CN106633647A - Ionic type flame-retardant anti-static high polymer material - Google Patents
Ionic type flame-retardant anti-static high polymer material Download PDFInfo
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- CN106633647A CN106633647A CN201611093244.4A CN201611093244A CN106633647A CN 106633647 A CN106633647 A CN 106633647A CN 201611093244 A CN201611093244 A CN 201611093244A CN 106633647 A CN106633647 A CN 106633647A
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- polymer material
- type flame
- ionic type
- flame retardant
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L63/00—Compositions of epoxy resins; Compositions of derivatives of epoxy resins
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/002—Physical properties
- C08K2201/003—Additives being defined by their diameter
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/011—Nanostructured additives
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/02—Flame or fire retardant/resistant
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/04—Antistatic
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
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- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Abstract
The invention relates to the technical field of high polymer materials, in particular to an ionic type flame-retardant anti-static high polymer material. The ionic type flame-retardant anti-static high polymer material is prepared from the following components in parts by mass: 50 to 60 parts of polyether ether ketone, 2.4 to 5.4 parts of carbon nanotubes, 8.6 to 14 parts of maleic anhydride grafted polyethylene, 60 to 80 parts of epoxy resin, 2.4 to 6 parts of potassium titanate, 4 to 10 parts of anhydrous calcium chloride, 0.8 to 1.6 parts of anti-static agent and 12 to 18 parts of flame retardant. Compared with traditional HKD-151 and traditional HKD-520, the anti-static agent in the invention has very strong moisture absorption ability; very good anti-static performance can be expressed even if the addition amount is very low; compared with a pure PP (Propene Polymer) product, the tensile strength of the ionic type flame-retardant anti-static high polymer material is increased after the anti-static agent is added.
Description
Technical field
The present invention relates to technical field of polymer materials, especially a kind of Ionic type flame retardant antistatic polymer material.
Background technology
Polypropylene (PP) has function admirable, the characteristics of cheap, therefore obtains a wide range of applications.But PP is non-pole
Property macromolecular material, surface resistivity Rs is up to 1015Ω～1018Ω, water imbibition is poor, therefore material surface electrostatic charge product when using
It is tired serious, affect it to use, it is therefore necessary to carry out antistatic treatment to it, the harm for preventing electrostatic from producing.Ionic macromolecule
Material obtains extensive research and applies at aspects such as Green Chemistry, chemical engineering, catalytic reaction and functional material preparations, but
Ionic macromolecular material is also less as the correlative study report of addition type Polymeric anti-static agent.
The content of the invention
The purpose of the present invention is：Overcome deficiency of the prior art, there is provided a kind of Ionic type flame retardant antistatic macromolecule material
Material.
For achieving the above object, the technical solution used in the present invention is as follows：
A kind of Ionic type flame retardant antistatic polymer material, its mass parts composition is as follows：Polyether-ether-ketone 50-60 parts, CNT
2.4-5.4 parts, maleic anhydride grafted polyethylene 8.6-14 parts, epoxy resin 60-80 parts, potassium titanate 2.4-6 parts, anhydrous chlorine
Change calcium 4-10 parts, antistatic additive 0.8-1.6 parts, fire retardant 12-18 parts.
Preferably, the particle diameter of the CNT is 28-38nm.
Preferably, the antistatic additive is from phenylethylene resin series, polyvinyl chloride, polyethylene terephthalate and gathers
Carbonic ester.
Preferably, the antistatic additive is from phenylethylene resin series, polyvinyl chloride and polyethylene terephthalate
Mixture, its mass ratio is 1:0.8-1.1:0.8.
Preferably, the antistatic additive is from phenylethylene resin series, polyvinyl chloride and polyethylene terephthalate
Mass ratio is 1:0.9:0.8.
Preferably, from APP and the mixture of triphenyl phosphate, its mass ratio is 1 to the fire retardant:0.6-
1.2。
Preferably, from APP and the mixture of triphenyl phosphate, its mass ratio is 1 to the fire retardant:0.8.
It is using the beneficial effect of technical scheme：
Antistatic additive is planted compared with traditional HKD-151, HKD-520, there is very strong wettability power in the present invention；Addition
When very low (1.0 mass parts), good antistatic property is just shown；Compared with pure PP products, add antistatic additive
Afterwards, the tensile strength of material is improved.
Specific embodiment
With reference to specific embodiment, the invention will be further described.
Embodiment 1
A kind of Ionic type flame retardant antistatic polymer material, its mass parts composition is as follows：50 parts of polyether-ether-ketone, CNT 2.4
It is part, 8.6 parts of maleic anhydride grafted polyethylene, 60 parts of epoxy resin, 2.4 parts of potassium titanate, 4 parts of anhydrous calcium chloride, antistatic
0.8 part of agent, 12 parts of fire retardant.
Wherein, the particle diameter of CNT is 28nm.
Wherein, antistatic additive selects phenylethylene resin series, polyvinyl chloride, polyethylene terephthalate and poly- carbonic acid
Ester, its mass ratio is 1:0.8:0.8.
Wherein, from APP and the mixture of triphenyl phosphate, its mass ratio is 1 to fire retardant:0.6.
Embodiment 2
A kind of Ionic type flame retardant antistatic polymer material, its mass parts composition is as follows：52 parts of polyether-ether-ketone, CNT 2.8
It is part, 8.8 parts of maleic anhydride grafted polyethylene, 62 parts of epoxy resin, 2.8 parts of potassium titanate, 5 parts of anhydrous calcium chloride, antistatic
1 part of agent, 13 parts of fire retardant.
Wherein, the particle diameter of CNT is 30nm.
Wherein, antistatic additive selects phenylethylene resin series, polyvinyl chloride, polyethylene terephthalate and Merlon
Mixture, its mass ratio be 1:0.9:0.8.
Wherein, from APP and the mixture of triphenyl phosphate, its mass ratio is 1 to fire retardant:0.8.
Embodiment 3
A kind of Ionic type flame retardant antistatic polymer material, its mass parts composition is as follows：55 parts of polyether-ether-ketone, 4 parts of CNT,
12 parts of maleic anhydride grafted polyethylene, 70 parts of epoxy resin, 4.2 parts of potassium titanate, 7 parts of anhydrous calcium chloride, antistatic additive 1.2
Part, 15 parts of fire retardant.
Wherein, the particle diameter of CNT is 32nm.
Wherein, antistatic additive selects phenylethylene resin series, polyvinyl chloride, polyethylene terephthalate and Merlon
Mixture, its mass ratio be 1:0.9:0.8.
Wherein, from APP and the mixture of triphenyl phosphate, its mass ratio is 1 to fire retardant:0.8.
Embodiment 4
A kind of Ionic type flame retardant antistatic polymer material, its mass parts composition is as follows：58 parts of polyether-ether-ketone, 5 parts of CNT,
13 parts of maleic anhydride grafted polyethylene, 76 parts of epoxy resin, 5.2 parts of potassium titanate, 9 parts of anhydrous calcium chloride, antistatic additive 1.5
Part, 16 parts of fire retardant.
Wherein, the particle diameter of CNT is 36nm.
Wherein, antistatic additive selects phenylethylene resin series, polyvinyl chloride, polyethylene terephthalate and Merlon
Mixture, its mass ratio be 1:1:0.8.
Wherein, from APP and the mixture of triphenyl phosphate, its mass ratio is 1 to fire retardant:1.
Embodiment 5
A kind of Ionic type flame retardant antistatic polymer material, its mass parts composition is as follows：60 parts of polyether-ether-ketone, CNT 5.4
Part, 14 parts of maleic anhydride grafted polyethylene, 80 parts of epoxy resin, 6 parts of potassium titanate, 10 parts of anhydrous calcium chloride, antistatic additive
1.6 parts, 18 parts of fire retardant.
Wherein, the particle diameter of CNT is 38nm.
Wherein, antistatic additive selects phenylethylene resin series, polyvinyl chloride, polyethylene terephthalate and Merlon
Mixture, its mass ratio be 1:1.1:0.8.
Wherein, from APP and the mixture of triphenyl phosphate, its mass ratio is 1 to fire retardant:1.2.
Embodiment 3 is preferred embodiment.
Embodiment 1-5 is obtained using conventional method.
With the above-mentioned desirable embodiment according to the present invention as enlightenment, by above-mentioned description, relevant staff is complete
Entirely various change and modification can be carried out in the range of without departing from this invention technological thought.The technology of this invention
Property scope is not limited to the content on specification, it is necessary to its technical scope is determined according to right.
Claims (7)
1. a kind of Ionic type flame retardant antistatic polymer material, it is characterised in that its mass parts composition is as follows：Polyether-ether-ketone 50-
60 parts, CNT 2.4-5.4 parts, maleic anhydride grafted polyethylene 8.6-14 parts, epoxy resin 60-80 parts, potassium titanate
2.4-6 parts, anhydrous calcium chloride 4-10 parts, antistatic additive 0.8-1.6 parts, fire retardant 12-18 parts.
2. a kind of Ionic type flame retardant antistatic polymer material according to claim 1, it is characterised in that：The carbon nanometer
The particle diameter of pipe is 28-38nm.
3. a kind of Ionic type flame retardant antistatic polymer material according to claim 1, it is characterised in that：It is described antistatic
Phenylethylene resin series, polyvinyl chloride, polyethylene terephthalate and Merlon are selected in agent.
4. a kind of Ionic type flame retardant antistatic polymer material according to claim 4, it is characterised in that：It is described antistatic
From the mixture of phenylethylene resin series, polyvinyl chloride and polyethylene terephthalate, its mass ratio is 1 for agent:0.8-
1.1:0.8。
5. a kind of Ionic type flame retardant antistatic polymer material according to claim 5, it is characterised in that：It is described antistatic
Agent is 1 from the mass ratio of phenylethylene resin series, polyvinyl chloride and polyethylene terephthalate:0.9:0.8.
6. a kind of Ionic type flame retardant antistatic polymer material according to claim 1, it is characterised in that：The fire retardant
From APP and the mixture of triphenyl phosphate, its mass ratio is 1:0.6-1.2.
7. a kind of Ionic type flame retardant antistatic polymer material according to claim 6, it is characterised in that：The fire retardant
From APP and the mixture of triphenyl phosphate, its mass ratio is 1:0.8.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201611093244.4A CN106633647A (en) | 2016-12-02 | 2016-12-02 | Ionic type flame-retardant anti-static high polymer material |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201611093244.4A CN106633647A (en) | 2016-12-02 | 2016-12-02 | Ionic type flame-retardant anti-static high polymer material |
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| CN106633647A true CN106633647A (en) | 2017-05-10 |
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|---|---|---|---|
| CN201611093244.4A Pending CN106633647A (en) | 2016-12-02 | 2016-12-02 | Ionic type flame-retardant anti-static high polymer material |
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Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102070876A (en) * | 2010-12-30 | 2011-05-25 | 桂林电子科技大学 | Epoxy resin base polynary conductive composite material with ultra-low threshold value and preparation method thereof |
| CN103951940A (en) * | 2014-04-10 | 2014-07-30 | 惠州学院 | Antistatic epoxy resin composite material and preparation method thereof |
| CN104744889A (en) * | 2013-12-26 | 2015-07-01 | 青岛东昌源仪器有限公司 | Antistatic electric conduction polymer material |
-
2016
- 2016-12-02 CN CN201611093244.4A patent/CN106633647A/en active Pending
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102070876A (en) * | 2010-12-30 | 2011-05-25 | 桂林电子科技大学 | Epoxy resin base polynary conductive composite material with ultra-low threshold value and preparation method thereof |
| CN104744889A (en) * | 2013-12-26 | 2015-07-01 | 青岛东昌源仪器有限公司 | Antistatic electric conduction polymer material |
| CN103951940A (en) * | 2014-04-10 | 2014-07-30 | 惠州学院 | Antistatic epoxy resin composite material and preparation method thereof |
Non-Patent Citations (1)
| Title |
|---|
| 《电工材料应用手册》编委会编: "《电工材料应用手册》", 31 March 1999, 机械工业出版社 * |
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