CN106635344B - Washable punching drawing oil - Google Patents

Washable punching drawing oil Download PDF

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Publication number
CN106635344B
CN106635344B CN201611208702.4A CN201611208702A CN106635344B CN 106635344 B CN106635344 B CN 106635344B CN 201611208702 A CN201611208702 A CN 201611208702A CN 106635344 B CN106635344 B CN 106635344B
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Prior art keywords
oil
punching
washable
punching drawing
drawing oil
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CN201611208702.4A
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CN106635344A (en
Inventor
石杰
张世伟
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SHANGHAI SYNNEX LUBRICATION TECHNOLOGY Co Ltd
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SHANGHAI SYNNEX LUBRICATION TECHNOLOGY Co Ltd
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    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M169/00—Lubricating compositions characterised by containing as components a mixture of at least two types of ingredient selected from base-materials, thickeners or additives, covered by the preceding groups, each of these compounds being essential
    • C10M169/04—Mixtures of base-materials and additives
    • C10M169/048—Mixtures of base-materials and additives the additives being a mixture of compounds of unknown or incompletely defined constitution, non-macromolecular and macromolecular compounds
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2203/00—Organic non-macromolecular hydrocarbon compounds and hydrocarbon fractions as ingredients in lubricant compositions
    • C10M2203/10—Petroleum or coal fractions, e.g. tars, solvents, bitumen
    • C10M2203/1006—Petroleum or coal fractions, e.g. tars, solvents, bitumen used as base material
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
    • C10M2207/04—Ethers; Acetals; Ortho-esters; Ortho-carbonates
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
    • C10M2207/10—Carboxylix acids; Neutral salts thereof
    • C10M2207/18—Tall oil acids
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2209/00—Organic macromolecular compounds containing oxygen as ingredients in lubricant compositions
    • C10M2209/10—Macromolecular compoundss obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • C10M2209/103—Polyethers, i.e. containing di- or higher polyoxyalkylene groups
    • C10M2209/104—Polyethers, i.e. containing di- or higher polyoxyalkylene groups of alkylene oxides containing two carbon atoms only
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2211/00—Organic non-macromolecular compounds containing halogen as ingredients in lubricant compositions
    • C10M2211/08—Halogenated waxes
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2215/00—Organic non-macromolecular compounds containing nitrogen as ingredients in lubricant compositions
    • C10M2215/22—Heterocyclic nitrogen compounds
    • C10M2215/223—Five-membered rings containing nitrogen and carbon only
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2215/00—Organic non-macromolecular compounds containing nitrogen as ingredients in lubricant compositions
    • C10M2215/26—Amines
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2219/00—Organic non-macromolecular compounds containing sulfur, selenium or tellurium as ingredients in lubricant compositions
    • C10M2219/02—Sulfur-containing compounds obtained by sulfurisation with sulfur or sulfur-containing compounds
    • C10M2219/022—Sulfur-containing compounds obtained by sulfurisation with sulfur or sulfur-containing compounds of hydrocarbons, e.g. olefines
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2219/00—Organic non-macromolecular compounds containing sulfur, selenium or tellurium as ingredients in lubricant compositions
    • C10M2219/02—Sulfur-containing compounds obtained by sulfurisation with sulfur or sulfur-containing compounds
    • C10M2219/024—Sulfur-containing compounds obtained by sulfurisation with sulfur or sulfur-containing compounds of esters, e.g. fats
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2219/00—Organic non-macromolecular compounds containing sulfur, selenium or tellurium as ingredients in lubricant compositions
    • C10M2219/04—Organic non-macromolecular compounds containing sulfur, selenium or tellurium as ingredients in lubricant compositions containing sulfur-to-oxygen bonds, i.e. sulfones, sulfoxides
    • C10M2219/044—Sulfonic acids, Derivatives thereof, e.g. neutral salts
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2223/00—Organic non-macromolecular compounds containing phosphorus as ingredients in lubricant compositions
    • C10M2223/02—Organic non-macromolecular compounds containing phosphorus as ingredients in lubricant compositions having no phosphorus-to-carbon bonds
    • C10M2223/04—Phosphate esters
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2010/00—Metal present as such or in compounds
    • C10N2010/02—Groups 1 or 11
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2010/00—Metal present as such or in compounds
    • C10N2010/04—Groups 2 or 12
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2040/00—Specified use or application for which the lubricating composition is intended
    • C10N2040/20—Metal working
    • C10N2040/24—Metal working without essential removal of material, e.g. forming, gorging, drawing, pressing, stamping, rolling or extruding; Punching metal

Abstract

The invention discloses a kind of washable punching drawing oils, by weight percentage, it is composed of the following components: 10%~15% base oil 150SN, 5%~10% high viscosity self-emulsifying ester, 3%~5% sulfide aliphatic acid ester, 1%~3% olefine sulfide, 30%~40% chlorinated paraffin, 1%~5% phosphate, 1%~5% calcium mahogany sulfonate, 5%~15% petroleum sodium sulfonate, 1%~5% ready denier oil acid, 1%~5% isomerous tridecanol polyoxyethylene ether, 1%~5% organic alcohol ether, 1%~5% pH buffer, 1% corrosion inhibiter.Punching drawing oil of the present invention, performance fully meet the use demand of punching stretch technique, can successfully substitute current pure oil type punching drawing oil, and be readily cleaned.

Description

Washable punching drawing oil
Technical field
The present invention relates to washable punching drawing oils.
Background technique
Intermetallic composite coating includes cutting and punching stretch etc., and for cutting, stretched product has superior power Learn performance, so on the high metal product of some load requirements be mostly used punching stretch processing, as vehicle body punching press, bend pipe, it is expanding, Oil sump stretches etc., and punching stretch processing has that one-pass molding, speed is fast, the characteristics such as high-efficient.It is drawn in heavy load punching press Stretching needs the lubricant medium of medium-high viscosity mold and workpiece is isolated in process, prevent mold from pulling, and improves workpiece and draws It is stretched into power.Current heavy load punching drawing oil is mostly used mineral base base oil, the extreme-pressure anti-wears such as addition chlorine system, sulphur system, phosphorus system Agent, and be aided with ester lubricant and some tackifier etc. and deploy, this type products can play during punching stretch Good effect, but since its 40 DEG C of kinematic viscosity are mostly in 30c or more, it is higher to reach thousands of viscosity, it is completing the process After remain on workpiece and be difficult cleaning removal, need using a large amount of hydrocarbon solvents and be aided with heating ultrasound etc. equipment and clean, both Waste of resource pollutes environment again.
Summary of the invention
The purpose of the present invention is to provide a kind of washable punching drawing oil, performance fully meets punching stretch technique Use demand, can successfully substitute current pure oil type punching drawing oil, and be readily cleaned.
To achieve the above object, the present invention provides a kind of washable punching drawing oil, by weight percentage, by following Group is grouped as:
10%~15% base oil 150SN,
5%~10% high viscosity self-emulsifying ester,
3%~5% sulfide aliphatic acid ester,
1%~3% olefine sulfide,
30%~40% chlorinated paraffin,
1%~5% phosphate,
1%~5% calcium mahogany sulfonate,
5%~15% petroleum sodium sulfonate,
1%~5% ready denier oil acid,
1%~5% isomerous tridecanol polyoxyethylene ether,
1%~5% organic alcohol ether,
1%~5% pH buffer,
1% corrosion inhibiter.
Preferably, the pH buffer is triethanolamine.
Preferably, the corrosion inhibiter is methyl benzotriazole.
Advantages and advantages of the present invention are to provide a kind of washable punching drawing oil, performance are fully met The use demand of punching stretch technique can successfully substitute current pure oil type punching drawing oil, and be readily cleaned.
The invention has the characteristics that:
1, when punching drawing oil of the present invention is used for stainless steel products punching press, former water-insoluble product can perfect be substituted.
2, punching drawing oil of the present invention is subsequent easy to clean, can directly be rinsed with cold water, eliminates hydrocarbon solvent cleaning When resource loss and VOC emission pressure.
3, punching drawing oil of the present invention can be made into the dilution of different proportion, Lai Jinhang with water according to practical punching press demand Punch process meets the diversity of punch process, both saves use cost, also reduces inventory cost.
Specific embodiment
With reference to embodiment, the specific embodiment of the present invention is further described.Following embodiment is only used for more Add and clearly demonstrate technical solution of the present invention, and not intended to limit the protection scope of the present invention.
A kind of washable punching drawing oil, by weight percentage, composed of the following components:
10%~15% base oil 150SN,
5%~10% high viscosity self-emulsifying ester,
3%~5% sulfide aliphatic acid ester,
1%~3% olefine sulfide,
30%~40% chlorinated paraffin,
1%~5% phosphate,
1%~5% calcium mahogany sulfonate,
5%~15% petroleum sodium sulfonate,
1%~5% ready denier oil acid,
1%~5% isomerous tridecanol polyoxyethylene ether,
1%~5% organic alcohol ether,
1%~5% pH buffer,
1% corrosion inhibiter.
The pH buffer is triethanolamine.
The corrosion inhibiter is methyl benzotriazole.
The performance test of the washable punching drawing oil of the present invention is as follows:
Stoste appearance: as clear as crystal liquid；
Density (g/cm3, 15 DEG C): 1.1~1.2；
40 DEG C of kinematic viscosity@, mm2/s:200；
Open flash point, DEG C: > 180；
Copper corrosion: 1b；
Pb value, kg:181；
Pd value, kg:600；
Property miscible with water: 100% is miscible.
The technical solution that the present invention embodies is:
Embodiment 1
A kind of washable punching drawing oil, by weight percentage, composed of the following components:
10% base oil 150SN,
10% high viscosity self-emulsifying ester,
5% sulfide aliphatic acid ester,
3% olefine sulfide,
30% chlorinated paraffin,
5% phosphate,
5% calcium mahogany sulfonate,
15% petroleum sodium sulfonate,
4% ready denier oil acid,
4% isomerous tridecanol polyoxyethylene ether,
4% organic alcohol ether,
4% triethanolamine,
1% methyl benzotriazole.
Embodiment 2
A kind of washable punching drawing oil, by weight percentage, composed of the following components:
15% base oil 150SN,
5% high viscosity self-emulsifying ester,
3% sulfide aliphatic acid ester,
1% olefine sulfide,
38% chlorinated paraffin,
1% phosphate,
1% calcium mahogany sulfonate,
15% petroleum sodium sulfonate,
5% ready denier oil acid,
5% isomerous tridecanol polyoxyethylene ether,
5% organic alcohol ether,
5% triethanolamine,
1% methyl benzotriazole.
Embodiment 3
A kind of washable punching drawing oil, by weight percentage, composed of the following components:
13% base oil 150SN,
7% high viscosity self-emulsifying ester,
4% sulfide aliphatic acid ester,
2% olefine sulfide,
37% chlorinated paraffin,
4% phosphate,
4% calcium mahogany sulfonate,
14% petroleum sodium sulfonate,
4% ready denier oil acid,
3% isomerous tridecanol polyoxyethylene ether,
4% organic alcohol ether,
3% triethanolamine,
1% methyl benzotriazole.
The above is only a preferred embodiment of the present invention, it is noted that for the ordinary skill people of the art For member, without departing from the technical principles of the invention, several improvements and modifications can also be made, these improvements and modifications Also it should be regarded as protection scope of the present invention.

Claims (1)

1. washable punching drawing oil, which is characterized in that by weight percentage, composed of the following components:
13% base oil 150SN,
7% high viscosity self-emulsifying ester,
4% sulfide aliphatic acid ester,
2% olefine sulfide,
37% chlorinated paraffin,
4% phosphate,
4% calcium mahogany sulfonate,
14% petroleum sodium sulfonate,
4% ready denier oil acid,
3% isomerous tridecanol polyoxyethylene ether,
4% organic alcohol ether,
3% triethanolamine,
1% methyl benzotriazole.
CN201611208702.4A 2016-12-23 2016-12-23 Washable punching drawing oil Active CN106635344B (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201611208702.4A CN106635344B (en) 2016-12-23 2016-12-23 Washable punching drawing oil

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201611208702.4A CN106635344B (en) 2016-12-23 2016-12-23 Washable punching drawing oil

Publications (2)

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CN106635344A CN106635344A (en) 2017-05-10
CN106635344B true CN106635344B (en) 2019-07-05

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Families Citing this family (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN108531279A (en) * 2018-06-12 2018-09-14 上海加美实业有限公司 A kind of easy cleaning can deep stretch punching oil
CN108753417A (en) * 2018-07-02 2018-11-06 嘉兴市国龙石油化工有限公司 A kind of Multi-functional aluminum metal working fluid and preparation method thereof
CN110452764A (en) * 2019-08-20 2019-11-15 嘉兴市国龙石油化工股份有限公司 A kind of low viscosity aqueous pressure cooker deep draw drawing oil and preparation method thereof
CN112457903A (en) * 2019-09-09 2021-03-09 东莞市英飞特润滑科技有限公司 Stretching oil and preparation method thereof
CN111560284A (en) * 2020-05-21 2020-08-21 昆山久茂电子科技有限公司 Stretching oil for stamping electronic product plates and preparation method thereof
CN115558538B (en) * 2022-09-22 2023-08-22 广州市联诺化工科技有限公司 Environment-friendly stamping drawing liquid and application thereof

Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4201681A (en) * 1977-10-03 1980-05-06 Exxon Research & Engineering Co. Metalworking corrosion inhibition/drawing lubricant
CN101260339A (en) * 2008-04-22 2008-09-10 大连三达奥克化学股份有限公司 Ultra-thin copper foil board water-base stamping stretching oil and producing method thereof
CN102787007A (en) * 2012-04-23 2012-11-21 广州市联诺化工科技有限公司 Green environment-friendly soluble stamping and drawing oil and preparation method thereof
CN103031189A (en) * 2011-10-10 2013-04-10 洛科斯润滑油（上海）有限公司 Metal drawing oil
CN105154187A (en) * 2015-09-18 2015-12-16 南京科润工业介质股份有限公司 Emulsified liquid capable of replacing oil products and preparation method of emulsified liquid

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4201681A (en) * 1977-10-03 1980-05-06 Exxon Research & Engineering Co. Metalworking corrosion inhibition/drawing lubricant
CN101260339A (en) * 2008-04-22 2008-09-10 大连三达奥克化学股份有限公司 Ultra-thin copper foil board water-base stamping stretching oil and producing method thereof
CN103031189A (en) * 2011-10-10 2013-04-10 洛科斯润滑油（上海）有限公司 Metal drawing oil
CN102787007A (en) * 2012-04-23 2012-11-21 广州市联诺化工科技有限公司 Green environment-friendly soluble stamping and drawing oil and preparation method thereof
CN105154187A (en) * 2015-09-18 2015-12-16 南京科润工业介质股份有限公司 Emulsified liquid capable of replacing oil products and preparation method of emulsified liquid

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