CN106676329B - A kind of NiAl alloy epitaxy of doped rare earth element and its preparation method and application - Google Patents
A kind of NiAl alloy epitaxy of doped rare earth element and its preparation method and application Download PDFInfo
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- CN106676329B CN106676329B CN201611168447.5A CN201611168447A CN106676329B CN 106676329 B CN106676329 B CN 106676329B CN 201611168447 A CN201611168447 A CN 201611168447A CN 106676329 B CN106676329 B CN 106676329B
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- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C19/00—Alloys based on nickel or cobalt
- C22C19/007—Alloys based on nickel or cobalt with a light metal (alkali metal Li, Na, K, Rb, Cs; earth alkali metal Be, Mg, Ca, Sr, Ba, Al Ga, Ge, Ti) or B, Si, Zr, Hf, Sc, Y, lanthanides, actinides, as the next major constituent
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- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C1/00—Making non-ferrous alloys
- C22C1/02—Making non-ferrous alloys by melting
- C22C1/023—Alloys based on nickel
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- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C1/00—Making non-ferrous alloys
- C22C1/02—Making non-ferrous alloys by melting
- C22C1/026—Alloys based on aluminium
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- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C1/00—Making non-ferrous alloys
- C22C1/02—Making non-ferrous alloys by melting
- C22C1/03—Making non-ferrous alloys by melting using master alloys
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- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C21/00—Alloys based on aluminium
Abstract
The invention discloses a kind of NiAl alloy epitaxies of doped rare earth element, based on molar content, consisting of: Al:37.5%~50%;RE:0.01%~2%;Surplus is Ni.Preparation method of the invention includes vacuum hotpressing or microcast process.The invention also discloses the NiAl alloy epitaxies of doped rare earth element to prepare the application in glass hot-bending die.NiAl alloy epitaxy of the invention has excellent temperature-room type plasticity and high-temperature oxidation resistance.NiAl alloy epitaxy of the invention is used for glass hot-bending die field, and mechanical behavior under high temperature and antioxygenic property are excellent, and recyclable, can effectively improve the service life of glass bending mold.
Description
Technical field
The present invention relates to a kind of NiAl alloy epitaxy and its preparation method and application more particularly to a kind of NiAl of doped rare earth element
Alloy and preparation method thereof is preparing the application in glass hot-bending die with it.
Background technique
With the progress of industrial level and the increasingly raising of living standards of the people, single plate glass has been unable to meet people
Demand, pattern is beautiful, the lines flow smoothly, the heat-bending glass of using flexible is also more and more in the use of civilian occasion.Hot bending
Glass need to reach softening point at high temperature, and the product of precise measure is shaped under mold suppressing action.Glass bending mould is in height
It works in air under temperature, needs to be in contact with the melten glass that chemical activity is high, undergo the heating and cooling procedure of circulation, this
The harsh operating condition of kind has the antioxygenic property, wear Characteristics and chemical stability of glass hot-bending die higher
Requirement.Graphite is the material of glass hot-bending die common at present, and high-temperature oxidation resistance is poor, it is therefore desirable to be protected in nitrogen
The lower hot bending forming for carrying out glass of shield, higher operating costs;In addition, graphite jig not recoverable, service life is low, limitation
The production efficiency of glass bending technique;Graphite jig has limited the forming of heat-bending glass to low cost, high efficiency direction
Development.Thus, research and develop the novel glass that a kind of mechanical behavior under high temperature is excellent, high-temperature oxidation resistance is excellent, the service life is long, recyclable
Hot bending die is that situation is compeled with material.
NiAl alloy epitaxy is B2 structure, and long-range order, fusing point is 1638 DEG C, and operating temperature is up to 1250 DEG C, high-temperature oxidation resistant
Function admirable, mechanical behavior under high temperature is excellent, is a kind of potential glass hot-bending die material of tool.But the room temperature of NiAl alloy epitaxy
Plasticity is low, and temperature-room type plasticity is less than 1%, fracture toughness 3-5MPam0.5, limit the practical application of this kind of material.Therefore, right
NiAl intermetallic compound is modified, and further increasing its temperature-room type plasticity and high-temperature oxidation resistance becomes urgent need to resolve in the industry
Critical issue.
Preparing heterogeneous alloy is a kind of very effective method for improving NiAl alloy epitaxy temperature-room type plasticity: being added into alloy
Pseudoeutectic formation element such as Cr, Mo, can form pseudoeutectic tissue, to play plastication, but change to the elevated temperature strength of alloy
It is kind little, if Chinese patent CN200710176115.6, CN200710176120.7, CN200710176114.1 are in NiAl-Cr
(Mo) it is added to the elements such as Hf, Co, Nb in alloy and advanced optimizes alloying component, forms hardening constituent, the high temperature for improving alloy is strong
Degree.Fe and Co has larger solid solubility in NiAl, and a large amount of Fe and Co is added in NiAl alloy epitaxy, introduces plasticity in the alloy
Phase γ can improve Alloy At Room Temperature plasticity [Chinese patent CN200610165120.2], still to form B2+ γ eutectic structure
The addition of Fe element is so that the oxidation behaviors of NiAl alloy epitaxy complicate, antioxygen when being especially reduction of long under hot conditions
Change performance, the thickness of oxide layer has been thickened, so that oxide layer is easier to peel off.
La element is obviously improved plasticity effect to NiAl alloy epitaxy, and La can reduce gold as a kind of active element
Belong to the surface tension of liquid, the crystal grain of refining alloy, extension and polymerization for crackle have better inhibition, rich Ni's
After the La for adding 0.05wt.% in NiAl alloy epitaxy, the compression plasticity of alloy is improved to 29.7%, but La element exacerbates NiAl
The internal oxidition of alloy improves the oxidation weight gain of NiAl alloy epitaxy.
To sum up, the extensive concern that NiAl alloy epitaxy plasticity causes researcher in recent years is improved using alloying means.But
It is the elements such as Fe, Co, Cr, Mo, La, its mechanical behavior under high temperature can not be improved simultaneously while improving NiAl alloy epitaxy temperature-room type plasticity
Keep its excellent high-temperature oxidation resistance.Therefore find that a kind of pair of NiAl alloy epitaxy has plastication and not lose its high temperature anti-
The alloying element of oxidation susceptibility is needed for situation.
Summary of the invention
The technical problem to be solved by the present invention is to overcome the shortcomings of to mention in background above technology and defect, provide one
NiAl alloy epitaxy of kind doped rare earth element and preparation method thereof is preparing the application in glass hot-bending die with it.
In order to solve the above technical problems, technical solution proposed by the present invention are as follows:
A kind of NiAl alloy epitaxy of doped rare earth element, based on molar content, the composition of the NiAl alloy epitaxy are as follows:
Al:37.5%~50%;
RE:0.01%~2%;
Surplus is Ni.
Above-mentioned NiAl alloy epitaxy, it is preferred that the content of the Al is 40%-50%.
Above-mentioned NiAl alloy epitaxy, it is preferred that the content of the RE is 0.05%-1%.
Above-mentioned NiAl alloy epitaxy, it is preferred that the RE is one or both of Ce, Gd combination.
The inventive concept total as one, the present invention also provides a kind of preparation methods of above-mentioned NiAl alloy epitaxy, including with
Lower step: using Ni block, Al block and Al-RE intermediate alloy as raw material;Ni block is placed on crucible bottom, Al-RE intermediate alloy is put
On Ni block, Al block is placed on crucible top, carries out vacuum induction melting, smelting temperature is 1600-1800 DEG C to get arriving
NiAl alloy epitaxy.
Above-mentioned preparation method, it is preferred that smelting temperature is 1680-1730 DEG C.
The inventive concept total as one, the present invention also provides a kind of preparation methods of above-mentioned NiAl alloy epitaxy, including with
Lower step:
Using Ni powder, Al powder and Al-RE master alloyed powder as raw material, NiAl alloy epitaxy is prepared using vacuum hot-pressing, wherein
The process conditions of vacuum hotpressing are as follows: pressing pressure is 15~30MPa;Temperature curve are as follows: be first warming up to 200 DEG C of 1~3h of heat preservation;Again
It is warming up to 500 DEG C of 1~2h of heat preservation;It is warming up to 600 DEG C of 2~4h of heat preservation again, is continuously heating to 800 DEG C of 1~2h of heat preservation;Finally heat up
Furnace cooling after to 1200~1300 DEG C of heat preservation 2h.
Above-mentioned preparation method, it is preferred that pressing pressure 15MPa;Temperature curve are as follows: be first warming up to 200 DEG C of heat preservation 2h;
It is warming up to 500 DEG C of heat preservation 1h again;It is warming up to 600 DEG C of heat preservation 3h again, is continuously heating to 800 DEG C of heat preservation 1h;Finally it is warming up to 1250
DEG C heat preservation 2h after furnace cooling.
The inventive concept total as one, the present invention also provides a kind of above-mentioned NiAl alloy epitaxies to prepare glass hot-bending die
In application.
Above-mentioned application, it is preferred that glass hot-bending die is prepared using vacuum hotpressing or microcast process.
The present invention is added to rare earth element ce or/and Gd in NiAl alloy epitaxy, the high temperature of Ce or/and Gd to NiAl alloy epitaxy
Antioxygenic property tool improves significantly, one side Ce or/and Gd change the mechanism of mass transmission of element so that cation to
Based on interior diffusion, reduce the cavity between oxidation film/matrix, improves the binding force of oxidation film and parent metal, it is suppressed that oxygen
Change the peeling of film;On the other hand, Ce or/and Gd inhibits Al in NiAl alloy epitaxy surface film oxide2O3From metastable state turning to stable state
Become;In addition, Ce or/and Gd change the mechanical property of oxidation film, so that can accommodate in higher stress or film in film
Stress is preferably discharged.
The present invention is added to rare earth element ce or/and Gd in NiAl alloy epitaxy, Ce or/and the impurity such as Gd and O, S it is affine
Power is strong, has catharsis to alloy substrate, can improve the plasticity of NiAl alloy epitaxy;Rare earth element ce is enriched in grain boundaries, to crystal boundary
Invigoration effect is played, so that NiAl alloy epitaxy plasticity is improved;The addition of rare earth Gd is so that there is richness Gd phase, the phase in alloy
It is distributed in grain boundaries and crystal grain, invigoration effect not only is played to crystal boundary, and toughening effect is risen to alloy substrate.From microcosmic angle
Understanding, the charge density of intermetallic compound is anisotropic, so that the covalent bond even characteristic of ionic bond is presented in chemical bond,
Common free electron is not particularly suited for NiAl intermetallic compound in plastic metal or alloy;The change of chemical bond attribute, makes
Forming core and the sliding for obtaining dislocation are all very difficult, thus NiAl intermetallic compound is not easy to be plastically deformed, and has brittleness at room temperature;Ce
The chemical bond and electronic configuration that element changes NiAl intermetallic compound improve Fermi so that charge density is more uniform
The degree of order of intermetallic compound can and be reduced, so that charge density is more intended to isotropism, thus NiAl alloy epitaxy
Temperature-room type plasticity is improved.
Compared with the prior art, the advantages of the present invention are as follows:
(1) there is excellent temperature-room type plasticity and high-temperature oxidation resistance in NiAl alloy epitaxy of the invention.
(2) present invention prepares NiAl alloy epitaxy glass bending mold using hot investment casting, should compared with conventional melting and casting
Method is near-net-shape method, and subsequent machining processes are few, saves alloy raw material, can reduce being fabricated to for glass hot-bending die
This.
(3) present invention prepares NiAl alloy epitaxy glass bending mold using vacuum hotpressing, and this method is a kind of near-net-shape
Method, and product composition is uniform, crystal grain is small, can avoid macro-components segregation.
(4) NiAl alloy epitaxy of the invention is used for glass hot-bending die field, and mechanical behavior under high temperature and antioxygenic property are excellent
It is good and recyclable, the service life of glass bending mold can be effectively improved.
Detailed description of the invention
Fig. 1 is precision casting mold schematic diagram needed for preparing evagination NiAl glass hot-bending die.
Fig. 2 is precision casting mold schematic diagram needed for preparation indent NiAl glass hot-bending die.
Fig. 3 is vacuum hotpressing mold sections figure needed for powder metallurgy process prepares evagination NiAl glass hot-bending die.
Fig. 4 is vacuum hotpressing mold sections figure needed for powder metallurgy process prepares indent NiAl glass hot-bending die.
Specific embodiment
To facilitate the understanding of the present invention, invention herein is done below in conjunction with Figure of description and preferred embodiment more complete
Face meticulously describes, but protection scope of the present invention is not limited to following specific embodiments.
Unless otherwise defined, all technical terms used hereinafter are generally understood meaning phase with those skilled in the art
Together.Technical term used herein is intended merely to the purpose of description specific embodiment, and it is of the invention to be not intended to limitation
Protection scope.
Unless otherwise specified, various raw material, reagent, the instrument and equipment etc. used in the present invention can pass through city
Field is commercially available or can be prepared by existing method.
Embodiment 1:
A kind of NiAl alloy epitaxy of the invention includes: by mole composition
Al:50%;
Ce:0.05%;
Surplus is Ni.
The preparation method of the NiAl alloy epitaxy of the present embodiment, is prepared using vacuum induction melting, with Ni block, Al block and Al-Ce
Intermediate alloy is raw material, and Ni block is placed on crucible bottom, Al-Ce intermediate alloy is placed on Ni block, and Al block is placed on crucible
Top, carries out vacuum induction melting, and smelting temperature is 1700 DEG C to get the NiAl alloy epitaxy containing Ce for arriving the present embodiment.
Referring to table 1, table 1 is that the oxidation of alloy and Ni-50Al at 800 DEG C, 1000 DEG C, 1200 DEG C in the present embodiment increases
It compares again.
As shown in Table 1, in 800 DEG C, 1000 DEG C, 1200 DEG C of high-temperature oxidation test, the alloy of the present embodiment, oxidation
Film is strong with basal body binding force, no peeling, and oxide thickness is lower than Ni-50Al, this shows the NiAl alloy epitaxy of the present embodiment
High-temperature oxidation resistance is better than Ni-50Al alloy.
Referring to table 2, table 2 is that the alloy and Ni-50Al room-temperature tensile plasticity in the present embodiment compare.
As shown in Table 2, the alloy of the present embodiment, room-temperature tensile plasticity are higher than Ni-50Al at room temperature, this shows this reality
The NiAl alloy epitaxy for applying example has apparent advantage in terms of temperature-room type plasticity.
Thickness of oxidation film of the alloy and Ni-50Al (at.%) alloy of 1 embodiment 1 of table at 800 DEG C, 1000 DEG C, 1200 DEG C
Degree comparison
2 embodiment 1 of table and the room-temperature tensile plasticity of Ni-50Al (at.%) alloy compare
Alloying component | Room-temperature tensile plasticity/% |
Ni-50Al | 2.2 |
Embodiment 1 | 3.1 |
Embodiment 2:
The present embodiment provides a kind of NiAl alloy epitaxies containing rare earth Gd, include: by mole composition
Al:50%;
Gd:0.05%;
Surplus is Ni.
The preparation method of the present embodiment: using Ni powder, Al powder and Al-Gd master alloyed powder as raw material, using vacuum hotpressing side
Method preparation, uses the technique of vacuum hotpressing as follows: pressing pressure 15MPa;200 DEG C of heat preservation 2h;500 DEG C of heat preservation 1h;600 DEG C of guarantors
Furnace cooling is after warm 3h, 800 DEG C of heat preservations 1h, 1250 DEG C of heat preservation 2h to get the NiAl alloy epitaxy containing Gd for arriving the present embodiment.
Referring to table 3, table 3 is that the oxidation of alloy and Ni-50Al at 800 DEG C, 1000 DEG C, 1200 DEG C in the present embodiment increases
It compares again.
As shown in Table 3, in 800 DEG C, 1000 DEG C, 1200 DEG C of high-temperature oxidation test, the alloy of the present embodiment, oxidation
Film is strong with basal body binding force, no peeling, and oxide thickness is lower than Ni-50Al, this shows the NiAl alloy epitaxy of the present embodiment
High-temperature oxidation resistance is better than Ni-50Al alloy.
Referring to table 4, table 4 is that the alloy and Ni-50Al room-temperature tensile plasticity in the present embodiment compare.
As shown in Table 4, the alloy of the present embodiment, room-temperature tensile plasticity are higher than Ni-50Al at room temperature, this shows this reality
The NiAl alloy epitaxy for applying example has apparent advantage in terms of temperature-room type plasticity.
The oxide thickness comparison of 3 embodiment 2 of table and Ni-50Al (at.%) alloy at 800 DEG C, 1000 DEG C, 1200 DEG C
4 embodiment 2 of table and the room-temperature tensile plasticity of Ni-50Al (at.%) alloy compare
Alloying component | Room-temperature tensile plasticity/% |
Ni-50Al | 2.3 |
Embodiment 2 | 3.2 |
Embodiment 3
A kind of NiAl alloy epitaxy of the invention is preparing the application in glass hot-bending die, and NiAl glass hot-bending die is by indent
It is formed with two molds of evagination.The product is prepared using method of smelting, precision casting mold need to be used, such as Fig. 1 and Fig. 2 institute
Show, Fig. 1 is the schematic diagram to prepare the NiAl glass hot-bending die of evagination, and Fig. 1 is the NiAl glass heat to prepare indent
The schematic diagram of bending mould.Precision casting mold is prepared by graphite or steel, is divided into two parts by die joint.
The present embodiment prepares mold using smelting process, specific method:
(1) Ni block, Al block, Al-Ce intermediate alloy are subjected to smelting, prepare master alloy;
(2) master alloy for obtaining step (1) carries out vacuum induction melting;
(3) alloy melt that step (2) obtain is poured, using precision casting mold as shown in Figure 1 or 2;
Melt is poured into from dead head 1, flows through running channel 2, shapes, is cooled to room temperature into type chamber 3;
(4) precision casting mold is opened along die joint, takes out NiAl alloy epitaxy block;
(5) by step (4) obtain NiAl alloy epitaxy block carry out mechanical grinding polish to get arrive NiAl alloy epitaxy glass bending
Mold.
Embodiment 4:
A kind of NiAl alloy epitaxy of the invention is preparing the application in glass hot-bending die, and NiAl glass hot-bending die is by indent
It is formed with two molds of evagination.The product is prepared using powder metallurgy process, vacuum hotpressing mold need to be used, such as Fig. 3 and Fig. 4
Shown, vacuum hotpressing mold is graphite material, and vacuum hotpressing mold includes Your Majesty's stamping 4, auxiliary upper punch 5, former 6, auxiliary
Bottom punch (including 7-1 and 7-2), main bottom punch 8;Wherein 7-1 is boss, to prepare the NiAl glass hot-bending die of indent,
7-2 is concave station, to prepare the NiAl glass hot-bending die of evagination.
The present embodiment prepares mold using powder metallurgic method, specific method:
(1) above-mentioned powder is carried out in V-type batch mixer as raw material using Ni powder, Al powder and Al-Gd master alloyed powder
Mixing;
(2) former 6 of vacuum hotpressing mold, auxiliary bottom punch and main bottom punch 8 are assembled, step (1) is mixed
Powder be packed into wherein, by Your Majesty's stamping 4 and auxiliary upper punch 5 be put into former;
(3) it will be packed into vacuum hotpressing stove according to the vacuum hotpressing mold and powder that step (2) combine, and according to following work
Skill is sintered: pressing pressure is 15~30MPa;200 DEG C of 1~3h of heat preservation;500 DEG C of 1~2h of heat preservation;600 DEG C of 2~4h of heat preservation,
Furnace cooling after 800 DEG C of heat preservations 1~2h, 1200~1300 DEG C of heat preservation 2h;
(4) alloy block for obtaining step (3) carries out mechanical grinding and polishing to get the glass for arriving NiAl alloy epitaxy material
Hot bending die.
Claims (1)
1. a kind of NiAl alloy epitaxy of doped rare earth element is preparing the application in glass hot-bending die, which is characterized in that it is described mix it is dilute
The NiAl alloy epitaxy of earth elements, based on molar content, the composition of the NiAl alloy epitaxy are as follows: Al:50%;RE:0.05%;It is described
RE is one or both of Ce, Gd combination;Surplus is Ni;
The glass hot-bending die is made of two molds of indent and evagination, the glass hot-bending die using vacuum hotpressing or
Microcast process preparation;The detailed process that the vacuum hot-pressing prepares glass hot-bending die includes:
(1) above-mentioned powder is mixed in V-type batch mixer as raw material using Ni powder, Al powder and Al-RE master alloyed powder
It closes;
(2) former (6) of vacuum hotpressing mold, auxiliary bottom punch and main bottom punch (8) are assembled, step (1) is mixed
Powder be packed into wherein, by Your Majesty's stamping (4) and assist upper punch (5) be put into former;
(3) will be packed into vacuum hotpressing stove according to vacuum hotpressing mold and powder that step (2) combine, and according to following technique into
Row sintering: pressing pressure is 15~30MPa;200 DEG C of 1~3h of heat preservation;500 DEG C of 1~2h of heat preservation;600 DEG C of heat preservation 2~4h, 800 DEG C
Keep the temperature 1~2h, furnace cooling after 1200~1300 DEG C of heat preservation 2h;
(4) alloy block for obtaining step (3) carries out mechanical grinding and polishing to get the glass bending for arriving NiAl alloy epitaxy material
Mold;
The detailed process that the microcast process prepares glass hot-bending die includes:
(1) Ni block, Al block, Al-RE intermediate alloy are subjected to smelting, prepare master alloy;
(2) master alloy for obtaining step (1) carries out vacuum induction melting;
(3) alloy melt that step (2) obtain is poured into from precision casting mold dead head (1), running channel (2) is flowed through, into type
Chamber (3) forming, is cooled to room temperature;
(4) precision casting mold is opened along die joint, takes out NiAl alloy epitaxy block;
(5) by step (4) obtain NiAl alloy epitaxy block carry out mechanical grinding polish to get arrive NiAl alloy epitaxy glass bending mould
Tool.
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CN113430487B (en) * | 2021-06-23 | 2022-04-08 | 哈尔滨工业大学 | Forming preparation method of NiAl-based alloy thin-wall component containing V element |
Citations (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN101857925A (en) * | 2010-07-07 | 2010-10-13 | 哈尔滨工业大学 | Preparation method of ultrafine grained Ni-Al alloy |
CN104404348A (en) * | 2014-12-02 | 2015-03-11 | 湖南科技大学 | Nickel-aluminum-based alloy and preparation method thereof |
Family Cites Families (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN1211482A (en) * | 1998-07-17 | 1999-03-24 | 浙江大学 | Composite material of precast powder unit with penetration of Ni-Al flux and its preparation method |
CN103757451B (en) * | 2014-01-24 | 2016-03-02 | 南京理工大学 | A kind of high-purity smelting process of nickel base superalloy |
-
2016
- 2016-12-16 CN CN201611168447.5A patent/CN106676329B/en active Active
Patent Citations (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN101857925A (en) * | 2010-07-07 | 2010-10-13 | 哈尔滨工业大学 | Preparation method of ultrafine grained Ni-Al alloy |
CN104404348A (en) * | 2014-12-02 | 2015-03-11 | 湖南科技大学 | Nickel-aluminum-based alloy and preparation method thereof |
Non-Patent Citations (2)
Title |
---|
稀土元素Gd对NiAl合金显微组织和力学性能的影响;梁永纯等;《金属学报》;20080531;第44卷(第5期);第1节试验方法第1段 |
稀土元素在NiAl合金中的作用;郭建亭等;《金属学报》;20080531;第44卷(第5期);全文 |
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Effective date of registration: 20210629 Address after: 337000 Industrial Park B, Lianhua County, Pingxiang City, Jiangxi Province Patentee after: Jiangxi Yongtai Powder Metallurgy Co.,Ltd. Address before: 410000 Zuojialuo Mountain, Yuelu District, Changsha City, Hunan Province Patentee before: CENTRAL SOUTH University |
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