CN106629950A - Silicon-free antifoaming agent specially used for waste water processing, and preparation method thereof - Google Patents
Silicon-free antifoaming agent specially used for waste water processing, and preparation method thereof Download PDFInfo
- Publication number
- CN106629950A CN106629950A CN201611225221.4A CN201611225221A CN106629950A CN 106629950 A CN106629950 A CN 106629950A CN 201611225221 A CN201611225221 A CN 201611225221A CN 106629950 A CN106629950 A CN 106629950A
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- CN
- China
- Prior art keywords
- silicon
- waste water
- antifoaming agent
- fatty alcohol
- free
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- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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Classifications
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- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F1/00—Treatment of water, waste water, or sewage
- C02F1/20—Treatment of water, waste water, or sewage by degassing, i.e. liberation of dissolved gases
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- Life Sciences & Earth Sciences (AREA)
- Hydrology & Water Resources (AREA)
- Engineering & Computer Science (AREA)
- Environmental & Geological Engineering (AREA)
- Water Supply & Treatment (AREA)
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Degasification And Air Bubble Elimination (AREA)
Abstract
The invention discloses a silicon-free antifoaming agent specially used for waste water processing, and a preparation method thereof. The silicon-free antifoaming agent specially used for waste water processing comprises, by weight, 5 to 20% of a fatty alcohol, 1 to 3% of fatty acid monoglyceride, 3 to 6% of a high aliphatic alcohol polyether, 60 to 70% of white oil, 15 to 35% of emulsifier S-60, 1 to 3% of lauryl sodium sulfate, 1 to 3% of white carbon black, and 2 to 5% of aluminium oxide, wherein the carbon atom number of the fatty alcohol ranges from 3 to 10, and the molecular weight of the high aliphatic alcohol polyether ranges from 5000 to 10000. The silicon-free antifoaming agent is capable of defoaming quickly, is low in using amount, possesses excellent thermal resistance, acid and alkali resistance, polyelectrolyte resistance, high shear resistance; the basic characteristics of foaming systems are not influenced by the silicon-free antifoaming agent; and the silicon-free antifoaming agent is capable of solving a problem that demulsification is easily caused when common antifoaming agents are added into polyelectrolyte, strong acid, strong base, and high shear systems.
Description
Technical field
The present invention relates to defoamer field, more particularly to one kind is without the special defoamer of silicon waste water process and its preparation side
Method.
Background technology
Use chemical assistant in a large number in the water treatment procedures such as industrial production, domestic water, wherein these auxiliary agents are with surface
Based on activating agent, the technique end of water process can all produce substantial amounts of foam, these materials be all based on macromolecular compound,
The foam that they are formed in water enhances bubble film strength because of intermolecular absorption problem so that froth breaking becomes difficult, and
Traditional organic silicon defoamer consumption is big, affects the fundamental property of the system of foaming, resistance to heat differential to have adverse side effect, therefore existing
There is defoamer performance to be improved;
Therefore, prior art has yet to be improved and developed.
The content of the invention
In view of above-mentioned the deficiencies in the prior art, it is an object of the invention to provide one kind is without the special froth breaking of silicon waste water process
Agent, it is intended to solve the problems, such as that prior art defoamer performance is to be improved.
It is a kind of to process special defoamer without silicon waste water, wherein:By weight percentage, including:
Fatty alcohol 5-20%;
Glyceryl stearate fat acid fat 1-3%;
Higher aliphatic polyethers 3-6%;
White oil 60-70%;
Emulsifying agent S-60 15-35%;
Lauryl sodium sulfate 1-3%;
White carbon 1-3%;
Aluminum oxide 2-5%.
Between 3-10, the molecular weight of higher aliphatic polyethers is between 5000-10000 for the wherein carbon atom of fatty alcohol.
A kind of preparation method without the special defoamer of silicon waste water process, wherein:Sequentially add fatty alcohol, the acid of glyceryl stearate fat
Fat, higher aliphatic polyethers, white oil, emulsifying agent S-60, lauryl sodium sulfate, white carbon, 30-60 point of aluminum oxide stirring
Clock is obtained without the special defoamer of silicon waste water process.Emulsifying agent S-60 is wherein added to be gradually added in batches.
The present invention's can be in industrial production, domestic water, consumption fast with froth breaking without the special defoamer of silicon waste water process
It is little, the fundamental property of the system of foaming is not affected, heat-resisting good, acid and alkali-resistance, resistance to polyelectrolyte, resistance to high shear, the present invention are solved
The defect of general common froth breaking agent emulsion easy breakdown of emulsion failure in polyelectrolyte, strong acid, highly basic, high shear system.The suds time
It is long, efficiency high, and it is nontoxic, corrosion-free, without adverse side effect.Low COD, low consumption amount, environmental protection.
Specific embodiment
The present invention provides a kind of without special defoamer of silicon waste water process and preparation method thereof, to make the purpose of the present invention, skill
Art scheme and effect are clearer, clear and definite, and below the present invention is described in more detail.It should be appreciated that tool described herein
Body embodiment only to explain the present invention, is not intended to limit the present invention.
Embodiment 1:
It is a kind of to process special defoamer without silicon waste water, by weight percentage, including:
Fatty alcohol 15%;
Glyceryl stearate fat acid fat 2%;
Higher aliphatic polyethers 4%;
White oil 60%;
Emulsifying agent S-60 15%;
Lauryl sodium sulfate 1%;
White carbon 1%;
Aluminum oxide 2%.
Wherein the carbon atom of fatty alcohol is 8, and the molecular weight of higher aliphatic polyethers is 8000.
Present invention also offers without the preparation method of the special defoamer of silicon waste water process described in embodiment 1, it is specific as follows:According to
It is secondary addition fatty alcohol, glyceryl stearate fat acid fat, higher aliphatic polyethers, white oil, emulsifying agent S-60, lauryl sodium sulfate, white
Carbon black, aluminum oxide are stirred and are obtained within 30 minutes without the special defoamer of silicon waste water process.
Embodiment 2:
It is a kind of to process special defoamer without silicon waste water, by weight percentage, including:
Fatty alcohol 12%;
Glyceryl stearate fat acid fat 2%;
Higher aliphatic polyethers 4%;
White oil 63%;
Emulsifying agent S-60 15%;
Lauryl sodium sulfate 1%;
White carbon 1%;
Aluminum oxide 2%.
Wherein the carbon atom of fatty alcohol is 7, and the molecular weight of higher aliphatic polyethers is 7500.
Present invention also offers without the preparation method of the special defoamer of silicon waste water process described in embodiment 2, it is specific as follows:According to
It is secondary addition fatty alcohol, glyceryl stearate fat acid fat, higher aliphatic polyethers, white oil, emulsifying agent S-60, lauryl sodium sulfate,
White carbon, aluminum oxide are stirred and are obtained within 60 minutes without the special defoamer of silicon waste water process.
It should be appreciated that the application of the present invention is not limited to above-mentioned citing, and for those of ordinary skills, can
To be improved according to the above description or be converted, all these modifications and variations should all belong to the guarantor of claims of the present invention
Shield scope.
Claims (3)
1. one kind is without the special defoamer of silicon waste water process, it is characterised in that:By weight percentage, including:
Fatty alcohol 5-20%;
Glyceryl stearate fat acid fat 1-3%;
Higher aliphatic polyethers 3-6%;
White oil 60-70%;
Emulsifying agent S-60 15-35%;
Lauryl sodium sulfate 1-3%;
White carbon 1-3%;
Aluminum oxide 2-5%.
2. according to claim 1 a kind of without the special defoamer of silicon waste water process, it is characterised in that:The wherein carbon of fatty alcohol
Between 3-10, the molecular weight of higher aliphatic polyethers is between 5000-10000 for atom.
3. a kind of preparation method without the special defoamer of silicon waste water process as claimed in claim 1, it is characterised in that:Successively plus
Enter fatty alcohol, glyceryl stearate fat acid fat, higher aliphatic polyethers, white oil, emulsifying agent S-60, lauryl sodium sulfate, white carbon,
Aluminum oxide stirring 30-60 minutes are obtained without the special defoamer of silicon waste water process.
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
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CN201611225221.4A CN106629950A (en) | 2016-12-27 | 2016-12-27 | Silicon-free antifoaming agent specially used for waste water processing, and preparation method thereof |
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CN201611225221.4A CN106629950A (en) | 2016-12-27 | 2016-12-27 | Silicon-free antifoaming agent specially used for waste water processing, and preparation method thereof |
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CN106629950A true CN106629950A (en) | 2017-05-10 |
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CN201611225221.4A Pending CN106629950A (en) | 2016-12-27 | 2016-12-27 | Silicon-free antifoaming agent specially used for waste water processing, and preparation method thereof |
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Citations (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN101445760A (en) * | 2008-12-30 | 2009-06-03 | 南京四新科技应用研究所有限公司 | Method for improving stability of mineral oil defoaming agent |
US20100076142A1 (en) * | 2008-09-24 | 2010-03-25 | Kusumoto Chemicals, Ltd. | Defoaming agent for water based paint |
CN102154939A (en) * | 2011-01-27 | 2011-08-17 | 南京四新科技应用研究所有限公司 | Anti-foaming agent for papermaking system |
CN102489049A (en) * | 2011-12-26 | 2012-06-13 | 南京四新科技应用研究所有限公司 | Mineral oil type antifoaming agent and preparation method thereof |
-
2016
- 2016-12-27 CN CN201611225221.4A patent/CN106629950A/en active Pending
Patent Citations (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US20100076142A1 (en) * | 2008-09-24 | 2010-03-25 | Kusumoto Chemicals, Ltd. | Defoaming agent for water based paint |
CN101445760A (en) * | 2008-12-30 | 2009-06-03 | 南京四新科技应用研究所有限公司 | Method for improving stability of mineral oil defoaming agent |
CN102154939A (en) * | 2011-01-27 | 2011-08-17 | 南京四新科技应用研究所有限公司 | Anti-foaming agent for papermaking system |
CN102489049A (en) * | 2011-12-26 | 2012-06-13 | 南京四新科技应用研究所有限公司 | Mineral oil type antifoaming agent and preparation method thereof |
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Application publication date: 20170510 |
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RJ01 | Rejection of invention patent application after publication |