CN106653579A - OLED chroma adjustment method - Google Patents

OLED chroma adjustment method Download PDF

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Publication number
CN106653579A
CN106653579A CN201710008840.6A CN201710008840A CN106653579A CN 106653579 A CN106653579 A CN 106653579A CN 201710008840 A CN201710008840 A CN 201710008840A CN 106653579 A CN106653579 A CN 106653579A
Authority
CN
China
Prior art keywords
oled
photoresist
layer
colourities
film layer
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201710008840.6A
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Chinese (zh)
Inventor
徐湘伦
赵梦
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Wuhan China Star Optoelectronics Technology Co Ltd
Original Assignee
Wuhan China Star Optoelectronics Technology Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Wuhan China Star Optoelectronics Technology Co Ltd filed Critical Wuhan China Star Optoelectronics Technology Co Ltd
Priority to CN201710008840.6A priority Critical patent/CN106653579A/en
Publication of CN106653579A publication Critical patent/CN106653579A/en
Pending legal-status Critical Current

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Classifications

    • HELECTRICITY
    • H10SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
    • H10KORGANIC ELECTRIC SOLID-STATE DEVICES
    • H10K71/00Manufacture or treatment specially adapted for the organic devices covered by this subclass
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01LSEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
    • H01L21/00Processes or apparatus adapted for the manufacture or treatment of semiconductor or solid state devices or of parts thereof
    • H01L21/02Manufacture or treatment of semiconductor devices or of parts thereof
    • H01L21/027Making masks on semiconductor bodies for further photolithographic processing not provided for in group H01L21/18 or H01L21/34
    • H01L21/0271Making masks on semiconductor bodies for further photolithographic processing not provided for in group H01L21/18 or H01L21/34 comprising organic layers
    • H01L21/0273Making masks on semiconductor bodies for further photolithographic processing not provided for in group H01L21/18 or H01L21/34 comprising organic layers characterised by the treatment of photoresist layers
    • H01L21/0274Photolithographic processes
    • HELECTRICITY
    • H10SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
    • H10KORGANIC ELECTRIC SOLID-STATE DEVICES
    • H10K50/00Organic light-emitting devices
    • H10K50/80Constructional details
    • H10K50/85Arrangements for extracting light from the devices
    • H10K50/858Arrangements for extracting light from the devices comprising refractive means, e.g. lenses

Abstract

The invention provides an OLED chroma adjustment method which comprises the following steps of S101, after packaging an OLED by means of a packaging layer, applying first photoresist on the surface of the packaging layer, wherein a dyeing agent is doped in the first photoresist; S102, performing exposure processing on the first photoresist by means of a photo mask board; and S103, processing the first photoresist after exposure processing by means of developing agent, thereby obtaining second photoresist on which holes are distributed in an arrangement. Refractive index of the photoresist is adjusted through adding the dyeing agent into the photoresist, thereby improving an optical coupling function of an OLED element and adjusting chroma of the OLED.

Description

OLED colourity methods of adjustment
Technical field
The present invention relates to display technology field, more particularly to a kind of OLED colourities method of adjustment.
Background technology
Organic Light Emitting Diode (Organic light-emitting Diode, abbreviation OLED), it is autonomous by organic layer Luminescence display, due to not needing backlight, therefore with faster response time, bigger visible angle, higher contrast And lighter component quality, it is most potential flat panel display generally acknowledged at present the features such as low-power consumption.
At present, Organic Light Emitting Diode is made up of the sandwich construction with difference in functionality.Per layer material build-in attribute and It is very important with the compatibility of other layer materials.In sandwich construction, hole injection layer (HIL) is generally included, hole passes Defeated layer (HTL), luminescent layer (EML), electron transfer layer (ETL) and electron injecting layer (EIL) etc..Due to the refractive index of each layer Difference, can occur the phenomenon being totally reflected, the most of light for causing luminescent layer organic matter to produce when light is transmitted between the layers Loss.Only about 20% light can effectively be launched, and most light is all wasted in reflection between the layers, and this is to lead The main cause for causing Organic Light Emitting Diode external quantum efficiency relatively low.Increase microlens array (microlens in light path Array) optical coupling to improve OLED element is acted on, and is a kind of method for improving OLED element external quantum efficiency.
OLED Display Techniques have at present two kinds of implementation methods.The first adds colored filter (color with white light OLED Filter), second is RGB OLED, i.e., be made up of the OLED subpixel that can respectively launch redness, green and blue light. In RGB OLED, the colourity of three kinds of colors just into one of main standard of assessment OLED performances, in being also current OLED techniques A difficult point.
The content of the invention
The present invention provides a kind of OLED colourities method of adjustment, to solve prior art in OLED colourity it is not up to standard, from And affect the technical problem of OLED performances.
The present invention provides a kind of OLED colourities method of adjustment, including:
Step 101, after being packaged using encapsulated layer to OLED, encapsulation layer surface cover the first photoresist, first Adulterate coloring agent in photoresist;
Step 102, process is exposed using photomask blank to the first photoresist;
Step 103, is processed the first photoresist through exposure-processed using developer solution, to obtain the second photoetching Glue, has the hole in array distribution on the second photoresist.
Further, exposure-processed adopts ultraviolet exposure.
Further, photoresist is negative photoresist.
Further, photoresist is positive photoresist.
Further, also include before step 101, plate separation layer in the negative electrode of OLED, separation layer includes organic film Layer and inorganic thin film layer;Encapsulated layer is covered in insulation surface, to complete the encapsulation of OLED.
Further, encapsulated layer is silicon nitride layer.
Further, organic thin film layer is film layer.
Further, inorganic thin film layer is inorganic oxide film layer.
Further, the negative electrode plating separation layer in OLED is specifically included, by technique for atomic layer deposition and/or chemical gaseous phase Deposition technique plates separation layer in the negative electrode of OLED.
The present invention provides a kind of OLED colourities method of adjustment, and by adding coloring agent in the first photoresist second is adjusted The refractive index of photoresist, so as to the optical coupling for improving OLED element is acted on, to adjust the colourity of OLED, simultaneously as photoetching The characteristics of technology has high-res, the second photoresist obtained after typesetting is used as microlens array, such micro- Lens array is more flexible in design.
Description of the drawings
Hereinafter the present invention will be described in more detail based on embodiment and refer to the attached drawing.Wherein:
Fig. 1 is a schematic flow sheet of OLED colourities method of adjustment provided in an embodiment of the present invention;
Fig. 2 is that ultraviolet exposure provided in an embodiment of the present invention processes schematic diagram;
Fig. 3 is another schematic flow sheet of OLED colourities method of adjustment provided in an embodiment of the present invention.
In the accompanying drawings, identical part uses identical reference.Accompanying drawing is not drawn according to actual ratio.
Specific embodiment
Below in conjunction with accompanying drawing, the invention will be further described.
As shown in figure 1, the present invention provides a kind of OLED colourities method of adjustment, including:
Step 101, after being packaged using encapsulated layer to OLED, encapsulation layer surface cover the first photoresist, first Adulterate coloring agent in photoresist.Coloring agent can be RGB coloring agents.Adulterate in the photoresist coloring agent, can be used as colored filter Use.The refractive index of photoresist is adjusted by coloring agent, so as to adjust the colourity of OLED.First photoresist can be negative photo Glue, alternatively positive photoresist.
Step 102, process ultraviolet is exposed using photomask blank to the first photoresist.Preferably, exposure-processed is adopted Use ultraviolet exposure.There is specific pierced pattern in photomask blank, photomask blank is positioned over into the first photoresist surface, and it is right It carries out ultraviolet exposure, makes corresponding first photoresist of photomask blank openwork part obtain ultraviolet exposure.
Step 103, is processed the first photoresist through exposure-processed using developer solution, to obtain the second photoetching Glue, has the hole in array distribution on the second photoresist.When the first photoresist is positive photoresist, expose on the first photoresist The part of light process, i.e. the part being irradiated to by ultraviolet on the first photoresist will be dissolved in developer solution, using developer solution to the When one photoresist is processed, the part being irradiated to by ultraviolet can be cleaned out.When the first photoresist is negative photoresist, Part (the photomask blank not being irradiated to by ultraviolet on the part of process, i.e. the first photoresist is not exposed on first photoresist The part that non-openwork part is covered) developer solution will be dissolved in, it is not ultraviolet when being processed the first photoresist using developer solution The part that line is irradiated to can be cleaned out.Either using positive photoresist or negative photoresist, the second photoresist is required for With the hole in array distribution, the second photoresist that should have the hole in array distribution can be used as microlens array. Because the bore hole size in the second photoresist is with the hollow out size of photomask blank relevant, therefore design photomask blank can be passed through Hollow out size controlling the bore hole size of the second photoresist, so the bore hole size of the second photoresist can accomplish very little.When When two photoresists are used as microlens array, can further increase the flexibility of design.
Fig. 2 is that ultraviolet exposure processes schematic diagram.4 represent ultraviolet exposure in Fig. 2, and 1 is photomask blank, and 2 is the first light Photoresist, 3 is encapsulated layer.For negative photoresist, the part of ultraviolet exposure will be insoluble in developer solution, therefore ultraviolet exposes Can remain in follow-up development step in the part of light, without being partially soluble in developer solution, therefore the part for exposure Can be washed off in development step.For positive photoresist, the part of ultraviolet exposure will be dissolved in developer solution, the part meeting It is washed off in development step, the part without exposure will be insoluble in developer solution, and the part can remain in development step.
The characteristics of there is high-resolution due to the method for photoetching, therefore, the second photoresist is used as microlens array, The optical coupling effect of OLED element can be improved, to improve the external quantum efficiency of OLED element.Due to will after typesetting obtain second Photoresist is used as microlens array, and this microlens array can be made to accomplish less size, increased the flexible of design Property.The OLED colourity methods of adjustment that the present embodiment is provided, will be doped with the first photoresist of coloring agent as colored filter film To use, the colourity of light can be adjusted out, so as to the optical coupling for improving OLED element is acted on, to adjust the colourity of OLED, meanwhile, Because photoetching can reach very high resolution ratio, the photoresist after typesetting is used as microlens array, in design more Flexibly.
As shown in figure 3, in a specific embodiment of the present invention, step 100a and step are also included before step 101 100b。
Wherein, step 100a, in the negative electrode of OLED separation layer is plated, and separation layer includes organic thin film layer and inorganic thin film layer. Organic thin film layer is film layer.Inorganic thin film layer is inorganic oxide film layer.
In the another specific embodiment of the present invention, specifically include in the negative electrode plating separation layer of OLED, by atomic layer deposition Product technology and/or chemical vapour deposition technique plate separation layer in the negative electrode of OLED.
In the encapsulation step of OLED, by being deposited with one layer of separation layer on negative electrode, ald skill is then passed through again Organic thin film layer and inorganic thin film layer interaction are plated in OLED cathode zones by art and/or chemical vapour deposition technique, to avoid water Gas and oxygen enter OLED, cause OLED element to damage.
Step 100b, covers encapsulated layer, to complete the encapsulation of OLED in insulation surface.Preferably, encapsulated layer is nitridation Silicon layer.
Although by reference to preferred embodiment, invention has been described, in the situation without departing from the scope of the present invention Under, various improvement can be carried out to it and part therein can be replaced with equivalent.Especially, as long as there is no structure punching Prominent, the every technical characteristic being previously mentioned in each embodiment can combine in any way.The invention is not limited in text Disclosed in specific embodiment, but including all technical schemes for falling within the scope of the appended claims.

Claims (9)

1. a kind of OLED colourities method of adjustment, it is characterised in that include:
Step 101, after being packaged using encapsulated layer to OLED, in the encapsulation layer surface the first photoresist is covered, described Adulterate coloring agent in first photoresist;
Step 102, process is exposed using photomask blank to first photoresist;
Step 103, is processed first photoresist through exposure-processed, to obtain the second photoetching using developer solution Glue, has the hole in array distribution on second photoresist.
2. OLED colourities method of adjustment according to claim 1, it is characterised in that the exposure-processed is exposed using ultraviolet Light.
3. OLED colourities method of adjustment according to claim 1, it is characterised in that the photoresist is negative photoresist.
4. OLED colourities method of adjustment according to claim 1, it is characterised in that the photoresist is positive photoresist.
5. according to the arbitrary described OLED colourity methods of adjustment of claim 1-4, it is characterised in that also wrap before step 101 Include, in the negative electrode of OLED separation layer is plated, the separation layer includes organic thin film layer and inorganic thin film layer;In the insulation surface The encapsulated layer is covered, to complete the encapsulation of OLED.
6. OLED colourities method of adjustment according to claim 5, it is characterised in that the encapsulated layer is silicon nitride layer.
7. OLED colourities method of adjustment according to claim 5, it is characterised in that the organic thin film layer is that polyethylene is thin Film layer.
8. OLED colourities method of adjustment according to claim 5, it is characterised in that the inorganic thin film layer is inorganic oxide Thing film layer.
9. OLED colourities method of adjustment according to claim 5, it is characterised in that the negative electrode in OLED plates separation layer Specifically include, separation layer is plated in the negative electrode of OLED by technique for atomic layer deposition and/or chemical vapour deposition technique.
CN201710008840.6A 2017-01-06 2017-01-06 OLED chroma adjustment method Pending CN106653579A (en)

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Application Number Priority Date Filing Date Title
CN201710008840.6A CN106653579A (en) 2017-01-06 2017-01-06 OLED chroma adjustment method

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Application Number Priority Date Filing Date Title
CN201710008840.6A CN106653579A (en) 2017-01-06 2017-01-06 OLED chroma adjustment method

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2018223691A1 (en) * 2017-06-05 2018-12-13 京东方科技集团股份有限公司 Method for manufacturing array substrate, array substrate and display apparatus

Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101276104A (en) * 2007-03-29 2008-10-01 奇美电子股份有限公司 Semi-penetration and semi-reflection type LCD and colorful pixel
CN102024749A (en) * 2009-09-17 2011-04-20 中芯国际集成电路制造(上海)有限公司 Forming method of through hole
CN102468450A (en) * 2010-11-17 2012-05-23 上海广电电子股份有限公司 Manufacturing method of organic light emitting display device
US20150144918A1 (en) * 2013-11-22 2015-05-28 Samsung Electronics Co., Ltd. Method of manufacturing optical film for reducing color shift, organic light-emitting display apparatus using optical film for reducing color shift, and method of manufacturing the same
CN104882562A (en) * 2014-02-28 2015-09-02 海洋王照明科技股份有限公司 OLED and preparation method thereof

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101276104A (en) * 2007-03-29 2008-10-01 奇美电子股份有限公司 Semi-penetration and semi-reflection type LCD and colorful pixel
CN102024749A (en) * 2009-09-17 2011-04-20 中芯国际集成电路制造(上海)有限公司 Forming method of through hole
CN102468450A (en) * 2010-11-17 2012-05-23 上海广电电子股份有限公司 Manufacturing method of organic light emitting display device
US20150144918A1 (en) * 2013-11-22 2015-05-28 Samsung Electronics Co., Ltd. Method of manufacturing optical film for reducing color shift, organic light-emitting display apparatus using optical film for reducing color shift, and method of manufacturing the same
CN104882562A (en) * 2014-02-28 2015-09-02 海洋王照明科技股份有限公司 OLED and preparation method thereof

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2018223691A1 (en) * 2017-06-05 2018-12-13 京东方科技集团股份有限公司 Method for manufacturing array substrate, array substrate and display apparatus

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Application publication date: 20170510

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