CN106670080A - Production process of waterproof glowing sheet - Google Patents

Production process of waterproof glowing sheet Download PDF

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Publication number
CN106670080A
CN106670080A CN201611134796.5A CN201611134796A CN106670080A CN 106670080 A CN106670080 A CN 106670080A CN 201611134796 A CN201611134796 A CN 201611134796A CN 106670080 A CN106670080 A CN 106670080A
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China
Prior art keywords
base material
waterproof
clear finish
sheet
glare
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Granted
Application number
CN201611134796.5A
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Chinese (zh)
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CN106670080B (en
Inventor
许东勇
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Individual
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Individual
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Priority to CN201611134796.5A priority Critical patent/CN106670080B/en
Priority to PCT/CN2016/111222 priority patent/WO2018103139A1/en
Publication of CN106670080A publication Critical patent/CN106670080A/en
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    • BPERFORMING OPERATIONS; TRANSPORTING
    • B05SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05DPROCESSES FOR APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05D7/00Processes, other than flocking, specially adapted for applying liquids or other fluent materials to particular surfaces or for applying particular liquids or other fluent materials
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B05SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05DPROCESSES FOR APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05D7/00Processes, other than flocking, specially adapted for applying liquids or other fluent materials to particular surfaces or for applying particular liquids or other fluent materials
    • B05D7/50Multilayers
    • B05D7/52Two layers
    • B05D7/53Base coat plus clear coat type
    • B05D7/534Base coat plus clear coat type the first layer being let to dry at least partially before applying the second layer
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B05SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05DPROCESSES FOR APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05D2502/00Acrylic polymers
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B05SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05DPROCESSES FOR APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05D2503/00Polyurethanes
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B05SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05DPROCESSES FOR APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05D2518/00Other type of polymers

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  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Wood Science & Technology (AREA)
  • Footwear And Its Accessory, Manufacturing Method And Apparatuses (AREA)
  • Treatment And Processing Of Natural Fur Or Leather (AREA)
  • Laminated Bodies (AREA)

Abstract

The invention discloses a production process of a waterproof glowing sheet. The production process comprises a base material selection step, a degreasing and dedusting step, a transparent top-coat blending step, a transparent top-coat spraying step and an optical filming step to obtain the ventilate waterproof glowing sheet. The production process is simple, easy to implement and environment-friendly and pollution-free during production, and the produced waterproof glowing sheet has extremely good waterproofness. The ventilate waterproof glowing shoe material has extremely good air permeability and waterproofness, meanwhile, has an extremely good glowing effect, and different zones have different colors and color changes in the dynamic observation processes at different angles and in different distances, so that more color changes are shown, and the colors are brighter.

Description

A kind of production technology of waterproof glare sheet material
Technical field
The present invention relates to the technical field of producing of waterproof glare sheet material, more particularly, to it is a kind of for make clothing, The production technology of the air permeable waterproof glare sheet material of shoes and medicated cap and other items.
Background technology
In prior art, clothing, shoes and medicated cap and other items typically select cloth or leatherwork, particularly shoes, right Permeability and water resistance have higher requirement, and the general color of this kind of material layer is relatively simple, and surface is covered with aperture, at present Cannot make material layer realize in itself glare effect, cloth or leather cannot also carry out electroplating, the technique such as optics plating, if will realize Glare effect, usually pastes or sews glare piece in material surface, it is therefore necessary to improved.
The content of the invention
In view of the shortcomings of the prior art, the purpose of the present invention is to put forward a kind of production technology of waterproof glare sheet material, this Invented technology is simple, it is easy to implement, and production process is environment friendly and pollution-free, and waterproof glare sheet material has fabulous glare effect.
In view of the shortcomings of the prior art, it is another object of the present invention to propose a kind of production of air permeable waterproof glare footwear material Technique, air permeable waterproof with fabulous permeability and water resistance, and have fabulous glare effect.
To achieve these goals, the technical solution adopted in the present invention is.
A kind of production technology of waterproof glare sheet material, comprises the following steps,
From base material, cloth, PU sheet materials from single layer structure, TPU sheet materials, KPU sheet materials, animal's leather sheet material or artificial Leather sheet material is used as base material, or selects the composite sheet for having at least aforementioned two kinds of sheet materials as composite bed to be base material;
Base material is processed, and is printed with pattern in the regional area or Zone Full of substrate surface and/or is fixed with cosmetic sheet;
Oil removing dedusting, cleans base material by ultrasound wave, then dries;
Allotment clear finish, by the percentage by weight of active substance, by 3~10% polyurethane and 45~60% butyl ester Acrylic resin mix homogeneously with 35~50%, obtains clear finish;
Spraying clear finish, by clear finish even application in the surface of the base material through oil removing dedusting;
Optical coating, after clear finish is parched, by optical coating technique base material one printing opacity waterproof of plated surface Film layer;
Finished product, obtains air permeable waterproof glare sheet material.
In further technical scheme, in the selection base material step, the base material is from carrying with permeability The sheet material of breathable mesh or ventilative grandson's gap, the regional area or Zone Full of base material are covered with breathable mesh or ventilative grandson's gap;It is described The material layer of composite sheet includes in bed of cloth, PU layers, TPU layer, KPU layers, animal's leather layer or dermatine layer at least two Kind.
In further technical scheme, in the base material procedure of processing, base material cutting is flattened into the vamp or upper of a shoe of shoes Shape afterwards.
In further technical scheme, production technology includes allocating transparent priming step, allocates transparent priming step, by having The percentage by weight of effect material, 40~60% isocyanates polymer and 40~60% butyl ester mix homogeneously are obtained Bright priming paint;First carry out spraying transparent priming step, by transparent priming even application on the surface of the base material through oil removing dedusting, After transparent priming is parched, then carry out spraying clear finish step.
In further technical scheme, in the allotment clear finish step, by the percentage by weight of active substance, will 5% polyurethane and 55% butyl ester and 45% acrylic resin mix homogeneously, obtain clear finish;The allotment clear bottom In paint step, by the percentage by weight of active substance, 55% isocyanates polymer and 45% butyl ester mix homogeneously are obtained To transparent priming.
In further technical scheme, in the spraying transparent priming step, the thickness of transparent priming is 1~50 μm, thoroughly Bright priming paint does not block the breathable mesh of base material or ventilative grandson's gap;In the spraying clear finish step, the thickness of clear finish is 1 ~50 μm, clear finish does not block the breathable mesh of base material or ventilative grandson's gap.
In further technical scheme, in the optical coating film step, using organic mixing medicine and metal-plated material simultaneously Optical coating technique is carried out, the printing opacity membrane waterproofing of the plated film for mixed type of substrate surface is formed in, printing opacity membrane waterproofing is not blocked up The breathable mesh or ventilative grandson's gap of plug base material.
In further technical scheme, increase at surface between the spraying clear finish step and the optical coating Reason step, by flame spraying process by nano level zirconia powder even application in the surface of clear finish, flame-spraying work At 80~90 DEG C, zirconia powder is combined with clear finish and forms one on the surface of clear finish for flame temperature control in skill Transparent nano zircite composite bed, the thickness of nano zircite composite bed is 1~2 μm.
The invention has the advantages that compared with the prior art,:The process is simple of the present invention, it is easy to implement, production process It is environment friendly and pollution-free, produce the waterproof glare sheet material for obtaining and there is fabulous water resistance, air permeable waterproof glare footwear material has fabulous Permeability and water resistance, while with fabulous glare effect, in different angles, different distance observation and in dynamic During observation, zones of different has different colors and color change respectively, presents more color changes, and color It is brighter.
Specific embodiment
Described below is only presently preferred embodiments of the present invention, is not intended to limit the scope of the present invention.
Embodiment one
A kind of production technology of waterproof glare sheet material, comprises the following steps,
From base material, cloth, PU sheet materials from single layer structure, TPU sheet materials, KPU sheet materials, animal's leather sheet material or artificial Leather sheet material is used as base material, or selects composite sheet for base material, and the material layer of composite sheet includes bed of cloth, PU layers, TPU In layer, KPU layers, animal's leather layer or dermatine layer at least two.
Base material process, be printed with pattern in the regional area or Zone Full of substrate surface, can pass through barbola work or Sewing technology fixes some cosmetic sheets, sheet material of the base material cutting into required form in substrate surface.
Oil removing dedusting, cleans base material by ultrasound wave, then dries.
Allotment clear finish, by the percentage by weight of active substance, by 3~10% polyurethane and 45~60% butyl ester Acrylic resin mix homogeneously with 35~50%, obtains clear finish;Wherein, the optimal components ratio of clear finish is, by effective The percentage by weight of material, by 5% polyurethane and 55% butyl ester and 45% acrylic resin mix homogeneously, obtain transparent Finish paint.
Spraying clear finish, by clear finish even application in the surface of the base material through oil removing dedusting;Clear finish Thickness is 1~50 μm.Clear finish enables optical coating technique as having fabulous adhesive force between interlayer, with base material In its plated surface glazing membrane waterproofing, and also there is between finish paint and printing opacity membrane waterproofing fabulous adhesive force, while also having Increase the effect of glare effect.
Optical coating, after clear finish is parched, by optical coating technique base material one printing opacity waterproof of plated surface Film layer;Specifically, optical coating technique is carried out simultaneously using organic mixing medicine and metal-plated material, be formed in the plated film of substrate surface For the printing opacity membrane waterproofing of mixed type, the thickness of printing opacity membrane waterproofing is 1~10 μm.
Finished product, obtains waterproof glare sheet material.
The process is simple of the present invention, it is easy to implement, production process is environment friendly and pollution-free, produces the waterproof glare sheet material for obtaining, With water resistance;In different angles and different distance observation waterproof glare sheet material, the zones of different difference of waterproof glare sheet material Different colors are presented, during dynamic observation air permeable waterproof glare sheet material, move in waterproof glare sheet material in other words or During rocking, the zones of different of waterproof glare sheet material is presented different colors and color change respectively, and color is more saturating It is bright, with fabulous glare effect.
Embodiment two
A kind of production technology of air permeable waterproof glare footwear material, comprises the following steps,
From base material, base material is from the sheet material with breathable mesh or ventilative grandson's gap with permeability, the office of base material Portion region or Zone Full are covered with breathable mesh or ventilative grandson's gap;Specifically, base material from the cloth of single layer structure, PU sheet materials, TPU sheet materials, KPU sheet materials, animal's leather sheet material or dermatine sheet material are used as base material, preferably, the base material of single layer structure is preferred It is covered with the cloth of breathable mesh.
Or select the composite sheet with least two lamination layer structures for base material, the material layer of composite sheet includes cloth In the bed of material, PU layers, TPU layer, KPU layers, animal's leather layer or dermatine layer at least two.As the preferred composite sheet of base material Material, the top layer and bottom of composite sheet are with meshed cloth, intermediate layer from regional area or Zone Full with saturating The PU layers of gas mesh or ventilative grandson's gap, TPU layer or KPU layers.
Base material process, be printed with pattern in the regional area or Zone Full of substrate surface, can pass through barbola work or Sewing technology fixes some cosmetic sheets in substrate surface, and base material cutting is into the shape after the vamp or upper of a shoe flattening of shoes.
Oil removing dedusting, cleans base material by ultrasound wave, then dries.
Allotment transparent priming step, by the percentage by weight of active substance, by 40~60% isocyanates polymer and 40~60% butyl ester mix homogeneously, obtains transparent priming;Wherein, the optimal components ratio of clear finish is, by the weight of active substance Amount percentage ratio, by 55% isocyanates polymer and 45% butyl ester mix homogeneously, obtains transparent priming.
Allotment clear finish, by the percentage by weight of active substance, by 3~10% polyurethane and 45~60% butyl ester Acrylic resin mix homogeneously with 35~50%, obtains clear finish;Wherein, the optimal components ratio of clear finish is, by effective The percentage by weight of material, by 5% polyurethane and 55% butyl ester and 45% acrylic resin mix homogeneously, obtain transparent Finish paint.
Spraying transparent priming, by transparent priming even application in the surface of the base material through oil removing dedusting, transparent priming Thickness be 1~10 μm, transparent priming does not block the breathable mesh of base material or ventilative grandson's gap.
Spraying clear finish, after transparent priming is parched, then carries out spraying clear finish step, and clear finish is uniform It is sprayed at the surface of transparent priming;The thickness of clear finish is 1~10 μm, and clear finish does not block the breathable mesh of base material or saturating Gas grandson's gap.
Optical coating, after clear finish is parched, by optical coating technique base material one printing opacity waterproof of plated surface Film layer;Specifically, optical coating technique is carried out simultaneously using organic mixing medicine and metal-plated material, be formed in the plated film of substrate surface For the printing opacity membrane waterproofing of mixed type, the thickness of printing opacity membrane waterproofing is 1~10 μm, and printing opacity membrane waterproofing does not block the saturating of base material Gas mesh or ventilative grandson's gap, priming paint, finish paint and printing opacity membrane waterproofing form the composite bed of a permeable watertight.
Finished product, obtains air permeable waterproof glare footwear material, for making shoes.
The process is simple of the present invention, it is easy to implement, production process is environment friendly and pollution-free, produces the air permeable waterproof glare footwear for obtaining Material, with fabulous permeability and water resistance;Also, in different angles and different distance observation air permeable waterproof glare footwear Material, the zones of different of air permeable waterproof glare footwear material are presented different colors respectively, in dynamic observation air permeable waterproof glare footwear material During, in other words during air permeable waterproof glare footwear material is moved or rocked, the zones of different of air permeable waterproof glare footwear material Different colors and color change are presented respectively, and color is brighter, with fabulous glare effect.
Embodiment three
A kind of production technology of air permeable waterproof glare footwear material, the key step of the present embodiment are identical with embodiment two, including From base material step, base material procedure of processing, oil removing dust removal step, allotment transparent priming step step, allotment clear finish step, Spraying transparent priming step, spraying clear finish step, optical coating step and finished product step, its same steps are no longer gone to live in the household of one's in-laws on getting married here State, its difference part is:Increase by a surface treatment step between spraying clear finish step and optical coating step, specifically , after clear finish is parched, by flame spraying process by nano level zirconia powder even application in clear finish Surface, the flame temperature in flame spraying process are controlled at 80~90 DEG C, and zirconia powder is combined with clear finish and transparent The surface of finish paint forms a transparent nano zircite composite bed, and the thickness of nano zircite composite bed is 1~2 μm.Make optics Plated film is easily implemented, and further improves the adhesive force of the printing opacity membrane waterproofing that optics depositing process is formed.Further improve ventilative The refractive index and the amplitude of variation of reflectance of the diverse location of waterproof glare footwear material, and refractive index and reflectance are more intended to nothing Directivity, in different angles and different distance observation air permeable waterproof glare footwear material, moves or shakes in air permeable waterproof glare footwear material In dynamic process, air permeable waterproof glare footwear material presents more colors and color change, and static observations and dynamic sight respectively Examine, color is brighter, and glare effect is more dazzled extremely.
Above content is only presently preferred embodiments of the present invention, for one of ordinary skill in the art, according to the present invention's Thought, will change in specific embodiments and applications, and this specification content is should not be construed as to the present invention Restriction.

Claims (8)

1. a kind of production technology of waterproof glare sheet material, it is characterised in that:Comprise the following steps,
From base material, the cloth, PU sheet materials, TPU sheet materials, KPU sheet materials, animal's leather sheet material or dermatine from single layer structure Sheet material is used as base material, or selects the composite sheet for having at least aforementioned two kinds of sheet materials as composite bed to be base material;
Base material is processed, and is printed with pattern in the regional area or Zone Full of substrate surface and/or is fixed with cosmetic sheet;
Oil removing dedusting, cleans base material by ultrasound wave, then dries;
Allotment clear finish, by the percentage by weight of active substance, by 3~10% polyurethane and 45~60% butyl ester and 35 ~50% acrylic resin mix homogeneously, obtains clear finish;
Spraying clear finish, by clear finish even application in the surface of the base material through oil removing dedusting;
Optical coating, after clear finish is parched, by optical coating technique base material one printing opacity membrane waterproofing of plated surface;
Finished product, obtains air permeable waterproof glare sheet material.
2. the production technology of a kind of waterproof glare sheet material according to claim 1, it is characterised in that:The selection base material step In rapid, the base material from the sheet material with breathable mesh or ventilative grandson's gap with permeability, the regional area of base material or Zone Full is covered with breathable mesh or ventilative grandson's gap;The material layer of the composite sheet includes bed of cloth, PU layers, TPU layer, KPU In layer, animal's leather layer or dermatine layer at least two.
3. the production technology of a kind of waterproof glare sheet material according to claim 2, it is characterised in that:The base material processing step In rapid, base material cutting is into the shape after the vamp or upper of a shoe flattening of shoes.
4. the production technology of a kind of waterproof glare sheet material according to claim 2, it is characterised in that:Production technology includes adjusting With transparent priming step,
Allotment transparent priming step, by the percentage by weight of active substance, by 40~60% isocyanates polymer and 40~ 60% butyl ester mix homogeneously, obtains transparent priming;
First carry out spraying transparent priming step, by transparent priming even application on the surface of the base material through oil removing dedusting, After transparent priming is parched, then carry out spraying clear finish step.
5. the production technology of a kind of waterproof glare sheet material according to claim 4, it is characterised in that:The allotment transparent area In paint step, by the percentage by weight of active substance, 5% polyurethane and 55% butyl ester and 45% acrylic resin are mixed Close uniform, obtain clear finish;
In the allotment transparent priming step, by the percentage by weight of active substance, by 55% isocyanates polymer and 45% butyl ester mix homogeneously, obtains transparent priming.
6. the production technology of a kind of waterproof glare sheet material according to claim 5, it is characterised in that:The spraying clear bottom In paint step, the thickness of transparent priming is 1~50 μm, and transparent priming does not block the breathable mesh of base material or ventilative grandson's gap;It is described In spraying clear finish step, the thickness of clear finish is 1~50 μm, and clear finish does not block the breathable mesh of base material or ventilative Grandson's gap.
7. the production technology of a kind of waterproof glare sheet material according to one of claim 1 to 6, it is characterised in that:The light Learn in plated film film step, optical coating technique is carried out simultaneously using organic mixing medicine and metal-plated material, be formed in substrate surface Printing opacity membrane waterproofing of the plated film for mixed type, printing opacity membrane waterproofing do not block the breathable mesh of base material or ventilative grandson's gap.
8. the production technology of a kind of waterproof glare sheet material according to claim 7, it is characterised in that:It is transparent in the spraying Increase surface treatment step between finish paint step and the optical coating, by flame spraying process by nano level zirconia powder Even application on the surface of clear finish, the flame temperature control in flame spraying process at 80~90 DEG C, zirconia powder with it is saturating Bright finish paint combines and forms a transparent nano zircite composite bed on the surface of clear finish, nano zircite composite bed Thickness is 1~2 μm.
CN201611134796.5A 2016-12-11 2016-12-11 Production process of waterproof glare sheet Active CN106670080B (en)

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CN201611134796.5A CN106670080B (en) 2016-12-11 2016-12-11 Production process of waterproof glare sheet
PCT/CN2016/111222 WO2018103139A1 (en) 2016-12-11 2016-12-21 Manufacturing method for waterproof glaring sheet

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Application Number Priority Date Filing Date Title
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Cited By (2)

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CN109043735A (en) * 2018-08-08 2018-12-21 晋江市履图鞋业科技有限公司 Manufacturing process of bottomless integrated shoe
CN110481107A (en) * 2019-09-05 2019-11-22 深圳市摩码克来沃化学科技有限公司 One kind can dynamic optically variable films and preparation method thereof

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CN1049124A (en) * 1990-07-11 1991-02-13 中国黄石金利新型包装材料有限公司 A kind of macromolecular compound cloth and production method thereof and application
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Publication number Priority date Publication date Assignee Title
CN109043735A (en) * 2018-08-08 2018-12-21 晋江市履图鞋业科技有限公司 Manufacturing process of bottomless integrated shoe
CN109043735B (en) * 2018-08-08 2021-05-04 福建省万物智联科技有限公司 Manufacturing process of bottomless integrated shoe
CN110481107A (en) * 2019-09-05 2019-11-22 深圳市摩码克来沃化学科技有限公司 One kind can dynamic optically variable films and preparation method thereof
CN110481107B (en) * 2019-09-05 2024-05-28 深圳市摩码克来沃化学科技有限公司 Dynamic color-changeable film and preparation method thereof

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WO2018103139A1 (en) 2018-06-14
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