CN106614657B - 含有吡丙醚及苦参碱的组合物及应用 - Google Patents
含有吡丙醚及苦参碱的组合物及应用 Download PDFInfo
- Publication number
- CN106614657B CN106614657B CN201611172206.8A CN201611172206A CN106614657B CN 106614657 B CN106614657 B CN 106614657B CN 201611172206 A CN201611172206 A CN 201611172206A CN 106614657 B CN106614657 B CN 106614657B
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- China
- Prior art keywords
- nylar
- matrine
- composition
- pest
- oxymatrine
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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Links
- NHDHVHZZCFYRSB-UHFFFAOYSA-N pyriproxyfen Chemical compound C=1C=CC=NC=1OC(C)COC(C=C1)=CC=C1OC1=CC=CC=C1 NHDHVHZZCFYRSB-UHFFFAOYSA-N 0.000 title claims abstract description 59
- ZSBXGIUJOOQZMP-UHFFFAOYSA-N Isomatrine Natural products C1CCC2CN3C(=O)CCCC3C3C2N1CCC3 ZSBXGIUJOOQZMP-UHFFFAOYSA-N 0.000 title claims abstract description 51
- 229930014456 matrine Natural products 0.000 title claims abstract description 51
- ZSBXGIUJOOQZMP-JLNYLFASSA-N Matrine Chemical compound C1CC[C@H]2CN3C(=O)CCC[C@@H]3[C@@H]3[C@H]2N1CCC3 ZSBXGIUJOOQZMP-JLNYLFASSA-N 0.000 title claims abstract description 45
- 239000000203 mixture Substances 0.000 title claims abstract description 34
- 241000607479 Yersinia pestis Species 0.000 claims abstract description 23
- 241001414989 Thysanoptera Species 0.000 claims abstract description 22
- 241000255925 Diptera Species 0.000 claims abstract description 11
- 241000258937 Hemiptera Species 0.000 claims abstract description 10
- 241000238631 Hexapoda Species 0.000 claims abstract description 7
- 239000004530 micro-emulsion Substances 0.000 claims abstract description 7
- 241000254173 Coleoptera Species 0.000 claims abstract description 4
- 241000255777 Lepidoptera Species 0.000 claims abstract description 4
- 239000000375 suspending agent Substances 0.000 claims abstract description 4
- 239000004562 water dispersible granule Substances 0.000 claims abstract description 4
- 239000004563 wettable powder Substances 0.000 claims abstract description 3
- 239000008187 granular material Substances 0.000 claims abstract 2
- 229930015582 oxymatrine Natural products 0.000 claims description 16
- XVPBINOPNYFXID-JARXUMMXSA-N 85u4c366qs Chemical compound C([C@@H]1CCC[N@+]2(CCC[C@H]3[C@@H]21)[O-])N1[C@@H]3CCCC1=O XVPBINOPNYFXID-JARXUMMXSA-N 0.000 claims description 14
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 11
- 241000257159 Musca domestica Species 0.000 claims description 10
- 239000003795 chemical substances by application Substances 0.000 claims description 10
- 229930013930 alkaloid Natural products 0.000 claims description 6
- 241001124076 Aphididae Species 0.000 claims description 5
- 150000003797 alkaloid derivatives Chemical class 0.000 claims description 5
- 239000008267 milk Substances 0.000 claims 1
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- 238000012545 processing Methods 0.000 abstract description 3
- 230000000694 effects Effects 0.000 description 19
- 239000003814 drug Substances 0.000 description 14
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- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 9
- -1 alkali Natural products 0.000 description 9
- 230000002195 synergetic effect Effects 0.000 description 9
- 239000007921 spray Substances 0.000 description 7
- 240000008067 Cucumis sativus Species 0.000 description 6
- 235000010799 Cucumis sativus var sativus Nutrition 0.000 description 6
- 238000013329 compounding Methods 0.000 description 6
- 238000000034 method Methods 0.000 description 6
- 235000004936 Bromus mango Nutrition 0.000 description 5
- 241001093152 Mangifera Species 0.000 description 5
- 235000014826 Mangifera indica Nutrition 0.000 description 5
- 239000005927 Pyriproxyfen Substances 0.000 description 5
- 235000009184 Spondias indica Nutrition 0.000 description 5
- 241000219977 Vigna Species 0.000 description 5
- 235000010726 Vigna sinensis Nutrition 0.000 description 5
- 230000002265 prevention Effects 0.000 description 5
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 4
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 3
- 229940079593 drug Drugs 0.000 description 3
- 238000003756 stirring Methods 0.000 description 3
- DMAXMXPDVWTIRV-UHFFFAOYSA-N 2-(2-phenylethyl)phenol Chemical compound OC1=CC=CC=C1CCC1=CC=CC=C1 DMAXMXPDVWTIRV-UHFFFAOYSA-N 0.000 description 2
- 241001425384 Cacopsylla pyricola Species 0.000 description 2
- 241000144210 Culex pipiens pallens Species 0.000 description 2
- 206010059866 Drug resistance Diseases 0.000 description 2
- 241000196324 Embryophyta Species 0.000 description 2
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 2
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 2
- 239000003513 alkali Substances 0.000 description 2
- 210000000481 breast Anatomy 0.000 description 2
- 239000006229 carbon black Substances 0.000 description 2
- 230000007423 decrease Effects 0.000 description 2
- YDEXUEFDPVHGHE-GGMCWBHBSA-L disodium;(2r)-3-(2-hydroxy-3-methoxyphenyl)-2-[2-methoxy-4-(3-sulfonatopropyl)phenoxy]propane-1-sulfonate Chemical compound [Na+].[Na+].COC1=CC=CC(C[C@H](CS([O-])(=O)=O)OC=2C(=CC(CCCS([O-])(=O)=O)=CC=2)OC)=C1O YDEXUEFDPVHGHE-GGMCWBHBSA-L 0.000 description 2
- 230000000857 drug effect Effects 0.000 description 2
- 239000011521 glass Substances 0.000 description 2
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- 230000003285 pharmacodynamic effect Effects 0.000 description 2
- 239000000843 powder Substances 0.000 description 2
- 238000002360 preparation method Methods 0.000 description 2
- 230000008569 process Effects 0.000 description 2
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- 231100000419 toxicity Toxicity 0.000 description 2
- 230000001988 toxicity Effects 0.000 description 2
- 230000001018 virulence Effects 0.000 description 2
- FFJCNSLCJOQHKM-CLFAGFIQSA-N (z)-1-[(z)-octadec-9-enoxy]octadec-9-ene Chemical compound CCCCCCCC\C=C/CCCCCCCCOCCCCCCCC\C=C/CCCCCCCC FFJCNSLCJOQHKM-CLFAGFIQSA-N 0.000 description 1
- 241000254127 Bemisia tabaci Species 0.000 description 1
- 241001674044 Blattodea Species 0.000 description 1
- 241000207199 Citrus Species 0.000 description 1
- 241000819999 Nymphes Species 0.000 description 1
- 241001674048 Phthiraptera Species 0.000 description 1
- 241000500437 Plutella xylostella Species 0.000 description 1
- 229920003171 Poly (ethylene oxide) Polymers 0.000 description 1
- AAGFPTSOPGCENQ-UHFFFAOYSA-N Sophocarpin I Natural products C1CCC2CN3C(=O)C=CCC3C3C2N1CCC3 AAGFPTSOPGCENQ-UHFFFAOYSA-N 0.000 description 1
- IGXQFUGORDJEST-UHFFFAOYSA-N Sophocarpine Natural products O=C1C=CCC2C3CCCC4CCCC(CN12)C34 IGXQFUGORDJEST-UHFFFAOYSA-N 0.000 description 1
- 244000046101 Sophora japonica Species 0.000 description 1
- 235000010586 Sophora japonica Nutrition 0.000 description 1
- 241000256247 Spodoptera exigua Species 0.000 description 1
- 241000985245 Spodoptera litura Species 0.000 description 1
- 244000269722 Thea sinensis Species 0.000 description 1
- OMOVVBIIQSXZSZ-UHFFFAOYSA-N [6-(4-acetyloxy-5,9a-dimethyl-2,7-dioxo-4,5a,6,9-tetrahydro-3h-pyrano[3,4-b]oxepin-5-yl)-5-formyloxy-3-(furan-3-yl)-3a-methyl-7-methylidene-1a,2,3,4,5,6-hexahydroindeno[1,7a-b]oxiren-4-yl] 2-hydroxy-3-methylpentanoate Chemical compound CC12C(OC(=O)C(O)C(C)CC)C(OC=O)C(C3(C)C(CC(=O)OC4(C)COC(=O)CC43)OC(C)=O)C(=C)C32OC3CC1C=1C=COC=1 OMOVVBIIQSXZSZ-UHFFFAOYSA-N 0.000 description 1
- 229940009868 aluminum magnesium silicate Drugs 0.000 description 1
- WMGSQTMJHBYJMQ-UHFFFAOYSA-N aluminum;magnesium;silicate Chemical compound [Mg+2].[Al+3].[O-][Si]([O-])([O-])[O-] WMGSQTMJHBYJMQ-UHFFFAOYSA-N 0.000 description 1
- 239000000440 bentonite Substances 0.000 description 1
- 229910000278 bentonite Inorganic materials 0.000 description 1
- SVPXDRXYRYOSEX-UHFFFAOYSA-N bentoquatam Chemical compound O.O=[Si]=O.O=[Al]O[Al]=O SVPXDRXYRYOSEX-UHFFFAOYSA-N 0.000 description 1
- 229940077388 benzenesulfonate Drugs 0.000 description 1
- 238000009395 breeding Methods 0.000 description 1
- 230000001488 breeding effect Effects 0.000 description 1
- 235000020971 citrus fruits Nutrition 0.000 description 1
- 230000000295 complement effect Effects 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 238000004590 computer program Methods 0.000 description 1
- 238000009833 condensation Methods 0.000 description 1
- 230000005494 condensation Effects 0.000 description 1
- 239000000470 constituent Substances 0.000 description 1
- 238000001816 cooling Methods 0.000 description 1
- 230000006378 damage Effects 0.000 description 1
- 238000011161 development Methods 0.000 description 1
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- 235000013399 edible fruits Nutrition 0.000 description 1
- 238000003912 environmental pollution Methods 0.000 description 1
- 235000019441 ethanol Nutrition 0.000 description 1
- 238000002474 experimental method Methods 0.000 description 1
- 238000000605 extraction Methods 0.000 description 1
- NVVZQXQBYZPMLJ-UHFFFAOYSA-N formaldehyde;naphthalene-1-sulfonic acid Chemical compound O=C.C1=CC=C2C(S(=O)(=O)O)=CC=CC2=C1 NVVZQXQBYZPMLJ-UHFFFAOYSA-N 0.000 description 1
- 238000009472 formulation Methods 0.000 description 1
- 238000000227 grinding Methods 0.000 description 1
- 239000003630 growth substance Substances 0.000 description 1
- 238000001802 infusion Methods 0.000 description 1
- 239000004615 ingredient Substances 0.000 description 1
- 239000002917 insecticide Substances 0.000 description 1
- 238000011835 investigation Methods 0.000 description 1
- 239000002950 juvenile hormone derivative Substances 0.000 description 1
- 230000002045 lasting effect Effects 0.000 description 1
- 238000002386 leaching Methods 0.000 description 1
- 231100000518 lethal Toxicity 0.000 description 1
- 231100000636 lethal dose Toxicity 0.000 description 1
- 231100000053 low toxicity Toxicity 0.000 description 1
- 230000010534 mechanism of action Effects 0.000 description 1
- 239000003595 mist Substances 0.000 description 1
- 238000002156 mixing Methods 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 230000003020 moisturizing effect Effects 0.000 description 1
- QMGGMESMCJCABO-UHFFFAOYSA-N n-oxysophocarpine Chemical compound C12C3CCC[N+]2([O-])CCCC1CN1C3CC=CC1=O QMGGMESMCJCABO-UHFFFAOYSA-N 0.000 description 1
- 239000003960 organic solvent Substances 0.000 description 1
- 239000000575 pesticide Substances 0.000 description 1
- 239000002574 poison Substances 0.000 description 1
- 231100000614 poison Toxicity 0.000 description 1
- 230000003449 preventive effect Effects 0.000 description 1
- 238000003672 processing method Methods 0.000 description 1
- 230000009467 reduction Effects 0.000 description 1
- 239000011734 sodium Substances 0.000 description 1
- 229910052708 sodium Inorganic materials 0.000 description 1
- AAGFPTSOPGCENQ-JLNYLFASSA-N sophocarpine Chemical compound C1CC[C@H]2CN3C(=O)C=CC[C@@H]3[C@@H]3[C@H]2N1CCC3 AAGFPTSOPGCENQ-JLNYLFASSA-N 0.000 description 1
- 210000002784 stomach Anatomy 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 239000000725 suspension Substances 0.000 description 1
- FWQHRZXEQNUCSY-UHFFFAOYSA-N tert-butyl N-[2-(ethoxycarbonylamino)-5-[(4-fluorophenyl)methyl-prop-2-ynylamino]phenyl]carbamate Chemical compound CCOC(=O)NC1=C(C=C(C=C1)N(CC#C)CC2=CC=C(C=C2)F)NC(=O)OC(C)(C)C FWQHRZXEQNUCSY-UHFFFAOYSA-N 0.000 description 1
- 238000012546 transfer Methods 0.000 description 1
Classifications
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
- A01N43/90—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having two or more relevant hetero rings, condensed among themselves or with a common carbocyclic ring system
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
- A01N43/34—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one nitrogen atom as the only ring hetero atom
- A01N43/40—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one nitrogen atom as the only ring hetero atom six-membered rings
Landscapes
- Life Sciences & Earth Sciences (AREA)
- Agronomy & Crop Science (AREA)
- Pest Control & Pesticides (AREA)
- Plant Pathology (AREA)
- Health & Medical Sciences (AREA)
- Engineering & Computer Science (AREA)
- Dentistry (AREA)
- General Health & Medical Sciences (AREA)
- Wood Science & Technology (AREA)
- Zoology (AREA)
- Environmental Sciences (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
Abstract
Description
药剂名称 | LC<sub>50</sub>(ppm) | ATI | TTI | CTC |
吡丙醚 | 25.3742 | 100 | - | - |
苦参碱 | 84.2627 | 30.11 | - | - |
吡丙醚:苦参碱=10:1 | 22.4224 | 113.16 | 93.65 | 120.84 |
吡丙醚:苦参碱=6:1 | 18.1381 | 139.89 | 90.02 | 155.40 |
吡丙醚:苦参碱=3:1 | 17.4563 | 145.36 | 82.53 | 176.13 |
吡丙醚:苦参碱=1:1 | 28.4337 | 89.24 | 65.06 | 137.17 |
吡丙醚:苦参碱=1:3 | 42.5612 | 59.62 | 47.58 | 125.30 |
吡丙醚:苦参碱=1:10 | 56.8647 | 44.62 | 36.46 | 122.39 |
药剂名称 | LC<sub>50</sub>(ppm) | ATI | TTI | CTC |
吡丙醚 | 18.2531 | 100 | - | - |
氧化苦参碱 | 56.1417 | 32.51 | - | - |
吡丙醚:氧化苦参碱=10:1 | 16.1628 | 112.93 | 93.86 | 120.32 |
吡丙醚:氧化苦参碱=6:1 | 15.2408 | 119.76 | 90.36 | 132.54 |
吡丙醚:氧化苦参碱=3:1 | 15.2557 | 119.65 | 83.13 | 143.93 |
吡丙醚:氧化苦参碱=1:1 | 19.3691 | 94.24 | 66.26 | 142.22 |
吡丙醚:氧化苦参碱=1:3 | 28.0426 | 65.09 | 49.38 | 131.82 |
吡丙醚:氧化苦参碱=1:10 | 38.2557 | 47.71 | 38.65 | 123.45 |
Claims (7)
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
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CN201611172206.8A CN106614657B (zh) | 2016-12-17 | 2016-12-17 | 含有吡丙醚及苦参碱的组合物及应用 |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
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CN201611172206.8A CN106614657B (zh) | 2016-12-17 | 2016-12-17 | 含有吡丙醚及苦参碱的组合物及应用 |
Publications (2)
Publication Number | Publication Date |
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CN106614657A CN106614657A (zh) | 2017-05-10 |
CN106614657B true CN106614657B (zh) | 2019-01-22 |
Family
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Family Applications (1)
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CN201611172206.8A Active CN106614657B (zh) | 2016-12-17 | 2016-12-17 | 含有吡丙醚及苦参碱的组合物及应用 |
Country Status (1)
Country | Link |
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CN (1) | CN106614657B (zh) |
Citations (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN101690495A (zh) * | 2009-08-28 | 2010-04-07 | 南通功成精细化工有限公司 | 一种用于蚊蝇的杀虫增效组合物 |
CN102450282A (zh) * | 2010-10-20 | 2012-05-16 | 周端午 | 绿色、长效人兽共患疾病传播媒介系列防控药剂 |
-
2016
- 2016-12-17 CN CN201611172206.8A patent/CN106614657B/zh active Active
Patent Citations (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN101690495A (zh) * | 2009-08-28 | 2010-04-07 | 南通功成精细化工有限公司 | 一种用于蚊蝇的杀虫增效组合物 |
CN102450282A (zh) * | 2010-10-20 | 2012-05-16 | 周端午 | 绿色、长效人兽共患疾病传播媒介系列防控药剂 |
Non-Patent Citations (1)
Title |
---|
杀虫剂吡丙醚;谭海军等;《现代农药》;20110430;第10卷(第2期);第40-45页 * |
Also Published As
Publication number | Publication date |
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CN106614657A (zh) | 2017-05-10 |
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Address after: Fuchang Village, Laocheng Development Zone, Chengmai County, Hainan Province, 571923 Patentee after: Hainan Zhengye Biotechnology Co.,Ltd. Country or region after: China Patentee after: NATIONWIDE AGRICULTURAL TECHNOLOGY PROMOTION SERVICE CENTER Patentee after: PLANT PROTECTION INSTITUTE, HAINAN ACADEMY OF AGRICULTURAL SCIENCES Address before: 571924 Fuchang village, Laocheng Development Zone, Chengmai County, Hainan Province Patentee before: HAINAN ZHENGYE ZHONGNONG HIGH TECHNOLOGY Co.,Ltd. Country or region before: China Patentee before: NATIONWIDE AGRICULTURAL TECHNOLOGY PROMOTION SERVICE CENTER Patentee before: PLANT PROTECTION INSTITUTE, HAINAN ACADEMY OF AGRICULTURAL SCIENCES |