CN106674962A - PC/ABS alloy with excellent thermal aging resistance and preparation method of PC/ABS alloy - Google Patents
PC/ABS alloy with excellent thermal aging resistance and preparation method of PC/ABS alloy Download PDFInfo
- Publication number
- CN106674962A CN106674962A CN201611189108.5A CN201611189108A CN106674962A CN 106674962 A CN106674962 A CN 106674962A CN 201611189108 A CN201611189108 A CN 201611189108A CN 106674962 A CN106674962 A CN 106674962A
- Authority
- CN
- China
- Prior art keywords
- abs
- heat aging
- aging performance
- parts
- performance according
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L69/00—Compositions of polycarbonates; Compositions of derivatives of polycarbonates
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/014—Additives containing two or more different additives of the same subgroup in C08K
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/08—Stabilised against heat, light or radiation or oxydation
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Injection Moulding Of Plastics Or The Like (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Abstract
The invention relates to the field of polymer materials, in particular to a PC/ABS alloy with excellent thermal aging resistance. The PC/ABS alloy is prepared from components in parts by weight as follows: 40-80 parts of PC, 20-50 parts of ABS, 2-10 parts of a flexibilizer, 0.1-1 part of a lubricating agent, 0.1-1 part of an antioxidant, 0.1-2 parts of epoxy resin and 0.1-2 parts of phosphate. Through addition of weak acid phosphate , the whole system is under a weak acid condition. Besides, PC is subjected to blocking through epoxy resin; the best use effect is realized after use through auxiliary matching, yellowing and impact of PC/ABS after long-term thermal storage experiments are avoided, so that the PC/ABS material can meet the requirement of long-term thermal aging at 100 DEG C for 1,000 h in a main engine factory of automobiles.
Description
Technical field
The present invention relates to polymeric material field, specifically, be a kind of excellent PC/ABS alloys of heat aging performance and
Its preparation method.
Background technology
Merlon/styrene-butadiene-acrylonitrile (PC/ABS) has excellent mechanical property, heat resistance etc., is
Widely used engineering plastics.In the basic conditions, PC can accelerate to degrade.
Chinese patent literature CN106046741A discloses a kind of high wet-heat resisting PC/ABS compositionss, by including following weight
The raw material of number is made：Merlon 30-85 parts, the step material 15-70 parts of ABS- toughener one, moisture-proof thermit powder 0.1-3 parts.Wherein,
The described step material of ABS- toughener one is made up of the raw material including following parts by weight：ABS50-80 parts, toughener 20-50 parts.
The patent improves the wet-hot aging performance of PC/ABS using PEP-36.But, PEP-36 has under conditions of 85 DEG C of 85% humidity
Effect well.But, in the long term heat ageing performance of 100 degree of 1000h, do not explain.
Chinese patent literature CN104927337A discloses a kind of wet and heat ageing resistant, high PU foams bond strength PC/ABS material
Material, described PC/ABS materials are prepared from by following component and content：Merlon 60-80 parts, response type compatilizer 0.1-3
Part, ABS 10-30 parts, PU foam bonding agent 0.2-10 parts, acrylic graft-modified type siloxane toughener 0.1-20 parts, antioxygen
Agent 0.1-3 parts.70 DEG C of 95% humidity aged property that the patent improves PC/ABS using the compatilizer with ethylene oxide group
Energy.But, evaluation of the Acidity of Aikalinity to PC/ABS long term heat ageing performances is not considered in system.
The content of the invention
It is an object of the invention to prevent PC/ABS from easily degrading under alkaline environment, adding by faintly acid phosphate ester
Enter, make whole system in solutions of weak acidity, PC is blocked additionally by epoxy resin；Both are auxiliary with reaching most after use
Good using effect, it is to avoid xanthochromia and impact that PC/ABS occurs after long term thermal deposits experiment.Enable PC/ABS materials
Meet the requirement of the long-term 100 degree of 1000h heat ageings of automobile main frame maker.
A first aspect of the present invention, there is provided the excellent PC/ABS alloys of a kind of heat aging performance, by following component by as follows
Weight portion is constituted：
Wherein,
Described PC (Merlon) is the bisphenol A polycarbonate that weight average molecular weight is 17000~30000g/mol, its
Vitrification point is 145~150 DEG C.It is preferred that PC molecular weight is 23000g/mol.L-1225Y, Tao Shi are produced in optional Supreme Being people's chemical conversion
PC-201-10, Hunan petrochemical industry PC-1100, PC-1220, Cohan wound PC 2600, PC 2400, the PC- for preferably being created with Cohan
2600。
Described ABS (acrylonitrile-butadiene-styrene copolymer) resinoid is substance law ABS material.Weight average molecular weight
For 80000~150000g/mol.The content of its butadiene is not in that butadiene is not coated by SAN between 18~30%
Problem, significantly improves the heat aging performance of PC/ABS.Described ABS include account for gross weight weight percent content be 5~
30% rubber, 10~30% acrylonitrile, 40~70% styrene, can select Korea Gumho Petrochemical Co., Ltd.
ABS P/D150, ABS P/D190, ABS8391, ABS8434 of Gaoqiao Petrochemical Company and the GP-22 of benzene neck；It is preferred that the GP-22 of benzene neck.
Described epoxy resin is selected from Dow DER330, three well R-140 and South Asia epoxy NPES 907.It is preferred that epoxy content
For the Dow DER330 of 182~192g/eq.
Described phosphate ester is triphenyl phosphite, sodium dihydrogen phosphate and sodium dihydrogen phosphite.It is preferred that weakly acidic phosphorous
Triphenyl phosphate ester.
Described toughener be s-B-S (SBS), ABS high glue powders, polyurethane elastomer, ethylene-
Methylmethacrylate copolymer (EMA), ethylene-methyl methacrylate acrylate copolymer (EBA), polyolefin elastomer, nucleocapsid knot
The silicone rubber or MBS (MBS) of structure.It is preferred that MBS.
Preferably, the particle diameter of described toughener is 50~700nm, and glue content is 40wt%~90wt%, can select and produces
EXL-2620, EXL-2330 of M521, ROHM AND HAAS in EM500, Zhong Yuan of LG；Wherein EM500, M521, EXL-2620 are equal
For MBS (MBS), EXL-2330 belongs to methyl methacrylate/acrylic acid class
Polymer (ACR)；It is preferred that the EXL-2620 of ROHM AND HAAS.
The antioxidant be phosphite antioxidant 168, phosphite antioxidant S-9228, hindered phenol antioxygen 1010,
One or two in hindered phenol antioxygen 1098, hindered phenol antioxygen 1076.The antioxidant of optional CIBA companies production
1098th, antioxidant 1010, antioxidant 1076 and irgasfos 168, the S-9228 of Dover companies.Preferably macromolecule phosphorous acid
The mixing of ester antioxidant S-9228 and hindered phenol antioxygen 1098.
Described lubricant is one or more in silicone powder, pentaerythritol ester (PETS), ethylene bis stearic amide.It is excellent
Select pentaerythritol ester.
A second aspect of the present invention, there is provided the preparation method of the excellent PC/ABS alloys of above-mentioned heat aging performance, including with
Lower step：
S1, according to weight preparation raw material, raw material mix homogeneously is made in input premixed device, and protect after being heated to 60 DEG C
Temperature 15 minutes, obtains premix material；
S2, the premix material for obtaining step S1 are added in double screw extruder, and simultaneously pelletizing obtains PC/ABS composite woods to extrusion
Material, wherein the barrel rotating speed of double screw extruder are 15-35rpm, and barrel temperature is 220-270 DEG C；
S3, by PC/ABS composites obtained in step S2 through injection moulding finished product.
Prior art adopts emulsion method ABS material as the PC/ABS of raw material, and after 100 degree of 1000h, yellowness index reaches
6, impact property reduces by 60%.And the addition that the present invention passes through phosphate ester so that whole PC/ABS systems are in solutions of weak acidity
Under, the degraded of PC will not be promoted；In addition, blocking to PC by epoxy resin, the degraded of PC is further prevented, both have
Have good auxiliary with effect, its yellowness index only has 2, and impact property only reduces by 15%, meets Ge great automobile main frame maker
Requirement.
Specific embodiment
The specific embodiment that the present invention is provided is elaborated with reference to embodiment.
In following each embodiment and comparative example, each raw material adopts following compositions：
From PC be Cohan wound PC-2600；
From body ABS for benzene neck GP-22；
From emulsion method ABS for Korea Jin Hu HR-181；
From toughener for ROHM AND HAAS EXL-2620；
From antioxidant for CIBA companies antioxidant 1098, the S-9228 of Dover companies；
From lubricant be pentaerythritol ester (PETS)；
From epoxy resin be Dow DER330；
From phosphate ester for Suning's chemical industry triphenyl phosphite；
From the AS117C strange beautiful polystyrene-acrylonitriles that are；
From PEP-36 be double (2,6- di-t-butyl -4- aminomethyl phenyls) pentaerythritol diphosphates；
From EMA-g-GMA for Hangzhou sea one EPA-810, GMA contents therein be 5%.
Embodiment 1
S1, according to the weight preparation raw material of table 1, make raw material mix homogeneously in input premixed device, and be heated to 60 DEG C
Afterwards 15 minutes are incubated, obtain premix material；
S2, the premix material for obtaining step S1 are added in double screw extruder, and simultaneously pelletizing obtains PC/ABS composite woods to extrusion
Material, wherein the barrel rotating speed of double screw extruder are 35rpm, and barrel temperature is 220 DEG C；
S3, by PC/ABS composites obtained in step S2 through injection moulding finished product.
Embodiment 2
S1, according to the weight preparation raw material of table 1, make raw material mix homogeneously in input premixed device, and be heated to 60 DEG C
Afterwards 15 minutes are incubated, obtain premix material；
S2, the premix material for obtaining step S1 are added in double screw extruder, and simultaneously pelletizing obtains PC/ABS composite woods to extrusion
Material, wherein the barrel rotating speed of double screw extruder are 15rpm, and barrel temperature is 230 DEG C；
S3, by PC/ABS composites obtained in step S2 through injection moulding finished product.
Embodiment 3
S1, according to the weight preparation raw material of table 1, make raw material mix homogeneously in input premixed device, and be heated to 60 DEG C
Afterwards 15 minutes are incubated, obtain premix material；
S2, the premix material for obtaining step S1 are added in double screw extruder, and simultaneously pelletizing obtains PC/ABS composite woods to extrusion
Material, wherein the barrel rotating speed of double screw extruder are 20rpm, and barrel temperature is 240 DEG C；
S3, by PC/ABS composites obtained in step S2 through injection moulding finished product.
Embodiment 4
S1, according to the weight preparation raw material of table 1, make raw material mix homogeneously in input premixed device, and be heated to 60 DEG C
Afterwards 15 minutes are incubated, obtain premix material；
S2, the premix material for obtaining step S1 are added in double screw extruder, and simultaneously pelletizing obtains PC/ABS composite woods to extrusion
Material, wherein the barrel rotating speed of double screw extruder are 30rpm, and barrel temperature is 250 DEG C；
S3, by PC/ABS composites obtained in step S2 through injection moulding finished product.
Embodiment 5
S1, according to the weight preparation raw material of table 2, make raw material mix homogeneously in input premixed device, and be heated to 60 DEG C
Afterwards 15 minutes are incubated, obtain premix material；
S2, the premix material for obtaining step S1 are added in double screw extruder, and simultaneously pelletizing obtains PC/ABS composite woods to extrusion
Material, wherein the barrel rotating speed of double screw extruder are 30rpm, and barrel temperature is 260 DEG C；
S3, by PC/ABS composites obtained in step S2 through injection moulding finished product.
Embodiment 6
S1, according to the weight preparation raw material of table 2, make raw material mix homogeneously in input premixed device, and be heated to 60 DEG C
Afterwards 15 minutes are incubated, obtain premix material；
S2, the premix material for obtaining step S1 are added in double screw extruder, and simultaneously pelletizing obtains PC/ABS composite woods to extrusion
Material, wherein the barrel rotating speed of double screw extruder are 30rpm, and barrel temperature is 270 DEG C；
S3, by PC/ABS composites obtained in step S2 through injection moulding finished product.
Embodiment 7
S1, according to the weight preparation raw material of table 2, make raw material mix homogeneously in input premixed device, and be heated to 60 DEG C
Afterwards 15 minutes are incubated, obtain premix material；
S2, the premix material for obtaining step S1 are added in double screw extruder, and simultaneously pelletizing obtains PC/ABS composite woods to extrusion
Material, wherein the barrel rotating speed of double screw extruder are 30rpm, and barrel temperature is 250 DEG C；
S3, by PC/ABS composites obtained in step S2 through injection moulding finished product.
Embodiment 8
S1, according to the weight preparation raw material of table 1, make raw material mix homogeneously in input premixed device, and be heated to 60 DEG C
Afterwards 15 minutes are incubated, obtain premix material；
S2, the premix material for obtaining step S1 are added in double screw extruder, and simultaneously pelletizing obtains PC/ABS composite woods to extrusion
Material, wherein the barrel rotating speed of double screw extruder are 30rpm, and barrel temperature is 240 DEG C；
S3, by PC/ABS composites obtained in step S2 through injection moulding finished product.
Comparative example 1-3
S1, according to the weight preparation raw material of table 1, make raw material mix homogeneously in input premixed device, and be heated to 60 DEG C
Afterwards 15 minutes are incubated, obtain premix material；
S2, the premix material for obtaining step S1 are added in double screw extruder, and simultaneously pelletizing obtains PC/ABS composite woods to extrusion
Material, wherein the barrel rotating speed of double screw extruder are 30rpm, and barrel temperature is 240 DEG C；
S3, by PC/ABS composites obtained in step S2 through injection moulding finished product.
The component and proportioning of comparative example 1-3 of table 1 and embodiment 1-4
The component and proportioning of embodiment 5-8 of table 2
| Formula (is calculated in parts by weight) | Embodiment 5 | Embodiment 6 | Embodiment 7 | Embodiment 8 |
| PC 2600 | 60 | 60 | 60 | 60 |
| GP22 | 35.9 | |||
| HR-181 | 17 | 17 | 17 | |
| EXL 2620 | 3 | 3 | 3 | 3 |
| AS 117C | 19.2 | 19.1 | 19.0 | |
| 1098 | 0.2 | 0.2 | 0.2 | 0.2 |
| S-9228 | 0.2 | 0.2 | 0.2 | 0.2 |
| PETS | 0.3 | 0.3 | 0.3 | 0.3 |
| Dow DER330 | 0.2 | |||
| Triphenyl phosphite | 0.1 | 0.2 | 0.3 | 0.2 |
| EPA-810 |
The evaluation of implementation result
The sample that above-described embodiment and comparative example are obtained is carried out into dependence test, test result is as shown in table 3 below and table 4：
The test result of comparative example 1-3 of table 1 and embodiment 1-4
The test result of embodiment 5-8 of table 2
From the point of view of comparative example 1 and embodiment 1, using body ABS GP22 than emulsion method ABS HR-181, heat aging performance
Have a very significant increase, be primarily due to the butadiene content of body ABS between 18-22%, and emulsion method ABS HR-181
Butadiene content about 50-60%.Due to the glue content of GP22 it is relatively low, so it is well by SAN
Cladding, so heat aging property is preferable.From the point of view of embodiment 1~4, by the addition of epoxy resin, can significantly increase
Heat aging property, but whole system or meta-alkalescence.From the point of view of embodiment 5~7, triphenyl phosphite is added so that whole
Individual system can prevent the degraded of PC in acidity.In addition, can see from embodiment 3,6,8, by epoxy resin and phosphorous acid
The auxiliary of triphenylmethyl methacrylate is matched somebody with somebody, and can significantly improve the down ratio of impact strength, and in addition yellowness index also can be reduced significantly.
Below the preferred embodiment to the invention is illustrated, but the invention be not limited to it is described
Embodiment, those of ordinary skill in the art can also make a variety of equivalents on the premise of without prejudice to the invention spirit
Modification or replacement, the modification of these equivalents or replacement are all contained in the application claim limited range.
Claims (9)
1. excellent PC/ABS alloys of a kind of heat aging performance, it is characterised in that be made up of by following weight portion following component：
Wherein, described ABS is substance law ABS material；Described epoxy resin is ring that epoxy content is 182~192g/eq
Oxygen tree fat；Described phosphate ester is triphenyl phosphite, sodium dihydrogen phosphate or sodium dihydrogen phosphite.
2. excellent PC/ABS alloys of heat aging performance according to claim 1, it is characterised in that described PC attaches most importance to
Molecular weight is the bisphenol A polycarbonate of 17000~30000g/mol, and its vitrification point is 145~150 DEG C.
3. excellent PC/ABS alloys of heat aging performance according to claim 1, it is characterised in that described ABS weights are equal
Molecular weight is 80000~150000g/mol.
4. excellent PC/ABS alloys of heat aging performance according to claim 1, it is characterised in that described epoxy resin
One kind selected from Dow DER330, in three well R-140 or South Asia epoxy NPES 907.
5. excellent PC/ABS alloys of heat aging performance according to claim 1, it is characterised in that described toughener choosing
From s-B-S, ABS high glue powders, polyurethane elastomer, ethylene methyl methacrylate copolymer, ethylene-
Butyl methacrylate copolymer, polyolefin elastomer, the silicone rubber or methyl methacrylate-butadiene-benzene of nucleocapsid structure
One kind in ethylene.
6. excellent PC/ABS alloys of heat aging performance according to claim 1, it is characterised in that described toughener
Particle diameter is 50~700nm, and glue content is 40wt%~90wt%.
7. excellent PC/ABS alloys of heat aging performance according to claim 1, it is characterised in that the antioxidant is Asia
Phosphate ester irgasfos 168, phosphite antioxidant S-9228, hindered phenol antioxygen 1010, hindered phenol antioxygen 1098, hindered phenol
One or two in antioxidant 1076.
8. excellent PC/ABS alloys of heat aging performance according to claim 1, it is characterised in that described lubricant is
One or more in silicone powder, pentaerythritol ester, ethylene bis stearic amide.
9. the preparation method of the excellent PC/ABS alloys of a kind of heat aging performance as described in claim 1-8 is arbitrary, its feature
It is to comprise the following steps：
S1, according to weight preparation raw material, make raw material mix homogeneously in input premixed device, and 15 are incubated after being heated to 60 DEG C
Minute, obtain premix material；
S2, the premix material for obtaining step S1 are added in double screw extruder, and simultaneously pelletizing obtains PC/ABS composites to extrusion, its
The barrel rotating speed of middle double screw extruder is 15-35rpm, and barrel temperature is 220-270 DEG C；
S3, by PC/ABS composites obtained in step S2 through injection moulding finished product.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201611189108.5A CN106674962B (en) | 2016-12-21 | 2016-12-21 | A kind of PC/ABS alloy and preparation method thereof that heat aging performance is excellent |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201611189108.5A CN106674962B (en) | 2016-12-21 | 2016-12-21 | A kind of PC/ABS alloy and preparation method thereof that heat aging performance is excellent |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN106674962A true CN106674962A (en) | 2017-05-17 |
| CN106674962B CN106674962B (en) | 2019-05-10 |
Family
ID=58870800
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201611189108.5A Active CN106674962B (en) | 2016-12-21 | 2016-12-21 | A kind of PC/ABS alloy and preparation method thereof that heat aging performance is excellent |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN106674962B (en) |
Cited By (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN109206878A (en) * | 2018-07-27 | 2019-01-15 | 会通新材料股份有限公司 | A kind of household electrical appliances anti-deformation polycarbonate composite material and preparation method thereof |
| CN109825056A (en) * | 2019-01-21 | 2019-05-31 | 金发科技股份有限公司 | A kind of polycarbonate alloy and preparation method thereof |
| CN111117184A (en) * | 2019-12-17 | 2020-05-08 | 中广核俊尔(浙江)新材料有限公司 | High-temperature and high-humidity resistant flame-retardant PC plastic and preparation method and application thereof |
| CN111138796A (en) * | 2019-12-26 | 2020-05-12 | 苏州润佳高分子材料有限公司 | Modified ABS material for automobile |
| CN111349330A (en) * | 2020-03-26 | 2020-06-30 | 上海长伟锦磁工程塑料有限公司 | PC/ABS alloy with stable performance after injection molding and preparation method thereof |
| CN111363294A (en) * | 2020-02-18 | 2020-07-03 | 东莞市高能高分子材料有限公司 | Anti-aging PC-ABS alloy material and preparation method thereof |
| CN112280274A (en) * | 2020-11-05 | 2021-01-29 | 宁波科德新能源科技有限公司 | High-toughness PC/ABS material and preparation method thereof |
| CN113736240A (en) * | 2021-08-17 | 2021-12-03 | 金发科技股份有限公司 | High-toughness flame-retardant polycarbonate alloy composition and preparation method and application thereof |
| WO2022095362A1 (en) * | 2020-11-06 | 2022-05-12 | 金发科技股份有限公司 | Pcabs composition, preparation method therefor, and application thereof |
Citations (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101003670A (en) * | 2006-01-20 | 2007-07-25 | 佛山市顺德区汉达精密电子科技有限公司 | High flexible flame retardant PC(polycarbonate)/ABS alloy |
| JP2008069356A (en) * | 2007-10-01 | 2008-03-27 | Sabic Innovative Plastics Japan Kk | Flame-retardant resin composition and its molded article |
| CN103709710A (en) * | 2013-12-25 | 2014-04-09 | 青岛润兴塑料新材料有限公司 | PC/ABS (polycarbonate/acrylonitrile-butadiene-styrene) alloy material with excellent working properties and preparation method thereof |
| CN104017343A (en) * | 2013-03-01 | 2014-09-03 | 上海杰事杰新材料(集团)股份有限公司 | Phosphate flame-retardant PC/ABS (polycarbonate/acrylonitrile-butadiene-styrene) alloy and preparation method thereof |
| CN104845306A (en) * | 2014-11-19 | 2015-08-19 | 青岛同创节能环保工程有限公司 | Anti-aging reinforcing polycarbonate alloy and preparation method thereof |
| CN104927337A (en) * | 2015-07-15 | 2015-09-23 | 上海锦湖日丽塑料有限公司 | PC/ABS material with hygrothermal aging resistance and high PU foam bonding strength |
| CN106084623A (en) * | 2016-06-23 | 2016-11-09 | 吴国庆 | A kind of environmental protection shock resistance PC/ABS plastic alloy and preparation method thereof |
| CN106221171A (en) * | 2016-08-18 | 2016-12-14 | 江苏金发科技新材料有限公司 | High-weatherability fire retardation PC/ABS composite material and preparation method thereof |
-
2016
- 2016-12-21 CN CN201611189108.5A patent/CN106674962B/en active Active
Patent Citations (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101003670A (en) * | 2006-01-20 | 2007-07-25 | 佛山市顺德区汉达精密电子科技有限公司 | High flexible flame retardant PC(polycarbonate)/ABS alloy |
| JP2008069356A (en) * | 2007-10-01 | 2008-03-27 | Sabic Innovative Plastics Japan Kk | Flame-retardant resin composition and its molded article |
| CN104017343A (en) * | 2013-03-01 | 2014-09-03 | 上海杰事杰新材料(集团)股份有限公司 | Phosphate flame-retardant PC/ABS (polycarbonate/acrylonitrile-butadiene-styrene) alloy and preparation method thereof |
| CN103709710A (en) * | 2013-12-25 | 2014-04-09 | 青岛润兴塑料新材料有限公司 | PC/ABS (polycarbonate/acrylonitrile-butadiene-styrene) alloy material with excellent working properties and preparation method thereof |
| CN104845306A (en) * | 2014-11-19 | 2015-08-19 | 青岛同创节能环保工程有限公司 | Anti-aging reinforcing polycarbonate alloy and preparation method thereof |
| CN104927337A (en) * | 2015-07-15 | 2015-09-23 | 上海锦湖日丽塑料有限公司 | PC/ABS material with hygrothermal aging resistance and high PU foam bonding strength |
| CN106084623A (en) * | 2016-06-23 | 2016-11-09 | 吴国庆 | A kind of environmental protection shock resistance PC/ABS plastic alloy and preparation method thereof |
| CN106221171A (en) * | 2016-08-18 | 2016-12-14 | 江苏金发科技新材料有限公司 | High-weatherability fire retardation PC/ABS composite material and preparation method thereof |
Non-Patent Citations (1)
| Title |
|---|
| 马之庚: "《工程塑料手册》", 31 October 2004, 机械工业出版社 * |
Cited By (12)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN109206878A (en) * | 2018-07-27 | 2019-01-15 | 会通新材料股份有限公司 | A kind of household electrical appliances anti-deformation polycarbonate composite material and preparation method thereof |
| CN109825056A (en) * | 2019-01-21 | 2019-05-31 | 金发科技股份有限公司 | A kind of polycarbonate alloy and preparation method thereof |
| WO2020151553A1 (en) * | 2019-01-21 | 2020-07-30 | 金发科技股份有限公司 | Polycarbonate alloy and preparation method therefor |
| CN109825056B (en) * | 2019-01-21 | 2022-07-19 | 金发科技股份有限公司 | Polycarbonate alloy and preparation method thereof |
| CN111117184A (en) * | 2019-12-17 | 2020-05-08 | 中广核俊尔(浙江)新材料有限公司 | High-temperature and high-humidity resistant flame-retardant PC plastic and preparation method and application thereof |
| CN111138796A (en) * | 2019-12-26 | 2020-05-12 | 苏州润佳高分子材料有限公司 | Modified ABS material for automobile |
| CN111363294A (en) * | 2020-02-18 | 2020-07-03 | 东莞市高能高分子材料有限公司 | Anti-aging PC-ABS alloy material and preparation method thereof |
| CN111349330A (en) * | 2020-03-26 | 2020-06-30 | 上海长伟锦磁工程塑料有限公司 | PC/ABS alloy with stable performance after injection molding and preparation method thereof |
| CN112280274A (en) * | 2020-11-05 | 2021-01-29 | 宁波科德新能源科技有限公司 | High-toughness PC/ABS material and preparation method thereof |
| WO2022095362A1 (en) * | 2020-11-06 | 2022-05-12 | 金发科技股份有限公司 | Pcabs composition, preparation method therefor, and application thereof |
| CN113736240A (en) * | 2021-08-17 | 2021-12-03 | 金发科技股份有限公司 | High-toughness flame-retardant polycarbonate alloy composition and preparation method and application thereof |
| WO2023020413A1 (en) * | 2021-08-17 | 2023-02-23 | 金发科技股份有限公司 | High-toughness flame-retardant polycarbonate alloy composition, and preparation method therefor and application thereof |
Also Published As
| Publication number | Publication date |
|---|---|
| CN106674962B (en) | 2019-05-10 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN106674962A (en) | PC/ABS alloy with excellent thermal aging resistance and preparation method of PC/ABS alloy | |
| US11186712B2 (en) | Ultralow-glossiness, ultralow-temperature resistant ASA resin composition and preparation method thereof | |
| CN107674396B (en) | A kind of ultralow gloss, high durable, scratch resistance PC/ABS alloy and preparation method thereof | |
| CN102399424A (en) | Polycarbonate/acrylonitrile-styrene-acrylate copolymer alloy material and preparation method thereof | |
| CN103467912A (en) | High flexibility epoxy resin composition | |
| CN107163486A (en) | A kind of ultra-toughness, resistance to braking fluid ABS/PBT alloy materials and preparation method thereof | |
| CN107118534B (en) | A kind of PC/ABS alloy and preparation method thereof that resistance to automotive paints cracking performance is excellent | |
| CN106317668B (en) | A kind of acrylate resin composition and preparation method thereof of high petrol-resistance | |
| CN107353617A (en) | PC/ABS alloys with anti-acoustic capability and preparation method thereof | |
| CN102051034B (en) | Polycarbonate composite with low gloss and high heat resistance | |
| CN109337302A (en) | A kind of ultralow warpage high impact resistance fiberglass enhancing PBT/PC/ABS ternary-alloy material and preparation method | |
| CN105153671B (en) | A kind of PC/ASA alloy materials of excellent in low temperature toughness and preparation method thereof | |
| CN102492268A (en) | Alkali resistance glass fiber reinforced thermoplasticity polyester composite material and preparation method thereof | |
| CN107177156A (en) | A kind of high-damping noise reduction ABS resin composition | |
| CN111484722A (en) | High-impact-resistance flame-retardant reinforced PC/ABS alloy material and preparation method thereof | |
| US12018148B2 (en) | Ultralow-gloss PC/ABS resin composition and preparation method thereof | |
| CN103030962A (en) | High weather-proofing and heat and humidity resistant PC/ABS blending material and preparation method thereof | |
| CN107955359B (en) | High-strength permanent antistatic PC/ASA alloy and preparation method thereof | |
| CN103483795A (en) | PC/ASA (polycarbonate/acrylonitrile-styrene-acrylate) composition with improved hardness and cold resistance | |
| CN103396643A (en) | Modifier-containing polyacrylate grafted vinyl chloride composite resin composition | |
| CN103834115A (en) | Glass fiber reinforced fire retardation styrene-acrylonitrile material and preparation method thereof | |
| KR20170063159A (en) | Polybutyleneterephthalate Resin Composition and Moded Article Produed with the Same | |
| KR101506766B1 (en) | Polycarbonate resin composition for non coating parts | |
| CN111138823A (en) | Noise-reduction permanent antistatic polycarbonate styrene resin alloy and preparation method thereof | |
| CN111647260A (en) | PC/ABS alloy for tail lamp housing and preparation method thereof |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PB01 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| TA01 | Transfer of patent application right |
Effective date of registration: 20180827 Address after: 200444 228 yuan Guang road, Baoshan District, Shanghai. Applicant after: SHANGHAI CHANGWEI JINCI ENGINEERING PLASTIC Co.,Ltd. Address before: 200444 3, 2 yuan 228, Garden Road, Baoshan District, Shanghai. Applicant before: SHANGHAI JIAYUAN BAILI INVESTMENT MANAGEMENT Co.,Ltd. |
|
| TA01 | Transfer of patent application right | ||
| GR01 | Patent grant | ||
| GR01 | Patent grant | ||
| PE01 | Entry into force of the registration of the contract for pledge of patent right |
Denomination of invention: A kind of PC/ABS alloy with excellent thermal aging performance and preparation method thereof Effective date of registration: 20220830 Granted publication date: 20190510 Pledgee: Industrial Bank Co.,Ltd. Shanghai Songjiang sub branch Pledgor: SHANGHAI CHANGWEI JINCI ENGINEERING PLASTIC Co.,Ltd. Registration number: Y2022310000216 |
|
| PE01 | Entry into force of the registration of the contract for pledge of patent right |