CN106674606A - Composite plastic additive for plastic processing and preparation method thereof - Google Patents
Composite plastic additive for plastic processing and preparation method thereof Download PDFInfo
- Publication number
- CN106674606A CN106674606A CN201611244387.0A CN201611244387A CN106674606A CN 106674606 A CN106674606 A CN 106674606A CN 201611244387 A CN201611244387 A CN 201611244387A CN 106674606 A CN106674606 A CN 106674606A
- Authority
- CN
- China
- Prior art keywords
- parts
- plastic
- auxiliary agent
- composite plastic
- plastic processing
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K13/00—Use of mixtures of ingredients not covered by one single of the preceding main groups, each of these compounds being essential
- C08K13/02—Organic and inorganic ingredients
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/30—Sulfur-, selenium- or tellurium-containing compounds
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/04—Oxygen-containing compounds
- C08K5/09—Carboxylic acids; Metal salts thereof; Anhydrides thereof
- C08K5/098—Metal salts of carboxylic acids
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/04—Oxygen-containing compounds
- C08K5/10—Esters; Ether-esters
- C08K5/101—Esters; Ether-esters of monocarboxylic acids
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/49—Phosphorus-containing compounds
- C08K5/51—Phosphorus bound to oxygen
- C08K5/52—Phosphorus bound to oxygen only
- C08K5/524—Esters of phosphorous acids, e.g. of H3PO3
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/014—Additives containing two or more different additives of the same subgroup in C08K
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Chemical And Physical Treatments For Wood And The Like (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Abstract
The invention discloses a composite plastic additive for plastic processing and a preparation method thereof. The composite plastic additive mainly comprises, by weight, 22-28 parts of methacrylate, 10-25 parts of ethyl acetate, 4-8 parts of laurate, 2-4 parts of phosphite, 2-4 parts of sodium thiosulfate, 0.3-0.7 part of eremophilone, 6-10 parts of D-phenylalanine, 1-3 parts of potassium pyrophosphate, 1-3 parts of ammonium phosphomolybdate and 1-3 parts of sodium tartrate. By the composite plastic additive, particle surface energy and interface tension can be lowered greatly, self-aggregation of fine particles can be prevented effectively, the compatibility of the fine particles in plastics can be increased, polymer plasticizing can be promoted, product impact resistance, rigidity and heat resistance can be increased, melt viscosity can be lowered, flowability can be improved, and the processing performance of the plastics can be increased.
Description
Technical field
The present invention relates to a kind of field of material technology, specifically a kind of plastic processing composite plastic auxiliary agent and its preparation side
Method.
Background technology
The three big key elements for affecting plastic products quality are resin, auxiliary agent, processing, it should pay attention to plastic additive, due to plastics
Auxiliary agent adds can reach on a small quantity good effect in the plastic, plastic additive or claim processing aid, actually process auxiliaries
Development is almost synchronous, all existing history of decades with the development of plastic raw materialss with use, the entirety of China's plastic additive
Level at least lags behind industrially developed country, particularly efficiently, high performance adjuvant, seriously governs sending out for China's plastic industry
Exhibition.The Plastics Additives of China are got up with the development of plastic industry, with sending out for plastic synthetic resin industry
Exhibition, the application of Plastics Additives constantly widens, and product variety has an increase by a relatively large margin, Plastics Additives into
For the important industry that class is more complete, product variety is various, in technical merit, product structure, production scale and scientific and technical personnel
The aspect such as quality have significant progress, substantially met demand of the downstream industry to plastic additive product.But, current China
Plastic additive manufacturer is all mostly small-sized workshop, small scale, production technology, equipment backwardness, and product quality is not sufficiently stable, product
Plant single, mostly low grade products.The research and development of plastic additive are at present also mainly based on imitated external mature product.For this
Develop a kind of Multifunctional plastic additive.
The content of the invention
It is an object of the invention to provide a kind of plastic processing composite plastic auxiliary agent and preparation method thereof, above-mentioned to solve
The problem proposed in background technology.
For achieving the above object, the present invention provides following technical scheme：
A kind of plastic processing composite plastic auxiliary agent, be according to the primary raw material of weight portion：Methacrylate 22-28
Part, ethyl acetate 10-25 part, laurate 4-8 parts, phosphite ester 2-4 parts, sodium thiosulfate 2-4 parts, Airy wood phenolic ketone 0.3-
0.7 part, D-phenylalanine 6-10 parts, potassium pyrophosphate 1-3 parts, ammonium phosphomolybdate 1-3 parts, sodium tartrate 1-3 parts.
As further scheme of the invention：Plastic processing composite plastic auxiliary agent, according to the main original of weight portion
Expect be：Methacrylate 24-26 parts, ethyl acetate 15-22 part, laurate 4-8 parts, phosphite ester 2-4 parts, thiosulfuric acid
Sodium 2-4 parts, Airy wood phenolic ketone 0.3-0.7 parts, D-phenylalanine 6-10 parts, potassium pyrophosphate 1-3 parts, ammonium phosphomolybdate 1-3 parts, winestone
Sour sodium 1-3 parts.
As further scheme of the invention：Plastic processing composite plastic auxiliary agent, according to the main original of weight portion
Expect be：25 parts of methacrylate, 18 parts of ethyl acetate, 6 parts of laurate, 3 parts of phosphite ester, 3 parts of sodium thiosulfate, Airy
0.5 part of wooden phenolic ketone, 8 parts of D-phenylalanine, 2 parts of potassium pyrophosphate, 2 parts of ammonium phosphomolybdate, 2 parts of sodium tartrate.
A kind of plastic processing preparation method of composite plastic auxiliary agent, concretely comprises the following steps：
First, by methacrylate, ethyl acetate, laurate, phosphite ester, sodium thiosulfate, Airy wood phenolic ketone,
D-phenylalanine, potassium pyrophosphate, ammonium phosphomolybdate, sodium tartrate are mixed, and in placing response kettle, temperature is 62-70 DEG C, and the time is
20-30min, reaction is cooled under nitrogen protection 4 DEG C after terminating, and obtains plastic processing composite plastic auxiliary agent.
As further scheme of the invention：Temperature is 66 DEG C, and the time is 25min.
Compared with prior art, the invention has the beneficial effects as follows：
The present invention can be greatly lowered particle surface energy and interfacial tension using auxiliary agent, effectively prevent miniaturization particle
Autohemagglutination, increases its compatibility in the plastic, promotes macromolecule plasticizing, improves product shock extent, rigidity and thermostability, reduces molten
Body viscosity, improves mobility, is improved plastic processing performance.
Specific embodiment
Below in conjunction with the embodiment of the present invention, the technical scheme in the embodiment of the present invention is clearly and completely described,
Obviously, described embodiment is only a part of embodiment of the invention, rather than the embodiment of whole.Based in the present invention
Embodiment, the every other embodiment that those of ordinary skill in the art are obtained under the premise of creative work is not made, all
Belong to the scope of protection of the invention.
Embodiment 1
A kind of plastic processing composite plastic auxiliary agent, be according to the primary raw material of weight portion：22 parts of methacrylate, second
10 parts of acetoacetic ester, 4 parts of laurate, 2 parts of phosphite ester, 2 parts of sodium thiosulfate, Airy 0.3 part of phenolic ketone of wood, D-phenylalanine 6
Part, 1 part of potassium pyrophosphate, 1 part of ammonium phosphomolybdate, 1 part of sodium tartrate.
A kind of plastic processing preparation method of composite plastic auxiliary agent, concretely comprises the following steps：
First, by methacrylate, ethyl acetate, laurate, phosphite ester, sodium thiosulfate, Airy wood phenolic ketone,
D-phenylalanine, potassium pyrophosphate, ammonium phosphomolybdate, sodium tartrate are mixed, and in placing response kettle, temperature is 62 DEG C, and the time is
20min, reaction is cooled under nitrogen protection 4 DEG C after terminating, and obtains plastic processing composite plastic auxiliary agent.
Embodiment 2
A kind of plastic processing composite plastic auxiliary agent, be according to the primary raw material of weight portion：24 parts of methacrylate, second
15 parts of acetoacetic ester, 4 parts of laurate, 2 parts of phosphite ester, 2 parts of sodium thiosulfate, Airy 0.3 part of phenolic ketone of wood, D-phenylalanine 6
Part, 1 part of potassium pyrophosphate, 1 part of ammonium phosphomolybdate, 1 part of sodium tartrate.
A kind of plastic processing preparation method of composite plastic auxiliary agent, concretely comprises the following steps：
First, by methacrylate, ethyl acetate, laurate, phosphite ester, sodium thiosulfate, Airy wood phenolic ketone,
D-phenylalanine, potassium pyrophosphate, ammonium phosphomolybdate, sodium tartrate are mixed, and in placing response kettle, temperature is 62 DEG C, and the time is
20min, reaction is cooled under nitrogen protection 4 DEG C after terminating, and obtains plastic processing composite plastic auxiliary agent.
Embodiment 3
A kind of plastic processing composite plastic auxiliary agent, be according to the primary raw material of weight portion：25 parts of methacrylate, second
18 parts of acetoacetic ester, 6 parts of laurate, 3 parts of phosphite ester, 3 parts of sodium thiosulfate, Airy 0.5 part of phenolic ketone of wood, D-phenylalanine 8
Part, 2 parts of potassium pyrophosphate, 2 parts of ammonium phosphomolybdate, 2 parts of sodium tartrate.
A kind of plastic processing preparation method of composite plastic auxiliary agent, concretely comprises the following steps：
First, by methacrylate, ethyl acetate, laurate, phosphite ester, sodium thiosulfate, Airy wood phenolic ketone,
D-phenylalanine, potassium pyrophosphate, ammonium phosphomolybdate, sodium tartrate are mixed, and in placing response kettle, temperature is 66 DEG C, and the time is
25min, reaction is cooled under nitrogen protection 4 DEG C after terminating, and obtains plastic processing composite plastic auxiliary agent.
Embodiment 4
A kind of plastic processing composite plastic auxiliary agent, be according to the primary raw material of weight portion：26 parts of methacrylate, second
22 parts of acetoacetic ester, 8 parts of laurate, 4 parts of phosphite ester, 4 parts of sodium thiosulfate, Airy 0.7 part of phenolic ketone of wood, D-phenylalanine 10
Part, 3 parts of potassium pyrophosphate, 3 parts of ammonium phosphomolybdate, 3 parts of sodium tartrate.
A kind of plastic processing preparation method of composite plastic auxiliary agent, concretely comprises the following steps：
First, by methacrylate, ethyl acetate, laurate, phosphite ester, sodium thiosulfate, Airy wood phenolic ketone,
D-phenylalanine, potassium pyrophosphate, ammonium phosphomolybdate, sodium tartrate are mixed, and in placing response kettle, temperature is 70 DEG C, and the time is
30min, reaction is cooled under nitrogen protection 4 DEG C after terminating, and obtains plastic processing composite plastic auxiliary agent.
Embodiment 5
A kind of plastic processing composite plastic auxiliary agent, be according to the primary raw material of weight portion：28 parts of methacrylate, second
25 parts of acetoacetic ester, 8 parts of laurate, 4 parts of phosphite ester, 4 parts of sodium thiosulfate, Airy 0.7 part of phenolic ketone of wood, D-phenylalanine 10
Part, 3 parts of potassium pyrophosphate, 3 parts of ammonium phosphomolybdate, 3 parts of sodium tartrate.
A kind of plastic processing preparation method of composite plastic auxiliary agent, concretely comprises the following steps：
First, by methacrylate, ethyl acetate, laurate, phosphite ester, sodium thiosulfate, Airy wood phenolic ketone,
D-phenylalanine, potassium pyrophosphate, ammonium phosphomolybdate, sodium tartrate are mixed, and in placing response kettle, temperature is 70 DEG C, and the time is
30min, reaction is cooled under nitrogen protection 4 DEG C after terminating, and obtains plastic processing composite plastic auxiliary agent.
(" YY-201 multiple-effect is coupled lubrication for composite plastic auxiliary agent obtained in above-described embodiment 1,3,5 and common plasticses auxiliary agent
Agent ", Guangzhou Yuan Tai synthetic materials company limited) it is added separately to PVC plastic and processes raw material middle mixing, in sending into mould, heat up
To 150~170 DEG C, 5-7MPa is boosted to, then constant temperature and pressure control time 30-40min draws finished product, after inspection
Go out such as the data in table 1 below.Table 1 is the performance test results.
Table 1
It is obvious to a person skilled in the art that the invention is not restricted to the details of above-mentioned one exemplary embodiment, Er Qie
In the case of spirit or essential attributes without departing substantially from the present invention, the present invention can be in other specific forms realized.Therefore, no matter
From the point of view of which point, embodiment all should be regarded as exemplary, and be nonrestrictive, the scope of the present invention is by appended power
Profit is required rather than described above is limited, it is intended that all in the implication and scope of the equivalency of claim by falling
Change is included in the present invention.
Moreover, it will be appreciated that although this specification is been described by according to embodiment, not each embodiment is only wrapped
Containing an independent technical scheme, this narrating mode of description is only that for clarity those skilled in the art should
Using description as an entirety, the technical scheme in each embodiment can also Jing it is appropriately combined, form those skilled in the art
Understandable other embodiment.
Claims (5)
1. a kind of plastic processing composite plastic auxiliary agent, it is characterised in that the primary raw material according to weight portion is：Methacrylic acid
Ester 22-28 parts, ethyl acetate 10-25 part, laurate 4-8 parts, phosphite ester 2-4 parts, sodium thiosulfate 2-4 parts, Airy wood
Phenolic ketone 0.3-0.7 parts, D-phenylalanine 6-10 parts, potassium pyrophosphate 1-3 parts, ammonium phosphomolybdate 1-3 parts, sodium tartrate 1-3 parts.
2. plastic processing according to claim 1 composite plastic auxiliary agent, it is characterised in that the plastic processing is with compound
Plastic additive, be according to the primary raw material of weight portion：Methacrylate 24-26 parts, ethyl acetate 15-22 part, laurate
4-8 parts, phosphite ester 2-4 parts, sodium thiosulfate 2-4 parts, Airy wood phenolic ketone 0.3-0.7 parts, D-phenylalanine 6-10 parts, burnt phosphorus
Sour potassium 1-3 parts, ammonium phosphomolybdate 1-3 parts, sodium tartrate 1-3 parts.
3. plastic processing according to claim 1 and 2 composite plastic auxiliary agent, it is characterised in that the plastic processing is used
Composite plastic auxiliary agent, be according to the primary raw material of weight portion：25 parts of methacrylate, 18 parts of ethyl acetate, laurate 6
Part, 3 parts of phosphite ester, 3 parts of sodium thiosulfate, Airy 0.5 part of phenolic ketone of wood, 8 parts of D-phenylalanine, 2 parts of potassium pyrophosphate, phosphomolybdic acid
2 parts of ammonium, 2 parts of sodium tartrate.
4. a kind of plastic processing as described in claim 1-3 is arbitrary preparation method of composite plastic auxiliary agent, it is characterised in that
Concretely comprise the following steps：
First, by methacrylate, ethyl acetate, laurate, phosphite ester, sodium thiosulfate, Airy wood phenolic ketone, D- benzene
Alanine, potassium pyrophosphate, ammonium phosphomolybdate, sodium tartrate are mixed, and in placing response kettle, temperature is 62-70 DEG C, and the time is 20-
30min, reaction is cooled under nitrogen protection 4 DEG C after terminating, and obtains plastic processing composite plastic auxiliary agent.
5. the plastic processing according to claim 4 preparation method of composite plastic auxiliary agent, it is characterised in that temperature is 66
DEG C, the time is 25min.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201611244387.0A CN106674606A (en) | 2016-12-29 | 2016-12-29 | Composite plastic additive for plastic processing and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201611244387.0A CN106674606A (en) | 2016-12-29 | 2016-12-29 | Composite plastic additive for plastic processing and preparation method thereof |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN106674606A true CN106674606A (en) | 2017-05-17 |
Family
ID=58871921
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201611244387.0A Pending CN106674606A (en) | 2016-12-29 | 2016-12-29 | Composite plastic additive for plastic processing and preparation method thereof |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN106674606A (en) |
-
2016
- 2016-12-29 CN CN201611244387.0A patent/CN106674606A/en active Pending
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN103992589B (en) | A kind of wood plastic building mould utilizing recovery waste material to produce and preparation method thereof | |
| CN102503232A (en) | Environment-friendly, high-efficient and composite liquid cement grinding aid and preparation method thereof | |
| CN102503233A (en) | Novel liquid cement grinding aid and preparation method thereof | |
| CN106589650A (en) | Fine-performance plastic material and preparation method thereof | |
| CN102660062A (en) | Anti-droplet high-transparency polyethylene film master batches | |
| CN110470521B (en) | Simulation material for polymer-based fusion-cast explosive process test | |
| CN106084716A (en) | Weather-proof high light exempts to spray PC/ASA alloy material and preparation method thereof | |
| CN106589751A (en) | Composite plastic auxiliary for high-strength plastic processing and preparation method thereof | |
| CN104861247A (en) | High strength flame retardant simulation wood and preparation method thereof | |
| CN106674606A (en) | Composite plastic additive for plastic processing and preparation method thereof | |
| CN106751125A (en) | A kind of highstrenghtpiston is processed with composite plastic auxiliary agent and preparation method thereof | |
| CN110015863B (en) | Modifier for water glass for casting sand mold of electric melting brick and modified water glass prepared by modifier | |
| CN103045106A (en) | Adhesive containing modified PVC (polyvinyl chloride) resin for packaging materials | |
| CN103450677B (en) | A kind of continuous long carbon fiber strengthens MXD6 mixture and preparation method thereof | |
| CN106699995A (en) | Composite plastic assistant agent for high-strength plastic processing | |
| CN105111572A (en) | Expanding material for preparing vehicle body cavity sound insulation block and preparation method therefor | |
| CN105304255A (en) | Neodymium iron boron magnetic material with high magnetic energy and preparation method thereof | |
| CN106432805A (en) | Composite plastic additive for plastic processing and preparation method thereof | |
| CN104861250A (en) | Flame retardant enhancing simulation wood and preparation method thereof | |
| CN103525078A (en) | Footwear leather environment-friendly type solvent-free foaming base material and preparation method thereof | |
| CN103613842A (en) | High water resistant wood and plastic composite material | |
| KR101107720B1 (en) | Process of synthetic wood through recycling polyurethane and synthetic wood product obtained therefrom | |
| CN111875900A (en) | Wood-plastic composite material prepared from modified ammonium polyphosphate and preparation method thereof | |
| CN103756110A (en) | Drip irrigation tape heat resistance improving production process | |
| CN105462040B (en) | A kind of water-fast fluorescence bamboo-plastic composite material and preparation method thereof |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PB01 | Publication | ||
| PB01 | Publication | ||
| WD01 | Invention patent application deemed withdrawn after publication | ||
| WD01 | Invention patent application deemed withdrawn after publication |
Application publication date: 20170517 |