CN106631698B - A kind of method of hyperpure isopropyl alcohol deodorization - Google Patents

A kind of method of hyperpure isopropyl alcohol deodorization Download PDF

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Publication number
CN106631698B
CN106631698B CN201611271223.7A CN201611271223A CN106631698B CN 106631698 B CN106631698 B CN 106631698B CN 201611271223 A CN201611271223 A CN 201611271223A CN 106631698 B CN106631698 B CN 106631698B
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isopropanol
isopropyl alcohol
organic matter
preferential
thoroughly
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CN106631698A (en
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丁晓斌
杜运平
南江普
王成
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Jiangsu jiumo Hi Tech Co., Ltd
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Nanjing Jiusi High Technology Co Ltd
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    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C29/00Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring
    • C07C29/74Separation; Purification; Use of additives, e.g. for stabilisation
    • C07C29/76Separation; Purification; Use of additives, e.g. for stabilisation by physical treatment

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  • Separation Using Semi-Permeable Membranes (AREA)

Abstract

The invention discloses a kind of methods of hyperpure isopropyl alcohol deodorization, comprising the following steps: (1) hyperpure isopropyl alcohol is sent into preferential organic matter film separator thoroughly;(2) it is vacuumized in the per-meate side of preferential organic matter film separator thoroughly, isopropanol, which selectively penetrates through preferential organic matter film separator thoroughly and vaporizes, becomes IPA vapor;(3) isopropanol penetrating fluid is obtained after condensing IPA vapor, isopropanol penetrating fluid is odorless isopropanol.The present invention is simple and effective, easy to operate, seek to fill that the deodorization demand for the isopropanol that market is 99.80% or more to purity, and this method is not only avoided using organic solvent or other third party's substances, realize green extraction process, effective list easy to operate, low energy consumption, safety and environmental protection, reduces cost while improving deodorizing effect.

Description

A kind of method of hyperpure isopropyl alcohol deodorization
Technical field
The present invention relates to a kind of methods of hyperpure isopropyl alcohol deodorization.
Background technique
Isopropanol is a kind of important industrial chemicals and organic solvent, and purposes is very extensive, is mainly used for pharmacy, makeup Product, plastics, fragrance, coating, surfactant, cleaning agent etc..Isopropanol also serves as the solvent of oil product and colloid, and is used for fish In the manufacture of powder feed concentrate.It is to be contained in the food such as water fruits and vegetables, dairy products and drinks since isopropanol has special fragrance One of natural component in product.In American-European countries using it for the products such as cold drink and candy reproduce fragrance and add use. Japan has formulated the standard that isopropanol is utilized as fragrance for 2004, and specifying isopropanol is food fragrance.It at present can be according to most Whole purposes supplies the isopropanol of different qualities, and the regular quality of anhydrous isopropyl alcohol is 99% or more, and private-use class isopropanol content In 99.8% or more (for essence and drug).For producing acetone, diisopropyl ether, isopropyl acetate and thymol etc..
The main method of production isopropanol is propylene hydration method both at home and abroad, according to whether generating intermediate products, it can divide again For two methods of propylene indirect hydration method and propylene direct hydration method.
Indirect hydration method, which exists, consumes that sulfuric acid amount is big, and equipment seriously corroded, the disadvantages of energy consumption is high limit its development System, the technology have been eliminated.
Direct hydration method is a kind of catalyst using high activity, and the new technology being adapted with environmental protection.The method gram The shortcomings that having taken indirect hydration method has many advantages, such as efficient, low consumption, short flow, is the Main way of current hydration development.Slightly After aqueous isopropanol alkali process, is refined through de- ether tower, azeotrope column, dehydrating tower, light, heavies column, just obtain high-purity isopropyl Alcohol.
Even if there are still make us uncomfortable stink however, up to 99.99% isopropanol currently on the market, it is generally recognized that It may be from the impurity such as sulfide, ether, aldehyde.Therefore, domestic and international one period is deodorized isopropanol, concentrates on sulfide removal such as sulphur In the research of alcohol.It is removed using PbO-NaOH, ZnO-NaOH and NaOH solution extracting removal mercaptan, or using CuX molecular sieve Mercaptan finally uses activated carbon adsorption.These methods can be reduced to mercaptans content 1ppm or so, but not remove at all so far different The stink of propyl alcohol.Even if sulfur content drops to ppb grades, still so.
Therefore, the method for the isopropanol deodorization carried out at present, focuses primarily upon extractive distillation process, using amberlite The material absorbings such as rouge, active carbon, activated aluminum and sand, there are many deficiencies for these methods, such as complicated for operation, and energy consumption is high, absorption Agent is not easy to regenerate, processing cost is higher, and there are secondary pollutions etc..
Summary of the invention
The object of the present invention is to provide a kind of methods of hyperpure isopropyl alcohol deodorization, suitable for the de- of hyperpure isopropyl alcohol stink It removes, which simplify the requirements of Processes and apparatus, and for hyperpure isopropyl alcohol, deodorising effect is good, and low energy consumption, and deodorising process will not Bring secondary pollution.
To achieve the above object, the technical solution adopted in the present invention is as follows:
A kind of method of hyperpure isopropyl alcohol deodorization, comprising the following steps:
(1) hyperpure isopropyl alcohol is sent into preferential organic matter film separator thoroughly;
(2) it is vacuumized in the per-meate side of the preferential organic matter film separator thoroughly, isopropanol selectively permeates logical Crossing the preferential organic matter film separator thoroughly and vaporizing becomes IPA vapor;
(3) isopropanol penetrating fluid will be obtained after IPA vapor condensation, the isopropanol penetrating fluid is odorless isopropyl Alcohol.
Preferably, the hyperpure isopropyl alcohol is the mixture that isopropanol content is greater than 99.80%.
Preferably, the preferential organic matter film thoroughly includes preferential saturating organic matter film, and the preferential organic matter film thoroughly is that have The preferential particular functionality film for penetrating isopropanol.
Further, the material of the preferential organic matter film thoroughly includes organosilicon polymer, fluoropolymer, poly- amino first Acid esters, Noryl, polyether amide block copolymer, cellulose acetate, hydrophobic nano-titanium dioxide, inorganic type molecular sieve or One or more of inorganic ceramic is combined.
Further, the organosilicon polymer includes but is not limited to dimethyl silicone polymer, poly- trimethyl silicane propine, gathers Vinyl trimethylsilane, two silicon of polyvinyl dimethylsilane, polymethylacrylic acid trimethyl silane methyl esters and poly- hexamethyl One of oxygen alkane is a variety of.
Further, the fluoropolymer includes but is not limited to that polytetrafluoroethylene (PTFE), Kynoar, polyhexafluoropropylene are poly- One of propylene, polysulfonate fluorovinyl ether and teflon-copolymers are a variety of.
Preferably, in the step (1), the hyperpure isopropyl alcohol is pumped into the preferential organic matter film point thoroughly by charging From device, and the absolute pressure range of the feed pump is 200~500kPa.
Preferably, in the step (1), the gauge pressure of the preferential organic matter film separator feed side thoroughly is 0~ 0.6MPa, feeding temperature are 20~60 DEG C, and crossflow velocity is 0.08~2m/s.Preferably, described preferential in the step (2) The per-meate side of saturating organic matter film separator is vacuumized by vacuum pump, and the vacuum degree of per-meate side is 1000~10000Pa.
Preferably, the odorless isopropanol obtained in the step (3) is molten to can be used as the use of food level isopropanol, does not pass through institute The seepage remaining liquid for stating preferential organic matter film separator thoroughly can be used as industrial level isopropanol and use.
A kind of method of hyperpure isopropyl alcohol deodorization proposed by the present invention, creatively uses preferential saturating organic matter film, due to Preferential organic matter film thoroughly is to the difference of different material absorption selective penetrated property, and the preferential organic matter film specific aim in the present invention Ground is using the particular functionality film for preferentially penetrating isopropanol.After the preferential processing of organic matter film thoroughly, in hyperpure isopropyl alcohol raw material Isopropanol is through preferential organic matter film thoroughly and is enriched in the form of a vapor in the per-meate side of film, obtains after condenser condenses Penetrating fluid, penetrating fluid can be used for the works such as food, essence, drug through stink organoleptic analysis without any stink for odorless isopropanol Industry field;And the seepage remaining liquid being trapped, for the isopropanol comprising substances such as water, sulfide, carbonyl classes, this kind of isopropanol can be used for Other insensitive industry are required stink.
The beneficial effects of the present invention are:
1. the present invention carries out the deodorization of hyperpure isopropyl alcohol, and preferential saturating organic matter by preferential organic matter film separator thoroughly Membrane separation device is used with preferentially through the particular functionality film of isopropanol, which can effectively remove the smelly of hyperpure isopropyl alcohol Taste, obtained odorless aqueous isopropanol, meets the requirement that food level isopropanol is odorless in the market;
2. the present invention uses novel membrane separation technique, not only avoid using organic solvent or other third party's substances, it is real Green extraction process is showed, effective list easy to operate, low energy consumption, and safety and environmental protection reduces into while improving deodorizing effect This.
Detailed description of the invention
Fig. 1 is a kind of process flow chart of the method for hyperpure isopropyl alcohol deodorization in the present invention;
Wherein: 1: head tank, 2: feed pump, 3: preferential organic matter film separator thoroughly, 4: condenser, 5: vacuum pump, A: Hyperpure isopropyl alcohol raw material, B: seepage remaining liquid, C: isopropanol penetrating fluid.
Specific embodiment
Below in conjunction with specific embodiment, the invention will be further described.
Embodiment 1
A kind of equipment of hyperpure isopropyl alcohol deodorization, including sequentially connected head tank 1, feed pump 2, preferential saturating organic matter film Separator 3, condenser 4 and vacuum pump 5, preferential organic matter film separator thoroughly include membrane module, and membrane module by single or Multiple preferential organic matter film unit series, parallel thoroughly or mixed connection composition.Membrane module includes preferential saturating organic matter film, preferential thoroughly organic Object film is with the preferential particular functionality film for penetrating isopropanol.Specifically, the material of preferential organic matter film thoroughly includes organosilicon It is polymer, fluoropolymer, polyurethanes, Noryl, polyether amide block copolymer, cellulose acetate, hydrophobic One or more of nano-titanium dioxide, inorganic type molecular sieve or inorganic ceramic are combined.Wherein, organosilicon polymer packet Include but be not limited to dimethyl silicone polymer, poly- trimethyl silicane propine, polyvinyl trimethyl silane, polyvinyl dimethyl-silicon One of alkane, polymethylacrylic acid trimethyl silane methyl esters and poly- hexamethyldisiloxane are a variety of.Fluoropolymer includes But it is total to be not limited to polytetrafluoroethylene (PTFE), Kynoar, polyhexafluoropropylene polypropylene, polysulfonate fluorovinyl ether and polytetrafluoroethylene (PTFE) One of polymers is a variety of.
Preferential organic matter film thoroughly uses ceramics/organosilicon polymer composite membrane in the present embodiment, specific to select nine to think company The tubular ceramic of production/dimethyl silicone polymer composite membrane.
A kind of method of hyperpure isopropyl alcohol deodorization, specific as follows:
Firstly, hyperpure isopropyl alcohol A is sent into preferential organic matter film separator 3 thoroughly.
The hyperpure isopropyl alcohol A that isopropanol content in head tank 1 is 99.850% is sent into through feed pump 2 preferential thoroughly organic Object membrane separation device 3,2 absolute pressure of feed pump are 200kPa, and preferential organic matter film separator feed side gauge pressure thoroughly is 0MPa, operation Temperature is 20 DEG C, crossflow velocity 0.08m/s.Preferential organic matter film thoroughly is with the preferential particular functionality for penetrating isopropanol Film selects the nine tubular ceramic/dimethyl silicone polymer composite membranes for thinking company's production, uses aperture for 20nm Al2O3Ceramic filtering Film is basement membrane, is prepared by the dimethyl silicone polymer being modified by mineral crystal for cortical material.
Then, it is vacuumized in the per-meate side of preferential organic matter film separator 3 thoroughly, isopropanol selectively penetrates through Preferential organic matter film separator 3 thoroughly is simultaneously vaporized as IPA vapor.
The per-meate side of membrane separation device is equipped with vacuum pump 5, opens vacuum pump and vacuumizes, vacuum degree 1000Pa, isopropanol Selectively infiltration evaporation becomes vapor permeable through film.
Finally, obtaining isopropanol penetrating fluid C after IPA vapor is condensed, isopropanol penetrating fluid C is odorless isopropanol.
Vapor permeable obtains penetrating fluid C after the condensation of condenser 4, does not obtain seepage remaining liquid B in retentate side through the liquid of film. Penetrating fluid C is odorless isopropanol, can be used for the industrial circles such as food, essence, drug;And the seepage remaining liquid being trapped, for comprising water, The isopropanol of the substances such as sulfide, carbonyl class, this kind of isopropanol can be used for other industry insensitive to stink requirement.By reason Change analysis and stink organoleptic analysis, specific experiment testing result is shown in Table 1.
Table 1
Embodiment 2
The equipment of the deodorization of hyperpure isopropyl alcohol used by the present embodiment is similar with equipment employed in embodiment 1.And this Preferential organic matter film employed in embodiment is that organosilicon polymer-fluoropolymer-hydrophobic nano-titanium dioxide is compound Film, organosilicon polymer are specially dimethyl silicone polymer, and fluoropolymer is specially polytetrafluoroethylene (PTFE).
The method of the deodorization of hyperpure isopropyl alcohol used by the present embodiment is similar to Example 1, specific as follows:
The hyperpure isopropyl alcohol A that isopropanol content in head tank 1 is 99.850% is sent into through feed pump 2 preferential thoroughly organic Object membrane separation device 3,2 absolute pressure of feed pump are 500kPa.Preferential organic matter film separator feed side gauge pressure thoroughly is 0.6MPa, behaviour Making temperature is 30 DEG C, crossflow velocity 0.5m/s.Preferential organic matter film thoroughly is with the preferential particular functionality for penetrating isopropanol Film selects dimethyl silicone polymer-polytetrafluoroethylene (PTFE)-hydrophobic nano-titanium dioxide composite membrane.The per-meate side of membrane separation device is set There is vacuum pump 5, opens vacuum pump and vacuumize, vacuum degree 10000Pa, selectively infiltration evaporation becomes isopropanol through film Vapor permeable, vapor permeable obtain penetrating fluid C after the condensation of condenser 4, do not obtain seepage remaining liquid in retentate side through the liquid of film B.Penetrating fluid C is odorless isopropanol, can be used for the industrial circles such as food, essence, drug;And the seepage remaining liquid being trapped, for comprising The isopropanol of the substances such as water, sulfide, carbonyl class, this kind of isopropanol can be used for other industry insensitive to stink requirement.Through Physico-chemical analysis and stink organoleptic analysis are crossed, specific experiment testing result is shown in Table 2.
Table 2
Embodiment 3
The equipment of the deodorization of hyperpure isopropyl alcohol used by the present embodiment is similar with equipment employed in embodiment 1.And this Preferential organic matter film employed in embodiment is that dimethyl silicone polymer-polyether amide block copolymer-inorganic ceramic is multiple Close film.
The method of the deodorization of hyperpure isopropyl alcohol used by the present embodiment is similar to Example 1, specific as follows:
The hyperpure isopropyl alcohol A that isopropanol content in head tank 1 is 99.900% is sent into through feed pump 2 preferential thoroughly organic Object membrane separation device 3,2 absolute pressure of feed pump are 400kPa, and preferential organic matter film separator feed side gauge pressure thoroughly is 0.1MPa, behaviour Making temperature is 60 DEG C, crossflow velocity 2m/s.Preferential organic matter film thoroughly is that have the preferential particular functionality film for penetrating isopropanol, Select dimethyl silicone polymer-polyether amide block copolymer-inorganic ceramic composite membrane.The per-meate side of membrane separation device is equipped with true Sky pump 5 is opened vacuum pump and is vacuumized, vacuum degree 5000Pa, and selectively infiltration evaporation penetrates film as infiltration to isopropanol Steam, vapor permeable obtain penetrating fluid C after the condensation of condenser 4, do not obtain seepage remaining liquid B in retentate side through the liquid of film.It seeps Transparent liquid C is odorless isopropanol, can be used for the industrial circles such as food, essence, drug;And the seepage remaining liquid being trapped, to include water, sulphur The isopropanol of the substances such as compound, carbonyl class, this kind of isopropanol can be used for other industry insensitive to stink requirement.By physics and chemistry Analysis and stink organoleptic analysis, specific experiment testing result are shown in Table 3.
Table 3
Embodiment 4
The equipment of the deodorization of hyperpure isopropyl alcohol used by the present embodiment is similar with equipment employed in embodiment 1.And this Preferential organic matter film employed in embodiment is modified dimethyl silicone polymer-Noryl-inorganic type molecular sieve Composite membrane.
The method of the deodorization of hyperpure isopropyl alcohol used by the present embodiment is similar to Example 1, specific as follows:
The hyperpure isopropyl alcohol A that isopropanol content in head tank 1 is 99.980% is sent into through feed pump 2 preferential thoroughly organic Object membrane separation device 3,2 absolute pressure of feed pump are 300kPa, and preferential organic matter film separator feed side gauge pressure thoroughly is 0.2MPa, behaviour Making temperature is 50 DEG C, crossflow velocity 1.5m/s.Preferential organic matter film thoroughly is with the preferential particular functionality for penetrating isopropanol Film selects modified dimethyl silicone polymer-Noryl-inorganic type Zeolite composite film.The per-meate side of membrane separation device Equipped with vacuum pump 5, open vacuum pump and vacuumize, vacuum degree 4000Pa, isopropanol selectively infiltration evaporation through film at For vapor permeable, vapor permeable obtains penetrating fluid C after the condensation of condenser 4, does not obtain more than infiltration through the liquid of film in retentate side Liquid B.Penetrating fluid C is odorless isopropanol, can be used for the industrial circles such as food, essence, drug;And the seepage remaining liquid being trapped, for packet The isopropanol of the substances such as aqueous, sulfide, carbonyl class, this kind of isopropanol can be used for other industry insensitive to stink requirement. By physico-chemical analysis and stink organoleptic analysis, specific experiment testing result is shown in Table 4.
Table 4
Certainly the above embodiments merely illustrate the technical concept and features of the present invention, and its object is to allow be familiar with technique People can understand the content of the present invention and implement it accordingly, it is not intended to limit the scope of the present invention.It is all according to this hair The equivalent transformation or modification that the Spirit Essence of bright main technical schemes is done, should be covered by the protection scope of the present invention.

Claims (8)

1. a kind of method of hyperpure isopropyl alcohol deodorization, it is characterised in that: itself the following steps are included:
(1) hyperpure isopropyl alcohol is sent into preferential organic matter film separator thoroughly;
(2) it is vacuumized in the per-meate side of the preferential organic matter film separator thoroughly, isopropanol selectively penetrates through institute Stating preferential organic matter film separator thoroughly and vaporizing becomes IPA vapor;The preferential organic matter film separator thoroughly includes excellent First saturating organic matter film, the preferential organic matter film thoroughly is with the preferential particular functionality film for penetrating isopropanol;
(3) isopropanol penetrating fluid will be obtained after IPA vapor condensation, the isopropanol penetrating fluid is odorless isopropanol;
The hyperpure isopropyl alcohol is the mixture that isopropanol content is greater than 99.80%.
2. a kind of method of hyperpure isopropyl alcohol deodorization according to claim 1, it is characterised in that: the preferential saturating organic matter The material of film includes organosilicon polymer, fluoropolymer, polyurethanes, Noryl, polyether amide block copolymerization One or more of object, cellulose acetate, hydrophobic nano-titanium dioxide, inorganic type molecular sieve or inorganic ceramic are combined.
3. a kind of method of hyperpure isopropyl alcohol deodorization according to claim 2, it is characterised in that: the organosilicon polymer Including dimethyl silicone polymer, poly- trimethyl silicane propine, polyvinyl trimethyl silane, polyvinyl dimethylsilane, poly- first One of base acrylic acid trimethylsilyl methyl esters and poly- hexamethyldisiloxane are a variety of.
4. a kind of method of hyperpure isopropyl alcohol deodorization according to claim 2, it is characterised in that: the fluoropolymer packet It includes in polytetrafluoroethylene (PTFE), Kynoar, polyhexafluoropropylene polypropylene, polysulfonate fluorovinyl ether and teflon-copolymers It is one or more.
5. a kind of method of hyperpure isopropyl alcohol deodorization according to claim 1, it is characterised in that: in the step (1), institute It states hyperpure isopropyl alcohol and the preferential organic matter film separator thoroughly is pumped by charging, and the absolute pressure range of the feed pump is 200~500kPa.
6. a kind of method of hyperpure isopropyl alcohol deodorization according to claim 1, it is characterised in that: in the step (1), institute The gauge pressure for stating preferential organic matter film separator feed side thoroughly is 0~0.6MPa, and feeding temperature is 20~60 DEG C, and crossflow velocity is 0.08~2m/s.
7. a kind of method of hyperpure isopropyl alcohol deodorization according to claim 1, it is characterised in that: in the step (2), institute The per-meate side for stating preferential organic matter film separator thoroughly is vacuumized by vacuum pump, and the vacuum degree of per-meate side be 1000~ 10000Pa。
8. a kind of method of hyperpure isopropyl alcohol deodorization according to claim 1, it is characterised in that: obtained in the step (3) The odorless isopropanol obtained can be used as the use of food level isopropanol, not can be used as industrial level isopropanol through the seepage remaining liquid of film and uses.
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CN102159528A (en) * 2008-09-19 2011-08-17 日挥株式会社 Method for producing alcohol, method for producing hydrogen or synthetic gas using method for producing alcohol, and alcohol

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* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102159528A (en) * 2008-09-19 2011-08-17 日挥株式会社 Method for producing alcohol, method for producing hydrogen or synthetic gas using method for producing alcohol, and alcohol

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