CN106614667A - Corn seed treating agent containing probenazole and fipronil - Google Patents

Corn seed treating agent containing probenazole and fipronil Download PDF

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Publication number
CN106614667A
CN106614667A CN201611160765.7A CN201611160765A CN106614667A CN 106614667 A CN106614667 A CN 106614667A CN 201611160765 A CN201611160765 A CN 201611160765A CN 106614667 A CN106614667 A CN 106614667A
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CN
China
Prior art keywords
probenazole
seed
ethiprole
agent
fipronil
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201611160765.7A
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Chinese (zh)
Inventor
邓付圆
申妍
张艳辉
吴宝国
梁进旭
韦恒友
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Guangxi Nanning Yitu Biotechnology Co Ltd
Original Assignee
Guangxi Nanning Yitu Biotechnology Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Guangxi Nanning Yitu Biotechnology Co Ltd filed Critical Guangxi Nanning Yitu Biotechnology Co Ltd
Priority to CN201611160765.7A priority Critical patent/CN106614667A/en
Publication of CN106614667A publication Critical patent/CN106614667A/en
Pending legal-status Critical Current

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Classifications

    • AHUMAN NECESSITIES
    • A01AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01NPRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N47/00Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid
    • A01N47/02Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid the carbon atom having no bond to a nitrogen atom
    • AHUMAN NECESSITIES
    • A01AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01CPLANTING; SOWING; FERTILISING
    • A01C1/00Apparatus, or methods of use thereof, for testing or treating seed, roots, or the like, prior to sowing or planting
    • A01C1/06Coating or dressing seed
    • AHUMAN NECESSITIES
    • A01AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01NPRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N25/00Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests
    • A01N25/02Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests containing liquids as carriers, diluents or solvents
    • A01N25/04Dispersions, emulsions, suspoemulsions, suspension concentrates or gels
    • AHUMAN NECESSITIES
    • A01AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01NPRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N43/00Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
    • A01N43/72Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with nitrogen atoms and oxygen or sulfur atoms as ring hetero atoms
    • A01N43/80Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with nitrogen atoms and oxygen or sulfur atoms as ring hetero atoms five-membered rings with one nitrogen atom and either one oxygen atom or one sulfur atom in positions 1,2

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  • Life Sciences & Earth Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Environmental Sciences (AREA)
  • General Health & Medical Sciences (AREA)
  • Dentistry (AREA)
  • Agronomy & Crop Science (AREA)
  • Pest Control & Pesticides (AREA)
  • Plant Pathology (AREA)
  • Engineering & Computer Science (AREA)
  • Wood Science & Technology (AREA)
  • Zoology (AREA)
  • Dispersion Chemistry (AREA)
  • Chemical & Material Sciences (AREA)
  • Toxicology (AREA)
  • Soil Sciences (AREA)
  • Agricultural Chemicals And Associated Chemicals (AREA)

Abstract

The invention relates to a corn seed treating agent containing probenazole and fipronil. The effective component of the corn seed treating agent is prepared from the following components by weight percents: 2%-10% of probenazole and 1%-6% of fipronil, wherein the weight ratio of the probenazole to the fipronil is (2-5):(1-3). The components work together, and the disinsection and disease-prevention effects of the mixture are obviously improved in comparison with those of a single agent.

Description

A kind of corn seed inorganic agent containing probenazole and ethiprole
Technical field
The present invention relates to agricultural technology field, specifically related to a kind of process of the corn seed containing probenazole and ethiprole Agent.
Background technology
In modern agricultural production, seed chemicals treatment is preventing and treating subterranean pest-insect and crops soil biography, seed-borne disease economy One of easy method.
Probenazole, English is general entitled:Probenazole, is Japanese Meiji Seika Kaisha, Ltd.'s exploitation A kind of inducing immunity bactericide, by exciting plant itself to immunity (resistance) reaction of disease protection effect is realized, is led to Plant root absorption is crossed, and relatively rapidly infiltration is conducted to plant each several part.Paddy rice is processed by probenazole, can be promoted Root Absorption, and relatively quickly infiltration conduction to plant each several part, cover crop is by Pyricularia oryzae and rhizoctonia solani Infect;Corn is processed by probenazole, the harm of base rot disease and head smut can be effectively prevented.
Ethiprole, English name is:Fiproni l, are that a kind of Phenylpyrazole insecticides, insecticidal spectrum are wide, to insect with Based on stomach poison function, have concurrently and tag and certain systemic action, its mechanism of action is to hinder the control of insect GABA Chloride metabolism, therefore have very high desinsection to important pests such as aphid, leafhopper, plant hopper, lepidopterous larvae, flies and coleopteras Activity, to crop without poisoning.The medicament can impose on soil, also can foliar spray.Impose on soil can effectively prevent and treat corn root leaf A, Wireworm and cutworm.During foliage spray, there is high-level preventive effect to diamondback moth, cabbage butterfly, rice thripses etc., and the lasting period is long.
In modern agriculture, it is preventing and treating subterranean pest-insect and soil biography, seed-borne disease that chemicals treatment is carried out to seed using seed coat agent One of method of economical and convenient.Seed coat agent is a kind of for crop or other plant Seed Treatment, the agriculture with film forming characteristics Medicine preparation, it can solidify to form the film of referred to as kind clothing in the surface of the seed.Seed coat agent in soil water swelling and be not dissolved, Moisture and air of the seed normally needed for germination is allowed to pass through, the material such as contained agricultural chemicals and seed manure slowly discharges, and can kill Subterranean pest-insect, prevention seedling stage insect and preventing and treating sprout term disease, improve percentage of seedgermination, promote seedling healthy growth so as to reach, Reduce effect of seed consumption.
The seed coat agent that at present Spread in China is used is various in style, but mostly there are problems that, such as Likeming Gel, it is suitable happy when, The single functions, only prophylaxis effect such as seed dressing pair, and technical sophistication is used, it is dangerous to crop and long-term clear, many to cough up bacterium The clever seed treatment for main sterilization component of bacterium, the resistance that germ produces is larger, therefore it is anti-with insect prevention to be badly in need of exploitation one kind Disease acts on and has the corn seed coating agent of better effects.
The content of the invention
The technical problem to be solved in the present invention is, a kind of corn seed inorganic agent containing probenazole and ethiprole, energy Subterranean pest-insect and Maize at Seedling Stage insect are effectively prevented and treated, while the harm of Causal Organism of Maize Basal Stalk and head smut can be controlled effectively.
The present invention is adopted the technical scheme that:A kind of corn seed inorganic agent containing probenazole and ethiprole, effectively Composition is made up of probenazole and ethiprole, and the weight ratio of probenazole and ethiprole is 2-5:1-3, preferred phenyl allyloxy The weight ratio of thiazole and ethiprole is 3:1.
Described corn seed inorganic agent, percentage by weight of the probenazole in inorganic agent be 2-10%, ethiprole Percentage by weight in inorganic agent is 1-6%.
The seed treatment of the present invention is prepared into agriculturally acceptable suspension seed-coating agent, and the adjuvant of addition includes wetting Dispersant, film forming agent, colouring agent, thickener, antifreezing agent, defoamer or other be beneficial to that active ingredient is stable in the formulation and medicine The material that effect is played.
Preparation method of the present invention is:By probenazole and ethiprole through air-flow crushing, after by mixture with wetting point After powder, film forming agent, colouring agent, thickener, antifreezing agent, defoamer and water are completely dissolved, sand mill grinding 2-4 is put in proportion Hour, make particle diameter all below 5 μm, filtration can be prepared by product.
The present invention has advantages below and significant technique effect:
1st, the present invention is with probenazole and ethiprole as active ingredient, it is adaptable to corn seed process, can effectively prevent and treat Causal Organism of Maize Basal Stalk, head smut, gall smut and the diseases such as the rough dwarf disease that causes are propagated by small brown rice planthopper, while can effectively prevent and treat The harm of the subterranean pest-insect such as the ground such as aphid, thrips and mole cricket, grub, cutworm, is conducive to improving planting percent.
2nd, composition Synergistic of the invention, mixed agent compares with single dose, and disinsection prophylaxis effect is significantly improved.
3rd, suspension seed-coating agent of the present invention is easy to use, when processing seed, both also can manually be grasped with machinery seed dressing Make, the needs of different user can be met.
Specific embodiment
Technical scheme and technique effect are described further below by way of specific embodiment, institute of the present invention The percentage stated is weight percentage.
According to the present invention, according to controlling object, a situation arises determines suitable consumption, and usual formulation rate is seed coat agent and seed Weight ratio be 1:50-100.
First, embodiment is prepared
Embodiment 1:4% probenazole ethiprole suspension seed-coating agent
Formula:Each component content (by weight), probenazole 3%, ethiprole 1%, NPE 3%th, dodecyl sodium sulfate (dispersant) 8%, benzenediol (stabilizer) 2%, xanthans (thickener) 0.2%, n-octyl alcohol (disappears Infusion) 1%, urea (antifreeze) 2%, basic rhodamine (colouring agent) 0.5%, add water and complement to 100%.
Embodiment 2:5% probenazole ethiprole suspension seed-coating agent
Formula:Each component content (by weight), probenazole 2%, ethiprole 3%, agriculture breast 602 (emulsifying agent) 2%, Sodium lignin sulfonate (dispersant) 5%, benzenediol (stabilizer) 2%, xanthans (thickener) 0.5%, silicone oil (defoamer) 1%th, urea (antifreeze) 2%, basic rhodamine (colouring agent) 0.5%, adds water and complements to 100%.
Embodiment 3:3% probenazole ethiprole suspension seed-coating agent
Formula:Each component content (by weight), probenazole 2%, ethiprole 1%, agriculture breast 602 (emulsifying agent) 2%, Dodecyl sodium sulfate (dispersant) 10%, benzenediol (stabilizer) 2%, sodium carboxymethylcellulose (film forming agent) 3%, n-octyl alcohol (defoamer) 1%, ethylene glycol (antifreeze) 2%, basic rhodamine (colouring agent) 0.5%, adds water and complements to 100%.
Embodiment 4:7% probenazole ethiprole suspension seed-coating agent
Formula:Each component content (by weight), probenazole 5%, ethiprole 2%, agriculture breast 602 (emulsifying agent) 2%, Dodecyl sodium sulfate (dispersant) 8%, benzenediol (stabilizer) 2%, xanthans (thickener) 0.2%, n-octyl alcohol (froth breaking Agent) 1%, urea (antifreeze) 2%, basic rhodamine (colouring agent) 0.5%, add water and complement to 100%.
Embodiment 5:12% probenazole ethiprole suspension seed-coating agent
Formula:Each component content (by weight), probenazole 10%, ethiprole 2%, NPE 2%th, dodecyl sodium sulfate (dispersant) 10%, benzenediol (stabilizer) 2%, sodium carboxymethylcellulose (film forming agent) 3%, just Octanol (defoamer) 2%, ethylene glycol (antifreeze) 2%, basic rhodamine (colouring agent) 0.5%, adds water and complements to 100%.
The preparation method of above-described embodiment 1-5 is to weigh probenazole and ethiprole by formula, through air-flow crushing, Mixture is well mixed with other components afterwards, 3-4 hours of milling in sand mill make particle diameter all below 5 μm.
2nd, BIOLOGICAL ACTIVITY EXAMPLES
Embodiment 1:The field control effectiveness test of the suspension seed-coating agent of ethiprole containing probenazole
Experimental design:Test is carried out in June, 2015 in the peasant household farmland of Nanning suburbs one, to prepare embodiment 1- The preparation of 3 gained is test group 1-3#, with 10% probenazole suspension seed-coating agent as control group 1#, with the suspension of 10% ethiprole Seed coat agent is control group 2#, while arranging one does not carry out seed pelleting for blank (CK).It is each process in dosing and Medicament is as shown in the table, test corn variety be Zheng Dan 958, in the leaf of corn three wholeheartedly when carry out observation measurement, each suspended seed coating Agent Cotton seeds are as shown in the table to the Pest management situation of Maize at Seedling Stage:
The suspension seed-coating agent of ethiprole containing probenazole of table 1 is used for the field control effectiveness test of corn seed dressing
As shown in Table 1, corn seed inorganic agent of the invention is being had using probenazole and the rational mixture of ethiprole In the case that effect Ingredient Amount is more relatively fewer than each single dose, prevention and treatment range or drug effect are higher than each single dose.Meanwhile, from result of the test Understand, another active component that this synergistic results are not due to be added directly acts on disease or insect pest obtains, but Due to interacting after two kinds of active components compounding, the effect of prevention and elimination of disease and pests each other is enhanced, advantageously reduce each single dose Dosage, reduces agricultural cost.

Claims (4)

1. a kind of corn seed inorganic agent containing probenazole and ethiprole, it is characterised in that active ingredient is by phenyl allyloxy thiophene Azoles and ethiprole are constituted, and the weight ratio of probenazole and ethiprole is 2-5:1-3.
2. seed treatment according to claim 1, it is characterised in that the weight ratio of probenazole and ethiprole is 3: 1。
3. seed treatment according to claim 1 and 2, it is characterised in that the percentage by weight of probenazole is 2- 10%, the percentage by weight of ethiprole is 1-6%.
4. the seed treatment according to claim 1-3 any one, it is characterised in that seed treatment is prepared into agricultural Upper acceptable suspension seed-coating agent.
CN201611160765.7A 2016-12-15 2016-12-15 Corn seed treating agent containing probenazole and fipronil Pending CN106614667A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201611160765.7A CN106614667A (en) 2016-12-15 2016-12-15 Corn seed treating agent containing probenazole and fipronil

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201611160765.7A CN106614667A (en) 2016-12-15 2016-12-15 Corn seed treating agent containing probenazole and fipronil

Publications (1)

Publication Number Publication Date
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Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101605461A (en) * 2007-02-06 2009-12-16 巴斯夫欧洲公司 Pesticide combination
CN103079404A (en) * 2010-08-11 2013-05-01 住友化学株式会社 Composition for controlling harmful arthropods and method for controlling harmful arthropods

Patent Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101605461A (en) * 2007-02-06 2009-12-16 巴斯夫欧洲公司 Pesticide combination
CN103079404A (en) * 2010-08-11 2013-05-01 住友化学株式会社 Composition for controlling harmful arthropods and method for controlling harmful arthropods

Non-Patent Citations (2)

* Cited by examiner, † Cited by third party
Title
余本水主编: "《高毒农药替代品应用技术指南》", 31 October 2008, 中国农业出版社 *
无: "日本Hokko公司2010年农化品销售上升18%", 《农药市场信息》 *

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