are diethylenetriamine, triethylene tetramine, institute
The weight ratio for stating diethylenetriamine and the triethylene tetramine is 1：0.7；The acrylic ester monomer is methyl acrylate, season
Penta tetrol triacrylate, diethylene glycol double methacrylate, the methyl acrylate and the pentaerythritol triacrylate, institute
It is 1 to state diethylene glycol double methacrylate weight ratio：1：1；The polyquaternium be polyquaternium -4 and polyquaternium -46, it is described
Polyquaternium -4 is 1 with -46 weight ratio of the polyquaternium：1；
The environment-friendly type cotton preparation method of hydrophilic color fixing agent, includes the following steps：
(1) quaternary ammonium salt monomer, amine monomers, acrylic ester monomer, Ji Wusi is added into reactor according to parts by weight
Alcohol triallyl ether and water are warming up to 80 DEG C；The water is 80 parts；
(2) initiator is added portionwise into reactor by weight, reacts 7h, obtains cationic copolymer, the initiation
Agent is azodiisobutyronitrile, and the initiator is 1.6 parts；
(3) cationic copolymer, polyquaternium, catalyst and water that step (2) obtains are added into reactor, is warming up to
90℃；The catalyst is Ziegler-Natta catalyst；The dosage of the catalyst is 0.56 part；The water is 100 parts；
The weight average molecular weight of the cationic copolymer is 6000；
(4) initiator is added portionwise into reactor, reacts 8h, obtains the hydrophilic color fixing agent of the environment-friendly type cotton；It is described
Initiator is 1.2 parts of benzoyl peroxides.
Comparative example 1
The environment-friendly type cotton with hydrophilic color fixing agent prepare raw material include 35 parts of quaternary ammonium salt monomers, 16 parts of amine monomers, 30 parts
Acrylic ester monomer；The quaternary ammonium salt monomer be acrylyl oxy-ethyl alkyl quaternary ammonium salts, allyl alkyl quaternary ammonium salt, described third
The weight ratio of alkene acyloxyethyl alkyl quaternary ammonium salts and the allyl alkyl quaternary ammonium salt is 1：0.63, the acrylyl oxy-ethyl alkane
Based quaternary ammonium salt is acrylyl oxy-ethyl-dodecyl-alkyl dimethyl ammonium chloride, acrylyl oxy-ethyl-myristyl-dimethylammonium chloride
Ammonium, the acrylyl oxy-ethyl-dodecyl-alkyl dimethyl ammonium chloride and acrylyl oxy-ethyl-myristyl-alkyl dimethyl ammonium chloride
Weight ratio be 1：0.52, the allyl alkyl quaternary ammonium salt is dimethyl diallyl ammonium chloride and dodecyldimethylamine base alkene
The weight ratio of propyl ammonium chloride, the dimethyl diallyl ammonium chloride and the dodecyldimethylamine base allyl ammonium chloride is
1：1.1；The amine monomers are diethylenetriamine, triethylene tetramine, the weight of the diethylenetriamine and the triethylene tetramine
Amount is than being 1：0.32；The acrylic ester monomer is methyl acrylate, pentaerythritol triacrylate, the double propylene of diethylene glycol
Acid esters, the methyl acrylate are 1 with the pentaerythritol triacrylate, the diethylene glycol double methacrylate weight ratio：
3：0.6；
The environment-friendly type cotton preparation method of hydrophilic color fixing agent, includes the following steps：
(1) quaternary ammonium salt monomer, amine monomers, acrylic ester monomer and water is added into reactor according to parts by weight, rises
Temperature is to 80 DEG C；The water is 80 parts；
(2) initiator is added portionwise into reactor by weight, reacts 7h, obtains the hydrophilic fixation of the environment-friendly type cotton
Agent, the initiator are azodiisobutyronitrile, and the initiator is 1.6 parts.
Comparative example 2
The environment-friendly type cotton with hydrophilic color fixing agent prepare raw material include 35 parts of quaternary ammonium salt monomers, 16 parts of amine monomers, 30 parts
Acrylic ester monomer；The quaternary ammonium salt monomer is allyl alkyl quaternary ammonium salt, and the allyl alkyl quaternary ammonium salt is dimethyl
Diallyl ammonium chloride and dodecyldimethylamine base allyl ammonium chloride, the dimethyl diallyl ammonium chloride and described 14
The weight ratio of alkyl dimethyl allyl ammonium chloride is 1：1.1；The amine monomers are diethylenetriamine, triethylene tetramine, institute
The weight ratio for stating diethylenetriamine and the triethylene tetramine is 1：0.32；The acrylic ester monomer be methyl acrylate,
Pentaerythritol triacrylate, diethylene glycol double methacrylate, the methyl acrylate and the pentaerythritol triacrylate,
The diethylene glycol double methacrylate weight ratio is 1：3：0.6；
The environment-friendly type cotton preparation method of hydrophilic color fixing agent, includes the following steps：
(1) quaternary ammonium salt monomer, amine monomers, acrylic ester monomer and water is added into reactor according to parts by weight, rises
Temperature is to 80 DEG C；The water is 80 parts；
(2) initiator is added portionwise into reactor by weight, reacts 7h, obtains the hydrophilic fixation of the environment-friendly type cotton
Agent, the initiator are azodiisobutyronitrile, and the initiator is 1.6 parts；
Comparative example 3
The environment-friendly type cotton with hydrophilic color fixing agent prepare raw material include 35 parts of quaternary ammonium salt monomers, 16 parts of amine monomers, 30 parts
Acrylic ester monomer；The quaternary ammonium salt monomer is allyl alkyl quaternary ammonium salt, and the allyl alkyl quaternary ammonium salt is dimethyl
Diallyl ammonium chloride and dodecyldimethylamine base allyl ammonium chloride, the dimethyl diallyl ammonium chloride and described 14
The weight ratio of alkyl dimethyl allyl ammonium chloride is 1：1.1；The amine monomers are diethylenetriamine；The esters of acrylic acid
Monomer is methyl acrylate；
The environment-friendly type cotton preparation method of hydrophilic color fixing agent, includes the following steps：
(1) quaternary ammonium salt monomer, amine monomers, acrylic ester monomer and water is added into reactor according to parts by weight, rises
Temperature is to 80 DEG C；The water is 80 parts；
(2) initiator is added portionwise into reactor by weight, reacts 7h, obtains the hydrophilic fixation of the environment-friendly type cotton
Agent, the initiator are azodiisobutyronitrile, and the initiator is 1.6 parts；
Performance test
1, soaping fastness:By GB/T3921-2008《Textile color stability is tested:Soaping fastness》Method measures；
2, crock fastness:By GB/T3920-2008《Textile color stability is tested:Crock fastness》Method measures；
3, perspiration fastness:It is tested by GB/T3922-1995；
4, feel is tested：It closes the fabric that mesh touches after arranging to grade using 10 people as a small group, according to different hands
PRINTED FABRIC is carried out hand feel evaluation by sense, and specific assessment method is：Feel grading is carried out in terms of flexibility, smooth feeling two, altogether
Divide 5 grades, 1 grade worst, and fabric feeling is harder, and sliding glutinous sense is poor.5 grades preferably, and fabrics feel soft, cunning are glutinous.
5, thermal stability：
Test method is as follows:A certain amount of hydrophilic color-fixing agent emulsion is put into the container of sealing, 5h is stored at 60 DEG C, is seen
It examines its state change and records, the unchanged hydrophilic color-fixing agent emulsion high-temperature stability of explanation is preferable；It is hydrophilic solid to vary less explanation
Toner lotion high-temperature stability is preferable；There is part precipitation to illustrate that hydrophilic color-fixing agent emulsion stability is poor.
1 the performance test results of table
The present invention is polymerize by quaternary ammonium salt monomer, amine monomers, acrylic ester monomer, pentaerythritol triallyl ether
The cationic polymer for being 5000~10000 to weight average molecular weight, introduces polar group hydroxyl and amino, and the cation
Crosslinked polymer degree is not high, and the cationic polymer further polymerize with polyquaternium -4 and polyquaternium -46, obtains high friendship
Connection degree and surface hydroxyl and hydroxyl on amine based polymer, with dyestuff and fiber or amido react crosslinking, enhancing
The binding force of polymer film and fiber and dyestuff, polymer occurs when improving the fixing property of color fixing agent while also avoiding high temperature
Cross-linking reaction and then influence hydrophily and flexibility.
Above-mentioned example is merely illustrative, some features of feature for explaining the present invention.The attached claims
It is intended to the range as wide as possible for requiring to be contemplated that, and embodiments as presented herein is only according to all possible embodiment
Combination selection embodiment explanation.Therefore, the purpose of applicant is that the attached claims are not illustrated the present invention
Feature exemplary selectional restriction, and the progress in science and technology will be formed language express inaccuracy due to and not
The possible equivalent or son being presently considered are replaced, and these variations also should in the conceived case be interpreted by appended
Claim covers.
Claims (9)
1. a kind of hydrophilic color fixing agent of environment-friendly type cotton, which is characterized in that calculate by weight, the hydrophilic fixation of the environment-friendly type cotton
Agent prepare raw material include 10~50 parts of quaternary ammonium salt monomers, 5~25 parts of amine monomers, 5~40 parts of acrylic ester monomers, 1~5 part
Pentaerythritol triallyl ether, 5~15 parts of polyquaterniums；Wherein, the quaternary ammonium salt monomer includes acrylyl oxy-ethyl alkyl quaternary
It is one or more in ammonium salt, allyl alkyl quaternary ammonium salt；The amine monomers include diethylenetriamine, triethylene tetramine, tetrem
It is one or more in five amine of alkene；
The environment-friendly type cotton preparation method of hydrophilic color fixing agent, includes the following steps：
(1) quaternary ammonium salt monomer, amine monomers, acrylic ester monomer, pentaerythrite three is added into reactor according to parts by weight
Allyl ether and water are warming up to 70~85 DEG C；
(2) initiator is added portionwise into reactor by weight, reacts 4~10h, obtains cationic copolymer, the initiation
Agent is 1~2 part；
(3) step (2) obtained cationic copolymer, polyquaternium, catalyst and water is added into reactor, it is warming up to 85~
90℃；
(4) initiator is added portionwise, reacts 6~8h, obtains the hydrophilic color fixing agent of the environment-friendly type cotton.
2. the hydrophilic color fixing agent of environment-friendly type cotton according to claim 1, which is characterized in that the acrylyl oxy-ethyl alkyl quaternary
The weight ratio of ammonium salt and the allyl alkyl quaternary ammonium salt is 1：(0.2~1).
3. the hydrophilic color fixing agent of environment-friendly type cotton according to claim 1, which is characterized in that the acrylyl oxy-ethyl alkyl quaternary
Ammonium salt includes acrylyl oxy-ethyl-trimethyl salmiac, MethacryloyloxyethylTrimethyl Trimethyl Ammonium Chloride, acrylyl oxy-ethyl three
Methyl bromide ammonium, methylacryoyloxyethyl trimethylammonium bromide, acrylyl oxy-ethyl-dodecyl-alkyl dimethyl ammonium chloride, first
Base acrylyl oxy-ethyl-dodecyl-alkyl dimethyl ammonium chloride, acrylyl oxy-ethyl-dodecyl-ditallowdimethyl ammonium bromide, methyl
Acrylyl oxy-ethyl-dodecyl-ditallowdimethyl ammonium bromide, acrylyl oxy-ethyl-myristyl-alkyl dimethyl ammonium chloride, methyl-prop
Alkene acyloxyethyl-myristyl-alkyl dimethyl ammonium chloride, acrylyl oxy-ethyl-myristyl-ditallowdimethyl ammonium bromide, metering system
Acyloxyethyl-myristyl-ditallowdimethyl ammonium bromide, acrylyl oxy-ethyl-cetyl-alkyl dimethyl ammonium chloride, methacryl
Oxygen ethyl-cetyl-alkyl dimethyl ammonium chloride, acrylyl oxy-ethyl-cetyl-ditallowdimethyl ammonium bromide, methacryloxypropyl
Ethyl-cetyl-ditallowdimethyl ammonium bromide, acrylyl oxy-ethyl-octadecyl-alkyl dimethyl ammonium chloride, methacryloxypropyl second
Base-octadecyl-alkyl dimethyl ammonium chloride, acrylyl oxy-ethyl-octadecyl-ditallowdimethyl ammonium bromide, methylacryoyloxyethyl-
It is one or more in octadecyl-ditallowdimethyl ammonium bromide；The allyl alkyl quaternary ammonium salt includes allyl trimethyl ammonia chloride
Ammonium, allyl trimethylammonium bromide, dimethyl diallyl ammonium chloride, dimethyl diallyl ammonium bromide, dimethyl
Base allyl ammonium chloride, dodecyl dimethyl allylic bromination ammonium, dodecyldimethylamine base allyl ammonium chloride, myristyl
Dimethyl-allyl ammonium bromide, hexadecyldimethyl benzyl ammonium allyl ammonium chloride, hexadecyldimethyl benzyl ammonium allylic bromination ammonium, 18
It is one or more in alkyl dimethyl allyl ammonium chloride, octadecyldimethyl allylic bromination ammonium.
4. the hydrophilic color fixing agent of environment-friendly type cotton according to claim 1, which is characterized in that the acrylic ester monomer includes
Methyl acrylate, ethyl acrylate, propyl acrylate, butyl acrylate, n-octyl, acrylic acid-2-ethyl caproite, season
It is a kind of in penta tetrol triacrylate, diethylene glycol double methacrylate, 2-hydroxyethyl methacry-late, methyl methacrylate
Or it is a variety of.
5. the hydrophilic color fixing agent of environment-friendly type cotton according to claim 4, which is characterized in that the acrylic ester monomer is third
E pioic acid methyl ester, pentaerythritol triacrylate, diethylene glycol double methacrylate.
6. the hydrophilic color fixing agent of environment-friendly type cotton according to claim 5, which is characterized in that the methyl acrylate and the season
Penta tetrol triacrylate, the diethylene glycol double methacrylate weight ratio are 1：(1~5)：(0.5~1).
7. the hydrophilic color fixing agent of environment-friendly type cotton according to claim 1, which is characterized in that the polyquaternium includes polyquaternary amine
Salt -2, polyquaternium -4, polyquaternium -5, polyquaternium -6, polyquaternium -7, Polyquaternium-10, polyquaternium -11, poly- season
Ammonium salt -16, Merquat 280, polyquaternium -24, polyquaternium -28, polyquaternium -32, polyquaternium -37, polyquaternium -
39, polyquaternium -42, polyquaternium -43, polyquaternium -44, polyquaternium -46, polyquaternium -47, polyquaternium -51, gather
Quaternary ammonium salt -53, polyquaternium -55, polyquaternium -57, polyquaternium -58, polyquaternium -59, polyquaternium -60, polyquaternary amine
Salt -63, polyquaternium -65 are one or more in polyquaternium -68.
8. the hydrophilic color fixing agent of environment-friendly type cotton according to claim 7, which is characterized in that the polyquaternium is polyquaternary amine
Salt -4 and polyquaternium -46.
9. the hydrophilic color fixing agent of environment-friendly type cotton according to claim 8, which is characterized in that the polyquaternium -4 gathers with described
- 46 weight ratio of quaternary ammonium salt is 1：(0.3~1).
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710052986.0A CN106676918B (en) | 2017-01-22 | 2017-01-22 | A kind of hydrophilic color fixing agent of environment-friendly type cotton |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710052986.0A CN106676918B (en) | 2017-01-22 | 2017-01-22 | A kind of hydrophilic color fixing agent of environment-friendly type cotton |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN106676918A CN106676918A (en) | 2017-05-17 |
| CN106676918B true CN106676918B (en) | 2018-10-23 |
Family
ID=58859693
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201710052986.0A Active CN106676918B (en) | 2017-01-22 | 2017-01-22 | A kind of hydrophilic color fixing agent of environment-friendly type cotton |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN106676918B (en) |
Families Citing this family (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107794786A (en) * | 2017-10-31 | 2018-03-13 | 杭州瑞江实业有限公司 | A kind of cotton fabric hydrophilic color fixing agent and preparation method thereof |
| CN109056383A (en) * | 2018-08-01 | 2018-12-21 | 湖南七纬科技有限公司 | A kind of printing and dyeing assistant and preparation method thereof |
| CN115748271A (en) * | 2022-10-26 | 2023-03-07 | 浙江海联新材料科技有限公司 | Ternary polymerization efficient formaldehyde-free color fixing agent for reactive dye and preparation method thereof |
Family Cites Families (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101684621B (en) * | 2009-06-09 | 2012-05-09 | 陕西科技大学 | Dendriform cationic leather fixing agent and preparation method thereof |
| JP6691908B2 (en) * | 2014-07-23 | 2020-05-13 | ザ プロクター アンド ギャンブル カンパニーＴｈｅ Ｐｒｏｃｔｅｒ ＆ Ｇａｍｂｌｅ Ｃｏｍｐａｎｙ | Fabric care and home care treatment compositions |
| CN104562803A (en) * | 2015-01-22 | 2015-04-29 | 南通优尼科化工有限公司 | Fabric fixing agent |
| CN106220785B (en) * | 2016-08-11 | 2019-03-29 | 四川省纺织科学研究院 | A kind of preparation method and application of the reactivity polyquarternium-type without aldehyde fixation crosslinking agent |
-
2017
- 2017-01-22 CN CN201710052986.0A patent/CN106676918B/en active Active
Also Published As
| Publication number | Publication date |
|---|---|
| CN106676918A (en) | 2017-05-17 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN106676918B (en) | A kind of hydrophilic color fixing agent of environment-friendly type cotton | |
| US3910862A (en) | Copolymers of vinyl pyrrolidone containing quarternary ammonium groups | |
| CA2005668C (en) | Emulsified functionalized polymers | |
| CN101283007B (en) | Polymeric extenders for surface effects | |
| CN104313926B (en) | The preparation method of the hydrophilic color-fixing agent of reactive dyeing | |
| CN101379098B (en) | High molecular weight compact structured polymers, methods of making and using | |
| AU2004291527B2 (en) | Fluorine efficient finishes for textiles | |
| WO2013033275A1 (en) | Soil adsorption polymers | |
| US8236911B2 (en) | Water-soluble resin, hair cosmetic material containing the same, and silicone oil adsorption assistant | |
| CN104074053A (en) | Efficient deep dyeing promoter, and preparation and after treatment application methods thereof | |
| CN102108638A (en) | Durable, waterproof, oil-proof, antistatic and antibacterial functional coating adhesive and preparation method | |
| CN105482032A (en) | Cationic color fixing agent and preparation method and application thereof | |
| FI76815B (en) | KATJONISKA LATEXER AV KOPOLYMERER BASERADE PAO KONJUGERADE DIENER. | |
| Cakal et al. | Novel poly (N-vinylcaprolactam-co-2-(diethylamino) ethyl methacrylate) gels: Characterization and detailed investigation on their stimuli-sensitive behaviors and network structure | |
| JP2018104850A (en) | Dye fixing agent for cellulose fiber | |
| CN106893042B (en) | A kind of environment-friendly type polyether silicones modified polyurethane and preparation method thereof | |
| CN103936941A (en) | Amphiphilic core-shell emulsion adhesive for pigment printing of textile and preparation method thereof | |
| JP7146164B2 (en) | Wet rubbing fastness improver for cellulosic fiber, method for producing dyed cellulose fiber using the same, and use thereof | |
| KR20210084436A (en) | Water and oil repellent composition, water and oil repellent treatment method, and water and oil repellent fiber | |
| CN109232794B (en) | Anti-pinhole-down acrylic ester coating emulsion, coating adhesive and preparation method thereof | |
| JP7051202B2 (en) | Finishing agent composition for clothing | |
| JPS62257481A (en) | Dye fixing agent | |
| JP2896015B2 (en) | Dye fixative for direct dye | |
| CN103694429B (en) | fluorine-containing block copolymer and preparation method and application thereof | |
| CN106750013A (en) | The preparation method of organic amphiprotic copolymerized macromolecule interpenetrating networks gel |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PB01 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| GR01 | Patent grant | ||
| GR01 | Patent grant |