CN106617421A - Antibacterial thermal carbon silver fabric and preparation technology thereof - Google Patents

Antibacterial thermal carbon silver fabric and preparation technology thereof Download PDF

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Publication number
CN106617421A
CN106617421A CN201510723367.0A CN201510723367A CN106617421A CN 106617421 A CN106617421 A CN 106617421A CN 201510723367 A CN201510723367 A CN 201510723367A CN 106617421 A CN106617421 A CN 106617421A
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China
Prior art keywords
thermal insulating
antibacterial thermal
elargol
fabric
charcoal
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CN201510723367.0A
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Chinese (zh)
Inventor
李健
徐卫林
张克勤
蔡玉梅
孔劲松
李肇魁
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TRYD TEXTILE FIBER TECHNOLOGY Co Ltd
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TRYD TEXTILE FIBER TECHNOLOGY Co Ltd
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Priority to CN201510723367.0A priority Critical patent/CN106617421A/en
Publication of CN106617421A publication Critical patent/CN106617421A/en
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Abstract

The invention provides an antibacterial thermal carbon silver fabric and a preparation technology thereof. The preparation technology includes the steps that carbon powder and silver powder are added into resin to form a carbon silver film, and the carbon silver film is applied to a woven spandex fabric through the gold printing technology. The fabric has good heat storage, heat preservation, antibacterial and deodorizing characteristics, and also has the advantages of being fashionable, small in friction coefficient, good in windproof property and elasticity and the like.

Description

A kind of antibacterial thermal insulating charcoal silver fabric and its preparation technology
Technical field
The present invention relates to the preparation technology of a kind of antibacterial thermal insulating charcoal silver fabric and the fabric, belongs to textile technology field.
Background technology
With economic development and life requirement, the feature of fabric and clothes constantly extends in practice, and people propose higher and higher requirement to the feature of textile, and wherein antibacterial and deodouring, the feature of heat storing and heat preserving enjoys great popularity.The more thermal fabric of practical application is that ectonexine is pure cotton knitting cloth on market, and interlayer is space wadding, although this kind of heat insulating material formed warmth retention property is slightly good, wet transmitting performance is poor.At present, in the industry many enterprises competitively release new heat preservation fabric, such as far-infrared warm clothes, ceramic fibre is obtained by different formulations with various oxides to knit again in underwear, so as to reach the function of heat generating and retention, but most of ceramic fibres produce about 40-50 DEG C of the excitation temperature of far infrared radiation, and the temperature of human body can not possibly reach it is so high, therefore ceramic fibre thermal property at normal temperatures is unsatisfactory, if sorting is improper, it is also possible to take radiogen in clothes to, radiological hazard can be brought to human body.On the market textile is the function of reaching antibacterial and deodouring, mainly adopt antibacterial finishing agent, antibacterial finishing agent main component is organonitrogen compound and Econazole compound, it is pale yellow powder, antibiotic property with good security and broad-spectrum high efficacy, it is easy to use, it is adaptable to produce antibacterial viscose fiber, but the scope of application is limited to.
In order to meet the dual-use function of antibacterial and deodouring, heat storing and heat preserving, the present invention is distributed using human body heat energy, it is most principles with radiation mode, the proposition of novelty is mixed into aluminium gold metal particles and activated carbon powder in coating resin, on the one hand the reflex to radiating is strengthened by aluminium gold metal particles, so as to reach best heat insulation effect;On the other hand by the adsorption capacity of activated carbon powder, so as to reach moisture absorption, deodorant, antibacterial effect.
The content of the invention
The technical problem of solution:For the deficiencies in the prior art, the present invention provides a kind of antibacterial thermal insulating charcoal silver fabric and its preparation technology, the preparation technology draws high powdered carbon, silver powder on polypropylene screen two-way with concavo-convex hot stamping process thermoprint, again the flower pattern transfer portions containing powdered carbon, silver powder are formed in base fabric by antibacterial thermal insulating charcoal silver fabric by caloric transfer printing technology, technique productions antibacterial thermal insulating charcoal silver fabric antibacterial deodourizing out is good, thermal storage and thermal insulating is high, it is high to depart from intensity between film layer and base fabric, steady quality, it is soft, comfortable and easy to wear.
Technical scheme:
A kind of antibacterial thermal insulating charcoal silver fabric, including base cloth layer, characterized by further comprising the antibacterial thermal insulating charcoal elargol bed of material, the antibacterial thermal insulating charcoal elargol bed of material is with the discrete thermoprint of design shape and protrudes on base cloth layer, it is dispersed in the antibacterial thermal insulating charcoal elargol bed of material to have powdered carbon and silver powder, its powdered carbon and silver powder tamped density in compound layer is 30- 50% 。
Used as a kind of preferred version, in the embedded base cloth layer of the antibacterial thermal insulating charcoal elargol bed of material, the thickness of embedded base cloth layer accounts for the 1/3-1/2 of base fabric thickness.
Used as a kind of preferred version, antibacterial thermal insulating charcoal elargol bed of material integral thickness is 20-30 μm, and the thickness of antibacterial thermal insulating charcoal elargol bed of material protrusion fabric is 5-15 μm.
As a kind of preferred version, the antibacterial thermal insulating charcoal elargol bed of material protrudes the design for being shaped as stereochemical structure of base cloth layer, and the design includes ramage, animal pattern, character pattern, monogram, scenery with hills and waters pattern etc. those skilled in the art will envision that the mixed pattern of one or two or more kinds in the pattern for obtaining.
Used as a kind of preferred version, the base cloth layer is 75D spandex fabrics.
The antibacterial thermal insulating charcoal silver fabric not only has good heat accumulation thermal effect, and with excellent wearability, wash wet, deodorant, antibacterial bacteriostatic, fastness good, soft, comfortable and easy to wear strong, thermal requirements of the people to dress ornament are not only met, while and the protective action of antibacterial and deodouring can be played.
The preparation technology of above-mentioned antibacterial thermal insulating charcoal silver fabric, comprises the following steps:
It is prepared by step one, antibacterial thermal insulating charcoal elargol material:Using 100 parts by weight of polyurethane solids, 5-10 weight portion bridging agents, 100-150 parts by weight solvent, 15-20 parts by weight of silver powder, 10-15 weight portion powdered carbons, 2-5 weight portion accelerator mixing and stirrings as antibacterial thermal insulating charcoal elargol material;
Step 2, gluing:The sizing material prepared in step one print is scalded into the formation antibacterial thermal insulating charcoal elargol bed of material on OPP films;
Step 3, half dries:The step 2 antibacterial thermal insulating charcoal elargol bed of material is carried out to heat half drying, oven temperature is 40-45 DEG C;
Step 4, base fabric laminating:Base fabric is unreeled, the speed such as base fabric and sizing material of OPP films fits to form semi-finished product winding, at 100-120 DEG C, in 15-20m/min, laminate pressure is 6-7KG to laminating speeds control to laminating wheel temperature control.
Step 5, semi-finished product maturation:Maturation time 12H, maturation temperature is 65 DEG C.
Step 6, the semi-finished product after maturation are cooled down, and peel off mould release membrance.
Wherein, the preparation of sensitization discoloration sizing material is comprised the following steps in the step one:
(1)Proportionally solvent is added in empty barrel, is started mixer and bucket internal solvent is stirred, stir speed (S.S.) is 200-500 rpm;
(2)Add 15-20 parts by weight of silver powder toward solvent in proportion, continue to stir 10-20min, make composition in bucket dispersed;
(3)Add 10-15 weight portion powdered carbons toward solvent in proportion, continue to stir 10-20min, make composition in bucket dispersed;
(4)Polyurethane resin is proportionally added into, and is 200-500rpm by stir speed (S.S.), persistently stir 10-30min;
(5)It is standby after stirring using bridging agent, accelerator is front proportionally added into.
Wherein, in the step 2, antibacterial thermal insulating charcoal elargol material is poured in sizing material groove, the concavo-convex thermoprint roller of design needed for preparing, by antibacterial thermal insulating charcoal silver fabric design of the concavo-convex thermoprint roller by the elargol material thermoprint of antibacterial thermal insulating charcoal on biaxial tension OPP films, needed for being formed.
Wherein, in the step 4, base fabric unwinding tension is controlled in 5-10 MPa so as to which cloth cover is smooth, uniform tension in order, while OPP films want smooth distribution, tension force is in 10-15 MPa.
The production technology is by powdered carbon, silver powder is according to certain ratio and solvent, solid, bridging agent, accelerator carries out being mixed and made into sizing material, then by sizing material with concavo-convex hot stamping process thermoprint on OPP films, carry out half drying, so, powdered carbon, silver powder compound powder just forms a layer sizing layer on OPP films, then it is fitted in base fabric after maturation and is peeled off, sizing material so containing powdered carbon and silver powder compound powder can be embedded in base fabric, fastness is high, the whole cloth number of plies is few, sizing material is uniform, comfortable feel, it is difficult for drop-off, the function of powdered carbon and silver powder obtains the performance of maximum, whole base fabric is set to have functions that to reach heat accumulation thermal and antibacterial and deodouring.
Description of the drawings
With reference to the accompanying drawings and examples the present invention is further described.
Fig. 1 is the structural representation of the embodiment of the present invention;
Fig. 2 is the process chart of the present invention;
In accompanying drawing:1. base cloth layer;2. the antibacterial thermal insulating charcoal elargol bed of material;3. powdered carbon;4. silver powder;5.OPP film let off roll;6. glue groove;7. recessed(It is convex)Thermoprint roller;8. dandy roll;9. baking oven;10. base fabric let off roll;11. laminating hot-pressing rollers;12. laminating rubber rollers;13. ripening chambers;14.OPP film wind-up rolls;15. finished product wind-up rolls.
Specific embodiment
Below by specific embodiment, the present invention is described in further detail.
Such as Fig. 1, a kind of antibacterial thermal insulating charcoal silver fabric, including base cloth layer 1 and the antibacterial thermal insulating charcoal elargol bed of material 2 for being mixed with powdered carbon 3 and silver powder 4, the powdered carbon 3 and silver powder 4 are evenly distributed in the antibacterial thermal insulating charcoal elargol bed of material 2, its powdered carbon 3 and silver powder 4 are evenly distributed on the density in the antibacterial thermal insulating charcoal elargol bed of material 2 for 30-50%, with the discrete thermoprint of stamp mode on one of surface of base cloth layer 1, the antibacterial thermal insulating charcoal elargol bed of material 2 forms design by recessed to the antibacterial thermal insulating charcoal elargol bed of material 2(It is convex)Thermoprint roller 7 determines, the antibacterial thermal insulating charcoal elargol bed of material 2 is embedded in base cloth layer 1, the thickness that the antibacterial thermal insulating charcoal elargol bed of material 2 is embedded in base cloth layer 1 accounts for the 1/3-1/2 of base fabric thickness, the antibacterial thermal insulating charcoal elargol bed of material 2 is discrete in the form of design to be distributed on base cloth layer 1, its discrete spacing be 20- 50 mm, so make the fabric can ensure that fastness is good while having discoloration sun-screening function, and soft, good permeability is worn more comfortable.The base cloth layer 1 is 75D spandex fabrics.
Embodiment 1
As shown in Fig. 2 a kind of production technology of antibacterial thermal insulating charcoal silver fabric, including:
It is prepared by step one, antibacterial thermal insulating charcoal elargol material:Using 100 parts by weight of polyurethane solids, 5-10 weight portion bridging agents, 100-150 parts by weight solvent, 15-20 parts by weight of silver powder, 5-10 weight portion powdered carbons, 2-5 weight portion accelerator mixing and stirrings as antibacterial thermal insulating charcoal elargol material;
The step one antibacterial thermal insulating charcoal elargol material is prepared and comprised the following steps:
(1)Proportionally solvent is added in empty barrel, is started mixer and bucket internal solvent is stirred, stir speed (S.S.) is 200-500 rpm;
(2)Add 15-20 parts by weight of silver powder toward solvent in proportion, continue to stir 10-20min, make composition in bucket dispersed;
(3)Add 5-10 weight portion powdered carbons toward solvent in proportion, continue to stir 10-20min, make composition in bucket dispersed;
(4)Polyurethane resin is proportionally added into, and is 200-500rpm by stir speed (S.S.), persistently stir 10-30min;
(5)It is standby after stirring using bridging agent, accelerator is front proportionally added into.
Step 2, gluing:The antibacterial thermal insulating charcoal elargol material prepared in step one is poured in glue groove 6, the concavo-convex thermoprint roller 7 of different flower pattern or full width thermoprint is selected according to customer demand, concavo-convex thermoprint roller 7 is placed on into the inner rotation gluing of glue groove 6, start OPP films let off roll 5 simultaneously, biaxial tension OPP films, tension force is in 10 MPa, the smooth of OPP films is kept, recycles dandy roll 8 that the antibacterial thermal insulating charcoal elargol material thermoprint adhered on concavo-convex thermoprint roller 7 is formed the antibacterial thermal insulating charcoal elargol bed of material 2 of different designs or full width thermoprint on OPP films;
Step 3, half dries:Baking oven 9 is delivered to the step 2 antibacterial thermal insulating charcoal elargol bed of material 2, carries out heating half drying, oven temperature is controlled at 40-45 DEG C, and drying time is 10S.
Step 4, base fabric laminating:Base fabric 1 is unreeled, base fabric 1 and the antibacterial thermal insulating charcoal elargol bed of material 2 on OPP films form semi-finished product winding using hot-pressing roller 11 is fitted and laminating rubber rollers 12 are at the uniform velocity fitted;The laminating temperature control of hot-pressing roller 11 is at 100-120 DEG C, laminating speeds control is in 15-20m/min, laminate pressure is controlled in 6KG, the unwinding tension of base fabric 1 is controlled in 6 MPa, make its cloth cover smooth, uniform tension in order, while OPP films want smooth distribution, in 10 MPa, the depth of the embedded base fabric of sizing material accounts for the 1/4-1/3 of base fabric thickness to tension force.
Step 5, semi-finished product maturation:The semi-finished product that step 4 is formed, into the maturation of ripening chamber 12, maturation time 12H, maturation temperature is 65 DEG C.
Step 6, the semi-finished product after maturation are cooled down, and using OPP films wind-up roll 14 and finished product wind-up roll 15 is peeled off, peel off OPP films.
The production technology is by powdered carbon, silver powder is according to certain ratio and solvent, solid, bridging agent, accelerator carries out being mixed and made into antibacterial thermal insulating charcoal elargol material, then by sizing material with concavo-convex hot stamping process thermoprint on OPP films, carry out half drying, so, powdered carbon, silver powder compound powder just forms a layer sizing layer on OPP films, then it is fitted in base fabric after maturation and is peeled off, so contain powdered carbon, the sizing material of silver powder compound powder can be embedded in base fabric, fastness is high, the whole cloth number of plies is few, sizing material is uniform, comfortable feel, it is difficult for drop-off, powdered carbon, the function of silver powder compound powder obtains the performance of maximum, make whole base fabric that there is antibacterial and deodouring, heat accumulation thermal function.
Embodiment 2
The production technology of the antibacterial thermal insulating charcoal silver fabric in the embodiment is essentially identical with the technique in embodiment 1, and the sizing material proportioning parameter and technological parameter when simply producing has adjustment.
It is prepared by step one, antibacterial thermal insulating charcoal elargol material:Using 100 parts by weight of polyurethane solids, 5-10 weight portion bridging agents, 100-150 parts by weight solvent, 15-20 parts by weight of silver powder, 10-15 weight portion powdered carbons, 2-5 weight portion accelerator mixing and stirrings as antibacterial thermal insulating charcoal elargol material;
The step one antibacterial thermal insulating charcoal elargol material is prepared and comprised the following steps:
(1)Proportionally solvent is added in empty barrel, is started mixer and bucket internal solvent is stirred, stir speed (S.S.) is 200-500 rpm;
(2)Add 15-20 parts by weight of silver powder toward solvent in proportion, continue to stir 10-20min, make composition in bucket dispersed;
(3)Add 10-15 weight portion powdered carbons toward solvent in proportion, continue to stir 10-20min, make composition in bucket dispersed;
(4)Polyurethane resin is proportionally added into, and is 200-500rpm by stir speed (S.S.), persistently stir 10-30min;
(5)It is standby after stirring using bridging agent, accelerator is front proportionally added into.
Step 2, gluing:The antibacterial thermal insulating charcoal elargol material prepared in step one is poured in glue groove 6, the concavo-convex thermoprint roller 7 of different flower pattern or full width thermoprint is selected according to customer demand, concavo-convex thermoprint roller 7 is placed on into the inner rotation gluing of glue groove 6, start OPP films let off roll 5 simultaneously, biaxial tension OPP films, tension force is in 10 MPa, the smooth of OPP films is kept, recycles dandy roll 8 that the antibacterial thermal insulating charcoal elargol material thermoprint adhered on concavo-convex thermoprint roller 7 is formed the antibacterial thermal insulating charcoal elargol bed of material 2 of different designs or full width thermoprint on OPP films;
Step 3, half dries:Baking oven 9 is delivered to the step 2 antibacterial thermal insulating charcoal elargol bed of material 2, carries out heating half drying, oven temperature is controlled at 40-45 DEG C, and drying time is 15S.
Step 4, base fabric laminating:Base fabric 1 is unreeled, base fabric 1 and the antibacterial thermal insulating charcoal elargol bed of material 2 on OPP films form semi-finished product winding using hot-pressing roller 11 is fitted and laminating rubber rollers 12 are at the uniform velocity fitted;The laminating temperature control of hot-pressing roller 11 is at 100-120 DEG C, laminating speeds control is in 15-20m/min, laminate pressure is controlled in 6KG, the unwinding tension of base fabric 1 is controlled in 6 MPa, make its cloth cover smooth, uniform tension in order, while OPP films want smooth distribution, in 10 MPa, the depth of the embedded base fabric of sizing material accounts for the 1/4-1/3 of base fabric thickness to tension force.
Step 5, semi-finished product maturation:The semi-finished product that step 4 is formed, into the maturation of ripening chamber 12, maturation time 12H, maturation temperature is 60 DEG C.
Step 6, the semi-finished product after maturation are cooled down, and using OPP films wind-up roll 14 and finished product wind-up roll 15 is peeled off, peel off OPP films.
The production technology is by powdered carbon, silver powder is according to certain ratio and solvent, solid, bridging agent, accelerator carries out being mixed and made into antibacterial thermal insulating charcoal elargol material, then by sizing material with concavo-convex hot stamping process thermoprint on OPP films, carry out half drying, so, powdered carbon, silver powder compound powder just forms a layer sizing layer on OPP films, then it is fitted in base fabric after maturation and is peeled off, so contain powdered carbon, the sizing material of silver powder compound powder can be embedded in base fabric, fastness is high, the whole cloth number of plies is few, sizing material is uniform, comfortable feel, it is difficult for drop-off, powdered carbon, the function of silver powder compound powder obtains the performance of maximum, make whole base fabric that there is antibacterial and deodouring, heat accumulation thermal function.
Powdered carbon, silver powder compound powder are carried out being mixed and made into antibacterial thermal insulating charcoal elargol material by the production technology according to certain ratio and solvent, solid, bridging agent, accelerator. and better than the heat accumulation thermal effect of real row 1, powdered carbon ratio is more than the density of real row 1.
Through each embodiment production antibacterial thermal insulating charcoal silver fabric after testing after obtain each functional parameter such as following table:
As can be seen from the above table the functional result of embodiment 2 is better than embodiment 1.

Claims (7)

1. the preparation technology of a kind of antibacterial thermal insulating charcoal silver fabric, including:
It is prepared by step one, antibacterial thermal insulating charcoal elargol material:Using 100 parts by weight of polyurethane solids, 5-10 weight portion bridging agents, 100-150 parts by weight solvent, 15-20 parts by weight of silver powder, 10-15 weight portion powdered carbons, 2-5 weight portion accelerator mixing and stirrings as antibacterial thermal insulating charcoal elargol material;
Step 2, gluing:The sizing material prepared in step one print is scalded into the formation antibacterial thermal insulating charcoal elargol bed of material on OPP films;
Step 3, half dries:The step 2 antibacterial thermal insulating charcoal elargol bed of material is carried out to heat half drying, oven temperature is 40-45 DEG C;
Step 4, base fabric laminating:Base fabric is unreeled, the speed such as base fabric and sizing material of OPP films fits to form semi-finished product winding, at 100-120 DEG C, in 15-20m/min, laminate pressure is 6-7KG to laminating speeds control to laminating wheel temperature control;
Step 5, semi-finished product maturation:Maturation time 12H, maturation temperature is 65 DEG C;
Step 6, the semi-finished product after maturation are cooled down, and peel off mould release membrance.
2. the preparation technology of a kind of antibacterial thermal insulating charcoal silver fabric as claimed in claim 1, it is characterised in that:Antibacterial thermal insulating charcoal elargol material is prepared and comprised the following steps in the step one:
(1)Proportionally solvent is added in empty barrel, is started mixer and bucket internal solvent is stirred, stir speed (S.S.) is 200-500 rpm;
(2)Add 15-20 parts by weight of silver powder toward solvent in proportion, continue to stir 10-20min, make composition in bucket dispersed;
(3)Add 10-15 weight portion powdered carbons toward solvent in proportion, continue to stir 10-20min, make composition in bucket dispersed;
(4)Polyurethane resin is proportionally added into, and is 200-500rpm by stir speed (S.S.), persistently stir 10-30min;
(5)It is standby after stirring using bridging agent, accelerator is front proportionally added into.
3. the preparation technology of a kind of antibacterial thermal insulating charcoal silver fabric as claimed in claim 1, it is characterised in that:In the step 2, antibacterial thermal insulating charcoal elargol material is poured in sizing material groove, the concavo-convex thermoprint roller of design needed for preparing, by antibacterial thermal insulating charcoal silver fabric design of the concavo-convex thermoprint roller by the elargol material thermoprint of antibacterial thermal insulating charcoal on biaxial tension OPP films, needed for being formed.
4. a kind of antibacterial thermal insulating charcoal silver fabric, including base cloth layer, it is characterised in that:Also include antibacterial thermal insulating charcoal silver fabric compound layer, the antibacterial thermal insulating charcoal elargol bed of material is with the discrete thermoprint of design shape and protrudes on base cloth layer, dispersed in the sensitization discoloration compound layer to have powdered carbon and silver powder.
5. a kind of Photochromic fabric as claimed in claim 4, it is characterised in that:Antibacterial thermal insulating charcoal elargol bed of material integral thickness is 20-30 μm, and the thickness of antibacterial thermal insulating charcoal elargol bed of material protrusion fabric is 5-15 μm.
6. a kind of antibacterial thermal insulating charcoal silver fabric as claimed in claim 7, it is characterised in that:The antibacterial thermal insulating charcoal elargol bed of material protrudes the design for being shaped as stereochemical structure of base cloth layer, and the design includes ramage, animal pattern, character pattern, monogram, scenery with hills and waters pattern etc. those skilled in the art will envision that the mixed pattern of one or two or more kinds in the pattern for obtaining.
7. a kind of Photochromic fabric as claimed in claim 6, it is characterised in that:Base cloth layer is 75D spandex fabrics.
CN201510723367.0A 2015-10-29 2015-10-29 Antibacterial thermal carbon silver fabric and preparation technology thereof Pending CN106617421A (en)

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Application Number Priority Date Filing Date Title
CN201510723367.0A CN106617421A (en) 2015-10-29 2015-10-29 Antibacterial thermal carbon silver fabric and preparation technology thereof

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Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN112192969A (en) * 2020-09-14 2021-01-08 浙江周氏新材料股份有限公司 Production method of antibacterial and warm-keeping composite fabric
CN115139634A (en) * 2022-04-01 2022-10-04 成工业制衣(苏州)有限公司 High-temperature hot stamping integrated automatic processing equipment

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN112192969A (en) * 2020-09-14 2021-01-08 浙江周氏新材料股份有限公司 Production method of antibacterial and warm-keeping composite fabric
CN115139634A (en) * 2022-04-01 2022-10-04 成工业制衣(苏州)有限公司 High-temperature hot stamping integrated automatic processing equipment

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Application publication date: 20170510