CN106630525A - Biological carbon ozonization reaction system - Google Patents

Biological carbon ozonization reaction system Download PDF

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Publication number
CN106630525A
CN106630525A CN201710134816.7A CN201710134816A CN106630525A CN 106630525 A CN106630525 A CN 106630525A CN 201710134816 A CN201710134816 A CN 201710134816A CN 106630525 A CN106630525 A CN 106630525A
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CN
China
Prior art keywords
ozone
charcoal
air
shower nozzle
outlet
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Withdrawn
Application number
CN201710134816.7A
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Chinese (zh)
Inventor
祝凤娟
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Individual
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Individual
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Priority to CN201710134816.7A priority Critical patent/CN106630525A/en
Publication of CN106630525A publication Critical patent/CN106630525A/en
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    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F11/00Treatment of sludge; Devices therefor
    • C02F11/06Treatment of sludge; Devices therefor by oxidation
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F2101/00Nature of the contaminant
    • C02F2101/30Organic compounds
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F2201/00Apparatus for treatment of water, waste water or sewage
    • C02F2201/78Details relating to ozone treatment devices
    • C02F2201/782Ozone generators
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F2209/00Controlling or monitoring parameters in water treatment
    • C02F2209/02Temperature
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F2303/00Specific treatment goals
    • C02F2303/04Disinfection

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  • Life Sciences & Earth Sciences (AREA)
  • Hydrology & Water Resources (AREA)
  • Engineering & Computer Science (AREA)
  • Environmental & Geological Engineering (AREA)
  • Water Supply & Treatment (AREA)
  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Treating Waste Gases (AREA)
  • Treatment Of Sludge (AREA)

Abstract

The invention relates to the field of environmental protection, in particular to a biological carbon ozonization reaction system. The biological carbon ozonization reaction system comprises a reactor housing and an air pump, wherein the air pump is communicated with an ozone generator; an outlet of the ozone generator is communicated with an ozone air pipeline; a multihole metal plate is arranged in the reactor housing; the multihole metal plate divides a cavity inside the reactor housing into an oxidization reaction cavity at the top and an ozone air cavity at the bottom; the ozone air pipeline penetrates through the reactor housing and is communicated with the ozone air cavity; a sludge and biological carbon mixing feeding device penetrates through the reactor housing and is communicated with the oxidization reaction cavity; an ozonized biological carbon discharging opening is formed in the oxidization reaction cavity. The biological carbon ozonization reaction system kills germs through ozone under conditions of high moisture content of sludge and extremely high organic matter concentration, so as to prevent mass propagation which may cause pipeline blocking; the reaction success rate can be increased, and water vapors and ozone are compounded to quickly degrade pollutants in the organic matter sludge.

Description

A kind of charcoal ozonization system
Technical field
The present invention relates to field of environment protection, more particularly to a kind of charcoal ozonization system.
Background technology
During the entire process of crude oil collection and processing, the on-site soil in oil field is produced out with crude oil from stratum Come, polluted by crude oil, substantial amounts of Organic substance is contained in sludge and many suspended solids are carried, and in the oil reservoir of High Temperature High Pressure Various salts and the gas in stratum is dissolved, has made Oilfield Soils composition more complicated, and added during crude oil transmission Various chemical agents also increase soil contamination grade.It is continuous strict with mud discharging standard, chemistry in sludge is needed The emission request more and more higher of the materials such as oxygen amount (COD), nitrogen, phosphorus, in industrial sludge the removal of COD (COD) with Denitrogenation dephosphorizing faces enormous challenge.Traditional processing mode often increases the expense and energy consumption of capital expenditure, and run compared with For complexity.
Charcoal ozonization device and its sludge treatment technique are a kind of high-efficiency appliances and technique of Treatment of Sludge.Its Few with volumetric loading, required capital expenditure, treatment effeciency is high, and operation energy consumption is low, the characteristics of operating cost is few.
But also there are problems in charcoal ozonization device of the prior art:Due to sludge moisture content height, In the case where organic concentration is too high, antibacterial amount reproduction can be caused, block pipeline, it is easy to cause reaction failure, so as to Affect treatment effect;And, charcoal ozonization device containing pollutant in hardly degraded organic substance sludge to going decapacitation Power is limited, and the problem is the principal element for restricting the development of charcoal ozonization device technique.
The content of the invention
In order to solve the above problems, it is an object of the invention to provide a kind of charcoal ozonization system.The system It is high in sludge moisture content, in the case where organic concentration is too high, antibacterial is killed by ozone, prevent its amount reproduction from causing to block up Plug pipeline, it is possible to increase reaction success rate, in combination with pollutant in vapor and the rapid degradation of organic substances sludge of ozone.
For achieving the above object, the present invention is employed the following technical solutions:
A kind of charcoal ozonization system, including reactor shell and air pump, the air pump connects an ozone to be occurred Device, the ozone generator outlet connects an ozone-air pipeline, and an expanded metal is provided with inside reactor shell, described Reactor shell internal cavity is separated into expanded metal the oxidation reaction chamber at top and the ozone-air chamber of bottom, described smelly Oxygen air line is connected through the reactor shell with ozone-air chamber, and a sludge organism charcoal mixed material feeding device is through reaction Device housing is connected with oxidation reaction chamber, and oxidation reaction chamber is provided with an ozonisation charcoal floss hole, and oxidation reaction connects at the top of chamber A logical tail gas exhaust apparatus, a flexible exhaust gas recirculation pipe is respectively communicated with tail gas exhaust apparatus and air pump, the flexible tail gas Recirculation pipe is provided with filter near tail gas exhaust apparatus one end, and near air pump one end check valve is provided with, oxidation reaction chamber Top is provided with the water injector with thermoinduction mechanism, and in the bottom in ozone-air chamber outlet valve is provided with, and the sludge organism charcoal is mixed Closing charging device includes metal cylinder, and the upper end of metal cylinder is provided with feed hopper, defecator is arranged between feed hopper and metal cylinder, Hot-air blower is provided with the inwall of feed hopper, transfer roller, transfer roller and a motor connection are installed in the inside of metal cylinder, on transfer roller Heater is installed, metal cylinder top offers steam vent, bottom and is provided with mudhole, and the lower end of transfer roller is provided with die head, die head Top is connected with cooling water inlet pipe, bottom and is connected with cooling water outlet pipe.
Wherein, the water injector also include water inlet pipe, shower nozzle, outlet and inlet valve, the shower nozzle be connected to into On water pipe, the outlet is located on shower nozzle, and the valve is arranged on water inlet pipe;The thermoinduction mechanism is located on shower nozzle, It is connected and controls the keying of inlet valve with the inlet valve signal of telecommunication.
Wherein, the shower nozzle can be around water inlet pipe in 360 ° of rotations.
Wherein, the shower nozzle is spheroid or cone.
Wherein, the thermoinduction mechanism is located at the top of shower nozzle upper water-out mouth.
Wherein, the outlet top is provided with dismountable filter screen.
The present invention has the advantages that:
1st, the present invention is high in sludge moisture content, in the case where organic concentration is too high, by ozone antibacterial is killed, and prevents its big Amount breeding results in blockage pipeline, improves reaction success rate.
2nd, the present invention combines vapor and ozone is stronger to the removal ability containing pollutant in hardly degraded organic substance sludge.
3rd, the process tail gas that present invention flexibility exhaust gas recirculation pipe recycling tail gas exhaust apparatus is collected, energy-conserving and environment-protective, More preferably result can be realized especially by multiple operation circulations.
4th, the shower nozzle of water injector of the invention can be around water inlet pipe in 360 ° of rotations, it is possible to which the scope of sensing is more Greatly, sludge organism carbon mixture can uniformly be sprayed.
5th, the thermoinduction mechanism of water injector of the invention is located at the top of shower nozzle upper water-out mouth, it is to avoid damage thermoinduction machine Structure.
6th, the outlet of water injector of the invention is additionally provided with dismountable filter screen, if the water of water inlet pipe is not clean, will Outlet is blocked, and filter screen can be taken off into cleaning.
Description of the drawings
Fig. 1 is a kind of structural representation of charcoal ozonization system of the present invention;
Fig. 2 is the structural representation of the sludge organism charcoal mixed material feeding device of the present invention;
Fig. 3 is the structural representation of the water injector of the present invention.
Description of reference numerals:
101- air pumps, 102- ozonators, 103- ozone-airs chamber, 104- expanded metals, 105- reactor shells, 106- outlet valves, 107- oxidation reactions chamber, 108- sludge organism charcoal mixed material feeding devices, 109- ozonisation charcoal floss holes, 110- tail gas exhaust apparatus, 111- flexibility exhaust gas recirculation pipes, 112- filters, 113- check valves, 114- water injectors, 116- Ozone-air pipeline, 201- water inlet pipes, 202- shower nozzles, 203- outlets, 204- thermoinductions mechanism, 205- inlet valves, 206- Filter screen, 301- metal cylinders, 302- feed hoppers, 303- motors, 304- hot-air blowers, 305- defecators, 306- transfer rollers, 307- add Hot device, 308- steam vents, 309- mudholes, 310- die heads, 311- cooling water inlet pipes, 312- cooling water outlet pipes.
Specific embodiment
The present invention is described in further details below in conjunction with the drawings and specific embodiments:
As shown in figure 1, a kind of charcoal ozonization system, including reactor shell 105 and air pump 101, the air Pump 101 connects an ozonator 102, the ozone-air pipeline 116 of 102 outlet of the ozonator one, in reactor An expanded metal 104 is provided with inside housing 105, the expanded metal 104 is separated into the internal cavity of reactor shell 105 The oxidation reaction chamber 107 at top and the ozone-air chamber 103 of bottom, the ozone-air pipeline 116 passes through the reactor enclosure Body 105 is connected with ozone-air chamber 103, and a sludge organism charcoal mixed material feeding device 108 is anti-with oxidation through reactor shell 105 Chamber 107 is answered to connect, oxidation reaction chamber 107 is provided with an ozonisation charcoal floss hole 109, the top connection in oxidation reaction chamber 107 One tail gas exhaust apparatus 110, a flexible exhaust gas recirculation pipe 111 is respectively communicated with tail gas exhaust apparatus 110 and air pump 101, institute State flexible exhaust gas recirculation pipe 111 and be provided with filter 112 near the one end of tail gas exhaust apparatus 110, set near the one end of air pump 101 The top for having check valve 113, oxidation reaction chamber 107 is provided with the water injector 114 with thermoinduction mechanism 204, in ozone-air chamber 103 bottom is provided with outlet valve 106, as shown in Fig. 2 the sludge organism charcoal mixed material feeding device 108 includes metal cylinder 301, The upper end of metal cylinder 301 is provided with feed hopper 302, and defecator 305, feed hopper are arranged between feed hopper 302 and metal cylinder 301 Hot-air blower 304 is provided with 302 inwall, transfer roller 306, the motor 303 of transfer roller 306 and are installed in the inside of metal cylinder 301 Connection, installs heater 307 on transfer roller 306, the top of metal cylinder 301 offers steam vent 308, bottom and is provided with mudhole 309, The lower end of transfer roller 306 is provided with die head 310, and the top of die head 310 is connected with cooling water inlet pipe 311, bottom and is connected with cooling Water outlet pipe 312.Preferably, as shown in figure 3, the water injector 114 includes water inlet pipe 201, shower nozzle 202, the and of outlet 203 Inlet valve 205, the shower nozzle 202 is connected on water inlet pipe 201, and the outlet 203 is located on shower nozzle 202, the valve 205 are arranged on water inlet pipe 201;The thermoinduction mechanism 204 is located on shower nozzle 202, is connected simultaneously with the signal of telecommunication of inlet valve 205 The keying of control inlet valve 205.
Preferably, the shower nozzle 202 can be around water inlet pipe 201 in 360 ° of rotations, due to 204, the thermoinduction mechanism On shower nozzle 202, the shower nozzle 202 around water inlet pipe 201 rotate when, the scope that can be sensed is bigger.The shower nozzle 202 is spheroid Or cone.The thermoinduction mechanism 204 is located at the top of the upper water-out mouth of shower nozzle 202, it is to avoid heat is damaged during 203 leak of outlet Induction mechanism 204.The outlet 203 is additionally provided with dismountable filter screen 206, if the water of water inlet pipe 201 is not clean, by water outlet Mouth 203 is blocked, and filter screen 206 can be taken off into cleaning.
The operation principle of the charcoal ozonization system of the present invention is as follows:
Sludge mixed biologic charcoal is put in reactor shell 105 by sludge organism charcoal mixed material feeding device 108 in proportion;It is dirty When mud charcoal mixed material feeding device 108 works, put into by feed hopper 302 after sludge is mixed with charcoal granule, feed hopper Hot-air blower 304 is provided with 302, drying charging can be played a part of, it is to avoid moist sludge mixed biologic charcoal granule is entered and led Cause inefficiency, the filter sludge mixed biologic charcoal granule of defecator 305 to adsorb metal debris, it is to avoid injury device, filter Sludge mixed biologic charcoal granule afterwards is entered inside metal cylinder 301, and transfer roller 306 drives sludge mixed biologic charcoal granule to transport forward OK, having heaters 307 is arranged on live-roller 306 makes sludge mixed biologic charcoal granule heat up, and makes the volatilizable thing contained in sludge Rapid evaporation, Electromagnetic Heating heats up very fast, and the top of metal cylinder 301 offers steam vent 308, bottom and offers mudhole 309, conveniently discharge the sewage stayed when the steam that is collected in metal cylinder and cleaning, transfer roller 306 is by sludge mixed biologic charcoal Granule is sent to die head 310, and is clamp-oned in reactor shell 105 by die head 310, arranges cooling water in the top of die head 310 and enters Water pipe 311, lower section arranges cooling water outlet pipe 312, improves the rate of cooling of die head 310, it is to avoid discharging sticks the feelings on die head 310 Condition, improve product quality;Then monitor and adjust charcoal temperature;While charcoal of the adjustment in reactor shell 105 Water content and relative humidity, according to required charcoal water content and relative humidity, the control inlet valve of thermoinduction mechanism 204 205 open, and the suitably water spray of shower nozzle 202 is to oxidation reaction chamber 107, and/or is introduced in ozone-air chamber 103 by outlet valve 106 Water vapour;The ozone that the pumping of air pump 101 is generated by ozonator 102 is in reactor shell 105;Ozone gas pass through The expanded metal 104 of the top of ozone-air chamber 103 enters oxidation reaction chamber 107, while can be by controlling the wind of air pump 101 Fan speed delivery of ozone gas;The outlet valve 106 in the bottom of ozone-air chamber 103 can also be utilized in addition, introduce other gases Component processes charcoal ozonation in reactor shell 105;At the same time it can also using flexible exhaust gas recirculation pipe 111 Recycle the process tail gas that tail gas exhaust apparatus 110 is collected;According to the temperature of charcoal in reactor shell 105 and containing ozone Air flow set time enough make ozone and charcoal particle interaction, obtained by ozonisation charcoal floss hole 109 The soil of environmental protection and public nuisance free, by multiple operation circulations more preferably result can be realized.
The specific embodiment of the present invention is the foregoing is only, the scope of the claims of the present invention, every profit is not thereby limited The equivalent structure transformation made with description of the invention and accompanying drawing content, or directly or indirectly it is used in other related technology necks Domain, is included within the scope of the present invention.

Claims (6)

1. a kind of charcoal ozonization system, it is characterised in that:Including reactor shell(105)And air pump(101), institute State air pump(101)Connect an ozonator(102), the ozonator(102)The ozone-air pipeline of outlet one (116), in reactor shell(105)Inside is provided with an expanded metal(104), the expanded metal(104)By reactor Housing(105)Internal cavity is separated into the oxidation reaction chamber at top(107)With the ozone-air chamber of bottom(103), the ozone Air line(116)Through the reactor shell(105)With ozone-air chamber(103)Connection, sludge organism charcoal mixing is thrown Material device(108)Through reactor shell(105)With oxidation reaction chamber(107)Connection, oxidation reaction chamber(107)It is provided with an ozone Change charcoal floss hole(109), oxidation reaction chamber(107)Top connect a tail gas exhaust apparatus(110), a flexible tail gas is again Circulation pipe(111)It is respectively communicated with tail gas exhaust apparatus(110)And air pump(101), the flexible exhaust gas recirculation pipe(111)Lean on Nearly tail gas exhaust apparatus(110)One end is provided with filter(112), near air pump(101)One end is provided with check valve(113), oxygen Change reaction chamber(107)Top be provided with band thermoinduction mechanism(204)Water injector(114), in ozone-air chamber(103)Bottom Portion is provided with outlet valve(106), the sludge organism charcoal mixed material feeding device(108)Including metal cylinder(301), metal cylinder(301) Upper end be provided with feed hopper(302), feed hopper(302)With metal cylinder(301)Between defecator is set(305), feed hopper (302)Inwall on be provided with hot-air blower(304), metal cylinder(301)Inside install transfer roller(306), transfer roller(306)With One motor(303)Connection, transfer roller(306)Upper installation heater(307), metal cylinder(301)Top offers steam vent (308), bottom be provided with mudhole(309), transfer roller(306)Lower end die head is installed(310), die head(310)Top connects There is cooling water inlet pipe(311), bottom be connected with cooling water outlet pipe(312).
2. charcoal ozonization system as claimed in claim 1, it is characterised in that:The water injector(114)Also wrap Include water inlet pipe(201), shower nozzle(202), outlet(203)And inlet valve(205), the shower nozzle(202)It is connected to water inlet pipe (201)On, the outlet(203)Positioned at shower nozzle(202)On, the valve(205)It is arranged on water inlet pipe(201)On;It is described Thermoinduction mechanism(204)Positioned at shower nozzle(202)On, with inlet valve(205)The signal of telecommunication connects and controls inlet valve(205)'s Open and close.
3. charcoal ozonization system as claimed in claim 2, it is characterised in that:The shower nozzle(202)Can be around Water inlet pipe(201)In 360 ° of rotations.
4. charcoal ozonization system as claimed in claim 3, it is characterised in that:The shower nozzle(202)For spheroid or Cone.
5. charcoal ozonization system as claimed in claim 4, it is characterised in that:The thermoinduction mechanism(204)Position In shower nozzle(202)The top of upper water-out mouth.
6. charcoal ozonization system as claimed in claim 5, it is characterised in that:The outlet(203)Top sets There is dismountable filter screen(206).
CN201710134816.7A 2017-03-08 2017-03-08 Biological carbon ozonization reaction system Withdrawn CN106630525A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201710134816.7A CN106630525A (en) 2017-03-08 2017-03-08 Biological carbon ozonization reaction system

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Application Number Priority Date Filing Date Title
CN201710134816.7A CN106630525A (en) 2017-03-08 2017-03-08 Biological carbon ozonization reaction system

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Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20150144564A1 (en) * 2013-11-25 2015-05-28 University Of Idaho Biochar water treatment
CN104924483A (en) * 2015-06-26 2015-09-23 天津辉达斯高分子环保材料有限公司 Modified plastic granulator
US20170036983A1 (en) * 2015-08-06 2017-02-09 James Weifu Lee Ozonized biochar compositions and methods of making and using the same
CN206570182U (en) * 2017-03-08 2017-10-20 祝凤娟 A kind of charcoal ozonization system

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20150144564A1 (en) * 2013-11-25 2015-05-28 University Of Idaho Biochar water treatment
CN104924483A (en) * 2015-06-26 2015-09-23 天津辉达斯高分子环保材料有限公司 Modified plastic granulator
US20170036983A1 (en) * 2015-08-06 2017-02-09 James Weifu Lee Ozonized biochar compositions and methods of making and using the same
CN206570182U (en) * 2017-03-08 2017-10-20 祝凤娟 A kind of charcoal ozonization system

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Application publication date: 20170510

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