CN106675256A - Antibacterial paint - Google Patents

Antibacterial paint Download PDF

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Publication number
CN106675256A
CN106675256A CN201611119379.3A CN201611119379A CN106675256A CN 106675256 A CN106675256 A CN 106675256A CN 201611119379 A CN201611119379 A CN 201611119379A CN 106675256 A CN106675256 A CN 106675256A
Authority
CN
China
Prior art keywords
parts
mixed material
paint
antibiotic paint
preparation
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201611119379.3A
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Chinese (zh)
Inventor
陈洋
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
GAOZHOU MINGYANG CHEMICAL Co Ltd
Original Assignee
GAOZHOU MINGYANG CHEMICAL Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by GAOZHOU MINGYANG CHEMICAL Co Ltd filed Critical GAOZHOU MINGYANG CHEMICAL Co Ltd
Priority to CN201611119379.3A priority Critical patent/CN106675256A/en
Publication of CN106675256A publication Critical patent/CN106675256A/en
Pending legal-status Critical Current

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Classifications

    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D133/00Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Coating compositions based on derivatives of such polymers
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D5/00Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
    • C09D5/14Paints containing biocides, e.g. fungicides, insecticides or pesticides
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40Additives
    • C09D7/60Additives non-macromolecular
    • C09D7/61Additives non-macromolecular inorganic
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40Additives
    • C09D7/60Additives non-macromolecular
    • C09D7/63Additives non-macromolecular organic
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40Additives
    • C09D7/65Additives macromolecular
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00Polymer mixtures characterised by other features
    • C08L2205/03Polymer mixtures characterised by other features containing three or more polymers in a blend

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  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Wood Science & Technology (AREA)
  • Organic Chemistry (AREA)
  • Inorganic Chemistry (AREA)
  • Plant Pathology (AREA)
  • Agricultural Chemicals And Associated Chemicals (AREA)
  • Paints Or Removers (AREA)

Abstract

The invention discloses an antibacterial paint and a preparation method thereof, belonging to the field of building raw materials. The antibacterial paint is prepared from an acrylic polylol emulsion, a polyurethane emulsion, a sodium carboxymethyl cellulose solution, titanium white, a sulfonate defoaming agent, a thickener, a film former and deionized water. The antioxidation paint is prepared by the following steps: mixing, dispersing, heating, reacting and standing. The antioxidation paint has the advantages of accessible raw material sources and simple preparation method, and is a novel paint product.

Description

A kind of antibiotic paint
Technical field
The invention belongs to building material field, and in particular to a kind of antibiotic paint and preparation method thereof.
Background technology
Coating is to be coated in be protected or decorated body surface, and can form the continuous thin of firm attachment with coated article Film, generally based on resin, oily, emulsion form, can add the auxiliary agents such as pigment, filler, be commonly divided into water paint and oiliness Coating.Coating belongs to fine chemical product, with multiple efficacies such as decoration, anti-corrosion and waterproofs, is widely used in building decoration work Journey.
Water paint as species important in coating, with extensive market range of application.Every use water as solvent or Person makees the coating of disperse medium, all can be described as water paint.Water paint includes water soluble paint, water-reducible coating, moisture Scattered property coating(Latex paint)3 kinds.Water soluble paint is with water-soluble resin as film forming matter, with polyvinyl alcohol and its various modified Thing is representative, in addition also water-soluble alkyd resin, water-soluble epoxy resin and inorganic polymer water-base resin etc..Water paint Coating without organic solvent, without toxic heavy metals such as benzene,toluene,xylene, formaldehyde, free TDIs, has no irritating odor, And have that paint film is plentiful, smooth, various colors, it is durable, environmentally friendly many advantages, such as.With the enforcement of environmental protection policy, consumer's ring The continuous lifting of consciousness is protected, provinces and cities especially in all parts of the country have put into effect VOC emission limit standard, encourage using non-solvent coating, The undoubtedly development to environmental protection coating materials such as water paints brings opportunity.
As the range of application of coating type gradually increases, the coating with difference in functionality there is also large market and need Ask.Sapecial coating refers to the new coating for having essential distinction with traditional coating, and different sapecial coatings have different qualities.It is anti- Bacterium coating is exactly the one kind in sapecial coating.Antibiotic paint has biocidal efficacies, can protect coated thing breed bacteria, while Also the service life of coating is extended accordingly.
The content of the invention
It is an object of the invention to provide a kind of antibiotic paint, to lift the antibiotic property of coating.
In order to solve above technical problem, the present invention is employed the following technical solutions:A kind of antibiotic paint, with weight portion as list Position, comprising following raw material:300 ~ 600 parts of acrylic polyol emulsion, 150 ~ 350 parts of polyaminoester emulsion, sodium carboxymethyl cellulose 35 ~ 105 parts of solution, 15 ~ 45 parts of titanium dioxide, 10 ~ 20 parts of Sulfonateses defoamer, 8 ~ 24 parts of thickening agent, 11 ~ 30 parts of film former, 120 ~ 280 parts of deionized water.
The present invention also provides a kind of preparation method of antibiotic paint, comprises the following steps:
S1:Will be deionized water, Sulfonateses defoamer, acrylic polyol emulsion, polyaminoester emulsion, sodium carboxymethyl cellulose molten Liquid sequentially adds dispersion cylinder uniform stirring;
S2:Titanium dioxide, thickening agent, film former are sequentially added into mixed material uniform stirring obtained by step S1;
S3:Stirring reaction after mixed material obtained by step S2 is heated up;
S4:After mixed material obtained by step S3 stands, that is, antibiotic paint is obtained.
Preferably, in step S1, the mixing time of mixed material is 15 ~ 30min, and rotating speed is 300 ~ 500r/min.
Preferably, in step S2, mixed material mixing time is 40 ~ 70min, and rotating speed is 800 ~ 1200r/min.
Preferably, in step S3, the reaction temperature of mixed material is 40 ~ 60 DEG C, and the response time is 30 ~ 60min, stirs and turns Speed is 400 ~ 600r/min.
Beneficial effects of the present invention:The antibiotic paint constituent wide material sources of the present invention, manufacturing process are simple, using this The coating that inventive method is prepared from not only remains with the good characteristic of water paint, also because having containing sodium carboxymethyl cellulose There are antibacterial characteristics.
Specific embodiment
1 a kind of antibiotic paint of embodiment, in units of weight portion, comprising following raw material:Acrylic polyol emulsion 300 Part, 150 parts of polyaminoester emulsion, 35 parts of carboxymethylcellulose sodium solution, 15 parts of titanium dioxide, 10 parts of Sulfonateses defoamer, thickening 8 parts of agent, 11 parts of film former, 120 parts of deionized water.
The preparation method of the antibiotic paint, comprises the following steps:
S1:Will be deionized water, Sulfonateses defoamer, acrylic polyol emulsion, polyaminoester emulsion, sodium carboxymethyl cellulose molten Liquid sequentially adds dispersion cylinder and stirs 30min under the conditions of rotating speed 300r/min;
S2:Titanium dioxide, thickening agent, film former are sequentially added mixed material obtained by step S1 to stir under the conditions of rotating speed 800r/min Mix 70min;
S3:Mixed material obtained by step S2 is warming up to into 40 DEG C, stirring reaction 60min under the conditions of 400r/min;
S4:After mixed material obtained by step S3 stands, that is, antibiotic paint is obtained.
2 a kind of antibiotic paint of embodiment, in units of weight portion, comprising following raw material:Acrylic polyol emulsion 600 Part, 350 parts of polyaminoester emulsion, 60 parts of carboxymethylcellulose sodium solution, 45 parts of titanium dioxide, 20 parts of Sulfonateses defoamer, thickening 24 parts of agent, 30 parts of film former, 280 parts of deionized water.
The preparation method of the antibiotic paint, comprises the following steps:
S1:Will be deionized water, Sulfonateses defoamer, acrylic polyol emulsion, polyaminoester emulsion, sodium carboxymethyl cellulose molten Liquid sequentially adds dispersion cylinder and stirs 15min under the conditions of rotating speed 500r/min;
S2:Titanium dioxide, thickening agent, film former are sequentially added into mixed material obtained by step S1 under the conditions of rotating speed 1200r/min Stirring 40min;
S3:Mixed material obtained by step S2 is warming up to into 60 DEG C, stirring reaction 30min under the conditions of 600r/min;
S4:After mixed material obtained by step S3 stands, that is, antibiotic paint is obtained.
3 a kind of antibiotic paint of embodiment, in units of weight portion, comprising following raw material:Acrylic polyol emulsion 450 Part, 230 parts of polyaminoester emulsion, 105 parts of carboxymethylcellulose sodium solution, 30 parts of titanium dioxide, 15 parts of Sulfonateses defoamer, thickening 12 parts of agent, 21 parts of film former, 210 parts of deionized water.
The preparation method of the antibiotic paint, comprises the following steps:
S1:Will be deionized water, Sulfonateses defoamer, acrylic polyol emulsion, polyaminoester emulsion, sodium carboxymethyl cellulose molten Liquid sequentially adds dispersion cylinder and stirs 20min under the conditions of rotating speed 400r/min;
S2:Titanium dioxide, thickening agent, film former are sequentially added into mixed material obtained by step S1 under the conditions of rotating speed 1000r/min Stirring 50min;
S3:Mixed material obtained by step S2 is warming up to into 50 DEG C, stirring reaction 45min under the conditions of 500r/min;
S4:After mixed material obtained by step S3 stands, that is, antibiotic paint is obtained.
Above content it cannot be assumed that the present invention be embodied as be confined to these explanation, for belonging to the present invention technology neck For the those of ordinary skill in domain, without departing from the inventive concept of the premise, some simple deduction or replace can also be made, The scope of patent protection that the present invention is determined by the claims submitted to should be all considered as belonging to.

Claims (5)

1. a kind of antibiotic paint, it is characterised in that in units of weight portion, comprising following raw material:Acrylic polyol emulsion 300 ~ 600 parts, 150 ~ 350 parts of polyaminoester emulsion, 35 ~ 105 parts of carboxymethylcellulose sodium solution, 15 ~ 45 parts of titanium dioxide, Sulfonateses 10 ~ 20 parts of defoamer, 8 ~ 24 parts of thickening agent, 11 ~ 30 parts of film former, 120 ~ 280 parts of deionized water.
2. the preparation method of antibiotic paint according to claim 1, it is characterised in that comprise the following steps:
S1:Will be deionized water, Sulfonateses defoamer, acrylic polyol emulsion, polyaminoester emulsion, sodium carboxymethyl cellulose molten Liquid sequentially adds dispersion cylinder uniform stirring;
S2:Titanium dioxide, thickening agent, film former are sequentially added into mixed material uniform stirring obtained by step S1;
S3:Stirring reaction after mixed material obtained by step S2 is heated up;
S4:After mixed material obtained by step S3 stands, that is, antibiotic paint is obtained.
3. the preparation method of antibiotic paint according to claim 2, it is characterised in that the stirring of mixed material in step S1 Time is 15 ~ 30min, and rotating speed is 300 ~ 500r/min.
4. the preparation method of antibiotic paint according to claim 2, it is characterised in that when mixed material is stirred in step S2 Between be 40 ~ 70min, rotating speed be 800 ~ 1200r/min.
5. the preparation method of antibiotic paint according to claim 2, it is characterised in that the reaction of mixed material in step S3 Temperature is 40 ~ 60 DEG C, and the response time is 30 ~ 60min, and speed of agitator is 400 ~ 600r/min.
CN201611119379.3A 2016-12-08 2016-12-08 Antibacterial paint Pending CN106675256A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201611119379.3A CN106675256A (en) 2016-12-08 2016-12-08 Antibacterial paint

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201611119379.3A CN106675256A (en) 2016-12-08 2016-12-08 Antibacterial paint

Publications (1)

Publication Number Publication Date
CN106675256A true CN106675256A (en) 2017-05-17

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Family Applications (1)

Application Number Title Priority Date Filing Date
CN201611119379.3A Pending CN106675256A (en) 2016-12-08 2016-12-08 Antibacterial paint

Country Status (1)

Country Link
CN (1) CN106675256A (en)

Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101423691A (en) * 2008-12-23 2009-05-06 王诗榕 Waterborne nature antibacterial interior wall coating material and production method thereof

Patent Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101423691A (en) * 2008-12-23 2009-05-06 王诗榕 Waterborne nature antibacterial interior wall coating material and production method thereof

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Application publication date: 20170517

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