CN106641482A - Compound pipeline and preparation process thereof - Google Patents

Compound pipeline and preparation process thereof Download PDF

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Publication number
CN106641482A
CN106641482A CN201610851267.0A CN201610851267A CN106641482A CN 106641482 A CN106641482 A CN 106641482A CN 201610851267 A CN201610851267 A CN 201610851267A CN 106641482 A CN106641482 A CN 106641482A
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CN
China
Prior art keywords
pipeline
compound
preparation technology
tdi
compound pipeline
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Application number
CN201610851267.0A
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Chinese (zh)
Inventor
陈生圣
王宏刚
高贵
任俊芳
杨生荣
王臻
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Lanzhou Institute of Chemical Physics LICP of CAS
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Lanzhou Institute of Chemical Physics LICP of CAS
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Priority to CN201610851267.0A priority Critical patent/CN106641482A/en
Publication of CN106641482A publication Critical patent/CN106641482A/en
Pending legal-status Critical Current

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Classifications

    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F16ENGINEERING ELEMENTS AND UNITS; GENERAL MEASURES FOR PRODUCING AND MAINTAINING EFFECTIVE FUNCTIONING OF MACHINES OR INSTALLATIONS; THERMAL INSULATION IN GENERAL
    • F16LPIPES; JOINTS OR FITTINGS FOR PIPES; SUPPORTS FOR PIPES, CABLES OR PROTECTIVE TUBING; MEANS FOR THERMAL INSULATION IN GENERAL
    • F16L9/00Rigid pipes
    • F16L9/14Compound tubes, i.e. made of materials not wholly covered by any one of the preceding groups
    • F16L9/147Compound tubes, i.e. made of materials not wholly covered by any one of the preceding groups comprising only layers of metal and plastics with or without reinforcement
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L75/00Compositions of polyureas or polyurethanes; Compositions of derivatives of such polymers
    • C08L75/04Polyurethanes
    • C08L75/08Polyurethanes from polyethers
    • EFIXED CONSTRUCTIONS
    • E21EARTH OR ROCK DRILLING; MINING
    • E21FSAFETY DEVICES, TRANSPORT, FILLING-UP, RESCUE, VENTILATION, OR DRAINING IN OR OF MINES OR TUNNELS
    • E21F15/00Methods or devices for placing filling-up materials in underground workings
    • E21F15/08Filling-up hydraulically or pneumatically
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2203/00Applications
    • C08L2203/18Applications used for pipes

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  • Engineering & Computer Science (AREA)
  • Chemical & Material Sciences (AREA)
  • General Engineering & Computer Science (AREA)
  • Mining & Mineral Resources (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Mechanical Engineering (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • General Life Sciences & Earth Sciences (AREA)
  • Geochemistry & Mineralogy (AREA)
  • Geology (AREA)
  • Lining Or Joining Of Plastics Or The Like (AREA)

Abstract

The invention provides a compound pipeline. The compound pipeline comprises a polymer lining pipe and a seamless steel pipe outer pipe. According to the raw material ratio, the polymer lining pipe comprises, by weight, 70%-82% of prepolymer, 10%-21% of curing agent, 6.5%-7.5% of lubricating agent and 2.0%-6.0% of reinforcing agent. The compound pipeline is resistant to wear, high in mobility, resistant to impact, corrosion and low temperature, and light in weight. The invention further discloses a preparation process of the compound pipeline.

Description

Compound pipeline complex pipeline and its preparation technology
Technical field
The invention belongs to technical field of polymer materials, and in particular to a kind of compound pipeline complex pipeline and its preparation technology.
Background technology
The method of mining by the way of filling is during the underground mining of mineral resources, as ore is in extraction, underground goaf apparatus The material for having certain physical and mechanical property is filled in time, so as to one side provides support to the country rock around goaf, separately On the one hand the exploitation for adjacent ore body provides a class mining methods of condition.It is the requisite main production link of mining One of.
At present using the pipeline fill material of the material such as cast iron, bimetallic liner, ceramic-lined in filling in mine, Fill material includes:The lotion of flyash, tailings, block stone, blast-furnace cinder etc., is pumped to pipeline, is transported to filling destination.Should Class filler belongs to the field of powder type material, because powder type material is larger to the frictional property of tubing, causes tubing loss serious, Therefore it is general in above-mentioned field or conveyed using metal pipe material, and metal pipe internal wall is easily because the problems such as friction, corrosion Make inner surface of pipeline become coarse, cause transfer efficiency step-down and gradually form blocking.Once forming blocking can only be by artificial Tubing, labor intensive material resources are changed in de-sludging, and reduce production efficiency.
Polyurethane is by polyisocyanates and PPG or PEPA and/or small molecule polyol, polyamine Or the polymer made by the raw material such as chain extender or crosslinking agent such as water.By feed change species and composition, can significantly change Become product form and its performance, obtain from softness to hard final products.
The pipeline material for using at present has:
(1) self- propagating ceramic composite pipe:The pipeline is that the raw material that ferriferous oxide and aluminium powder mix is directly loadable into pipeline, It is placed on centrifuge, by centrifugal action, material is distributed on into the steel pipe inner wall of backing, reacted by high-temp combustion, will melts Ceramic lining material solidification afterwards is compounded in backing steel pipe and forms ceramic-steel pipe double-layer composite material.
(2) bimetal composite wear resistant tube road:Evaporative pattern, suction pouring or centrifugal casting technique are mainly adopted, is fabricated to outer Layer is common steel tube, and internal layer is the compound pipeline complex pipeline of high alloy wear-resistance material, reaches the best fit of toughness and wearability, solves resistance to The contradiction of mill property and solderability.
(3) macromolecule steel lining multiple tube:Macromolecule steel lining multiple tube is, by seamless steel pipe and polymer material lined, to pass through Steel-composite metal plastic pipe that chemical bonding is composited, the features such as with excellent wearability, anticorrosive property and light weight, can be with Being applied to the macromolecular material of inner lining of steel pipe mainly has nitrile rubber, ultra-high molecular weight polyethylene and casting type polyurethane.Pass through Addition reinforcing agent, anti-wear agent and lubricant etc., improve the processing characteristics and frictional behaviour of inner lining material.
The content of the invention
In view of this, the present invention provide a kind of high-wearing feature, high fluidity, high impact properties, corrosion resistance, it is low temperature resistant, The compound pipeline complex pipeline and its preparation technology of lightweight.
Specifically, embodiments of the invention provide a kind of compound pipeline complex pipeline, including macromolecular lining pipe and seamless steel pipe outer tube, The percentage by weight of the raw material proportioning of the macromolecular lining pipe is:Performed polymer 70%~82%, curing agent 10%~21%, profit Lubrication prescription 6.5%~7.5% and reinforcing agent 2.0%~6.0%.
Preferably, the performed polymer is technical grade polytetrahydrofuran diol diisocyanate.
Preferably, the curing agent is toluene di-isocyanate(TDI) (TDI) tripolymer, toluene di-isocyanate(TDI) (TDI)/tri- hydroxyl Methylpropane (TMP) addition product or toluene di-isocyanate(TDI) (TDI)/alkyd addition product.
Preferably, the lubricant is Tissuemat E.
Preferably, the reinforcing agent is carbon fiber.
Preferably, the internal diameter size interference 1.5 of the external diameter of the macromolecular lining pipe and the seamless steel pipe outer tube~ 3%.
The present invention also provides a kind of preparation technology of compound pipeline complex pipeline, including the preparation technology and compound work of macromolecular lining pipe Skill.
Preferably, the preparation technology of the macromolecular lining pipe is comprised the following steps:
(1) pre-process:Performed polymer is weighed, in being put into 62 DEG C of oil bath pan, after half an hour performed polymer melts, is started stirring and is taken out Vacuum to below 0.08Mpa, till producing without bubble;
(2) raw material configuration:Filler carbon fiber, Tissuemat E that addition is mixed, stirring, agitator temperature is 65 DEG C, in advance Aggressiveness muddiness has bubble, starts to vacuumize.
Preferably, the combination process includes:
(1) pre-process:Curing agent is placed in advance in 120 DEG C of baking oven and melts, and will solidify before adding curing agent half an hour Agent temperature brings up to 130 DEG C, takes out curing agent, and hand 4min in being added to performed polymer, stirs rapidly 30s, then deflates, takes out Vacuum, after repeating this process 1-2 time;
(2) it is combined:Step (1) pretreatment gained raw material is quickly poured into prior in the centrifugal pipeline of 100 DEG C of preheatings;
(3) solidify:The solidification point three phases, wherein, at room temperature~100 DEG C, it is incubated 20min;100 DEG C~ At 150 DEG C, 40min is incubated;At 150~200 DEG C, 120min is incubated.
Preferably, the centrifugal pipeline internal layer during the step (2) is compound is also coated with bonded adhesives.
Preferably, the bonded adhesives is ROHM AND HAAS 422.
Compound pipeline complex pipeline and its preparation technology that embodiments of the invention are provided, macromolecular lining pipeline is directly in seamless steel The outer pipeline inside direct combination of pipe simultaneously connects with gluing, realizes macromolecular lining pipe seamless tight with seamless steel pipe outer tube It is compound, it is ensured that the dimensional stability of internal lining pipe, after liner pipe is worn, effectively prevent from managing interior pumped (conveying) medium inflow folder Layer, extruding liner pipe is entered inside pipeline, causes the blocking of conveying circuit;In addition, polyurethane has impact resistance and absorption Impact property, this pliability provides safe and reliable guarantee for induction system.
Described above is only the general introduction of technical solution of the present invention, in order to better understand the technological means of the present invention, And can be practiced according to the content of specification, and in order to allow the present invention above and other objects, features and advantages can Become apparent, below especially exemplified by preferred embodiment, describe in detail as follows.
Specific embodiment
Further to illustrate the present invention to reach technological means and effect that predetermined goal of the invention is taken, below in conjunction with Preferred embodiment, to according to compound pipeline complex pipeline proposed by the present invention and its preparation technology and its specific embodiment, method, step, Feature and effect, describe in detail as after.
For the present invention aforementioned and other technology contents, feature and effect, in following preferred embodiment specifically Can clearly present in bright.By the explanation of specific embodiment, taken when predetermined purpose can be reached to the present invention Technological means and effect are able to more go deep into and specific understanding, but the embodiment is only to provide reference and purposes of discussion, Not it is used for being any limitation as the present invention.
Embodiment one
The embodiment of the present invention provides a kind of compound pipeline complex pipeline, and the compound pipeline complex pipeline is included outside macromolecular lining pipe and seamless steel pipe Manage, the percentage by weight of the raw material proportioning of the macromolecular lining pipe is:Technical grade polytetrahydrofuran diol diisocyanate 70%, toluene di-isocyanate(TDI) (TDI)/trimethylolpropane (TMP) addition product 21%, Tissuemat E 7% and carbon fiber 2.0%.
The embodiment of the present invention also provides a kind of preparation technology of compound pipeline complex pipeline, including macromolecular lining pipe preparation technology and Combination process.
In the present embodiment, the preparation technology of the macromolecular lining pipe is comprised the following steps:
(1) pre-process:Performed polymer is weighed, in being put into 62 DEG C of oil bath pan, after half an hour performed polymer melts, is started stirring and is taken out Vacuum to below 0.08Mpa, till producing without bubble;
(2) configuration is expected:Filler carbon fiber, Tissuemat E that addition is mixed, stirring, agitator temperature is 65 DEG C, in advance Aggressiveness muddiness has bubble, starts to vacuumize.
In the present embodiment, the combination process includes:
(1) pre-process:Curing agent is placed in advance in 120 DEG C of baking oven and melts, and will solidify before adding curing agent half an hour Agent temperature brings up to 130 DEG C, takes out curing agent, and hand 4min in being added to performed polymer, stirs rapidly 30s, then deflates, takes out Vacuum, after repeating this process 1-2 time;
(2) it is combined:Step (1) is pre-processed into gained raw material to be quickly poured into advance in the centrifugal pipeline of 100 DEG C of preheatings, institute State centrifugal pipeline internal layer and be also coated with bonded adhesives ROHM AND HAAS 422;
(3) solidify:Solidification point three phases, wherein, at room temperature~100 DEG C, it is incubated 20min;At 100 DEG C~150 DEG C Under, it is incubated 40min;At 150~200 DEG C, 120min is incubated.
Embodiment two
The embodiment of the present invention provides a kind of compound pipeline complex pipeline, and the compound pipeline complex pipeline is included outside macromolecular lining pipe and seamless steel pipe Manage, the percentage by weight of the raw material proportioning of the macromolecular lining pipe is:Technical grade polytetrahydrofuran diol diisocyanate 80%, toluene di-isocyanate(TDI) (TDI)/alkyd addition product 10%, Tissuemat E 7.5% and carbon fiber 2.5%.In this enforcement In example, the internal diameter size interference 1.5~3% of the external diameter of the macromolecular lining pipe and the seamless steel pipe outer tube.
The embodiment of the present invention provides the preparation technology of a kind of preparation technology of compound pipeline complex pipeline, the preparation technology and embodiment one It is similar.
Embodiment three
The embodiment of the present invention provides a kind of compound pipeline complex pipeline, and the compound pipeline complex pipeline is included outside macromolecular lining pipe and seamless steel pipe Manage, the percentage by weight of the raw material proportioning of the macromolecular lining pipe is:Technical grade polytetrahydrofuran diol diisocyanate 75%, toluene di-isocyanate(TDI) (TDI) tripolymer 12.5%, Tissuemat E 6.5% and carbon fiber 6.0%.In the present embodiment In, the internal diameter size interference 1.5~3% of the external diameter of the macromolecular lining pipe and the seamless steel pipe outer tube.
The embodiment of the present invention provides the preparation technology of a kind of preparation technology of compound pipeline complex pipeline, the preparation technology and embodiment two It is similar.
Example IV
The embodiment of the present invention provides a kind of compound pipeline complex pipeline, and the compound pipeline complex pipeline is included outside macromolecular lining pipe and seamless steel pipe Pipe, the seamless steel pipe outer tube adopts Φ 133mm × 5mm × 2000mm standard seamless pipes, the macromolecular lining to adopt the poly- ammonia of liner The specification of ester is Φ 123mm × 19mm × 2000mm, and cryogenic temperature scope is -110 DEG C~-140 DEG C, and cooling time is 1h.
This compound pipeline complex pipeline is arranged on the horizontal lane below medium input port at 500m for certain domestic well-known large-scale mine enterprise In road, pumped (conveying) medium is cement, the portland cements of PO in bulk 32.5, with reference to the regulation of GB/T175-1999;Dry powder coal ash, With reference to the regulation of GB/T 1596-1991 and JGJ63-1989;Rod milling sand, with reference to the regulation of Q/YSJC-ZB01-2001;It is natural Sand, quality index is performed with reference to rod milling sand technical standard.Slurrying water quality meets the regulation of JGJ63-1989.
Casting resin is 1 with dust and sand ratio:4, wherein natural sand addition is less than the 20% of rod milling sand consumption.Dry powder coal ash Addition less than cement amount 30%.
Using result:Through the Mediawear of 220,000 cube volumes of 6 months, straight tube position abrasion very little, vertically to position Bottom pipe bent position has part liner not worn.
Due to present invention employs macromolecular lining pipeline directly direct combination and band inside the outer pipeline of seamless steel pipe It is gluing to connect, realize macromolecular lining pipe seamless closely compound with seamless steel pipe outer tube, it is ensured that the size of internal lining pipe is steady It is qualitative, prevent slip of the internal lining pipe in the outer pipeline of seamless steel pipe.Topmost effect be after liner pipe is worn, Effectively prevent from managing interior pumped (conveying) medium inflow interlayer, extruding liner pipe is entered inside pipeline, causes the blocking of conveying circuit.
In addition, in addition, there is polyurethane impact resistance to provide for induction system with impact property, this pliability is absorbed Safe and reliable guarantee.
The above, is only the preferred embodiment of invention, and any pro forma restriction is not made to the present invention, although The present invention is disclosed above with preferred embodiment, but is not limited to the present invention, any those skilled in the art, In the range of without departing from technical solution of the present invention, when using the technology contents of the disclosure above make it is a little change or be modified to With the Equivalent embodiments of change, as long as being without departing from technical solution of the present invention content, according to the technical spirit of the present invention to the above Any simple modification, equivalent variations and modification that embodiment is made, still fall within the range of technical solution of the present invention.

Claims (10)

1. a kind of compound pipeline complex pipeline, including macromolecular lining pipe and seamless steel pipe outer tube, it is characterised in that:The macromolecular lining pipe The percentage by weight of raw material proportioning be:Performed polymer 70%~82%, curing agent 10%~21%, lubricant 6.5%~7.5% And reinforcing agent 2.0%~6.0%.
2. compound pipeline complex pipeline according to claim 1, it is characterised in that the performed polymer is technical grade polytetrahydrofuran diol Diisocyanate.
3. compound pipeline complex pipeline according to claim 1, it is characterised in that the curing agent is toluene di-isocyanate(TDI) (TDI) Tripolymer, toluene di-isocyanate(TDI) (TDI)/trimethylolpropane (TMP) addition product or toluene di-isocyanate(TDI) (TDI)/alkyd Addition product.
4. compound pipeline complex pipeline according to claim 1, it is characterised in that the lubricant is Tissuemat E.
5. compound pipeline complex pipeline according to claim 1, it is characterised in that the reinforcing agent is carbon fiber.
6. the preparation technology of a kind of compound pipeline complex pipeline according to claim 1, it is characterised in that including macromolecular lining pipe Preparation technology and combination process.
7. the preparation technology of a kind of compound pipeline complex pipeline according to claim 6, it is characterised in that the macromolecular lining pipe Preparation technology is comprised the following steps:
(1) pre-process:Performed polymer is weighed, in being put into 62 DEG C of oil bath pan, after half an hour performed polymer melts, is started stirring and is vacuumized To below 0.08Mpa, till producing without bubble;
(2) raw material configuration:Filler carbon fiber, Tissuemat E that addition is mixed, stirring, agitator temperature setting is 65 DEG C, in advance Aggressiveness muddiness has bubble, starts to vacuumize.
8. the preparation technology of a kind of compound pipeline complex pipeline according to claim 6, it is characterised in that the combination process includes:
(1) pre-process:Curing agent is previously positioned in 120 DEG C of baking oven and melts, by curing agent temperature before addition curing agent half an hour Degree brings up to 130 DEG C, takes out curing agent, and hand 4min in being added to performed polymer, stirs rapidly 30s, then deflates, vacuumizes, After repeating this process 1-2 time;
(2) it is combined:Step (1) pretreatment gained raw material is quickly poured into prior in the centrifugal pipeline of 100 DEG C of preheatings;
(3) solidify:Solidification point three phases, wherein, at room temperature~100 DEG C, it is incubated 20min;At 100 DEG C~150 DEG C, protect Warm 40min;At 150~200 DEG C, 120min is incubated.
9. the preparation technology of compound pipeline complex pipeline according to claim 8, it is characterised in that during the step (2) is compound from Heart pipeline lining is also coated with bonded adhesives.
10. the preparation technology of compound pipeline complex pipeline according to claim 9, it is characterised in that the bonded adhesives is ROHM AND HAAS 422。
CN201610851267.0A 2016-09-26 2016-09-26 Compound pipeline and preparation process thereof Pending CN106641482A (en)

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CN201610851267.0A CN106641482A (en) 2016-09-26 2016-09-26 Compound pipeline and preparation process thereof

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Application Number Priority Date Filing Date Title
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Citations (11)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1200324A (en) * 1997-05-28 1998-12-02 王剑秋 Process for mfg. composite tube or pipe
WO2004007194A1 (en) * 2002-07-12 2004-01-22 Daicel-Degussa Ltd. Composite and process for producing the same
CN201066001Y (en) * 2007-07-23 2008-05-28 潍坊市长胜管业有限公司 Liner and outer-coated steel-plastic composite pipe
WO2008089167A1 (en) * 2007-01-18 2008-07-24 Lubrizol Advanced Materials, Inc. Cured in place pipe liner
CN101603616A (en) * 2008-06-11 2009-12-16 张传勇 A kind of polyurethane composite pipe
CN101694251A (en) * 2009-10-26 2010-04-14 王春彦 Self-heating high pressure resistant oil transmission pipeline and manufacturing process thereof
CN201680073U (en) * 2010-02-09 2010-12-22 徐州胜海机械制造科技有限公司 Metal tube with ceramic particle strengthened composite material lining
CN202118426U (en) * 2011-06-20 2012-01-18 河南省耕生高温材料有限公司 Composite bend of aluminum oxide ceramic lining
CN102814888A (en) * 2012-08-29 2012-12-12 广州华工百川科技股份有限公司 Metal composite delivery pipe with polyurethane elastomer lining and manufacturing method and application of metal composite delivery pipe
CN102825808A (en) * 2012-08-30 2012-12-19 江苏双达工程技术研究中心有限公司 Processing technology of nanoscale polyurethane composite steel tube
CN103304762A (en) * 2013-07-01 2013-09-18 浙江大学 Method for preparing organosilicon quaternary ammonium salt modified polyurethane resin for marine antifouling coating

Patent Citations (11)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1200324A (en) * 1997-05-28 1998-12-02 王剑秋 Process for mfg. composite tube or pipe
WO2004007194A1 (en) * 2002-07-12 2004-01-22 Daicel-Degussa Ltd. Composite and process for producing the same
WO2008089167A1 (en) * 2007-01-18 2008-07-24 Lubrizol Advanced Materials, Inc. Cured in place pipe liner
CN201066001Y (en) * 2007-07-23 2008-05-28 潍坊市长胜管业有限公司 Liner and outer-coated steel-plastic composite pipe
CN101603616A (en) * 2008-06-11 2009-12-16 张传勇 A kind of polyurethane composite pipe
CN101694251A (en) * 2009-10-26 2010-04-14 王春彦 Self-heating high pressure resistant oil transmission pipeline and manufacturing process thereof
CN201680073U (en) * 2010-02-09 2010-12-22 徐州胜海机械制造科技有限公司 Metal tube with ceramic particle strengthened composite material lining
CN202118426U (en) * 2011-06-20 2012-01-18 河南省耕生高温材料有限公司 Composite bend of aluminum oxide ceramic lining
CN102814888A (en) * 2012-08-29 2012-12-12 广州华工百川科技股份有限公司 Metal composite delivery pipe with polyurethane elastomer lining and manufacturing method and application of metal composite delivery pipe
CN102825808A (en) * 2012-08-30 2012-12-19 江苏双达工程技术研究中心有限公司 Processing technology of nanoscale polyurethane composite steel tube
CN103304762A (en) * 2013-07-01 2013-09-18 浙江大学 Method for preparing organosilicon quaternary ammonium salt modified polyurethane resin for marine antifouling coating

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Application publication date: 20170510