CN106635191A - Fuel prepared from renewable resources and preparation method thereof - Google Patents

Fuel prepared from renewable resources and preparation method thereof Download PDF

Info

Publication number
CN106635191A
CN106635191A CN201611150463.1A CN201611150463A CN106635191A CN 106635191 A CN106635191 A CN 106635191A CN 201611150463 A CN201611150463 A CN 201611150463A CN 106635191 A CN106635191 A CN 106635191A
Authority
CN
China
Prior art keywords
parts
fuel
aqueous solution
amine
amidin
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201611150463.1A
Other languages
Chinese (zh)
Inventor
钟书明
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Qinzhou University
Original Assignee
Qinzhou University
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Qinzhou University filed Critical Qinzhou University
Priority to CN201611150463.1A priority Critical patent/CN106635191A/en
Publication of CN106635191A publication Critical patent/CN106635191A/en
Pending legal-status Critical Current

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10LFUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L1/00Liquid carbonaceous fuels
    • C10L1/02Liquid carbonaceous fuels essentially based on components consisting of carbon, hydrogen, and oxygen only
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02EREDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E50/00Technologies for the production of fuel of non-fossil origin
    • Y02E50/10Biofuels, e.g. bio-diesel

Landscapes

  • Chemical & Material Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Liquid Carbonaceous Fuels (AREA)
  • Solid Fuels And Fuel-Associated Substances (AREA)

Abstract

The invention discloses a fuel prepared from renewable resources and a preparation method thereof. The fuel is composed of the following components in parts by weight: 20 to 25 parts of biological diesel, 20 to 22 parts of coal-to-liquids, 18 to 20 parts of plant grease, 18 to 20 parts of microbial grease, 18 to 20 parts of vegetable oleic acid, 10 to 12 parts of diethanolamine, 5 to 7 parts of di-n-pentyl ether (DNPE), 5 to 7 parts of vinyl ester copolymer, 5 to 6 parts of water solution of polyacrylamide, 5 to 6 parts of water solution of sodium dialkyl sulfate, 3 to 4 parts of water solution of plant soap powder, 5 to 10 parts of hydrogen oxide, and 5 to 10 parts of cyclohexyl amine.

Description

A kind of fuel and preparation method of utilization renewable resource
Technical field
The present invention relates to fuel technology field, the fuel and its preparation side in particular to a kind of utilization renewable resource Method.
Background technology
Oil and fuel oil eries product must add various additives according to China about the policy of environmental protection and energy-conservation, make Vehicle and engine structure need not be changed with fuel oil additive, engine power just can be improved, oil is reduced and is released, purifying engine row Put, reduce pollution.But the enterprise of the country can only apply at present traditional mediation, emulsification, the production technology of sulfonation, produce function Single common uprising dose, antioxidant, lubricant, stabilizer or Cetane number dose etc., but effect is undesirable, equal nothing Method reaches the double effectses of energy-conservation and purification simultaneously.Fuel oil additive is caused to use loaded down with trivial details and high into wood.And, it is domestic Existing various fuel oil additive manufacturing process do not reach environmental protection requirement and manufacturing enterprise technical indicator, and storage and Also it is limited by transit link, yield can not meet the market demand.Fuel oil additive (the composite type fuel oil of high-quality Additive-the function with multiple additives) mainly for a long time dependence on import causes the loss of a large amount of foreign exchange funds.
The content of the invention
For the problems referred to above, the invention provides the fuel and preparation method of a kind of utilization renewable resource.
For achieving the above object, the present invention provides following technical scheme:
A kind of fuel of utilization renewable resource, is made up of following mass fraction formula components:
20~25 parts of biodiesel, 20~22 parts of coal liquifaction, 18~20 parts of vegetable fat, 18~20 parts of microbial grease, 18~20 parts of vegetable oil acid, 10~12 parts of diethanol amine, 5~7 parts of two n-pentyl ether, 5~7 parts of vinyl ester copolymers, polypropylene 5~6 parts of phthalein amine aqueous solution, 5~6 parts of the sodium dialkyl sulfate aqueous solution, 3~4 parts of plant soap amidin, 5~10 parts of hydrogen oxide, 5~10 parts of ring amine.
Further, it is made up of following mass fraction formula components:
20 parts of biodiesel, 20 parts of coal liquifaction, 18 parts of vegetable fat, 18 parts of microbial grease, 18 parts of vegetable oil acid, diethyl 10 parts of hydramine, 5 parts of two n-pentyl ether, 5 parts of vinyl ester copolymers, 5 parts of polypropylene phthalein amine aqueous solution, the sodium dialkyl sulfate aqueous solution 5 parts, 3 parts of plant soap amidin, 5 parts of hydrogen oxide, 5 parts of ring amine.
Further, it is made up of following mass fraction formula components:
25 parts of biodiesel, 22 parts of coal liquifaction, 20 parts of vegetable fat, 20 parts of microbial grease, 20 parts of vegetable oil acid, diethyl 12 parts of hydramine, 7 parts of two n-pentyl ether, 7 parts of vinyl ester copolymers, 6 parts of polypropylene phthalein amine aqueous solution, the sodium dialkyl sulfate aqueous solution 6 parts, 4 parts of plant soap amidin, 10 parts of hydrogen oxide, 10 parts of ring amine.
Further, it is made up of following mass fraction formula components:
23 parts of biodiesel, 21 parts of coal liquifaction, 19 parts of vegetable fat, 19 parts of microbial grease, 19 parts of vegetable oil acid, diethyl 11 parts of hydramine, 6 parts of two n-pentyl ether, 6 parts of vinyl ester copolymers, 5 parts of polypropylene phthalein amine aqueous solution, the sodium dialkyl sulfate aqueous solution 5 parts, 4 parts of plant soap amidin, 7 parts of hydrogen oxide, 7 parts of ring amine.
Further:Preparation method of the present invention has following steps:
Step one, diethanol amine, two n-pentyl ethers, vinyl ester copolymers are mixed 5~10 minutes, make the first examination Agent;
Step 2, by polypropylene phthalein amine aqueous solution, the sodium dialkyl sulfate aqueous solution, plant soap amidin 5 are mixed ~10 minutes, make the second reagent;
Step 3, by biodiesel, coal liquifaction, vegetable fat, microbial grease, vegetable oil acid reactor is added, and is added First reagent carries out oxidation reaction, and the reaction time is 1~1.5 hour, and reaction temperature is 90~110 DEG C, makes intermediate fuel 1;
Step 4, the second reagent, hydrogen oxide and ring amine are added in intermediate fuel 1, carry out secondary oxidation reaction, are reacted Time is 1~1.5 hour, and reaction temperature is 150~200 DEG C, makes intermediate fuel 2;
Step 5, plus 2 by intermediate fuel and adding in complex reactor carries out complex reaction, and the reaction time is 0.5~1 little When, make intermediate fuel 3;
Step 6, intermediate fuel 3 is put in purifying column and is refined, and extraction temperature is 80~110 DEG C, makes middle combustion Material 4.
The invention has the beneficial effects as follows:
1st, produce without waste in fuel production of the invention and combustion process;
2nd, fuel combustion of the invention cleaning, beneficial to environmental protection;
3rd, fuel cost of the invention is low.
Specific embodiment
Below in conjunction with the embodiment of the present invention, the technical scheme in the embodiment of the present invention is clearly and completely described, Obviously, described embodiment is only a part of embodiment of the invention, rather than the embodiment of whole.Based in the present invention Embodiment, the every other embodiment that those of ordinary skill in the art are obtained under the premise of creative work is not made, all Belong to the scope of protection of the invention.
Embodiment one:
A kind of fuel of utilization renewable resource, is made up of following mass fraction formula components:20~25 parts of biodiesel, 20~22 parts of coal liquifaction, 18~20 parts of vegetable fat, 18~20 parts of microbial grease, 18~20 parts of vegetable oil acid, diethanol amine 10~12 parts, 5~7 parts of two n-pentyl ether, 5~7 parts of vinyl ester copolymers, 5~6 parts of polypropylene phthalein amine aqueous solution, dialkyl group sulphur 5~6 parts of acid sodium aqueous solution, 3~4 parts of plant soap amidin, 5~10 parts of hydrogen oxide, 5~10 parts of ring amine.
Embodiment two:
A kind of fuel of utilization renewable resource, is made up of following mass fraction formula components:20 parts of biodiesel, coal system 20 parts of oil, 18 parts of vegetable fat, 18 parts of microbial grease, 18 parts of vegetable oil acid, 10 parts of diethanol amine, 5 parts of two n-pentyl ether, second 5 parts of enoate copolymer, 5 parts of polypropylene phthalein amine aqueous solution, 5 parts of the sodium dialkyl sulfate aqueous solution, 3 parts of plant soap amidin, oxygen Change 5 parts of hydrogen, 5 parts of ring amine.
Embodiment three:
A kind of fuel of utilization renewable resource, is made up of following mass fraction formula components:25 parts of biodiesel, coal system 22 parts of oil, 20 parts of vegetable fat, 20 parts of microbial grease, 20 parts of vegetable oil acid, 12 parts of diethanol amine, 7 parts of two n-pentyl ether, second 7 parts of enoate copolymer, 6 parts of polypropylene phthalein amine aqueous solution, 6 parts of the sodium dialkyl sulfate aqueous solution, 4 parts of plant soap amidin, oxygen Change 10 parts of hydrogen, 10 parts of ring amine.
Example IV:
A kind of fuel of utilization renewable resource, is made up of following mass fraction formula components:23 parts of biodiesel, coal system 21 parts of oil, 19 parts of vegetable fat, 19 parts of microbial grease, 19 parts of vegetable oil acid, 11 parts of diethanol amine, 6 parts of two n-pentyl ether, second 6 parts of enoate copolymer, 5 parts of polypropylene phthalein amine aqueous solution, 5 parts of the sodium dialkyl sulfate aqueous solution, 4 parts of plant soap amidin, oxygen Change 7 parts of hydrogen, 7 parts of ring amine.
Embodiment five:
A kind of fuel its preparation method of utilization renewable resource comprises the steps:
Step one, diethanol amine, two n-pentyl ethers, vinyl ester copolymers are mixed 5~10 minutes, make the first examination Agent;
Step 2, by polypropylene phthalein amine aqueous solution, the sodium dialkyl sulfate aqueous solution, plant soap amidin 5 are mixed ~10 minutes, make the second reagent;
Step 3, by biodiesel, coal liquifaction, vegetable fat, microbial grease, vegetable oil acid reactor is added, and is added First reagent carries out oxidation reaction, and the reaction time is 1~1.5 hour, and reaction temperature is 90~110 DEG C, makes intermediate fuel 1;
Step 4, the second reagent, hydrogen oxide and ring amine are added in intermediate fuel 1, carry out secondary oxidation reaction, are reacted Time is 1~1.5 hour, and reaction temperature is 150~200 DEG C, makes intermediate fuel 2;
Step 5, plus 2 by intermediate fuel and adding in complex reactor carries out complex reaction, and the reaction time is 0.5~1 little When, make intermediate fuel 3;
Step 6, intermediate fuel 3 is put in purifying column and is refined, and extraction temperature is 80~110 DEG C, makes middle combustion Material 4.
Moreover, it will be appreciated that although this specification is been described by according to embodiment, not each embodiment is only wrapped Containing an independent technical scheme, this narrating mode of specification is only that for clarity those skilled in the art should Using specification as an entirety, the technical scheme in each embodiment can also Jing it is appropriately combined, form those skilled in the art Understandable other embodiment.

Claims (5)

1. a kind of fuel of utilization renewable resource, it is characterised in that:It is made up of following mass fraction formula components:
20~25 parts of biodiesel, 20~22 parts of coal liquifaction, 18~20 parts of vegetable fat, 18~20 parts of microbial grease, plant 18~20 parts of oleic acid, 10~12 parts of diethanol amine, 5~7 parts of two n-pentyl ether, 5~7 parts of vinyl ester copolymers, polypropylene phthalein amine 5~6 parts of the aqueous solution, 5~6 parts of the sodium dialkyl sulfate aqueous solution, 3~4 parts of plant soap amidin, 5~10 parts of hydrogen oxide, ring are 5~10 parts of amine.
2. the fuel of a kind of utilization renewable resource according to claim 1, it is characterised in that:Matched somebody with somebody by following mass fraction Side is into being grouped into:
20 parts of biodiesel, 20 parts of coal liquifaction, 18 parts of vegetable fat, 18 parts of microbial grease, 18 parts of vegetable oil acid, diethanol amine 10 parts, 5 parts of two n-pentyl ether, 5 parts of vinyl ester copolymers, 5 parts of polypropylene phthalein amine aqueous solution, 5 parts of the sodium dialkyl sulfate aqueous solution, 3 parts of plant soap amidin, 5 parts of hydrogen oxide, 5 parts of ring amine.
3. the fuel of a kind of utilization renewable resource according to claim 1, it is characterised in that:Matched somebody with somebody by following mass fraction Side is into being grouped into:
25 parts of biodiesel, 22 parts of coal liquifaction, 20 parts of vegetable fat, 20 parts of microbial grease, 20 parts of vegetable oil acid, diethanol amine 12 parts, 7 parts of two n-pentyl ether, 7 parts of vinyl ester copolymers, 6 parts of polypropylene phthalein amine aqueous solution, 6 parts of the sodium dialkyl sulfate aqueous solution, 4 parts of plant soap amidin, 10 parts of hydrogen oxide, 10 parts of ring amine.
4. the fuel of a kind of utilization renewable resource according to claim 1, it is characterised in that:Matched somebody with somebody by following mass fraction Side is into being grouped into:
23 parts of biodiesel, 21 parts of coal liquifaction, 19 parts of vegetable fat, 19 parts of microbial grease, 19 parts of vegetable oil acid, diethanol amine 11 parts, 6 parts of two n-pentyl ether, 6 parts of vinyl ester copolymers, 5 parts of polypropylene phthalein amine aqueous solution, 5 parts of the sodium dialkyl sulfate aqueous solution, 4 parts of plant soap amidin, 7 parts of hydrogen oxide, 7 parts of ring amine.
5. a kind of a kind of preparation method of the fuel of utilization renewable resource according to claim 1, it is characterised in that:Bag Include following steps:
Step one, diethanol amine, two n-pentyl ethers, vinyl ester copolymers are mixed 5~10 minutes, make the first reagent;
Step 2, by polypropylene phthalein amine aqueous solution, the sodium dialkyl sulfate aqueous solution, plant soap amidin 5~10 are mixed Minute, make the second reagent;
Step 3, biodiesel, coal liquifaction, vegetable fat, microbial grease, vegetable oil acid are added reactor, and Jia the first Reagent carries out oxidation reaction, and the reaction time is 1~1.5 hour, and reaction temperature is 90~110 DEG C, makes intermediate fuel 1;
Step 4, the second reagent, hydrogen oxide and ring amine are added in intermediate fuel 1, carry out secondary oxidation reaction, reaction time For 1~1.5 hour, reaction temperature was 150~200 DEG C, makes intermediate fuel 2;
Step 5, plus 2 by intermediate fuel and adding in complex reactor carries out complex reaction, and the reaction time is 0.5~1 hour, system Into intermediate fuel 3;
Step 6, intermediate fuel 3 is put in purifying column and is refined, and extraction temperature is 80~110 DEG C, makes intermediate fuel 4.
CN201611150463.1A 2016-12-14 2016-12-14 Fuel prepared from renewable resources and preparation method thereof Pending CN106635191A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201611150463.1A CN106635191A (en) 2016-12-14 2016-12-14 Fuel prepared from renewable resources and preparation method thereof

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201611150463.1A CN106635191A (en) 2016-12-14 2016-12-14 Fuel prepared from renewable resources and preparation method thereof

Publications (1)

Publication Number Publication Date
CN106635191A true CN106635191A (en) 2017-05-10

Family

ID=58825187

Family Applications (1)

Application Number Title Priority Date Filing Date
CN201611150463.1A Pending CN106635191A (en) 2016-12-14 2016-12-14 Fuel prepared from renewable resources and preparation method thereof

Country Status (1)

Country Link
CN (1) CN106635191A (en)

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101280229A (en) * 2008-05-16 2008-10-08 运城市丰喜新能源开发有限公司 Alcohol fuel additive capable of preventing metal corrosion and inhibiting rubber swelling
CN102174337A (en) * 2011-03-17 2011-09-07 吉林市富源化工厂 Modified alcohol-base environment-protection fuel and preparation method thereof
CN102643686A (en) * 2012-04-23 2012-08-22 哈尔滨宏利盛达科技发展有限公司 Compound-type environmentally-friendly fuel oil solution and preparation method thereof
CN104099141A (en) * 2014-08-01 2014-10-15 东莞市向阳世纪能源有限公司 Energy-saving environment-friendly fuel oil and preparation method thereof

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101280229A (en) * 2008-05-16 2008-10-08 运城市丰喜新能源开发有限公司 Alcohol fuel additive capable of preventing metal corrosion and inhibiting rubber swelling
CN102174337A (en) * 2011-03-17 2011-09-07 吉林市富源化工厂 Modified alcohol-base environment-protection fuel and preparation method thereof
CN102643686A (en) * 2012-04-23 2012-08-22 哈尔滨宏利盛达科技发展有限公司 Compound-type environmentally-friendly fuel oil solution and preparation method thereof
CN104099141A (en) * 2014-08-01 2014-10-15 东莞市向阳世纪能源有限公司 Energy-saving environment-friendly fuel oil and preparation method thereof

Similar Documents

Publication Publication Date Title
Masri et al. A sustainable, high-performance process for the economic production of waste-free microbial oils that can replace plant-based equivalents
Wang et al. Biofuels in China: opportunities and challenges
Zhong et al. Biofuels in China: past, present and future
Siddique et al. Biofuels in Malaysian perspective: Debates and benefits
CN100489072C (en) Blended fuel oil and manufacturing technique
CN102994176A (en) Environment-friendly gasoline additive
Gong et al. Synergistic effect of glucose and glycerol accelerates microbial lipid production from low-cost substrates by Cutaneotrichosporon oleaginosum
CN106635191A (en) Fuel prepared from renewable resources and preparation method thereof
CN101423767A (en) Method for preparing biodiesel by alcohol extraction and solid base catalysis two-step method
CN102876403A (en) Alcohol ether diesel fuel for new-energy-resource vehicle
CN103421550B (en) A kind of environment protection type biological liquid fuel and preparation method thereof
CN101974356A (en) Low-carbon type biological product oil
CN106520218B (en) Ecological fuel oil and preparation method thereof
CN101307262B (en) Biology liquid fuel of high heat value and method for preparing same
CN106367127B (en) Alcohol-based fuel and preparation method thereof
CN103382416B (en) A kind of technique of biodiesel esterification
CN100516181C (en) Alcoholic composite gasoline and its preparing method
CN105132043B (en) A kind of bio-fuel-oil and preparation method thereof
CN102732332B (en) Preparation method of methanol/butanol mixed vehicle fuel
CN103382417B (en) A kind of technique of biofuel transesterification reaction
CN102732354A (en) Municipal domestic garbage biomass environment-friendly renewable energy additive, and preparation method thereof
Liang Preparation of fuel ethanol from lignocellulose and design of fermenatin tank
Hilgert Techno-economic feasibility analysis of a second-generation ethanol plant using the solid part of digestate as feedstock
CN104073300B (en) A kind of biodiesel and preparation method thereof
CN109097114A (en) Multipurpose non-pollution liquid fuel and preparation method thereof

Legal Events

Date Code Title Description
PB01 Publication
PB01 Publication
SE01 Entry into force of request for substantive examination
SE01 Entry into force of request for substantive examination
CB03 Change of inventor or designer information

Inventor after: Wang Weijian

Inventor after: Xie Meijuan

Inventor after: Zhan Hao

Inventor before: Zhong Shuming

CB03 Change of inventor or designer information
WD01 Invention patent application deemed withdrawn after publication

Application publication date: 20170510

WD01 Invention patent application deemed withdrawn after publication