CN106592283A - High-temperature-resistant formaldehyde-free color fixing agent and preparation method thereof - Google Patents
High-temperature-resistant formaldehyde-free color fixing agent and preparation method thereof Download PDFInfo
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- CN106592283A CN106592283A CN201611142203.XA CN201611142203A CN106592283A CN 106592283 A CN106592283 A CN 106592283A CN 201611142203 A CN201611142203 A CN 201611142203A CN 106592283 A CN106592283 A CN 106592283A
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- salicylic acid
- temperature
- color
- fixing agent
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Links
- 238000002360 preparation method Methods 0.000 title claims abstract description 8
- YGSDEFSMJLZEOE-UHFFFAOYSA-N salicylic acid Chemical compound OC(=O)C1=CC=CC=C1O YGSDEFSMJLZEOE-UHFFFAOYSA-N 0.000 claims abstract description 68
- XTXRWKRVRITETP-UHFFFAOYSA-N Vinyl acetate Chemical compound CC(=O)OC=C XTXRWKRVRITETP-UHFFFAOYSA-N 0.000 claims abstract description 36
- FJKROLUGYXJWQN-UHFFFAOYSA-N papa-hydroxy-benzoic acid Natural products OC(=O)C1=CC=C(O)C=C1 FJKROLUGYXJWQN-UHFFFAOYSA-N 0.000 claims abstract description 34
- 229960004889 salicylic acid Drugs 0.000 claims abstract description 34
- QGBSISYHAICWAH-UHFFFAOYSA-N dicyandiamide Chemical compound NC(N)=NC#N QGBSISYHAICWAH-UHFFFAOYSA-N 0.000 claims abstract description 20
- 239000003795 chemical substances by application Substances 0.000 claims abstract description 15
- 150000002191 fatty alcohols Chemical class 0.000 claims abstract description 15
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 15
- HPNMFZURTQLUMO-UHFFFAOYSA-N diethylamine Chemical compound CCNCC HPNMFZURTQLUMO-UHFFFAOYSA-N 0.000 claims abstract description 13
- 239000000203 mixture Substances 0.000 claims abstract description 6
- 238000003756 stirring Methods 0.000 claims description 35
- 229940117958 vinyl acetate Drugs 0.000 claims description 34
- 238000000034 method Methods 0.000 claims description 31
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 20
- 239000003381 stabilizer Substances 0.000 claims description 17
- 239000002994 raw material Substances 0.000 claims description 11
- PIICEJLVQHRZGT-UHFFFAOYSA-N Ethylenediamine Chemical compound NCCN PIICEJLVQHRZGT-UHFFFAOYSA-N 0.000 claims description 7
- 239000012467 final product Substances 0.000 claims description 7
- 238000010792 warming Methods 0.000 claims description 7
- 239000004744 fabric Substances 0.000 abstract description 14
- 238000005406 washing Methods 0.000 abstract description 8
- 238000004519 manufacturing process Methods 0.000 abstract description 5
- 238000009835 boiling Methods 0.000 abstract description 4
- 230000003993 interaction Effects 0.000 abstract description 2
- 239000000985 reactive dye Substances 0.000 abstract description 2
- 239000000243 solution Substances 0.000 abstract 4
- 239000011259 mixed solution Substances 0.000 abstract 3
- 229920000742 Cotton Polymers 0.000 abstract 1
- 238000009776 industrial production Methods 0.000 abstract 1
- WSFSSNUMVMOOMR-NJFSPNSNSA-N methanone Chemical compound O=[14CH2] WSFSSNUMVMOOMR-NJFSPNSNSA-N 0.000 abstract 1
- 238000002791 soaking Methods 0.000 abstract 1
- WSFSSNUMVMOOMR-UHFFFAOYSA-N Formaldehyde Chemical compound O=C WSFSSNUMVMOOMR-UHFFFAOYSA-N 0.000 description 9
- 239000008367 deionised water Substances 0.000 description 6
- 229910021641 deionized water Inorganic materials 0.000 description 6
- 239000000975 dye Substances 0.000 description 6
- 239000004753 textile Substances 0.000 description 5
- 230000000052 comparative effect Effects 0.000 description 4
- 239000012752 auxiliary agent Substances 0.000 description 3
- 238000005516 engineering process Methods 0.000 description 3
- 241001270131 Agaricus moelleri Species 0.000 description 2
- 238000001514 detection method Methods 0.000 description 2
- 238000004043 dyeing Methods 0.000 description 2
- 235000013861 fat-free Nutrition 0.000 description 2
- 238000010186 staining Methods 0.000 description 2
- QBUKAFSEUHGMMX-MTJSOVHGSA-N (5z)-5-[[3-(1-hydroxyethyl)thiophen-2-yl]methylidene]-10-methoxy-2,2,4-trimethyl-1h-chromeno[3,4-f]quinolin-9-ol Chemical group C1=CC=2NC(C)(C)C=C(C)C=2C2=C1C=1C(OC)=C(O)C=CC=1O\C2=C/C=1SC=CC=1C(C)O QBUKAFSEUHGMMX-MTJSOVHGSA-N 0.000 description 1
- NIPNSKYNPDTRPC-UHFFFAOYSA-N N-[2-oxo-2-(2,4,6,7-tetrahydrotriazolo[4,5-c]pyridin-5-yl)ethyl]-2-[[3-(trifluoromethoxy)phenyl]methylamino]pyrimidine-5-carboxamide Chemical compound O=C(CNC(=O)C=1C=NC(=NC=1)NCC1=CC(=CC=C1)OC(F)(F)F)N1CC2=C(CC1)NN=N2 NIPNSKYNPDTRPC-UHFFFAOYSA-N 0.000 description 1
- 125000000129 anionic group Chemical group 0.000 description 1
- 239000003125 aqueous solvent Substances 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 150000001768 cations Chemical group 0.000 description 1
- 238000011109 contamination Methods 0.000 description 1
- 230000007812 deficiency Effects 0.000 description 1
- 238000002845 discoloration Methods 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 229910001385 heavy metal Inorganic materials 0.000 description 1
- 238000007654 immersion Methods 0.000 description 1
- 150000002500 ions Chemical class 0.000 description 1
- 238000009940 knitting Methods 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 239000000047 product Substances 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 238000009941 weaving Methods 0.000 description 1
Classifications
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P5/00—Other features in dyeing or printing textiles, or dyeing leather, furs, or solid macromolecular substances in any form
- D06P5/02—After-treatment
- D06P5/04—After-treatment with organic compounds
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P3/00—Special processes of dyeing or printing textiles, or dyeing leather, furs, or solid macromolecular substances in any form, classified according to the material treated
- D06P3/58—Material containing hydroxyl groups
- D06P3/60—Natural or regenerated cellulose
- D06P3/66—Natural or regenerated cellulose using reactive dyes
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P5/00—Other features in dyeing or printing textiles, or dyeing leather, furs, or solid macromolecular substances in any form
- D06P5/02—After-treatment
- D06P5/04—After-treatment with organic compounds
- D06P5/06—After-treatment with organic compounds containing nitrogen
Landscapes
- Engineering & Computer Science (AREA)
- Textile Engineering (AREA)
- Coloring (AREA)
Abstract
The invention discloses a high-temperature-resistant formaldehyde-free color fixing agent and a preparation method thereof. The formaldehyde-free color fixing agent is prepared from, by weight, 3-7 parts of fatty alcohol, 15-25 parts of dicyandiamide, 23-31 parts of diethylamine, 8-16 parts of salicylic acid and 11-19 parts of vinyl acetate. Fatty alcohol, dicyandiamide and diethylamine are mixed, heated and stirred, a salicylic acid solution is dropwise added in the mixture while the mixed solution is stirred, the mixed solution is cooled and stirred, then a vinyl acetate solution is added into the mixed solution while the solution is heated and stirred, and the color fixing agent is obtained after the solution is stirred and cooled to room temperature. The color fixing agent prepared under the interaction of all components is free of formaldehyde, and has the advantages of being high in color fastness, improving the dry and wet fastness and the washing color fastness, resisting high temperature, and being environmentally friendly and free of pollution; the color fixing agent is good in color fixation effect, can be applied in color fixation of cotton fabrics dyed with reactive dyes, can improve the washing color fastness and the boiling water soaking fastness, is simple in production process, low in production cost, stable in performance and suitable for industrial production and has broad market prospects.
Description
Technical field
The present invention relates to printing and dyeing assistant technical field, specifically a kind of resistant to elevated temperatures aldehyde-free colour stabilizer and preparation method thereof.
Background technology
During fabric knitting, although some dyeing color and lusters are more beautiful, due to wet process firmness not
It is good, fade and viscous color phenomenon than more serious, this not only causes fabric to seem older in itself, while easily fade when water is met,
It is easier to cause and the mutual staining of other fabrics.
Color fixing agent is the auxiliary agent for improving dyestuff on the fabric used by color moisture resistant fastness.Can be with dyestuff shape on fabric
The washing of color, perspiration fastness are improve into insoluble colored substance, its light fastness can be also improved sometimes.Traditional color fixing agent
Containing the material that formaldehyde etc. is harmful, but with the raising of economic level, requirement more and more higher of the people to textile,
Increasing people is keen to Green Textiles.This is because the auxiliary agent used in the weaving process of fabric does not contain heavy metal
Ion and free formaldehyde is not produced, but the aldehyde-free colour stabilizer washing color fastness for occurring in the market is undesirable, produces work
Skill is complicated, therefore how to overcome the problem that the deficiencies in the prior art are current technical field of textile auxiliary agent urgent need to resolve.
The content of the invention
It is an object of the invention to provide a kind of resistant to elevated temperatures aldehyde-free colour stabilizer and preparation method thereof, to solve above-mentioned background
The problem proposed in technology.
For achieving the above object, the present invention provides following technical scheme：
A kind of resistant to elevated temperatures aldehyde-free colour stabilizer, is made up of the following raw material according to weight portion：Fatty alcohol 3-7 parts, dicyandiamide
15-25 parts, diethylamine 23-31 parts, salicylic acid 8-16 parts, vinylacetate 11-19 parts.
As further scheme of the invention：The resistant to elevated temperatures aldehyde-free colour stabilizer, by the following raw material according to weight portion
Composition：Fatty alcohol 4-6 parts, dicyandiamide 18-22 parts, diethylamine 25-29 parts, salicylic acid 10-14 parts, vinylacetate 13-17 parts.
As further scheme of the invention：The resistant to elevated temperatures aldehyde-free colour stabilizer, by the following raw material according to weight portion
Composition：5 parts of fatty alcohol, 20 parts of dicyandiamide, 27 parts of diethylamine, 12 parts of salicylic acid, 15 parts of vinylacetate.
A kind of preparation method of resistant to elevated temperatures aldehyde-free colour stabilizer, comprises the steps of：
1) salicylic acid and 65% ethanol are hybridly prepared into into the salicylic acid solution that mass concentration is 42%；By vinylacetate
The vinyl acetate solution that mass concentration is 16% is hybridly prepared into deionized water；
2) fatty alcohol, ethylenediamine and dicyandiamide are mixed, is warming up to 86 DEG C, and stir process 72min at such a temperature, so
Deca salicylic acid solution while stirring afterwards, altogether Deca 38min, is down to 62 DEG C and at such a temperature stir process after dripping
66min；Vinyl acetate solution is subsequently adding, stir process 28min at a temperature of 92 DEG C；Then it is cooled to 42 DEG C of temperature
Lower stir process 42-45min, is down to room temperature and obtains final product color fixing agent.
Compared with prior art, the invention has the beneficial effects as follows：
Preparation process is simple of the present invention, obtained color fixing agent does not contain formaldehyde under the interaction of each component, can be by solid
Cation group in dye molecules carries out electrostatical binding with the anionic group in dyestuff, forms insoluble in fabric face
Color lake, and then the aqueous solvent group of dyestuff is closed, so as to improve dyed fabric washing fastness.With dyefastness height, improve
Dry and wet fastness, Washing, high temperature resistant, environmental protection, free of contamination feature, colour fixation is good, can be applicable to reactive dye dye
The fixation treatment of bafta, can improve the washing color fastness and boiling water immersion fastness of fabric, and production technology is easy, production cost
Low, stable performance is suitable to industrialized production, with wide market prospect.
Specific embodiment
Below in conjunction with the embodiment of the present invention, the technical scheme in the embodiment of the present invention is clearly and completely described,
Obviously, described embodiment is only a part of embodiment of the invention, rather than the embodiment of whole.Based in the present invention
Embodiment, the every other embodiment that those of ordinary skill in the art are obtained under the premise of creative work is not made, all
Belong to the scope of protection of the invention.
Embodiment 1
In the embodiment of the present invention, a kind of resistant to elevated temperatures aldehyde-free colour stabilizer is made up of the following raw material according to weight portion：Fat
3 parts of alcohol, 15 parts of dicyandiamide, 23 parts of diethylamine, 8 parts of salicylic acid, 11 parts of vinylacetate.
Salicylic acid and 65% ethanol are hybridly prepared into into the salicylic acid solution that mass concentration is 42%；By vinylacetate with
Deionized water is hybridly prepared into the vinyl acetate solution that mass concentration is 16%.Fatty alcohol, ethylenediamine are mixed with dicyandiamide,
86 DEG C, and stir process 72min at such a temperature are warming up to, then Deca salicylic acid solution while stirring, altogether Deca 38min,
62 DEG C and at such a temperature stir process 66min are down to after dripping；Vinyl acetate solution is subsequently adding, in 92 DEG C of temperature
Lower stir process 28min；Then stir process 42min at a temperature of 42 DEG C is cooled to, room temperature is down to and is obtained final product color fixing agent.
Embodiment 2
In the embodiment of the present invention, a kind of resistant to elevated temperatures aldehyde-free colour stabilizer is made up of the following raw material according to weight portion：Fat
7 parts of alcohol, 25 parts of dicyandiamide, 31 parts of diethylamine, 16 parts of salicylic acid, 19 parts of vinylacetate.
Salicylic acid and 65% ethanol are hybridly prepared into into the salicylic acid solution that mass concentration is 42%；By vinylacetate with
Deionized water is hybridly prepared into the vinyl acetate solution that mass concentration is 16%.Fatty alcohol, ethylenediamine are mixed with dicyandiamide,
86 DEG C, and stir process 72min at such a temperature are warming up to, then Deca salicylic acid solution while stirring, altogether Deca 38min,
62 DEG C and at such a temperature stir process 66min are down to after dripping；Vinyl acetate solution is subsequently adding, in 92 DEG C of temperature
Lower stir process 28min；Then stir process 45min at a temperature of 42 DEG C is cooled to, room temperature is down to and is obtained final product color fixing agent.
Embodiment 3
In the embodiment of the present invention, a kind of resistant to elevated temperatures aldehyde-free colour stabilizer is made up of the following raw material according to weight portion：Fat
4 parts of alcohol, 18 parts of dicyandiamide, 25 parts of diethylamine, 10 parts of salicylic acid, 13 parts of vinylacetate.
Salicylic acid and 65% ethanol are hybridly prepared into into the salicylic acid solution that mass concentration is 42%；By vinylacetate with
Deionized water is hybridly prepared into the vinyl acetate solution that mass concentration is 16%.Fatty alcohol, ethylenediamine are mixed with dicyandiamide,
86 DEG C, and stir process 72min at such a temperature are warming up to, then Deca salicylic acid solution while stirring, altogether Deca 38min,
62 DEG C and at such a temperature stir process 66min are down to after dripping；Vinyl acetate solution is subsequently adding, in 92 DEG C of temperature
Lower stir process 28min；Then stir process 43min at a temperature of 42 DEG C is cooled to, room temperature is down to and is obtained final product color fixing agent.
Embodiment 4
In the embodiment of the present invention, a kind of resistant to elevated temperatures aldehyde-free colour stabilizer is made up of the following raw material according to weight portion：Fat
6 parts of alcohol, 22 parts of dicyandiamide, 29 parts of diethylamine, 14 parts of salicylic acid, 17 parts of vinylacetate.
Salicylic acid and 65% ethanol are hybridly prepared into into the salicylic acid solution that mass concentration is 42%；By vinylacetate with
Deionized water is hybridly prepared into the vinyl acetate solution that mass concentration is 16%.Fatty alcohol, ethylenediamine are mixed with dicyandiamide,
86 DEG C, and stir process 72min at such a temperature are warming up to, then Deca salicylic acid solution while stirring, altogether Deca 38min,
62 DEG C and at such a temperature stir process 66min are down to after dripping；Vinyl acetate solution is subsequently adding, in 92 DEG C of temperature
Lower stir process 28min；Then stir process 43min at a temperature of 42 DEG C is cooled to, room temperature is down to and is obtained final product color fixing agent.
Embodiment 5
In the embodiment of the present invention, a kind of resistant to elevated temperatures aldehyde-free colour stabilizer is made up of the following raw material according to weight portion：Fat
5 parts of alcohol, 20 parts of dicyandiamide, 27 parts of diethylamine, 12 parts of salicylic acid, 15 parts of vinylacetate.
Salicylic acid and 65% ethanol are hybridly prepared into into the salicylic acid solution that mass concentration is 42%；By vinylacetate with
Deionized water is hybridly prepared into the vinyl acetate solution that mass concentration is 16%.Fatty alcohol, ethylenediamine are mixed with dicyandiamide,
86 DEG C, and stir process 72min at such a temperature are warming up to, then Deca salicylic acid solution while stirring, altogether Deca 38min,
62 DEG C and at such a temperature stir process 66min are down to after dripping；Vinyl acetate solution is subsequently adding, in 92 DEG C of temperature
Lower stir process 28min；Then stir process 43min at a temperature of 42 DEG C is cooled to, room temperature is down to and is obtained final product color fixing agent.
Comparative example 1
In addition to fat-free alcohol, other are consistent with embodiment 5.
Comparative example 2
In addition to without vinylacetate, other are consistent with embodiment 5.
Comparative example 3
In addition to fat-free alcohol, vinylacetate, other are consistent with embodiment 5.
Using the performance detection and the fabric of non-fixation of embodiment of the present invention 1-5 and the fabric of comparative example 1-3 product fixation
Compare, its data is as shown in table 1.
The performance detection data of table 1
Note：
1st, color fastness to washing：By GB/T3921-2008《Textile color stability is tested：Fastness to soaping》Method is determined.
2nd, colour fastness to rubbing：By GB/T3920-2008《Textile color stability is tested：Colour fastness to rubbing》Method is surveyed
It is fixed.
3rd, rating is respectively with GB/T250-2008 discoloration gray scales and GB/T251-2008 staining gray scales.Color
Degree difference Δ CC:Sample L*, a*, b* are measured with computer colour matching instrument Gretag Macbeth Color-EYER 3100, is then pressed
CIELAB color difference formula is calculated.
4th, resistance to boiling water soaks fastness：By the cloth specimen after fixation, by bath raio 1:20, soak 5- in 100 DEG C of boiling water
10min, then takes out cloth specimen, sees that residual night foot water fades the depth.Foot water color is deeper, and series is lower.5 grades of water white transparencies, preferably,
1 grade is color depth, by that analogy.
It is obvious to a person skilled in the art that the invention is not restricted to the details of above-mentioned one exemplary embodiment, Er Qie
In the case of spirit or essential attributes without departing substantially from the present invention, the present invention can be in other specific forms realized.Therefore, no matter
From the point of view of which point, embodiment all should be regarded as exemplary, and be nonrestrictive, the scope of the present invention is by appended power
Profit is required rather than described above is limited, it is intended that all in the implication and scope of the equivalency of claim by falling
Change is included in the present invention.
Moreover, it will be appreciated that although this specification is been described by according to embodiment, not each embodiment is only wrapped
Containing an independent technical scheme, this narrating mode of description is only that for clarity those skilled in the art should
Using description as an entirety, the technical scheme in each embodiment can also Jing it is appropriately combined, form those skilled in the art
Understandable other embodiment.
Claims (4)
1. a kind of resistant to elevated temperatures aldehyde-free colour stabilizer, it is characterised in that be made up of the following raw material according to weight portion：Fatty alcohol 3-7
Part, dicyandiamide 15-25 parts, diethylamine 23-31 parts, salicylic acid 8-16 parts, vinylacetate 11-19 parts.
2. resistant to elevated temperatures aldehyde-free colour stabilizer according to claim 1, it is characterised in that by the following raw material according to weight portion
Composition：Fatty alcohol 4-6 parts, dicyandiamide 18-22 parts, diethylamine 25-29 parts, salicylic acid 10-14 parts, vinylacetate 13-17 parts.
3. resistant to elevated temperatures aldehyde-free colour stabilizer according to claim 1, it is characterised in that by the following raw material according to weight portion
Composition：5 parts of fatty alcohol, 20 parts of dicyandiamide, 27 parts of diethylamine, 12 parts of salicylic acid, 15 parts of vinylacetate.
4. a kind of preparation method of the resistant to elevated temperatures aldehyde-free colour stabilizer as described in claim 1-3 is arbitrary, it is characterised in that by with
Lower step composition：
1) salicylic acid and 65% ethanol are hybridly prepared into into the salicylic acid solution that mass concentration is 42%；By vinylacetate with go
Ionized water is hybridly prepared into the vinyl acetate solution that mass concentration is 16%；
2) fatty alcohol, ethylenediamine and dicyandiamide are mixed, is warming up to 86 DEG C, and stir process 72min at such a temperature, Ran Houbian
Stirring side Deca salicylic acid solution, altogether Deca 38min, is down to 62 DEG C and at such a temperature stir process 66min after dripping；So
After add vinyl acetate solution, stir process 28min at a temperature of 92 DEG C；Then it is cooled at a temperature of 42 DEG C at stirring
Reason 42-45min, is down to room temperature and obtains final product color fixing agent.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201611142203.XA CN106592283B (en) | 2016-12-12 | 2016-12-12 | A kind of heat safe aldehyde-free colour stabilizer and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201611142203.XA CN106592283B (en) | 2016-12-12 | 2016-12-12 | A kind of heat safe aldehyde-free colour stabilizer and preparation method thereof |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN106592283A true CN106592283A (en) | 2017-04-26 |
| CN106592283B CN106592283B (en) | 2018-10-09 |
Family
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| CN201611142203.XA Active CN106592283B (en) | 2016-12-12 | 2016-12-12 | A kind of heat safe aldehyde-free colour stabilizer and preparation method thereof |
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Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN109577045A (en) * | 2018-12-28 | 2019-04-05 | 北京泛博科技有限责任公司 | A kind of fur color fixing agent and its preparation method and application |
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|---|---|---|---|---|
| WO2009103615A1 (en) * | 2008-02-21 | 2009-08-27 | Unilever Plc | Improvements relating to benefit particles |
| CN102493232A (en) * | 2010-06-30 | 2012-06-13 | 苏州大学 | Formaldehyde-free fixing agent for active dye |
| CN103343464A (en) * | 2013-06-24 | 2013-10-09 | 张家港市东方特种染色有限公司 | Textile printing and dyeing pigment color fixing agent and preparation method thereof |
| CN103469640A (en) * | 2013-09-25 | 2013-12-25 | 句容市后白镇迎瑞印花厂 | Dye fixing agent and preparation method thereof |
| CN105544254A (en) * | 2015-12-18 | 2016-05-04 | 常熟市通顺印染有限公司 | Special cleaning solution for dyed fabrics |
-
2016
- 2016-12-12 CN CN201611142203.XA patent/CN106592283B/en active Active
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2009103615A1 (en) * | 2008-02-21 | 2009-08-27 | Unilever Plc | Improvements relating to benefit particles |
| CN102493232A (en) * | 2010-06-30 | 2012-06-13 | 苏州大学 | Formaldehyde-free fixing agent for active dye |
| CN103343464A (en) * | 2013-06-24 | 2013-10-09 | 张家港市东方特种染色有限公司 | Textile printing and dyeing pigment color fixing agent and preparation method thereof |
| CN103469640A (en) * | 2013-09-25 | 2013-12-25 | 句容市后白镇迎瑞印花厂 | Dye fixing agent and preparation method thereof |
| CN105544254A (en) * | 2015-12-18 | 2016-05-04 | 常熟市通顺印染有限公司 | Special cleaning solution for dyed fabrics |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN109577045A (en) * | 2018-12-28 | 2019-04-05 | 北京泛博科技有限责任公司 | A kind of fur color fixing agent and its preparation method and application |
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| CN106592283B (en) | 2018-10-09 |
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