CN106675100A - Environment friendly active calcium carbonate - Google Patents
Environment friendly active calcium carbonate Download PDFInfo
- Publication number
- CN106675100A CN106675100A CN201510752439.4A CN201510752439A CN106675100A CN 106675100 A CN106675100 A CN 106675100A CN 201510752439 A CN201510752439 A CN 201510752439A CN 106675100 A CN106675100 A CN 106675100A
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- CN
- China
- Prior art keywords
- parts
- calcium carbonate
- environment friendly
- active calcium
- friendly active
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- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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Classifications
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09C—TREATMENT OF INORGANIC MATERIALS, OTHER THAN FIBROUS FILLERS, TO ENHANCE THEIR PIGMENTING OR FILLING PROPERTIES ; PREPARATION OF CARBON BLACK ; PREPARATION OF INORGANIC MATERIALS WHICH ARE NO SINGLE CHEMICAL COMPOUNDS AND WHICH ARE MAINLY USED AS PIGMENTS OR FILLERS
- C09C1/00—Treatment of specific inorganic materials other than fibrous fillers; Preparation of carbon black
- C09C1/02—Compounds of alkaline earth metals or magnesium
- C09C1/021—Calcium carbonates
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09C—TREATMENT OF INORGANIC MATERIALS, OTHER THAN FIBROUS FILLERS, TO ENHANCE THEIR PIGMENTING OR FILLING PROPERTIES ; PREPARATION OF CARBON BLACK ; PREPARATION OF INORGANIC MATERIALS WHICH ARE NO SINGLE CHEMICAL COMPOUNDS AND WHICH ARE MAINLY USED AS PIGMENTS OR FILLERS
- C09C3/00—Treatment in general of inorganic materials, other than fibrous fillers, to enhance their pigmenting or filling properties
- C09C3/006—Combinations of treatments provided for in groups C09C3/04 - C09C3/12
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
- C01P2006/00—Physical properties of inorganic compounds
- C01P2006/20—Powder free flowing behaviour
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
- C01P2006/00—Physical properties of inorganic compounds
- C01P2006/32—Thermal properties
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- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Compounds Of Alkaline-Earth Elements, Aluminum Or Rare-Earth Metals (AREA)
Abstract
The invention discloses environment friendly active calcium carbonate. The environment friendly active calcium carbonate comprises the following raw materials in parts by weight: 90-110 parts of calcium carbonate, 3-4 parts of polyethylene wax, 3-4 parts of benzoic acid, 1-3 parts of sodium sulfate, 1-1.5 parts of phenolic resin, 2-4 parts of polyether polyol, 5.5-6 parts of anilmomethyl triethoxy, 3-5 parts of copper stearate, 0.1-0.2 parts of sodium alginate, 0.5-2.5 parts of styrene, and a proper amount of deionized water. The formula of the environment friendly active calcium carbonate employs environment friendly and nontoxic raw materials, adds safe and nontoxic components, and uses a high-molecular polymer for greatly increasing the reinforcing, toughening, high temperature resistance and low cold resistance performances.
Description
Technical field
The present invention relates to calcium carbonate field, more particularly to a kind of environment-friendly active calcium carbonate.
Background technology
Calcium carbonate is a kind of highly important functional inorganic filling, be widely used in plastics, rubber,
The industrial circle such as coating and papermaking.In the application of calcium carbonate, most products belong to the category of polymer,
Such as plastics, rubber, adhesive, coating etc., and occupy the important market share..However, dispersant
With the addition of surface modifier so that nano-calcium carbonate temperature is diminished significantly using window, reason is conventional
Dispersant and coupling agent are easily decomposes at high temperature, cause bubble, cracking, defect, deformation etc., and not
Beneficial to environmental protection；Activated Calcium carbonate is with calcium carbonate as base-material, using polyfunctional surfactant and compound height
Effect processing aid, is modified activation process and forms to inorganic powder surface.Calcium carbonate after modified process
Powder, surface forms a kind of special cladding structure, can significantly improve in the polymer matrixs such as polyolefin
Dispersiveness and compatibility, and interface interaction can be produced and between polymer matrix, so as to improve the anti-impact of product
Hit intensity, is a kind of incremental filling additive of function admirable.
A kind of environment-friendly active calcium carbonate disclosed by the invention, it is obtained by the raw material of following weight parts：Carbonic acid
Calcium 90-110, Tissuemat E 3-4, benzoic acid 3-4, sodium sulphate 1-3, phenolic resin 1-1.5, polyethers are more
First alcohol 2-4, anilinomethyl triethoxy 5.5-6, copper stearate 3-5, sodium alginate 0.1-0.2, benzene second
Alkene 0.5-2.5, appropriate deionized water.Inventive formulation adopts environment-protecting asepsis raw material, adds safety non-toxic composition,
Product is set cold can all to improve a lot enhancing, toughness reinforcing, high temperature resistant are low with high molecular polymer.
The content of the invention
The technical solution adopted for the present invention to solve the technical problems is：A kind of environment-friendly active calcium carbonate, it is
It is obtained by the raw material of following weight parts：Calcium carbonate 90-110, Tissuemat E 3-4, benzoic acid 3-4, sulfuric acid
Sodium 1-3, phenolic resin 1-1.5, PPG 2-4, anilinomethyl triethoxy 5.5-6, stearic acid
Copper 3-5, sodium alginate 0.1-0.2, styrene 0.5-2.5, appropriate deionized water.
A kind of preparation method of environment-friendly active calcium carbonate of the present invention is comprised the following steps：
(1) calcium carbonate is added after homogenizer, adds Tissuemat E, benzoic acid, sodium sulphate, phenolic aldehyde
Resin, PPG, anilinomethyl triethoxy, copper stearate, sodium alginate, are warming up to 70-80 DEG C
Between stir, insulation 20-30 minutes after pour out.
(2) appropriate deionized water, stirring is added to form suspension and pour out the material poured out while hot；
(3) suspension is mixed with styrene, is stirred 20 minutes, dried, be ground into fine powder.
The invention has the beneficial effects as follows：Formula adopts environment-protecting asepsis raw material, adds safety non-toxic composition, with height
Molecularly Imprinted Polymer makes product cold can all improve a lot enhancing, toughness reinforcing, high temperature resistant are low.
Specific embodiment
Specific embodiment：A kind of environment-friendly active calcium carbonate, it is obtained by the raw material of following weight parts：Calcium carbonate
90-110, Tissuemat E 3-4, benzoic acid 3-4, sodium sulphate 1-3, phenolic resin 1-1.5, polyether polyols
Alcohol 2-4, anilinomethyl triethoxy 5.5-6, copper stearate 3-5, sodium alginate 0.1-0.2, styrene
0.5-2.5, appropriate deionized water.
A kind of preparation method of environment-friendly active calcium carbonate of the present invention is comprised the following steps：
(1) calcium carbonate is added after homogenizer, adds poly- Tissuemat E, benzoic acid, sodium sulphate, phenol
Urea formaldehyde, PPG, anilinomethyl triethoxy, copper stearate, sodium alginate, are warming up to 70-80 DEG C
Between stir, insulation 20-30 minutes after pour out.
(2) appropriate deionized water, stirring is added to form suspension and pour out the material poured out while hot；
(3) suspension is mixed with styrene, is stirred 20 minutes, dried, be ground into fine powder.
Inventive formulation adopts environment-protecting asepsis raw material, adds safety non-toxic composition, and with high molecular polymer product is made
Product cold can all improve a lot enhancing, toughness reinforcing, high temperature resistant are low.
Obviously, above-described embodiment is only intended to clearly illustrate example, and not to embodiment
Limit.For those of ordinary skill in the field, it can also be made on the basis of the above description
The change or variation of its multi-form.There is no need to be exhaustive to all of embodiment.And by
Among this obvious change extended out or variation are still in the protection domain of the invention.
Claims (2)
1. a kind of environment-friendly active calcium carbonate, it is characterised in that：It is obtained by the raw material of following weight parts：Carbonic acid
Calcium 90-110, Tissuemat E 3-4, benzoic acid 3-4, sodium sulphate 1-3, phenolic resin 1-1.5, polyethers are more
First alcohol 2-4, anilinomethyl triethoxy 5.5-6, copper stearate 3-5, sodium alginate 0.1-0.2, benzene second
Alkene 0.5-2.5, appropriate deionized water.
2. a kind of environment-friendly active calcium carbonate according to claim 1, it is characterised in that：Preparation method include with
Lower step：
(1) calcium carbonate is added after homogenizer, adds Tissuemat E, benzoic acid, sodium sulphate, phenolic aldehyde tree
Fat, PPG, anilinomethyl triethoxy, copper stearate, sodium alginate, be warming up to 70-80 DEG C it
Between stir, insulation 20-30 minutes after pour out.
(2) appropriate deionized water, stirring is added to form suspension and pour out the material poured out while hot；
(3) suspension is mixed with styrene, is stirred 20 minutes, dried, be ground into fine powder.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201510752439.4A CN106675100A (en) | 2015-11-05 | 2015-11-05 | Environment friendly active calcium carbonate |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201510752439.4A CN106675100A (en) | 2015-11-05 | 2015-11-05 | Environment friendly active calcium carbonate |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN106675100A true CN106675100A (en) | 2017-05-17 |
Family
ID=58863195
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201510752439.4A Pending CN106675100A (en) | 2015-11-05 | 2015-11-05 | Environment friendly active calcium carbonate |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN106675100A (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN112143257A (en) * | 2020-10-27 | 2020-12-29 | 池州市金隆钙业有限公司 | Environment-friendly active calcium carbonate and preparation method thereof |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103360680A (en) * | 2013-05-23 | 2013-10-23 | 建德市新裕塑胶材料有限公司 | Calcium carbonate filler master batch for polypropylene and polyethylene and preparation process thereof |
| CN103554704A (en) * | 2013-07-02 | 2014-02-05 | 安徽金阳电器科技发展有限责任公司 | Modified calcium carbonate for anti-ultraviolet electric cable material, and preparation method thereof |
| CN104910548A (en) * | 2015-05-28 | 2015-09-16 | 青阳县恒源化工原料有限责任公司 | Environmental protection shell powder active calcium carbonate |
-
2015
- 2015-11-05 CN CN201510752439.4A patent/CN106675100A/en active Pending
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103360680A (en) * | 2013-05-23 | 2013-10-23 | 建德市新裕塑胶材料有限公司 | Calcium carbonate filler master batch for polypropylene and polyethylene and preparation process thereof |
| CN103554704A (en) * | 2013-07-02 | 2014-02-05 | 安徽金阳电器科技发展有限责任公司 | Modified calcium carbonate for anti-ultraviolet electric cable material, and preparation method thereof |
| CN104910548A (en) * | 2015-05-28 | 2015-09-16 | 青阳县恒源化工原料有限责任公司 | Environmental protection shell powder active calcium carbonate |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN112143257A (en) * | 2020-10-27 | 2020-12-29 | 池州市金隆钙业有限公司 | Environment-friendly active calcium carbonate and preparation method thereof |
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| PB01 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| WD01 | Invention patent application deemed withdrawn after publication |
Application publication date: 20170517 |
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| WD01 | Invention patent application deemed withdrawn after publication |