CN106621561A - Sewage filter screen for adsorbing nitrogen and phosphorus elements in sewage - Google Patents

Sewage filter screen for adsorbing nitrogen and phosphorus elements in sewage Download PDF

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Publication number
CN106621561A
CN106621561A CN201610954430.6A CN201610954430A CN106621561A CN 106621561 A CN106621561 A CN 106621561A CN 201610954430 A CN201610954430 A CN 201610954430A CN 106621561 A CN106621561 A CN 106621561A
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China
Prior art keywords
nitrogen
phosphorus
synchronous
sewage
phosphorus adsorbent
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Application number
CN201610954430.6A
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Chinese (zh)
Inventor
缪东伟
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Wuhu Hangda Network Industry Co Ltd
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Wuhu Hangda Network Industry Co Ltd
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Priority to CN201610954430.6A priority Critical patent/CN106621561A/en
Publication of CN106621561A publication Critical patent/CN106621561A/en
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    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D39/00Filtering material for liquid or gaseous fluids
    • B01D39/10Filter screens essentially made of metal
    • B01D39/12Filter screens essentially made of metal of wire gauze; of knitted wire; of expanded metal
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/02Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material
    • B01J20/10Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material comprising silica or silicate
    • B01J20/12Naturally occurring clays or bleaching earth
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/28Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof characterised by their form or physical properties
    • B01J20/28014Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof characterised by their form or physical properties characterised by their form
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F1/28Treatment of water, waste water, or sewage by sorption
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F11/00Treatment of sludge; Devices therefor
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D2239/00Aspects relating to filtering material for liquid or gaseous fluids
    • B01D2239/04Additives and treatments of the filtering material
    • B01D2239/0407Additives and treatments of the filtering material comprising particulate additives, e.g. adsorbents
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D2239/00Aspects relating to filtering material for liquid or gaseous fluids
    • B01D2239/10Filtering material manufacturing
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F1/28Treatment of water, waste water, or sewage by sorption
    • C02F1/281Treatment of water, waste water, or sewage by sorption using inorganic sorbents

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Analytical Chemistry (AREA)
  • Hydrology & Water Resources (AREA)
  • Environmental & Geological Engineering (AREA)
  • Water Supply & Treatment (AREA)
  • Textile Engineering (AREA)
  • Dispersion Chemistry (AREA)
  • Geochemistry & Mineralogy (AREA)
  • Inorganic Chemistry (AREA)
  • Water Treatment By Sorption (AREA)
  • Solid-Sorbent Or Filter-Aiding Compositions (AREA)

Abstract

The invention discloses a sewage filter screen for adsorbing nitrogen and phosphorus elements in sewage. A body of the sewage filter screen is a steel filter screen, and the steel filter screen is filled with a synchronous nitrogen and phosphorus adsorbent in the production process. A preparation method of the synchronous nitrogen and phosphorus adsorbent comprises the steps that dolomite and attapulgite clay is mechanically smashed and screened into powdery particles, the mass content of the attapulgite in the attapulgite clay is 30-50%, and the mass content of the dolomite is 10-30%; ion exchange treatment is performed in a sodium salt and magnesium salt mixed water solution, then the product obtained after treatment is heated and modified, the heating and modifying temperature is 800-1000 DEG C, and the heating and modifying time is 0.5-2 hours; the synchronous nitrogen and phosphorus adsorbent is prepared. The body of the sewage filter screen for adsorbing the nitrogen and phosphorus elements in sewage is the steel filter screen, and the steel filter screen is filled with the synchronous nitrogen and phosphorus adsorbent in the production process.

Description

A kind of sewage filter net for nitrogen P elements in absorption effluent
Technical field
The present invention relates to a kind of screen pack, more particularly to a kind of sewage filter net for nitrogen P elements in absorption effluent.
Background technology
With China's industrial progress and social development, water pollution is also on the rise, into a difficult problem for environmental improvement.According to ring Border department monitors, and the daily at least 100,000,000 tons sewage in national cities and towns are unprocessed to be directly discharged into water body.Half in national seven big water systems Above section water quality is contaminated, and the water body in the whole nation 1/3 is unsuitable for Fish Survival, and 1/4 water body is unsuitable for irrigating, 90% city City's water pollution is serious, and 50% cities and towns water source does not meet drinking water standard.With economic continuous development, these statistics Also continuing to increase.
Water pollution is mainly caused by the pollutant of mankind's activity generation, and it includes industrial pollution source, agricultural pollution source With domestic pollution source three parts.Industrial wastewater is the important pollution sources in waters, with big, the wide, complicated component of amount, toxicity Greatly, be difficult purification, it is difficult the features such as.Agricultural pollution source includes excrement of animals, agricultural chemicals, chemical fertilizer etc..China is water and soil in the world One of country of most serious is lost in, about 5,000,000,000 tons of annual ground surface soil number of dropouts causes a large amount of agricultural chemicals, chemical fertilizer to flow into ground surface soil River, river, lake, storehouse, the nitrogen being lost in therewith, phosphorus, potassium nutrition element, the lake for making 2/3 is subject to different degrees of eutrophication pollution Harm, causes algae and other biological distorted proliferation, causes the change of water transparency and dissolved oxygen, so as to cause water quality to be disliked Change.Domestic pollution source is mainly the various detergent used in urban life and sewage, rubbish, excrement etc., mostly nontoxic nothing Machine salt, many containing nitrogen phosphate and sulfur in sanitary sewage, malignant bacteria is more.
Nitrogen and phosphorus, as inorganic nutrient substance, are the main matters for causing water pollution and eutrophication.Therefore, effectively go Except nitrogen and phosphorus in sewage, to protecting water environment significant.That what is reported both at home and abroad at present denitrogenates phosphorus method mainly having Method, the precipitation method, biochemical process and absorption method.In these methods, the features such as adsorption technology is because having convenient and swift, efficient, more Come the concerns for causing people more.The core of adsorption technology is to select suitable sorbing material.Activated carbon is at the most frequently used water Reason adsorbent, but its is expensive, separates difficult, regeneration condition harshness, and adsorption effect is undesirable.In recent years, using molecule Sieve or cheap clay carry out adsorption treatment and also have been reported that to Nitrogen-and Phosphorus-containing waste water, but adsorption time is long, and adsorption capacity is low.
Organo-mineral complexing adsorbent is developing direction new in recent years, due to having hydrophilic functional in compound adsorbent Group, there is capability of fast response and high adsorbance to pollutant.Clay class material is introduced in compound adsorbent, can further be dropped Low product cost.Therefore, using dispersin polymerization technology, the appropriately crosslinked process of Jing is obtained granular attapulgite clay base and answers Close adsorbent.Such adsorbent has higher adsorption capacity and faster absorption/desorption rate to nitrogen phosphorus, undoubtedly in high nitrogen phosphorus Have broad application prospects in water body.
The content of the invention
The invention aims to shortcoming present in prior art is solved, and the one kind for proposing is used in absorption effluent The sewage filter net of nitrogen P elements.
To achieve these goals, present invention employs following technical scheme:
A kind of sewage filter net for nitrogen P elements in absorption effluent, its main body be steel screen pack, the steel screen pack Synchronous nitrogen and phosphorus adsorbent is filled with process of production, and the preparation method of the synchronous nitrogen and phosphorus adsorbent is:
S1, by dolomite attapulgite clay mechanical crushing, be screened into powder particle, concave convex rod quality contains in the attapulgite clay Measure as 30-50%, dolomite mass content is 10-30%;
S2, it is placed in sodium salt and magnesium salts mixed aqueous solution and carries out ion-exchange treatment, then product heats after process are modified, heats Modified temperature is 800 DEG C -1000 DEG C, and the heat modification time is 0.5-2 hours;
S3, prepared synchronous nitrogen and phosphorus adsorbent.
In the preparation process of the synchronous nitrogen and phosphorus adsorbent, dolomite concave convex rod mechanical crushing, sieve after, powder particle grain Footpath is less than 100 mesh.
In the preparation process of the synchronous nitrogen and phosphorus adsorbent, sodium salt is NaCl and MgCl with magnesium salts mixed aqueous solution2It is mixed Heshui solution, wherein NaCl and MgCl2Mol ratio be 2:1.
In the preparation process of the synchronous nitrogen and phosphorus adsorbent, the time of dolomite concave convex rod ion-exchange treatment is at least 4 Hour.
The synchronous nitrogen and phosphorus adsorbent is applied to nitrogen and phosphorus in synchronous Adsorption polluted-water, in polluted-water simultaneously It is the nitrogen of 1-100mg/L and the phosphorus of 0.1-100mg/L containing concentration.
The synchronous nitrogen and phosphorus adsorbent is applied to nitrogen and phosphorus in synchronous Adsorption polluted bed mud, in control polluted bed mud Nitrogen phosphorus release.
Compared with prior art, the invention has the beneficial effects as follows:For the sewage filter net of nitrogen P elements in absorption effluent, Its main body is steel screen pack, and steel screen pack is filled with process of production synchronous nitrogen and phosphorus adsorbent, synchronous nitrogen and phosphorus adsorbent Natural dolomite concave convex rod is adopted for raw material, first by NaCl and MgCl2Mixed solution carry out ion-exchange treatment so as to With larger cation exchange capacity (CEC), then by products therefrom in high temperature heat modification, by the inertia in dolomite concave convex rod Calcium activation is calcium oxide, so as to strengthen its adsorption capacity to nitrogen, makes it have higher fixed capacity and absorption effect to phosphorus again Rate.Synchronous nitrogen and phosphorus adsorbent comprehensive inorganic salt and high-temperature heat treatment in the present invention, is modified to dolomite concave convex rod, except Promote outside phosphorus adsorption capacity, also to greatly improve adsorption capacity and removal efficiency of the dolomite concave convex rod to nitrogen;And adopt sodium Salt carries out ion-exchange treatment with the mixed solution of magnesium salts, for the raising of the N2 adsorption ability of dolomite concave convex rod has significantly Synergistic function.Synchronous nitrogen and phosphorus phosphorus adsorbent in the present invention can not only efficiently, quickly remove life and trade effluent, Nitrogen and phosphorus in eutrophication water, but also nitrogen phosphorus in lake, wetland, river course in polluted bed mud can be efficiently controlled Release, effectively cuts down and controls water body eutrophication degree.
Specific embodiment
The technical scheme in the embodiment of the present invention will be clearly and completely described below, it is clear that described enforcement Example is only a part of embodiment of the invention, rather than the embodiment of whole.
A kind of sewage filter net for nitrogen P elements in absorption effluent, its main body be steel screen pack, the steel mistake Filter screen is filled with process of production synchronous nitrogen and phosphorus adsorbent, and the preparation method of the synchronous nitrogen and phosphorus adsorbent is:
S1, by dolomite attapulgite clay mechanical crushing, be screened into powder particle, concave convex rod quality contains in the attapulgite clay Measure as 30-50%, dolomite mass content is 10-30%;
S2, it is placed in sodium salt and magnesium salts mixed aqueous solution and carries out ion-exchange treatment, then product heats after process are modified, heats Modified temperature is 800 DEG C -1000 DEG C, and the heat modification time is 0.5-2 hours;
S3, prepared synchronous nitrogen and phosphorus adsorbent.
In the preparation process of the synchronous nitrogen and phosphorus adsorbent, dolomite concave convex rod mechanical crushing, sieve after, powder particle grain Footpath is less than 100 mesh.
In the preparation process of the synchronous nitrogen and phosphorus adsorbent, sodium salt is NaCl and MgCl with magnesium salts mixed aqueous solution2It is mixed Heshui solution, wherein NaCl and MgCl2Mol ratio be 2:1.
In the preparation process of the synchronous nitrogen and phosphorus adsorbent, the time of dolomite concave convex rod ion-exchange treatment is at least 4 Hour.
The synchronous nitrogen and phosphorus adsorbent is applied to nitrogen and phosphorus in synchronous Adsorption polluted-water, in polluted-water simultaneously It is the nitrogen of 1-100mg/L and the phosphorus of 0.1-100mg/L containing concentration.
The synchronous nitrogen and phosphorus adsorbent is applied to nitrogen and phosphorus in synchronous Adsorption polluted bed mud, in control polluted bed mud Nitrogen phosphorus release.
The above, the only present invention preferably specific embodiment, but protection scope of the present invention is not limited thereto, Any those familiar with the art the invention discloses technical scope in, technology according to the present invention scheme and its Inventive concept equivalent or change in addition, all should be included within the scope of the present invention.

Claims (6)

1. a kind of sewage filter net for nitrogen P elements in absorption effluent, its main body is steel screen pack, and the steel is filtered Net is filled with process of production synchronous nitrogen and phosphorus adsorbent, it is characterised in that the preparation method of the synchronous nitrogen and phosphorus adsorbent is:
S1, by dolomite attapulgite clay mechanical crushing, be screened into powder particle, concave convex rod quality contains in the attapulgite clay Measure as 30-50%, dolomite mass content is 10-30%;
S2, it is placed in sodium salt and magnesium salts mixed aqueous solution and carries out ion-exchange treatment, then product heats after process are modified, heats Modified temperature is 800 DEG C -1000 DEG C, and the heat modification time is 0.5-2 hours;
S3, prepared synchronous nitrogen and phosphorus adsorbent.
2. a kind of sewage filter net for nitrogen P elements in absorption effluent according to claim 1, it is characterised in that institute In stating the preparation process of synchronous nitrogen and phosphorus adsorbent, dolomite concave convex rod mechanical crushing, sieve after, powder particle particle diameter be less than 100 Mesh.
3. a kind of sewage filter net for nitrogen P elements in absorption effluent according to claim 1, it is characterised in that institute In stating the preparation process of synchronous nitrogen and phosphorus adsorbent, sodium salt is NaCl and MgCl with magnesium salts mixed aqueous solution2Mixed aqueous solution, its Middle NaCl and MgCl2Mol ratio be 2:1.
4. a kind of sewage filter net for nitrogen P elements in absorption effluent according to claim 1, it is characterised in that institute In stating the preparation process of synchronous nitrogen and phosphorus adsorbent, the time of dolomite concave convex rod ion-exchange treatment is at least 4 hours.
5. a kind of sewage filter net for nitrogen P elements in absorption effluent according to claim 1, it is characterised in that institute Nitrogen and phosphorus that synchronous nitrogen and phosphorus adsorbent is applied in synchronous Adsorption polluted-water are stated, containing concentration is simultaneously in polluted-water The nitrogen of 1-100mg/L and the phosphorus of 0.1-100mg/L.
6. a kind of sewage filter net for nitrogen P elements in absorption effluent according to claim 1, it is characterised in that institute Nitrogen and phosphorus that synchronous nitrogen and phosphorus adsorbent is applied in synchronous Adsorption polluted bed mud are stated, the nitrogen phosphorus controlled in polluted bed mud is released Put.
CN201610954430.6A 2016-11-03 2016-11-03 Sewage filter screen for adsorbing nitrogen and phosphorus elements in sewage Withdrawn CN106621561A (en)

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Application Number Priority Date Filing Date Title
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Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN107642203A (en) * 2017-10-31 2018-01-30 山东毅康科技股份有限公司 It is a kind of that there is self-cleaning, the Green Roof structure of dephosphorization ability
CN108404518A (en) * 2018-04-23 2018-08-17 苏州清荷坊环保科技有限公司 A kind of industrial wastewater filter screen
CN115196771A (en) * 2022-07-18 2022-10-18 上海江柘环境工程技术有限公司 Agricultural non-point source pollution treatment system

Citations (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN2392626Y (en) * 1999-10-10 2000-08-23 季克章 Mould for casting metal ball
CN1435382A (en) * 2002-01-30 2003-08-13 唐文浩 Filtering material for deep treatment of sewage
JP2004181354A (en) * 2002-12-03 2004-07-02 Toyobo Co Ltd Flame-retardant filter medium
CN101306343A (en) * 2007-11-14 2008-11-19 中国科学院南京土壤研究所 Method for preparing water body dephosphorized granule adsorbent using attapulgite clay
CN102219233A (en) * 2010-10-19 2011-10-19 华北电力大学 Method for removing nitrogen and phosphorus in sewage by zeolite synthesized by coal ash
CN103145210A (en) * 2013-03-25 2013-06-12 苏州绿世界园林发展有限公司 Environment-friendly sewage nitrogen and phosphorus removal cleaning agent and preparation method thereof
CN103223327A (en) * 2013-05-13 2013-07-31 中国科学院南京地理与湖泊研究所 Preparation method and applications of synchronous nitrogen and phosphorus absorption agent
CN103846009A (en) * 2012-11-29 2014-06-11 大连凯泓科技有限公司 Filter net used for sewage treatment

Patent Citations (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN2392626Y (en) * 1999-10-10 2000-08-23 季克章 Mould for casting metal ball
CN1435382A (en) * 2002-01-30 2003-08-13 唐文浩 Filtering material for deep treatment of sewage
JP2004181354A (en) * 2002-12-03 2004-07-02 Toyobo Co Ltd Flame-retardant filter medium
CN101306343A (en) * 2007-11-14 2008-11-19 中国科学院南京土壤研究所 Method for preparing water body dephosphorized granule adsorbent using attapulgite clay
CN102219233A (en) * 2010-10-19 2011-10-19 华北电力大学 Method for removing nitrogen and phosphorus in sewage by zeolite synthesized by coal ash
CN103846009A (en) * 2012-11-29 2014-06-11 大连凯泓科技有限公司 Filter net used for sewage treatment
CN103145210A (en) * 2013-03-25 2013-06-12 苏州绿世界园林发展有限公司 Environment-friendly sewage nitrogen and phosphorus removal cleaning agent and preparation method thereof
CN103223327A (en) * 2013-05-13 2013-07-31 中国科学院南京地理与湖泊研究所 Preparation method and applications of synchronous nitrogen and phosphorus absorption agent

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN107642203A (en) * 2017-10-31 2018-01-30 山东毅康科技股份有限公司 It is a kind of that there is self-cleaning, the Green Roof structure of dephosphorization ability
CN108404518A (en) * 2018-04-23 2018-08-17 苏州清荷坊环保科技有限公司 A kind of industrial wastewater filter screen
CN115196771A (en) * 2022-07-18 2022-10-18 上海江柘环境工程技术有限公司 Agricultural non-point source pollution treatment system

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