CN106637477A - Halogen-free flame retardant polyamide fiber - Google Patents

Halogen-free flame retardant polyamide fiber Download PDF

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Publication number
CN106637477A
CN106637477A CN201710003707.1A CN201710003707A CN106637477A CN 106637477 A CN106637477 A CN 106637477A CN 201710003707 A CN201710003707 A CN 201710003707A CN 106637477 A CN106637477 A CN 106637477A
Authority
CN
China
Prior art keywords
fiber
halogen
flame
retardant
nylon fibre
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201710003707.1A
Other languages
Chinese (zh)
Inventor
刘子胜
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Nantong Anheng Chemical Fiber Co Ltd
Original Assignee
Nantong Anheng Chemical Fiber Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Nantong Anheng Chemical Fiber Co Ltd filed Critical Nantong Anheng Chemical Fiber Co Ltd
Priority to CN201710003707.1A priority Critical patent/CN106637477A/en
Publication of CN106637477A publication Critical patent/CN106637477A/en
Pending legal-status Critical Current

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Classifications

    • DTEXTILES; PAPER
    • D01NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
    • D01FCHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
    • D01F6/00Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof
    • D01F6/88Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof from mixtures of polycondensation products as major constituent with other polymers or low-molecular-weight compounds
    • D01F6/90Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof from mixtures of polycondensation products as major constituent with other polymers or low-molecular-weight compounds of polyamides
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D5/00Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
    • C09D5/18Fireproof paints including high temperature resistant paints
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D5/00Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
    • C09D5/24Electrically-conducting paints
    • DTEXTILES; PAPER
    • D01NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
    • D01FCHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
    • D01F1/00General methods for the manufacture of artificial filaments or the like
    • D01F1/02Addition of substances to the spinning solution or to the melt
    • D01F1/07Addition of substances to the spinning solution or to the melt for making fire- or flame-proof filaments
    • DTEXTILES; PAPER
    • D01NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
    • D01FCHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
    • D01F1/00General methods for the manufacture of artificial filaments or the like
    • D01F1/02Addition of substances to the spinning solution or to the melt
    • D01F1/08Addition of substances to the spinning solution or to the melt for forming hollow filaments
    • DTEXTILES; PAPER
    • D01NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
    • D01FCHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
    • D01F1/00General methods for the manufacture of artificial filaments or the like
    • D01F1/02Addition of substances to the spinning solution or to the melt
    • D01F1/09Addition of substances to the spinning solution or to the melt for making electroconductive or anti-static filaments

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  • Engineering & Computer Science (AREA)
  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Textile Engineering (AREA)
  • Manufacturing & Machinery (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Materials Engineering (AREA)
  • Wood Science & Technology (AREA)
  • Organic Chemistry (AREA)
  • Chemical Or Physical Treatment Of Fibers (AREA)
  • Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)

Abstract

The invention relates to a halogen-free flame retardant polyamide fiber. The halogen-free flame retardant polyamide fiber comprises a fiber body, wherein the cross section of the fiber body is in a ring-shaped structure; the fiber body has a hollow cavity of which the cross section is a circle; a graphene conducting fiber and a plurality of Aramid fiber yarns are arranged in the hollow cavity; the Aramid fiber yarns are uniformly distributed at the periphery of the graphene conducting fiber; and the external surface of the fiber body is sequentially provided with an antistatic coating and a flame-retardant fiber layer. According to the invention, the Aramid fiber yarns and the flame-retardant fiber layer are added, so that the polyamide fiber has favorable flame retardancy and heat-insulating property; and meanwhile, the graphene conducting fiber is arranged in the fiber body, and the antistatic coating is arranged on the external surface, so that the friction between polyamide fibers can be decreased to reduce generation of static electricity, thereby ensuring that the polyamide fiber has favorable long-lasting antistatic functionality.

Description

A kind of halogen-free flameproof nylon fibre
Technical field
The present invention relates to a kind of textile material, and in particular to a kind of halogen-free flameproof nylon fibre.
Background technology
Nylon fibre is a kind of important textile material, and in the modern life, its application is ubiquitous, strong with taking exercise Degree is high, and anti-wear performance is excellent, and elasticity is good and the features such as light specific gravity, so in field and the defence and military such as clothing, family's decorations, industry On be widely used.
At present, harm of the electrostatic to human body is gradually taken seriously, with the enhancing of people's health consciousness, fiber system Product antistatic behaviour is increasingly paid close attention to by people, due to the hydrophobicity of nylon fibre, the static electricity gathered lotus easily on fiber, makes fibre Repel each other between dimension or be attracted on mechanical part, and be easily stained with dust, cause processing difficulties;For drawbacks described above, ability Field technique personnel need a kind of halogen-free flameproof nylon fibre of offer badly, not only improve the fire resistance of nylon fibre, while improving brocade The antistatic property of synthetic fibre fiber.
The content of the invention
It is an object of the invention to provide a kind of halogen-free flameproof nylon fibre, not only improves the fire resistance of nylon fibre, together The antistatic property of Shi Tigao nylon fibres.
For achieving the above object, there is provided following technical scheme:A kind of halogen-free flameproof nylon fibre, including fiber bodies, institute The cross section of fiber bodies is stated in cirque structure, it has the hollow cavity of circular in cross-section, sets in the hollow cavity There are graphene conductive fiber and some aramid fiber yarns, the aramid fiber yarn is evenly distributed on the periphery of the graphene conductive fiber, The outer surface of the fiber bodies is sequentially provided with antistatic coating and flame-retardant fibrous layer.
Preferably, the quantity of the aramid fiber yarn is 6~10.
Preferably, the flame-retardant fibrous layer is the flame-retardant fibrous layer containing phosphorus flame retardant.
Preferably, the antistatic coating is Teflon coating.
Preferably, the thickness of the antistatic coating is 10~20 μm.
The present invention provides a kind of having the beneficial effect that for halogen-free flameproof nylon fibre:The present invention is by adding aramid fiber yarn and resistance Combustion fibrage so that nylon fibre has good fire resistance and heat-proof quality, meanwhile, Graphene is set in fiber bodies Conductive fiber simultaneously arranges antistatic coating in its outer surface, reduces the friction between polyamide fibre, the generation of minimizing electrostatic so that polyamide fibre Possess excellent, lasting anti-static functional, increased value-added content of product, occupation rate of market is improve again, can obtain good Economic benefit and social benefit.
Description of the drawings
Technical scheme in order to be illustrated more clearly that the embodiment of the present invention, below by to be used needed for embodiment Accompanying drawing is briefly described, it should be apparent that, drawings in the following description are only some embodiments of the present invention, for ability For the those of ordinary skill of domain, on the premise of not paying creative work, can be attached to obtain others according to these accompanying drawings Figure.
Fig. 1 is the structural representation of halogen-free flameproof nylon fibre in the present invention.
Description of reference numerals:10. fiber bodies;20. hollow cavities;30. graphene conductive fibers;40. aramid fiber yarns; 50. antistatic coatings;60. flame-retardant fibrous layers.
Specific embodiment
To make present disclosure more clear understandable, below in conjunction with Figure of description, present disclosure is made into one Step explanation.Certainly the specific embodiment, the general replacement known to those skilled in the art be the invention is not limited in Cover within the scope of the present invention.Secondly, the present invention has carried out detailed statement using schematic diagram, real the present invention is described in detail During example, for convenience of description, schematic diagram, should not be in this, as limitation of the invention not according to general ratio partial enlargement.
Above and other technical characteristic and beneficial effect, by conjunction with the embodiments and accompanying drawing to the present invention halogen-free flameproof polyamide fibre Fiber is described in detail.Fig. 1 is the structural representation of halogen-free flameproof nylon fibre in the present invention.
As shown in figure 1, the present invention provides a kind of halogen-free flameproof nylon fibre, including fiber bodies 10, fiber bodies 10 Cross section is in cirque structure, and it has the hollow cavity 20 of circular in cross-section, and hollow cavity 20 is interior to be provided with graphene conductive Fiber 30, the outer surface of fiber bodies 10 is provided with antistatic coating 50, and antistatic coating 50 is Teflon coating, antistatic coating 50 thickness is preferably 10~20 μm.
The present invention in fiber bodies by arranging graphene conductive fiber 30 and arranging antistatic coating in its outer surface 50, reduce the friction between fiber bodies, the generation of minimizing electrostatic so that polyamide fibre possesses excellent, lasting anti-static functional.
6~10 aramid fiber yarns 40, aramid fiber are preferable provided with fire resistance in order to improve the present invention, hollow cavity 20 Silk 40 is evenly distributed on the periphery of graphene conductive fiber 30, and the outer surface of fiber bodies 10 is provided with flame-retardant fibrous layer 60, fire-retardant Fibrage 60 is preferably the flame-retardant fibrous layer containing phosphorus flame retardant.
In sum, the present invention is by adding aramid fiber yarn 40 and flame-retardant fibrous layer 60 so that nylon fibre has good Fire resistance and heat-proof quality, meanwhile, graphene conductive fiber 30 is set in the fiber bodies 10 and is arranged in its outer surface Antistatic coating 50, reduces the friction between polyamide fibre, the generation of minimizing electrostatic so that polyamide fibre possesses excellent, lasting antistatic Feature, increased value-added content of product, and occupation rate of market is improve again, can obtain good economic benefit and social benefit.
Although the present invention essentially describes above example, it is intended only as example to be been described by, and the present invention is simultaneously Not limited to this.Those of ordinary skill in the art can make the essential characteristics of various modifications and application without deviating from embodiment.For example, Each part being shown in detail to embodiment can be changed and run, and be believed that and be included in the modification and the related difference of application In protection scope of the present invention that claims are limited.
Involved embodiment in this specification, it is meant that the specially feature with reference to the embodiment description, structure or spy Property be included in the present invention at least one embodiment in.These terms for coming across in specification everywhere are not necessarily directed to same Embodiment.Additionally, when special characteristic, structure or characteristic is described with reference to any embodiment, all thinking that it falls into this area common Technical staff is combined in the range of these special characteristics, structure or characteristic that other embodiment just can be realized.

Claims (5)

1. a kind of halogen-free flameproof nylon fibre, including fiber bodies, it is characterised in that the cross section of the fiber bodies is in annulus Shape structure, it has the hollow cavity of circular in cross-section, and graphene conductive fiber and some is provided with the hollow cavity Aramid fiber yarn, the aramid fiber yarn is evenly distributed on the periphery of the graphene conductive fiber, and the outer surface of the fiber bodies is successively It is provided with antistatic coating and flame-retardant fibrous layer.
2. halogen-free flameproof nylon fibre according to claim 1, it is characterised in that the quantity of the aramid fiber yarn is 6~10 It is individual.
3. halogen-free flameproof nylon fibre according to claim 1, it is characterised in that the flame-retardant fibrous layer is containing phosphorus system The flame-retardant fibrous layer of fire retardant.
4. halogen-free flameproof nylon fibre according to claim 1, it is characterised in that the antistatic coating is that Teflon is applied Layer.
5. halogen-free flameproof nylon fibre according to claim 4, it is characterised in that the thickness of the antistatic coating is 10 ~20 μm.
CN201710003707.1A 2017-01-04 2017-01-04 Halogen-free flame retardant polyamide fiber Pending CN106637477A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201710003707.1A CN106637477A (en) 2017-01-04 2017-01-04 Halogen-free flame retardant polyamide fiber

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201710003707.1A CN106637477A (en) 2017-01-04 2017-01-04 Halogen-free flame retardant polyamide fiber

Publications (1)

Publication Number Publication Date
CN106637477A true CN106637477A (en) 2017-05-10

Family

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CN201710003707.1A Pending CN106637477A (en) 2017-01-04 2017-01-04 Halogen-free flame retardant polyamide fiber

Country Status (1)

Country Link
CN (1) CN106637477A (en)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN113584678A (en) * 2021-08-04 2021-11-02 广东坚达聚纤科技实业有限公司 Full-dull polyamide functional fiber

Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103541039A (en) * 2012-08-08 2014-01-29 江苏德赛化纤有限公司 Multifunctional modified polyester staple fiber and preparation method of same
CN204311186U (en) * 2014-12-05 2015-05-06 江西金源纺织有限公司 A kind of flame-resistant terylene complex yarn
CN105239178A (en) * 2015-10-30 2016-01-13 张家港欣阳化纤有限公司 A flame-retardant breathable compound filament yarn and a preparation method thereof
CN105369371A (en) * 2015-12-01 2016-03-02 马忠华 Antistatic polyamide fiber
KR20160053320A (en) * 2014-11-03 2016-05-13 주식회사 효성 Method for manufacturing core-sheath type antistatic fiber and the fiber manufactured thereof
CN206396364U (en) * 2017-01-04 2017-08-11 南通安恒化纤有限公司 A kind of halogen-free flameproof nylon fibre

Patent Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103541039A (en) * 2012-08-08 2014-01-29 江苏德赛化纤有限公司 Multifunctional modified polyester staple fiber and preparation method of same
KR20160053320A (en) * 2014-11-03 2016-05-13 주식회사 효성 Method for manufacturing core-sheath type antistatic fiber and the fiber manufactured thereof
CN204311186U (en) * 2014-12-05 2015-05-06 江西金源纺织有限公司 A kind of flame-resistant terylene complex yarn
CN105239178A (en) * 2015-10-30 2016-01-13 张家港欣阳化纤有限公司 A flame-retardant breathable compound filament yarn and a preparation method thereof
CN105369371A (en) * 2015-12-01 2016-03-02 马忠华 Antistatic polyamide fiber
CN206396364U (en) * 2017-01-04 2017-08-11 南通安恒化纤有限公司 A kind of halogen-free flameproof nylon fibre

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN113584678A (en) * 2021-08-04 2021-11-02 广东坚达聚纤科技实业有限公司 Full-dull polyamide functional fiber

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Application publication date: 20170510