CN106637954A - Environment-friendly textile auxiliary and preparation method thereof - Google Patents

Environment-friendly textile auxiliary and preparation method thereof Download PDF

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Publication number
CN106637954A
CN106637954A CN201611166414.7A CN201611166414A CN106637954A CN 106637954 A CN106637954 A CN 106637954A CN 201611166414 A CN201611166414 A CN 201611166414A CN 106637954 A CN106637954 A CN 106637954A
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textile auxiliary
environment
mixed
added
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钱华
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WUJIANG BEISHE SHENGYUAN TEXTILE AUXILIARIES FACTORY
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WUJIANG BEISHE SHENGYUAN TEXTILE AUXILIARIES FACTORY
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    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
    • D06M13/244—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing sulfur or phosphorus
    • D06M13/248—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing sulfur or phosphorus with compounds containing sulfur
    • D06M13/256—Sulfonated compounds esters thereof, e.g. sultones
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    • D06M11/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
    • D06M11/07—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with halogens; with halogen acids or salts thereof; with oxides or oxyacids of halogens or salts thereof
    • D06M11/11—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with halogens; with halogen acids or salts thereof; with oxides or oxyacids of halogens or salts thereof with halogen acids or salts thereof
    • D06M11/155—Halides of elements of Groups 2 or 12 of the Periodic System
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    • D06M11/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
    • D06M11/73—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with carbon or compounds thereof
    • D06M11/74—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with carbon or compounds thereof with carbon or graphite; with carbides; with graphitic acids or their salts
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    • D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
    • D06M13/10—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing oxygen
    • D06M13/184—Carboxylic acids; Anhydrides, halides or salts thereof
    • D06M13/188—Monocarboxylic acids; Anhydrides, halides or salts thereof
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    • D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
    • D06M13/10—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing oxygen
    • D06M13/184—Carboxylic acids; Anhydrides, halides or salts thereof
    • D06M13/203—Unsaturated carboxylic acids; Anhydrides, halides or salts thereof
    • D—TEXTILES; PAPER
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    • D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
    • D06M13/10—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing oxygen
    • D06M13/184—Carboxylic acids; Anhydrides, halides or salts thereof
    • D06M13/207—Substituted carboxylic acids, e.g. by hydroxy or keto groups; Anhydrides, halides or salts thereof
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    • D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
    • D06M13/322—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing nitrogen
    • D06M13/325—Amines
    • D06M13/342—Amino-carboxylic acids; Betaines; Aminosulfonic acids; Sulfo-betaines
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    • D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
    • D06M13/322—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing nitrogen
    • D06M13/402—Amides imides, sulfamic acids
    • D06M13/419—Amides having nitrogen atoms of amide groups substituted by hydroxyalkyl or by etherified or esterified hydroxyalkyl groups
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    • D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
    • D06M15/01—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with natural macromolecular compounds or derivatives thereof
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    • D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
    • D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
    • D06M15/21—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • D06M15/227—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds of hydrocarbons, or reaction products thereof, e.g. afterhalogenated or sulfochlorinated
    • D06M15/233—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds of hydrocarbons, or reaction products thereof, e.g. afterhalogenated or sulfochlorinated aromatic, e.g. styrene
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    • D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
    • D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
    • D06M15/37—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • D06M15/53—Polyethers
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    • D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
    • D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
    • D06M15/37—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • D06M15/643—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds containing silicon in the main chain

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  • Engineering & Computer Science (AREA)
  • Textile Engineering (AREA)
  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)

Abstract

The invention discloses an environment-friendly textile auxiliary and a preparation method thereof. The environment-friendly textile auxiliary is prepared with sodium diethylhexyl sulfosuccinate, ethylene diamine tetraacetic acid, methyl silicone resin and styrene maleic anhydride resin as main components, phthalic anhydride, polyethylene glycol monostearate, fatty alcohol-polyoxyethylene ether, cocomut oil diethanolamide, nonylphenol polyoxyethylene ether, lignin sulfate, activated carbon, barium chloride, organic acid, a cross-linking agent and deionzied water are added, and the technologies of ball milling, stirring, emulsifying, pH adjusting, heating, heat preservation, ultrasonic oscillation, high-speed shearing and the like are also used. Therefore, after the prepared textile auxiliary is used, textile fabrics are high in toughness and good in viscosity stability, and the textile auxiliary is environmentally friendly, free of toxins, capable of meeting industrial requirements and good in application prospect.

Description

A kind of environment-friendly type textile auxiliary and preparation method thereof
Technical field
The present invention relates to technical field of textile auxiliary agent, more particularly to a kind of environment-friendly type textile auxiliary and preparation method thereof.
Background technology
Textile auxiliary is necessary chemicals in textile production process.Product of the textile auxiliary to raising textile Quality and surcharge have indispensable important function, and it can not only give the various specific functions of textile and style, such as Soft, wrinkle resistant, shrinkproof, waterproof, antibacterial, antistatic, fire-retardant etc., can also improve dyeing and finishing technology, play energy saving and reduction The effect of processing cost.Textile auxiliary to lifted textile industry integral level and the effect in Textile Chain be to pass Important.Whole world textile auxiliary has nearly 100 classes, produces nearly 1.6 ten thousand kinds, about 4,100,000 tons of annual production.It is wherein American-European 48 classes of textile auxiliary kind, more than 8000 kind；There are 5500 kinds in Japan.It is reported that, world textile auxiliary agent market pin Sell sales volume of the volume considerably beyond Dyestuff Market.Existing textile auxiliary mainly has scouring agent, coloring agent, levelling agent, softness Agent, capillary effect elevator, terylene low temperature dyeing carrier, substitute alkali, CT powder, preparation medium, efficiently move back boil powder, hydrogen peroxide stabilizer, Desiliconizing agent, foaming agent, raising agent, color fixing agent etc..
Specific to China, the textile auxiliary kind that the current country can produce is nearly 2000, and the kind of Jing often productions has 800 Remaining, principal item has 200 or so.China's textile auxiliary yield is big, and the industry output value is high, with wide market prospects.But Domestic textile auxiliary also larger difference compared with international most advanced level in kind and quality and in terms of synthesis and application technology Still have to dependence on import away from, special and high-grade textile auxiliary.Also, textile industry is particularly dyeing and finishing industry by national supervisor portion Door is defined as heavy polluted industry.Impact and make that textile auxiliary comes in the manufacturing and its application process to environment and zoology Into pollution problem can not be ignored, it would be highly desirable to solve.
Therefore, Devoting Major Efforts To Developing meets the environmentally friendly textile auxiliary of ecodevelopment, the whole competitiveness to improving auxiliary industry, carries Rise textile auxiliary product quality and technical merit is particularly important, be the key of industry value chain.Also, the weaving developed Additives Products will not only meet the market demand of domestic dyeing and finishing industry, also reach every quality standard of textile exports, just Seem particularly necessary.
The content of the invention
To solve above-mentioned technical problem, the present invention provides a kind of environment-friendly type textile auxiliary, by being entered using specific raw material Row combination, coordinates specific production technology so that the textile auxiliary being prepared from makes that yarn fabric toughness is strong, viscosity stabilization using after Property is good, and textile auxiliary itself environment-protecting asepsis, the requirement of industry is disclosure satisfy that, with preferable application prospect.
The purpose of the present invention can be achieved through the following technical solutions：
A kind of environment-friendly type textile auxiliary, is prepared by the raw materials in：Dioctyl sodium sulfosuccinate 35-45 parts, second two Amine tetraacethyl disodium 30-36 parts, poly- methyl silicon resin 28-32 parts, styrene maleic resin 22-26 parts, phthalic acid Acid anhydride 12-16 parts, polyethylene glycol mono stearate 10-14 parts, AEO 8-10 parts, cocounut oil diglycollic amide 6-8 Part, NPE 4-6 parts, ligninsulfonate 4-6 parts, activated carbon 2-4 parts, barium chloride 1-3 parts, organic acid 3-5 parts, 100 parts of crosslinking agent 3-5 parts, deionized water.
Preferably, any one of the organic acid in palmitic acid, citric acid, linoleic acid.
Preferably, the crosslinking agent is selected from methylene diacrylamine, PEGDMA-400, ethylene glycol two Any one in glycidol ether.
The preparation method of described environment-friendly type textile auxiliary, comprises the following steps：
（1）Each raw material is accurately weighed by the weight portion；
（2）Cocounut oil diglycollic amide, NPE, ligninsulfonate, activated carbon, barium chloride are added into ball mill In, ball milling 1-2 hours, then deionized water is added to the mixture after ball milling, stir under the stir speed (S.S.) of 1000-2000 rpm 2-3 hours, obtain preliminary mixed liquor；
（3）Preliminary mixed liquor is sent into reactor, poly- methyl silicon resin, styrene maleic resin, O-phthalic is added Acid anhydrides, polyethylene glycol mono stearate, uniform rear emulsification 40-50 minutes at a high speed to be mixed, obtain emulsion mixture, are subsequently added The HCl solution of 0.5 mol/L adjusts pH of mixed to 5.5, is heated to 90 DEG C, is incubated 25-35 minutes；
（4）Liquid to be mixed is cooled to after room temperature, adds dioctyl sodium sulfosuccinate, disodium ethylene diamine tetraacetate, poly alkyl alcohol Oxygen vinethene, ultrasonically treated 2-3 hours, are subsequently added organic acid, crosslinking agent in ultrasonator, and Jing is high at 60-70 DEG C Fast shear-mixed obtains finished product.
Preferably, the step（4）In, the power of ultrasonic vibration is 500W, and the time of ultrasonic vibration is 2 hours.
Preferably, the step（4）In, shear rate is 9000-15000 rpm, and shear time is 30 minutes.
Compared with prior art, its advantage is the present invention：
（1）The environment-friendly type textile auxiliary of the present invention is with dioctyl sodium sulfosuccinate, disodium ethylene diamine tetraacetate, poly- methyl silicon tree Fat, styrene maleic resin are main component, by adding phthalic anhydride, polyethylene glycol mono stearate, fat Alcohol APEO, cocounut oil diglycollic amide, NPE, ligninsulfonate, activated carbon, barium chloride, organic acid, Crosslinking agent, deionized water, are aided with the techniques such as ball milling, stirring, emulsification, regulation pH, heating, insulation, ultrasonic vibration, high speed shear, So that the textile auxiliary being prepared from can make after use, and yarn fabric toughness is strong, viscosity stability is good, and textile auxiliary self loop Protect nontoxic, the requirement of industry is disclosure satisfy that, with preferable application prospect.
（2）The environment-friendly type textile auxiliary raw material of the present invention is cheap, process is simple, is suitable to heavy industrialization utilization, practical Property is strong.
Specific embodiment
The technical scheme invented is described in detail with reference to specific embodiment.
Embodiment 1
（1）35 parts of dioctyl sodium sulfosuccinate, 30 parts of disodium ethylene diamine tetraacetate, poly- methyl are accurately weighed by the weight portion 28 parts of silicones, 22 parts of styrene maleic resin, 12 parts of phthalic anhydride, 10 parts of polyethylene glycol mono stearate, fat 8 parts of fat alcohol APEO, 6 parts of cocounut oil diglycollic amide, 4 parts of NPE, 4 parts of ligninsulfonate, activated carbon 2 Part, 1 part of barium chloride, 3 parts of palmitic acid, 3 parts of methylene diacrylamine, 100 parts of deionized water；
（2）Cocounut oil diglycollic amide, NPE, ligninsulfonate, activated carbon, barium chloride are added into ball mill In, ball milling 1 hour, then deionized water is added to the mixture after ball milling, stir 2 hours under the stir speed (S.S.) of 1000rpm, obtain Preliminary mixed liquor；
（3）Preliminary mixed liquor is sent into reactor, poly- methyl silicon resin, styrene maleic resin, O-phthalic is added Acid anhydrides, polyethylene glycol mono stearate, uniform rear emulsification 40 minutes at a high speed to be mixed, obtain emulsion mixture, are subsequently added 0.5 The HCl solution of mol/L adjusts pH of mixed to 5.5, is heated to 90 DEG C, is incubated 25 minutes；
（4）Liquid to be mixed is cooled to after room temperature, adds dioctyl sodium sulfosuccinate, disodium ethylene diamine tetraacetate, poly alkyl alcohol Oxygen vinethene, ultrasonically treated in ultrasonator, the power of ultrasonic vibration is 500W, and the time of ultrasonic vibration is 2 hours, with Palmitic acid, methylene diacrylamine are added afterwards, and Jing high speed shears are mixed to get finished product at 60 DEG C, and its medium shear rate is 9000 rpm, shear time is 30 minutes.
The performance test results of obtained environment-friendly type textile auxiliary are as shown in table 1.
Embodiment 2
（1）40 parts of dioctyl sodium sulfosuccinate, 33 parts of disodium ethylene diamine tetraacetate, poly- methyl are accurately weighed by the weight portion 30 parts of silicones, 24 parts of styrene maleic resin, 14 parts of phthalic anhydride, 12 parts of polyethylene glycol mono stearate, fat 9 parts of fat alcohol APEO, 7 parts of cocounut oil diglycollic amide, 5 parts of NPE, 5 parts of ligninsulfonate, activated carbon 3 Part, 2 parts of barium chloride, 4 parts of citric acid, 4 parts of PEGDMA-400,100 parts of deionized water；
（2）Cocounut oil diglycollic amide, NPE, ligninsulfonate, activated carbon, barium chloride are added into ball mill In, ball milling 1.5 hours, then deionized water is added to the mixture after ball milling, stirring 2.5 is little under the stir speed (S.S.) of 1500 rpm When, obtain preliminary mixed liquor；
（3）Preliminary mixed liquor is sent into reactor, poly- methyl silicon resin, styrene maleic resin, O-phthalic is added Acid anhydrides, polyethylene glycol mono stearate, uniform rear emulsification 45 minutes at a high speed to be mixed, obtain emulsion mixture, are subsequently added 0.5 The HCl solution of mol/L adjusts pH of mixed to 5.5, is heated to 90 DEG C, is incubated 30 minutes；
（4）Liquid to be mixed is cooled to after room temperature, adds dioctyl sodium sulfosuccinate, disodium ethylene diamine tetraacetate, poly alkyl alcohol Oxygen vinethene, ultrasonically treated in ultrasonator, the power of ultrasonic vibration is 500W, and the time of ultrasonic vibration is 2 hours, with Citric acid, PEGDMA-400 are added afterwards, Jing high speed shears are mixed to get finished product at 65 DEG C, wherein shearing speed Rate is 12000 rpm, and shear time is 30 minutes.
The performance test results of obtained environment-friendly type textile auxiliary are as shown in table 1.
Embodiment 3
（1）45 parts of dioctyl sodium sulfosuccinate, 36 parts of disodium ethylene diamine tetraacetate, poly- methyl are accurately weighed by the weight portion 32 parts of silicones, 26 parts of styrene maleic resin, 16 parts of phthalic anhydride, 14 parts of polyethylene glycol mono stearate, fat 10 parts of fat alcohol APEO, 8 parts of cocounut oil diglycollic amide, 6 parts of NPE, 6 parts of ligninsulfonate, activated carbon 4 parts, 3 parts of barium chloride, 5 parts of linoleic acid, 5 parts of ethylene glycol diglycidylether, 100 parts of deionized water；
（2）Cocounut oil diglycollic amide, NPE, ligninsulfonate, activated carbon, barium chloride are added into ball mill In, ball milling 2 hours, then deionized water is added to the mixture after ball milling, stir 3 hours under the stir speed (S.S.) of 2000 rpm, Obtain preliminary mixed liquor；
（3）Preliminary mixed liquor is sent into reactor, poly- methyl silicon resin, styrene maleic resin, O-phthalic is added Acid anhydrides, polyethylene glycol mono stearate, uniform rear emulsification 50 minutes at a high speed to be mixed, obtain emulsion mixture, are subsequently added 0.5 The HCl solution of mol/L adjusts pH of mixed to 5.5, is heated to 90 DEG C, is incubated 35 minutes；
（4）Liquid to be mixed is cooled to after room temperature, adds dioctyl sodium sulfosuccinate, disodium ethylene diamine tetraacetate, poly alkyl alcohol Oxygen vinethene, ultrasonically treated in ultrasonator, the power of ultrasonic vibration is 500W, and the time of ultrasonic vibration is 2 hours, with Linoleic acid, ethylene glycol diglycidylether are added afterwards, and Jing high speed shears are mixed to get finished product at 70 DEG C, and its medium shear rate is 15000 rpm, shear time is 30 minutes.
The performance test results of obtained environment-friendly type textile auxiliary are as shown in table 1.
Embodiment 4
（1）45 parts of dioctyl sodium sulfosuccinate, 30 parts of disodium ethylene diamine tetraacetate, poly- methyl are accurately weighed by the weight portion 32 parts of silicones, 22 parts of styrene maleic resin, 16 parts of phthalic anhydride, 10 parts of polyethylene glycol mono stearate, fat 10 parts of fat alcohol APEO, 6 parts of cocounut oil diglycollic amide, 6 parts of NPE, 4 parts of ligninsulfonate, activated carbon 4 parts, 1 part of barium chloride, 3 parts of palmitic acid, 5 parts of PEGDMA-400,100 parts of deionized water；
（2）Cocounut oil diglycollic amide, NPE, ligninsulfonate, activated carbon, barium chloride are added into ball mill In, ball milling 2 hours, then deionized water is added to the mixture after ball milling, stir 3 hours under the stir speed (S.S.) of 1000 rpm, Obtain preliminary mixed liquor；
（3）Preliminary mixed liquor is sent into reactor, poly- methyl silicon resin, styrene maleic resin, O-phthalic is added Acid anhydrides, polyethylene glycol mono stearate, uniform rear emulsification 40 minutes at a high speed to be mixed, obtain emulsion mixture, are subsequently added 0.5 The HCl solution of mol/L adjusts pH of mixed to 5.5, is heated to 90 DEG C, is incubated 35 minutes；
（4）Liquid to be mixed is cooled to after room temperature, adds dioctyl sodium sulfosuccinate, disodium ethylene diamine tetraacetate, poly alkyl alcohol Oxygen vinethene, ultrasonically treated in ultrasonator, the power of ultrasonic vibration is 500W, and the time of ultrasonic vibration is 2 hours, with Palmitic acid, PEGDMA-400 are added afterwards, Jing high speed shears are mixed to get finished product at 70 DEG C, wherein shearing speed Rate is 9000 rpm, and shear time is 30 minutes.
The performance test results of obtained environment-friendly type textile auxiliary are as shown in table 1.
Comparative example 1
（1）40 parts of dioctyl sodium sulfosuccinate, 33 parts of disodium ethylene diamine tetraacetate, poly- methyl are accurately weighed by the weight portion 30 parts of silicones, 24 parts of styrene maleic resin, 14 parts of phthalic anhydride, 12 parts of polyethylene glycol mono stearate, fat 9 parts of fat alcohol APEO, 7 parts of cocounut oil diglycollic amide, 5 parts of ligninsulfonate, 3 parts of activated carbon, 4 parts of citric acid, dimethyl 4 parts of polyalkylene glycol acrylate ester, 100 parts of deionized water；
（2）Cocounut oil diglycollic amide, ligninsulfonate, activated carbon are added in ball mill, ball milling 1.5 hours, then to after ball milling Mixture add deionized water, under the stir speed (S.S.) of 1500 rpm stir 2.5 hours, obtain preliminary mixed liquor；
（3）Preliminary mixed liquor is sent into reactor, poly- methyl silicon resin, styrene maleic resin, O-phthalic is added Acid anhydrides, polyethylene glycol mono stearate, uniform rear emulsification 45 minutes at a high speed to be mixed, obtain emulsion mixture, are subsequently added 0.5 The HCl solution of mol/L adjusts pH of mixed to 5.5, is heated to 90 DEG C, is incubated 30 minutes；
（4）Liquid to be mixed is cooled to after room temperature, adds dioctyl sodium sulfosuccinate, disodium ethylene diamine tetraacetate, poly alkyl alcohol Oxygen vinethene, ultrasonically treated in ultrasonator, the power of ultrasonic vibration is 500W, and the time of ultrasonic vibration is 2 hours, with Citric acid, PEGDMA-400 are added afterwards, Jing high speed shears are mixed to get finished product at 65 DEG C, wherein shearing speed Rate is 12000 rpm, and shear time is 30 minutes.
The performance test results of obtained environment-friendly type textile auxiliary are as shown in table 1.
Comparative example 2
（1）45 parts of dioctyl sodium sulfosuccinate, 30 parts of disodium ethylene diamine tetraacetate, poly- methyl are accurately weighed by the weight portion 32 parts of silicones, 22 parts of styrene maleic resin, 16 parts of phthalic anhydride, 10 parts of polyethylene glycol mono stearate, fat 10 parts of fat alcohol APEO, 6 parts of NPE, 4 parts of ligninsulfonate, 1 part of barium chloride, 3 parts of palmitic acid, diformazan 5 parts of base polyalkylene glycol acrylate ester, 100 parts of deionized water；
（2）NPE, ligninsulfonate, barium chloride are added in ball mill, ball milling 2 hours, then to after ball milling Mixture add deionized water, under the stir speed (S.S.) of 1000 rpm stir 3 hours, obtain preliminary mixed liquor；
（3）Preliminary mixed liquor is sent into reactor, poly- methyl silicon resin, styrene maleic resin, O-phthalic is added Acid anhydrides, polyethylene glycol mono stearate, uniform rear emulsification 40 minutes at a high speed to be mixed, obtain emulsion mixture, are subsequently added 0.5 The HCl solution of mol/L adjusts pH of mixed to 5.5, is heated to 90 DEG C, is incubated 35 minutes；
（4）Liquid to be mixed is cooled to after room temperature, adds dioctyl sodium sulfosuccinate, disodium ethylene diamine tetraacetate, poly alkyl alcohol Oxygen vinethene, ultrasonically treated in ultrasonator, the power of ultrasonic vibration is 500W, and the time of ultrasonic vibration is 2 hours, with Palmitic acid, PEGDMA-400 are added afterwards, Jing high speed shears are mixed to get finished product at 70 DEG C, wherein shearing speed Rate is 9000 rpm, and shear time is 30 minutes.
The performance test results of obtained environment-friendly type textile auxiliary are as shown in table 1.
The environment-friendly type textile auxiliary of embodiment 1-4 and comparative example 1-2 is applied to respectively after yarn fabric carries out extension at break Rate, viscosity thermal stability, this several tests of toxotest.
Table 1
　 Elongation at break（%） Viscosity thermal stability（%） Toxotest
Embodiment 1 172.8 97.2 It is non-toxic
Embodiment 2 185.3 98.3 It is non-toxic
Embodiment 3 184.1 97.9 It is non-toxic
Embodiment 4 176.3 97.5 It is non-toxic
Comparative example 1 130.9 92.2 It is non-toxic
Comparative example 2 131.6 91.6 It is non-toxic
The present invention environment-friendly type textile auxiliary with dioctyl sodium sulfosuccinate, disodium ethylene diamine tetraacetate, poly- methyl silicon resin, Styrene maleic resin is main component, by adding phthalic anhydride, polyethylene glycol mono stearate, poly alkyl alcohol Oxygen vinethene, cocounut oil diglycollic amide, NPE, ligninsulfonate, activated carbon, barium chloride, organic acid, crosslinking Agent, deionized water, are aided with the techniques such as ball milling, stirring, emulsification, regulation pH, heating, insulation, ultrasonic vibration, high speed shear so that The textile auxiliary being prepared from can make after use that yarn fabric toughness is strong, viscosity stability is good, and the environmentally friendly nothing of textile auxiliary itself Poison, disclosure satisfy that the requirement of industry, with preferable application prospect.The environment-friendly type textile auxiliary raw material of the present invention is cheap, technique Simply, heavy industrialization utilization is suitable to, it is practical.
Embodiments of the invention are the foregoing is only, the scope of the claims of the present invention is not thereby limited, it is every using this Equivalent structure or equivalent flow conversion that bright description is made, or directly or indirectly it is used in other related technology necks Domain, is included within the scope of the present invention.

Claims (6)

1. a kind of environment-friendly type textile auxiliary, it is characterised in that：It is prepared by the raw materials in：Dioctyl sodium sulfosuccinate 35-45 parts, disodium ethylene diamine tetraacetate 30-36 parts, poly- methyl silicon resin 28-32 parts, styrene maleic resin 22-26 Part, phthalic anhydride 12-16 parts, polyethylene glycol mono stearate 10-14 parts, AEO 8-10 parts, cocounut oil Diglycollic amide 6-8 parts, NPE 4-6 parts, ligninsulfonate 4-6 parts, activated carbon 2-4 parts, barium chloride 1-3 Part, organic acid 3-5 parts, crosslinking agent 3-5 parts, 100 parts of deionized water.
2. environment-friendly type textile auxiliary according to claim 1, it is characterised in that：The organic acid is selected from palmitic acid, lemon Any one in acid, linoleic acid.
3. environment-friendly type textile auxiliary according to claim 1, it is characterised in that：The crosslinking agent is selected from the propylene of methylene two Any one in acid amides, PEGDMA-400, ethylene glycol diglycidylether.
4. according to the preparation method of the arbitrary described environment-friendly type textile auxiliary of claim 1-3, it is characterised in that including following step Suddenly：
（1）Each raw material is accurately weighed by the weight portion；
（2）Cocounut oil diglycollic amide, NPE, ligninsulfonate, activated carbon, barium chloride are added into ball mill In, ball milling 1-2 hours, then deionized water is added to the mixture after ball milling, stir under the stir speed (S.S.) of 1000-2000 rpm 2-3 hours, obtain preliminary mixed liquor；
（3）Preliminary mixed liquor is sent into reactor, poly- methyl silicon resin, styrene maleic resin, O-phthalic is added Acid anhydrides, polyethylene glycol mono stearate, uniform rear emulsification 40-50 minutes at a high speed to be mixed, obtain emulsion mixture, are subsequently added The HCl solution of 0.5 mol/L adjusts pH of mixed to 5.5, is heated to 90 DEG C, is incubated 25-35 minutes；
（4）Liquid to be mixed is cooled to after room temperature, adds dioctyl sodium sulfosuccinate, disodium ethylene diamine tetraacetate, poly alkyl alcohol Oxygen vinethene, ultrasonically treated 2-3 hours, are subsequently added organic acid, crosslinking agent in ultrasonator, and Jing is high at 60-70 DEG C Fast shear-mixed obtains finished product.
5. the preparation method of environment-friendly type textile auxiliary according to claim 4, it is characterised in that the step（4）In, surpass The power that acoustic shock is swung is 500W, and the time of ultrasonic vibration is 2 hours.
6. the preparation method of environment-friendly type textile auxiliary according to claim 4, it is characterised in that the step（4）In, cut Cutting speed rate is 9000-15000rpm, and shear time is 30 minutes.
CN201611166414.7A 2016-12-16 2016-12-16 Environment-friendly textile auxiliary and preparation method thereof Pending CN106637954A (en)

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WO2019006940A1 (en) * 2017-07-07 2019-01-10 苏州市晨彩纺织研发有限公司 Artificial compound staining agent for textiles and preparation method therefor
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CN112626852A (en) * 2020-12-19 2021-04-09 刘桃凤 Antibacterial textile auxiliary and preparation method thereof
CN114182392A (en) * 2021-12-17 2022-03-15 开封大学 Heat-resistant non-silicon carbon fiber oil agent and preparation and application thereof

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Application publication date: 20170510