CN106637905A - Bleaching reagent as well as preparation method and application thereof, and application of peracetic acid A liquid - Google Patents
Bleaching reagent as well as preparation method and application thereof, and application of peracetic acid A liquid Download PDFInfo
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- CN106637905A CN106637905A CN201710030139.4A CN201710030139A CN106637905A CN 106637905 A CN106637905 A CN 106637905A CN 201710030139 A CN201710030139 A CN 201710030139A CN 106637905 A CN106637905 A CN 106637905A
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- hair
- bleaching
- bleaching agent
- peracetic acid
- liquid
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Abstract
The invention provides a bleaching reagent as well as a preparation method and application thereof, and application of peracetic acid A liquid. The bleaching reagent comprises the following components: the peracetic acid A liquid, water, sodium pyrophosphate and a pH regulator; in the bleaching reagent, the mass ratio of the peracetic acid A liquid to the water is 1:(3-5); the sodium pyrophosphate concentration is 2 to 4 g/L; and the pH value of the bleaching reagent is 5.3 to 8.58. The bleaching reagent provided by the invention can effectively bleach hair, particularly has a good bleaching effect on permed and dyed hair; compared with the original sample, the hair intensity loss is not serious; the bleaching effect of hair subjected to hot oil treatment and the permed and dyed hair is greatly improved; a bleaching method with minimal damage to the hair and best treatment effect on the hair is realized; and compared with the traditional method, the pollution to the surrounding environment is reduced.
Description
Technical field
Shu Yu of the present invention treat with oil human hair bleaching field, more particularly, to a kind of bleaching agent and preparation method and application,
And the purposes of Peracetic acid A liquid.
Background technology
In the international market, the wig sheath for really sending out making with the mankind is especially precious.It is reported that, made with Asian true
Hair net, its quality is more superior, because Asian has the custom of hair long, hair is long, is easy to be woven into the wig of all size
Set.And during wig manufacturing, it is necessary first to the bleached hair of Asian's black, the dyeing that can just carry out the later stage are processed.
The bleaching effect that the current mankind really send out is good, but Jing Guo treatment oil or the hair existing process of dyeing are difficult to bleach.Therefore send out
The hair of product enterprise purchase is all true not processed through any boiling hot dye.Mostly pass through yet with the hair of modern
Treatment oil is had hair dyed, and causes true sending out to purchase difficult and expensive, and such hair is needed in India or remote mountain village
Purchase, increases production cost significantly.The data that company provides are produced according to Xuchang wig, the mankind really send out one kilogram of purchasing price
Between 1200-2000 is first, Ran Er treat with oil send out or boiling hot dyeing hair only 400 yuan or so of one kilogram of purchasing price.If energy
Reach Xie Jue treatment oil or scald the bleaching problem of dyeing hair, the production cost of enterprise will be substantially reduced, it will bring huge economy
Benefit.
Present human hair bleaching conditions are：
Hair is catalyzed first, tartaric acid 20%, FeSO420%, NaCl 30%, 80 degree of water (80 degree are heated to,
Then it is no longer heat up) temperature two hours of catalysis.
Second step, uses 15% ammoniacal liquor, 80 degrees Celsius of water temperature to neutralize 15 minutes and clean.
3rd step, oxidation：30%H2O2, 15% ammoniacal liquor, pH=9-10,8% Na4PO7, if than shallower color number,
50 degrees Celsius of temperature can be controlled with 5% potassium peroxydisulfate etc..
The technique is good to really sending out bleaching effect, but Dui Yu treatment oil bleaching effects are very poor.
Peracetic acid is a kind of important liquid organic peroxide, and its oxidability is higher than hydrogen peroxide, used as sterilization
There is its unique effect when disinfectant, oxidant, epoxidizing agent, and environmental pollution is little.It is in textile industry as bleaching agent
It is studied always.So bleaching it is contemplated that hydrogen oxide being substituted with Peracetic acid treatment oil being sent out, Peracetic acid is found
Bleaching effect is good, but the destruction to hair is very serious, does not reach requirement.
The content of the invention
In view of this, it is contemplated that proposing a kind of bleaching agent and preparation method and application and Peracetic acid A liquid
Purposes, with solve existing bleaching agent and method for bleaching bleaching effect it is poor or bleaching to hair injury it is very big the problems such as.
To reach above-mentioned purpose, the technical scheme is that what is be achieved in that：
A kind of bleaching agent, Peracetic acid A liquid, water, sodium pyrophosphate and pH adjusting agent；
Peracetic acid A liquid and the mass ratio of water are 1 in the bleaching agent：3～5；
The concentration of the sodium pyrophosphate is 2～4g/L；
The pH value of the bleaching agent is 5.3～8.58.
The bleaching agent also includes pH adjusting agent, and the pH value of the bleaching agent is 5.3～8.58.
Preferably, PH conditioning agents are stated for Carbon Dioxide calcium.
A kind of preparation method of bleaching agent, it is characterised in that：Comprise the steps：
Comprise the steps：
Take the Peracetic acid A liquid of certain mass；
Plus 3～the water dilution of 5 times of Peracetic acid A liquid quality；
50～65 DEG C of heated at constant temperature；
The concentration that sodium pyrophosphate to sodium pyrophosphate is added in solution is 2～4g/L, is well mixed；
Mixed liquor pH value is adjusted to 5.3～8.58, obtain bleaching agent with pH adjusting agent.
Preferably, 50～65 DEG C of water bath with thermostatic control heating.
A kind of purposes of bleaching agent, above-mentioned bleaching agent is used to bleach hair.
Further, above-mentioned bleaching agent is used for into Piao Bai treatment oil or scalds dyeing hair.
Further, the purposes of bleaching agent, comprises the steps：
Hair to be bleached and 50～65 DEG C of bleaching agents are put into container, to bleaching agent head to be bleached was flooded
Send out, 50～65 DEG C of constant temperature bleach 50～90min, and bleaching terminates.
Further, bleaching takes out in hair after terminating, and the bleaching agent of hair surface is removed.
Preferably, bleaching takes out in hair after terminating, and is rinsed with water and removes the bleaching agent of hair surface.
A kind of purposes of Peracetic acid A liquid, Peracetic acid A liquid is used to bleach hair.
Further, Peracetic acid A liquid is used for into Piao Bai treatment oil or scalds dyeing hair.
The bleaching agent that the present invention is provided can be bleached effectively to hair, especially to the bleaching effect of boiling hot dyeing hair
Preferably, compared with as former state, hair loss of strength is not very serious, and great is big, and the bleaching effect of hair dyeing is sent out and scalded to Ti Gao treatment oil,
Realize and treatment effect best method for bleaching minimum to hair damage.The realization of the method so that enterprise is high without spending
The expensive price purchase mankind really send out, and less cost can be spent to purchase and be available anywhere treatment oil or scalded hair dyeing, substantially reduce
The production cost of enterprise, and than conventional method, reduce the pollution to surrounding enviroment.
Specific embodiment
Unless otherwise indicated, term used herein is respectively provided with the implication that those skilled in the art routinely understand, in order to
The present invention is readily appreciated, some terms used herein have been carried out into following definitions.
Use in the specification and in the claims, all of Digital ID, such as pH, temperature, time, concentration, wrap
Scope is included, is all approximation.It is to be understood that, although always clearly do not describe and all add before all of Digital ID term
" about ".While it will also be understood that, although always clearly do not describe, reagent described herein is only example, its equivalent is
It is known in the art.
Except special instruction, the Peracetic acid A liquid referred in the application, Peracetic acid B are all from Shandong West Asia chemistry work
Industry Co., Ltd, lot number：Z72464；Peracetic acid A liquid presses quality 1 with Peracetic acid B liquid：1 mixing generates the matter of Peracetic acid
Amount fraction is 18～20%.
The present invention is described in detail with reference to embodiment.
Following examples and comparative example are to the assay method of the relevant parameter of hair and the instrument for using：
1. the measure of technical parameter
The measure of 1.1 intensity
Human hair after human hair or bleaching is placed on surface plate and is dried, then measured with digital displaying push-and-pull tensiometer, successively
5 groups of hair intensity is measured, the mean value of 5 groups of data is taken.
The measure of 1.2 whiteness
Human hair after human hair or bleaching is placed on surface plate and is dried, be compared using colorimetric card draw it is more close
Registration, in the color that bleached rear hair is obtained by registration.
2. key instrument
| Instrument title | Manufacturer |
| Electronic analytical balance | Shanghai Pu Chun metrical instruments Co., Ltd |
| Heat collecting type constant-temperature heating magnetic stirring apparatus | Yuhua Instrument Co., Ltd., Gongyi City |
| Digital displaying push-and-pull tensiometer | Leqing Sheng Yuan Instrument Ltd. |
| Automatic programme control baking oven | Hangzhou Zhuo Chi Instrument Ltd. |
| PHS-3C-PH is counted | Shanghai INESA Scientific Instrument Co., Ltd. |
Embodiment 1
Peracetic acid A liquid is added into 4 times of water dilutions, the Peracetic acid A liquid dilution of 40ml is taken in beaker, 60 DEG C of perseverances are put into
Tepidarium is heated, and 0.096g sodium pyrophosphates are added in solution, is well mixed, and with Carbon Dioxide calcium pH value is adjusted, and is bleached
Reagent.A little dyed hair is added as former state in beaker and adds 60 DEG C of bleaching agents to not having hair as former state, in 60 DEG C of perseverances
Bleached under the conditions of temperature, reaction is terminated when hair bleaching time is 80min, hair is taken out, used excessive distilled water flushing
The bleaching agent of hair surface is removed clean.Impact of the different pH value to hair bleaching effect is shown in Table 1.
Comparative example 1
Directly testing result is shown in Table in 1-4 to be detected as former state to hair.The hair that embodiment 1-5 is used is as former state and right
Ratio 2-4 hair is consistent as former state with the hair of comparative example 1 as former state.
Table 1
When pH value be less than 5 when, bleaching effect is poor, and pH value be more than 9 when, it is very poor that intensity becomes again.So it is final we
Selection pH is detailed measurements pH value in the range of 5-9 for the impact of whiteness and intensity after bleached hair.As seen from the above table, solution is worked as
PH value when being 8.18, the whiteness and intensity after bleached hair is most widely suited, and compared with as former state, hair loss of strength is not very
Seriously.
Embodiment 2
Peracetic acid A liquid is added into 4 times of water dilutions, the Peracetic acid A liquid dilution of 40ml is taken in beaker, 60 DEG C of perseverances are put into
Tepidarium is heated, and 0.096g sodium pyrophosphates are added in solution, is well mixed, and pH value is adjusted to 8.18 with Carbon Dioxide calcium, is obtained
To bleaching agent.A little dyed hair is added as former state in beaker and adds 60 DEG C of bleaching agents to not having hair as former state,
Bleached under 60 DEG C of constant temperatures, adjusted the different reaction time, after reaction terminates, hair is taken out, used excessive distilled water
Rinse and remove the bleaching agent of hair surface totally.Impact of the different reaction time to hair bleaching effect is shown in Table 2.
Table 2
As shown in Table 2, with the rising of temperature, the bleaching effect of hair improves, but the intensity of hair has declined, and examines
Consider practical situations, optimum reacting time is 80min, and now the intensity of hair is optimal with whiteness.
Embodiment 3
Peracetic acid A liquid is added into 4 times of water dilutions, the Peracetic acid A liquid of 40ml is taken in beaker, different temperatures constant temperature is put into
Heating water bath, 0.096g sodium pyrophosphates are added in solution, are well mixed, and pH value is adjusted to 8.18 with Carbon Dioxide calcium, are obtained
Bleaching agent.A little dyed hair is added as former state and adds bleaching agent that above-mentioned water bath with thermostatic control obtains in beaker to not having
Hair as former state, and continues to be bleached under constant temperature, and reaction is terminated when hair bleaching time is 80min, and hair is taken
Go out, removed the bleaching agent of hair surface with excessive distilled water flushing clean.Different bath temperatures is to hair bleaching effect
Impact be shown in Table 3.
Comparative example 2
As different from Example 4 constant temperature water bath is different for comparative example 2, and remaining condition is same as Example 4.Different water-baths
Impact of the temperature to hair bleaching effect is shown in Table 3.
Table 3
Can be learnt by the data of table 3, when the pH stable of solution is 8.18 or so, and solution in time for reacting and beaker
In the case that concentration is constant, hair is bleached in 60 DEG C of water bath with thermostatic control, and the whiteness of hair is optimal with intensity.
Embodiment 4
Peracetic acid A liquid is added into 4 times of water dilutions, the Peracetic acid A liquid dilution of 40ml is taken in beaker, 60 DEG C of perseverances are put into
Tepidarium heat, in solution add different quality sodium pyrophosphate, be well mixed, with Carbon Dioxide calcium adjust pH value to
8.18, obtain bleaching agent.A little dyed hair is added as former state in beaker and adds 60 DEG C of bleaching agents to not having hair
As former state, bleached under 60 DEG C of constant temperatures, reaction is terminated when hair bleaching time is 80min, hair is taken out, with excess
Distilled water flushing removes the bleaching agent of hair surface clean.Impact of the concentration of different sodium pyrophosphates to bleached hair is shown in Table
4。
Table 4
Can be drawn by the data of table 4, when the pH value of bleaching liquid is 8.18 or so, and keep the reaction time 80min of experiment,
In the case of 60 DEG C of reaction temperature, intensity of the content of sodium pyrophosphate in the case of 2.4g/L after the human hair bleaching of ， treatment oil in solution
It is optimal with whiteness.
Embodiment 5
Peracetic acid A liquid is added into 4 times of water dilutions, the Peracetic acid A liquid dilution of 40ml is taken in beaker, 60 DEG C of perseverances are put into
Tepidarium is heated, and 0.096g sodium pyrophosphates are added in solution, is well mixed, and pH value is adjusted to 8.18 with Carbon Dioxide calcium, is obtained
To bleaching agent.A little dyed hair is added as former state in beaker and adds 60 DEG C of bleaching agents to not having hair as former state,
Bleached under 60 DEG C of constant conditions, reaction is terminated when hair bleaching time is 80min, hair is taken out, used excessive distilled water
Rinse and remove the bleaching agent of hair surface totally.Hair inspection result after bleaching is shown in Table 5.
Comparative example 3
A little dyed hair is bleached using technique in background technology, as a result as shown in table 5.
Comparative example 4
Peracetic acid liquid that mass concentration is 18～20% plus 4 times of water are diluted into concentration for 3.6～4%, take 40ml's
Concentration is 3.6～4% Peracetic acid liquid in beaker, is put into 60 DEG C of waters bath with thermostatic control heating, and 0.096g Jiao's phosphorus is added in solution
Sour sodium, is well mixed, and pH value is adjusted to 8.18 with Carbon Dioxide calcium, obtains bleaching agent.By a little dyed hair as former state
Add and add in beaker 60 DEG C of bleaching agents to not having hair as former state, bleached under 60 DEG C of constant temperature, when hair bleaching time
For 80min when terminate reaction, hair is taken out, the bleaching agent of hair surface is removed with excessive distilled water flushing clean.Drift
Hair inspection result after white is as shown in table 5.
Table 5
Learnt by table 5, existing process hydrogen peroxide bleaching scalds dye human hair, after bleaching with former state contrast color change less,
Bleaching effect is poor；It is larger to hair damage after Peracetic acid bleaching hair；And Peracetic acid A liquid bleaching effect was substantially better than
Hydrogen oxide and Peracetic acid bleaching process, whiteness and intensity it is good, that is to say, that our Gong Yi Dui treatment oil human hair effectively, energy
Reach requirement of the hair products company to bleached hair.
The bleaching agent that the present invention is provided is sent out Qi Ta treatment oil also preferable bleaching effect.
Presently preferred embodiments of the present invention is the foregoing is only, not to limit the present invention, all essences in the present invention
Within god and principle, any modification, equivalent substitution and improvements made etc. should be included within the scope of the present invention.
Claims (10)
1. a kind of bleaching agent, it is characterised in that：Including following components：Peracetic acid A liquid, water, sodium pyrophosphate and pH adjusting agent；
Peracetic acid A liquid and the mass ratio of water are 1 in the bleaching agent：3～5；
The concentration of the sodium pyrophosphate is 2～4g/L；
The pH value of the bleaching agent is 5.3～8.58.
2. bleaching agent according to claim 1, it is characterised in that：The PH conditioning agents are Carbon Dioxide calcium.
3. the preparation method of the bleaching agent described in claim 1 or 2, it is characterised in that：Comprise the steps：
Take the Peracetic acid A liquid of certain mass；
Plus 3～the water dilution of 5 times of Peracetic acid A liquid quality；
50～65 DEG C of heated at constant temperature；
The concentration that sodium pyrophosphate to sodium pyrophosphate is added in solution is 2～4g/L, is well mixed；
Mixed liquor pH value is adjusted to 5.3～8.58, obtain bleaching agent with pH adjusting agent.
4. a kind of purposes of bleaching agent, it is characterised in that：Bleaching agent described in claim 1 or 2 is used to bleach hair.
5. bleaching agent purposes according to claim 4, it is characterised in that：By the bleaching agent described in claim 1 or 2
Dyeing hair is treated with oil or scalded for Piao Bai.
6. bleaching agent purposes according to claim 5, it is characterised in that：Comprise the steps：
Hair to be bleached and 50～65 DEG C of bleaching agents are put into container, to bleaching agent hair to be bleached were flooded,
50～65 DEG C of constant temperature bleach 50～90min, and bleaching terminates.
7. the bleaching agent purposes described in claim 6, it is characterised in that：Bleaching takes out in hair after terminating, and by hair table
The bleaching agent in face is removed.
8. the purposes of the bleaching agent described in claim 6, it is characterised in that：Bleaching takes out in hair after terminating, and is rinsed with water
The bleaching agent of hair surface is removed.
9. a kind of purposes of Peracetic acid A liquid, it is characterised in that：Peracetic acid A liquid is used to bleach hair.
10. the purposes of the Peracetic acid A liquid described in claim 9, it is characterised in that：By Peracetic acid A liquid for Piao Bai treatment oil
Or boiling hot dyeing hair.
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710030139.4A CN106637905A (en) | 2017-01-16 | 2017-01-16 | Bleaching reagent as well as preparation method and application thereof, and application of peracetic acid A liquid |
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710030139.4A CN106637905A (en) | 2017-01-16 | 2017-01-16 | Bleaching reagent as well as preparation method and application thereof, and application of peracetic acid A liquid |
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| CN106637905A true CN106637905A (en) | 2017-05-10 |
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| CN201710030139.4A Pending CN106637905A (en) | 2017-01-16 | 2017-01-16 | Bleaching reagent as well as preparation method and application thereof, and application of peracetic acid A liquid |
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Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN113152072A (en) * | 2021-02-09 | 2021-07-23 | 青岛融美发制品集团有限公司 | Quick and efficient bleaching process for real human hair |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5064441A (en) * | 1989-04-24 | 1991-11-12 | Kao Corporation | Hair treatment composition, bleaching composition and hair color tone modifier composition |
| CN102071567A (en) * | 2010-12-21 | 2011-05-25 | 东华大学 | Method for bleaching human hair fibers at low temperature with low damage |
| CN102517869A (en) * | 2011-12-06 | 2012-06-27 | 常熟市凯达印染有限公司 | Bleaching process of natural fibers |
| CN106263465A (en) * | 2015-05-18 | 2017-01-04 | 安徽金瑞祥发制品有限公司 | A kind of hair fades process technique |
-
2017
- 2017-01-16 CN CN201710030139.4A patent/CN106637905A/en active Pending
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5064441A (en) * | 1989-04-24 | 1991-11-12 | Kao Corporation | Hair treatment composition, bleaching composition and hair color tone modifier composition |
| CN102071567A (en) * | 2010-12-21 | 2011-05-25 | 东华大学 | Method for bleaching human hair fibers at low temperature with low damage |
| CN102517869A (en) * | 2011-12-06 | 2012-06-27 | 常熟市凯达印染有限公司 | Bleaching process of natural fibers |
| CN106263465A (en) * | 2015-05-18 | 2017-01-04 | 安徽金瑞祥发制品有限公司 | A kind of hair fades process technique |
Non-Patent Citations (2)
| Title |
|---|
| 杨华明等: "《现代医院消毒学》", 28 February 2013, 人民军医出版社 * |
| 裘炳毅等: "《现代化妆品科学与技术（中册）》", 31 March 2016, 中国轻工业出版社 * |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN113152072A (en) * | 2021-02-09 | 2021-07-23 | 青岛融美发制品集团有限公司 | Quick and efficient bleaching process for real human hair |
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