CN106636218A - Method for preparing biogas and paper pulp from energy grass - Google Patents
Method for preparing biogas and paper pulp from energy grass Download PDFInfo
- Publication number
- CN106636218A CN106636218A CN201710155267.1A CN201710155267A CN106636218A CN 106636218 A CN106636218 A CN 106636218A CN 201710155267 A CN201710155267 A CN 201710155267A CN 106636218 A CN106636218 A CN 106636218A
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- China
- Prior art keywords
- grass
- biogas
- paper pulp
- energy
- energy grass
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- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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Classifications
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- C—CHEMISTRY; METALLURGY
- C12—BIOCHEMISTRY; BEER; SPIRITS; WINE; VINEGAR; MICROBIOLOGY; ENZYMOLOGY; MUTATION OR GENETIC ENGINEERING
- C12P—FERMENTATION OR ENZYME-USING PROCESSES TO SYNTHESISE A DESIRED CHEMICAL COMPOUND OR COMPOSITION OR TO SEPARATE OPTICAL ISOMERS FROM A RACEMIC MIXTURE
- C12P5/00—Preparation of hydrocarbons or halogenated hydrocarbons
- C12P5/02—Preparation of hydrocarbons or halogenated hydrocarbons acyclic
- C12P5/023—Methane
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21C—PRODUCTION OF CELLULOSE BY REMOVING NON-CELLULOSE SUBSTANCES FROM CELLULOSE-CONTAINING MATERIALS; REGENERATION OF PULPING LIQUORS; APPARATUS THEREFOR
- D21C5/00—Other processes for obtaining cellulose, e.g. cooking cotton linters ; Processes characterised by the choice of cellulose-containing starting materials
- D21C5/005—Treatment of cellulose-containing material with microorganisms or enzymes
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H11/00—Pulp or paper, comprising cellulose or lignocellulose fibres of natural origin only
- D21H11/12—Pulp from non-woody plants or crops, e.g. cotton, flax, straw, bagasse
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E50/00—Technologies for the production of fuel of non-fossil origin
- Y02E50/30—Fuel from waste, e.g. synthetic alcohol or diesel
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- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Organic Chemistry (AREA)
- Wood Science & Technology (AREA)
- Engineering & Computer Science (AREA)
- Biochemistry (AREA)
- Zoology (AREA)
- Microbiology (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Biotechnology (AREA)
- Bioinformatics & Cheminformatics (AREA)
- General Engineering & Computer Science (AREA)
- General Health & Medical Sciences (AREA)
- Genetics & Genomics (AREA)
- Paper (AREA)
Abstract
The invention discloses a method for preparing biogas and paper pulp from energy grass, belonging to the field of agricultural production. The method uses the energy grass as a raw material for high-efficiency production of biogas and paper pulp. According to the invention, the juice and residues of the energy grass are mechanically separated; the juice of the energy grass is subjected to anaerobic fermentation to prepare biogas; and the residues of the energy grass are used for production of paper pulp by using an ultrasonic-assisted biological enzyme method. The method provided by the invention realizes efficient and diversified utilization of the energy grass and provides a novel approach for comprehensive development and utilization of the energy grass.
Description
Technical field
The invention belongs to agricultural production system field, and in particular to a kind of utilization energy grass prepares the side of biogas and paper pulp
Method.
Background technology
Energy grass means a class based on grass, annual or perennial, high yield, high cellulose content
Energy-source plant.It is widely used in field of biological energy source, but not yet forms complete, rational system, therefore energy grass
Value does not maximize the use.
Paper pulp is the fibrous material obtained in Jing different processing methods with string as raw material.Can be according to processing method
It is divided into mechanical pulp, chemical pulp and chemimechanical pulp, it is the base stock of papermaking.Generally to the plant of pulping raw material
4 big class can be divided into:Stem fiber-like, bast fiber class, seed hair fiber class and lumber fibre class, stem fiber-like resource therein
Far from the needs for meeting growing pulp and paper industry.Paper, bast fiber class, seed hair fiber class needed for annual China
With lumber fibre class, all there is a problem of insufficient raw material, wherein especially with lumber fibre class as most important.Current China wood pulp
More than 40% needs from external import.
Biogas be organic substance under anaerobic, through a kind of mixed gas that the fermentation of microorganism is generated,
Its main component is methane and carbon dioxide, the gas such as also a small amount of nitrogen, hydrogen and hydrogen sulfide.Biogas is after purification highly concentrated
Degree methane, is also a kind of regenerative resource, and property is similar to natural gas.Biogas removes and directly burns for cooking, dries agricultural and sideline product
Product, heating, illumination and gas welding etc. are outer, can also make the fuel and production methyl alcohol, formalin, carbon tetrachloride of internal combustion engine etc.
Industrial chemicals.
The content of the invention
Object of the present invention is to provide a kind of method that utilization energy grass prepares biogas and paper pulp, is utilizing energy grass
Paper pulp is also produced while production biogas, the utilization scope of energy grass has been widened, a multi-direction comprehensive utilization energy has been constructed
The system of source grass.
For achieving the above object, the present invention is adopted the following technical scheme that:
A kind of method that utilization energy grass prepares biogas and paper pulp, by raw material of energy grass biogas and paper pulp are produced, including as follows
Step:
1) fresh energy grass is first ground into 0.1 ~ 5cm, then grass juice factor and careless slag is separated into by mechanical expression;
2) energy grass grass juice factor prepares biogas:By step 1) in isolated grass juice factor carry out biogas fermentation, 30 ~ 55 DEG C of temperature,
Total dry content is 3 ~ 20wt.%, and an input and output material was then carried out every 3 ~ 10 days;
3) carelessly slag prepares paper pulp to the energy:Take step 1) in the isolated further removal of impurities of careless slag, crush after, in ultrasonic wave
Water, mixed enzyme are added in reactor, mixing enzyme concentration is 1 ~ 100mg/g, 10 ~ 100khz of ultrasonic frequency, first at 40 ~ 70 DEG C
At a temperature of react after 1 ~ 5h, be warming up to 90 ~ 120 DEG C and react 1 ~ 5h again, then through defibrination, washing, screen and dehydration obtains paper
Slurry.
Wherein, described energy grass be Pennisetum plant, Sorghum propinquum, sugar grass, giantreed, reed, class reed, spot thatch, that
In special grass, sudangrass, Caulis Miscanthis floriduli, reed, awns, Arundinella hirta (Thunb.) Tanaka, Plantula Neyraudiae Reynaudianae, silage corn, lemongrass, Spartina alterniflora, Value of Spartina Anglica, switchgrass
One or more.
The present invention remarkable advantage be:There is provided various utilization orientations of energy grass, made using the fermentation of energy grass juice factor
On the basis of standby biogas, while producing paper pulp, a kind of system of agriculturally comprehensive energy utilization grass is formed.The present invention can be efficient
Ground utilize energy grass, individually the efficiency of fermentation is higher than and is directly fermented using energy grass grass juice factor.Overall process no pollution of the present invention,
The product of any pollution environment will not be produced.The present invention has prominent novelty and practical value.
Specific embodiment
Embodiment 1
Below with 10 tons of Jujun grasses(Pennisetum plant, dry matter content 25%)The concrete of the present invention is expanded on further for example
Embodiment, the present invention includes but is not limited to following instance.
1)Fresh Jujun grasses are first ground into 3cm, then grass juice factor and careless slag are separated into by mechanical expression;
2)Jujun grasses grass juice factor prepares biogas:By step 1) in isolated Jujun grasses grass juice factor carry out biogas fermentation, 55 DEG C of temperature,
Total dry content is 10wt.%, and an input and output material was then carried out every 3 days, and the biogas of generation can be applied directly to actual life
Produce, it is also possible to be purified to the bio-natural gas made above of methane concentration 97%.
3) Jujun grasses grass slag prepares paper pulp:Take step 1) in the isolated further removal of impurities of careless slag, crush after, super
Water, mixed enzyme are added in sound wave reactor, mixing enzyme concentration is 10mg/g, and ultrasonic frequency 70khz is first anti-at a temperature of 55 DEG C
After answering 2h, it is warming up to 110 DEG C and reacts 2h again, then paper pulp is obtained through defibrination, washing, screening and dehydration.
Paper pulp can further produce writing paper, paper for daily use and newsprint etc..
Using 10 tons of Jujun grasses of dry matter content 25% of the invention, the biogas 500 of methane content more than 55% can be produced within 3 days
Cubic meter, while the paper pulp of 1.5 tons of dries can be produced, substantially increases production efficiency, improves the economy of Jujun grasses
Value.
Embodiment 2
Below with 10 tons of silage corns(Dry matter content 35%)Specific embodiment of the invention is expanded on further for example, this
Invention includes but is not limited to following instance.
1)Fresh silage corn is first ground into 5cm, then grass juice factor and careless slag is separated into by mechanical expression;
2)Silage corn grass juice factor prepares biogas:By step 1) in isolated silage corn grass juice factor carry out biogas fermentation, temperature
37 DEG C, total dry content is 12wt.%, and an input and output material was then carried out every 7 days, and the biogas of generation can be applied directly to
Actual production, it is also possible to be purified to the bio-natural gas made above of methane concentration 97%.
3) silage corn grass slag prepares paper pulp:Take step 1) in the isolated further removal of impurities of careless slag, crush after,
Water, mixed enzyme are added in ultrasonic response kettle, mixing enzyme concentration is 20mg/g, and ultrasonic frequency 50khz is first at a temperature of 50 DEG C
After reaction 1.5h, it is warming up to 120 DEG C and reacts 1.5h again, then paper pulp is obtained through defibrination, washing, screening and dehydration.
Paper pulp can further produce writing paper, paper for daily use and newsprint etc..
Using 10 tons of silage corns of dry matter content 35% of the invention, the biogas that methane content more than 55% can be produced in 7 days
450 cubic metres, while the paper pulp of 2.5 tons of dries can be produced, production efficiency is substantially increased, improve silage corn
Economic worth.
The foregoing is only 2 embodiments of the present invention, all impartial changes done according to scope of the present invention patent with
Modification, should all belong to the covering scope of the present invention.
Claims (2)
1. a kind of method that utilization energy grass prepares biogas and paper pulp, it is characterised in that:With energy grass as raw material production biogas and
Paper pulp, comprises the steps:
1) fresh energy grass is first ground into 0.1 ~ 5cm, then grass juice factor and careless slag is separated into by mechanical expression;
2) energy grass grass juice factor prepares biogas:By step 1) in isolated grass juice factor carry out biogas fermentation, 30 ~ 55 DEG C of temperature,
Total dry content is 3 ~ 20wt.%, and an input and output material was then carried out every 3 ~ 10 days;
3) carelessly slag prepares paper pulp to the energy:Take step 1) in the isolated further removal of impurities of careless slag, crush after, in ultrasonic wave
Water, mixed enzyme are added in reactor, mixing enzyme concentration is 1 ~ 100mg/g, 10 ~ 100khz of ultrasonic frequency, first at 40 ~ 70 DEG C
At a temperature of react after 1 ~ 5h, be warmed up to 90 ~ 120 DEG C and react 1 ~ 5h again, then through defibrination, washing, screen and dehydration obtains paper
Slurry.
2. a kind of method that utilization energy grass prepares biogas and paper pulp, it is characterised in that:The energy grass is Pennisetum plant
Thing, Sorghum propinquum, sugar grass, giantreed, reed, class reed, spot thatch, that special grass, sudangrass, Caulis Miscanthis floriduli, reed, awns, Arundinella hirta (Thunb.) Tanaka, Shi Mang
One or more in grass, silage corn, lemongrass, Spartina alterniflora, Value of Spartina Anglica, switchgrass.
Priority Applications (1)
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CN201710155267.1A CN106636218A (en) | 2017-03-16 | 2017-03-16 | Method for preparing biogas and paper pulp from energy grass |
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CN201710155267.1A CN106636218A (en) | 2017-03-16 | 2017-03-16 | Method for preparing biogas and paper pulp from energy grass |
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CN201710155267.1A Pending CN106636218A (en) | 2017-03-16 | 2017-03-16 | Method for preparing biogas and paper pulp from energy grass |
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Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN109505187A (en) * | 2018-10-18 | 2019-03-22 | 黑龙江徐盛农业科技有限公司 | A kind of quick anaerobic fermentation biogas residue of stalk can make paper pulp |
CN112411229A (en) * | 2020-11-05 | 2021-02-26 | 江西中竹生物质科技有限公司 | Method for manufacturing sorghum stalk fiber pulp for packaging paper by ultrasonic wave |
Citations (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN1754961A (en) * | 2005-09-13 | 2006-04-05 | 新疆大学 | Production of ethyl alcohol and micro-fermentation feedstuff by sorgo straw |
CN101397575A (en) * | 2008-11-03 | 2009-04-01 | 新疆农垦科学院 | Method for improving sweet sorghum comprehensive utilization value |
CN104605153A (en) * | 2015-02-06 | 2015-05-13 | 福建农林大学 | Method for comprehensive utilization of energy grass in fields of feeds, biogas and paper pulp |
CN106120418A (en) * | 2016-06-30 | 2016-11-16 | 齐鲁工业大学 | A kind of poplar sonochemistry mechanical feedback technique |
-
2017
- 2017-03-16 CN CN201710155267.1A patent/CN106636218A/en active Pending
Patent Citations (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN1754961A (en) * | 2005-09-13 | 2006-04-05 | 新疆大学 | Production of ethyl alcohol and micro-fermentation feedstuff by sorgo straw |
CN101397575A (en) * | 2008-11-03 | 2009-04-01 | 新疆农垦科学院 | Method for improving sweet sorghum comprehensive utilization value |
CN104605153A (en) * | 2015-02-06 | 2015-05-13 | 福建农林大学 | Method for comprehensive utilization of energy grass in fields of feeds, biogas and paper pulp |
CN106120418A (en) * | 2016-06-30 | 2016-11-16 | 齐鲁工业大学 | A kind of poplar sonochemistry mechanical feedback technique |
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN109505187A (en) * | 2018-10-18 | 2019-03-22 | 黑龙江徐盛农业科技有限公司 | A kind of quick anaerobic fermentation biogas residue of stalk can make paper pulp |
CN112411229A (en) * | 2020-11-05 | 2021-02-26 | 江西中竹生物质科技有限公司 | Method for manufacturing sorghum stalk fiber pulp for packaging paper by ultrasonic wave |
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Application publication date: 20170510 |
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