CN106635315A - Environmental-friendly lubricating oil and preparation method thereof - Google Patents

Environmental-friendly lubricating oil and preparation method thereof Download PDF

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Publication number
CN106635315A
CN106635315A CN201610960626.6A CN201610960626A CN106635315A CN 106635315 A CN106635315 A CN 106635315A CN 201610960626 A CN201610960626 A CN 201610960626A CN 106635315 A CN106635315 A CN 106635315A
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parts
temperature
environment
lubricant oil
stirring reaction
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钱华
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Suzhou Shengxin New Materials Co Ltd
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Suzhou Shengxin New Materials Co Ltd
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    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M169/00—Lubricating compositions characterised by containing as components a mixture of at least two types of ingredient selected from base-materials, thickeners or additives, covered by the preceding groups, each of these compounds being essential
    • C10M169/04—Mixtures of base-materials and additives
    • C10M169/048—Mixtures of base-materials and additives the additives being a mixture of compounds of unknown or incompletely defined constitution, non-macromolecular and macromolecular compounds
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2205/00—Organic macromolecular hydrocarbon compounds or fractions, whether or not modified by oxidation as ingredients in lubricant compositions
    • C10M2205/02—Organic macromolecular hydrocarbon compounds or fractions, whether or not modified by oxidation as ingredients in lubricant compositions containing acyclic monomers
    • C10M2205/026—Butene
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
    • C10M2207/02—Hydroxy compounds
    • C10M2207/021—Hydroxy compounds having hydroxy groups bound to acyclic or cycloaliphatic carbon atoms
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
    • C10M2207/02—Hydroxy compounds
    • C10M2207/023—Hydroxy compounds having hydroxy groups bound to carbon atoms of six-membered aromatic rings
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
    • C10M2207/08—Aldehydes; Ketones
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
    • C10M2207/10—Carboxylix acids; Neutral salts thereof
    • C10M2207/12—Carboxylix acids; Neutral salts thereof having carboxyl groups bound to acyclic or cycloaliphatic carbon atoms
    • C10M2207/125—Carboxylix acids; Neutral salts thereof having carboxyl groups bound to acyclic or cycloaliphatic carbon atoms having hydrocarbon chains of eight up to twenty-nine carbon atoms, i.e. fatty acids
    • C10M2207/126—Carboxylix acids; Neutral salts thereof having carboxyl groups bound to acyclic or cycloaliphatic carbon atoms having hydrocarbon chains of eight up to twenty-nine carbon atoms, i.e. fatty acids monocarboxylic
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
    • C10M2207/28—Esters
    • C10M2207/281—Esters of (cyclo)aliphatic monocarboxylic acids
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
    • C10M2207/28—Esters
    • C10M2207/32—Esters of carbonic acid
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
    • C10M2207/40—Fatty vegetable or animal oils
    • C10M2207/401—Fatty vegetable or animal oils used as base material
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2209/00—Organic macromolecular compounds containing oxygen as ingredients in lubricant compositions
    • C10M2209/12—Polysaccharides, e.g. cellulose, biopolymers
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2211/00—Organic non-macromolecular compounds containing halogen as ingredients in lubricant compositions
    • C10M2211/08—Halogenated waxes
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2215/00—Organic non-macromolecular compounds containing nitrogen as ingredients in lubricant compositions
    • C10M2215/08—Amides
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2030/00—Specified physical or chemical properties which is improved by the additive characterising the lubricating composition, e.g. multifunctional additives
    • C10N2030/02—Pour-point; Viscosity index
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2030/00—Specified physical or chemical properties which is improved by the additive characterising the lubricating composition, e.g. multifunctional additives
    • C10N2030/06—Oiliness; Film-strength; Anti-wear; Resistance to extreme pressure
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2030/00—Specified physical or chemical properties which is improved by the additive characterising the lubricating composition, e.g. multifunctional additives
    • C10N2030/64—Environmental friendly compositions

Abstract

The invention discloses environmental-friendly lubricating oil which comprises the following substances in parts by weight: 50-60 parts of soybean oil, 40-60 parts of sunflower seed oil, 6-11 parts of calcium 2-ethylcaproate, 8-13 parts of carboxymethylcellulose, 10-16 parts of 2,3,4-trimethyl-3-amyl alcohol, 4-9 parts of chlorinated paraffin, 5-10 parts of L-glutamine, 3-8 parts of 2-ethoxyphenol, 3-6 parts of bomyl acetate, 8-12 parts of dicyclopentadiene diepoxide, 1-5 parts of 1,3-cyclohexanedione, 7-15 parts of lauryl methacrylate, 8-12 parts of polyisobutene and 5-11 parts of propylene carbonate. In the preparation process of the lubricating oil, adding mineral oil and animal oil is avoided, so that the prepared lubricating oil is slight in environment pollution, high in viscosity index and good in wearing resistance.

Description

A kind of environment-protective lubricant oil and preparation method thereof
Technical field
The invention belongs to technical field of lubricating oil, more particularly to a kind of environment-protective lubricant oil and preparation method thereof.
Background technology
In enterprise production process, be chronically at due to plant equipment lubrication " it is say important, do secondary, hurry Come should not " situation, cause equipment lubrication failure many, lubriation material wastes big, and environmental pollution is serious, and lubricating arrangement complexity is numerous Trivial, lubrication workload is too big, and this causes many equipment to suffer very big economic loss using enterprise.What is more, and management personnel lack Weary equipment lubrication knowledge, the relevant personnel are also to cause a reason more than lubrication trouble to lubricating main points and not grasping, such as：Machine Serious wear, noise are big, power consumption is high, oil vacuole is more, oil temperature is high and fat loss, oil leak are universal, poor performance at low temperatures, difficulty in starting and Slide creeping, bearing is stuck（Vexed car）, the shake of elevating screw, the de- of freewheel clutch do not open（It is out of control）Deng a series of problems, such as May be bad with equipment lubrication relevant, it can be seen that lubricating oil is requisite in plant equipment.
Lubricating oil is a kind of nonvolatile oily lubricant, and by its source animal and vegetable oil, petroleum oil and synthesis are divided into Lubricating oil three major types.In plant equipment Industry Quick Development instantly, lubricating oil is widely used in all kinds mechanically, main Play the effects such as lubrication, cooling, antirust, cleaning, sealing and buffering.
The very big satisfaction of people's material life, also improve people's spirit and consciousness, and problem of environmental pollution is also increasingly becoming Focus of concern.On the market still based on mineral lubricating oil, these mineral lubricating oils are such as the lubrication of a large amount of plant equipment Fruit is emitted in air, soil, waters, then can cause environmental pollution, destroys ecological balance, gives people class health and lives seat belt Carry out hidden danger.Accordingly, it would be desirable to develop a kind of environmental protection, high lubricating effect lubricating oil to reduce environmental disruption.
The content of the invention
For drawbacks described above, it is an object of the invention to provide a kind of environment-protective lubricant oil and preparation method thereof, with Oleum Glycines, sunflower Oil based on seed oil, and add many kinds of substance, obtain the environment-friendly lubricating oil of high lubricating effect.
The purpose of the present invention can be achieved through the following technical solutions：
A kind of environment-protective lubricant oil, each material comprising following composition by weight：Oleum Glycines 50-60 parts, Oleum Helianthi 40-60 parts, 2- second Base caproic acid calcium 6-11 parts, carboxymethyl cellulose 8-13 parts, 2,3,4- trimethyl -3- amylalcohol 10-16 parts, chlorinated paraffin 4-9 parts, L- Glutamine 5-10 parts, 2- thanatol 3-8 parts, borneol acetate 3-6 parts, titanium dioxide dicyclopentadiene 8-12 parts, 1, Hydroresorcinol 1-5 parts, lauryl methacrylate 7-15 parts, polyisobutylene 8-12 parts, Allyl carbonate 5-11 part.
Further, described Oleum Glycines 55-60 parts, Oleum Helianthi 40-50 parts, 2 ethyl hexanoic acid calcium 7-10 parts, carboxymethyl are fine Dimension element 9-12 parts, 2,3,4- trimethyl -3- amylalcohol 12-15 parts, chlorinated paraffin 5-8 parts, L-glutaminate 7-9 parts, 2- ethyoxyls Phenol 5-7 parts, borneol acetate 4-6 parts, titanium dioxide dicyclopentadiene 9-11 parts, hydroresorcinol 2-4 parts, metering system Sour lauryl 9-12 parts, polyisobutylene 10-12 parts, Allyl carbonate 7-10 part.
Further, 58 parts of the Oleum Glycines, 45 parts of Oleum Helianthi, 8 parts of 2 ethyl hexanoic acid calcium, 11 parts of carboxymethyl cellulose, 13 parts of 2,3,4- trimethyl -3- amylalcohols, 6 parts of chlorinated paraffin, 8 parts of L-glutaminate, 6 parts of 2- thanatols, borneol acetate 5 Part, 10 parts of titanium dioxide dicyclopentadiene, 3 parts of hydroresorcinol, 10 parts of lauryl methacrylate, 11 parts of polyisobutylene, 9 parts of Allyl carbonate.
A kind of preparation method of environment-protective lubricant oil, comprises the steps：
S1：By Oleum Glycines 50-60 parts, Oleum Helianthi 40-60 parts, 2 ethyl hexanoic acid calcium 6-11 parts, carboxymethyl cellulose 8-13 parts, two Oxidative dimerization cyclopentadiene 8-12 parts and 1, the mixing of hydroresorcinol 1-5 parts, stirring reaction 15- at temperature 50-60 DEG C 20min, obtains mixed liquor A；
S2：By 2,3,4- trimethyl -3- amylalcohol 10-16 parts, chlorinated paraffin 4-9 parts, L-glutaminate 5-10 parts, 2- ethoxybenzenes Phenol 3-8 parts, polyisobutylene 8-12 parts, the mixing of Allyl carbonate 5-11 part, stirring reaction 20-30min at temperature 70-80 DEG C, Obtain mixed liquid B；
S3：Mixed liquid B in mixed liquor A in step S1 and step S2 is mixed, Dropping funnel Deca second is used at temperature 80-90 DEG C Sour norbornene ester 3-6 parts, Deca lauryl methacrylate 7-15 parts again after reaction 5-10min, are subsequently increased to 120- by temperature 130 DEG C, with speed 500-800r/min stirring reaction 1-3h；The environment-protective lubricant oil is obtained after question response cooling.
Further, temperature described in step S1 is 57 DEG C, with speed 400-500r/min stirring reaction 18min.
Further, temperature described in step S2 is 75 DEG C, with speed 600-800r/min stirring reaction 25min.
Further, the temperature of Deca borneol acetate 3-6 parts is 88 DEG C in step S3, and time for adding is 8-10min；Drop The time of methylate lauryl acrylate is 10-12min；Temperature is increased to 126 DEG C, with speed 700r/min stirring reaction 2h.
Compared with prior art, its advantage is the present invention：
The preparation method of environment-protective lubricant oil of the present invention, the oil based on Oleum Glycines and Oleum Helianthi mixture, with 2- ethyl hexyls The materials such as sour calcium, carboxymethyl cellulose, 2- thanatols and borneol acetate are additive, and heated hybrid reaction is prepared into To the lubricating oil of environment-friendly type；Avoid the addition of mineral oil and animal oil, resulting lubricating oil environmental pollution, viscosity index (VI) High, wear resistence is good.
Specific embodiment
With reference to embodiments the present invention is further illustrated.
Embodiment 1
S1：By 50 parts of Oleum Glycines, 40 parts of Oleum Helianthi, 6 parts of 2 ethyl hexanoic acid calcium, 8 parts of carboxymethyl cellulose, the polycyclic penta of titanium dioxide two 8 parts of diene and 1,1 part of mixing of hydroresorcinol, under temperature 50 C, with speed 400r/min stirring reaction 15min, must mix Liquid A；
S2：By 10 parts of 2,3,4- trimethyl -3- amylalcohols, 4 parts of chlorinated paraffin, 5 parts of L-glutaminate, 3 parts of 2- thanatols, poly- 8 parts of isobutene., 5 parts of mixing of Allyl carbonate, under temperature 70 C, with speed 600r/min stirring reaction 20min, obtain mixed liquor B；
S3：Mixed liquid B in mixed liquor A in step S1 and step S2 is mixed, at 80 DEG C of temperature with Dropping funnel in 8min 3 parts of Deca borneol acetate, 7 parts of Deca lauryl methacrylate in 10min again after reaction 5min, subsequently raises temperature To 120 DEG C, with speed 500r/min stirring reaction 1h；The environment-protective lubricant oil is obtained after question response cooling.
Comparative example 1
S1：By 50 parts of Oleum Glycines, the 8 parts of mixing of 40 parts of Oleum Helianthi and titanium dioxide dicyclopentadiene, under temperature 50 C, with speed 400r/min stirring reactions 15min, obtain mixed liquor A；
S2：By 4 parts of chlorinated paraffin, the 5 parts of mixing of 8 parts of polyisobutylene and Allyl carbonate, under temperature 70 C, with speed 600r/ Min stirring reactions 20min, obtain mixed liquid B；
S3：Mixed liquid B in mixed liquor A in step S1 and step S2 is mixed, temperature 120 DEG C is increased to into, with speed 500r/ Min stirring reactions 1h；Lubricating oil is obtained after question response cooling.
Embodiment 2
S1：By 60 parts of Oleum Glycines, 60 parts of Oleum Helianthi, 11 parts of 2 ethyl hexanoic acid calcium, 13 parts of carboxymethyl cellulose, the polycyclic of titanium dioxide two 12 parts of pentadiene and 1,5 parts of mixing of hydroresorcinol, under temperature 60 C, with speed 500r/min stirring reaction 20min, obtains mixed Close liquid A；
S2：By 16 parts of 2,3,4- trimethyl -3- amylalcohols, 9 parts of chlorinated paraffin, 10 parts of L-glutaminate, 8 parts of 2- thanatols, 12 parts of polyisobutylene, 11 parts of mixing of Allyl carbonate, at 80 DEG C of temperature, with speed 800r/min stirring reaction 30min, obtain mixed Close liquid B；
S3：Mixed liquid B in mixed liquor A in step S1 and step S2 is mixed, at 90 DEG C of temperature with Dropping funnel in 10min 6 parts of Deca borneol acetate, 15 parts of Deca lauryl methacrylate in 12min again after reaction 10min, subsequently by temperature liter Up to 130 DEG C, with speed 800r/min stirring reaction 3h；The environment-protective lubricant oil is obtained after question response cooling.
Comparative example 2
S1：By 60 parts of Oleum Glycines, the 12 parts of mixing of 60 parts of Oleum Helianthi and titanium dioxide dicyclopentadiene, under temperature 60 C, with speed Rate 500r/min stirring reaction 20min, obtains mixed liquor A；
S2：By 9 parts of chlorinated paraffin, the 11 parts of mixing of 12 parts of polyisobutylene and Allyl carbonate, at 80 DEG C of temperature, with speed 800r/min stirring reactions 30min, obtain mixed liquid B；
S3：Mixed liquid B in mixed liquor A in step S1 and step S2 is mixed, temperature 130 DEG C is increased to into, with speed 800r/ Min stirring reactions 3h；Lubricating oil is obtained after question response cooling.
Embodiment 3
S1：By 55 parts of Oleum Glycines, 40 parts of Oleum Helianthi, 7 parts of 2 ethyl hexanoic acid calcium, 9 parts of carboxymethyl cellulose, the polycyclic penta of titanium dioxide two 9 parts of diene and 1,2 parts of mixing of hydroresorcinol, under temperature 50 C, with speed 400r/min stirring reaction 15min, must mix Liquid A；
S2：By 12 parts of 2,3,4- trimethyl -3- amylalcohols, 5 parts of chlorinated paraffin, 7 parts of L-glutaminate, 5 parts of 2- thanatols, poly- 10 parts of isobutene., 7 parts of mixing of Allyl carbonate, under temperature 70 C, with speed 600r/min stirring reaction 20min, must mix Liquid B；
S3：Mixed liquid B in mixed liquor A in step S1 and step S2 is mixed, at 80 DEG C of temperature with Dropping funnel in 8min 4 parts of Deca borneol acetate, 9 parts of Deca lauryl methacrylate in 12min again after reaction 5min, subsequently raises temperature To 130 DEG C, with speed 800r/min stirring reaction 3h；The environment-protective lubricant oil is obtained after question response cooling.
Embodiment 4
S1：By 60 parts of Oleum Glycines, 50 parts of Oleum Helianthi, 10 parts of 2 ethyl hexanoic acid calcium, 12 parts of carboxymethyl cellulose, the polycyclic of titanium dioxide two 11 parts of pentadiene and 1,4 parts of mixing of hydroresorcinol, under temperature 60 C, with speed 500r/min stirring reaction 20min, obtains mixed Close liquid A；
S2：By 15 parts of 2,3,4- trimethyl -3- amylalcohols, 8 parts of chlorinated paraffin, 9 parts of L-glutaminate, 7 parts of 2- thanatols, poly- 12 parts of isobutene., 10 parts of mixing of Allyl carbonate, at 80 DEG C of temperature, with speed 800r/min stirring reaction 30min, must mix Liquid B；
S3：Mixed liquid B in mixed liquor A in step S1 and step S2 is mixed, at 90 DEG C of temperature with Dropping funnel in 10min 6 parts of Deca borneol acetate, 12 parts of Deca lauryl methacrylate in 10min again after reaction 10min, subsequently by temperature liter Up to 120 DEG C, with speed 700r/min stirring reaction 1h；The environment-protective lubricant oil is obtained after question response cooling.
Embodiment 5
S1：By 58 parts of Oleum Glycines, 45 parts of Oleum Helianthi, 8 parts of 2 ethyl hexanoic acid calcium, 11 parts of carboxymethyl cellulose, the polycyclic of titanium dioxide two 10 parts of pentadiene and 1,3 parts of mixing of hydroresorcinol, at 57 DEG C of temperature, with speed 450r/min stirring reaction 18min, obtains mixed Close liquid A；
S2：By 13 parts of 2,3,4- trimethyl -3- amylalcohols, 6 parts of chlorinated paraffin, 8 parts of L-glutaminate, 6 parts of 2- thanatols, poly- 11 parts of isobutene., 9 parts of mixing of Allyl carbonate, at 75 DEG C of temperature, with speed 700r/min stirring reaction 25min, must mix Liquid B；
S3：Mixed liquid B in mixed liquor A in step S1 and step S2 is mixed, at 88 DEG C of temperature with Dropping funnel in 9min 5 parts of Deca borneol acetate, 10 parts of Deca lauryl methacrylate in 11min again after reaction 8min, subsequently by temperature liter Up to 126 DEG C, with speed 700r/min stirring reaction 2h；The environment-protective lubricant oil is obtained after question response cooling.
Above example and comparative example gained lubricating oil are carried out into performance detection；As a result such as following table：
The invention is not restricted to embodiment here, those skilled in the art's announcement of the invention, without departing from scope The improvement and modification made all should be within protection scope of the present invention.

Claims (7)

1. a kind of environment-protective lubricant oil, it is characterised in that each material comprising following composition by weight：Oleum Glycines 50-60 parts, Oleum Helianthi 40-60 parts, 2 ethyl hexanoic acid calcium 6-11 parts, carboxymethyl cellulose 8-13 parts, 2,3,4- trimethyl -3- amylalcohol 10-16 parts, chlorination Paraffin 4-9 parts, L-glutaminate 5-10 parts, 2- thanatol 3-8 parts, borneol acetate 3-6 parts, the polycyclopentadithio.henes of titanium dioxide two Alkene 8-12 parts, hydroresorcinol 1-5 parts, lauryl methacrylate 7-15 parts, polyisobutylene 8-12 parts, Allyl carbonate 5- 11 parts.
2. a kind of environment-protective lubricant oil according to claim 1, it is characterised in that described Oleum Glycines 55-60 parts, Oleum Helianthi 40-50 parts, 2 ethyl hexanoic acid calcium 7-10 parts, carboxymethyl cellulose 9-12 parts, 2,3,4- trimethyl -3- amylalcohol 12-15 parts, chlorination Paraffin 5-8 parts, L-glutaminate 7-9 parts, 2- thanatol 5-7 parts, borneol acetate 4-6 parts, the polycyclopentadithio.henes of titanium dioxide two Alkene 9-11 parts, hydroresorcinol 2-4 parts, lauryl methacrylate 9-12 parts, polyisobutylene 10-12 parts, Allyl carbonate 7-10 parts.
3. a kind of environment-protective lubricant oil according to claim 2, it is characterised in that 58 parts of the Oleum Glycines, 45 parts of Oleum Helianthi, 8 parts of 2 ethyl hexanoic acid calcium, 11 parts of carboxymethyl cellulose, 13 parts of 2,3,4- trimethyl -3- amylalcohols, 6 parts of chlorinated paraffin, L- glutamy 8 parts of amine, 6 parts of 2- thanatols, 5 parts of borneol acetate, 10 parts of titanium dioxide dicyclopentadiene, 3 parts of hydroresorcinol, first 10 parts of base lauryl acrylate, 11 parts of polyisobutylene, 9 parts of Allyl carbonate.
4. a kind of preparation method of environment-protective lubricant oil, it is characterised in that comprise the steps：
S1：By Oleum Glycines 50-60 parts, Oleum Helianthi 40-60 parts, 2 ethyl hexanoic acid calcium 6-11 parts, carboxymethyl cellulose 8-13 parts, two Oxidative dimerization cyclopentadiene 8-12 parts and 1, the mixing of hydroresorcinol 1-5 parts, stirring reaction 15- at temperature 50-60 DEG C 20min, obtains mixed liquor A；
S2：By 2,3,4- trimethyl -3- amylalcohol 10-16 parts, chlorinated paraffin 4-9 parts, L-glutaminate 5-10 parts, 2- ethoxybenzenes Phenol 3-8 parts, polyisobutylene 8-12 parts, the mixing of Allyl carbonate 5-11 part, stirring reaction 20-30min at temperature 70-80 DEG C, Obtain mixed liquid B；
S3：Mixed liquid B in mixed liquor A in step S1 and step S2 is mixed, Dropping funnel Deca second is used at temperature 80-90 DEG C Sour norbornene ester 3-6 parts, Deca lauryl methacrylate 7-15 parts again after reaction 5-10min, are subsequently increased to 120- by temperature 130 DEG C, with speed 500-800r/min stirring reaction 1-3h；The environment-protective lubricant oil is obtained after question response cooling.
5. a kind of preparation method of environment-protective lubricant oil according to claim 4, it is characterised in that temperature described in step S1 For 57 DEG C, with speed 400-500r/min stirring reaction 18min.
6. a kind of preparation method of environment-protective lubricant oil according to claim 4, it is characterised in that temperature described in step S2 For 75 DEG C, with speed 600-800r/min stirring reaction 25min.
7. a kind of preparation method of environment-protective lubricant oil according to claim 4, it is characterised in that Deca acetic acid in step S3 The temperature of norbornene ester 3-6 parts is 88 DEG C, and time for adding is 8-10min；The time of Deca lauryl methacrylate is 10- 12min；Temperature is increased to 126 DEG C, with speed 700r/min stirring reaction 2h.
CN201610960626.6A 2016-11-04 2016-11-04 Environmental-friendly lubricating oil and preparation method thereof Pending CN106635315A (en)

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Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102433195A (en) * 2011-10-24 2012-05-02 中国石油化工股份有限公司 Open gear lubricating grease composition
CN104263486A (en) * 2014-09-09 2015-01-07 安徽旺达铜业发展有限公司 Water-based metal wire drawing liquid with good lubricating effect and preparation method thereof
CN104804797A (en) * 2015-05-06 2015-07-29 颜凤生 Engine oil composition and preparation method thereof

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102433195A (en) * 2011-10-24 2012-05-02 中国石油化工股份有限公司 Open gear lubricating grease composition
CN104263486A (en) * 2014-09-09 2015-01-07 安徽旺达铜业发展有限公司 Water-based metal wire drawing liquid with good lubricating effect and preparation method thereof
CN104804797A (en) * 2015-05-06 2015-07-29 颜凤生 Engine oil composition and preparation method thereof

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Application publication date: 20170510