CN106629950A - Silicon-free antifoaming agent specially used for waste water processing, and preparation method thereof - Google Patents

Silicon-free antifoaming agent specially used for waste water processing, and preparation method thereof Download PDF

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Publication number
CN106629950A
CN106629950A CN201611225221.4A CN201611225221A CN106629950A CN 106629950 A CN106629950 A CN 106629950A CN 201611225221 A CN201611225221 A CN 201611225221A CN 106629950 A CN106629950 A CN 106629950A
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CN
China
Prior art keywords
silicon
waste water
antifoaming agent
fatty alcohol
free
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201611225221.4A
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Chinese (zh)
Inventor
王梅玲
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Guangdong Federal Fine Chemical Co Ltd
Original Assignee
Guangdong Federal Fine Chemical Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Guangdong Federal Fine Chemical Co Ltd filed Critical Guangdong Federal Fine Chemical Co Ltd
Priority to CN201611225221.4A priority Critical patent/CN106629950A/en
Publication of CN106629950A publication Critical patent/CN106629950A/en
Pending legal-status Critical Current

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Classifications

    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F1/20Treatment of water, waste water, or sewage by degassing, i.e. liberation of dissolved gases

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  • Life Sciences & Earth Sciences (AREA)
  • Hydrology & Water Resources (AREA)
  • Engineering & Computer Science (AREA)
  • Environmental & Geological Engineering (AREA)
  • Water Supply & Treatment (AREA)
  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Degasification And Air Bubble Elimination (AREA)

Abstract

The invention discloses a silicon-free antifoaming agent specially used for waste water processing, and a preparation method thereof. The silicon-free antifoaming agent specially used for waste water processing comprises, by weight, 5 to 20% of a fatty alcohol, 1 to 3% of fatty acid monoglyceride, 3 to 6% of a high aliphatic alcohol polyether, 60 to 70% of white oil, 15 to 35% of emulsifier S-60, 1 to 3% of lauryl sodium sulfate, 1 to 3% of white carbon black, and 2 to 5% of aluminium oxide, wherein the carbon atom number of the fatty alcohol ranges from 3 to 10, and the molecular weight of the high aliphatic alcohol polyether ranges from 5000 to 10000. The silicon-free antifoaming agent is capable of defoaming quickly, is low in using amount, possesses excellent thermal resistance, acid and alkali resistance, polyelectrolyte resistance, high shear resistance; the basic characteristics of foaming systems are not influenced by the silicon-free antifoaming agent; and the silicon-free antifoaming agent is capable of solving a problem that demulsification is easily caused when common antifoaming agents are added into polyelectrolyte, strong acid, strong base, and high shear systems.

Description

It is a kind of to process special defoamer and preparation method thereof without silicon waste water
Technical field
The present invention relates to defoamer field, more particularly to one kind is without the special defoamer of silicon waste water process and its preparation side Method.
Background technology
Use chemical assistant in a large number in the water treatment procedures such as industrial production, domestic water, wherein these auxiliary agents are with surface Based on activating agent, the technique end of water process can all produce substantial amounts of foam, these materials be all based on macromolecular compound, The foam that they are formed in water enhances bubble film strength because of intermolecular absorption problem so that froth breaking becomes difficult, and Traditional organic silicon defoamer consumption is big, affects the fundamental property of the system of foaming, resistance to heat differential to have adverse side effect, therefore existing There is defoamer performance to be improved;
Therefore, prior art has yet to be improved and developed.
The content of the invention
In view of above-mentioned the deficiencies in the prior art, it is an object of the invention to provide one kind is without the special froth breaking of silicon waste water process Agent, it is intended to solve the problems, such as that prior art defoamer performance is to be improved.
It is a kind of to process special defoamer without silicon waste water, wherein:By weight percentage, including:
Fatty alcohol 5-20%;
Glyceryl stearate fat acid fat 1-3%;
Higher aliphatic polyethers 3-6%;
White oil 60-70%;
Emulsifying agent S-60 15-35%;
Lauryl sodium sulfate 1-3%;
White carbon 1-3%;
Aluminum oxide 2-5%.
Between 3-10, the molecular weight of higher aliphatic polyethers is between 5000-10000 for the wherein carbon atom of fatty alcohol.
A kind of preparation method without the special defoamer of silicon waste water process, wherein:Sequentially add fatty alcohol, the acid of glyceryl stearate fat Fat, higher aliphatic polyethers, white oil, emulsifying agent S-60, lauryl sodium sulfate, white carbon, 30-60 point of aluminum oxide stirring Clock is obtained without the special defoamer of silicon waste water process.Emulsifying agent S-60 is wherein added to be gradually added in batches.
The present invention's can be in industrial production, domestic water, consumption fast with froth breaking without the special defoamer of silicon waste water process It is little, the fundamental property of the system of foaming is not affected, heat-resisting good, acid and alkali-resistance, resistance to polyelectrolyte, resistance to high shear, the present invention are solved The defect of general common froth breaking agent emulsion easy breakdown of emulsion failure in polyelectrolyte, strong acid, highly basic, high shear system.The suds time It is long, efficiency high, and it is nontoxic, corrosion-free, without adverse side effect.Low COD, low consumption amount, environmental protection.
Specific embodiment
The present invention provides a kind of without special defoamer of silicon waste water process and preparation method thereof, to make the purpose of the present invention, skill Art scheme and effect are clearer, clear and definite, and below the present invention is described in more detail.It should be appreciated that tool described herein Body embodiment only to explain the present invention, is not intended to limit the present invention.
Embodiment 1:
It is a kind of to process special defoamer without silicon waste water, by weight percentage, including:
Fatty alcohol 15%;
Glyceryl stearate fat acid fat 2%;
Higher aliphatic polyethers 4%;
White oil 60%;
Emulsifying agent S-60 15%;
Lauryl sodium sulfate 1%;
White carbon 1%;
Aluminum oxide 2%.
Wherein the carbon atom of fatty alcohol is 8, and the molecular weight of higher aliphatic polyethers is 8000.
Present invention also offers without the preparation method of the special defoamer of silicon waste water process described in embodiment 1, it is specific as follows:According to It is secondary addition fatty alcohol, glyceryl stearate fat acid fat, higher aliphatic polyethers, white oil, emulsifying agent S-60, lauryl sodium sulfate, white Carbon black, aluminum oxide are stirred and are obtained within 30 minutes without the special defoamer of silicon waste water process.
Embodiment 2:
It is a kind of to process special defoamer without silicon waste water, by weight percentage, including:
Fatty alcohol 12%;
Glyceryl stearate fat acid fat 2%;
Higher aliphatic polyethers 4%;
White oil 63%;
Emulsifying agent S-60 15%;
Lauryl sodium sulfate 1%;
White carbon 1%;
Aluminum oxide 2%.
Wherein the carbon atom of fatty alcohol is 7, and the molecular weight of higher aliphatic polyethers is 7500.
Present invention also offers without the preparation method of the special defoamer of silicon waste water process described in embodiment 2, it is specific as follows:According to It is secondary addition fatty alcohol, glyceryl stearate fat acid fat, higher aliphatic polyethers, white oil, emulsifying agent S-60, lauryl sodium sulfate, White carbon, aluminum oxide are stirred and are obtained within 60 minutes without the special defoamer of silicon waste water process.
It should be appreciated that the application of the present invention is not limited to above-mentioned citing, and for those of ordinary skills, can To be improved according to the above description or be converted, all these modifications and variations should all belong to the guarantor of claims of the present invention Shield scope.

Claims (3)

1. one kind is without the special defoamer of silicon waste water process, it is characterised in that:By weight percentage, including:
Fatty alcohol 5-20%;
Glyceryl stearate fat acid fat 1-3%;
Higher aliphatic polyethers 3-6%;
White oil 60-70%;
Emulsifying agent S-60 15-35%;
Lauryl sodium sulfate 1-3%;
White carbon 1-3%;
Aluminum oxide 2-5%.
2. according to claim 1 a kind of without the special defoamer of silicon waste water process, it is characterised in that:The wherein carbon of fatty alcohol Between 3-10, the molecular weight of higher aliphatic polyethers is between 5000-10000 for atom.
3. a kind of preparation method without the special defoamer of silicon waste water process as claimed in claim 1, it is characterised in that:Successively plus Enter fatty alcohol, glyceryl stearate fat acid fat, higher aliphatic polyethers, white oil, emulsifying agent S-60, lauryl sodium sulfate, white carbon, Aluminum oxide stirring 30-60 minutes are obtained without the special defoamer of silicon waste water process.
CN201611225221.4A 2016-12-27 2016-12-27 Silicon-free antifoaming agent specially used for waste water processing, and preparation method thereof Pending CN106629950A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201611225221.4A CN106629950A (en) 2016-12-27 2016-12-27 Silicon-free antifoaming agent specially used for waste water processing, and preparation method thereof

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201611225221.4A CN106629950A (en) 2016-12-27 2016-12-27 Silicon-free antifoaming agent specially used for waste water processing, and preparation method thereof

Publications (1)

Publication Number Publication Date
CN106629950A true CN106629950A (en) 2017-05-10

Family

ID=58832573

Family Applications (1)

Application Number Title Priority Date Filing Date
CN201611225221.4A Pending CN106629950A (en) 2016-12-27 2016-12-27 Silicon-free antifoaming agent specially used for waste water processing, and preparation method thereof

Country Status (1)

Country Link
CN (1) CN106629950A (en)

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101445760A (en) * 2008-12-30 2009-06-03 南京四新科技应用研究所有限公司 Method for improving stability of mineral oil defoaming agent
US20100076142A1 (en) * 2008-09-24 2010-03-25 Kusumoto Chemicals, Ltd. Defoaming agent for water based paint
CN102154939A (en) * 2011-01-27 2011-08-17 南京四新科技应用研究所有限公司 Anti-foaming agent for papermaking system
CN102489049A (en) * 2011-12-26 2012-06-13 南京四新科技应用研究所有限公司 Mineral oil type antifoaming agent and preparation method thereof

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20100076142A1 (en) * 2008-09-24 2010-03-25 Kusumoto Chemicals, Ltd. Defoaming agent for water based paint
CN101445760A (en) * 2008-12-30 2009-06-03 南京四新科技应用研究所有限公司 Method for improving stability of mineral oil defoaming agent
CN102154939A (en) * 2011-01-27 2011-08-17 南京四新科技应用研究所有限公司 Anti-foaming agent for papermaking system
CN102489049A (en) * 2011-12-26 2012-06-13 南京四新科技应用研究所有限公司 Mineral oil type antifoaming agent and preparation method thereof

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Application publication date: 20170510

RJ01 Rejection of invention patent application after publication