CN106666323A - Preparation method of compound food deoxidizing agent - Google Patents
Preparation method of compound food deoxidizing agent Download PDFInfo
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- CN106666323A CN106666323A CN201611030345.7A CN201611030345A CN106666323A CN 106666323 A CN106666323 A CN 106666323A CN 201611030345 A CN201611030345 A CN 201611030345A CN 106666323 A CN106666323 A CN 106666323A
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- deoxidizing agent
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- 235000013305 food Nutrition 0.000 title claims abstract description 54
- 238000002360 preparation method Methods 0.000 title claims abstract description 10
- 150000001875 compounds Chemical class 0.000 title abstract 5
- AKEJUJNQAAGONA-UHFFFAOYSA-N sulfur trioxide Chemical compound O=S(=O)=O AKEJUJNQAAGONA-UHFFFAOYSA-N 0.000 claims abstract description 28
- MHAJPDPJQMAIIY-UHFFFAOYSA-N Hydrogen peroxide Chemical compound OO MHAJPDPJQMAIIY-UHFFFAOYSA-N 0.000 claims abstract description 27
- BASFCYQUMIYNBI-UHFFFAOYSA-N platinum Substances [Pt] BASFCYQUMIYNBI-UHFFFAOYSA-N 0.000 claims abstract description 21
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 claims abstract description 18
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 claims abstract description 14
- 229910052697 platinum Inorganic materials 0.000 claims abstract description 13
- QJZYHAIUNVAGQP-UHFFFAOYSA-N 3-nitrobicyclo[2.2.1]hept-5-ene-2,3-dicarboxylic acid Chemical compound C1C2C=CC1C(C(=O)O)C2(C(O)=O)[N+]([O-])=O QJZYHAIUNVAGQP-UHFFFAOYSA-N 0.000 claims abstract description 12
- 239000004021 humic acid Substances 0.000 claims abstract description 12
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 claims abstract description 9
- GUJOJGAPFQRJSV-UHFFFAOYSA-N dialuminum;dioxosilane;oxygen(2-);hydrate Chemical compound O.[O-2].[O-2].[O-2].[Al+3].[Al+3].O=[Si]=O.O=[Si]=O.O=[Si]=O.O=[Si]=O GUJOJGAPFQRJSV-UHFFFAOYSA-N 0.000 claims abstract description 9
- 229910052901 montmorillonite Inorganic materials 0.000 claims abstract description 9
- 238000001914 filtration Methods 0.000 claims description 21
- 238000000498 ball milling Methods 0.000 claims description 18
- FAPWRFPIFSIZLT-UHFFFAOYSA-M Sodium chloride Chemical compound [Na+].[Cl-] FAPWRFPIFSIZLT-UHFFFAOYSA-M 0.000 claims description 12
- 238000013461 design Methods 0.000 claims description 12
- 239000000463 material Substances 0.000 claims description 12
- 239000000203 mixture Substances 0.000 claims description 11
- 239000008187 granular material Substances 0.000 claims description 10
- 238000006243 chemical reaction Methods 0.000 claims description 9
- 238000003756 stirring Methods 0.000 claims description 9
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 8
- NGNBDVOYPDDBFK-UHFFFAOYSA-N 2-[2,4-di(pentan-2-yl)phenoxy]acetyl chloride Chemical compound CCCC(C)C1=CC=C(OCC(Cl)=O)C(C(C)CCC)=C1 NGNBDVOYPDDBFK-UHFFFAOYSA-N 0.000 claims description 7
- 238000002844 melting Methods 0.000 claims description 7
- 230000008018 melting Effects 0.000 claims description 7
- 229910000831 Steel Inorganic materials 0.000 claims description 6
- 238000001354 calcination Methods 0.000 claims description 6
- 238000001816 cooling Methods 0.000 claims description 6
- 239000012153 distilled water Substances 0.000 claims description 6
- 238000000227 grinding Methods 0.000 claims description 6
- 238000009413 insulation Methods 0.000 claims description 6
- 229910052757 nitrogen Inorganic materials 0.000 claims description 6
- 239000011780 sodium chloride Substances 0.000 claims description 6
- 239000010959 steel Substances 0.000 claims description 6
- 238000004140 cleaning Methods 0.000 claims description 5
- 238000007789 sealing Methods 0.000 claims description 5
- 238000003801 milling Methods 0.000 claims description 2
- UXVMQQNJUSDDNG-UHFFFAOYSA-L Calcium chloride Chemical compound [Cl-].[Cl-].[Ca+2] UXVMQQNJUSDDNG-UHFFFAOYSA-L 0.000 claims 1
- 239000001110 calcium chloride Substances 0.000 claims 1
- 229910001628 calcium chloride Inorganic materials 0.000 claims 1
- 229910052760 oxygen Inorganic materials 0.000 abstract description 19
- 239000001301 oxygen Substances 0.000 abstract description 19
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 abstract description 18
- 230000000694 effects Effects 0.000 abstract description 12
- 239000003795 chemical substances by application Substances 0.000 abstract description 10
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 abstract description 9
- -1 platinum ions Chemical class 0.000 abstract description 7
- 239000000126 substance Substances 0.000 abstract description 7
- 238000000034 method Methods 0.000 abstract description 6
- 229910052742 iron Inorganic materials 0.000 abstract description 5
- RAHZWNYVWXNFOC-UHFFFAOYSA-N Sulphur dioxide Chemical compound O=S=O RAHZWNYVWXNFOC-UHFFFAOYSA-N 0.000 abstract description 4
- JVBXVOWTABLYPX-UHFFFAOYSA-L sodium dithionite Chemical compound [Na+].[Na+].[O-]S(=O)S([O-])=O JVBXVOWTABLYPX-UHFFFAOYSA-L 0.000 abstract description 4
- 238000010521 absorption reaction Methods 0.000 abstract description 2
- 229910001873 dinitrogen Inorganic materials 0.000 abstract description 2
- 238000003723 Smelting Methods 0.000 abstract 2
- CPLXHLVBOLITMK-UHFFFAOYSA-N magnesium oxide Inorganic materials [Mg]=O CPLXHLVBOLITMK-UHFFFAOYSA-N 0.000 abstract 2
- 239000000395 magnesium oxide Substances 0.000 abstract 2
- AXZKOIWUVFPNLO-UHFFFAOYSA-N magnesium;oxygen(2-) Chemical compound [O-2].[Mg+2] AXZKOIWUVFPNLO-UHFFFAOYSA-N 0.000 abstract 2
- 239000002253 acid Substances 0.000 abstract 1
- 238000005536 corrosion prevention Methods 0.000 abstract 1
- 230000007547 defect Effects 0.000 abstract 1
- 230000001590 oxidative effect Effects 0.000 abstract 1
- 230000003647 oxidation Effects 0.000 description 6
- 238000007254 oxidation reaction Methods 0.000 description 6
- 230000000844 anti-bacterial effect Effects 0.000 description 5
- 230000006378 damage Effects 0.000 description 5
- 150000002505 iron Chemical class 0.000 description 5
- 244000005700 microbiome Species 0.000 description 5
- 235000015097 nutrients Nutrition 0.000 description 5
- 239000003921 oil Substances 0.000 description 5
- 239000000843 powder Substances 0.000 description 5
- 229910021529 ammonia Inorganic materials 0.000 description 4
- 230000002421 anti-septic effect Effects 0.000 description 4
- 235000002864 food coloring agent Nutrition 0.000 description 4
- 238000012856 packing Methods 0.000 description 4
- GEHJYWRUCIMESM-UHFFFAOYSA-L sodium sulfite Chemical compound [Na+].[Na+].[O-]S([O-])=O GEHJYWRUCIMESM-UHFFFAOYSA-L 0.000 description 4
- 238000003860 storage Methods 0.000 description 4
- 238000012360 testing method Methods 0.000 description 4
- 239000000945 filler Substances 0.000 description 3
- 239000011777 magnesium Substances 0.000 description 3
- 229910052749 magnesium Inorganic materials 0.000 description 3
- 238000004321 preservation Methods 0.000 description 3
- GDSOZVZXVXTJMI-SNAWJCMRSA-N (e)-1-methylbut-1-ene-1,2,4-tricarboxylic acid Chemical compound OC(=O)C(/C)=C(C(O)=O)\CCC(O)=O GDSOZVZXVXTJMI-SNAWJCMRSA-N 0.000 description 2
- CIWBSHSKHKDKBQ-JLAZNSOCSA-N Ascorbic acid Chemical compound OC[C@H](O)[C@H]1OC(=O)C(O)=C1O CIWBSHSKHKDKBQ-JLAZNSOCSA-N 0.000 description 2
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 description 2
- 102000004190 Enzymes Human genes 0.000 description 2
- 108090000790 Enzymes Proteins 0.000 description 2
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 2
- 238000006555 catalytic reaction Methods 0.000 description 2
- 238000005516 engineering process Methods 0.000 description 2
- 239000007788 liquid Substances 0.000 description 2
- 239000011159 matrix material Substances 0.000 description 2
- 238000012545 processing Methods 0.000 description 2
- 235000010265 sodium sulphite Nutrition 0.000 description 2
- 239000000758 substrate Substances 0.000 description 2
- WWILHZQYNPQALT-UHFFFAOYSA-N 2-methyl-2-morpholin-4-ylpropanal Chemical compound O=CC(C)(C)N1CCOCC1 WWILHZQYNPQALT-UHFFFAOYSA-N 0.000 description 1
- JPVYNHNXODAKFH-UHFFFAOYSA-N Cu2+ Chemical compound [Cu+2] JPVYNHNXODAKFH-UHFFFAOYSA-N 0.000 description 1
- RGHNJXZEOKUKBD-UHFFFAOYSA-N D-gluconic acid Natural products OCC(O)C(O)C(O)C(O)C(O)=O RGHNJXZEOKUKBD-UHFFFAOYSA-N 0.000 description 1
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 1
- RGHNJXZEOKUKBD-SQOUGZDYSA-N Gluconic acid Natural products OC[C@@H](O)[C@@H](O)[C@H](O)[C@@H](O)C(O)=O RGHNJXZEOKUKBD-SQOUGZDYSA-N 0.000 description 1
- WQZGKKKJIJFFOK-GASJEMHNSA-N Glucose Natural products OC[C@H]1OC(O)[C@H](O)[C@@H](O)[C@@H]1O WQZGKKKJIJFFOK-GASJEMHNSA-N 0.000 description 1
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 1
- PMZURENOXWZQFD-UHFFFAOYSA-L Sodium Sulfate Chemical compound [Na+].[Na+].[O-]S([O-])(=O)=O PMZURENOXWZQFD-UHFFFAOYSA-L 0.000 description 1
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 1
- 235000009392 Vitis Nutrition 0.000 description 1
- 241000219095 Vitis Species 0.000 description 1
- 230000003213 activating effect Effects 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- 230000000996 additive effect Effects 0.000 description 1
- BFNBIHQBYMNNAN-UHFFFAOYSA-N ammonium sulfate Chemical compound N.N.OS(O)(=O)=O BFNBIHQBYMNNAN-UHFFFAOYSA-N 0.000 description 1
- 229910052921 ammonium sulfate Inorganic materials 0.000 description 1
- 235000011130 ammonium sulphate Nutrition 0.000 description 1
- 235000010323 ascorbic acid Nutrition 0.000 description 1
- 229960005070 ascorbic acid Drugs 0.000 description 1
- 239000011668 ascorbic acid Substances 0.000 description 1
- 235000008429 bread Nutrition 0.000 description 1
- 239000001569 carbon dioxide Substances 0.000 description 1
- 229910002092 carbon dioxide Inorganic materials 0.000 description 1
- 239000003054 catalyst Substances 0.000 description 1
- 235000013339 cereals Nutrition 0.000 description 1
- 239000003638 chemical reducing agent Substances 0.000 description 1
- 230000009514 concussion Effects 0.000 description 1
- 229910001431 copper ion Inorganic materials 0.000 description 1
- 238000005260 corrosion Methods 0.000 description 1
- 238000006356 dehydrogenation reaction Methods 0.000 description 1
- 235000013332 fish product Nutrition 0.000 description 1
- 235000013312 flour Nutrition 0.000 description 1
- 235000012208 gluconic acid Nutrition 0.000 description 1
- 239000000174 gluconic acid Substances 0.000 description 1
- 239000008103 glucose Substances 0.000 description 1
- LDHBWEYLDHLIBQ-UHFFFAOYSA-M iron(3+);oxygen(2-);hydroxide;hydrate Chemical compound O.[OH-].[O-2].[Fe+3] LDHBWEYLDHLIBQ-UHFFFAOYSA-M 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 235000013622 meat product Nutrition 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 239000011734 sodium Substances 0.000 description 1
- 229910052708 sodium Inorganic materials 0.000 description 1
- 229910052938 sodium sulfate Inorganic materials 0.000 description 1
- 235000011152 sodium sulphate Nutrition 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 238000006277 sulfonation reaction Methods 0.000 description 1
- 229910052717 sulfur Inorganic materials 0.000 description 1
- 239000011593 sulfur Substances 0.000 description 1
- 239000004408 titanium dioxide Substances 0.000 description 1
- 235000013343 vitamin Nutrition 0.000 description 1
- 239000011782 vitamin Substances 0.000 description 1
- 229940088594 vitamin Drugs 0.000 description 1
- 229930003231 vitamin Natural products 0.000 description 1
- 150000003722 vitamin derivatives Chemical class 0.000 description 1
- 238000005406 washing Methods 0.000 description 1
- 238000001238 wet grinding Methods 0.000 description 1
Classifications
-
- A—HUMAN NECESSITIES
- A23—FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
- A23L—FOODS, FOODSTUFFS, OR NON-ALCOHOLIC BEVERAGES, NOT COVERED BY SUBCLASSES A21D OR A23B-A23J; THEIR PREPARATION OR TREATMENT, e.g. COOKING, MODIFICATION OF NUTRITIVE QUALITIES, PHYSICAL TREATMENT; PRESERVATION OF FOODS OR FOODSTUFFS, IN GENERAL
- A23L3/00—Preservation of foods or foodstuffs, in general, e.g. pasteurising, sterilising, specially adapted for foods or foodstuffs
- A23L3/34—Preservation of foods or foodstuffs, in general, e.g. pasteurising, sterilising, specially adapted for foods or foodstuffs by treatment with chemicals
- A23L3/3409—Preservation of foods or foodstuffs, in general, e.g. pasteurising, sterilising, specially adapted for foods or foodstuffs by treatment with chemicals in the form of gases, e.g. fumigation; Compositions or apparatus therefor
- A23L3/3418—Preservation of foods or foodstuffs, in general, e.g. pasteurising, sterilising, specially adapted for foods or foodstuffs by treatment with chemicals in the form of gases, e.g. fumigation; Compositions or apparatus therefor in a controlled atmosphere, e.g. partial vacuum, comprising only CO2, N2, O2 or H2O
- A23L3/3427—Preservation of foods or foodstuffs, in general, e.g. pasteurising, sterilising, specially adapted for foods or foodstuffs by treatment with chemicals in the form of gases, e.g. fumigation; Compositions or apparatus therefor in a controlled atmosphere, e.g. partial vacuum, comprising only CO2, N2, O2 or H2O in which an absorbent is placed or used
- A23L3/3436—Oxygen absorbent
-
- A—HUMAN NECESSITIES
- A23—FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
- A23V—INDEXING SCHEME RELATING TO FOODS, FOODSTUFFS OR NON-ALCOHOLIC BEVERAGES AND LACTIC OR PROPIONIC ACID BACTERIA USED IN FOODSTUFFS OR FOOD PREPARATION
- A23V2002/00—Food compositions, function of food ingredients or processes for food or foodstuffs
Landscapes
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Nutrition Science (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Food Science & Technology (AREA)
- Polymers & Plastics (AREA)
- Food Preservation Except Freezing, Refrigeration, And Drying (AREA)
- Meat, Egg Or Seafood Products (AREA)
- Silicates, Zeolites, And Molecular Sieves (AREA)
Abstract
The invention discloses a preparation method of a compound food deoxidizing agent, belongs to the technical field of deoxidizing agent preparation, and aims to overcome the defects of poor refreshment and corrosion prevention effects due to high moisture regain and low oxygen absorbing rate after use of the conventional iron-based deoxidizing agent with a poor low-temperature deoxidizing effect. The preparation method of the compound food deoxidizing agent comprises the following steps: making montmorillonite serving as a filling substance load platinum ions provided through a chloroplatinic acid solution; smelting and wrapping the platinum ions at a high temperature to increase the catalyzing efficiency; burning magnesium powder in nitrogen gas to generate magnesium oxide, and smelting the magnesium oxide on the surface of the filling substance; oxidizing the humic acid with hydrogen peroxide; sulfonating the humic acid oxide through sulfur trioxide to improve absorption of sulfur dioxide and ammonia gas; mixing the humic acid oxide with iron powder and sodium hydrosulfite to prepare the compound food deoxidizing agent. Compared with the conventional deoxidizing agent, the compound food deoxidizing agent prepared by the method has the advantages that the oxygen absorbing rate is increased by 18 to 22 percent, and the moisture regain after use is lowered by 26 to 35 percent.
Description
Technical field
The present invention relates to a kind of preparation method of complex food deoxidizer, belongs to deoxidizer preparing technical field.
Background technology
While food production and food processing is developed, food fresh keeping is highly valued people.Prevent to reach food
It is rotten, fresh-keeping, extend the purpose of effective period of food quality and shelf life, people employ various preservation techniques, such as cold preservation, irradiation, but
Facilitate the most and economic technology is using methods such as deoxidizer preservations.It is closed by removing in chemical reaction, short time
Oxygen in container, makes growth of the food in microorganisms such as anaerobic state, effective control antibacterial, mycetes, prevents Oxidation of Fat and Oils, from
And the color of food can be effectively kept, and prevent the nutrient substance such as vitamin to be oxidized destruction, extend effective period of food quality, one
As be to be made up of host, filler, activating agent, modifying agent or Function Extension agent.
Deoxidizer can be divided into organic substrate deoxidizer and inorganic matrix deoxidizer.Organic substrate deoxidizer has enzyme, anti-bad
Hematic acid etc..Ascorbic acid is in itself reducing agent, in the case of aerobic, makees that catalyst can be oxidized or dehydrogenation is anti-bad with copper ion
Hematic acid, so as to remove environment in oxygen, commonly use this method to remove food liquid in oxygen, it be at present use deoxidizer in safety
Property higher one kind, enzyme system deoxidizer it is conventional be the glycoxidative alcohol of Fructus Vitis viniferae, consume oxygen when being and being oxidized to gluconic acid using glucose
To reach deoxidation purpose.Inorganic matrix deoxidizer has reduced iron powder, its principle be iron powder in the presence of oxygen and vapor,
It is oxidized to hydrated ferric oxide..At present conventional deoxidizer be easy to get with raw material, low cost, the application of safe iron series deoxidizers
It is most wide, iron series deoxidizers typically with iron powder as base stock, be widely used in wet bread flour, wet face, wet-milling silk, the wet point heart, half
The numerous foods such as dry fish product.But at present iron series deoxidizers also has that low-temperature deoxidation effect is poor, and high using rear regain, oxygen uptake is fast
Rate is low, causes the problems such as its is fresh-keeping, antiseptic effect is poor.
The content of the invention
The technical problem to be solved：It is poor for current iron series deoxidizers low-temperature deoxidation effect, using rear moisture regain
Rate is high, and speed of oxygen intake is low, causes the drawbacks of its is fresh-keeping, antiseptic effect is poor, there is provided one kind using montmorillonite as filler,
Platinum ion is provided by platinum acid chloride solution, montmorillonite-loaded platinum ion, and melting parcel platinum ion at high temperature is made, increases catalysis
Efficiency, is burnt in nitrogen by magnesium powder and generates magnesium nitride, and is melted in filler surface, uses hydrogen peroxide oxidation humic acid,
Sulfonation is carried out to aoxidizing humic acid by sulfur trioxide, increases the absorption to sulfur dioxide and ammonia, finally with iron powder, Lian Erya
The method that sodium sulfate is mixed with complex food deoxidizer, the present invention generates hydrogen-oxygen using magnesium nitride and water under the catalysis of platinum
Change magnesium and ammonia, ammonia, the titanium dioxide that ammonia and sodium dithionite are produced with oxygen reaction are adsorbed by the humic acid for processing
Sulfur, produces ammonium hydrogen sulfate in the environment of having water, and quickly with oxygen reaction generates ammonium sulfate, to protecting during iron powder deoxidation,
The principle of deoxidation effectiveness being improved simultaneously, efficiently solving that traditional iron series deoxidizers low-temperature deoxidation effect is poor, regain is high, and oxygen uptake is fast
Rate is low, the problem for causing its fresh-keeping, antiseptic effect poor.Preparation process of the present invention is simple, and gained complex food deoxidizer has
Preferably low-temperature deoxidation effect, can effectively reduce regain after use, improve speed of oxygen intake, with preferably fresh-keeping, anti-corrosion effect
Really.
To solve above-mentioned technical problem, the present invention is using technical scheme as described below：
（1）In mass ratio 1:3, take montmorillonite and the platinum acid chloride solution of mass fraction 10% is put in container, and container is placed in super
Shake in sound wave vibrator after 30~40min and filter, filtering residue is put in calcining furnace, design temperature is 1800~1900 DEG C, is forged
1~2h is burnt, then room temperature is cooled to the furnace, calcined material is removed and placed in crush in pulverizer, cross 200 mesh sieves, collection is sieved
Grain；
（2）The above-mentioned granule that sieves is mixed homogeneously with the magnesium powder of its quality 10~15%, and is put in electric smelter, protected using nitrogen
Shield, design temperature is 810~850 DEG C, insulation 40~50min of melting, after naturally cooling to room temperature, molten mixture is taken out,
In being put into vacuum ball grinder, by ratio of grinding media to material 20:1, a diameter of 50mm steel balls are added, with 150r/min 40~50min of ball milling, collect
Ball milling thing, it is standby；
（3）By mass percentage, it is 10% hydrogen peroxide, 3~5% sulfur trioxide to take 45~50% mass fractions, and remaining is 300 mesh
Humic acidss, are first put into 300 mesh humic acid and mass fraction in flask for 10% hydrogen peroxide, with 150r/min stirring 50~
After 70min, sulfur trioxide is added, 4~5h of stirring reaction is subsequently filtered, in being in cleaning mixture using distilled water wash filtering residue
Property, then filtering residue is put in air-dry machine air-dried, the air-dried thing of collection；
（4）Count by weight, weigh 40~50 parts of steps（2）Standby ball milling thing, 30~35 parts of above-mentioned air-dried things, 28~33
Part iron powder, 12~13 parts of Sodium Chloride and 8~10 parts of sodium dithionites, in being sequentially placed into mill, with 200r/min 30 are milled
~40min, collects thing of milling, and is put into sealing preserve in hermetic bag, you can obtain complex food deoxidizer.
The application process of the present invention：To be put in food pack after complex food deoxidant packing obtained in the present invention,
The control deoxidizer amount of being put into accounts for the 1.2~1.3% of food quality, then food pack is placed under the conditions of -8~40 DEG C, 3~4
After it, after testing oxygen inhalation rate is 71.6~82.3%, can in effective control food the microorganism such as antibacterial, mycete growth, prevent
Oxidation of Fat and Oils, and food color can be effectively kept, prevent nutrient substance to be oxidized destruction, storage food moisture regain in 2~3 months
Rate is 5.3~7.8%, is worthy to be popularized and uses.
Compared with additive method, Advantageous Effects are the present invention：
（1）Preparation process of the present invention is simple, and gained complex food deoxidizer low-temperature deoxidation effect is good, and oxygen inhalation rate is than traditional deoxidizer
Improve 26~35%；
（2）Complex food deoxidizer of the present invention reduces 25~30% using rear regain than traditional deoxidizer, with preferable
Fresh-keeping, antiseptic effect, can be applicable to cake food, leisure food, solid carbon dioxide product, dry meat products field.
Specific embodiment
First in mass ratio 1:3, take montmorillonite and the platinum acid chloride solution of mass fraction 10% is put in container, and container is put
Shake in ultrasonic wave concussion device after 30~40min and filter, filtering residue is put in calcining furnace, design temperature is 1800~1900
DEG C, 1~2h is calcined, then cool to room temperature with the furnace, calcined material is removed and placed in crush in pulverizer, 200 mesh sieves are crossed, collected
Sieve granule；Then the above-mentioned granule that sieves is mixed homogeneously with the magnesium powder of its quality 10~15%, and is put in electric smelter, using nitrogen
Gas shielded, design temperature is 810~850 DEG C, insulation 40~50min of melting, after naturally cooling to room temperature, molten mixture is taken
Go out, in being put into vacuum ball grinder, by ratio of grinding media to material 20:1, a diameter of 50mm steel balls are added, with 150r/min 40~50min of ball milling,
Ball milling thing is collected, it is standby；Again by mass percentage, 45~50% mass fractions are taken for 10% hydrogen peroxide, 3~5% sulfur trioxide,
Remaining is 300 mesh humic acidss, first 300 mesh humic acid and mass fraction is put in flask for 10% hydrogen peroxide, with 150r/min
After 50~70min of stirring, sulfur trioxide is added, 4~5h of stirring reaction is subsequently filtered, using distilled water wash filtering residue to washing
Liquid is washed in neutrality, then filtering residue is put in air-dry machine air-dried, the air-dried thing of collection；Finally count by weight, weigh 40~50 parts
Standby ball milling thing, 30~35 parts of above-mentioned air-dried things, 28~33 parts of iron powders, 12~13 parts of Sodium Chloride and 8~10 parts of sulfurous of company two
Sour sodium, in being sequentially placed into mill, is milled 30~40min with 200r/min, and collection is milled thing, is put into sealing in hermetic bag and is protected
Deposit, you can obtain complex food deoxidizer.
Example 1
First in mass ratio 1:3, take montmorillonite and the platinum acid chloride solution of mass fraction 10% is put in container, and container is placed in super
Shake in sound wave vibrator after 30min and filter, filtering residue is put in calcining furnace, design temperature is 1800 DEG C, calcines 1h, then with stove
Room temperature is cooled to, calcined material is removed and placed in crush in pulverizer, cross 200 mesh sieves, collect the granule that sieves；Then by above-mentioned mistake
Sieve granule is mixed homogeneously with the magnesium powder of its quality 10%, and is put in electric smelter, is protected using nitrogen, and design temperature is 810 DEG C,
Insulation melting 40min, after naturally cooling to room temperature, molten mixture is taken out, in being put into vacuum ball grinder, by ratio of grinding media to material 20:
1, a diameter of 50mm steel balls are added, with 150r/min ball milling 40min, ball milling thing is collected, it is standby；Again by mass percentage, take
45% mass fraction is 10% hydrogen peroxide, 3% sulfur trioxide, and remaining is 300 mesh humic acidss, first by 300 mesh humic acid and quality point
Number is put in flask for 10% hydrogen peroxide, is stirred after 50min with 150r/min, adds sulfur trioxide, stirring reaction 4h, subsequently
Filtration, using distilled water wash filtering residue to cleaning mixture in neutrality, then filtering residue is put in air-dry machine air-dried, the air-dried thing of collection；Most
Count by weight afterwards, weigh 40 parts of standby ball milling things, 30 parts of above-mentioned air-dried things, 28 parts of iron powders, 12 parts of Sodium Chloride and 8 parts of companies
Sodium sulfite, in being sequentially placed into mill, is milled 30min with 200r/min, and collection is milled thing, is put into sealing in hermetic bag and is protected
Deposit, you can obtain complex food deoxidizer.
To be put in food pack after complex food deoxidant packing obtained in the present invention, the control deoxidizer amount of being put into is accounted for
The 1.2% of food quality, then food pack is placed under the conditions of -8 DEG C, after 3 days, after testing oxygen inhalation rate is 71.6%, can be had
The growth of the microorganism such as antibacterial, mycete, prevents Oxidation of Fat and Oils in effect control food, and can effectively keep food color, prevents
Only nutrient substance is oxidized destruction, and 2 months food regains of storage are 5.3%, are worthy to be popularized and use.
Example 2
First in mass ratio 1:3, take montmorillonite and the platinum acid chloride solution of mass fraction 10% is put in container, and container is placed in super
Shake in sound wave vibrator after 35min and filter, filtering residue is put in calcining furnace, design temperature is 1850 DEG C, calcines 2h, then with stove
Room temperature is cooled to, calcined material is removed and placed in crush in pulverizer, cross 200 mesh sieves, collect the granule that sieves；Then by above-mentioned mistake
Sieve granule is mixed homogeneously with the magnesium powder of its quality 13%, and is put in electric smelter, is protected using nitrogen, and design temperature is 830 DEG C,
Insulation melting 45min, after naturally cooling to room temperature, molten mixture is taken out, in being put into vacuum ball grinder, by ratio of grinding media to material 20:
1, a diameter of 50mm steel balls are added, with 150r/min ball milling 45min, ball milling thing is collected, it is standby；Again by mass percentage, take
48% mass fraction is 10% hydrogen peroxide, 4% sulfur trioxide, and remaining is 300 mesh humic acidss, first by 300 mesh humic acid and quality point
Number is put in flask for 10% hydrogen peroxide, is stirred after 60min with 150r/min, adds sulfur trioxide, stirring reaction 5h, subsequently
Filtration, using distilled water wash filtering residue to cleaning mixture in neutrality, then filtering residue is put in air-dry machine air-dried, the air-dried thing of collection；Most
Count by weight afterwards, weigh 45 parts of standby ball milling things, 33 parts of above-mentioned air-dried things, 30 parts of iron powders, 13 parts of Sodium Chloride and 9 parts of companies
Sodium sulfite, in being sequentially placed into mill, is milled 35min with 200r/min, and collection is milled thing, is put into sealing in hermetic bag and is protected
Deposit, you can obtain complex food deoxidizer.
To be put in food pack after complex food deoxidant packing obtained in the present invention, the control deoxidizer amount of being put into is accounted for
The 1.3% of food quality, then food pack is placed under the conditions of 16 DEG C, after 4 days, after testing oxygen inhalation rate is 76.9%, can be had
The growth of the microorganism such as antibacterial, mycete, prevents Oxidation of Fat and Oils in effect control food, and can effectively keep food color, prevents
Only nutrient substance is oxidized destruction, and 3 months food regains of storage are 6.5%, are worthy to be popularized and use.
Example 3
First in mass ratio 1:3, take montmorillonite and the platinum acid chloride solution of mass fraction 10% is put in container, and container is placed in super
Shake in sound wave vibrator after 40min and filter, filtering residue is put in calcining furnace, design temperature is 1900 DEG C, calcines 2h, then with stove
Room temperature is cooled to, calcined material is removed and placed in crush in pulverizer, cross 200 mesh sieves, collect the granule that sieves；Then by above-mentioned mistake
Sieve granule is mixed homogeneously with the magnesium powder of its quality 15%, and is put in electric smelter, is protected using nitrogen, and design temperature is 850 DEG C,
Insulation melting 50min, after naturally cooling to room temperature, molten mixture is taken out, in being put into vacuum ball grinder, by ratio of grinding media to material 20:
1, a diameter of 50mm steel balls are added, with 150r/min ball milling 50min, ball milling thing is collected, it is standby；Again by mass percentage, take
50% mass fraction is 10% hydrogen peroxide, 5% sulfur trioxide, and remaining is 300 mesh humic acidss, first by 300 mesh humic acid and quality point
Number is put in flask for 10% hydrogen peroxide, is stirred after 70min with 150r/min, adds sulfur trioxide, stirring reaction 5h, subsequently
Filtration, using distilled water wash filtering residue to cleaning mixture in neutrality, then filtering residue is put in air-dry machine air-dried, the air-dried thing of collection；Most
Count by weight afterwards, weigh 50 parts of standby ball milling things, 35 parts of above-mentioned air-dried things, 33 parts of iron powders, 13 parts of Sodium Chloride and 10 parts
Sodium dithionite, in being sequentially placed into mill, is milled 40min with 200r/min, and collection is milled thing, is put in hermetic bag and is sealed
Preserve, you can obtain complex food deoxidizer.
To be put in food pack after complex food deoxidant packing obtained in the present invention, the control deoxidizer amount of being put into is accounted for
The 1.3% of food quality, then food pack is placed under the conditions of 40 DEG C, after 4 days, after testing oxygen inhalation rate is 82.3%, can be had
The growth of the microorganism such as antibacterial, mycete, prevents Oxidation of Fat and Oils in effect control food, and can effectively keep food color, prevents
Only nutrient substance is oxidized destruction, and 3 months food regains of storage are 7.8%, are worthy to be popularized and use.
Claims (1)
1. a kind of preparation method of complex food deoxidizer, it is characterised in that concrete preparation process is：
（1）In mass ratio 1:3, take montmorillonite and the platinum acid chloride solution of mass fraction 10% is put in container, and container is placed in super
Shake in sound wave vibrator after 30~40min and filter, filtering residue is put in calcining furnace, design temperature is 1800~1900 DEG C, is forged
1~2h is burnt, then room temperature is cooled to the furnace, calcined material is removed and placed in crush in pulverizer, cross 200 mesh sieves, collection is sieved
Grain；
（2）The above-mentioned granule that sieves is mixed homogeneously with the magnesium powder of its quality 10~15%, and is put in electric smelter, protected using nitrogen
Shield, design temperature is 810~850 DEG C, insulation 40~50min of melting, after naturally cooling to room temperature, molten mixture is taken out,
In being put into vacuum ball grinder, by ratio of grinding media to material 20:1, a diameter of 50mm steel balls are added, with 150r/min 40~50min of ball milling, collect
Ball milling thing, it is standby；
（3）By mass percentage, it is 10% hydrogen peroxide, 3~5% sulfur trioxide to take 45~50% mass fractions, and remaining is 300 mesh
Humic acidss, are first put into 300 mesh humic acid and mass fraction in flask for 10% hydrogen peroxide, with 150r/min stirring 50~
After 70min, sulfur trioxide is added, 4~5h of stirring reaction is subsequently filtered, in being in cleaning mixture using distilled water wash filtering residue
Property, then filtering residue is put in air-dry machine air-dried, the air-dried thing of collection；
（4）Count by weight, weigh 40~50 parts of steps（2）Standby ball milling thing, 30~35 parts of above-mentioned air-dried things, 28~33
Part iron powder, 12~13 parts of Sodium Chloride and 8~10 parts of calcium chloride, in being sequentially placed into mill, 30 are milled with 200r/min~
40min, collects thing of milling, and is put into sealing preserve in hermetic bag, you can obtain complex food deoxidizer.
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Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108936194A (en) * | 2018-07-24 | 2018-12-07 | 武汉轻工大学 | Colloid carbon ball/nano zero-valence iron composite material preparation method, food deoxidant and preparation method thereof |
| CN109965178A (en) * | 2018-11-17 | 2019-07-05 | 沈哲明 | A kind of food fresh keeping packet |
| CN115297945A (en) * | 2020-03-19 | 2022-11-04 | 三菱瓦斯化学株式会社 | Oxygen scavenger composition |
Citations (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS59179790A (en) * | 1983-03-29 | 1984-10-12 | Mitsubishi Gas Chem Co Inc | Method for preventing discoloration of metallic product |
| JPS6255820B2 (en) * | 1980-02-19 | 1987-11-21 | Mitsubishi Gas Chemical Co | |
| CN101700053A (en) * | 2009-10-23 | 2010-05-05 | 南京农业大学 | Mixed type special deoxidizer for ham and preparation method |
| CN102511896A (en) * | 2011-12-02 | 2012-06-27 | 华南理工大学 | Difunctional deoxidier capable of quickly dehumidifying and preparation method thereof |
| CN103653185A (en) * | 2013-11-13 | 2014-03-26 | 广西弘耀祥科技有限公司 | Moisture-proof deoxidizing agent for foodstuff |
| CN105360876A (en) * | 2014-08-21 | 2016-03-02 | 武汉凌科达科技有限公司 | Preparation method of deoxidizer for foods |
| CN105433190A (en) * | 2014-08-21 | 2016-03-30 | 武汉凌科达科技有限公司 | Deoxidizer for foodstuff |
-
2016
- 2016-11-22 CN CN201611030345.7A patent/CN106666323B/en active Active
Patent Citations (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS6255820B2 (en) * | 1980-02-19 | 1987-11-21 | Mitsubishi Gas Chemical Co | |
| JPS59179790A (en) * | 1983-03-29 | 1984-10-12 | Mitsubishi Gas Chem Co Inc | Method for preventing discoloration of metallic product |
| CN101700053A (en) * | 2009-10-23 | 2010-05-05 | 南京农业大学 | Mixed type special deoxidizer for ham and preparation method |
| CN102511896A (en) * | 2011-12-02 | 2012-06-27 | 华南理工大学 | Difunctional deoxidier capable of quickly dehumidifying and preparation method thereof |
| CN103653185A (en) * | 2013-11-13 | 2014-03-26 | 广西弘耀祥科技有限公司 | Moisture-proof deoxidizing agent for foodstuff |
| CN105360876A (en) * | 2014-08-21 | 2016-03-02 | 武汉凌科达科技有限公司 | Preparation method of deoxidizer for foods |
| CN105433190A (en) * | 2014-08-21 | 2016-03-30 | 武汉凌科达科技有限公司 | Deoxidizer for foodstuff |
Non-Patent Citations (1)
| Title |
|---|
| 王佳媚，等: "混合型火腿专用脱氧剂研制及脱氧特性研究", 《食品科学》 * |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108936194A (en) * | 2018-07-24 | 2018-12-07 | 武汉轻工大学 | Colloid carbon ball/nano zero-valence iron composite material preparation method, food deoxidant and preparation method thereof |
| CN109965178A (en) * | 2018-11-17 | 2019-07-05 | 沈哲明 | A kind of food fresh keeping packet |
| CN115297945A (en) * | 2020-03-19 | 2022-11-04 | 三菱瓦斯化学株式会社 | Oxygen scavenger composition |
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| CN106666323B (en) | 2019-12-06 |
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Address after: 313300 Xiaoyuan village, Zhuanshan Township, Anji County, Huzhou City, Zhejiang Province Patentee after: Zhejiang huaweiheng Food Co.,Ltd. Patentee after: Hangzhou huaweiheng Biotechnology Co., Ltd Address before: 313300 Xiaoyuan village, Zhuanshan Township, Anji County, Huzhou City, Zhejiang Province Patentee before: Zhejiang huaweiheng Food Co.,Ltd. Patentee before: Hangzhou huaweiheng Food Co., Ltd |
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