CN106630674A - Glass with self-cleaning, ultraviolet ray resisting and sound-proofing functions and preparation method of same - Google Patents
Glass with self-cleaning, ultraviolet ray resisting and sound-proofing functions and preparation method of same Download PDFInfo
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- CN106630674A CN106630674A CN201610880314.4A CN201610880314A CN106630674A CN 106630674 A CN106630674 A CN 106630674A CN 201610880314 A CN201610880314 A CN 201610880314A CN 106630674 A CN106630674 A CN 106630674A
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- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C17/00—Surface treatment of glass, not in the form of fibres or filaments, by coating
- C03C17/34—Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions
- C03C17/3411—Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions with at least two coatings of inorganic materials
- C03C17/3417—Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions with at least two coatings of inorganic materials all coatings being oxide coatings
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- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C27/00—Joining pieces of glass to pieces of other inorganic material; Joining glass to glass other than by fusing
- C03C27/06—Joining glass to glass by processes other than fusing
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- Engineering & Computer Science (AREA)
- Life Sciences & Earth Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Geochemistry & Mineralogy (AREA)
- Materials Engineering (AREA)
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- Ceramic Engineering (AREA)
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Abstract
The invention provides glass with self-cleaning, ultraviolet ray resisting and sound-proofing functions and a preparation method of the same. The glass comprises a vacuum sound-proofing layer, transparent baseplates, ultraviolet ray resisting thin film layers and self-cleaning thin film layers, the ultraviolet ray resisting thin film layers and the self-cleaning thin film layers are distributed on the transparent baseplates, and the ultraviolet ray resisting thin film layers are positioned between the glass and the self-cleaning thin film layers respectively. The glass is capable of absorbing light rays at wavelength of 100-350nm by more than 90%, and thereby being capable of preventing ultraviolet rays from injuring skins and causing cancers and achieving a function of air purification. The self-cleaning layers on the surfaces of the glass are ultra-hydrophilic, so that the trouble of cleaning the surfaces of the glass is reduced. The sound-proofing layers have a certain function of proofing various kinds of noises, so that a quite indoor environment can be provided.
Description
【Technical field】
The present invention relates to film application, and in particular to one kind have self-cleaning function, anti-ultraviolet sound control glass and
Its preparation method.
【Background technology】
If it is well known that people's long-time is exposed to the sun the sun, ultraviolet can make it is accelerated skin ageing, so as to producing wrinkle, producing
Add lustre to spot, cause skin to become coarse or cause some disease of skin, such as dermatitis, cutaneum carcinoma etc..In addition, strong sunshine
According to house is also resulted in and some ornaments in automobile are aging, fade, shorten its use time.But current automobile mostly,
The simple glass general utility functions that use on the window of material storage room, Sea View Room etc. are less, for ultraviolet radiation absorption is not good enough, stain resistance
It is poor, not easy to clean.And soundproof effect is bad, indoor or in-car is easily disturbed by ambient noise.In order to reduce ultraviolet and make an uproar
Sound brings harmful effect to the life of people and body, and seeking has glass of building and automobile window glass strong to absorb purple
Outside line and sound insulation function are requisite.
At present, there are multiple technologies to prepare with the glass for absorbing UV resistance, for example, Chinese publication
CN103613280A discloses a kind of masking liquid and ultraviolet absorbing glass of ultraviolet absorbing coatings, the ultraviolet absorbing glass
Ultraviolet absorbing coatings include SiO2And ultra-violet absorber, the ultraviolet absorbing coatings also include for storing and discharging purple
The oxide M O of electronics is excited in ultraviolet absorbers by ultravioletz, wherein M=V, Mn, Fe, Co, Ni, Zr, Nb, Mo, Ru, Ir,
Rh, Pd, W, Re, Bi, In, Ga, Os；1≤z≤4.This kind of glass can protect ultra-violet absorber and SiO2Matrix, prevents purple
Outside line heat absorbing glass changes colour or devitrification.But the glass does not possess sound insulation and self-cleaning function.
Chinese publication CN103097320A discloses a kind of laminated glass, i.e., add one layer of PVB in the middle of two sheet glass
(polyvinyl butyral resin) film, the interlayer film has the function of absorbing ultraviolet.However, this laminated glass preparation technology is more multiple
It is miscellaneous, improve manufacturing cost.
In addition, Jing retrievals find that the method for being usually used in manufacturing ultraviolet ray screening film-plating glass includes magnetron sputtering, chemical gaseous phase
Sedimentation and sol-gel process.
【The content of the invention】
To solve the problems, such as prior art, the present invention provides a kind of with self-cleaning function, anti-ultraviolet sound insulation glass
Glass and preparation method thereof, the glass is not only strong to ultraviolet absorption ability, realizes anti-ultraviolet function, so as to effectively prevent ultraviolet
Injury and carcinogenicity of the line to skin, and reach the effect of purify air.Additionally, also there is the glass self-cleaning function and sound insulation to imitate
Really, self-cleaning function causes glass easy to clean, mitigates the trouble of cleaning glass；Sound insulation value can be played necessarily noise to external world
Shielding action so that interior feel become soft.The preparation method of the present invention is simple, and film doping ratio is easily adjusted
Section, the film even compact made, hardness is high.Preparation technology parameter is easily controlled, and reproducibility is good.
For achieving the above object, the present invention adopts following technological means：
One kind has self-cleaning function, anti-ultraviolet sound control glass, including：Interior transparency carrier, outer transparency carrier and set
Vacuum sound insulation layer between interior transparency carrier and outer transparency carrier, interior transparency carrier surface sets gradually interior uvioresistant film
Layer and interior self-cleaning function layer, outer transparent substrate surface sets gradually outer uvioresistant film layer and outer self-cleaning function layer；
Inside and outside uvioresistant film layer is mixed with V2O5SiO2Film；
Inside and outside self-cleaning function layer is TiO2Film or nano silver film.
The light-absorbing wavelength of the sound control glass is 100-350nm, and absorption of UV is 90%-95%.
Described inside and outside uvioresistant film layer is SiO2With V2O5Using same chamber, altogether the mode of steaming is deposited with and makes；Wherein SiO2
It is deposited with by electron-beam evaporation mode as material of main part；V2O5It is deposited with by vacuum evaporation mode as guest materials.
Described inside and outside self-cleaning function layer is TiO2It is deposited with using electron beam mode prepared.
Described vacuum sound insulation layer inside is vacuum cavity, and vacuum cavity is to arrange raised by small supporter or surface
Lucite is made, and inside and outside transparency carrier is sealed by encapsulant.
Inside and outside transparency carrier is water soda glass or plastics.
A kind of preparation method with self-cleaning function, anti-ultraviolet sound control glass, comprises the following steps：
1) interior glass substrate is sequentially placed into liquid detergent, acetone, alcohol, deionized water and is cleaned by ultrasonic respectively, after taking-up
Dried with nitrogen；
2) the interior glass substrate dried is proceeded into deposited chamber simultaneously using vacuum evaporation V2O5And electron beam evaporation
SiO2, form SiO2And V2O5The interior uvioresistant film layer of composition, obtains being deposited with the interior glass base of interior uvioresistant film layer
Plate；
3) the interior glass substrate of uvioresistant film layer in evaporation is put into drying baker drying；
4) sheet glass dried is placed into vacuum chamber and TiO is evaporated using electron beam mode2, prepare interior self-cleaning function
Layer；Obtain that there is self-cleaning function, anti-ultraviolet sheet glass；
5) by outer glass substrate successively according to it is above-mentioned 1), 2), 3) and 4) described in method prepare other a piece of tool
There are self-cleaning function, anti-ultraviolet sheet glass；
6) will be arranged between raised lucite support and formation by small supporter or surface between two sheet glass
Gap, after being evacuated in gap, two panels semi-finished product is sealed using encapsulant, is formed and is had self-cleaning function, uvioresistant
Sound control glass.
Step 2) in, V2O5With SiO2Doping content ratio be 3:4；Evaporation pressure is 2.5 × 10-4─5.0×10-4Pa。
Step 3) in, evaporation current is 20-25mA, evaporation pressure is 1.2 × 10-4─2.6×10-4Pa。
The thickness of uvioresistant film layer is 70-100nm；Self-cleaning function thickness degree is 10-20nm；Vacuum sound insulation thickness degree
For 1-1.7mm.
The present invention compared with prior art, with advantages below：
The present invention has self-cleaning function, anti-ultraviolet sound control glass piece, by transparency carrier, vacuum sound insulation layer, uvioresistant
Line film layer and self-cleaning function layer are constituted；The glass includes transparency carrier and distribution uvioresistant film layer, tool thereon
There are the film layer and vacuum sound insulation layer of self-cleaning function, described uvioresistant film layer is located at glass and has self-cleaning function film
Between layer.Transparency carrier can realize that the institute of simple glass is functional；Ground floor uvioresistant film layer is by mixed with V2O5Deng
SiO2Film, or other film layers compositions with absorption ultraviolet function, can in a large number absorb ultraviolet incident light, reduce harmful
The amount of incident of ultraviolet, absorptivity reaches more than 90 percent, effectively shields harmful light, there is stronger protection work(to human body
Energy.Additionally, the second layer film self-cleaning function layer is Superhydrophilic oxide TiO2Film and organic matter can be converted into dioxy
Change the films such as the Nano Silver of carbon and water, not only with protective effect, and with anti-reflection effect, also with certain self-cleaning function,
Antifouling effect significantly, reduces cleaning frequency.The present invention automatically cleaning principle be：For TiO2Film, TiO2In the effect of ultraviolet
Good photocatalysis characteristic can be produced down so as to super hydrophilic characteristic so that the water droplet of very little is converged to large water droplet,
Come off under Action of Gravity Field, so that contamination spot thereon is easily washed away, make glass that there is self-cleaning function.Intermediate layer is
Vacuum sound insulation layer, sound leans on Medium Propagation, and vacuum layer can play effective shielding action by noise to external world, so that interior
Feel to become soft.
The present invention with self-cleaning function, anti-ultraviolet sound control glass, light that can be with absorbing wavelength as 100-350nm
Line, absorptivity is up to more than 90%, so as to effectively prevent injury and carcinogenicity of the ultraviolet to skin.Meanwhile, glass of the present invention
The TiO on surface2Film layer has the self-cleaning function of Superhydrophilic, reduces the trouble of cleaning glass surface.
The preparation method of the present invention is simple, using with chamber, altogether the mode of steaming is deposited with V2O5Deng SiO2Film, then use electron beam side
Formula evaporation metal oxide TiO2.The method doping is convenient, ratio is more easily adjusted, and the film even compact made, hardness is high.
Preparation technology parameter is easily controlled, and reproducibility is good.
【Description of the drawings】
Fig. 1 is that the present invention has self-cleaning function, the generalized section of anti-ultraviolet sound control glass.
Wherein, A1 and A is respectively inside and outside glass substrate, and middle D is vacuum sound insulation layer, and B1 and B is respectively inside and outside uvioresistant
Line film layer, C1 and C are respectively inside and outside self-cleaning function layer.
Fig. 2 is that the variable concentrations of the present invention adulterate on absorbing the analog simulation figure that ultraviolet affects.
【Specific embodiment】
Below in conjunction with the accompanying drawings the present invention is described in detail：
As shown in figure 1, the present invention is a kind of to have self-cleaning function, an anti-ultraviolet sound control glass, including interior transparency carrier A1,
The outer transparency carrier A and vacuum sound insulation layer D between interior transparency carrier and outer transparency carrier, presses close to inside and outside transparency carrier
Distinguishing from inside to outside includes successively uvioresistant film layer B1 and B and self-cleaning function layer C1 and C, and sheet glass is to absorption of UV
Up to 90%-95%.
Transparency carrier A and A1 are simple glass or other transparency carriers with flexibility function；
Uvioresistant film layer B and B1 are mixed with V2O5Deng SiO2Film, or other are with the thin of absorption ultraviolet function
Film layer.SiO2With V2O5Using same chamber, altogether the mode of steaming is deposited with；V2O5It is deposited with by vacuum evaporation mode as guest materials.SiO2Make
It is deposited with by electron-beam evaporation mode for material of main part；
Self-cleaning function layer C and C1 are TiO2Film, and organic matter can be converted into Nano Silver of carbon dioxide and water etc.
Film layer, is deposited with using electron beam mode..
The above-mentioned preparation method with self-cleaning function, anti-ultraviolet sound control glass, comprises the following steps：
1) transparency carrier A is sequentially placed into liquid detergent, acetone, alcohol, deionized water and is cleaned by ultrasonic 10-15min respectively,
Dried with nitrogen after taking-up；
2) cleaned transparency carrier is proceeded into deposited chamber simultaneously using vacuum evaporation V2O5Deng and electron beam evaporation
SiO2, uvioresistant film layer is formed, this film layer is by described oxide S iO2And V2O5Composition；The uvioresistant that altogether evaporation is produced
Line film thickness is 70-100nm.
3) substrate being deposited with is put into drying baker drying；
4) substrate dried is placed into vacuum chamber and TiO is evaporated using electron beam mode2Deng film, electron beam evaporation material
Material TiO2Deng thickness be 10-20nm.Complete the film layer with self-cleaning function；So far, prepare with self-cleaning function, resist
The sheet glass of ultraviolet.
5) by transparency carrier A1 successively according to it is above-mentioned 1), 2), 3) and 4) described in method prepare another tool
There are self-cleaning function, anti-ultraviolet glass.
6) sealed what two panels was prepared using encapsulant with self-cleaning function, anti-ultraviolet glass, centre is logical
It is 1-1.7mm spaces to cross supporter and isolate thickness, and this space is evacuated.
Wherein, used as thin-film carrier, the selection of material is water soda glass or other transparent bases with flexibility to transparency carrier
Plate.The uvioresistant film layer is by mixed with V2O5Deng SiO2Film is constituted.The self-cleaning function layer is located at uvioresistant film
The upper surface of layer, mainly by the oxide TiO containing super hydrophilic characteristic2Film can be converted into carbon dioxide and water organic matter
Other films composition.
TiO2Good photocatalysis characteristic can be produced in the presence of ultraviolet so as to super hydrophilic characteristic so that very
Little water droplet is converged to large water droplet, comes off under gravity, so that contamination spot thereon is easily washed away, makes
Glass has self-cleaning function.
A kind of concrete preparation process with self-cleaning function, anti-ultraviolet sound control glass of the present invention is as follows, now with part
Illustrate as a example by material, be certainly not limited to following material.
Glass substrate A is the water soda glass of high-flatness.Uvioresistant film layer is that deposited chamber is steamed using vacuum simultaneously
Plating V2O5And electron beam evaporation SiO2, film layer V for completing2O5:SiO2.Self-cleaning function layer is Superhydrophilic oxide TiO2It is thin
Film, not only with protective effect, and with anti-reflection effect.It is lucite in the middle of vacuum sound insulation layer, is then with concentration
1%-60% acetone soak lucite, then convex-concave profile is made this layer of lucite by serigraphy, form supporter.
Embodiment 1
It is described as follows with self-cleaning function, anti-ultraviolet glass preparation process：
1st, soda-lime glass is sequentially placed into liquid detergent, acetone, alcohol, deionized water and is cleaned by ultrasonic respectively ten minutes, taken
Dried with nitrogen after going out.
2nd, cleaned glass substrate is proceeded into deposited chamber simultaneously using vacuum evaporation V2O5And electron beam evaporation SiO2,
Ultraviolet film layer is formed, this film layer is by described oxide S iO2And V2O5Composition, film thickness monitoring is 70-100nm, V2O5Doping
Concentration is 10% SiO2, doping content is V2O5:SiO2=3:4, evaporation pressure is 5.0 × 10-4Pa；.
3rd, the sheet glass being deposited with is put into drying baker drying；
4th, the sheet glass dried is placed into vacuum chamber and TiO is evaporated using electron beam mode2, complete with self-cleaning function
Film layer, thickness is 10-20nm, and evaporation current is 20mA, evaporation pressure be 2.6 × 10-4Pa。
So far, prepare with self-cleaning function, anti-ultraviolet sheet glass.
5th, by other one block of soda-lime glass successively according to it is above-mentioned 1), 2), 3) and 4) described in method prepare in addition
One kind has self-cleaning function, anti-ultraviolet glass.
6th, sealed what two panels was prepared using encapsulant with self-cleaning function, anti-ultraviolet glass, centre is logical
It is 1.0mm spaces to cross supporter and isolate thickness, and this space is evacuated.
Embodiment 2
It is described as follows with self-cleaning function, anti-ultraviolet glass preparation process：
1st, soda-lime glass is sequentially placed into liquid detergent, acetone, alcohol, deionized water and is cleaned by ultrasonic respectively 15 minutes, taken
Dried with nitrogen after going out.
2nd, cleaned glass substrate is proceeded into deposited chamber simultaneously using vacuum evaporation V2O5And electron beam evaporation SiO2,
Ultraviolet film layer is formed, this film layer is by described oxide S iO2And V2O5Composition, film thickness monitoring is 80-100nm, V2O5Doping
Concentration is 37.5% SiO2, doping content is V2O5:SiO2=3:4, evaporation pressure is 5.0 × 10-4Pa；.
3rd, the sheet glass being deposited with is put into drying baker drying；
4th, the sheet glass dried is placed into vacuum chamber and TiO is evaporated using electron beam mode2, complete with self-cleaning function
Film layer, thickness is 15-20nm, and evaporation current is 20mA, evaporation pressure be 2.6 × 10-4Pa。
So far, prepare with self-cleaning function, anti-ultraviolet sheet glass.
5th, by other one block of soda-lime glass successively according to it is above-mentioned 1), 2), 3) and 4) described in method prepare in addition
One kind has self-cleaning function, anti-ultraviolet glass.
6th, sealed what two panels was prepared using encapsulant with self-cleaning function, anti-ultraviolet glass, centre is logical
It is 1.5mm spaces to cross supporter and isolate thickness, and this space is evacuated.
Embodiment 3
It is described as follows with self-cleaning function, anti-ultraviolet glass preparation process：
1st, soda-lime glass is sequentially placed into liquid detergent, acetone, alcohol, deionized water and is cleaned by ultrasonic respectively 20 minutes, taken
Dried with nitrogen after going out.
2nd, cleaned glass substrate is proceeded into deposited chamber simultaneously using vacuum evaporation V2O5And electron beam evaporation SiO2,
Ultraviolet film layer is formed, this film layer is by described oxide S iO2And V2O5Composition, thickness is 70-80nm, V2O5Doping content
For 50% SiO2, doping content is V2O5:SiO2=3:4, evaporation pressure is 5.0 × 10-4Pa；.
3rd, the sheet glass being deposited with is put into drying baker drying；
4th, the sheet glass dried is placed into vacuum chamber and TiO is evaporated using electron beam mode2, complete with self-cleaning function
Film layer, thickness is 10-18nm, and evaporation current is 20mA, evaporation pressure be 2.6 × 10-4Pa。
So far, prepare with self-cleaning function, anti-ultraviolet sheet glass.
5th, by other one block of soda-lime glass successively according to it is above-mentioned 1), 2), 3) and 4) described in method prepare in addition
One kind has self-cleaning function, anti-ultraviolet glass.
6th, sealed what two panels was prepared using encapsulant with self-cleaning function, anti-ultraviolet glass, centre is logical
It is 1.7mm spaces to cross supporter and isolate thickness, and this space is evacuated.
As shown in Fig. 2 the different levels of doping of the present invention affects the analog simulation figure for absorbing ultraviolet：
Uvioresistant film layer is by mixed with V2O5SiO2Film is constituted, and we are by changing V2O5Doping content simulation paint
Absorption spectra of the made membrane layer to ultraviolet (100-350nm), by absorption spectra different proportion concentration film is clear that
Absorbing state.As seen from the figure, V on the whole2O5Doping SiO2Film has stronger absorbability to ultraviolet.And for can
See that light (390-780nm) does not then absorb or absorbs less substantially.So can ensure that the present invention with self-cleaning function, anti-purple
Assimilation effect of the glass of outside line to ultraviolet, while not affecting the transmission of visible ray, does not affect the light of interior or in-car.
Each bar curve in relatively Fig. 2, it has been found that pure SiO2Although there is peak-peak to the absorption of ultraviolet at 50nm in film.But
The scope that it absorbs light wave is very narrow, is limited only to the shortwave of 10-100nm scopes.As doping V2O5Afterwards, SiO2The suction of film layer
Receive optical wavelength range to significantly increase, especially work as V2O5When doping content is 37.5% and 50%, the light wave to 40-320nm scopes
There is preferably absorption.It is well known that the medium wave carcinogenicity of wavelength 290-320nm is most strong, turn to red because of sun burn and sunburn effect are other frequencies
1000 times of Duan Guangbo.And V2O5Doping content is 37.5% and 50% SiO2Film layer has preferable assimilation effect to it,
Can effective protection human body skin, prevent even carcinogenic etc. phenomenon of wrinkle of skin caused by ultraviolet, aging, blackspot from occurring.
The present invention with self-cleaning function, anti-ultraviolet sound control glass, the transmitance of required wavelength light can be made
Up to more than 90%, so as to effectively prevent injury and carcinogenicity of the ultraviolet to skin, and reach the effect of purify air.Together
When, the TiO of glass surface of the present invention2Film layer has the self-cleaning function of Superhydrophilic, reduces the trouble of cleaning glass surface.
Puigging can play certain shielding action to all kinds of noises, make interior feel become soft.
One embodiment of the present invention is the foregoing is only, is not all of or unique embodiment, this area is common
Any equivalent conversion that technical staff is taken technical solution of the present invention by reading description of the invention, is the present invention
Claim covered.
Claims (10)
1. it is a kind of that there is self-cleaning function, anti-ultraviolet sound control glass, it is characterised in that to include：Interior transparency carrier (A1), pass through inside
Bright substrate (A) and the vacuum sound insulation layer (D) between interior transparency carrier and outer transparency carrier, interior transparency carrier (A1) surface
Interior uvioresistant film layer (B1) and interior self-cleaning function layer (C1) are set gradually, outer transparency carrier (A) surface sets gradually outer anti-
Ultraviolet film layer (B) and outer self-cleaning function layer (C)；
Inside and outside uvioresistant film layer (B1, B) is mixed with V2O5SiO2Film；
Inside and outside self-cleaning function layer (C1, C) is TiO2Film or nano silver film.
2. the one kind according to right 1 has self-cleaning function, anti-ultraviolet sound control glass, it is characterised in that：The sound insulation glass
The light-absorbing wavelength of glass is 100-350nm, and absorption of UV is 90%-95%.
3. it is according to claim 1 a kind of with self-cleaning function, anti-ultraviolet sound control glass, it is characterised in that described
Inside and outside uvioresistant film layer (B1, B) be SiO2With V2O5Using same chamber, altogether the mode of steaming is deposited with and makes；Wherein SiO2As master
Body material is deposited with by electron-beam evaporation mode；V2O5It is deposited with by vacuum evaporation mode as guest materials.
4. it is according to claim 1 a kind of with self-cleaning function, anti-ultraviolet sound control glass, it is characterised in that described
Inside and outside self-cleaning function layer (C1, C) be TiO2It is deposited with using electron beam mode prepared.
5. it is according to claim 1 a kind of with self-cleaning function, anti-ultraviolet sound control glass, it is characterised in that described
Vacuum sound insulation layer (D) inside be vacuum cavity, vacuum cavity is to arrange raised lucite by small supporter or surface
Make, inside and outside transparency carrier (A1, A) is sealed by encapsulant.
6. it is according to claim 1 a kind of with self-cleaning function, anti-ultraviolet sound control glass, it is characterised in that inside and outside
Transparency carrier (A1, A) is water soda glass or plastics.
7. a kind of preparation with self-cleaning function, anti-ultraviolet sound control glass according to claim 1 to 6 any one
Method, it is characterised in that comprise the following steps：
1) interior glass substrate (A1) is sequentially placed into liquid detergent, acetone, alcohol, deionized water and is cleaned by ultrasonic respectively, after taking-up
Dried with nitrogen；
2) the interior glass substrate (A1) dried is proceeded into deposited chamber simultaneously using vacuum evaporation V2O5And electron beam evaporation
SiO2, formed by SiO2And V2O5The interior uvioresistant film layer (B1) of composition, obtains being deposited with interior uvioresistant film layer (B1)
Interior glass substrate (A1)；
3) the interior glass substrate (A1) of uvioresistant film layer (B1) in evaporation is put into drying baker drying；
4) sheet glass dried is placed into vacuum chamber and TiO is evaporated using electron beam mode2, prepare interior self-cleaning function layer (C1)；
Obtain that there is self-cleaning function, anti-ultraviolet sheet glass；
5) by outer glass substrate (A) successively according to above-mentioned 1), 2), 3) and 4) described in method prepare and in addition a piece of have
Self-cleaning function, anti-ultraviolet sheet glass；
6) raised lucite will be arranged by small supporter or surface between two sheet glass and supports and formed gap, will
After being evacuated in gap, two panels semi-finished product are sealed using encapsulant, formed and there is self-cleaning function, anti-ultraviolet sound insulation
Glass.
8. a kind of preparation method with self-cleaning function, anti-ultraviolet sound control glass according to claim 7, its feature
It is, step 2) in, V2O5Doping content is 10～50% SiO2, V2O5With SiO2Doping content ratio be 3:4；Evaporation pressure
For 2.5 × 10-4─5.0×10-4Pa。
9. a kind of preparation method with self-cleaning function, anti-ultraviolet sound control glass according to claim 7, its feature
It is, step 3) in, evaporation current is 20-25mA, evaporation pressure is 1.2 × 10-4─2.6×10-4Pa。
10. a kind of preparation method with self-cleaning function, anti-ultraviolet sound control glass according to claim 7, it is special
Levy and be, the thickness of uvioresistant film layer is 70-100nm；The thickness of self-cleaning function layer is 10-20nm；Vacuum sound insulation layer
Thickness is 1-1.7mm.
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| CN201610880314.4A CN106630674B (en) | 2016-10-09 | 2016-10-09 | One kind having self-cleaning function, anti-ultraviolet sound control glass and preparation method thereof |
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| CN201610880314.4A CN106630674B (en) | 2016-10-09 | 2016-10-09 | One kind having self-cleaning function, anti-ultraviolet sound control glass and preparation method thereof |
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| CN106630674B CN106630674B (en) | 2019-05-24 |
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Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN110433671A (en) * | 2019-07-23 | 2019-11-12 | 江苏大学 | A kind of preparation method and its usage of visible light-inducing automatically cleaning carbon-fiber film |
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Cited By (2)
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| CN110433671A (en) * | 2019-07-23 | 2019-11-12 | 江苏大学 | A kind of preparation method and its usage of visible light-inducing automatically cleaning carbon-fiber film |
| CN110433671B (en) * | 2019-07-23 | 2021-09-10 | 江苏大学 | Preparation method and application of visible light induced self-cleaning carbon fiber film |
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