CN106654361A - Three-electrode device and preparation method thereof - Google Patents

Three-electrode device and preparation method thereof Download PDF

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Publication number
CN106654361A
CN106654361A CN201710041967.8A CN201710041967A CN106654361A CN 106654361 A CN106654361 A CN 106654361A CN 201710041967 A CN201710041967 A CN 201710041967A CN 106654361 A CN106654361 A CN 106654361A
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China
Prior art keywords
electrode
lead bar
fixedly connected
metal rod
bar
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Pending
Application number
CN201710041967.8A
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Chinese (zh)
Inventor
刘铭辉
连林
郑媛媛
薛驰
缪永华
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Zhongtian Energy Storage Technology Co Ltd
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Zhongtian Energy Storage Technology Co Ltd
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Priority to CN201710041967.8A priority Critical patent/CN106654361A/en
Publication of CN106654361A publication Critical patent/CN106654361A/en
Pending legal-status Critical Current

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    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M10/00Secondary cells; Manufacture thereof
    • H01M10/05Accumulators with non-aqueous electrolyte
    • H01M10/052Li-accumulators
    • H01M10/0525Rocking-chair batteries, i.e. batteries with lithium insertion or intercalation in both electrodes; Lithium-ion batteries
    • GPHYSICS
    • G01MEASURING; TESTING
    • G01NINVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES
    • G01N27/00Investigating or analysing materials by the use of electric, electrochemical, or magnetic means
    • G01N27/26Investigating or analysing materials by the use of electric, electrochemical, or magnetic means by investigating electrochemical variables; by using electrolysis or electrophoresis
    • G01N27/403Cells and electrode assemblies
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M10/00Secondary cells; Manufacture thereof
    • H01M10/05Accumulators with non-aqueous electrolyte
    • H01M10/058Construction or manufacture
    • H01M10/0587Construction or manufacture of accumulators having only wound construction elements, i.e. wound positive electrodes, wound negative electrodes and wound separators
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M50/00Constructional details or processes of manufacture of the non-active parts of electrochemical cells other than fuel cells, e.g. hybrid cells
    • H01M50/10Primary casings; Jackets or wrappings
    • H01M50/183Sealing members
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02EREDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E60/00Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
    • Y02E60/10Energy storage using batteries
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02PCLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P70/00Climate change mitigation technologies in the production process for final industrial or consumer products
    • Y02P70/50Manufacturing or production processes characterised by the final manufactured product

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  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Electrochemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Manufacturing & Machinery (AREA)
  • Health & Medical Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Molecular Biology (AREA)
  • Physics & Mathematics (AREA)
  • Analytical Chemistry (AREA)
  • Biochemistry (AREA)
  • General Health & Medical Sciences (AREA)
  • General Physics & Mathematics (AREA)
  • Immunology (AREA)
  • Pathology (AREA)
  • Materials Engineering (AREA)
  • Secondary Cells (AREA)
  • Battery Electrode And Active Subsutance (AREA)

Abstract

The invention discloses a three-electrode device and a preparation method thereof. The three-electrode device comprises an upper cover, a cup body, electrode metal bars, lead strips, a roll core, a membrane a, a membrane b and a reference electrode, wherein the electrode metal bars run through the upper cover; one end of each electrode metal bar is fixedly connected with one corresponding lead strip; the lead strips are arranged in the cup body; the side position of the bottom end part of the roll core is fixedly connected with the reference electrode; the membrane a is fixedly connected between the roll core and the reference electrode; the membrane b is also fixedly connected with the outer surface of the reference electrode; a sealing ring accommodating groove is formed in the inner side of the upper end part of the cup body; a sealing ring is fixedly arranged in the sealing ring accommodating groove; and the upper cover is fixedly connected with the upper end part of the cup body. Through arrangement of the sealing ring, the air-tightness of the three-electrode device is effectively improved; the wrapped reference electrode is attached to the roll core, the membrane a is arranged between the reference electrode and the roll core and the upper cover is insulated with the cup body, so that the insulating performance is effectively strengthened; and meanwhile, the three-electrode device is simple and convenient to manufacture and suitable for various wound battery cores.

Description

A kind of three electrode assemblies and preparation method thereof
Technical field
The invention belongs to technical field of lithium ion, and in particular to a kind of three electrode assembly and preparation method thereof.
Background technology
Three electrode assemblies are the infrastructure devices for studying electrochemical reaction process, in electrochemical analysis and electrochemical energy storage field There is application widely.Three traditional electrode assemblies, are only applicable to water system and open wide system, it is difficult to suitable for including lithium mostly Ion battery is in the high system of interior sealing requirements.
It is actually rare for three electrode assemblies of convoluted battery core potentiometric analysis, and existing apparatus making complexity, disadvantage are numerous It is many, it is difficult to meet the basic technology requirement of sealing and insulating properties in many cases.
The content of the invention
Present invention aims to the deficiencies in the prior art, now provide a kind of good seal performance, assembling simple three Electrode assembly and preparation method thereof.
To solve above-mentioned technical problem, the technical solution used in the present invention is:A kind of three electrode assemblies, its innovative point exists In:Including upper lid, cup, electrode metal rod, lead bar, core, barrier film a, barrier film b and reference electrode, the electrode metal rod Through upper lid, and electrode metal rod is fixedly connected with upper lid, and one end of the electrode metal rod is fixedly connected leaded Bar, the lead bar is arranged in cup, and the bottom side position of the core is fixedly connected with reference electrode, the core and ginseng Than being also fixedly connected with a barrier film a between electrode, the outer surface of the reference electrode is also fixedly connected with a barrier film b, the cup Body upper end inner side offers a sealing ring holding tank, and sealing ring, the upper lid are installed with the sealing ring holding tank It is formed by fixedly connecting with cup upper end.
Further, the electrode metal rod includes electrode metal rod a, electrode metal rod b and electrode metal rod c;It is described Lead bar includes lead bar a, lead bar b and lead bar c, and the electrode metal rod a is fixedly connected with lead bar a, described Electrode metal rod b is fixedly connected with lead bar b, and the electrode metal rod c is fixedly connected with lead bar c.
Further, the positive and negative lug of the reference electrode, core and lead bar are fixedly connected by electrode holder, described Lead bar is fixedly connected with electrode metal rod by electrode holder.
Another object of the present invention is to disclose a kind of preparation method of three electrode assemblies, and its innovative point is:Concrete step It is rapid as follows:
(1)One layer of barrier film a is enclosed with standby core outer surface, then reference electrode T-type structure is cut into, by lead bar a It is attached with reference electrode by way of extruding;
(2)The reference electrode of T-type structure is wrapped in into the outer surface of barrier film a, the reference electrode afterbody bending is attached to core Bottom;
(3)Then the outer surface in reference electrode is enclosed with barrier film b;
(4)Positive and negative lug is fixedly connected respectively by electrode holder with lead bar b, lead bar c, lead bar b, lead bar c It is fixedly connected with electrode metal rod b, electrode metal rod c respectively by electrode holder, by lead bar a by electrode holder and electrode Metal bar a is fixedly connected;
(5)Inject electrolyte in cup, the height submergence core of the electrolyte, but less than the height of reference electrode;
(6)Sealing ring is placed in sealing ring holding tank, the core that is connected on upper lid of completing slowly is put into cup It is interior, upper lid is fastened with cup with screw, complete the preparation of three electrode assemblies.
Further, the step(1)Or(4)In lead bar a be copper wire, lead bar b be aluminum strip, lead bar c be nickel Bar;The electrode metal rod a is copper rod, and electrode metal rod b is aluminium bar, and electrode metal rod c is nickel rod.
Further, the reference electrode is lithium piece.
Beneficial effects of the present invention are as follows:The present invention provides a kind of three electrode assembly, including upper lid, cup, and arranges Electrode metal rod on upper lid, the sealing ring being arranged between lid and cup, by the setting of sealing ring, is effectively improved The sealing of three electrode assemblies, the lead bar, core, the electrolyte that are arranged in cup, core is attached with the reference electricity for wrapping Pole, is provided with barrier film a between reference electrode and core, upper lid insulate with cup, reference electrode and the positive and negative lug of core with Draw line and curve connection, lead bar is connected with electrode metal rod, effectively enhances the performance of insulation, while the present invention makes simple side Just, and suitable for all kinds of convoluted battery cores.
Description of the drawings
Fig. 1 is the overall structure diagram of the present invention.
Specific embodiment
Hereinafter embodiments of the present invention are illustrated by particular specific embodiment, those skilled in the art can be by this explanation Content disclosed by book understands easily other advantages and effect of the present invention.
It is illustrated in figure 1 the overall structure diagram of the present invention, a kind of three electrode assembly, including upper lid 4, cup 5, electrode Metal bar, lead bar, core 10, barrier film a15, barrier film b16 and reference electrode 9, electrode metal rod runs through upper lid 4, and electrode Metal bar is fixedly connected with upper lid 4, and one end of electrode metal rod is fixedly connected leaded bar, and lead bar is arranged on cup 5 Interior, the bottom side position of core 10 is fixedly connected with reference electrode 9, and one is also fixedly connected between core 10 and reference electrode 9 Barrier film a15, the outer surface of reference electrode 9 is also fixedly connected with a barrier film b16, and the upper end of cup 5 inner side offers a sealing ring Sealing ring 13 is installed with holding tank 14, sealing ring holding tank 14, upper lid 4 is formed by fixedly connecting with the upper end of cup 5.
Electrode metal rod includes electrode metal rod a1, electrode metal rod b2 and electrode metal rod c3;Lead bar includes lead Bar a11, lead bar b6 and lead bar c7, electrode metal rod a1 are fixedly connected with lead bar a11, electrode metal rod b2 with draw Lines b6 is fixedly connected, and electrode metal rod c3 is fixedly connected with lead bar c7.
Reference electrode 9, the positive and negative lug of core 10 and lead bar are fixedly connected by electrode holder, and lead bar is golden with electrode Category rod is fixedly connected by electrode holder.
A kind of preparation method of three electrode assemblies, comprises the following steps that:
(1)One layer of barrier film a15 is enclosed with the standby outer surface of core 10, then reference electrode 9 T-type structure is cut into, will be drawn Lines a11 is attached by way of extruding with reference electrode 9;
(2)The reference electrode 9 of T-type structure is wrapped in into the outer surface of barrier film a15, the bending of the afterbody of reference electrode 9 is attached to core 10 bottom;
(3)Then the outer surface in reference electrode 9 is enclosed with barrier film b16;
(4)Positive and negative lug is fixedly connected respectively by electrode holder with lead bar b6, lead bar c7, lead bar b6, lead Bar c7 is fixedly connected respectively by electrode holder with electrode metal rod b2, electrode metal rod c3, and lead bar a11 is passed through into electrode Folder is fixedly connected with electrode metal rod a1;
(5)Inject electrolyte in cup 5, the height submergence core of electrolyte, but less than the height of reference electrode 9;
(6)Sealing ring 13 is placed in sealing ring holding tank 14, the core 10 that is connected on upper lid 4 of completing slowly is put Enter in cup 5, fastened upper lid 4 with cup 5 with screw, complete the preparation of three electrode assemblies.
Feasible, lead bar a11 is copper wire, and lead bar b6 is aluminum strip, and lead bar c7 is nickel bar;Electrode metal rod a1 is copper Rod, electrode metal rod b2 is aluminium bar, and electrode metal rod c3 is nickel rod.
Feasible, reference electrode 9 is lithium piece.
The present invention provides a kind of three electrode assembly, including upper lid 4, cup 5, and the electrode metal being arranged on lid 4 Rod, the sealing ring 13 being arranged between lid 4 and cup 5, by the setting of sealing ring 13, effectively raises three electrode assemblies Sealing, be arranged in cup 5 lead bar, core 10, electrolyte, core 10 is attached with the reference electrode 9 for wrapping, reference Barrier film a15 is provided between electrode 9 and core 10, upper lid 4 insulate with cup 5, reference electrode 9 and the positive and negative lug of core 10 are equal With draw line and curve connection, lead bar is connected with electrode metal rod, effectively enhances the performance of insulation, while the present invention makes simple It is convenient, and suitable for all kinds of convoluted battery cores.
Above-described embodiment is presently preferred embodiments of the present invention, is not the restriction to technical solution of the present invention, as long as Without the technical scheme that creative work can be realized on the basis of above-described embodiment, it is regarded as falling into patent of the present invention Rights protection scope in.

Claims (6)

1. a kind of three electrode assembly, it is characterised in that:Including upper lid, cup, electrode metal rod, lead bar, core, barrier film a, every Film b and reference electrode, the electrode metal rod runs through upper lid, and electrode metal rod is fixedly connected with upper lid, the electricity One end of pole metal bar is fixedly connected leaded bar, and the lead bar is arranged in cup, and the bottom side position of the core is consolidated Surely reference electrode is connected with, a barrier film a, the appearance of the reference electrode is also fixedly connected between the core and reference electrode Face is also fixedly connected with a barrier film b, and the cup upper end inner side offers a sealing ring holding tank, the sealing ring holding tank Sealing ring is inside installed with, the upper lid is formed by fixedly connecting with cup upper end.
2. a kind of three electrode assembly according to claim 1, it is characterised in that:The electrode metal rod includes electrode metal Rod a, electrode metal rod b and electrode metal rod c;The lead bar includes lead bar a, lead bar b and lead bar c, the electrode Metal bar a is fixedly connected with lead bar a, and the electrode metal rod b is fixedly connected with lead bar b, the electrode gold Category rod c and lead bar c is fixedly connected.
3. a kind of three electrode assembly according to claim 1, it is characterised in that:The positive and negative lug of the reference electrode, core It is fixedly connected by electrode holder with lead bar, the lead bar is fixedly connected with electrode metal rod by electrode holder.
4. a kind of preparation method of three electrode assembly as claimed in claim 1, it is characterised in that:Comprise the following steps that:
(1)One layer of barrier film a is enclosed with standby core outer surface, then reference electrode T-type structure is cut into, by lead bar a It is attached with reference electrode by way of extruding;
(2)The reference electrode of T-type structure is wrapped in into the outer surface of barrier film a, the reference electrode afterbody bending is attached to core Bottom;
(3)Then the outer surface in reference electrode is enclosed with barrier film b;
(4)Positive and negative lug is fixedly connected respectively by electrode holder with lead bar b, lead bar c, lead bar b, lead bar c It is fixedly connected with electrode metal rod b, electrode metal rod c respectively by electrode holder, by lead bar a by electrode holder and electrode Metal bar a is fixedly connected;
(5)Inject electrolyte in cup, the height submergence core of the electrolyte, but less than the height of reference electrode;
(6)Sealing ring is placed in sealing ring holding tank, the core that is connected on upper lid of completing slowly is put into cup It is interior, upper lid is fastened with cup with screw, complete the preparation of three electrode assemblies.
5. the preparation method of a kind of three electrode assembly according to claim 4, it is characterised in that:The step(1)Or(4) In lead bar a be copper wire, lead bar b be aluminum strip, lead bar c be nickel bar;The electrode metal rod a be copper rod, electrode metal Rod b is aluminium bar, and electrode metal rod c is nickel rod.
6. the preparation method of a kind of three electrode assembly according to claim 4, it is characterised in that:The reference electrode is lithium Piece.
CN201710041967.8A 2017-01-20 2017-01-20 Three-electrode device and preparation method thereof Pending CN106654361A (en)

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Application Number Priority Date Filing Date Title
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Application Number Priority Date Filing Date Title
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Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN107607873A (en) * 2017-08-04 2018-01-19 深圳市比克动力电池有限公司 Three electrodes of cylindrical battery original position and preparation method thereof
CN111600077A (en) * 2020-05-29 2020-08-28 重庆金康新能源汽车有限公司 Battery cell with coated lithium reference electrode and method of providing
CN112335112A (en) * 2018-03-08 2021-02-05 瓦尔达微电池有限责任公司 Lithium ion battery for automobile energy storage device and manufacturing method thereof
CN114019390A (en) * 2021-09-30 2022-02-08 广东微电新能源有限公司 Three-electrode battery testing device
CN114018994A (en) * 2021-09-30 2022-02-08 广东微电新能源有限公司 Novel three-electrode battery testing device

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101216537A (en) * 2007-12-27 2008-07-09 上海万宏动力能源有限公司 Single-electrode potential measurement method suitable for alkaline sealed cell and its device
CN201904414U (en) * 2010-12-16 2011-07-20 天津力神电池股份有限公司 Three-electrode battery
US20140375325A1 (en) * 2013-06-20 2014-12-25 Hrl Laboratories, Llc Battery with reference electrode for voltage monitoring
CN106099164A (en) * 2016-08-23 2016-11-09 辽宁九夷锂能股份有限公司 A kind of cylindrical battery three electrode assembly and assemble method thereof

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101216537A (en) * 2007-12-27 2008-07-09 上海万宏动力能源有限公司 Single-electrode potential measurement method suitable for alkaline sealed cell and its device
CN201904414U (en) * 2010-12-16 2011-07-20 天津力神电池股份有限公司 Three-electrode battery
US20140375325A1 (en) * 2013-06-20 2014-12-25 Hrl Laboratories, Llc Battery with reference electrode for voltage monitoring
CN106099164A (en) * 2016-08-23 2016-11-09 辽宁九夷锂能股份有限公司 A kind of cylindrical battery three electrode assembly and assemble method thereof

Cited By (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN107607873A (en) * 2017-08-04 2018-01-19 深圳市比克动力电池有限公司 Three electrodes of cylindrical battery original position and preparation method thereof
CN112335112A (en) * 2018-03-08 2021-02-05 瓦尔达微电池有限责任公司 Lithium ion battery for automobile energy storage device and manufacturing method thereof
CN112335112B (en) * 2018-03-08 2023-07-28 瓦尔达微电池有限责任公司 Lithium ion battery for automobile energy storage device and manufacturing method thereof
CN111600077A (en) * 2020-05-29 2020-08-28 重庆金康新能源汽车有限公司 Battery cell with coated lithium reference electrode and method of providing
CN111600077B (en) * 2020-05-29 2021-07-06 重庆金康新能源汽车有限公司 Battery cell with coated lithium reference electrode and method of providing
CN114019390A (en) * 2021-09-30 2022-02-08 广东微电新能源有限公司 Three-electrode battery testing device
CN114018994A (en) * 2021-09-30 2022-02-08 广东微电新能源有限公司 Novel three-electrode battery testing device
CN114018994B (en) * 2021-09-30 2024-04-16 广东微电新能源有限公司 Three-electrode battery testing device

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