CN106633589A - Thermoplastic-elastomer sole patch material and manufacturing method thereof - Google Patents
Thermoplastic-elastomer sole patch material and manufacturing method thereof Download PDFInfo
- Publication number
- CN106633589A CN106633589A CN201611263128.2A CN201611263128A CN106633589A CN 106633589 A CN106633589 A CN 106633589A CN 201611263128 A CN201611263128 A CN 201611263128A CN 106633589 A CN106633589 A CN 106633589A
- Authority
- CN
- China
- Prior art keywords
- elastic body
- shoe bottom
- thermoplastic elastic
- oil
- paster material
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
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Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L53/00—Compositions of block copolymers containing at least one sequence of a polymer obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers
- C08L53/02—Compositions of block copolymers containing at least one sequence of a polymer obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers of vinyl-aromatic monomers and conjugated dienes
-
- A—HUMAN NECESSITIES
- A43—FOOTWEAR
- A43B—CHARACTERISTIC FEATURES OF FOOTWEAR; PARTS OF FOOTWEAR
- A43B13/00—Soles; Sole-and-heel integral units
- A43B13/02—Soles; Sole-and-heel integral units characterised by the material
- A43B13/04—Plastics, rubber or vulcanised fibre
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L91/00—Compositions of oils, fats or waxes; Compositions of derivatives thereof
- C08L91/06—Waxes
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/08—Stabilised against heat, light or radiation or oxydation
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/02—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
- C08L2205/025—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group containing two or more polymers of the same hierarchy C08L, and differing only in parameters such as density, comonomer content, molecular weight, structure
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
Abstract
The invention provides a thermoplastic-elastomer sole patch material, which is characterized by being prepared from the following substances in percentages by mass: 33 to 67 percent of styrene elastomer, 7 to 36 percent of processing oil, 5 to 39 percent of plastic, 1 to 9 percent of filler, 0 to 1 percent of antioxidant, 0 to 1 percent of silicone and 0 to 1 percent of other aid. The thermoplastic-elastomer sole patch material provided by the invention is novel in material and excellent in performance, has excellent performance of recyclability, simple processing procedure, no toxicity, favorable wear resistance and slip resistance, wide hardness range, light weight, conformable hand feeling, and the like, and is deeply favored by a client.
Description
Technical field
The present invention relates to sole paster material field, in particular it relates to a kind of thermoplastic elastic body shoe bottom paster material and
Its manufacture method.
Background technology
At present, the sole paster material on market mostly be natural rubber (NR), butadiene-styrene rubber (SBR), butadiene rubber (BR),
The materials such as polyurethane (TPU).
It is well known that natural rubber (NR) needs Jing sulfidization moldings, manufacturing procedure is complicated, high energy consumption, the rubber that Jing vulcanized
It is not recyclable, not environmentally, it is not light；
Butadiene-styrene rubber (SBR) needs Jing sulfidization moldings, and manufacturing procedure is complicated, high energy consumption, the rubber that Jing vulcanized is recyclable,
Not environmentally, it is not light；
Butadiene rubber (BR) then needs Jing sulfidization moldings, and manufacturing procedure is complicated, and high energy consumption is not recyclable and it is necessary to it
He is used in combination glue kind；
And the material facile hydrolysis such as polyurethane (TPU), poor flexibility, resistance to ag(e)ing is poor, and hardness range is narrow, and proportion is high, usability
Also it is restricted.
As can be seen here, the rubber for being manufactured using above-mentioned material is present, manufacturing procedure and auxiliary material is more, process is complicated
The Cost Problems for causing, the environmental pressure problem that recoverable is not caused, sex chromosome mosaicism comfortable and easy to wear caused by product is heavy, with
And aging speed is fast, the various problems such as hardness is high, anti-slip effect is poor.
For the problems referred to above, in traditional technique, often adopt a large amount of antioxidants of addition or sole is embossed
Solve etc. mode, on the one hand considerably increase cost, the problems such as on the other hand will also result in appearance poor.
The content of the invention
There are various technical barriers to solve above-mentioned conventional soles paster material, in the present invention there is provided a kind of new
Thermoplastic elastic body shoe bottom paster material, to meet market sole paster material it is simple and environmentally-friendly for processing technology it is recyclable,
Light weight, wearability are good, on-slip is good, hardness is moderate, the performance requirement that ageing-resistant performance is good.
The invention provides a kind of thermoplastic elastic body shoe bottom paster material, it is characterised in that by following mass percent
Material be prepared from：
Further, a kind of thermoplastic elastic body shoe bottom paster material that the present invention is provided, it is also special with such technology
Point：I.e., one or more of above-mentioned styrenic elastomer in linear SBS.
The styrenic elastomer is preferably the low molecule styrenic elastomer that molecular weight is not more than 120,000.
Further, a kind of thermoplastic elastic body shoe bottom paster material that the present invention is provided, it is also special with such technology
Point：I.e., one or more of above-mentioned processing oil in base oil, white oil, naphthenic oil, rubber oil, paraffin oil, aromatic naphtha.
Preferably good with low molecule styrenic elastomer compatibility solvent, especially such as：White oil.
Further, a kind of thermoplastic elastic body shoe bottom paster material that the present invention is provided, it is also special with such technology
Point：I.e., one or more of above-mentioned plastics in polystyrene plastics.
Further, a kind of thermoplastic elastic body shoe bottom paster material that the present invention is provided, it is also special with such technology
Point：I.e., above-mentioned filler is in carbon black, silica, titanium dioxide, talcum powder, calcium carbonate, the barium sulfate of 600-1000 mesh
One or more.
Further, a kind of thermoplastic elastic body shoe bottom paster material that the present invention is provided, it is also special with such technology
Point：I.e., above-mentioned antioxidant is the mixture of main anti-oxidant and secondary antioxidant.
The antioxidant may be selected from hydroquinone type, phosphite ester, organosulfur compound, paraffin, dibutyl dithio ammonia
Base formates, 6,6- ethyoxyl -2,2,4-3 methyl isophthalic acids, 2- EEDQs, replace hydroquinones, p-phenylenediamine class,
Secondary amine class, phenols, phosphite ester, mantoquita, triazines etc..
Further, a kind of thermoplastic elastic body shoe bottom paster material that the present invention is provided, it is also special with such technology
Point：I.e., one or more of above-mentioned other auxiliary agents in dispersant, stabilizer, anti-wear agent etc..
Further, a kind of thermoplastic elastic body shoe bottom paster material that the present invention is provided, it is also special with such technology
Point：I.e., it is prepared from by the material of following mass percent：
Wherein, other compositions are made up of main anti-oxidant, secondary antioxidants, silicone material, dispersant；
Above-mentioned main anti-oxidant, secondary antioxidants, silicone material, the mass ratio of dispersant are 1：0.1-10：0.1-10：
0.1-10。
In addition, present invention also offers a kind of manufacture method of above-mentioned thermoplastic elastic body shoe bottom paster material, its feature
It is to be manufactured by the way of extruding pelletization, concrete technology step is as follows：
Step one, styrenic elastomer low speed oil suction；I.e., by styrenic elastomer and processing oil in stirring at low speed
Under the conditions of mix.
Step 2, standing oil suction；The time of the standing determines by the characteristic of product, generally 0.5-36 hours, such as：
Using processing oil and elastomer compatibility performance it is good in the case of, it is only necessary to the Standing operation of 0.5-2 hours.
Step 3, other components are mixed into；The process that this is mixed into can mix for substep, or disposable mixing.
Step 4, extruding pelletization.The general process that step 4 is carried out using twin-screw extruder granulator.
Further, the manufacture method of above-mentioned a kind of thermoplastic elastic body shoe bottom paster material that the present invention is provided, also has
The characteristics of having such：I.e., its moulding process adopts the technique of injection mo(u)lding, and barrel is as follows in the temperature in each stage：
The effect of the present invention and effect：
The novel thermoplastic elastomer sole paster material that the present invention is provided, it is auxiliary based on styrenic elastomer SBS
With materials such as a small amount of plastics, processing oil, antioxidant, anti-wear agents, with different ratio, physical blending is formed, the Part able to be adhered to sole
Compared with traditional sole paster material, material is novel, excellent performance for sheet material, with recoverable, manufacturing procedure it is simple,
The excellent performance such as nontoxic, good wearability and antiskid property, hardness range wide, light weight, comfortable feel, no matter from production or
All more hold out broad prospects for the angle for using.
Find in the research of the present invention, the most excellent material for manufacturing sole paster of SBS systems, at present, on market
The use of more styrenic elastomer is SEBS and SBS, although SEBS heat-resistant agings are well many compared with SBS, is unable to brush coating
Viscose glue, and relatively costly, and SBS it is with low cost while, wear-resisting with good low temperature resistant, warping strength gas permeability and moisture-resistant
Slip, easy processing shaping, without the need for sulfuration, energy consumption is low, easy coloring, the features such as leftover pieces can be recycled.
It is different due to molecular weight for for SBS, the performances such as its mobility, oil absorption can be affected.Based on the present invention
Manufacturing characteristics and properties of product on consider, find in the present invention, the linear SBS of low-molecular-weight, performance is optimal, such as：SBS-
188, such SBS shaping easier to process, non-skid property is good, can also meet while meeting product performance client to non-skid property,
Requirement in comfort level, hardness, weight.
Considering based on material compatibility, the product optimal in order to obtain performance, processing oil should select with formula its
Its material compatibility is best, modest viscosity, the oils that heat aging property is optimum.Find in the research of the present invention, in vain
Oil due to cycloalkane that it is saturation and the mixture of alkane, the characteristics of based in its structure, when by such compound input
Find after system, while excellent compatibility can be played to other components, further function as raising mobility and improve processability
Effect.
Additionally, finding in the research of the present invention, in the selection of plastics, PS has high fluidity, and easy mold release keeps good
The characteristic of physical property well and mechanical strength, compares the plastics such as PE, PP, and based on its design feature, the polarity of such compound is high, also
The characteristics of quick viscose being realized and improves processing characteristics.
Additionally, find in the research of the present invention, it is reachable in the formula of body series from the filler of 600-1000 mesh
While reinforcement, the effect of reduction contraction, cost can be also further reduced and controlled.
Additionally, find in the research of the present invention, it is anti-oxidant by being specifically designed the micro master of addition in formula design
Agent A.O and two grades of antioxidant A.O carry out collocation and use, and can meet this kind of specialities of sole paster and non-oxidizability is wanted
Ask.
Additionally, finding in the research of the present invention, by adding micro anti-wear agent silicone slicone, one can also be entered
Step improves the wear-resisting requirement of sole simultaneously, there is provided the property such as anti-oxidant.
Additionally, in the present invention, by performances such as the physical property of compound material, mechanical strength, antiskid property, wearability, surfaces,
This is finally established with being used for final formula, the product obtained under the formula scheme, more lightweight, profit again can be reclaimed
With the moderate characteristic of wear-resisting on-slip, hardness.
Specific embodiment
Embodiment one, sole paster material 1#
Sole paster material 1# is prepared from by the material of following quality：
| Raw material | Proportioning |
| SBS-188 | 40kg |
| Oil-150N | 30kg |
| PS-143E | 24kg |
| LM800 | 5kg |
| PS800 | 100g |
| B225 | 400g |
| MBTS | 400g |
| SY580 | 100g |
The physical property of sole paster material 1#：
The moulding process of sole paster material 1#：Injection mo(u)lding
The machined parameters of sole paster material 1#：
Embodiment two, sole paster material 2#
Sole paster material 2# is prepared from by the material of following quality：
| Raw material | Proportioning |
| SBS-188 | 60kg |
| Oil-150N | 27kg |
| PS-143E | 10kg |
| LM800 | 3kg |
| PS800 | 100g |
| B225 | 10g |
| MBTS | 100g |
| SY580 | 100g |
The moulding process of sole paster material 2#：Injection mo(u)lding
The machined parameters of sole paster material 2#：
Embodiment three, sole paster material 3#
Sole paster material 3# is prepared from by the material of following quality：
| Raw material | Proportioning |
| SBS-188 | 30kg |
| SBS-1401 | 25kg |
| Oil-150N | 10kg |
| PS-143E | 30kg |
| LM1000 | 2kg |
| PS800 | 100g |
| B225 | 1kg |
| EBS | 10g |
| HY-100A | 100g |
The moulding process of sole paster material 3#：Injection mo(u)lding
The machined parameters of sole paster material 3#：
Example IV, sole paster material 4#
Sole paster material 4# is prepared from by the material of following quality：
| Raw material | Proportioning |
| IICT 3028214 | 33kg |
| Oil-150N | 36kg |
| PS-143E | 17kg |
| LM1000 | 10kg |
| T501 | 1kg |
| 1010 | 1kg |
| EBS | 1kg |
| WFP36 | 1kg |
The moulding process of sole paster material 4#：Injection mo(u)lding
The machined parameters of sole paster material 4#：
Embodiment five, sole paster material 5#
Sole paster material 5# is prepared from by the material of following quality：
| Raw material | Proportioning |
| KRATON D1101 | 70kg |
| Base oil | 36kg |
| PS-476 | 17kg |
| LM600 | 20kg |
| 1076 | 50kg |
| PS802FL | 300kg |
| EBS | 100g |
| WFP36 | 250g |
The moulding process of sole paster material 5#：Injection mo(u)lding
The machined parameters of sole paster material 5#：
Claims (10)
1. a kind of thermoplastic elastic body shoe bottom paster material, it is characterised in that be prepared from by the material of following mass percent：
2. a kind of thermoplastic elastic body shoe bottom paster material as claimed in claim 1, it is characterised in that：
One or more of the styrenic elastomer in linear SBS.
3. a kind of thermoplastic elastic body shoe bottom paster material as claimed in claim 1, it is characterised in that：
One or more of the processing oil in base oil, white oil, naphthenic oil, rubber oil, paraffin oil, aromatic naphtha.
4. a kind of thermoplastic elastic body shoe bottom paster material as claimed in claim 1, it is characterised in that：
One or more of the plastics in polystyrene plastics.
5. a kind of thermoplastic elastic body shoe bottom paster material as claimed in claim 1, it is characterised in that：
Described filler is selected from carbon black, silica, titanium dioxide, talcum powder, calcium carbonate, the barium sulfate of 600-1000 mesh
Plant or several.
6. a kind of thermoplastic elastic body shoe bottom paster material as claimed in claim 1, it is characterised in that：
The antioxidant is the mixture of main anti-oxidant and secondary antioxidant.
7. a kind of thermoplastic elastic body shoe bottom paster material as claimed in claim 1, it is characterised in that：
One or more of described other auxiliary agents in dispersant, stabilizer, anti-wear agent.
8. a kind of thermoplastic elastic body shoe bottom paster material as claimed in claim 1, it is characterised in that by following quality percentage
The material of ratio is prepared from：
Wherein, other compositions are made up of main anti-oxidant, secondary antioxidants, silicone material, dispersant；
The main anti-oxidant, secondary antioxidants, silicone material, the mass ratio of dispersant are 1：0.1-10：0.1-10：0.1-
10。
9. a kind of manufacture method of the thermoplastic elastic body shoe bottom paster material as described in claim 1-8 is arbitrary, its feature exists
In, being manufactured by the way of extruding pelletization, concrete technology step is as follows：
Step one, styrenic elastomer low speed oil suction；
Step 2, standing oil suction；
Step 3, other components are mixed into；
Step 4, extruding pelletization.
10. the manufacture method of a kind of thermoplastic elastic body shoe bottom paster material as claimed in claim 9, it is characterised in that：
Its moulding process adopts the technique of injection mo(u)lding, and barrel is as follows in the temperature in each stage：
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201611263128.2A CN106633589A (en) | 2016-12-30 | 2016-12-30 | Thermoplastic-elastomer sole patch material and manufacturing method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201611263128.2A CN106633589A (en) | 2016-12-30 | 2016-12-30 | Thermoplastic-elastomer sole patch material and manufacturing method thereof |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN106633589A true CN106633589A (en) | 2017-05-10 |
Family
ID=58837774
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201611263128.2A Pending CN106633589A (en) | 2016-12-30 | 2016-12-30 | Thermoplastic-elastomer sole patch material and manufacturing method thereof |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN106633589A (en) |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN109206827A (en) * | 2017-07-05 | 2019-01-15 | 奇美实业股份有限公司 | Resin composition and use thereof |
| CN112011144A (en) * | 2020-09-08 | 2020-12-01 | 惠州市元塑高分子材料有限公司 | Wire rod coating material and preparation method and application thereof |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH0543769A (en) * | 1991-08-08 | 1993-02-23 | Oouchi Shinko Kagaku Kogyo Kk | Thermoplastic elastomer composition |
| CN1454928A (en) * | 2003-05-14 | 2003-11-12 | 阳范文 | Ultrahigh wear-resistant thermoplastic elastomer material for shoe-sole |
| CN1724589A (en) * | 2005-06-17 | 2006-01-25 | 闫俊龙 | Thermoplastic elastomer and its production method |
| CN101845195A (en) * | 2010-05-07 | 2010-09-29 | 浙江俊尔新材料有限公司 | Wear-resistant thermoplastic elastomer and preparation method thereof |
-
2016
- 2016-12-30 CN CN201611263128.2A patent/CN106633589A/en active Pending
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH0543769A (en) * | 1991-08-08 | 1993-02-23 | Oouchi Shinko Kagaku Kogyo Kk | Thermoplastic elastomer composition |
| CN1454928A (en) * | 2003-05-14 | 2003-11-12 | 阳范文 | Ultrahigh wear-resistant thermoplastic elastomer material for shoe-sole |
| CN1724589A (en) * | 2005-06-17 | 2006-01-25 | 闫俊龙 | Thermoplastic elastomer and its production method |
| CN101845195A (en) * | 2010-05-07 | 2010-09-29 | 浙江俊尔新材料有限公司 | Wear-resistant thermoplastic elastomer and preparation method thereof |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN109206827A (en) * | 2017-07-05 | 2019-01-15 | 奇美实业股份有限公司 | Resin composition and use thereof |
| CN109206827B (en) * | 2017-07-05 | 2021-08-24 | 奇美实业股份有限公司 | Resin composition and use thereof |
| CN112011144A (en) * | 2020-09-08 | 2020-12-01 | 惠州市元塑高分子材料有限公司 | Wire rod coating material and preparation method and application thereof |
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Application publication date: 20170510 |