CN106676918A - Environment-friendly hydrophilic color fixing agent applied to cotton - Google Patents

Environment-friendly hydrophilic color fixing agent applied to cotton Download PDF

Info

Publication number
CN106676918A
CN106676918A CN201710052986.0A CN201710052986A CN106676918A CN 106676918 A CN106676918 A CN 106676918A CN 201710052986 A CN201710052986 A CN 201710052986A CN 106676918 A CN106676918 A CN 106676918A
Authority
CN
China
Prior art keywords
ammonium salt
polyquaternary
ethyl
parts
acrylyl oxy
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
CN201710052986.0A
Other languages
Chinese (zh)
Other versions
CN106676918B (en
Inventor
刘锦凡
方伟洪
戴红梅
陈群喜
程文静
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Qingyuan Hongtu Assistant Co Ltd
Original Assignee
Qingyuan Hongtu Assistant Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Qingyuan Hongtu Assistant Co Ltd filed Critical Qingyuan Hongtu Assistant Co Ltd
Priority to CN201710052986.0A priority Critical patent/CN106676918B/en
Publication of CN106676918A publication Critical patent/CN106676918A/en
Application granted granted Critical
Publication of CN106676918B publication Critical patent/CN106676918B/en
Active legal-status Critical Current
Anticipated expiration legal-status Critical

Links

Classifications

    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
    • D06P5/00—Other features in dyeing or printing textiles, or dyeing leather, furs, or solid macromolecular substances in any form
    • D06P5/02—After-treatment
    • D06P5/04—After-treatment with organic compounds
    • D06P5/08—After-treatment with organic compounds macromolecular
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F220/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
    • C08F220/02—Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
    • C08F220/10—Esters
    • C08F220/34—Esters containing nitrogen, e.g. N,N-dimethylaminoethyl (meth)acrylate
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F222/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a carboxyl radical and containing at least one other carboxyl radical in the molecule; Salts, anhydrides, esters, amides, imides, or nitriles thereof
    • C08F222/10—Esters
    • C08F222/1006—Esters of polyhydric alcohols or polyhydric phenols
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F222/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a carboxyl radical and containing at least one other carboxyl radical in the molecule; Salts, anhydrides, esters, amides, imides, or nitriles thereof
    • C08F222/10—Esters
    • C08F222/1006—Esters of polyhydric alcohols or polyhydric phenols
    • C08F222/104—Esters of polyhydric alcohols or polyhydric phenols of tetraalcohols, e.g. pentaerythritol tetra(meth)acrylate

Landscapes

  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Textile Engineering (AREA)
  • Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)

Abstract

The invention provides an environment-friendly hydrophilic color fixing agent applied to cotton. The environment-friendly hydrophilic color fixing agent applied to the cotton is prepared from the following raw materials in parts by weight: 10-50 parts of quaternary ammonium salt monomers, 5-25 parts of amine monomers, 5-40 parts of acrylate monomers, 1-5 parts of pentaerythritol triallyl ethers and 5-15 parts of polyquaternary ammonium salts, wherein the quaternary ammonium salt monomers comprise one or more of propylene acyloxyethyl alkyl quaternary ammonium salts and allyl alkyl quaternary ammonium salts; the amine monomers comprise one or more of diethylenetriamine, triethylene tetramine and tetraethylenepentamine.

Description

A kind of hydrophilic color fixing agent of environment-friendly type cotton
Technical field
The present invention relates to color fixing agent technical field, more particularly it relates to a kind of hydrophilic color fixing agent of environment-friendly type cotton And preparation method thereof.
Background technology
In today's society, people pay attention to all the more health dress, increasingly like the natural fiber of Eco-friendly.Cotton is fine Dimension is a kind of natural fiber, and it has the series of advantages such as good warmth retention property, hygroscopicity in wearability, thus natural There is consequence in fiber.
The reactive dye series of advantages such as have cheap, chromatograph complete, bright in colour, has been widely used for the dye of cotton Color.Although it can be combined into covalent bond with cotton fiber, because reactive dye are present in hydrolysis and color dyeing kind fiber The group for being available for reactive dye to react is limited, therefore its covalent bonding between cotton fiber is still not enough fully, upper on fiber Dye rate is not high, and still needing to color fixing agent carries out fixation.
Color fixing agent is exactly in order that dyed fabric reaches satisfied color fastness, holding outward appearance as the use of dyeing and finishing auxiliaries. Fabric using color fixing agent process after, then can by make dyestuff formed insoluble color lake, on fabric generate reticulated film, make dyestuff Chemical bonds are produced between fiber and increases dyestuff and improve the washing of dyed fabric with the mode of the intermolecular attraction of fiber Fastness.
Polyquaternium cationic type color fixing agent, can well be used for the fixation of Fabrics Dyed with Reactive Dyes, its can and dyestuff Insoluble color lake is generated on dyed fabric, while it also can reduce coming off for dyestuff in fiber surface film forming, it is good so as to reach Good colour fixation.But due to the crosslinking feature of its high temperature film forming, the hydrophilic that bafta is made after fixation is deteriorated, or makes to knit Thing is hardened, and feel is bad.
Therefore, the present invention provides a kind of hydrophilic color fixing agent of environment-friendly type cotton, and it does not only affect the hydrophilic and handss of fabric Sense, and reticulated film can be generated on fabric, with good film property, improve washing fastness and the wet friction jail of dyed fabric Degree, colour fixation is good, does not also reduce the sunlight fastness of fabric, fastness to perspiration.
The content of the invention
The present invention provides a kind of hydrophilic color fixing agent of environment-friendly type cotton, calculates by weight, and the environment-friendly type cotton is with hydrophilic solid Toner preparing raw material include 10~50 parts of quaternary ammonium salt monomers, 5~25 parts of amine monomers, 5~40 parts of acrylic ester monomers, 1~5 Part pentaerythritol triallyl ether, 5~15 parts of polyquaternary ammonium salt；Wherein, the quaternary ammonium salt monomer includes acrylyl oxy-ethyl alkyl One or more in quaternary ammonium salt, allyl alkyl quaternary ammonium salt；The amine monomers include diethylenetriamine, triethylene tetramine, four One or more in the amine of ethylene five.
In one embodiment, the weight of the acrylyl oxy-ethyl alkyl quaternary ammonium saltss and the allyl alkyl quaternary ammonium salt Amount is than being 1：(0.2~1).
In one embodiment, the acrylyl oxy-ethyl alkyl quaternary ammonium saltss include acrylyl oxy-ethyl-trimethyl chlorination Ammonium, MethacryloyloxyethylTrimethyl Trimethyl Ammonium Chloride, acrylyl oxy-ethyl-trimethyl ammonium bromide, methylacryoyloxyethyl front three Base ammonium bromide, acrylyl oxy-ethyl-dodecyl-alkyl dimethyl ammonium chloride, methylacryoyloxyethyl-dodecyl-dimethyl Ammonium chloride, acrylyl oxy-ethyl-dodecyl-ditallowdimethyl ammonium bromide, methylacryoyloxyethyl-dodecyl-diformazan bromide Change ammonium, acrylyl oxy-ethyl-myristyl-alkyl dimethyl ammonium chloride, methylacryoyloxyethyl-myristyl-dimethylammonium chloride Ammonium, acrylyl oxy-ethyl-myristyl-ditallowdimethyl ammonium bromide, methylacryoyloxyethyl-myristyl-ditallowdimethyl ammonium bromide, Acrylyl oxy-ethyl-cetyl-alkyl dimethyl ammonium chloride, methylacryoyloxyethyl-cetyl-alkyl dimethyl ammonium chloride, third Alkene acyloxyethyl-cetyl-ditallowdimethyl ammonium bromide, methylacryoyloxyethyl-cetyl-ditallowdimethyl ammonium bromide, propylene Acyloxyethyl-octadecyl-alkyl dimethyl ammonium chloride, methylacryoyloxyethyl-octadecyl-alkyl dimethyl ammonium chloride, acryloyl One kind in oxygen ethyl-octadecyl-ditallowdimethyl ammonium bromide, methylacryoyloxyethyl-octadecyl-ditallowdimethyl ammonium bromide or It is various；The allyl alkyl quaternary ammonium salt includes pi-allyl trimethyl ammonium chloride, pi-allyl trimethylammonium bromide, dimethyl diene Propyl ammonium chloride, dimethyl diallyl ammonium bromide, dodecylallyldimethylammonium chloride, dodecyl dimethyl allyl Base ammonium bromide, dodecyldimethylamine base allyl ammonium chloride, dodecyldimethylamine base allylic bromination ammonium, hexadecyldimethyl benzyl ammonium Allyl ammonium chloride, hexadecyldimethyl benzyl ammonium allylic bromination ammonium, solution property, octadecyl two One or more in methacrylic ammonium bromide.
In one embodiment, the acrylic ester monomer includes acrylic acid methyl ester., ethyl acrylate, acrylic acid third Ester, butyl acrylate, n-octyl, acrylic acid-2-ethyl caproite, pentaerythritol triacrylate, diethylene glycol double third One or more in olefin(e) acid ester, 2-hydroxyethyl methacry-late, methyl methacrylate.
In one embodiment, the acrylic ester monomer be acrylic acid methyl ester., pentaerythritol triacrylate, two Ethylene glycol diacrylate.
In one embodiment, the acrylic acid methyl ester. and the pentaerythritol triacrylate, the diethylene glycol Double methacrylate weight ratio is 1：(1~5)：(0.5~1).
In one embodiment, the polyquaternary ammonium salt includes polyquaternary ammonium salt -2, and polyquaternary ammonium salt -4, polyquaternary ammonium salt -5 are poly- Quaternary ammonium salt -6, polyquaternary ammonium salt -7, Polyquaternium-10, polyquaternary ammonium salt -11, polyquaternary ammonium salt -16, Merquat 280, polyquaternary ammonium salt - 24, polyquaternary ammonium salt -28, polyquaternium -32, polyquaternary ammonium salt -37, polyquaternary ammonium salt -39, polyquaternary ammonium salt -42, polyquaternary ammonium salt -43 are gathered Quaternary ammonium salt -44, polyquaternary ammonium salt -46, polyquaternary ammonium salt -47, polyquaternary ammonium salt -51, polyquaternary ammonium salt -53, polyquaternary ammonium salt -55, polyquaternary amine Salt -57, polyquaternary ammonium salt -58, polyquaternary ammonium salt -59, polyquaternary ammonium salt -60, polyquaternary ammonium salt -63, polyquaternary ammonium salt -65, polyquaternary ammonium salt -68 In one or more.
In one embodiment, the polyquaternary ammonium salt is polyquaternary ammonium salt -4 and polyquaternary ammonium salt -46.
In one embodiment, the polyquaternary ammonium salt -4 and the weight of polyquaternary ammonium salt -46 ratio are 1：(0.3~1).
Another aspect of the present invention provides a kind of environment-friendly type cotton preparation method of hydrophilic color fixing agent, comprises the following steps：
(1) quaternary ammonium salt monomer, amine monomers, acrylic ester monomer, Ji Wusi are added in reactor according to weight portion Alcohol triallyl ether and water, are warming up to 70~85 DEG C；
(2) it is dividedly in some parts initiator in reactor by weight, reacts 4~10h, obtains cation copolymer, it is described Initiator is 1~2 part；
(3) cation copolymer, polyquaternary ammonium salt, catalyst and the water for adding step (2) to obtain in reactor, is warming up to 85~90 DEG C；
(4) initiator is dividedly in some parts, 6~8h is reacted, the hydrophilic color fixing agent of environment-friendly type cotton is obtained.
The above-mentioned of the application and other features, aspect and advantage is more readily understood with reference to described further below.
Specific embodiment
The participation in the election detailed description for being preferable to carry out method of the invention below and including embodiment this can be more easily understood Bright content.Unless otherwise defined, all technologies used herein and scientific terminology have common with art of the present invention The identical implication that technical staff is generally understood that.When there is contradiction, the definition in this specification is defined.
As used herein term " by ... prepare " it is synonymous with "comprising".Term "comprising" used herein, " including ", " having ", " containing " or its any other deformation, it is intended that cover including for non-exclusionism.For example, the combination comprising listed elements Thing, step, method, product or device are not necessarily solely those key elements, and can be including not expressly listed other key elements or The intrinsic key element of this kind of compositionss, step, method, product or device.
Conjunction " Consists of " excludes any key element do not pointed out, step or component.If in being used for claim, this Phrase will make claim for closed so as to not comprising the material in addition to the material that those are described, but it is relative often Except rule impurity.When phrase " Consists of " is occurred in be rather than immediately following after theme in the clause of claim main body, It is only limited to the key element described in the clause；Other key elements are not excluded outside as the overall claim.
Equivalent, concentration or other values or parameter are excellent with scope, preferred scope or a series of upper limit preferred values and lower limit During the Range Representation that choosing value is limited, this is appreciated that and specifically discloses by any range limit or preferred value and any scope All scopes that arbitrary pairing of lower limit or preferred value is formed, regardless of whether whether the scope separately discloses.For example, when open During scope " 1 to 5 ", described scope should be interpreted as including scope " 1 to 4 ", " 1 to 3 ", " 1 to 2 ", " 1 to 2 and 4 to 5 ", " 1 to 3 and 5 " etc..When numerical range is described herein, unless otherwise indicated, otherwise the scope is intended to include its end Value and all integers within the range and fraction.
Singulative includes that plural number discusses object, unless the context clearly dictates otherwise." optional " or " arbitrarily It is a kind of " refer to that the item for describing thereafter or event may or may not occur, and the description include situation that event occurs and The situation that event does not occur.
Approximate term in specification and claims is used for modifying quantity, represents that the present invention is not limited to this concrete Quantity, also includes the acceptable part without causing the amendment of the change of related basic function being close to the quantity.Phase Answer, with " about ", a numerical value of the modification such as " about ", mean and the invention is not restricted to the exact numerical.In some examples, approximately Term likely corresponds to the precision of the instrument of measured value.In present specification and claims, scope is limited can be with Combine and/or exchange, if not stated otherwise these scopes include all subranges contained therebetween.
Additionally, key element of the present invention or indefinite article " one kind " and " one " before component are to key element or the quantitative requirement of component (i.e. occurrence number) unrestriction.Therefore " one " or " one kind " should be read as including one or at least one, and odd number The key element or component of form also includes plural form, unless the obvious purport of the quantity refers to singulative.
" polymer " means the polymerizable compound prepared by the monomer by the identical or different type that is polymerized.Generic term " polymer " includes term " homopolymer ", " copolymer ", " terpolymer " and " copolymer ".
" copolymer " means the polymer prepared by least two different monomers that are polymerized.Generic term " copolymer " includes (its is general with term " terpolymer " for term " copolymer " (it is typically to refer to the polymer prepared by two kinds of different monomers) To refer to the polymer prepared by three kinds of different monomers).It is also comprising the polymer manufactured by the more kinds of monomers of polymerization. " blend " means the polymer that two or more polymer is mixed and formed jointly by physics or chemistry method.
The present invention provides a kind of hydrophilic color fixing agent of environment-friendly type cotton, calculates by weight, and the environment-friendly type cotton is with hydrophilic solid Toner preparing raw material include 10~50 parts of quaternary ammonium salt monomers, 5~25 parts of amine monomers, 5~40 parts of acrylic ester monomers, 1~5 Part pentaerythritol triallyl ether, 5~15 parts of polyquaternary ammonium salt；Wherein, the quaternary ammonium salt monomer includes acrylyl oxy-ethyl alkyl One or more in quaternary ammonium salt, allyl alkyl quaternary ammonium salt；The amine monomers include diethylenetriamine, triethylene tetramine, four One or more in the amine of ethylene five.
In one embodiment, the amine monomers are diethylenetriamine, triethylene tetramine.
In one embodiment, the diethylenetriamine and the weight ratio of the triethylene tetramine are 1：(0.2~ 1.1)；Preferably, the diethylenetriamine and the weight ratio of the triethylene tetramine are 1：(0.3~0.7)；It is highly preferred that institute It is 1 that diethylenetriamine is stated with the weight ratio of the triethylene tetramine：0.32.
There is quaternary ammonium salt bactericidal active quaternary ammonium salt compound to have a cation group, it is easy to which absorption is in band negative electricity The bacterium surface of lotus, in cell surface the ionic group of high concentration is formed, and so as to change the property of cell membrane, directly affects antibacterial Metabolism.
In one embodiment, the weight of the acrylyl oxy-ethyl alkyl quaternary ammonium saltss and the allyl alkyl quaternary ammonium salt Amount is than being 1：(0.2~1)；Preferably, the weight of the acrylyl oxy-ethyl alkyl quaternary ammonium saltss and the allyl alkyl quaternary ammonium salt Amount is than being 1：(0.5~1)；It is highly preferred that the acrylyl oxy-ethyl alkyl quaternary ammonium saltss and the allyl alkyl quaternary ammonium salt Weight ratio is 1：0.63.
In one embodiment, the acrylyl oxy-ethyl alkyl quaternary ammonium saltss include acrylyl oxy-ethyl-trimethyl chlorination Ammonium, MethacryloyloxyethylTrimethyl Trimethyl Ammonium Chloride, acrylyl oxy-ethyl-trimethyl ammonium bromide, methylacryoyloxyethyl front three Base ammonium bromide, acrylyl oxy-ethyl-dodecyl-alkyl dimethyl ammonium chloride, methylacryoyloxyethyl-dodecyl-dimethyl Ammonium chloride, acrylyl oxy-ethyl-dodecyl-ditallowdimethyl ammonium bromide, methylacryoyloxyethyl-dodecyl-diformazan bromide Change ammonium, acrylyl oxy-ethyl-myristyl-alkyl dimethyl ammonium chloride, methylacryoyloxyethyl-myristyl-dimethylammonium chloride Ammonium, acrylyl oxy-ethyl-myristyl-ditallowdimethyl ammonium bromide, methylacryoyloxyethyl-myristyl-ditallowdimethyl ammonium bromide, Acrylyl oxy-ethyl-cetyl-alkyl dimethyl ammonium chloride, methylacryoyloxyethyl-cetyl-alkyl dimethyl ammonium chloride, third Alkene acyloxyethyl-cetyl-ditallowdimethyl ammonium bromide, methylacryoyloxyethyl-cetyl-ditallowdimethyl ammonium bromide, propylene Acyloxyethyl-octadecyl-alkyl dimethyl ammonium chloride, methylacryoyloxyethyl-octadecyl-alkyl dimethyl ammonium chloride, acryloyl One kind in oxygen ethyl-octadecyl-ditallowdimethyl ammonium bromide, methylacryoyloxyethyl-octadecyl-ditallowdimethyl ammonium bromide or It is various；The allyl alkyl quaternary ammonium salt includes pi-allyl trimethyl ammonium chloride, pi-allyl trimethylammonium bromide, dimethyl diene Propyl ammonium chloride, dimethyl diallyl ammonium bromide, dodecylallyldimethylammonium chloride, dodecyl dimethyl allyl Base ammonium bromide, dodecyldimethylamine base allyl ammonium chloride, dodecyldimethylamine base allylic bromination ammonium, hexadecyldimethyl benzyl ammonium Allyl ammonium chloride, hexadecyldimethyl benzyl ammonium allylic bromination ammonium, solution property, octadecyl two One or more in methacrylic ammonium bromide；
Preferably, the acrylyl oxy-ethyl alkyl quaternary ammonium saltss include acrylyl oxy-ethyl-dodecyl-dimethylammonium chloride Ammonium, methylacryoyloxyethyl-dodecyl-alkyl dimethyl ammonium chloride, acrylyl oxy-ethyl-myristyl-alkyl dimethyl ammonium chloride, Methylacryoyloxyethyl-myristyl-alkyl dimethyl ammonium chloride, acrylyl oxy-ethyl-cetyl-alkyl dimethyl ammonium chloride, first Base acrylyl oxy-ethyl-cetyl-alkyl dimethyl ammonium chloride, acrylyl oxy-ethyl-octadecyl-alkyl dimethyl ammonium chloride, methyl One or more in acrylyl oxy-ethyl-octadecyl-alkyl dimethyl ammonium chloride；It is highly preferred that the acrylyl oxy-ethyl alkane Based quaternary ammonium salt is acrylyl oxy-ethyl-dodecyl-alkyl dimethyl ammonium chloride, acrylyl oxy-ethyl-myristyl-dimethylammonium chloride Ammonium；Acrylyl oxy-ethyl-dodecyl-the alkyl dimethyl ammonium chloride and acrylyl oxy-ethyl-myristyl-alkyl dimethyl ammonium chloride Weight ratio be 1：0.52.
Preferably, the allyl alkyl quaternary ammonium salt include pi-allyl trimethyl ammonium chloride, pi-allyl trimethylammonium bromide, Dimethyl diallyl ammonium chloride, dimethyl diallyl ammonium bromide, dodecylallyldimethylammonium chloride, dodecyl Dimethyl-allyl ammonium bromide, dodecyldimethylamine base allyl ammonium chloride, dodecyldimethylamine base allylic bromination ammonium, 16 Alkyl dimethyl allyl ammonium chloride, hexadecyldimethyl benzyl ammonium allylic bromination ammonium, solution property, One or more in octadecyldimethyl allylic bromination ammonium；Preferably, the allyl alkyl quaternary ammonium salt is dimethyl Diallyl ammonium chloride and dodecyldimethylamine base allyl ammonium chloride；The dimethyl diallyl ammonium chloride and described 14 The weight ratio of alkyl dimethyl allyl ammonium chloride is 1：1.1.
Alkyl carbon number is C in the present invention12-C18Cationic monomer, in addition to excellent fixing property, also have Excellent bactericidal performance, and it is C that fabric can be made to obtain more preferable flexibility and feel, particularly alkyl carbon number12-C14 Quaternary ammonium salt bactericide bacteriostasis property it is best；Additionally, compared with single quaternary ammonium salt small molecule and hydrophilic quaternary ammonium salt, the present invention is provided Cationic monomer copolymerization polymeric quaternary ammonium salt compound, will not be less by bio-absorbable, toxicity.
In one embodiment, the acrylic ester monomer includes acrylic acid methyl ester., ethyl acrylate, acrylic acid third Ester, butyl acrylate, n-octyl, acrylic acid-2-ethyl caproite, pentaerythritol triacrylate, diethylene glycol double third One or more in olefin(e) acid ester, 2-hydroxyethyl methacry-late, methyl methacrylate.
In one embodiment, the acrylic ester monomer be acrylic acid methyl ester., pentaerythritol triacrylate, two Ethylene glycol diacrylate.
In one embodiment, the acrylic acid methyl ester. and the pentaerythritol triacrylate, the diethylene glycol Double methacrylate weight ratio is 1：(1~5)：(0.5~1)；Preferably, the acrylic acid methyl ester. and the propylene of the tetramethylolmethane three Acid esters, the diethylene glycol double methacrylate weight ratio are 1：3：0.6.
In one embodiment, the polyquaternary ammonium salt includes polyquaternary ammonium salt -2, and polyquaternary ammonium salt -4, polyquaternary ammonium salt -5 are poly- Quaternary ammonium salt -6, polyquaternary ammonium salt -7, Polyquaternium-10, polyquaternary ammonium salt -11, polyquaternary ammonium salt -16, Merquat 280, polyquaternary ammonium salt - 24, polyquaternary ammonium salt -28, polyquaternium -32, polyquaternary ammonium salt -37, polyquaternary ammonium salt -39, polyquaternary ammonium salt -42, polyquaternary ammonium salt -43 are gathered Quaternary ammonium salt -44, polyquaternary ammonium salt -46, polyquaternary ammonium salt -47, polyquaternary ammonium salt -51, polyquaternary ammonium salt -53, polyquaternary ammonium salt -55, polyquaternary amine Salt -57, polyquaternary ammonium salt -58, polyquaternary ammonium salt -59, polyquaternary ammonium salt -60, polyquaternary ammonium salt -63, polyquaternary ammonium salt -65, polyquaternary ammonium salt -68 In one or more.
Polyquaternary ammonium salt-X
Polyquaternary ammonium salt -2 is the polymer of two (2- chloroethyls) ethers and N, N '-two [3- (dimethylamino) propyl group] urea；
Polyquaternary ammonium salt -4 is the copolymer of hydroxy ethyl cellulose and dimethyl diallyl ammonium chloride；
Polyquaternary ammonium salt -5 is the copolymer of acrylamide and Beta-methyl acryloyl group epoxide ethyl-trimethyl ammonium methyl sulfate；
Polyquaternary ammonium salt -6 is PDDA；
Polyquaternary ammonium salt -7 is the copolymer of dimethyl diallyl ammonium chloride and acrylamide；
Polyquaternium-10 is the epoxide reactive hydroxyethyl cellulose replaced with trimethyl ammonium；
Polyquaternary ammonium salt -11 is the copolymer dithyl sulfate solution of PVP and N, N- dimethyl aminoethyl methacrylic acid；
Polyquaternary ammonium salt -16 is 3- methyl isophthalic acids-vinylimidazolium chloride imidazoles-l-vinyl-2-pyrrolidone chloride；
Merquat 280 is acrylic acid-diallyldimethylammonium chloride (DADMAC) polymer；
Polyquaternary ammonium salt -24 is the polyquaternary amine of the epoxide reactive hydroxyethyl cellulose replaced with lauryl dimethyl ammonium Salt；
Polyquaternary ammonium salt -28 is vinyl pyrrolidone/methacryiamidopropyl trimethyl ammonium chloride copolymer；
Polyquaternium -32 is common for acrylamide-dimethylamine ethylacrylate methyl chloride (DMAEMA) Polymers；
Polyquaternary ammonium salt -37 is base acrylic acid trimethylaminoethyl group ester chloride polymer；
Polyquaternary ammonium salt -39 is the polymerization of acrylic acid (AA)/acrylamide and diallyldimethylammonium chloride (DADMAC) Thing；
Polyquaternary ammonium salt -42 is Polyethylene oxide (dimethyl) ethylidene-(dimethyl) ethylene dichloride；
Polyquaternary ammonium salt -43 be acrylamide, acrylamidopropyl trimethyl ammonium chloride, amidopropyl acrylamide and The copolymer of DMAPA monomers；
Polyquaternary ammonium salt -44 is the polyquaternary ammonium salt of vinyl pyrrolidone and quaternized imidazoline monomer；
Polyquaternary ammonium salt -46 is the quaternary ammonium salt of thiazolinyl caprolactam, vinyl pyrrolidone and methylvinyl imidazolium；
Polyquaternary ammonium salt -47 is aliquat-acrylic acid, acrylic acid methyl ester. and methacryiamidopropyl trimethyl chlorine Change ammonium；
Polyquaternary ammonium salt -51 be the carbon -10- alkene -1- ammoniums of 3,5,8- tri- oxygen -4- phosphorus 11,4- hydroxy-ns, N, N, 10- tetramethyl - 9- oxos, inner salt, 4- oxides, the polymer with 2- methyl -2- butyl acrylate；
Polyquaternary ammonium salt -53 is acrylic acid (AA)/acrylamide/methacryiamidopropyl trimethyl ammonium chloride (MAPTAC) copolymer；
Polyquaternary ammonium salt -55 is N, N- dimethyl-N -s [3- [(2- methyl isophthalic acids-oxo -2- acrylic) aminopropyl] -1- ten Dialkylammonium chloride and N- [3- (dimethylamino) propyl group] -2- methyl -2- acrylamides and l-vinyl-2-pyrrolidone Polymer；
Polyquaternary ammonium salt -57 is by Semen Ricini isostearate succinate and castor oil amidopropyl trimethyl ammonium chloride The polymeric quaternary ammonium salt of (appropriate) monomer composition；
Polyquaternary ammonium salt -58 is 2- acrylic acid methyl ester .s and [(2- acrylic epoxides) the methyl]-n-butyl alcohol of 2,2- bis- and divinyl The polymer of base benzene, with N, N- dimethyl -1, the product of 3- propanediamines (chloromethanes-quaternized)；
The polyquaternary ammonium salt polyester of polyquaternary ammonium salt -59；
Polyquaternary ammonium salt -60 be 9- octadecenoic acids, 12- hydroxyls -, [(2- hydroxyethyls) imido grpup] two -2,1- ethane two Base ester, with 5- isocyanate group -1- (isocyanatomethyl) -1, the polymer of 3,3- trimethyl-cyclohexanes is mixed with dimethyl sulfate Close；
Polyquaternary ammonium salt -63 is the copolymer of acrylamide, acrylic acid and ethyl-trimethyl salmiac acrylate；
Polyquaternary ammonium salt -65 is by 2- methylacryloyl epoxide ethylphosphocholines, butyl methacrylate and methyl-prop The polymeric quaternary ammonium salt of olefin(e) acid sodium monomer composition；
Polyquaternary ammonium salt -68 is vinyl pyrrolidone (VP), Methacrylamide (MAM) vinyl imidazole and quaternized The quatemized copolymer of vinyl imidazole.
In one embodiment, the polyquaternary ammonium salt is polyquaternary ammonium salt -4 and polyquaternary ammonium salt -46.
In one embodiment, the polyquaternary ammonium salt -4 and the weight of polyquaternary ammonium salt -46 ratio are 1：(0.3~1).
Another aspect of the present invention provides a kind of environment-friendly type cotton preparation method of hydrophilic color fixing agent, comprises the following steps：
(1) quaternary ammonium salt monomer, amine monomers, acrylic ester monomer, Ji Wusi are added in reactor according to weight portion Alcohol triallyl ether and water, are warming up to 70~85 DEG C；
(2) it is dividedly in some parts initiator in reactor by weight, reacts 4~10h, obtains cation copolymer, it is described Initiator is 1~2 part；
(3) cation copolymer, polyquaternary ammonium salt, catalyst and the water for adding step (2) to obtain in reactor, is warming up to 85~90 DEG C；
(4) initiator is dividedly in some parts, 6~8h is reacted, the hydrophilic color fixing agent of environment-friendly type cotton is obtained.
In one embodiment, calculate by weight, the consumption of the water is 20~100 parts.
In one embodiment, the initiator includes azodiisobutyronitrile, 2,2'-Azobis(2,4-dimethylvaleronitrile), azo diisobutyl One or more in amidine hydrochlorate, cyclohexanone peroxide, benzoyl peroxide, persulfate；Preferably, the initiator is Azodiisobutyronitrile.
In one embodiment, calculate by weight, the consumption of the initiator is 0.1~0.3 part；Preferably, institute The consumption for stating initiator is 0.25 part.
In one embodiment, the weight average molecular weight of the cation copolymer is 3000~20000；Preferably, institute The weight average molecular weight for stating cation copolymer is 5000~10000.
Weight average molecular weight is to be based on gel permeation chromatography (hreinafter referred to as " GPC ".) determine and carry out polystyrene and change Value after calculation.The condition determination of GPC for example, can be tested by the way of following and obtained using the conventional condition test in this area.
Post：Following posts are connected in series and are used.
" TSKgelG5000 " (7.8mmI.D. × 30cm) × 1 piece
" TSKgelG4000 " (7.8mmI.D. × 30cm) × 1 piece
" TSKgelG3000 " (7.8mmI.D. × 30cm) × 1 piece
" TSKgelG2000 " (7.8mmI.D. × 30cm) × 1 piece
Detector：RI (differential refractometer)；Column temperature：40℃；Eluent：Tetrahydrofuran；Flow velocity：1.0mL/ minute；Note Enter amount：100 μ L (tetrahydrofuran solution of sample solution concentration 4mg/mL)；Standard specimen：Using following monodisperse polystyrenes, make Standard curve.
In one embodiment, the catalyst is Ziegler-Natta catalyst.
In one embodiment, calculate by weight, the consumption of the catalyst is 0.5~1 part；Preferably, it is described The consumption of catalyst is 0.56 part.
In the present invention by making color fixing agent structure in obtain reactive group, the reactive group can make color fixing agent itself Reaction is crosslinked, and covalent bond can be formed with the hydroxyl reaction on fiber, make color fixing agent that there is good filming performance With cross-linking reaction performance.
The cationic monomer that the present invention is provided can be combined with reactive dye, form color lake；Wherein, alkyl carbon number is C12- C18Cationic monomer, in addition to excellent fixing property, also with excellent bactericidal performance, and fabric can be made More preferable flexibility and feel are obtained, in addition, compared with single quaternary ammonium salt small molecule and hydrophilic quaternary ammonium salt, what the present invention was provided Cationic monomer is hydrophobicity and hydrophilic polymerized polymeric quaternary ammonium salt compound, will not be less by bio-absorbable, toxicity.
Traditional color fixing agent easily affects the feel of fabric, especially in high consumption after fixation treatment is carried out to fabric When, the feel and flexibility of fabric can substantially be deteriorated, so generally require add softening agent, or fixation in fixation liquid after need Soft treatment is carried out again；Contain acrylic acid methyl ester., pentaerythritol triallyl ether and Long carbon chain in the monomer of present invention polymerization During quaternary ammonium salt, the fabric after fixation treatment can have comfortable flexibility；Meanwhile, the monomer methyl acrylate of present invention offer, Pentaerythritol triacrylate, diethylene glycol double methacrylate, pentaerythritol triallyl ether, quaternary ammonium salt are easy during the course of the reaction In polymerization, make course of reaction easily controllable, product is easily generated, and polymer itself is crosslinked instead in the present invention Should, and covalent bond can be formed with the hydroxyl reaction on fiber, make color fixing agent that there is good filming performance and cross-linking reaction Performance.
In addition, the present invention cationic polymer that weight average molecular weight is 5000~10000 by being polymerized, introduces polar group Group's hydroxyl and amino, and the cationic polymer degree of cross linking is not high, the cationic polymer and polyquaternary ammonium salt -4 and poly- season Ammonium salt -46 is further polymerized, obtain high-crosslinking-degree and surface hydroxyl and amine based polymer, its with dyestuff and fiber on hydroxyl Base or amido react crosslinking, strengthen polymeric film and fiber and the adhesion of dyestuff, and the fixing property for improving color fixing agent is same When it also avoid high temperature polymer crosslink reaction and then affect hydrophilic and flexibility.
The present invention is specifically described below by embodiment.Be necessary it is pointed out here that, following examples are only used In the invention will be further described, it is impossible to be interpreted as limiting the scope of the invention, professional and technical personnel in the field According to some nonessential modifications and adaptations that the content of the invention described above is made, protection scope of the present invention is still fallen within.
In addition, if without other explanation, it is raw materials used be all it is commercially available, be purchased from traditional Chinese medicines chemical reagent.
Embodiment 1
The hydrophilic color fixing agent preparing raw material of the environment-friendly type cotton include 24 parts of quaternary ammonium salt monomers, 16 parts of amine monomers, 30 parts Acrylic ester monomer, 3 parts of pentaerythritol triallyl ethers, 8 parts of polyquaternary ammonium salt；The quaternary ammonium salt monomer is acrylyl oxy-ethyl Alkyl quaternary ammonium saltss, allyl alkyl quaternary ammonium salt, the acrylyl oxy-ethyl alkyl quaternary ammonium saltss and the allyl alkyl quaternary ammonium salt Weight ratio be 1：0.63, the acrylyl oxy-ethyl alkyl quaternary ammonium saltss are acrylyl oxy-ethyl-dodecyl-dimethylammonium chloride Ammonium, acrylyl oxy-ethyl-myristyl-alkyl dimethyl ammonium chloride, the acrylyl oxy-ethyl-dodecyl-alkyl dimethyl ammonium chloride It is 1 with the weight ratio of acrylyl oxy-ethyl-myristyl-alkyl dimethyl ammonium chloride：0.52, the allyl alkyl quaternary ammonium salt is two Methyl diallyl ammonium chloride and dodecyldimethylamine base allyl ammonium chloride, the dimethyl diallyl ammonium chloride with it is described The weight ratio of dodecyldimethylamine base allyl ammonium chloride is 1：1.1；The amine monomers are diethylenetriamine, triethylene four Amine, the diethylenetriamine is 1 with the weight ratio of the triethylene tetramine：0.32；The acrylic ester monomer is acrylic acid Methyl ester, pentaerythritol triacrylate, diethylene glycol double methacrylate, the acrylic acid methyl ester. and the propylene of the tetramethylolmethane three Acid esters, the diethylene glycol double methacrylate weight ratio are 1：3：0.6；The polyquaternary ammonium salt is polyquaternary ammonium salt -4 and polyquaternary amine Salt -46, the polyquaternary ammonium salt -4 is 1 with the weight of polyquaternary ammonium salt -46 ratio：0.72；
The environment-friendly type cotton preparation method of hydrophilic color fixing agent, comprises the following steps：
(1) quaternary ammonium salt monomer, amine monomers, acrylic ester monomer, Ji Wusi are added in reactor according to weight portion Alcohol triallyl ether and water, are warming up to 80 DEG C；The water is 80 parts；
(2) it is dividedly in some parts initiator in reactor by weight, reacts 7h, obtains cation copolymer, the initiation Agent is azodiisobutyronitrile, and the initiator is 1.6 parts；
(3) cation copolymer, polyquaternary ammonium salt, catalyst and the water for adding step (2) to obtain in reactor, is warming up to 90℃；The catalyst is Ziegler-Natta catalyst；The consumption of the catalyst is 0.56 part；The water is 100 parts； The weight average molecular weight of the cation copolymer is 6000；
(4) initiator is dividedly in some parts in reactor, 8h is reacted, the hydrophilic color fixing agent of environment-friendly type cotton is obtained；It is described Initiator is 1.2 parts of benzoyl peroxides.
Embodiment 2
The hydrophilic color fixing agent preparing raw material of the environment-friendly type cotton include 24 parts of quaternary ammonium salt monomers, 16 parts of amine monomers, 30 parts Acrylic ester monomer, 3 parts of pentaerythritol triallyl ethers, 8 parts of polyquaternary ammonium salt；The quaternary ammonium salt monomer is acrylyl oxy-ethyl Alkyl quaternary ammonium saltss, allyl alkyl quaternary ammonium salt, the acrylyl oxy-ethyl alkyl quaternary ammonium saltss and the allyl alkyl quaternary ammonium salt Weight ratio be 1：0.2, the acrylyl oxy-ethyl alkyl quaternary ammonium saltss are acrylyl oxy-ethyl-dodecyl-dimethylammonium chloride Ammonium, acrylyl oxy-ethyl-myristyl-alkyl dimethyl ammonium chloride, the acrylyl oxy-ethyl-dodecyl-alkyl dimethyl ammonium chloride It is 1 with the weight ratio of acrylyl oxy-ethyl-myristyl-alkyl dimethyl ammonium chloride：0.52, the allyl alkyl quaternary ammonium salt is two Methyl diallyl ammonium chloride and dodecyldimethylamine base allyl ammonium chloride, the dimethyl diallyl ammonium chloride with it is described The weight ratio of dodecyldimethylamine base allyl ammonium chloride is 1：1.1；The amine monomers are diethylenetriamine, triethylene four Amine, the diethylenetriamine is 1 with the weight ratio of the triethylene tetramine：0.7；The acrylic ester monomer is acrylic acid first Ester, pentaerythritol triacrylate, diethylene glycol double methacrylate, the acrylic acid methyl ester. and the acrylic acid of the tetramethylolmethane three Ester, the diethylene glycol double methacrylate weight ratio are 1：3：0.6；The polyquaternary ammonium salt be polyquaternary ammonium salt -4 and polyquaternary ammonium salt - 46, the polyquaternary ammonium salt -4 is 1 with the weight of polyquaternary ammonium salt -46 ratio：1；
The environment-friendly type cotton preparation method of hydrophilic color fixing agent, comprises the following steps：
(1) quaternary ammonium salt monomer, amine monomers, acrylic ester monomer, Ji Wusi are added in reactor according to weight portion Alcohol triallyl ether and water, are warming up to 80 DEG C；The water is 80 parts；
(2) it is dividedly in some parts initiator in reactor by weight, reacts 7h, obtains cation copolymer, the initiation Agent is azodiisobutyronitrile, and the initiator is 1.6 parts；
(3) cation copolymer, polyquaternary ammonium salt, catalyst and the water for adding step (2) to obtain in reactor, is warming up to 90℃；The catalyst is Ziegler-Natta catalyst；The consumption of the catalyst is 0.56 part；The water is 100 parts； The weight average molecular weight of the cation copolymer is 6000；
(4) initiator is dividedly in some parts in reactor, 8h is reacted, the hydrophilic color fixing agent of environment-friendly type cotton is obtained；It is described Initiator is 1.2 parts of benzoyl peroxides.
Embodiment 3
The hydrophilic color fixing agent preparing raw material of the environment-friendly type cotton include 24 parts of quaternary ammonium salt monomers, 16 parts of amine monomers, 30 parts Acrylic ester monomer, 3 parts of pentaerythritol triallyl ethers, 8 parts of polyquaternary ammonium salt；The quaternary ammonium salt monomer is acrylyl oxy-ethyl Alkyl quaternary ammonium saltss, the acrylyl oxy-ethyl alkyl quaternary ammonium saltss be acrylyl oxy-ethyl-dodecyl-alkyl dimethyl ammonium chloride, third Alkene acyloxyethyl-myristyl-alkyl dimethyl ammonium chloride, the acrylyl oxy-ethyl-dodecyl-alkyl dimethyl ammonium chloride and propylene The weight ratio of acyloxyethyl-myristyl-alkyl dimethyl ammonium chloride is 1：0.52；The amine monomers are diethylenetriamine, three second Alkene tetramine, the diethylenetriamine is 1 with the weight ratio of the triethylene tetramine：0.32；The acrylic ester monomer is third E pioic acid methyl ester, pentaerythritol triacrylate, diethylene glycol double methacrylate, the acrylic acid methyl ester. and the tetramethylolmethane three Acrylate, the diethylene glycol double methacrylate weight ratio are 1：3：0.6；The polyquaternary ammonium salt is polyquaternary ammonium salt -4 and poly- season Ammonium salt -46, the polyquaternary ammonium salt -4 is 1 with the weight of polyquaternary ammonium salt -46 ratio：0.72；
The environment-friendly type cotton preparation method of hydrophilic color fixing agent, comprises the following steps：
(1) quaternary ammonium salt monomer, amine monomers, acrylic ester monomer, Ji Wusi are added in reactor according to weight portion Alcohol triallyl ether and water, are warming up to 80 DEG C；The water is 80 parts of water；
(2) it is dividedly in some parts initiator in reactor by weight, reacts 7h, obtains cation copolymer, the initiation Agent is azodiisobutyronitrile, and the initiator is 1.6 parts；
(3) cation copolymer, polyquaternary ammonium salt, catalyst and the water for adding step (2) to obtain in reactor, is warming up to 90℃；The catalyst is Ziegler-Natta catalyst；The consumption of the catalyst is 0.56 part；The water is 100 parts Water；The weight average molecular weight of the cation copolymer is 6000；
(4) initiator is dividedly in some parts in reactor, 8h is reacted, the hydrophilic color fixing agent of environment-friendly type cotton is obtained；It is described Initiator is 1.2 parts of benzoyl peroxides.
Embodiment 4
The hydrophilic color fixing agent preparing raw material of the environment-friendly type cotton include 24 parts of quaternary ammonium salt monomers, 16 parts of amine monomers, 30 parts Acrylic ester monomer, 3 parts of pentaerythritol triallyl ethers, 8 parts of polyquaternary ammonium salt；The quaternary ammonium salt monomer is acrylyl oxy-ethyl Alkyl quaternary ammonium saltss, allyl alkyl quaternary ammonium salt, the acrylyl oxy-ethyl alkyl quaternary ammonium saltss and the allyl alkyl quaternary ammonium salt Weight ratio be 1：0.63, the acrylyl oxy-ethyl alkyl quaternary ammonium saltss are acrylyl oxy-ethyl-dodecyl-dimethylammonium chloride Ammonium, acrylyl oxy-ethyl-myristyl-alkyl dimethyl ammonium chloride, the acrylyl oxy-ethyl-dodecyl-alkyl dimethyl ammonium chloride It is 1 with the weight ratio of acrylyl oxy-ethyl-myristyl-alkyl dimethyl ammonium chloride：0.52, the allyl alkyl quaternary ammonium salt is two Methyl diallyl ammonium chloride and dodecyldimethylamine base allyl ammonium chloride, the dimethyl diallyl ammonium chloride with it is described The weight ratio of dodecyldimethylamine base allyl ammonium chloride is 1：1.1；The amine monomers are diethylenetriamine；The acrylic acid Esters monomer is acrylic acid methyl ester., pentaerythritol triacrylate, diethylene glycol double methacrylate, the acrylic acid methyl ester. and institute Pentaerythritol triacrylate, the diethylene glycol double methacrylate weight ratio are stated for 1：3：0.6；The polyquaternary ammonium salt is poly- season Ammonium salt -4 and polyquaternary ammonium salt -46, the polyquaternary ammonium salt -4 is 1 with the weight of polyquaternary ammonium salt -46 ratio：0.72；
The environment-friendly type cotton preparation method of hydrophilic color fixing agent, comprises the following steps：
(1) quaternary ammonium salt monomer, amine monomers, acrylic ester monomer, Ji Wusi are added in reactor according to weight portion Alcohol triallyl ether and water, are warming up to 80 DEG C；The water is 80 parts；
(2) it is dividedly in some parts initiator in reactor by weight, reacts 7h, obtains cation copolymer, the initiation Agent is azodiisobutyronitrile, and the initiator is 1.6 parts；
(3) cation copolymer, polyquaternary ammonium salt, catalyst and the water for adding step (2) to obtain in reactor, is warming up to 90℃；The catalyst is Ziegler-Natta catalyst；The consumption of the catalyst is 0.56 part；The water is 100 parts Water；The weight average molecular weight of the cation copolymer is 6000；
(4) initiator is dividedly in some parts in reactor, 8h is reacted, the hydrophilic color fixing agent of environment-friendly type cotton is obtained；It is described Initiator is 1.2 parts of benzoyl peroxides.
Embodiment 5
The hydrophilic color fixing agent preparing raw material of the environment-friendly type cotton include 24 parts of quaternary ammonium salt monomers, 16 parts of amine monomers, 30 parts Acrylic ester monomer, 3 parts of pentaerythritol triallyl ethers, 8 parts of polyquaternary ammonium salt；The quaternary ammonium salt monomer is acrylyl oxy-ethyl Alkyl quaternary ammonium saltss, allyl alkyl quaternary ammonium salt, the acrylyl oxy-ethyl alkyl quaternary ammonium saltss and the allyl alkyl quaternary ammonium salt Weight ratio be 1：0.63, the acrylyl oxy-ethyl alkyl quaternary ammonium saltss are acrylyl oxy-ethyl-dodecyl-dimethylammonium chloride Ammonium, acrylyl oxy-ethyl-myristyl-alkyl dimethyl ammonium chloride, the acrylyl oxy-ethyl-dodecyl-alkyl dimethyl ammonium chloride It is 1 with the weight ratio of acrylyl oxy-ethyl-myristyl-alkyl dimethyl ammonium chloride：0.52, the allyl alkyl quaternary ammonium salt is two Methyl diallyl ammonium chloride and dodecyldimethylamine base allyl ammonium chloride, the dimethyl diallyl ammonium chloride with it is described The weight ratio of dodecyldimethylamine base allyl ammonium chloride is 1：1.1；The amine monomers are diethylenetriamine, triethylene four Amine, the diethylenetriamine is 1 with the weight ratio of the triethylene tetramine：0.32；The acrylic ester monomer is acrylic acid Methyl ester；The polyquaternary ammonium salt is polyquaternary ammonium salt -4 and polyquaternary ammonium salt -46, the polyquaternary ammonium salt -4 and the weight of polyquaternary ammonium salt -46 Amount is than being 1：0.72；
The environment-friendly type cotton preparation method of hydrophilic color fixing agent, comprises the following steps：
(1) quaternary ammonium salt monomer, amine monomers, acrylic ester monomer, Ji Wusi are added in reactor according to weight portion Alcohol triallyl ether and water, are warming up to 80 DEG C；The water is 80 parts；
(2) it is dividedly in some parts initiator in reactor by weight, reacts 7h, obtains cation copolymer, the initiation Agent is azodiisobutyronitrile, and the initiator is 1.6 parts；
(3) cation copolymer, polyquaternary ammonium salt, catalyst and the water for adding step (2) to obtain in reactor, is warming up to 90℃；The catalyst is Ziegler-Natta catalyst；The consumption of the catalyst is 0.56 part；The water is 100 parts； The weight average molecular weight of the cation copolymer is 6000；
(4) initiator is dividedly in some parts in reactor, 8h is reacted, the hydrophilic color fixing agent of environment-friendly type cotton is obtained；It is described Initiator is 1.2 parts of benzoyl peroxides.
Embodiment 6
The hydrophilic color fixing agent preparing raw material of the environment-friendly type cotton include 24 parts of quaternary ammonium salt monomers, 16 parts of amine monomers, 30 parts Acrylic ester monomer, 3 parts of pentaerythritol triallyl ethers, 8 parts of polyquaternary ammonium salt；The quaternary ammonium salt monomer is acrylyl oxy-ethyl Alkyl quaternary ammonium saltss, allyl alkyl quaternary ammonium salt, the acrylyl oxy-ethyl alkyl quaternary ammonium saltss and the allyl alkyl quaternary ammonium salt Weight ratio be 1：0.63, the acrylyl oxy-ethyl alkyl quaternary ammonium saltss are acrylyl oxy-ethyl-dodecyl-dimethylammonium chloride Ammonium, acrylyl oxy-ethyl-myristyl-alkyl dimethyl ammonium chloride, the acrylyl oxy-ethyl-dodecyl-alkyl dimethyl ammonium chloride It is 1 with the weight ratio of acrylyl oxy-ethyl-myristyl-alkyl dimethyl ammonium chloride：0.52, the allyl alkyl quaternary ammonium salt is two Methyl diallyl ammonium chloride and dodecyldimethylamine base allyl ammonium chloride, the dimethyl diallyl ammonium chloride with it is described The weight ratio of dodecyldimethylamine base allyl ammonium chloride is 1：1.1；The amine monomers are diethylenetriamine, triethylene four Amine, the diethylenetriamine is 1 with the weight ratio of the triethylene tetramine：0.32；The acrylic ester monomer is acrylic acid Methyl ester, pentaerythritol triacrylate, diethylene glycol double methacrylate, the acrylic acid methyl ester. and the propylene of the tetramethylolmethane three Acid esters, the diethylene glycol double methacrylate weight ratio are 1：3：0.6；The polyquaternary ammonium salt is polyquaternary ammonium salt -4；
The environment-friendly type cotton preparation method of hydrophilic color fixing agent, comprises the following steps：
(1) quaternary ammonium salt monomer, amine monomers, acrylic ester monomer, Ji Wusi are added in reactor according to weight portion Alcohol triallyl ether and water, are warming up to 80 DEG C；The water is 80 parts；
(2) it is dividedly in some parts initiator in reactor by weight, reacts 7h, obtains cation copolymer, the initiation Agent is azodiisobutyronitrile, and the initiator is 1.6 parts；
(3) cation copolymer, polyquaternary ammonium salt, catalyst and the water for adding step (2) to obtain in reactor, is warming up to 90℃；The catalyst is Ziegler-Natta catalyst；The consumption of the catalyst is 0.56 part；The water is 100 parts； The weight average molecular weight of the cation copolymer is 6000；
(4) initiator is dividedly in some parts in reactor, 8h is reacted, the hydrophilic color fixing agent of environment-friendly type cotton is obtained；It is described Initiator is 1.2 parts of benzoyl peroxides.
Embodiment 7
The hydrophilic color fixing agent preparing raw material of the environment-friendly type cotton include 24 parts of quaternary ammonium salt monomers, 16 parts of amine monomers, 33 parts Acrylic ester monomer, 8 parts of polyquaternary ammonium salt；The quaternary ammonium salt monomer is acrylyl oxy-ethyl alkyl quaternary ammonium saltss, allyl alkyl Quaternary ammonium salt, the acrylyl oxy-ethyl alkyl quaternary ammonium saltss are 1 with the weight ratio of the allyl alkyl quaternary ammonium salt：0.63, it is described Acrylyl oxy-ethyl alkyl quaternary ammonium saltss are acrylyl oxy-ethyl-dodecyl-alkyl dimethyl ammonium chloride, acrylyl oxy-ethyl-ten four Alkyl-alkyl dimethyl ammonium chloride, the acrylyl oxy-ethyl-dodecyl-alkyl dimethyl ammonium chloride and acrylyl oxy-ethyl-tetradecane The weight ratio of base-alkyl dimethyl ammonium chloride is 1：0.52, the allyl alkyl quaternary ammonium salt be dimethyl diallyl ammonium chloride and Dodecyldimethylamine base allyl ammonium chloride, the dimethyl diallyl ammonium chloride and the dodecyldimethylamine base pi-allyl The weight ratio of ammonium chloride is 1：1.1；The amine monomers are diethylenetriamine, triethylene tetramine, the diethylenetriamine and institute The weight ratio for stating triethylene tetramine is 1：0.32；The acrylic ester monomer is acrylic acid methyl ester., the acrylic acid of tetramethylolmethane three Ester, diethylene glycol double methacrylate, the acrylic acid methyl ester. and the pentaerythritol triacrylate, the diethylene glycol double third Olefin(e) acid ester weight ratio is 1：3：0.6；The polyquaternary ammonium salt is polyquaternary ammonium salt -4 and polyquaternary ammonium salt -46, the polyquaternary ammonium salt -4 with The weight of polyquaternary ammonium salt -46 ratio is 1：0.72；
The environment-friendly type cotton preparation method of hydrophilic color fixing agent, comprises the following steps：
(1) quaternary ammonium salt monomer, amine monomers, acrylic ester monomer and water are added in reactor according to weight portion, is risen Temperature is to 80 DEG C；The water is 80 parts；
(2) it is dividedly in some parts initiator in reactor by weight, reacts 7h, obtains cation copolymer, the initiation Agent is azodiisobutyronitrile, and the initiator is 1.6 parts；
(3) cation copolymer, polyquaternary ammonium salt, catalyst and the water for adding step (2) to obtain in reactor, is warming up to 90℃；The catalyst is Ziegler-Natta catalyst；The consumption of the catalyst is 0.56 part；The water is 100 parts； The weight average molecular weight of the cation copolymer is 6000；
(4) initiator is dividedly in some parts in reactor, 8h is reacted, the hydrophilic color fixing agent of environment-friendly type cotton is obtained；It is described Initiator is 1.2 parts of benzoyl peroxides.
Embodiment 8
The hydrophilic color fixing agent preparing raw material of the environment-friendly type cotton include 20 parts of quaternary ammonium salt monomers, 20 parts of amine monomers, 30 parts Acrylic ester monomer, 3 parts of pentaerythritol triallyl ethers, 8 parts of polyquaternary ammonium salt；The quaternary ammonium salt monomer is acrylyl oxy-ethyl Alkyl quaternary ammonium saltss, allyl alkyl quaternary ammonium salt, the acrylyl oxy-ethyl alkyl quaternary ammonium saltss and the allyl alkyl quaternary ammonium salt Weight ratio be 1：0.63, the acrylyl oxy-ethyl alkyl quaternary ammonium saltss are acrylyl oxy-ethyl-dodecyl-dimethylammonium chloride Ammonium, acrylyl oxy-ethyl-myristyl-alkyl dimethyl ammonium chloride, the acrylyl oxy-ethyl-dodecyl-alkyl dimethyl ammonium chloride It is 1 with the weight ratio of acrylyl oxy-ethyl-myristyl-alkyl dimethyl ammonium chloride：0.52, the allyl alkyl quaternary ammonium salt is two Methyl diallyl ammonium chloride and dodecyldimethylamine base allyl ammonium chloride, the dimethyl diallyl ammonium chloride with it is described The weight ratio of dodecyldimethylamine base allyl ammonium chloride is 1：1.1；The amine monomers are diethylenetriamine, triethylene four Amine, the diethylenetriamine is 1 with the weight ratio of the triethylene tetramine：0.32；The acrylic ester monomer is acrylic acid Methyl ester, pentaerythritol triacrylate, diethylene glycol double methacrylate, the acrylic acid methyl ester. and the propylene of the tetramethylolmethane three Acid esters, the diethylene glycol double methacrylate weight ratio are 1：3：0.6；The polyquaternary ammonium salt is polyquaternary ammonium salt -4 and polyquaternary amine Salt -46, the polyquaternary ammonium salt -4 is 1 with the weight of polyquaternary ammonium salt -46 ratio：0.72；
The environment-friendly type cotton preparation method of hydrophilic color fixing agent, comprises the following steps：
(1) quaternary ammonium salt monomer, amine monomers, acrylic ester monomer, Ji Wusi are added in reactor according to weight portion Alcohol triallyl ether and water, are warming up to 80 DEG C；The water is 80 parts；
(2) it is dividedly in some parts initiator in reactor by weight, reacts 7h, obtains cation copolymer, the initiation Agent is azodiisobutyronitrile, and the initiator is 1.6 parts；
(3) cation copolymer, polyquaternary ammonium salt, catalyst and the water for adding step (2) to obtain in reactor, is warming up to 90℃；The catalyst is Ziegler-Natta catalyst；The consumption of the catalyst is 0.56 part；The water is 100 parts； The weight average molecular weight of the cation copolymer is 8000；
(4) initiator is dividedly in some parts in reactor, 8h is reacted, the hydrophilic color fixing agent of environment-friendly type cotton is obtained；It is described Initiator is 1.2 parts of benzoyl peroxides.
Embodiment 9
The hydrophilic color fixing agent preparing raw material of the environment-friendly type cotton include 40 parts of quaternary ammonium salt monomers, 10 parts of amine monomers, 20 parts Acrylic ester monomer, 3 parts of pentaerythritol triallyl ethers, 8 parts of polyquaternary ammonium salt；The quaternary ammonium salt monomer is acrylyl oxy-ethyl Alkyl quaternary ammonium saltss, allyl alkyl quaternary ammonium salt, the acrylyl oxy-ethyl alkyl quaternary ammonium saltss and the allyl alkyl quaternary ammonium salt Weight ratio be 1：0.63, the acrylyl oxy-ethyl alkyl quaternary ammonium saltss are acrylyl oxy-ethyl-dodecyl-dimethylammonium chloride Ammonium, acrylyl oxy-ethyl-myristyl-alkyl dimethyl ammonium chloride, the acrylyl oxy-ethyl-dodecyl-alkyl dimethyl ammonium chloride It is 1 with the weight ratio of acrylyl oxy-ethyl-myristyl-alkyl dimethyl ammonium chloride：0.52, the allyl alkyl quaternary ammonium salt is two Methyl diallyl ammonium chloride and dodecyldimethylamine base allyl ammonium chloride, the dimethyl diallyl ammonium chloride with it is described The weight ratio of dodecyldimethylamine base allyl ammonium chloride is 1：1.1；The amine monomers are diethylenetriamine, triethylene four Amine, the diethylenetriamine is 1 with the weight ratio of the triethylene tetramine：0.32；The acrylic ester monomer is acrylic acid Methyl ester, pentaerythritol triacrylate, diethylene glycol double methacrylate, the acrylic acid methyl ester. and the propylene of the tetramethylolmethane three Acid esters, the diethylene glycol double methacrylate weight ratio are 1：3：0.6；The polyquaternary ammonium salt is polyquaternary ammonium salt -4 and polyquaternary amine Salt -46, the polyquaternary ammonium salt -4 is 1 with the weight of polyquaternary ammonium salt -46 ratio：0.72；
The environment-friendly type cotton preparation method of hydrophilic color fixing agent, comprises the following steps：
(1) quaternary ammonium salt monomer, amine monomers, acrylic ester monomer, Ji Wusi are added in reactor according to weight portion Alcohol triallyl ether and water, are warming up to 80 DEG C；The water is 80 parts；
(2) it is dividedly in some parts initiator in reactor by weight, reacts 7h, obtains cation copolymer, the initiation Agent is azodiisobutyronitrile, and the initiator is 1.6 parts；
(3) cation copolymer, polyquaternary ammonium salt, catalyst and the water for adding step (2) to obtain in reactor, is warming up to 90℃；The catalyst is Ziegler-Natta catalyst；The consumption of the catalyst is 0.56 part；The water is 100 parts； The weight average molecular weight of the cation copolymer is 6000；
(4) initiator is dividedly in some parts in reactor, 8h is reacted, the hydrophilic color fixing agent of environment-friendly type cotton is obtained；It is described Initiator is 1.2 parts of benzoyl peroxides.
Embodiment 10
The hydrophilic color fixing agent preparing raw material of the environment-friendly type cotton include 24 parts of quaternary ammonium salt monomers, 16 parts of amine monomers, 30 parts Acrylic ester monomer, 3 parts of pentaerythritol triallyl ethers, 8 parts of polyquaternary ammonium salt；The quaternary ammonium salt monomer is acrylyl oxy-ethyl Alkyl quaternary ammonium saltss, allyl alkyl quaternary ammonium salt, the acrylyl oxy-ethyl alkyl quaternary ammonium saltss and the allyl alkyl quaternary ammonium salt Weight ratio be 1：1, the acrylyl oxy-ethyl alkyl quaternary ammonium saltss be acrylyl oxy-ethyl-dodecyl-alkyl dimethyl ammonium chloride, Acrylyl oxy-ethyl-myristyl-alkyl dimethyl ammonium chloride, the acrylyl oxy-ethyl-dodecyl-alkyl dimethyl ammonium chloride and third The weight ratio of alkene acyloxyethyl-myristyl-alkyl dimethyl ammonium chloride is 1：0.52, the allyl alkyl quaternary ammonium salt is dimethyl Diallyl ammonium chloride and dodecyldimethylamine base allyl ammonium chloride, the dimethyl diallyl ammonium chloride and described 14 The weight ratio of alkyl dimethyl allyl ammonium chloride is 1：1.1；The amine monomers be diethylenetriamine, triethylene tetramine, institute It is 1 that diethylenetriamine is stated with the weight ratio of the triethylene tetramine：0.7；The acrylic ester monomer is acrylic acid methyl ester., season Penta tetrol triacrylate, diethylene glycol double methacrylate, the acrylic acid methyl ester. and the pentaerythritol triacrylate, institute Diethylene glycol double methacrylate weight ratio is stated for 1：1：1；The polyquaternary ammonium salt is polyquaternary ammonium salt -4 and polyquaternary ammonium salt -46, described Polyquaternary ammonium salt -4 is 1 with the weight of polyquaternary ammonium salt -46 ratio：1；
The environment-friendly type cotton preparation method of hydrophilic color fixing agent, comprises the following steps：
(1) quaternary ammonium salt monomer, amine monomers, acrylic ester monomer, Ji Wusi are added in reactor according to weight portion Alcohol triallyl ether and water, are warming up to 80 DEG C；The water is 80 parts；
(2) it is dividedly in some parts initiator in reactor by weight, reacts 7h, obtains cation copolymer, the initiation Agent is azodiisobutyronitrile, and the initiator is 1.6 parts；
(3) cation copolymer, polyquaternary ammonium salt, catalyst and the water for adding step (2) to obtain in reactor, is warming up to 90℃；The catalyst is Ziegler-Natta catalyst；The consumption of the catalyst is 0.56 part；The water is 100 parts； The weight average molecular weight of the cation copolymer is 6000；
(4) initiator is dividedly in some parts in reactor, 8h is reacted, the hydrophilic color fixing agent of environment-friendly type cotton is obtained；It is described Initiator is 1.2 parts of benzoyl peroxides.
Comparative example 1
The hydrophilic color fixing agent preparing raw material of the environment-friendly type cotton include 35 parts of quaternary ammonium salt monomers, 16 parts of amine monomers, 30 parts Acrylic ester monomer；The quaternary ammonium salt monomer be acrylyl oxy-ethyl alkyl quaternary ammonium saltss, allyl alkyl quaternary ammonium salt, described third Alkene acyloxyethyl alkyl quaternary ammonium saltss are 1 with the weight ratio of the allyl alkyl quaternary ammonium salt：0.63, the acrylyl oxy-ethyl alkane Based quaternary ammonium salt is acrylyl oxy-ethyl-dodecyl-alkyl dimethyl ammonium chloride, acrylyl oxy-ethyl-myristyl-dimethylammonium chloride Ammonium, the acrylyl oxy-ethyl-dodecyl-alkyl dimethyl ammonium chloride and acrylyl oxy-ethyl-myristyl-alkyl dimethyl ammonium chloride Weight ratio be 1：0.52, the allyl alkyl quaternary ammonium salt is dimethyl diallyl ammonium chloride and dodecyldimethylamine base alkene Propyl ammonium chloride, the dimethyl diallyl ammonium chloride is with the weight ratio of the dodecyldimethylamine base allyl ammonium chloride 1：1.1；The amine monomers are diethylenetriamine, triethylene tetramine, the weight of the diethylenetriamine and the triethylene tetramine Amount is than being 1：0.32；The acrylic ester monomer is acrylic acid methyl ester., pentaerythritol triacrylate, the double propylene of diethylene glycol Acid esters, the acrylic acid methyl ester. is 1 with the pentaerythritol triacrylate, the diethylene glycol double methacrylate weight ratio： 3：0.6；
The environment-friendly type cotton preparation method of hydrophilic color fixing agent, comprises the following steps：
(1) quaternary ammonium salt monomer, amine monomers, acrylic ester monomer and water are added in reactor according to weight portion, is risen Temperature is to 80 DEG C；The water is 80 parts；
(2) it is dividedly in some parts initiator in reactor by weight, reacts 7h, obtains the hydrophilic fixation of environment-friendly type cotton Agent, the initiator is azodiisobutyronitrile, and the initiator is 1.6 parts.
Comparative example 2
The hydrophilic color fixing agent preparing raw material of the environment-friendly type cotton include 35 parts of quaternary ammonium salt monomers, 16 parts of amine monomers, 30 parts Acrylic ester monomer；The quaternary ammonium salt monomer is allyl alkyl quaternary ammonium salt, and the allyl alkyl quaternary ammonium salt is dimethyl Diallyl ammonium chloride and dodecyldimethylamine base allyl ammonium chloride, the dimethyl diallyl ammonium chloride and described 14 The weight ratio of alkyl dimethyl allyl ammonium chloride is 1：1.1；The amine monomers be diethylenetriamine, triethylene tetramine, institute It is 1 that diethylenetriamine is stated with the weight ratio of the triethylene tetramine：0.32；The acrylic ester monomer be acrylic acid methyl ester., Pentaerythritol triacrylate, diethylene glycol double methacrylate, the acrylic acid methyl ester. and the pentaerythritol triacrylate, The diethylene glycol double methacrylate weight ratio is 1：3：0.6；
The environment-friendly type cotton preparation method of hydrophilic color fixing agent, comprises the following steps：
(1) quaternary ammonium salt monomer, amine monomers, acrylic ester monomer and water are added in reactor according to weight portion, is risen Temperature is to 80 DEG C；The water is 80 parts；
(2) it is dividedly in some parts initiator in reactor by weight, reacts 7h, obtains the hydrophilic fixation of environment-friendly type cotton Agent, the initiator is azodiisobutyronitrile, and the initiator is 1.6 parts；
Comparative example 3
The hydrophilic color fixing agent preparing raw material of the environment-friendly type cotton include 35 parts of quaternary ammonium salt monomers, 16 parts of amine monomers, 30 parts Acrylic ester monomer；The quaternary ammonium salt monomer is allyl alkyl quaternary ammonium salt, and the allyl alkyl quaternary ammonium salt is dimethyl Diallyl ammonium chloride and dodecyldimethylamine base allyl ammonium chloride, the dimethyl diallyl ammonium chloride and described 14 The weight ratio of alkyl dimethyl allyl ammonium chloride is 1：1.1；The amine monomers are diethylenetriamine；The esters of acrylic acid Monomer is acrylic acid methyl ester.；
The environment-friendly type cotton preparation method of hydrophilic color fixing agent, comprises the following steps：
(1) quaternary ammonium salt monomer, amine monomers, acrylic ester monomer and water are added in reactor according to weight portion, is risen Temperature is to 80 DEG C；The water is 80 parts；
(2) it is dividedly in some parts initiator in reactor by weight, reacts 7h, obtains the hydrophilic fixation of environment-friendly type cotton Agent, the initiator is azodiisobutyronitrile, and the initiator is 1.6 parts；
Performance test
1st, soaping fastness:By GB/T3921-2008《Textile color stability is tested:Soaping fastness》Method is determined；
2nd, crock fastness:By GB/T3920-2008《Textile color stability is tested:Crock fastness》Method is determined；
3rd, perspiration fastness:Tested by GB/T3922-1995；
4th, feel test：Close mesh and touch the fabric after arranging, with 10 people as a small group, graded, according to different handss PRINTED FABRIC is carried out hand feel evaluation by sense, and concrete assessment method is：Feel grading is carried out in terms of flexibility, smooth feeling two, altogether Divide 5 grades, 1 grade worst, and fabric feeling is harder, the glutinous sense of cunning is poor.5 grades preferably, and fabrics feel soft, cunning are glutinous.
5th, heat stability：
Method of testing is as follows:A certain amount of hydrophilic color-fixing agent emulsion is put in the container of sealing, at 60 DEG C 5h is deposited, seen Examine its state change and record, it is unchanged to illustrate that hydrophilic color-fixing agent emulsion high-temperature stability is preferable；Vary less explanation hydrophilic solid Toner emulsion high-temperature stability is preferable；There is the hydrophilic color-fixing agent emulsion stability of part precipitation explanation poor.
The performance test results of table 1
The present invention is polymerized by quaternary ammonium salt monomer, amine monomers, acrylic ester monomer, pentaerythritol triallyl ether To the cationic polymer that weight average molecular weight is 5000~10000, polar group hydroxyl and amino, and the cation are introduced Crosslinked polymer degree is not high, and the cationic polymer is further polymerized with polyquaternary ammonium salt -4 and polyquaternary ammonium salt -46, obtains high friendship Connection degree and surface hydroxyl and amine based polymer, its with dyestuff and fiber on hydroxyl or amido react crosslinking, strengthen Polymeric film and fiber and the adhesion of dyestuff, the fixing property for improving color fixing agent it also avoid polymer generation during high temperature simultaneously Cross-linking reaction and then impact hydrophilic and flexibility.
Above-mentioned example is merely illustrative, for explaining some features of the feature of the present invention.Appended claim The scope as wide as possible for requiring to be contemplated that is intended to, and embodiments as presented herein is only according to all possible embodiment Combination selection embodiment explanation.Therefore, the purpose of applicant is appended claim not by the explanation present invention Feature example selectional restriction, and the progress in science and technology will be formed due to language performance inaccurate reason and not The possible equivalent or son being presently considered is replaced, and these changes also should be interpreted in the conceived case by appended Claim is covered.

Claims (10)

1. a kind of hydrophilic color fixing agent of environment-friendly type cotton, it is characterised in that calculate by weight, the hydrophilic fixation of environment-friendly type cotton Agent preparing raw material include 10~50 parts of quaternary ammonium salt monomers, 5~25 parts of amine monomers, 5~40 parts of acrylic ester monomers, 1~5 part Pentaerythritol triallyl ether, 5~15 parts of polyquaternary ammonium salt；Wherein, the quaternary ammonium salt monomer includes acrylyl oxy-ethyl alkyl quaternary One or more in ammonium salt, allyl alkyl quaternary ammonium salt；The amine monomers include diethylenetriamine, triethylene tetramine, tetrem One or more in the amine of alkene five.
2. the hydrophilic color fixing agent of environment-friendly type cotton according to claim 1, it is characterised in that the acrylyl oxy-ethyl alkyl quaternary Ammonium salt is 1 with the weight ratio of the allyl alkyl quaternary ammonium salt：(0.2~1).
3. the hydrophilic color fixing agent of environment-friendly type cotton according to claim 1, it is characterised in that the acrylyl oxy-ethyl alkyl quaternary Ammonium salt includes acrylyl oxy-ethyl-trimethyl salmiac, MethacryloyloxyethylTrimethyl Trimethyl Ammonium Chloride, acrylyl oxy-ethyl three Methyl bromide ammonium, methylacryoyloxyethyl trimethylammonium bromide, acrylyl oxy-ethyl-dodecyl-alkyl dimethyl ammonium chloride, first Base acrylyl oxy-ethyl-dodecyl-alkyl dimethyl ammonium chloride, acrylyl oxy-ethyl-dodecyl-ditallowdimethyl ammonium bromide, methyl Acrylyl oxy-ethyl-dodecyl-ditallowdimethyl ammonium bromide, acrylyl oxy-ethyl-myristyl-alkyl dimethyl ammonium chloride, methyl-prop Alkene acyloxyethyl-myristyl-alkyl dimethyl ammonium chloride, acrylyl oxy-ethyl-myristyl-ditallowdimethyl ammonium bromide, metering system Acyloxyethyl-myristyl-ditallowdimethyl ammonium bromide, acrylyl oxy-ethyl-cetyl-alkyl dimethyl ammonium chloride, methacryl Oxygen ethyl-cetyl-alkyl dimethyl ammonium chloride, acrylyl oxy-ethyl-cetyl-ditallowdimethyl ammonium bromide, methacryloxypropyl Ethyl-cetyl-ditallowdimethyl ammonium bromide, acrylyl oxy-ethyl-octadecyl-alkyl dimethyl ammonium chloride, methacryloxypropyl second Base-octadecyl-alkyl dimethyl ammonium chloride, acrylyl oxy-ethyl-octadecyl-ditallowdimethyl ammonium bromide, methylacryoyloxyethyl- One or more in octadecyl-ditallowdimethyl ammonium bromide；The allyl alkyl quaternary ammonium salt includes pi-allyl trimethyl ammonia chloride Ammonium, pi-allyl trimethylammonium bromide, dimethyl diallyl ammonium chloride, dimethyl diallyl ammonium bromide, dimethyl Base allyl ammonium chloride, dodecyl dimethyl allylic bromination ammonium, dodecyldimethylamine base allyl ammonium chloride, myristyl Dimethyl-allyl ammonium bromide, hexadecyldimethyl benzyl ammonium allyl ammonium chloride, hexadecyldimethyl benzyl ammonium allylic bromination ammonium, 18 One or more in alkyl dimethyl allyl ammonium chloride, octadecyldimethyl allylic bromination ammonium.
4. the hydrophilic color fixing agent of environment-friendly type cotton according to claim 1, it is characterised in that the acrylic ester monomer includes Acrylic acid methyl ester., ethyl acrylate, propyl acrylate, butyl acrylate, n-octyl, acrylic acid-2-ethyl caproite, season It is a kind of in penta tetrol triacrylate, diethylene glycol double methacrylate, 2-hydroxyethyl methacry-late, methyl methacrylate Or it is various.
5. the hydrophilic color fixing agent of environment-friendly type cotton according to claim 4, it is characterised in that the acrylic ester monomer is third E pioic acid methyl ester, pentaerythritol triacrylate, diethylene glycol double methacrylate.
6. the hydrophilic color fixing agent of environment-friendly type cotton according to claim 5, it is characterised in that the acrylic acid methyl ester. and the season Penta tetrol triacrylate, the diethylene glycol double methacrylate weight ratio are 1：(1~5)：(0.5~1).
7. the hydrophilic color fixing agent of environment-friendly type cotton according to claim 1, it is characterised in that the polyquaternary ammonium salt includes polyquaternary amine Salt -2, polyquaternary ammonium salt -4, polyquaternary ammonium salt -5, polyquaternary ammonium salt -6, polyquaternary ammonium salt -7, Polyquaternium-10, polyquaternary ammonium salt -11, poly- season Ammonium salt -16, Merquat 280, polyquaternary ammonium salt -24, polyquaternary ammonium salt -28, polyquaternium -32, polyquaternary ammonium salt -37, polyquaternary ammonium salt - 39, polyquaternary ammonium salt -42, polyquaternary ammonium salt -43, polyquaternary ammonium salt -44, polyquaternary ammonium salt -46, polyquaternary ammonium salt -47, polyquaternary ammonium salt -51 are gathered Quaternary ammonium salt -53, polyquaternary ammonium salt -55, polyquaternary ammonium salt -57, polyquaternary ammonium salt -58, polyquaternary ammonium salt -59, polyquaternary ammonium salt -60, polyquaternary amine Salt -63, polyquaternary ammonium salt -65, one or more in polyquaternary ammonium salt -68.
8. the hydrophilic color fixing agent of environment-friendly type cotton according to claim 7, it is characterised in that the polyquaternary ammonium salt is polyquaternary amine Salt -4 and polyquaternary ammonium salt -46.
9. the hydrophilic color fixing agent of environment-friendly type cotton according to claim 8, it is characterised in that the polyquaternary ammonium salt -4 is poly- with described The weight of quaternary ammonium salt -46 ratio is 1：(0.3~1).
10. the environment-friendly type cotton according to claims 1 to 9 preparation method of hydrophilic color fixing agent, it is characterised in that including following Step：
(1) quaternary ammonium salt monomer, amine monomers, acrylic ester monomer, tetramethylolmethane three are added in reactor according to weight portion Allyl ether and water, are warming up to 70~85 DEG C；
(2) it is dividedly in some parts initiator in reactor by weight, reacts 4~10h, obtains cation copolymer, the initiation Agent is 1~2 part；
(3) step (2) cation copolymer, polyquaternary ammonium salt, catalyst and the water that obtain are added in reactor, it is warming up to 85~ 90℃；
(4) initiator is dividedly in some parts, 6~8h is reacted, the hydrophilic color fixing agent of environment-friendly type cotton is obtained.
CN201710052986.0A 2017-01-22 2017-01-22 A kind of hydrophilic color fixing agent of environment-friendly type cotton Active CN106676918B (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201710052986.0A CN106676918B (en) 2017-01-22 2017-01-22 A kind of hydrophilic color fixing agent of environment-friendly type cotton

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201710052986.0A CN106676918B (en) 2017-01-22 2017-01-22 A kind of hydrophilic color fixing agent of environment-friendly type cotton

Publications (2)

Publication Number Publication Date
CN106676918A true CN106676918A (en) 2017-05-17
CN106676918B CN106676918B (en) 2018-10-23

Family

ID=58859693

Family Applications (1)

Application Number Title Priority Date Filing Date
CN201710052986.0A Active CN106676918B (en) 2017-01-22 2017-01-22 A kind of hydrophilic color fixing agent of environment-friendly type cotton

Country Status (1)

Country Link
CN (1) CN106676918B (en)

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN107794786A (en) * 2017-10-31 2018-03-13 杭州瑞江实业有限公司 A kind of cotton fabric hydrophilic color fixing agent and preparation method thereof
CN109056383A (en) * 2018-08-01 2018-12-21 湖南七纬科技有限公司 A kind of printing and dyeing assistant and preparation method thereof
CN115748271A (en) * 2022-10-26 2023-03-07 浙江海联新材料科技有限公司 Ternary polymerization efficient formaldehyde-free color fixing agent for reactive dye and preparation method thereof

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101684621A (en) * 2009-06-09 2010-03-31 陕西科技大学 Dendriform cationic leather fixing agent and preparation method thereof
CN104562803A (en) * 2015-01-22 2015-04-29 南通优尼科化工有限公司 Fabric fixing agent
US20160024428A1 (en) * 2014-07-23 2016-01-28 The Procter & Gamble Company Treatment compositions
CN106220785A (en) * 2016-08-11 2016-12-14 四川省纺织科学研究院 A kind of reactive polyquarternium-type is without the preparation method and application of aldehyde fixation crosslinking agent

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101684621A (en) * 2009-06-09 2010-03-31 陕西科技大学 Dendriform cationic leather fixing agent and preparation method thereof
US20160024428A1 (en) * 2014-07-23 2016-01-28 The Procter & Gamble Company Treatment compositions
CN104562803A (en) * 2015-01-22 2015-04-29 南通优尼科化工有限公司 Fabric fixing agent
CN106220785A (en) * 2016-08-11 2016-12-14 四川省纺织科学研究院 A kind of reactive polyquarternium-type is without the preparation method and application of aldehyde fixation crosslinking agent

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN107794786A (en) * 2017-10-31 2018-03-13 杭州瑞江实业有限公司 A kind of cotton fabric hydrophilic color fixing agent and preparation method thereof
CN109056383A (en) * 2018-08-01 2018-12-21 湖南七纬科技有限公司 A kind of printing and dyeing assistant and preparation method thereof
CN115748271A (en) * 2022-10-26 2023-03-07 浙江海联新材料科技有限公司 Ternary polymerization efficient formaldehyde-free color fixing agent for reactive dye and preparation method thereof

Also Published As

Publication number Publication date
CN106676918B (en) 2018-10-23

Similar Documents

Publication Publication Date Title
CN106676918A (en) Environment-friendly hydrophilic color fixing agent applied to cotton
CA2005668C (en) Emulsified functionalized polymers
CN102108638B (en) Durable, waterproof, oil-proof, antistatic and antibacterial functional coating adhesive and preparation method
AU2004291527B2 (en) Fluorine efficient finishes for textiles
CN106749878A (en) A kind of preparation of quaternary ammonium salt cationic type aqueous fluorine-containing polyacrylate and emulsion and the emulsion
EP0479245A2 (en) Absorbent polymer
KR20070045253A (en) Acrylic shrinkable fiber and process for producing the same
CN104313926A (en) Preparation method for hydrophilic dye-fixing agent for reactive dyeing
CN1811052A (en) Amphoteric water soluble color-fixing agent and its application
CN108699426A (en) Surface conditioning agent
CN105568723A (en) Synthesis method for cationic waterborne polyurethane acid dye fixing agent
CN103936941A (en) Amphiphilic core-shell emulsion adhesive for pigment printing of textile and preparation method thereof
JPS60108409A (en) Cationic amphoteric quaternary polymer and cosmetic composition
JP7146164B2 (en) Wet rubbing fastness improver for cellulosic fiber, method for producing dyed cellulose fiber using the same, and use thereof
CN107476063B (en) The good water-and acrylate coating adhesive used for textiles and preparation method thereof of soft, cold-resistant, elastic, fastness, resistance to hydrostatic pressure performance
US20230313448A1 (en) Water-repellent organic fine particles having slip prevention effect
Chantawong et al. Modification of silk fabrics with diallyldimethylammonium chloride
US3082178A (en) Composition consisting of cellulose acetate and copolymer of n, n-dimethyl-acrylamide
US3133039A (en) Acrylonitrile polymer compositions
Zohdy et al. Selective properties of polyester and cotton/polyester fabrics gamma radiation grafted with different binary mixtures of vinyl monomers
CN109183467B (en) Hydrophilic alkali-resistant color fixing agent and preparation method thereof
CN100441606C (en) Polyacrylonitrile resin dyeable with both cationic dye and acid dye
CN101384692B (en) Soil releasing agent for fiber
CN115094654B (en) Polymer color fixing agent and preparation method thereof
US3076771A (en) Spinning solution containing n-substituted amide, polymer, and cellulose acetate

Legal Events

Date Code Title Description
PB01 Publication
PB01 Publication
SE01 Entry into force of request for substantive examination
SE01 Entry into force of request for substantive examination
GR01 Patent grant
GR01 Patent grant