CN106590874A - Composition of total-synthesis high temperature resistance anti-radiation nuclear equipment high-speed bearing circulation oil - Google Patents

Composition of total-synthesis high temperature resistance anti-radiation nuclear equipment high-speed bearing circulation oil Download PDF

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Publication number
CN106590874A
CN106590874A CN201611066759.5A CN201611066759A CN106590874A CN 106590874 A CN106590874 A CN 106590874A CN 201611066759 A CN201611066759 A CN 201611066759A CN 106590874 A CN106590874 A CN 106590874A
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China
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agent
high temperature
resisting
speed bearing
nuclear equipment
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黄福川
李康春
邓富康
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Guangxi University
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Guangxi University
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Priority to CN201611066759.5A priority Critical patent/CN106590874A/en
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    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M169/00—Lubricating compositions characterised by containing as components a mixture of at least two types of ingredient selected from base-materials, thickeners or additives, covered by the preceding groups, each of these compounds being essential
    • C10M169/04—Mixtures of base-materials and additives
    • C10M169/044—Mixtures of base-materials and additives the additives being a mixture of non-macromolecular and macromolecular compounds
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M169/00—Lubricating compositions characterised by containing as components a mixture of at least two types of ingredient selected from base-materials, thickeners or additives, covered by the preceding groups, each of these compounds being essential
    • C10M169/04—Mixtures of base-materials and additives
    • C10M169/045—Mixtures of base-materials and additives the additives being a mixture of compounds of unknown or incompletely defined constitution and non-macromolecular compounds
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2205/00—Organic macromolecular hydrocarbon compounds or fractions, whether or not modified by oxidation as ingredients in lubricant compositions
    • C10M2205/02—Organic macromolecular hydrocarbon compounds or fractions, whether or not modified by oxidation as ingredients in lubricant compositions containing acyclic monomers
    • C10M2205/0206—Organic macromolecular hydrocarbon compounds or fractions, whether or not modified by oxidation as ingredients in lubricant compositions containing acyclic monomers used as base material
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
    • C10M2207/10—Carboxylix acids; Neutral salts thereof
    • C10M2207/22—Acids obtained from polymerised unsaturated acids
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2209/00—Organic macromolecular compounds containing oxygen as ingredients in lubricant compositions
    • C10M2209/10—Macromolecular compoundss obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • C10M2209/103—Polyethers, i.e. containing di- or higher polyoxyalkylene groups
    • C10M2209/1033—Polyethers, i.e. containing di- or higher polyoxyalkylene groups used as base material
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2215/00—Organic non-macromolecular compounds containing nitrogen as ingredients in lubricant compositions
    • C10M2215/02—Amines, e.g. polyalkylene polyamines; Quaternary amines
    • C10M2215/06—Amines, e.g. polyalkylene polyamines; Quaternary amines having amino groups bound to carbon atoms of six-membered aromatic rings
    • C10M2215/064—Di- and triaryl amines
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2215/00—Organic non-macromolecular compounds containing nitrogen as ingredients in lubricant compositions
    • C10M2215/22—Heterocyclic nitrogen compounds
    • C10M2215/223—Five-membered rings containing nitrogen and carbon only
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2219/00—Organic non-macromolecular compounds containing sulfur, selenium or tellurium as ingredients in lubricant compositions
    • C10M2219/04—Organic non-macromolecular compounds containing sulfur, selenium or tellurium as ingredients in lubricant compositions containing sulfur-to-oxygen bonds, i.e. sulfones, sulfoxides
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2219/00—Organic non-macromolecular compounds containing sulfur, selenium or tellurium as ingredients in lubricant compositions
    • C10M2219/04—Organic non-macromolecular compounds containing sulfur, selenium or tellurium as ingredients in lubricant compositions containing sulfur-to-oxygen bonds, i.e. sulfones, sulfoxides
    • C10M2219/044—Sulfonic acids, Derivatives thereof, e.g. neutral salts
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2219/00—Organic non-macromolecular compounds containing sulfur, selenium or tellurium as ingredients in lubricant compositions
    • C10M2219/06—Thio-acids; Thiocyanates; Derivatives thereof
    • C10M2219/062—Thio-acids; Thiocyanates; Derivatives thereof having carbon-to-sulfur double bonds
    • C10M2219/066—Thiocarbamic type compounds
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2219/00—Organic non-macromolecular compounds containing sulfur, selenium or tellurium as ingredients in lubricant compositions
    • C10M2219/08—Thiols; Sulfides; Polysulfides; Mercaptals
    • C10M2219/082—Thiols; Sulfides; Polysulfides; Mercaptals containing sulfur atoms bound to acyclic or cycloaliphatic carbon atoms
    • C10M2219/087—Thiols; Sulfides; Polysulfides; Mercaptals containing sulfur atoms bound to acyclic or cycloaliphatic carbon atoms containing hydroxy groups; Derivatives thereof, e.g. sulfurised phenols
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2219/00—Organic non-macromolecular compounds containing sulfur, selenium or tellurium as ingredients in lubricant compositions
    • C10M2219/10—Heterocyclic compounds containing sulfur, selenium or tellurium compounds in the ring
    • C10M2219/104—Heterocyclic compounds containing sulfur, selenium or tellurium compounds in the ring containing sulfur and carbon with nitrogen or oxygen in the ring
    • C10M2219/106—Thiadiazoles
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2223/00—Organic non-macromolecular compounds containing phosphorus as ingredients in lubricant compositions
    • C10M2223/02—Organic non-macromolecular compounds containing phosphorus as ingredients in lubricant compositions having no phosphorus-to-carbon bonds
    • C10M2223/04—Phosphate esters
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2223/00—Organic non-macromolecular compounds containing phosphorus as ingredients in lubricant compositions
    • C10M2223/02—Organic non-macromolecular compounds containing phosphorus as ingredients in lubricant compositions having no phosphorus-to-carbon bonds
    • C10M2223/04—Phosphate esters
    • C10M2223/045—Metal containing thio derivatives
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2223/00—Organic non-macromolecular compounds containing phosphorus as ingredients in lubricant compositions
    • C10M2223/02—Organic non-macromolecular compounds containing phosphorus as ingredients in lubricant compositions having no phosphorus-to-carbon bonds
    • C10M2223/04—Phosphate esters
    • C10M2223/047—Thioderivatives not containing metallic elements
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2223/00—Organic non-macromolecular compounds containing phosphorus as ingredients in lubricant compositions
    • C10M2223/06—Organic non-macromolecular compounds containing phosphorus as ingredients in lubricant compositions having phosphorus-to-carbon bonds
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2227/00—Organic non-macromolecular compounds containing atoms of elements not provided for in groups C10M2203/00, C10M2207/00, C10M2211/00, C10M2215/00, C10M2219/00 or C10M2223/00 as ingredients in lubricant compositions
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2030/00—Specified physical or chemical properties which is improved by the additive characterising the lubricating composition, e.g. multifunctional additives
    • C10N2030/10—Inhibition of oxidation, e.g. anti-oxidants
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2030/00—Specified physical or chemical properties which is improved by the additive characterising the lubricating composition, e.g. multifunctional additives
    • C10N2030/12—Inhibition of corrosion, e.g. anti-rust agents or anti-corrosives
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2030/00—Specified physical or chemical properties which is improved by the additive characterising the lubricating composition, e.g. multifunctional additives
    • C10N2030/16—Antiseptic; (micro) biocidal or bactericidal
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2030/00—Specified physical or chemical properties which is improved by the additive characterising the lubricating composition, e.g. multifunctional additives
    • C10N2030/18—Anti-foaming property
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2030/00—Specified physical or chemical properties which is improved by the additive characterising the lubricating composition, e.g. multifunctional additives
    • C10N2030/68—Shear stability
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2040/00—Specified use or application for which the lubricating composition is intended
    • C10N2040/02—Bearings

Abstract

The invention discloses a composition of total-synthesis high temperature resistance anti-radiation nuclear equipment high-speed bearing circulation oil. 50% of poly alpha-alkene and 50% of perfluoropolyether are composited by mass to be adopted as base oil, and various composite additives are matched and include an antioxidant, a metal deactivator, an oiliness agent, a friction improver, an anti-wear agent, an extreme pressure agent, an anti-rust agent, an anti-foaming agent, a reinforcer, a cooling accelerant and an antioxidation additive. The composition has the properties of resisting emulsion, resisting foams, removing foams, resisting oxidation, resisting hearing, resisting corrosion, resisting radiation, resisting salt and resisting a high-intensity magnetic field.

Description

A kind of compositionss of complete synthesis high temperature resistant radioprotective nuclear equipment high-speed bearing recycle oil
Technical field
A kind of compositionss of complete synthesis high temperature resistant radioprotective nuclear equipment high-speed bearing recycle oil of the present invention belong to bearing lubrication Agent field.
Background technology
The bearing lubrication purpose of nuclear equipment is by supplying the lubricating oil between rubbing surface, being allowed to form oil film, so as to dispersion Load simultaneously reduces friction, abrasion, noise and vibration, prevents bearing from sintering.Bearing recycle oil is mainly used in oil cooling bearing.By Bearing in the fluid machines of the particular/special requirement such as naval vessel nuclear power station of operating mode, generally in high temperature, high pressure, the state for radiating Lower work, it is desirable to bearing recycle oil guarantee viscosity required for the oil film to form enough support loading intensity, oiliness, cooling and Extreme pressure anti-wear, will have and be enough to because high-speed motion and radiation, friction produce mobility and the diffusibility that heat is excluded, to have guaranteed To antifriction, cooling, cleaning, rust cleaning, sealing effect, and possess emulsion resistance, anti-bubble, froth breaking, antioxidation, anti-shearing, anti-rotten, anti- The performances such as radiation, salt resistance, anti-high-intensity magnetic field.
The content of the invention
The technical problem to be solved in the present invention is to provide one kind and possesses emulsion resistance, anti-bubble, froth breaking, antioxidation, anti-shearing, anti- Corruption, radioprotective, salt resistance, the combination of the complete synthesis high temperature resistant radioprotective nuclear equipment high-speed bearing recycle oil of the performance of anti-high-intensity magnetic field Thing.
The present invention adopts the following technical scheme that solution above-mentioned technical problem：
A kind of compositionss of complete synthesis high temperature resistant radioprotective nuclear equipment high-speed bearing recycle oil, using the poly- of mass ratio 50% Oil based on alpha-olefin and 50% PFPE, coordinates various compound additives, its each mass percent into packet Into：
Component Mass percentage content
Base oil Surplus
Antioxidant 0.1%～0.3%
Metal deactivator 0.3%～0.5%
Oiliness improver 1.5%～2.0%
Friction improver 1.5%～2.0%
Antiwear additive 1.5%～2.0%
Extreme pressure agent 1.0%～2.0%
Antirust agent 0.3%～0.5%
Anti-foaming agent 10～30ppm
Reinforcing agent 0.5%～0.8%
Urge cryogen 0.6%～1.0%
Antioxidant preservative 0.8%～1.2%
The mass percent summation of above each component is 100%.
Antioxidant is that the pungent/butyl diphenylamines T557 of the sulfenyl phenolate T504 and 50% of mass ratio 50% is combined；
Metal deactivator is that benzotriazole derivant T551 and 50% thiadiazole of mass ratio 50% are combined.
Oiliness improver is dimeric dibasic acid T402；Friction improver is phosphate ester T451.
Antiwear additive is sulfur phosphoric acid nitrogen containing derivative T305；Extreme pressure agent is boronation phosphate ester T3011.
Antirust agent is that the alkyl phosphoric acid imidazoline salt T708 of the BTA T706 and 50% of mass ratio 50% is combined；It is anti- Infusion is No. 3 composite anti-foam agent T923.
Reinforcing agent is Sulphurized Oxymolybdenum Dialkylthiophosphate MoDTP；Cryogen is urged to be petroleum sodium sulfonate；Antioxidant preservative is Dialkyl dithio amino formate.
The present invention remarkable advantage be：The compositionss of the present invention possess emulsion resistance, anti-bubble, froth breaking, antioxidation, shearing resistance Cut, anti-corruption, radioprotective, salt resistance, the performance of anti-high-intensity magnetic field.
Specific embodiment
Embodiment 1：
Following ingredients are reconciled by mass percentage and is formed：
The mass percent summation of above each component is 100%.
Embodiment 2：
Following ingredients are reconciled by mass percentage and is formed：
The mass percent summation of above each component is 100%.
Embodiment 3：
Following ingredients are reconciled by mass percentage and is formed：
The mass percent summation of above each component is 100%.
The typical physical and chemical index of the product of embodiment 3：
Project Quality index
40 DEG C of kinematic viscosity/(mm2﹒ s-1) 43.6
Viscosity Index 169
Pour point/DEG C -61
Flash-point (opening)/DEG C 276
24 DEG C of spumescence (foam tendentiousness/foam stability)/(mL/mL) 100/10
Copper strip test (100 DEG C, 3h)/level 1
Liquid-phase corrosion test (artificial seawater) It is rustless
Oxidation stability：Acid number reaches 2.0mgKOH/g times/h 12000
Rubber seal adaptability index 4
Moisture/% Vestige
Mechanical admixture/% 0.001
Resistance to emulsion (40-37-3mL)/min 4
Demulsification value/min 10
Air release value (50 DEG C)/min 7
Wear resistence, FZG (A/83/90)/failure level 13
Tetra-ball machine test Pb/N 889
The typical physical and chemical index of the product of embodiment 2：
Project Quality index
40 DEG C of kinematic viscosity/(mm2﹒ s-1) 43.3
Viscosity Index 172
Pour point/DEG C -63
Flash-point (opening)/DEG C 272
24 DEG C of spumescence (foam tendentiousness/foam stability)/(mL/mL) 80/10
Copper strip test (100 DEG C, 3h)/level 1
Liquid-phase corrosion test (artificial seawater) It is rustless
Oxidation stability：Acid number reaches 2.0mgKOH/g times/h 12000
Rubber seal adaptability index 4
Moisture/% Vestige
Mechanical admixture/% 0.001
Resistance to emulsion (40-37-3mL)/min 4
Demulsification value/min 9
Air release value (50 DEG C)/min 6.5
Wear resistence, FZG (A/83/90)/failure level 13
Tetra-ball machine test Pb/N 880
The typical physical and chemical index of the product of embodiment 1：
Project Quality index
40 DEG C of kinematic viscosity/(mm2﹒ s-1) 43.1
Viscosity Index 165
Pour point/DEG C -62
Flash-point (opening)/DEG C 279
24 DEG C of spumescence (foam tendentiousness/foam stability)/(mL/mL) 80/10
Copper strip test (100 DEG C, 3h)/level 1
Liquid-phase corrosion test (artificial seawater) It is rustless
Oxidation stability：Acid number reaches 2.0mgKOH/g times/h 12000
Rubber seal adaptability index 4
Moisture/% Vestige
Mechanical admixture/% 0.001
Resistance to emulsion (40-37-3mL)/min 4
Demulsification value/min 9
Air release value (50 DEG C)/min 7
Wear resistence, FZG (A/83/90)/failure level 13
Tetra-ball machine test Pb/N 892

Claims (6)

1. a kind of compositionss of complete synthesis high temperature resistant radioprotective nuclear equipment high-speed bearing recycle oil, it is characterised in that：Using quality Oil based on poly alpha olefin and 50% PFPE than 50%, coordinates various compound additives, its respective quality percentage It is several into being grouped into：
Component Mass percentage content Base oil Surplus Antioxidant 0.1%～0.3% Metal deactivator 0.3%～0.5% Oiliness improver 1.5%～2.0% Friction improver 1.5%～2.0% Antiwear additive 1.5%～2.0% Extreme pressure agent 1.0%～2.0% Antirust agent 0.3%～0.5% Anti-foaming agent 10～30ppm Reinforcing agent 0.5%～0.8% Urge cryogen 0.6%～1.0% Antioxidant preservative 0.8%～1.2%
The mass percent summation of above each component is 100%.
2. a kind of compositionss of complete synthesis high temperature resistant radioprotective nuclear equipment high-speed bearing recycle oil as claimed in claim 1, its It is characterised by that antioxidant is that the pungent/butyl diphenylamines T557 of the sulfenyl phenolate T504 and 50% of mass ratio 50% is combined；Metal Passivator is that benzotriazole derivant T551 and 50% thiadiazole of mass ratio 50% are combined.
3. a kind of compositionss of complete synthesis high temperature resistant radioprotective nuclear equipment high-speed bearing recycle oil as claimed in claim 1, its It is characterised by that oiliness improver is dimeric dibasic acid T402；Friction improver is phosphate ester T451.
4. as claimed in claim 1 a kind of anti-spoke nuclear equipment of complete synthesis high temperature resistant penetrates the compositionss of high-speed bearing recycle oil, its It is characterised by that antiwear additive is sulfur phosphoric acid nitrogen containing derivative T305；Extreme pressure agent is boronation phosphate ester T3011.
5. a kind of compositionss of complete synthesis high temperature resistant radioprotective nuclear equipment high-speed bearing recycle oil as claimed in claim 1, its It is characterised by that antirust agent is that the alkyl phosphoric acid imidazoline salt T708 of the BTA T706 and 50% of mass ratio 50% is combined；It is anti- Infusion is No. 3 composite anti-foam agent T923.
6. a kind of compositionss of complete synthesis high temperature resistant radioprotective nuclear equipment high-speed bearing recycle oil as claimed in claim 1, its It is characterised by that reinforcing agent is Sulphurized Oxymolybdenum Dialkylthiophosphate MoDTP；Cryogen is urged to be petroleum sodium sulfonate；Antioxidant preservative is Dialkyl dithio amino formate.
CN201611066759.5A 2016-11-28 2016-11-28 Composition of total-synthesis high temperature resistance anti-radiation nuclear equipment high-speed bearing circulation oil Pending CN106590874A (en)

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CN201611066759.5A Pending CN106590874A (en) 2016-11-28 2016-11-28 Composition of total-synthesis high temperature resistance anti-radiation nuclear equipment high-speed bearing circulation oil

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2022241683A1 (en) * 2021-05-19 2022-11-24 安美科技股份有限公司 Fiber lubricant and preparation method therefor

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN104450073A (en) * 2014-11-17 2015-03-25 广西大学 Adiabatic lubricant composition for diesel engine
CN105087107A (en) * 2015-08-31 2015-11-25 宁夏宝塔石化科技实业发展有限公司 Preparation method of bearing lubricating grease
CN105400573A (en) * 2015-11-23 2016-03-16 广西大学 Lubricant composition for oil-gas lubricating system for high-speed bearing

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN104450073A (en) * 2014-11-17 2015-03-25 广西大学 Adiabatic lubricant composition for diesel engine
CN105087107A (en) * 2015-08-31 2015-11-25 宁夏宝塔石化科技实业发展有限公司 Preparation method of bearing lubricating grease
CN105400573A (en) * 2015-11-23 2016-03-16 广西大学 Lubricant composition for oil-gas lubricating system for high-speed bearing

Non-Patent Citations (2)

* Cited by examiner, † Cited by third party
Title
唐晓东: "《石油加工助剂作用原理与应用》", 30 November 2004, 石油工业出版社 *
汪建业等: "《机械润滑设计手册与图集》", 30 September 2016, 机械工业出版社 *

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2022241683A1 (en) * 2021-05-19 2022-11-24 安美科技股份有限公司 Fiber lubricant and preparation method therefor

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